Absolute level-resolved reactive and inelastic rate constants in Li+Li2*.
We have used nuclear parity-changing collisions to obtain absolute level-to-level rate constants for reactive scattering in a triatomic system with identical nuclei. We have determined rate constants for the system (7)Li(2) (*)(A (1)Sigma(u) (+))(v(i)=2,j(i)=19)+(7)Li-->(7)Li+(7)Li(2) (*)(A (1)Sigma(u) (+))(v(f),j(f)), from laser-induced fluorescence spectra of lithium vapor in a heat pipe oven. Parity-preserving collisions yielded measurements of absolute rotationally and vibrationally inelastic rate constants as well. We compare the reactive rate constants with statistical prior distributions and the inelastic results with previously measured results on the Ne+(7)Li(2) (*) system.
Coppage
Steven
S
Department of Physics, Wesleyan University, Middletown, Connecticut 06459, USA.
Matei
Paula
P
Stewart
Brian
B