Characterisation of Bionate polycarbonate polyurethanes for orthopaedic applications.
Two polycarbonate polyurethanes, Bionate 75D and Bionate 80A, have been characterized for application in biomimetic joint replacement systems. Procedures involved measurement of the effects of compounding and moulding on molecular weight, melt rheometry, and mechanical testing using conditioned and aged specimens. The effects of compounding with hydroxyapatite and carbon fibres were also evaluated. With Bionate 75D moulding reduces the molecular weight by 30%. Passing the material through a twin screw extruder without filler has similar molecular weight reduction effects to injection moulding. Inclusion of carbon fibre has little additional effect on molecular weight, although moulding of the fibre filled compound causes some further degradation, and Mw is almost halved compared with the original value. Inclusion of hydroxyapatite reduces Mw in a moulded component to less than a quarter of the original value and some form of chemical interaction between the polymer and filler is presumed. The apparent melt viscosity of the Bionate 75D was reduced by the addition of both carbon fibres and hydroxyapatite and this is thought to arise from reduction in molecular weight during the compounding process and the development of shear planes at the polymer-filler interface. The polymer glass transition temperatures are shifted to slightly higher values by the inclusion of filler. The tensile test results show the reinforcing effect of the carbon fibres, but poor wetting and pull out of the fibres was evident. Water absorption results suggest that the materials stabilise after 2 weeks, but the tensile results indicate that property change occurred between 1 month and 5 months of exposure. However the shape of the stress-strain curves is not altered, but with extended water exposure is translated to lower stress levels.
Geary
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Department of Materials Science and Technology, University of Limerick, Limerick, Ireland.
Birkinshaw
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Jones
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D001672:Biocompatible Materials / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry; D000077482:Carbon Fiber; D017886:Durapatite / Q000737:chemistry; D006801:Humans; D008422:Materials Testing; D015394:Molecular Structure; D008970:Molecular Weight; D009985:Orthopedics; D026741:Physical Therapy Modalities; D011076:Polycarboxylate Cement / Q000737:chemistry; D011108:Polymers / Q000737:chemistry*; D011140:Polyurethanes / Q000737:chemistry*; D013499:Surface Properties; D013696:Temperature; D013718:Tensile Strength; D014783:Viscosity
D001672:Biocompatible Materials; D000077482:Carbon Fiber; D011076:Polycarboxylate Cement; D011108:Polymers; D011140:Polyurethanes; C005506:polycarbonate; D002244:Carbon; D017886:Durapatite