A new heart-like Co-containing polyoxoanion based on the lacunary Preyssler anion.
Reaction of the metastable anion [H(2)P(2)W(12)O(48)](12-) with Co(2+) yields a novel heart-like polyoxoanion based on the lacunary Preyssler-type anion [P(4)W(24)O(92)](20-).
Zhang
Zhiming
Z
Key Laboratory of Polyoxometalate Science of Ministry of Education, Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, P R China.
Yao
Shuang
S
Qi
Yanfei
Y
Li
Yangguang
Y
Wang
Yonghui
Y
Wang
Enbo
E