Electronic modification of an aminotroponiminate zinc complex leading to an increased reactivity in the hydroamination of alkenes.
The electronically modified zinc complex 5-phenylsulfanyl-N-isopropyl-2-(isopropylamino)troponiminate zinc methyl, [(PhS-ATI(iPr)2)ZnMe], was synthesized. It showed an increased reactivity in the intramolecular hydroamination reaction of non-activated alkenes compared to a previously-reported, non-substituted complex.
Dochnahl
Maximilian
M
Technische Universität Berlin, Institut für Chemie, Strabe des 17. Juni 135, 10623, Berlin, Germany.
Löhnwitz
Karolin
K
Pissarek
Jens-Wolfgang
JW
Roesky
Peter W
PW
Blechert
Siegfried
S
D000475:Alkenes / Q000737:chemistry*; D000586:Amination; D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D018360:Crystallography, X-Ray; D004583:Electrons; D007097:Imines / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D013237:Stereoisomerism; D014334:Tropolone / Q000031:analogs & derivatives* / Q000737:chemistry; D015032:Zinc / Q000737:chemistry*
D000475:Alkenes; D000588:Amines; D007097:Imines; D008024:Ligands; D009942:Organometallic Compounds; C523247:aminotroponiminate; D014334:Tropolone; D015032:Zinc