Toward autonomously operating molecular machines driven by transition-metal catalyst.
A Vaska-type complex carrying a ferrocene-appended diphosphine ligand was developed as a prototype of autonomous molecular machines that is able to undergo continuous scissoring motion in the presence of diphenylphosphoryl azide and aldehyde.
Tanaka
Kenichi
K
Department of Chemistry and Biotechnology, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
Kinbara
Kazushi
K
D000447:Aldehydes / Q000737:chemistry; D001386:Azides / Q000737:chemistry; D002384:Catalysis; D002942:Circular Dichroism; D018360:Crystallography, X-Ray; D005296:Ferrous Compounds / Q000737:chemistry*; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D000075163:Metallocenes; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010666:Phenylpropionates; D010720:Phosphines / Q000737:chemistry; D012015:Reference Standards; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
C520847:3-(2,4-dihydroxyphenyl)propionic acid; D000447:Aldehydes; D001386:Azides; D005296:Ferrous Compounds; D008024:Ligands; D000075163:Metallocenes; D009942:Organometallic Compounds; D010666:Phenylpropionates; D010720:Phosphines; D012238:Rhodium; C007523:diphenylphosphorazidate; C004998:ferrocene