Ligand-to-metal ratio controlled assembly of nanoporous metal-organic frameworks.
Two bilayered metal-organic frameworks with nanoporous channels were synthesized at different ligand-to-metal ratios, which demonstrated an interesting crystal-to-crystal transformation property and a special fluorescent response to the different guest molecules included.
Lin
Jian-Guo
JG
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.
Xu
Yan-Yan
YY
Qiu
Ling
L
Zang
Shuang-Quan
SQ
Lu
Chang-Sheng
CS
Duan
Chun-Ying
CY
Li
Yi-Zhi
YZ
Gao
Song
S
Meng
Qing-Jin
QJ
D018360:Crystallography, X-Ray; D005453:Fluorescence; D008024:Ligands; D008670:Metals / Q000737:chemistry*; D049329:Nanostructures / Q000737:chemistry*; D009930:Organic Chemicals / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis*; D009947:Organotin Compounds / Q000737:chemistry*; D016062:Porosity; D012997:Solvents / Q000737:chemistry; D013050:Spectrometry, Fluorescence
D008024:Ligands; D008670:Metals; D009930:Organic Chemicals; D009942:Organometallic Compounds; D009947:Organotin Compounds; D012997:Solvents; C012594:triphenyltin chloride