Synthesis of dinuclear boron complexes of sulfinylcalix[4]arenes: Syn/Anti stereocontrol by the arrangement of the sulfinyl functions.
Stereocontrol in the synthesis of dinuclear metal complexes of sulfinylcalix[4]arenes 2 has been achieved by the arrangement of sulfinyl functionalities. Thus, the treatment of the(rtct) isomer of 2 (2(rtct)) with an excess of Et(3)B affords syn dinuclear boron complex 4, while a similar treatment of rctt and rcct isomers 2(rctt) and 2(rcct) yields anti dinuclear complexes 5 and 6, respectively.
Department of Environmental Studies, Graduate School of Environmental Studies, Tohoku University, 6-6-11 Aramaki-Aoba, Aoba-ku, Sendai 980-8579, Japan. morohashi@orgsynth.che.tohoku.ac.jp
Naoya
N
Morohashi
Tsuyoshi
T
Kitahara
Tomoko
T
Arima
Shinya
S
Tanaka
Yoshihiro
Y
Ohba
Tetsutaro
T
Hattori