Controlled regio- and chemoselective addition of isothiocyanate to the dione moiety of a cage-opened fullerene-mixed peroxide derivative.
Addition of the ambident SCN group to a fullerendione derivative follows two different pathways in the presence and absence of Lewis acid.
Yang
Xiaobing
X
Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
Gan
Liangbing
L
Wang
Zheming
Z
D018360:Crystallography, X-Ray; D037741:Fullerenes / Q000737:chemistry*; D017879:Isothiocyanates / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D010545:Peroxides / Q000737:chemistry*; D013237:Stereoisomerism
D037741:Fullerenes; D017879:Isothiocyanates; D010545:Peroxides; C037152:isothiocyanic acid