Sintering behavior of two roughened crystals just after contact.
We consider two spherical, roughened crystals with approximately isotropic surface free energy, which are brought into contact and begin to sinter. We argue that the geometry immediately postcontact is two dimensional and Cartesian and can be approximated by the evolution of a slot-shaped cavity. On this basis, we construct traveling wave solutions for the crystal shape in the limits of bulk- and surface-diffusion-limited kinetics. These solutions are then used to calculate scalings for the neck size as a function of time t after contact: We predict that neck size is proportional to t 1/4 for the bulk-diffusion-limited case and (following a single pinch-off event) approximately proportional to t 1/3 for the surface-diffusion-limited case.
Farr
Robert S
RS
Unilever R&D, Olivier van Noortlaan 120, AT3133, Vlaardingen, The Netherlands. robert.farr@unilever.com
Izzard
Martin J
MJ