Efficient preconcentration and determination of traces of aluminum ion using silica-bonded glycerol sorbent.
A solid-phase extraction system was proposed for the determination of aluminum after preconcentration with glycerol-bonded silica gel. The method is rapid and efficient for the enrichment of aluminum ions at trace levels. Optimal sorption conditions were found for sorption and desorption of aluminum ions. The effects of diverse ions on the sorption and recovery of aluminum have been studied and it was shown that the selectivity of the sorption process was very good. A very satisfactory preconcentration factor of 500 was achieved by this method. The lowest concentration of aluminum ions for quantitative recovery was 2ngml(-1). The capacity of sorbent was 400microg per gram of sorbent. The method showed good reproducibility (R.S.D.=2.2% for n=7) and was applied to the determination of aluminum in mineral water, hair and green tea samples.
Department of Chemistry, Faculty of Sciences, Shiraz University, Shiraz 71454, Iran. safavi@chem.susc.ac.ir
Afsaneh
A
Safavi
Safieh
S
Momeni
Narges
N
Saghir
D000085:Acetates; D000327:Adsorption; D017607:Aluminum Compounds / Q000032:analysis*; D002021:Buffers; D005990:Glycerol / Q000737:chemistry*; D006197:Hair / Q000737:chemistry; D006801:Humans; D006863:Hydrogen-Ion Concentration; D007202:Indicators and Reagents; D007477:Ions; D012822:Silicon Dioxide / Q000737:chemistry*
D000085:Acetates; D017607:Aluminum Compounds; D002021:Buffers; D007202:Indicators and Reagents; D007477:Ions; D012822:Silicon Dioxide; D005990:Glycerol; C018824:ammonium acetate