Anion complexation via C-H...X interactions using a palladacyclic receptor.
A novel organometallic receptor binds anions in solution and in the solid state, with complexes stabilised through a series of C-HX interactions, as evidenced by 1H NMR spectroscopy, X-ray crystallography and computational models.
Bedford
Robin B
RB
School of Chemistry, University of Bristol, Cantock's Close, Bristol, UKBS8 1TS. r.bedford@bristol.ac.uk
Betham
Michael
M
Butts
Craig P
CP
Coles
Simon J
SJ
Hursthouse
Michael B
MB
Noelle Scully
P
P
Tucker
James H R
JH
Wilkie
John
J
Willener
Yasmine
Y
D000838:Anions / Q000737:chemistry; D003198:Computer Simulation; D018360:Crystallography, X-Ray; D003500:Cyclization; D006860:Hydrogen Bonding; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*
D000838:Anions; D009942:Organometallic Compounds; D010165:Palladium