Carbohydrate functionalization using cationic iron carbonyl complexes.
Cationic iron carbonyl cyclohexadiene complexes were employed in the derivatization of the 3-OH position of unprotected and protected methyl beta-D-galactopyranosides using two different approaches, giving access to galactopyranosides with an aromatic or cyclohexadienoic functionality in this position.
Bergh
Anders
A
Organic Chemistry, Department of Chemical and Biological Engineering, Chalmers University of Technology, Göteborg, Sweden.
Gradén
Henrik
H
Pera
Núria Parera
NP
Olsson
Thomas
T
Nilsson
Ulf J
UJ
Kann
Nina
N
D002412:Cations / Q000737:chemistry; D053138:Cyclohexenes / Q000737:chemistry*; D054354:Iron Carbonyl Compounds / Q000737:chemistry*; D008756:Methylgalactosides / Q000138:chemical synthesis / Q000737:chemistry*
D002412:Cations; D053138:Cyclohexenes; D008756:Methylgalactosides; D054354:Iron Carbonyl Compounds