Spectral data of two new asymmetric sesquiterpene alcohols: (14R)-beta-oplopenol and (14S)-beta-oplopenol.
The epimeric sesquiterpene alcohols (14R)-beta-oplopenol and (14S)-beta-oplopenolwere obtained by LiAlH(4) reduction of beta-oplopenone. The complete (1)H- and (13)C-NMR assignments of these two new sesquiterpene alcohols have been made using 1D and 2D NMR techniques, including COSY, NOESY, HSQC, HMBC experiments.
Paolini
Julien
J
Université de Corse, UMR-CNRS 6134, Laboratoire de Chimie des Produits Naturels, BP 52, 20250 Corti, France. paolini@univ-corse.fr
Desjobert
Jean-Marie
JM
Muselli
Alain
A
Costa
Jean
J
D000438:Alcohols / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D012717:Sesquiterpenes / Q000737:chemistry*
D000438:Alcohols; D012717:Sesquiterpenes; C529845:beta-oplopenol