An alternative tuning approach to enhance NMR signals.
By using spin-noise type measurement we show that the resonance frequency of the reception circuit of classical NMR spectrometers does not match the Larmor frequency even if, in emission, the electronic circuit is perfectly tuned at the Larmor frequency and matches the amplifier impedance. We also show that this spin-noise method can be used to ensure a match between the Larmor frequency and the reception circuit resonance frequency. In these conditions, (i) the radiation damping field is in perfect quadrature to the magnetization and (ii) the NMR signal level and potentially the signal-to-noise ratio, are enhanced. This choice induces a change of the probe resonance frequency by several hundreds of kHz for 500 or 700 MHz spectrometer. We show that the resulting mismatch condition for emission can be removed by adding other tuning and matching degrees of freedom located on the excitation line (or by symmetry on the reception line) decoupled to the probe resonance circuit by the crossed diodes.
Marion
Denis J-Y
DJ
Laboratoire de Structure et Dynamique par Résonance Magnétique, Service de Chimie Moléculaire, URA CEA/CNRS 331, CEA/Saclay, 91191 Gif-sur-Yvette, France.
Desvaux
Hervé
H