Investigation of optical limiting in iron oxide nanoparticles.
We present the study of optical limiting in iron oxide nanoparticles of diameters 31, 44, and 61 nm dispersed in toluene under exposure to nanosecond laser pulses at 532 nm. In the low fluence region smaller size nanoparticles show better optical limiting compared to larger size nanoparticles while in the high fluence region all the three samples show same limiting performance. Experimental results were compared with the well reported limiter fullerene C(60) dissolved in toluene. Iron oxide nanoparticles show better optical limiting compared to C(60) in the intermediate fluence region and comparable performance in the high fluence region. The pico-second Z-scan studies indicate that the contribution of electronic nonlinear refractive index and the two-photon absorption to the optical limiting is negligible. Our observations further indicate that the dominant mechanism for the optical limiting in iron oxide nanoparticles is nonlinear scattering.
Laser Physics Application Division, Raja Ramanna Centre for Advanced Technology, Indore-452013 India.
C P
CP
Singh
K S
KS
Bindra
G M
GM
Bhalerao
S M
SM
Oak
D003102:Colloids / Q000737:chemistry; D003198:Computer Simulation; D004867:Equipment Design; D019544:Equipment Failure Analysis; D005290:Ferric Compounds / Q000737:chemistry*; D008027:Light; D008956:Models, Chemical; D053758:Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure*; D009391:Nephelometry and Turbidimetry / Q000379:methods*; D010316:Particle Size; D012031:Refractometry / Q000379:methods*; D012542:Scattering, Radiation
D003102:Colloids; D005290:Ferric Compounds; C000499:ferric oxide