Solution decomposition of the layered double hydroxide of Co with Fe: phase segregation of normal and inverse spinels.
The nitrate-intercalated layered double hydroxide of Co with Fe decomposes on hydrothermal treatment to yield an oxide residue at a temperature as low as 180 degrees C. The oxide product is phase segregated into a Co(3)O(4)-type normal spinel and a CoFe(2)O(4)-type inverse spinel. Phase segregation is facilitated as decomposition in a solution medium takes place by dissolution of the precursor hydroxide followed by reprecipitation of the oxide phases. In contrast, thermal decomposition takes place at 400 degrees C. This temperature is inadequate to induce diffusion in the solid state whereby phase segregation into the thermodynamically stable individual spinels is suppressed. The result is a single-phase metastable mixed spinel oxide. This is rather uncommon in that a hydrothermal treatment yields thermodynamically stable products where as thermal decomposition yields a metastable product.
Department of Chemistry, Central College, Bangalore University, Bangalore 560 001, India.
Sylvia
S
Britto
P Vishnu
PV
Kamath
N
N
Ravishankar