Highly efficient methyl ketone synthesis by water-assisted C-C coupling between olefins and photoactivated acetone.
Photoirradiation of an acetone/water mixture containing olefins affords the corresponding methyl ketones highly efficiently via a water-assisted C-C coupling between acetonyl radical and olefins.
Shiraishi
Yasuhiro
Y
Research Center for Solar Energy Chemistry, Osaka University, Toyonaka, Japan. shiraish@cheng.es.osaka-u.ac.jp
Tsukamoto
Daijiro
D
Hirai
Takayuki
T
D000096:Acetone / Q000737:chemistry*; D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D007659:Ketones / Q000138:chemical synthesis*; D015394:Molecular Structure; D010777:Photochemistry / Q000379:methods; D014867:Water / Q000737:chemistry
D000475:Alkenes; D007659:Ketones; D014867:Water; D000096:Acetone