Reactivity of niobium-carbon cluster ions with hydrogen molecules in relation to formation mechanism of Met-Car cluster ions.
It is known that a niobium-carbon Met-Car cluster ion (Nb 8C 12 (+)) and its intermediates (Nb 4C 4 (+), Nb 6C 7 (+), etc.) are selectively formed by the aggregation of the Nb atoms in the presence of hydrocarbons. To elucidate the formation mechanism, we prepared Nb n C m (+) with every combination of n and m in the gas phase by the laser vaporization technique. The reactivity of Nb n C m (+) with H 2 was examined under the multiple collision condition, finding that Nb n C m (+) between Nb 2C 3 (+) and Nb 8C 12 (+) are not reactive with H 2. On the basis of the H 2 affinity of Nb n C m (+) experimentally obtained, we propose a dehydrogenation-controlled formation mechanism of niobium-carbon Met-Car cluster ions.
Miyajima
Ken
K
Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo 153-8902, Japan.
Fukushima
Naoya
N
Mafuné
Fumitaka
F
D002244:Carbon / Q000737:chemistry*; D005740:Gases / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry*; D006865:Hydrogenation; D007834:Lasers; D013058:Mass Spectrometry; D009556:Niobium / Q000737:chemistry*
D005740:Gases; D009556:Niobium; D002244:Carbon; D006859:Hydrogen