Synthesis of (+)-uniflorine a: a structural reassignment and a configurational assignment.
The total synthesis of (+)-uniflorine A has allowed for the structural reassignment and the configurational assignment of the alkaloid (-)-uniflorine A from a 1,2,6,7,8-pentahydroxyindolizidine structure to (-)-(1 R,2 R,3 R,6 R,7 S,7a R)-1,2,6,7-tetrahydroxy-3-hydroxymethylpyrrolizidine (6- epi-casuarine).
Ritthiwigrom
Thunwadee
T
School of Chemistry, University of Wollongong, Wollongong, New South Wales 2522, Australia.
Pyne
Stephen G
SG
D007212:Indolizines / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure
D007212:Indolizines; C487671:uniflorine A