Synthesis of allylsilanes and dienylsilanes by a one-pot catalytic C-H borylation--Suzuki-Miyaura coupling sequence.
Allylsilane and various vinyl substrates undergo selective C-H bond functionalization based boronation reactions using iridium catalysis. The products were further reacted with aryl and vinyl halogenides in a one-pot sequence. This method is suitable for regio- and stereoselective synthesis of various allylsilanes and dienylsilanes.
Olsson
Vilhelm J
VJ
Stockholm University, Arrhenius Laboratory, Department of Organic Chemistry, Stockhom, Sweden.
Szabó
Kálmán J
KJ
D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry; D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D012821:Silanes / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D000475:Alkenes; D001897:Boronic Acids; D012821:Silanes; C511847:allylsilane