A three-dimensional lanthanide-organic radical open-framework.
The reaction of a 3-connecting PTMTC radical with Tb(III) ions forms a three-dimensional open-framework with the formula [Tb(PTMTC)(DMF)(3)] (1), which associates a lattice complex T topology with large channels, guest-induced reversible crystal to amorphous transformations and ferromagnetic metal-radical interactions.
Roques
Nans
N
Institut de Ciència de Materials de Barcelona (CSIC), Campus Universitari, 08193 Bellaterra, Catalonia, Spain.
Maspoch
Daniel
D
Imaz
Inhar
I
Datcu
Angela
A
Sutter
Jean-Pascal
JP
Rovira
Concepció
C
Veciana
Jaume
J