Blue organic light-emitting supramolecular microfibers: the self-assembly of a 1,2,4-triazolo[1,5-a]pyrimidine derivative.
The design and synthesis of 5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine-2-thioaceto-(2-fluorobenzyl) hydrazone (TPTH), which self-assembled into supramolecular microfibers with blue organic light-emitting properties, is reported. This is the first occurrence of the molecular self-assembly of 1,2,4-triazolo[1,5-a]pyrimidine derivatives.
Liu
Zu-Ming
ZM
Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, PR China.
Wang
Hong-Bo
HB
Zhu
Xiao-Lei
XL
Tu
Hai-Yang
HY
Yang
Guang-Fu
GF
D006860:Hydrogen Bonding / Q000528:radiation effects; D008027:Light; D008855:Microscopy, Electron, Scanning; D008958:Models, Molecular; D011743:Pyrimidines / Q000138:chemical synthesis / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D014230:Triazoles / Q000138:chemical synthesis / Q000737:chemistry*
C419143:1,2,4-triazole(1,5a)pyrimidine; D011743:Pyrimidines; D014230:Triazoles