Palladium-catalyzed hydrophosphorylation and hydrophosphinylation of cyclopropenes.
Novel transition-metal-catalyzed addition of P-H entities across the cyclopropene double bond has been developed. This transformation allows for mild and efficient preparation of phosphorus-containing cyclopropanes in good yields and high degrees of diastereoselectivity.
Alnasleh
Bassam K
BK
Department of Chemistry, Univeristy of Kansas, 1251 Wescoe Hall Drive, Lawrence, Kansas 66045-75832, USA.
Sherrill
William M
WM
Rubin
Michael
M
D002384:Catalysis; D003521:Cyclopropanes / Q000138:chemical synthesis* / Q000737:chemistry; D009943:Organophosphorus Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010165:Palladium / Q000737:chemistry; D010720:Phosphines / Q000138:chemical synthesis; D010766:Phosphorylation; D013237:Stereoisomerism
D003521:Cyclopropanes; D009943:Organophosphorus Compounds; D010720:Phosphines; D010165:Palladium; C021985:cyclopropene