A viscosity self-oscillation of polymer solution induced by the Belousov-Zhabotinsky reaction under acid-free condition.
We succeeded in measuring a viscosity self-oscillation induced by the Belousov-Zhabotinsky (BZ) reaction for a polymer solution on the constant temperature condition under acid-free condition. The polymer chain is consisted of N-isopropylacrylamide, ruthenium complex as a catalyst of the BZ reaction, and an acrylamide-2-methylpropanesulfonic acid (AMPS) as a pH and the solubility control site. The viscosity self-oscillation for the AMPS-containing polymer solution was attributed to the difference between viscosities for the polymer solution in the reduced and oxidized states. The effects of the polymer concentration and the temperature of the polymer solution on the viscosity self-oscillation were investigated. As a result, the viscosity self-oscillating behavior significantly depended on the polymer concentration and the temperature of the polymer solution. The period of the viscosity self-oscillation decreased with increasing temperature in accordance with the Arrenius equation.
Hara
Yusuke
Y
Department of Materials Engineering, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan. yhara@shalab.phys.waseda.ac.jp
Yoshida
Ryo
R
D000143:Acids / Q000737:chemistry; D011108:Polymers / Q000737:chemistry*; D012996:Solutions; D013696:Temperature; D014783:Viscosity
D000143:Acids; D011108:Polymers; D012996:Solutions