The generation of intense radiofrequency fields in microcoils.
Large amplitude radiofrequency (rf) fields hold great promise in wide line NMR where it becomes possible to excite the full breadth of the line in a quantitative fashion. Applications in quadrupole NMR and in NMR of paramagnetic systems benefit greatly from intense fields. Spin manipulations in multiple quantum NMR experiments, specifically, the generation of multiple quantum coherence in MQ NMR, are more efficiently produced using intense rf fields. In this work we describe a microcoil probe that produces an rf field of 25 MHz, more than five times larger than the greatest rf field reported in the literature. We accomplish this in a robust, 127 microm diameter solenoid coil using 1 kW of rf power.
Hagaman
Edward W
EW
Chemical Sciences Division, Oak Ridge National Laboratory, P.O. Box 2008, 1 Bethel Valley Road, Oak Ridge, TN 37831-6201, USA. hagamanew@ornl.gov
Jiao
Jian
J
Moore
Tony
T