High-resolution NMR spectra in inhomogeneous fields utilizing the CRAZED sequence without coherence selection gradients.
Coherence selection gradients have been considered as indispensable for high-resolution NMR spectroscopy in inhomogeneous fields utilizing the CRAZED-type sequences. However, our experimental results demonstrate that these gradients can be omitted if an appropriate phase cycling is applied. The measured linewidth of reconstructing 1D high-resolution spectral peaks does not depend on the dipolar correlation distance determined by the coherence selection gradients, but is only affected by diffusion and T(2) relaxation. This finding suggests the need to reconsider the mechanism for the iMQC-based high-resolution spectroscopy.
Cai
Congbo
C
Department of Physics, State Key Laboratory for Physical Chemistry of Solid Surface, Xiamen University, Siming South Road, Xiamen, Fujian 361005, China.
Lin
Yanqin
Y
Cai
Shuhui
S
Chen
Zhong
Z
Zhong
Jianhui
J