Electronic polarizability and Judd-Ofelt parameters of Nd3+ and Er3+ ions in transparent crystallized glasses with nonlinear optical Ba2 TiSi2O8 nanocrystals.
Transparent crystallized glasses consisting of nonlinear optical Ba(2)TiSi(2)O(8) nanocrystals are prepared in Eu(2)O(3)-, Nd(2)O(3)-, and Er(2)O(3)-doped 40BaO-20TiO(2)-40SiO(2) glasses by a conventional heat treatment method in order to clarify the optical properties of rare-earth (RE) ions in nanocrystals. The electronic polarizabilities of crystallized glasses are evaluated from the values of density and refractive index, and are found to decrease due to nanocrystallization, which indicates that the chemical bonding state in the crystallized glasses is more covalent compared to the precursor glasses. It is proposed from x-ray diffraction analyses and photoluminescence spectra of Eu(3+) ions that RE ions such as Nd(3+) and Eu(3+) are incorporated into Ba(2)TiSi(2)O(8) nanocrystals. The Judd-Ofelt parameters, Omega(t) (t=2, 4, and 6), of Nd(3+) and Er(3+) ions are evaluated from optical absorption spectra. It is observed that the Omega(2) parameter of Nd(3+) and Er(3+) increases largely due to nanocrystallization, suggesting that the site symmetry of Nd(3+) and Er(3+) ions in nanocrystallized glasses is largely distorted due to their incorporations into the Ba(2+) sites in Ba(2)TiSi(2)O(8) nanocrystals. The change in the Omega(4) and Omega(6) parameters due to nanocrystallization is small. It is proposed that nonlinear optical Ba(2)TiSi(2)O(8) nanocrystals including RE ions would have a high potential as active optical materials.
Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka, Japan.
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N
Maruyama
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T
Honma
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T
Komatsu
D001464:Barium / Q000737:chemistry; D002412:Cations; D004581:Electronics; D004871:Erbium / Q000737:chemistry*; D005063:Europium / Q000737:chemistry*; D005898:Glass / Q000737:chemistry*; D053758:Nanoparticles / Q000737:chemistry*; D009354:Neodymium / Q000737:chemistry*; D055095:Optics and Photonics; D010087:Oxides / Q000737:chemistry*; D012825:Silicon / Q000737:chemistry; D013053:Spectrophotometry; D013691:Tellurium / Q000737:chemistry
D002412:Cations; D010087:Oxides; D001464:Barium; D009354:Neodymium; D005063:Europium; D004871:Erbium; D013691:Tellurium; D012825:Silicon