Metallaborane reaction chemistry. A predicted and found tailored facile and reversible capture of SO2 by a B-frame-supported bimetallic: structures of [(PMe2Ph)2PtPd(phen)B10H10] and [(PMe2Ph)2Pt(SO2)Pd(phen)B10H10].
The formally closo twelve-vertex {ortho-M2B10} dimetallaborane system has been predictively tailored for reversible uptake of SO2 across the metal-metal bond, as exemplified by the formation of [(PMe2Ph)2Pt(SO2)Pd(phen)B10H10] from [(PMe2Ph)2PtPd(phen)B10H10].
Bould
Jonathan
J
The School of Chemistry of the University of Leeds, UKLS2 9JT. jbould@gmail.com
Kennedy
John D
JD
D001880:Boranes / Q000737:chemistry*; D001896:Boron Compounds / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008956:Models, Chemical; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry*; D013458:Sulfur Dioxide / Q000737:chemistry*
D001880:Boranes; D001896:Boron Compounds; D009942:Organometallic Compounds; D013458:Sulfur Dioxide; D010984:Platinum; D010165:Palladium