Studies toward the total synthesis of ristocetin A aglycone using arene-ruthenium complexes as S(N)Ar substrates: Construction of an advanced tricyclic intermediate.
Ruthenium-mediated S(N)Ar reactions are used to construct the diaryl ether linkages in two key intermediates for a projected total synthesis of the aglycone of ristocetin A.
Pearson
Anthony J
AJ
Department of Chemistry, Case Western Reserve University, Cleveland, OH 44106, USA.
Ciurea
Diana V
DV
Velankar
Avdhoot
A