Identification of an intermediate in the deboronation of ortho-carborane: an adduct of ortho-carborane with two nucleophiles on one boron atom.
The 1 : 2 adduct of 1-bromo-ortho-carborane and pyridine has been identified as a significant intermediate in the deboronation of ortho-carborane to a nido-anion.
Taoda
Yoshiyuki
Y
Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Sawabe
Takehiko
T
Endo
Yasuyuki
Y
Yamaguchi
Kentaro
K
Fujii
Shinya
S
Kagechika
Hiroyuki
H
D001895:Boron / Q000737:chemistry*; D001896:Boron Compounds / Q000737:chemistry*; D004563:Electrochemistry; D046529:Microscopy, Electron, Transmission; D015394:Molecular Structure; D013059:Spectrum Analysis, Raman
D001896:Boron Compounds; D001895:Boron