Hydrogenation of 1-butene on nanosized Pd/ZnO catalysts.
The reaction concerning the hydrogenation of 1-butene has occupied the researchers conducting research based on the method of reversed-flow inverse gas chromatography (RF-IGC), for extended time periods. This work aims to define and record, with the utmost accuracy, the phenomena and their possible parallel reactions. It was a challenge for the RF-IGC, which was met. The venture consisted of many parts. Answers had to be provided to the following questions: (a) Can RF-IGC deal with issues of catalysis? (b) Can RF-IGC be applied to thin films? (c) Can RF-IGC identify peaks? (d) Can RF-IGC define the gnostic regions of adsorption, desorption, surface diffusion, surface reaction, the existence of more than one reaction? (e) Can it kinetically follow the above? The answer is certainly yes. The effort made is presented in this work and aims to answer all the above questions.
Agelakopoulou
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School of Chemical Engineering, National Technical University of Athens, 9 Iroon Polytechniou St., 157 80 Zografou, Athens, Greece.
Roubani-Kalantzopoulou
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D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D002849:Chromatography, Gas / Q000379:methods; D006865:Hydrogenation; D053758:Nanoparticles / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*; D015203:Reproducibility of Results; D015034:Zinc Oxide / Q000737:chemistry*
D000475:Alkenes; D010165:Palladium; C058602:1-butene; D015034:Zinc Oxide