title: Chelant-aided enhancement of lead mobilization in residential soils.
abstract: Chelation of metals is an important factor in enhancing solubility and hence, availability to plants to promote phytoremediation. We compared the effects of two chelants, namely, ethylenediaminetetraacetic acid (EDTA) and ethylenediaminedisuccinic acid (EDDS) in enhancing mobilized lead (Pb) in Pb-based paint contaminated residential soils collected from San Antonio, Texas and Baltimore, Maryland. Batch incubation studies were performed to investigate the effectiveness of the two chelants in enhancing mobilized Pb, at various concentrations and treatment durations. Over a period of 1 month, the mobilized Pb pool in the San Antonio study soils increased from 52 mg kg(-1) to 287 and 114 mg kg(-1) in the presence of 15 mM kg(-1) EDTA and EDDS, respectively. Stepwise linear regression analysis demonstrated that pH and organic matter content significantly affected the mobilized Pb fraction. The regression models explained a large percentage, from 83 to 99%, of the total variation in mobilized Pb concentrations.
authors.affiliation: Environmental Geochemistry Laboratory, University of Texas at San Antonio, One UTSA Circle, San Antonio, TX 78249-0663, USA. dibyendu.sarkar@utsa.edu
authors.forename: Dibyendu
authors.initials: D
authors.lastname: Sarkar
authors.forename: Syam S
authors.initials: SS
authors.lastname: Andra
authors.forename: Sumathi K M
authors.initials: SK
authors.lastname: Saminathan
authors.forename: Rupali
authors.initials: R
authors.lastname: Datta
mesh_terms: D001673:Biodegradation, Environmental; D002614:Chelating Agents / Q000494:pharmacology*; D004492:Edetic Acid / Q000494:pharmacology; D052918:Environmental Restoration and Remediation / Q000379:methods*; D005029:Ethylenediamines / Q000494:pharmacology; D006798:Housing; D006812:Humic Substances; D006863:Hydrogen-Ion Concentration; D007854:Lead / Q000032:analysis*; D008396:Maryland; D019216:Metals, Heavy / Q000032:analysis; D010150:Paint; D012987:Soil / Q000032:analysis; D012989:Soil Pollutants / Q000032:analysis*; D013386:Succinates / Q000494:pharmacology; D013781:Texas
chemical_list: D002614:Chelating Agents; D005029:Ethylenediamines; D006812:Humic Substances; D019216:Metals, Heavy; D012987:Soil; D012989:Soil Pollutants; D013386:Succinates; C041447:N,N'-ethylenediamine disuccinic acid; D007854:Lead; D004492:Edetic Acid