title: Direct synthesis of bicyclic guanidines through unprecedented palladium(ii) catalysed diamination with copper chloride as oxidant.
abstract: Palladium catalysed intramolecular guanidine transfer to alkenes can be accomplished with copper chloride as the oxidant to give bicyclic guanidines with complete selectivity and in high yields.
authors.affiliation: Institut de Chimie, UMR 7177, Université Louis Pasteur, Strasbourg Cedex, France.
authors.forename: Claas H
authors.initials: CH
authors.lastname: Hövelmann
authors.forename: Jan
authors.initials: J
authors.lastname: Streuff
authors.forename: Lydia
authors.initials: L
authors.lastname: Brelot
authors.forename: Kilian
authors.initials: K
authors.lastname: Muñiz
mesh_terms: D000586:Amination; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D003500:Cyclization; D006146:Guanidines / Q000138:chemical synthesis* / Q000737:chemistry; D016877:Oxidants / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry
chemical_list: D006146:Guanidines; D016877:Oxidants; D010165:Palladium; D003300:Copper; C029892:cupric chloride