A highly active and reusable copper(I)-tren catalyst for the "click" 1,3-dipolar cycloaddition of azides and alkynes.
The copper(I) complex [Cu(C18(6)tren)]Br 1 (C18(6)tren = tris(2-dioctadecylaminoethyl)amine) which exhibits a good stability towards aerobic conditions is a versatile, highly reactive and recyclable catalyst for the Huisgen cycloaddition of azides with terminal or internal alkynes and is a useful catalyst for the preparation of "click" dendrimers.
Candelon
Nicolas
N
University Bordeaux-1, CNRS-UMR 5255, Institut des Sciences Moléculaires, 351 Cours de la libération, 33405 Talence, France.
Lastécouères
Dominique
D
Diallo
Abdou Khadri
AK
Aranzaes
Jaime Ruiz
JR
Astruc
Didier
D
Vincent
Jean-Marc
JM