title: Rate constants and Arrhenius functions for ring opening of a cyclobutylcarbinyl radical clock and for hydrogen atom transfer from the Et(3)B-MeOH complex.
abstract: Kinetics of ring opening of the 1-cyclobutyldodecyl radical (1) were studied, and an Arrhenius function over the temperature range -20 to 47 degrees C was determined. The radical clock reaction has kinetics described by log k = 13.2 - 13.5/2.313 RT (in kcal/mol), and k = 1.5 x 10(3) s(-1) at 20 degrees C. Previous kinetic studies of hydrogen atom transfer trapping of radical 1 by the triethylborane-methanol complex at variable temperatures (J. Org. Chem. 2007, 72, 5098) were analyzed with the newly obtained kinetic data.
authors.affiliation: Department of Chemistry, University of Illinois at Chicago, Chicago, IL 60607, USA.
authors.forename: Jing
authors.initials: J
authors.lastname: Jin
authors.forename: Martin
authors.initials: M
authors.lastname: Newcomb