Micropatterning of ZnO nanoarrays by forced hydrolysis of anhydrous zinc acetate.
Micropatterns of ZnO nanoarrays were simply and successfully fabricated in an aqueous solution without any high-temperature treatment and/or expensive catalyst. In situ forced hydrolysis of patterned anhydrous zinc acetate, derived by ultraviolet irradiation with a photomask, resulted in heterogeneous nucleation and growth to form ZnO nanoarrays. Micropatterns of ZnO nanoarrays were characterized by FE-SEM and XRD. ZnO nanoarrays were well site-selectively deposited on anhydrous zinc acetate coated regions at 88 degrees C. HR-TEM clarified the formation mechanism in which anhydrous zinc acetate showed a tendency of forced hydrolyzation to ZnO nanocrystals at the initial stage in the reaction solution.
Hu
Xiulan
X
National Institute of Advanced Industrial Science and Technology (AIST), 2266-98 Anagahora, Shimoshidami, Moriyama-ku, Nagoya 463-8560, Japan. xiulan-hu@aist.go.jp
Masuda
Yoshitake
Y
Ohji
Tatsuki
T
Kato
Kazumi
K