Ozonation of trichloroethylene in acetic acid solution with soluble and solid humic acid.
The combined flushing and oxidation process using acetic acid and ozone has been used successfully to remove trichloroethylene (TCE) completely from contaminated soil. In this study, the effects of humic acid, a fraction of the organic matter in soil, over the performance of TCE decomposition was evaluated. TCE decomposition by ozone was enhanced by the presence of humic acid at concentrations lower than 8mgCL(-1) and then inhibited at higher concentrations. It is possible that the presence of the soluble humic acid fraction during the ozonation of TCE in acetic acid solutions produces hydroxyl radicals during the TCE ozonation which appears to be the reason for the enhanced TCE decomposition rate. Solid humic acid reduced TCE decomposition rate by acting as an ozone scavenger. Similarly, sorbed TCE reduced the amount of TCE available for decomposition by ozone in solution.
Alcántara-Garduño
Martha E
ME
Department of Chemical Engineering, Graduate School of Engineering, Hiroshima University, 1-4-1 Kagamiyama, Higashi-Hiroshima 739-8527, Japan. martele31@angel.umar.mx
Okuda
Tetsuji
T
Nishijima
Wataru
W
Okada
Mitsumasa
M
D000085:Acetates / Q000737:chemistry*; D001578:Benzopyrans / Q000737:chemistry; D005609:Free Radicals / Q000032:analysis; D006812:Humic Substances / Q000032:analysis*; D007202:Indicators and Reagents; D010083:Oxidants, Photochemical / Q000737:chemistry*; D010126:Ozone / Q000737:chemistry*; D012995:Solubility; D012996:Solutions; D014241:Trichloroethylene / Q000737:chemistry*
D000085:Acetates; D001578:Benzopyrans; D005609:Free Radicals; D006812:Humic Substances; D007202:Indicators and Reagents; D010083:Oxidants, Photochemical; D012996:Solutions; D014241:Trichloroethylene; D010126:Ozone; C005023:fulvic acid