Specific insertion reactions of a germylene, stannylene and plumbylene into the unique P-P bond of the hexaphospha-pentaprismane cage, P6C4tBu4: crystal and molecular structures of P6C4tBu4ER2 (E = Ge, Sn, R = N(SiMe3)2; E = Pb, R = (C6H3(NMe2)2 -2,6).
Treatment of the cage compound P6C4(t)Bu4 with M(N(SiMe3)2)2 (M = Ge or Sn) or Pb(C6H3(NMe2)2- 2,6) at room temperature results in their specific insertion into the P-P bond connecting the two 5-membered P3C2(t)Bu2 rings. The products were fully characterised by multinuclear NMR spectroscopy and single crystal X-ray diffraction studies.
Al-Ktaifani
Mahmoud M
MM
Department of Chemistry, School of Life Sciences, University of Sussex, Brighton, Sussex, UK BN1 9QJ.
Hitchcock
Peter B
PB
Lappert
Michael F
MF
Nixon
John F
JF
Uiterweerd
Philip
P
D018360:Crystallography, X-Ray; D005857:Germanium / Q000737:chemistry*; D007854:Lead / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D009947:Organotin Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D013237:Stereoisomerism
D009942:Organometallic Compounds; D009943:Organophosphorus Compounds; D009947:Organotin Compounds; D005857:Germanium; D007854:Lead