Gold-ligand interaction studies of water-soluble aminoalcohol capped gold nanoparticles by NMR.
Novel reproducible preparations of gold nanoparticles capped by aminoalcohols have been set up by reduction of HAuCl4 with NaBH4 in aqueous solution. The characterization of Au@aminoalcohol nanoparticles performed by 1H NMR, ATR-FTIR, UV-vis spectroscopies, and TEM microscopy highlighted the binding site and the nature of the Au-NH bond.
Porta
Francesca
F
University of Milan, Dip. Chimica Inorganica Metallorganica Analitica, L. Malatesta Centre of Excellence, CIMAINA, and INSTM Unit, Via Venezian 21, Milan, Italy. francesca.porta@unimi.it
Krpetić
Zeljka
Z
Prati
Laura
L
Gaiassi
Aureliano
A
Scarì
Giorgio
G
D000605:Amino Alcohols / Q000737:chemistry*; D006046:Gold / Q000737:chemistry*; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D053768:Metal Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D046529:Microscopy, Electron, Transmission; D015394:Molecular Structure; D012995:Solubility; D017550:Spectroscopy, Fourier Transform Infrared; D014867:Water / Q000737:chemistry*
D000605:Amino Alcohols; D008024:Ligands; D014867:Water; D006046:Gold