A non-photochemical route for the regioselective preparation of rtct-pyridylcyclobutanes via hydrothermal isomerisation promoted by polymolybdates.
A novel approach for the regioselective preparation of rtct-tpcb (tpcb = tetrapyridylcyclobutanes) compounds promoted by polymolybdates under hydrothermal conditions is reported; these isomers are stabilised as counterions in inorganic-organic hybrid solids and are obtained in high to fair yield.
Briceño
Alexander
A
Laboratorio de Síntesis y Caracterización de Nuevos Materiales, Centro de Química, Instituto Venezolano de Investigaciones Científicas (IVIC), Apartado 21827, Caracas, 1020-A, Venezuela. abriceno@ivic.ve
Fulgence
Aaron
A
Hill
Yennifer
Y
Atencio
Reinaldo
R