Sequential chemical treatment of radium species in TENORM waste sludge produced from oil and natural gas production.
This paper is dedicated to the treatment of sludge occurring in frame of the Egyptian produced from oil and gas production. The activity levels of three radium isotopes: Ra-226 (of U-series), Ra-228 and Ra-224 (of Th-series) in the solid TENORM waste (sludge) were first evaluated and followed by a sequential treatment for all radium species (fractions) presented in TENORM. The sequential treatment was carried out based on two approaches 'A' and 'B' using different chemical solutions. The results obtained indicate that the activity levels of all radium isotopes (Ra-226, Ra-228 and Ra-224) of the environmental interest in the TENORM waste sludge were elevated with regard to exemption levels established by IAEA [International Atomic Energy Agency (IAEA), International basic safety standards for the protection against ionizing radiation and for the safety of radiation sources. GOV/2715/Vienna, 1994]. Each approach of the sequential treatment was performed through four steps using different chemical solutions to reduce the activity concentration of radium in a large extent. Most of the leached radium was found as an oxidizable Ra species. The actual removal % leached using approach B was relatively efficient compared to A. It is observed that the actual removal percentages (%) of Ra-226, Ra-228 and Ra-224 using approach A are 78+/-2.8, 64.8+/-4.1 and 76.4+/-5.2%, respectively. Whereas in approach A, the overall removal % of Ra-226, Ra-228 and Ra-228 was increased to approximately 91+/-3.5, 87+/-4.1 and 90+/-6.2%, respectively.
Analytical Chemistry and Environmental Control Department, Hot Laboratories and Waste Management Center (HLWMC), Atomic Energy Authority, Post Office No. 13759, Cairo, Egypt.
E M
EM
El Afifi
N S
NS
Awwad
M A
MA
Hilal
D001709:Biotechnology / Q000379:methods; D005579:Fossil Fuels; D006863:Hydrogen-Ion Concentration; D015233:Models, Statistical; D009821:Oils; D010100:Oxygen / Q000737:chemistry; D010578:Petroleum; D011874:Radiometry / Q000379:methods; D011883:Radium / Q000032:analysis*; D012037:Refuse Disposal; D012722:Sewage; D013696:Temperature; D014865:Waste Disposal, Fluid / Q000379:methods*; D014875:Water Pollutants, Radioactive / Q000032:analysis*; D018508:Water Purification / Q000379:methods
D005579:Fossil Fuels; D009821:Oils; D010578:Petroleum; D012722:Sewage; D014875:Water Pollutants, Radioactive; D010100:Oxygen; D011883:Radium