title: X-ray microtomography determination of air-water interfacial area-water saturation relationships in sandy porous media.
abstract: In this work, total smooth air-water interfacial areas were measured for a series of nine natural and model sandy porous media as a function of water saturation using synchrotron X-ray microtomography. Interfacial areas decreased linearly with water satuation, while the estimated maximum interfacial area compared favorably to the media geometric surface areas. Importantly, relative interfacial area (i.e., normalized by geometric surface area) versus water saturation plots for all media collapsed into a single linear cluster (r2 = 0.93), suggesting that geometric surface area is an important, and perhaps sufficient, descriptor of sandy media that governs total smooth interfacial area-water saturation relationships. Measured relationships were used to develop an empirical model for estimating interfacial area-water saturation relationships for sandy porous media. Model-based interfacial area estimates for independent media were generally slightly higher than interfacial areas measured using aqueous-phase interfacial tracer methods, which may indicate that microtomography captures regions of the air-water interface that are not accessible to aqueous-phase interfacial tracers. The empirical model presented here requires only average particle diameter and porosity as input parameters and can be used to readily estimate air-water interfacial area-water saturation relationships for sandy porous media.
authors.affiliation: Environmental Studies Program and Department of Chemistry and Biochemistry, Middlebury College, McCardell Bicentennial Hall 446, Middlebury, Vermont 05753, USA. mcostanz@middlebury.edu
authors.forename: Molly S
authors.initials: MS
authors.lastname: Costanza-Robinson
authors.forename: Katherine H
authors.initials: KH
authors.lastname: Harrold
authors.forename: Ross M
authors.initials: RM
authors.lastname: Lieb-Lappen
mesh_terms: D000388:Air; D008956:Models, Chemical; D016062:Porosity; D012822:Silicon Dioxide; D014054:Tomography / Q000379:methods; D014867:Water / Q000737:chemistry*; D014965:X-Rays
chemical_list: D014867:Water; D012822:Silicon Dioxide