Stable P-N bridged cyclophosphazenes with a spiro or ansa arrangement.
Deprotonation reactions of cyclophosphazenes containing secondary amino groups in the side chain lead to a doubly bridged tricyclophosphazene structure or to a cyclophosphazene-cyclophosphazane-cyclophosphazene compound, which are very stable and could be used as building blocks for larger structures.
Beşli
Serap
S
Department of Chemistry, Gebze Institute of Technology, 41400 Gebze-Kocaeli, Turkey. besli@gyte.edu.tr
Coles
Simon J
SJ
Davies
David B
DB
Erkovan
Ayşen O
AO
Hursthouse
Michael B
MB
Kiliç
Adem
A
D003460:Crystallization; D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000737:chemistry*; D010758:Phosphorus / Q000737:chemistry*; D013141:Spiro Compounds / Q000737:chemistry*
D009943:Organophosphorus Compounds; D013141:Spiro Compounds; C074235:cyclophosphazene monomer; D010758:Phosphorus; D009584:Nitrogen