title: An efficient method for synthesising unsymmetrical silaketals: substrates for ring-closing, including macrocycle-closing, metathesis.
abstract: Diisopropylsilyl ethers were activated with N-bromosuccinimide, and reacted with a fluorous-tagged alcohol, to yield tethered substrates for ring-closing metathesis reactions.
authors.affiliation: School of Chemistry, University of Leeds, Leeds, UK, LS2 9JT.
authors.forename: Christopher
authors.initials: C
authors.lastname: Cordier
authors.forename: Daniel
authors.initials: D
authors.lastname: Morton
authors.forename: Stuart
authors.initials: S
authors.lastname: Leach
authors.forename: Thomas
authors.initials: T
authors.lastname: Woodhall
authors.forename: Catherine
authors.initials: C
authors.lastname: O'Leary-Steele
authors.forename: Stuart
authors.initials: S
authors.lastname: Warriner
authors.forename: Adam
authors.initials: A
authors.lastname: Nelson
mesh_terms: D003432:Cross-Linking Reagents / Q000737:chemistry; D017611:Fluorine Compounds / Q000737:chemistry; D047028:Macrocyclic Compounds / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D012821:Silanes / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D003432:Cross-Linking Reagents; D017611:Fluorine Compounds; D047028:Macrocyclic Compounds; D012821:Silanes