Molecular complexation and binding studied by electrophoretic NMR spectroscopy.
Electrophoretic mobilities obtained on a molecularly selective manner by electrophoretic NMR can be used to provide a quantitative characterization of the composition and stoichiometry of molecular complexes. This is demonstrated in complexes formed by uncharged cyclodextrins which attain an electrophoretic mobility upon inclusion of charged surfactants.
Hallberg
Fredrik
F
Division of Physical Chemistry, Department of Chemistry, Royal Institute of Technology, SE-10044 Stockholm, Sweden.
Weise
Christoph F
CF
Yushmanov
Pavel V
PV
Pettersson
Erik Thyboll
ET
Stilbs
Peter
P
Furó
István
I
D003505:Cyclodextrins / Q000737:chemistry; D004586:Electrophoresis / Q000379:methods*; D019906:Nuclear Magnetic Resonance, Biomolecular / Q000379:methods*; D013501:Surface-Active Agents / Q000737:chemistry
D003505:Cyclodextrins; D013501:Surface-Active Agents