title: Synthesis and biological activity of organothiophosphoryl polyoxotungstates.
abstract: Organothiophosphoryl polyoxotungstates R(contains)XW(infinityinfinity)O(contains exists) (/-) , R(contains) P(contains)W(infinity),O(infinity) (/-), R(contains)PW( exists)O(contains) (Delta) (-)(X = P, Si, Ge, B or Ga; R = PhP(S), C(6)H(11)P(S)) have been prepared from lacunary polyoxoanions and PhP(S). The products were characterized by elemental analysis, IR, and NMR spectroscopy. According to spectroscopic observations, the hybrid anions consist of a lacunary anion framework on which are grafted two equivalent or groups through P-O-W bridges. Some of the title compounds showed the antigerm activity.
authors.affiliation: Department of Chemistry Northeast Normal University Changchun 130024 China.
authors.forename: Zhengang
authors.initials: Z
authors.lastname: Sun
authors.forename: Jutao
authors.initials: J
authors.lastname: Liu
authors.forename: Jianfang
authors.initials: J
authors.lastname: Ma
authors.forename: Jingfu
authors.initials: J
authors.lastname: Liu