'Click' cycloaddition catalysts: copper(I) and copper(II) tris(triazolylmethyl)amine complexes.
The CuI complex of the 'click' ligand tris(benzyltriazolylmethyl)amine is an unusual dinuclear dication with one triazole unit bridging two metal centers, and is an effective catalyst for the 'click' cycloaddition reaction.
Donnelly
Paul S
PS
School of Chemistry and Bio21 Institute of Molecular Science and Biotechnology, 30 Flemington Rd, University of Melbourne, Parkville 3010, Australia. pauld@unimelb.edu.au
Zanatta
Shannon D
SD
Zammit
Steven C
SC
White
Jonathan M
JM
Williams
Spencer J
SJ
D000480:Alkynes / Q000737:chemistry; D001386:Azides / Q000138:chemical synthesis / Q000737:chemistry; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D003500:Cyclization; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D014230:Triazoles / Q000138:chemical synthesis / Q000737:chemistry
D000480:Alkynes; D001386:Azides; D008024:Ligands; D009942:Organometallic Compounds; D014230:Triazoles; D003300:Copper