Electronic structure of the glyoxalbis(2-hydroxyanil) (gha) ligand in [Co(III)(gha)(PPh3)2]+: radical vs. non-radical states.
The synthesis, structure and spectroscopic properties of a complex salt [Co(III)(gha)(PPh3)2][Co(II)Cl3(PPh3)] x C2H5OH (1) are reported; gha = glyoxalbis(2-hydroxyanil). This is the first single crystal X-ray structure of a (gha)2- complex with a transition element. Though the determined bond parameters and UV-Vis spectroscopic data correlate well with a diradical description for the cation in 1, detailed electronic structure calculations using density functional theory confirm that [Co(gha)(PPh3)2]+ can be described as a closed shell singlet species which nevertheless displays an interesting electronic structure with significant electron transfer to the formally unoccupied LUMO of the square planar [Co(gha)]+ fragment. It was found that without the phosphine coligands, the [Co(gha)]+ unit has a triplet ground state with the lowest energy singlet diradical state lying only 1 kcal mol(-1) higher in energy. The chemistry of the gha ligand is of interest as a spin diverse redox active system.
Roy
Amit Saha
AS
Department of Chemistry, R. K. Mission Residential College, Narendrapur, Kolkata, 103, India.
Muresan
Nicoleta
N
Tuononen
Heikki M
HM
Rath
Sankar P
SP
Ghosh
Prasanta
P