title: O-TBS-N-tosylhydroxylamine: a reagent for facile conversion of alcohols to oximes.
abstract: A variety of oximes were synthesized from the corresponding alcohols, alkyl halides, or alkyl sulfonates without using external oxidants. With this simple two-step procedure involving substitution with readily available TsNHOTBS and subsequent treatment with CsF, a range of oximes were prepared including the ones hardly preparable with conventional procedures.
authors.affiliation: Graduate School of Pharmaceutical Sciences, University of Tokyo, Hongo, Tokyo, Japan.
authors.forename: Katsushi
authors.initials: K
authors.lastname: Kitahara
authors.forename: Tatsuya
authors.initials: T
authors.lastname: Toma
authors.forename: Jun
authors.initials: J
authors.lastname: Shimokawa
authors.forename: Tohru
authors.initials: T
authors.lastname: Fukuyama
mesh_terms: D000438:Alcohols / Q000737:chemistry*; D002586:Cesium / Q000737:chemistry; D005459:Fluorides / Q000737:chemistry; D007202:Indicators and Reagents; D010091:Oximes / Q000737:chemistry*; D014105:Tosyl Compounds / Q000737:chemistry*
chemical_list: D000438:Alcohols; D007202:Indicators and Reagents; D010091:Oximes; D014105:Tosyl Compounds; D002586:Cesium; D005459:Fluorides; C027754:cesium fluoride