Ruthenium-olefin complexes: effect of ligand variation upon geometry.
The development of a model system to study ruthenium-olefin complexes relevant to the mechanism of olefin metathesis has been reported recently. Upon addition of the ligand precursor 1,2-divinylbenzene to [RuCl(2)(Py)(2)(H(2)IMes)(==CHPh)] (H(2)IMes=1,3-dimesityl-4,5-dihydroimidazol-2-ylidene), two ruthenium-olefin adducts are formed. Based on (1)H NMR spectroscopy experiments and X-ray crystallographic analysis, these complexes are assigned as side-bound isomers in which the olefin and H(2)IMes ligands are coordinated cis to each other. Herein is reported an investigation of the generality of these observations through variation of the N-heterocyclic carbene ligand and the ligand precursor.
Anderson
Donde R
DR
Arnold and Mabel Beckman Laboratories of Chemical Synthesis, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA.
O'Leary
Daniel J
DJ
Grubbs
Robert H
RH
D000475:Alkenes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy / Q000379:methods / Q000592:standards; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012015:Reference Standards; D012428:Ruthenium / Q000737:chemistry*; D013237:Stereoisomerism; D014753:Vinyl Compounds / Q000737:chemistry
D000475:Alkenes; D008024:Ligands; D009942:Organometallic Compounds; D014753:Vinyl Compounds; D012428:Ruthenium; C004985:divinyl benzene