Ionothermal synthesis of homochiral framework with acetate-pillared cobalt-camphorate architecture.
A new organically templated homochiral material (EMIm)[Co 2( d-cam) 2(ac)] ( 1; d-H 2cam = d-camphoric acid; ac = acetate; EMIm = 1-ethyl-3-methylimidazolium) has been ionothermally synthesized, and it features an unusual acetate-pillared cobalt-camphorate architecture encapsulating the cationic component of the ionic liquid.
Department of Chemistry and Biochemistry, California State University, Long Beach, 1250 Bellflower Boulevard, Long Beach, California 90840, USA.
Shumei
S
Chen
Jian
J
Zhang
Xianhui
X
Bu
D000085:Acetates; D002164:Camphor / Q000031:analogs & derivatives / Q000737:chemistry*; D002412:Cations; D003035:Cobalt / Q000737:chemistry*; D052578:Ionic Liquids; D046911:Macromolecular Substances / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D013237:Stereoisomerism
D000085:Acetates; D002412:Cations; D052578:Ionic Liquids; D046911:Macromolecular Substances; D003035:Cobalt; D002164:Camphor