title: Towards organocatalytic polyketide synthases with diverse electrophile scope: trifluoroethyl thioesters as nucleophiles in organocatalytic Michael reactions and beyond.
authors.affiliation: The Skaggs Institute for Chemical Biology and the Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA.
authors.forename: Diego A
authors.initials: DA
authors.lastname: Alonso
authors.forename: Shinji
authors.initials: S
authors.lastname: Kitagaki
authors.forename: Naoto
authors.initials: N
authors.lastname: Utsumi
authors.forename: Carlos F
authors.initials: CF
authors.lastname: Barbas
mesh_terms: D040761:Biomimetic Materials / Q000138:chemical synthesis*; D002384:Catalysis; D004952:Esters; D048630:Polyketide Synthases / Q000737:chemistry*; D013438:Sulfhydryl Compounds
chemical_list: D004952:Esters; D013438:Sulfhydryl Compounds; D048630:Polyketide Synthases