Synthesis of bis(sigma-aryl)dirhodium(III) caprolactamates by oxidative arylation with arylboronic acids.
Recently discovered stable bis(sigma-phenyl)dirhodium(III) caprolactamate and its substituted derivatives are conveniently prepared in high yields from dirhodium(II) caprolactamate and commercially available arylboronic acids in a copper-catalyzed process.
Xie
Jian-Hua
JH
Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742, USA.
Nichols
Jason M
JM
Lubek
Conrad
C
Doyle
Michael P
MP