Intramolecular aglycon delivery.
A Minireview with 51 references covering the two-step tethering and intramolecular glycosylation process termed intramolecular aglycon delivery (IAD). Specifically, glycosylation reactions where the tethered oxygen acts as nucleophile are covered. In the majority of cases, tethering to O-2 of a glycosyl donor ensures formation of a 1,2-cis glycoside after intramolecular glycosylation.
Cumpstey
Ian
I
Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, Stockholm, Sweden. cumpstey@organ.su.se
D000080:Acetals / Q000737:chemistry; D001593:Benzyl Compounds / Q000737:chemistry; D006027:Glycosides / Q000138:chemical synthesis*; D006031:Glycosylation; D009844:Oligosaccharides / Q000138:chemical synthesis; D017655:Silicon Compounds / Q000737:chemistry; D014753:Vinyl Compounds / Q000737:chemistry
D000080:Acetals; D001593:Benzyl Compounds; D006027:Glycosides; D009844:Oligosaccharides; D017655:Silicon Compounds; D014753:Vinyl Compounds; C100195:vinyl ether