Sampling in freshwater environments: suspended particle traps and variability in the final data.
This paper reports one practical method to estimate the measurement uncertainty including sampling, derived by the approach implemented by Ramsey for soil investigations. The methodology has been applied to estimate the measurements uncertainty (sampling and analyses) of (137)Cs activity concentration (Bq kg(-1)) and total carbon content (%) in suspended particle sampling in a freshwater ecosystem. Uncertainty estimates for between locations, sampling and analysis components have been evaluated. For the considered measurands, the relative expanded measurement uncertainties are 12.3% for (137)Cs and 4.5% for total carbon. For (137)Cs, the measurement (sampling+analysis) variance gives the major contribution to the total variance, while for total carbon the spatial variance is the dominant contributor to the total variance. The limitations and advantages of this basic method are discussed.
Barbizzi
Sabrina
S
Agenzia per la Protezione dell'Ambiente e per i Servizi Tecnici (APAT), Servizio Metrologia Ambientale, Via di Castel Romano, 100-00128 Roma, Italy. sabrina.barbizzi@apat.it
Pati
Alessandra
A
D000465:Algorithms; D003627:Data Interpretation, Statistical; D004781:Environmental Exposure / Q000032:analysis; D005618:Fresh Water / Q000032:analysis* / Q000737:chemistry; D033161:Government Regulation; D007558:Italy; D011834:Radiation Monitoring / Q000295:instrumentation* / Q000379:methods; D011835:Radiation Protection / Q000379:methods; D011868:Radioisotopes / Q000032:analysis*; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity; D013048:Specimen Handling / Q000295:instrumentation* / Q000379:methods; D014462:Ultrafiltration / Q000295:instrumentation / Q000379:methods; D014875:Water Pollutants, Radioactive / Q000032:analysis*
D011868:Radioisotopes; D014875:Water Pollutants, Radioactive