title: Indium(i) iodide-catalyzed regio- and diastereoselective formal alpha-addition of an alpha-methylallylboronate to N-acylhydrazones.
abstract: Indium(i) iodide was found to catalyze the formal alpha-addition of an alpha-methylallylboronate to various N-acylhydrazones, in the presence of an alcohol additive, to afford the corresponding anti-alpha-adducts with high regio- and diastereoselectivity in high yields.
authors.affiliation: Department of Chemistry, School of Science and Graduate School of Pharmaceutical Sciences, The University of Tokyo, Tokyo, Japan. shu_kobayashi@chem.s.u-tokyo.ac.jp
authors.forename: Shū
authors.initials: S
authors.lastname: Kobayashi
authors.forename: Hideyuki
authors.initials: H
authors.lastname: Konishi
authors.forename: Uwe
authors.initials: U
authors.lastname: Schneider
mesh_terms: D000498:Allyl Compounds / Q000737:chemistry*; D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D006834:Hydrazines / Q000138:chemical synthesis*; D006835:Hydrazones / Q000737:chemistry*; D007204:Indium / Q000737:chemistry; D007454:Iodides / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D000498:Allyl Compounds; D001897:Boronic Acids; D006834:Hydrazines; D006835:Hydrazones; D007454:Iodides; D007204:Indium