Stereoselective synthesis of glycosyl amides by traceless Staudinger ligation of unprotected glycosyl azides.
The stereoconservative Staudinger ligation of unprotected alpha- and beta-glucosyl azides with diphenylphosphanyl-phenyl esters to afford alpha- and beta-glucosyl amides is described.
Nisic
Filippo
F
Dipartimento di Chimica Organica e Industriale and CISI, Universita' degli Studi di Milano, Milano, Italy.
Bernardi
Anna
A
D000577:Amides / Q000138:chemical synthesis*; D001386:Azides / Q000737:chemistry; D006027:Glycosides / Q000138:chemical synthesis*; D013237:Stereoisomerism
D000577:Amides; D001386:Azides; D006027:Glycosides