[Synthesis and luminescent spectral characteristics of porphyrin complexes with platinum group metals].
The synthesis of natural and synthetic porphyrin complexes with Pt, Pd, Rh, and Ru is reported. Their electronic absorption spectra, phosphorescence spectra, and lifetimes at room temperature both in the presence and in the absence of oxygen were studied. It has been shown that the variation of the nature of the central metal atom and of the substituents in pyrrole and phenyl rings allows the obtaining of metalloporphyrins with various phosphorescence excitation and phosphorescing emission spectra at room temperature. The English version of the paper: Russian Journal of Bioorganic Chemistry, 2008, vol. 34, no. 2; see also http://www.maik.ru.
V D
VD
Rumiantseva
N P
NP
Ivanovskaia
L I
LI
Konovalenko
S V
SV
Tsukanov
A F
AF
Mironov
N S
NS
Osin
D002614:Chelating Agents / Q000138:chemical synthesis* / Q000737:chemistry; D008163:Luminescent Measurements; D010165:Palladium; D010984:Platinum; D011166:Porphyrins / Q000138:chemical synthesis* / Q000737:chemistry; D012238:Rhodium; D012428:Ruthenium
D002614:Chelating Agents; D011166:Porphyrins; D010984:Platinum; D010165:Palladium; D012428:Ruthenium; D012238:Rhodium