Dinickel complexes of disubstituted benzoate polydentate ligands: mimics for the active site of urease.
Two dinickel mimics, [LNi2(DMF)4](ClO4)3 () and [L'Ni2(CH3CN)4](ClO4)3 (), for the active site of urease supported by a disubstituted benzoate polydentate ligand were synthesized and fully characterized, subsequently addition of urea afforded two urea adducts, [LNi2(urea)4](ClO4)3 () and [L'Ni2(urea)4](ClO4)3 ().
Lee
Way-Zen
WZ
Department of Chemistry, National Taiwan Normal University, 88 Sec. 4 Ting-Chow Rd., Taipei, 11677, Taiwan. wzlee@ntnu.edu.tw
Tseng
Huan-Sheng
HS
Ku
Meng-Yu
MY
Kuo
Ting-Shen
TS
D001565:Benzoates / Q000737:chemistry*; D001665:Binding Sites; D008024:Ligands; D018716:Molecular Mimicry; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis*; D013696:Temperature; D014508:Urea / Q000737:chemistry; D014510:Urease / Q000737:chemistry / Q000378:metabolism*
D001565:Benzoates; D008024:Ligands; D009942:Organometallic Compounds; D009532:Nickel; D014508:Urea; D014510:Urease