Signatures of dynamical heterogeneity in the structure of glassy free-energy minima.
From numerical minimization of a model free-energy functional for a system of hard spheres, we show that the width of the local peaks of the time-averaged density field at a glassy free-energy minimum exhibits large spatial variation, similar to that of the "local Debye-Waller factor" in simulations of dynamical heterogeneity. Molecular dynamics simulations starting from a particle configuration generated from the density distribution at a glassy free-energy minimum show similar spatial heterogeneity in the degree of localization, implying a direct connection between dynamical heterogeneity and the structure of glassy free-energy minima.
Department of Physics, Indian Institute of Science, Bangalore 560012, India.
Pinaki
P
Chaudhuri
Smarajit
S
Karmakar
Chandan
C
Dasgupta