On the mechano-chiral effect of vortical flows on the dichroic spectra of 5-phenyl-10,15,20-tris(4-sulfonatophenyl)porphyrin J-aggregates.
Phase-modulated ellipsometry of the J-aggregates of the title porphyrin shows that the material gives a true CD signal. This confirms that there is a real chiral transfer by mechanical forces, mediated by shear gradient flows, from the macroscopic to the electronic transition level. Dislocations in the structure of the aggregate could justify the formation of chirality at the level of the electronic transitions once the mesophases can be sculptured by hydrodynamic gradient flows.
Departament de Química Orgànica, Universitat de Barcelona c Martí i Franquès 1, Barcelona, Catalonia, Spain.
Zoubir
Z
El-Hachemi
Oriol
O
Arteaga
Adolf
A
Canillas
Joaquim
J
Crusats
Carlos
C
Escudero
Reiko
R
Kuroda
Takunori
T
Harada
Mònica
M
Rosa
Josep M
JM
Ribó