A "jellyfish" shaped green emitting gallium(III)-containing metallomesogen.
The synthesis of the first gallium(III)-based liquid crystal has been achieved grafting around the metal centre two chelating 2-methylquinolin-8-olate anions and one monodentate 3,4,5-tris(hexadecyloxy)benzoyloxy ligand, allowing the resulting complex to be a soft luminescent material with the typical high quantum yield of pentacordinated gallium species.
Pucci
Daniela
D
Centro di Eccellenza CEMIF.CAL, LASCAMM CR-INSTM Unità INSTM della Calabria and Laboratorio Regionale Licryl, CNR-INFM, Dipartimento di Chimica, Università della Calabria, 87030, Arcavacata di Rende (CS), Italy. d.pucci@unical.it
Aiello
Iolinda
I
Bellusci
Anna
A
Crispini
Alessandra
A
De Franco
Irene
I
Ghedini
Mauro
M
La Deda
Massimo
M
D001555:Benzene Derivatives / Q000737:chemistry; D018360:Crystallography, X-Ray; D005708:Gallium / Q000737:chemistry*; D008024:Ligands; D050866:Liquid Crystals / Q000737:chemistry; D049449:Luminescence; D009942:Organometallic Compounds / Q000737:chemistry*; D011798:Quinaldines / Q000737:chemistry
D001555:Benzene Derivatives; D008024:Ligands; D009942:Organometallic Compounds; D011798:Quinaldines; D005708:Gallium; C037073:2-methylquinoline