N-Dealkylation of aliphatic amines and selective synthesis of monoalkylated aryl amines.
Highly selective alkyl transfer processes of mono-, di- and trialkyl amines in the presence of the Shvo catalyst have been realized; in addition, a general method for N-alkylation of aniline with di- and trialkyl amines is presented.
Hollmann
Dirk
D
Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Str. 29a, D-18059, Rostock, Germany.
Bähn
Sebastian
S
Tillack
Annegret
A
Beller
Matthias
M
D000588:Amines / Q000737:chemistry*; D000814:Aniline Compounds / Q000737:chemistry; D003640:Dealkylation; D013379:Substrate Specificity
D000588:Amines; D000814:Aniline Compounds; C023650:aniline