Hysteretic sorption of light gases by a porous metal-organic framework containing tris(para-carboxylated) triphenylphosphine oxide.
The porous metal-organic framework (MOF) PCM-4, based on tris(para-carboxylated) triphenylphosphine oxide, contains atypical, polar organic substituents; the material exhibits a hysteretic sorption of Ar, N2 and O2, and demonstrates the advantage of ligands of this type.
University Chemical Laboratory, University of Cambridge, Lensfield Road, Cambridge, UKCB2 1EW. smh49@cam.ac.uk
Simon M
SM
Humphrey
Shaunt E
SE
Oungoulian
Ji Woong
JW
Yoon
Young Kyu
YK
Hwang
Erica R
ER
Wise
Jong-San
JS
Chang