A rare unsupported iridium(II) dimer, [IrCl2(CO)2]2.
Oxidative additions of dichloromethanes to a diiridium(i) core, bridged by 2-ferrocenyl-1,8-naphthyridines (NP-Fc), provide an iridium(II) dimer, [IrCl2(CO)2(eta 1-NP-Fc)]2, featuring an unsupported Ir-Ir single bond (2.7121(8) A).
Patra
Sanjib K
SK
Department of Chemistry, Indian Institute of Technology, Kanpur, 208016, India.
Rahaman
S M Wahidur
SM
Majumdar
Moumita
M
Sinha
Arup
A
Bera
Jitendra K
JK