Hysteretic sorption of light gases by a porous metal-organic framework containing tris(para-carboxylated) triphenylphosphine oxide.
The porous metal-organic framework (MOF) PCM-4, based on tris(para-carboxylated) triphenylphosphine oxide, contains atypical, polar organic substituents; the material exhibits a hysteretic sorption of Ar, N2 and O2, and demonstrates the advantage of ligands of this type.
Humphrey
Simon M
SM
University Chemical Laboratory, University of Cambridge, Lensfield Road, Cambridge, UKCB2 1EW. smh49@cam.ac.uk
Oungoulian
Shaunt E
SE
Yoon
Ji Woong
JW
Hwang
Young Kyu
YK
Wise
Erica R
ER
Chang
Jong-San
JS