Growth, characterization, vibrational spectroscopic and thermal studies of a new metallorganic non-linear optical crystal-Bisthiourea cadmium bromide.
Single crystals of bisthiourea cadmium bromide (BTCB), a new metallorganic material crystallizing in orthorhombic system were grown from slow evaporation solution growth. The grown crystals were characterized by X-ray diffraction, FTIR and FT-Raman spectral studies. The crystals were also subjected to TGA/DTA analysis and second harmonic generation test. The transmission characteristics of the crystal was also studied.
Ramachandraraja
C
C
Department of Physics, Government Arts College (Autonomous), Kumbakonam 612001, India. crraja_phy@yahoo.com
Sundararajan
R S
RS
D001965:Bromides / Q000737:chemistry*; D002104:Cadmium / Q000737:chemistry*; D002625:Chemistry, Organic / Q000379:methods; D003460:Crystallization; D006860:Hydrogen Bonding; D008670:Metals / Q000737:chemistry; D008956:Models, Chemical; D055095:Optics and Photonics; D009942:Organometallic Compounds / Q000737:chemistry*; D013053:Spectrophotometry / Q000379:methods*; D017550:Spectroscopy, Fourier Transform Infrared; D013059:Spectrum Analysis, Raman / Q000379:methods*; D013696:Temperature; D013818:Thermogravimetry / Q000379:methods; D013890:Thiourea / Q000737:chemistry*; D014961:X-Ray Diffraction
D001965:Bromides; D008670:Metals; D009942:Organometallic Compounds; C538808:bis(thiourea)cadmium(II); D002104:Cadmium; D013890:Thiourea