Self-assembly of a cyclic metalladecapyridine from the reaction of 2,6-bis(bis(2-pyridyl)methoxymethane)pyridine with silver(I).
Reaction of Ag( p-MeC 6H 4SO 3) with 2,6-bis(bis(2-pyridyl)methoxymethane)pyridine (PY5) in CH 2Cl 2 gave [Ag (I) 2(PY5) 2](p-MeC 6H 4SO 3) 2 (1). Treatment of 2,6-bis(bis(2-pyridyl)hydroxymethane)pyridine (PY5-OH) with AgNO 3 in MeOH gave [Ag (I) 2(PY5-OH) 2](NO3) 2 (2); in the presence of PPh 3, this reaction afforded [Ag (I)(PY5-OH)(PPh 3)]NO 3 (3). The structures of 1- 3 have been determined by X-ray crystal analysis, revealing four-coordinate Ag (I) ions in these complexes. Both 1 and 2 feature a quadruply branched 28-membered C 16N 10M 2 metallamacrocycle fused to 10 pyridyl groups. On the basis of (1)H NMR measurements, the dinuclear 1 and 2 dissociate into a mononuclear complex upon dissolving in MeCN but in MeOH an equilibrium between the mono- and dinuclear species can be detected.
Huang
Jie-Sheng
JS
Department of Chemistry and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis, The University of Hong Kong, Pokfulam Road, Hong Kong, China. jshuang@hkucc.hku.hk
Xie
Jin
J
Kui
Steven C F
SC
Fang
Guo-Su
GS
Zhu
Nianyong
N
Che
Chi-Ming
CM
D018360:Crystallography, X-Ray; D019281:Dimerization; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*
D009942:Organometallic Compounds; D011725:Pyridines; D012834:Silver