Identification of an intermediate in the deboronation of ortho-carborane: an adduct of ortho-carborane with two nucleophiles on one boron atom.
The 1 : 2 adduct of 1-bromo-ortho-carborane and pyridine has been identified as a significant intermediate in the deboronation of ortho-carborane to a nido-anion.
Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Yoshiyuki
Y
Taoda
Takehiko
T
Sawabe
Yasuyuki
Y
Endo
Kentaro
K
Yamaguchi
Shinya
S
Fujii
Hiroyuki
H
Kagechika
D001895:Boron / Q000737:chemistry*; D001896:Boron Compounds / Q000737:chemistry*; D004563:Electrochemistry; D046529:Microscopy, Electron, Transmission; D015394:Molecular Structure; D013059:Spectrum Analysis, Raman
D001896:Boron Compounds; D001895:Boron