title: Palladium-catalyzed hydrophosphorylation and hydrophosphinylation of cyclopropenes.
abstract: Novel transition-metal-catalyzed addition of P-H entities across the cyclopropene double bond has been developed. This transformation allows for mild and efficient preparation of phosphorus-containing cyclopropanes in good yields and high degrees of diastereoselectivity.
authors.affiliation: Department of Chemistry, Univeristy of Kansas, 1251 Wescoe Hall Drive, Lawrence, Kansas 66045-75832, USA.
authors.forename: Bassam K
authors.initials: BK
authors.lastname: Alnasleh
authors.forename: William M
authors.initials: WM
authors.lastname: Sherrill
authors.forename: Michael
authors.initials: M
authors.lastname: Rubin
mesh_terms: D002384:Catalysis; D003521:Cyclopropanes / Q000138:chemical synthesis* / Q000737:chemistry; D009943:Organophosphorus Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010165:Palladium / Q000737:chemistry; D010720:Phosphines / Q000138:chemical synthesis; D010766:Phosphorylation; D013237:Stereoisomerism
chemical_list: D003521:Cyclopropanes; D009943:Organophosphorus Compounds; D010720:Phosphines; D010165:Palladium; C021985:cyclopropene