Comparative studies of diphenyl-diketo-pyrrolopyrrole derivatives for electroluminescence applications.
Four different derivatives of diphenyl-diketo-pyrrolopyrrole (DPP) with alkyl side groups were synthesized to increase their solubility. Quantum chemical calculations revealed that the substitution influenced molecular geometry and subsequently modified absorption and photoluminescence spectra. The theoretical results were confirmed by experimental characterization. With increasing phenyl torsion the vibrational structure was less pronounced and larger Stokes shift was observed. Simultaneously, the molar absorption coefficient decreased as the deformation increased. On the other hand, the measured fluorescence quantum yields were modified only slightly. This indicates the possibility to prepare soluble derivatives without loss of quantum yields and to use these materials for construction of efficient and stable electroluminescent devices. Furthermore, the electroluminescence of the thin layer devices based on the soluble low molecular DPPs were characterized and discussed.
Vala
Martin
M
Faculty of Chemistry, Brno University of Technology, Purkynova 118, Brno, 612 00, Czech Republic. vala@fch.vutbr.cz
Weiter
Martin
M
Vynuchal
Jan
J
Toman
Petr
P
Lunák
Stanislav
S