DOSY technique applied to palladium nanoparticles in ionic liquids.
Multinuclear ((1)H, (31)P, (19)F and (11)B) diffusion ordered spectroscopy (DOSY) technique has been applied to palladium nanoparticles systems dispersed in ionic liquids (ILs). Even if the nanoparticles themselves cannot be detected through NMR, observation of the solvent (methanol) and the IL ([BMI][PF(6)] or [BMI][NTf(2)]), their diffusion coefficients and their changes in the presence of nanoparticles allow us to draw significant assumptions about the organisation of palladium nanoparticles in the IL. For comparison, the corresponding molecular precursors ([PdCl(2)(cod)] or [Pd(2)(dba)(3)]) have been also studied.
Laboratoire Hétérochimie Fondamentale et Appliquée, UMR-CNRS 5069, Bât 2R1, Université Paul Sabatier, 118 route de Narbonne, 31062 Toulouse cedex 9, France.
Jérôme
J
Durand
Fernando
F
Fernández
Clément
C
Barrière
Emmanuelle
E
Teuma
Kerman
K
Gómez
Gabriel
G
González
Montserrat
M
Gómez