Synthesis of N,N-disubstituted phosphoramidates via a Lewis acid-catalyzed phosphorimidate rearrangement.
A Lewis acid-catalyzed rearrangement of phosphorimidates allows a direct, high-yielding transformation of azides with commercially available phosphites into secondary phosphoramidates.
Freie Universität Berlin, Institut für Chemie und Biochemie, Takustrabe 3, 14195 Berlin, Germany.
Ina
I
Wilkening
Giuseppe
G
del Signore
Christian P R
CP
Hackenberger