New catalytic route to borasiloxanes.
A new, highly selective method for effective synthesis of boryl silyl ethers (borasiloxanes) via O-borylation of silanols with vinylboronates catalyzed by the Ru-H complexes [RuHCl(CO)(PCy3)2] and [RuHCl(CO)(PPh3)3] is described.
Department of Organometallic Chemistry, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780, Poznań, Poland. marcinb@amu.edu.pl
Bogdan
B
Marciniec
Jedrzej
J
Walkowiak