Study of the Xe-NH3 van der Waals complex: high-resolution microwave spectra and ab initio calculations.
An ab initio potential energy surface of the Xe-NH(3) van der Waals complex was constructed at the coupled cluster level of theory with single, double, and pertubatively included triple excitations. The small-core pseudopotential and augmented correlation-consistent polarized valence quadruple-zeta basis set was used for the Xe atom and Dunning's augmented correlation-consistent polarized valence triple-zeta basis set for the other atoms. The basis sets were supplemented with midbond functions. Rotational spectra of the Xe-NH(3) van der Waals complex were recorded using a pulsed-nozzle Fourier transform microwave spectrometer. Rotational transitions within two internal rotor states, namely, the Sigma0(0) and Pi1(1) (lower) states, were measured and assigned to the Xe-(14)NH(3) and Xe-(15)NH(3) isotopologues. For the deuterated isotopologues, only the Sigma0(0) states were observed. Two inversion components were observed for each state except for the "s" component of the Sigma0(0) state of the Xe-(14)NH(3) and Xe-(15)NH(3) isotopologues, which has a spin statistical weight of zero. Nuclear quadrupole hyperfine structures arising from the (14)N (nuclear spin angular momentum quantum number I=1) and (131)Xe (I=32) nuclei were detected and analyzed. The observed spectra suggest that the Pi1(1) (lower) state has lower energy than the unobserved Sigma1(1) state, in contrast to the case of Ar-NH(3).
Department of Chemistry, University of Alberta, Edmonton AB T6G 2G2, Canada. wolfgang.jaeger@ualberta.ca
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