A novel glycosyl donor for chemo-enzymatic oligosaccharide synthesis: 4,6-dimethoxy-1,3,5-triazin-2-yl glycoside.
A novel activated glycosidic compound, 4,6-dimethoxy-1,3,5-triazin-2-yl beta-lactoside (DMT-beta-Lac), which can be prepared directly from lactose in water without using any protecting groups, was found to be an efficient glycosyl donor for enzymatic glycosylation catalyzed by an endo-1,4-beta-glucanase.
Tanaka
Tomonari
T
Department of Biomolecular Engineering, Graduate School of Engineering, Tohoku University, Aoba, Sendai, 980-8579, Japan.
Noguchi
Masato
M
Kobayashi
Atsushi
A
Shoda
Shin-Ichiro
S
D002480:Cellulase / Q000378:metabolism*; D002851:Chromatography, High Pressure Liquid; D006027:Glycosides / Q000737:chemistry*; D006031:Glycosylation; D015394:Molecular Structure; D009844:Oligosaccharides / Q000737:chemistry* / Q000378:metabolism*; D014227:Triazines / Q000737:chemistry*
D006027:Glycosides; D009844:Oligosaccharides; D014227:Triazines; D002480:Cellulase