Effect of undesalted dissolved organic matter from composts on persistence, adsorption, and mobility of cyhalofop herbicide in soils.
The effect of undesalted dissolved organic matter (DOM) extracted from composts on the degradation, adsorption, and mobility of cyhalofop herbicide in soils was studied. A paddy-field sediment poor in organic matter (OM), an OM-rich forest soil, and DOM from agroindustrial or municipal waste compost were used. DOM increased the cyhalofop-acid but not the cyhalofop-butyl solubility in water. The degradation of cyhalofop-butyl in the sediment was slow, giving cyhalofop-acid as the only metabolite, whereas in forest soil, the process was faster, and three byproducts were detected. Soil pretreatment with DOM did not modify the degradation pattern but only reduced the adsorption of cyhalofop-butyl by soil, whereas it increased the adsorption of cyhalofop-acid. Among the cationic components of DOM solutions, the potassium ion seems to be related to the increased adsorption of the cyhalofop-acid in both OM-poor and OM-rich soils, yielding reversible complexes with the former and favoring hydrophobic interactions with the latter.
Blasioli
Sonia
S
Dipartimento di Scienze e Tecnologie Agroambientali, Universita di Bologna, Bologna, Italy. sblasioli@agrsci.unibo.it
Braschi
Ilaria
I
Pinna
Maria V
MV
Pusino
Alba
A
Gessa
Carlo E
CE
D000327:Adsorption; D002073:Butanes / Q000032:analysis* / Q000737:chemistry*; D002412:Cations; D006540:Herbicides / Q000032:analysis* / Q000737:chemistry*; D007700:Kinetics; D009570:Nitriles / Q000032:analysis* / Q000737:chemistry*; D011188:Potassium / Q000494:pharmacology; D012987:Soil / Q000032:analysis*; D012995:Solubility
D002073:Butanes; D002412:Cations; D006540:Herbicides; D009570:Nitriles; D012987:Soil; C501583:cyhalofop-butyl; D011188:Potassium