Self-assembly of two different hierarchical nanostructures on either side of an organic supramolecular film in one step.
We fabricated different hierarchical organic nanostructures on each side of a supramolecular film, by using hydrogen-bonding interactions between tetrapyridylporphyrin and benzene-1,3,5-tricarboxylic acid at the H2O/CHCl3 interface. The surface of the film that faces water is composed of nanoprism arrays, whereas the surface facing CHCl3 is composed of three-dimensional sunflower-like hierarchical micro- and nanostructures. FTIR spectral evidence showed that all pyridyl groups of the tetrapyridylporphyrin hydrogen bonded to the carboxylic acid groups of 1,3,5-benzene-tricarboxylic acid. The aggregation modes of porphyrin presented in this supramolecular film were studied by UV/Vis and fluorescence spectroscopy. Moreover, each side of the film exhibits distinct soakage properties.
Shi
Naien E
NE
State Key Laboratory of Coordination Chemistry, National Laboratory of Solid State Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P.R. China.
Yin
Gui
G
Han
Min
M
Jiang
Lei
L
Xu
Zheng
Z