Thermally changing lattice distance of lamella in the hydrated solid of octadecyltrimethylammonium chloride.
A temperature scanning small-angle X-ray scattering measurement was carried out for the hydrated solids of octadecyltrimethylammonium chloride (OTAC). A gradual change of the lattice spacing of lamella-like structure from 40 nm at 5 degrees C to 20 nm at 18 degrees C was observed in the melting process of the hydrated solid that was incubated at 4 degrees C for a period of 24 h in the aqueous solution, while little change of the lattice spacing of about 20 nm was observed in the same process of the hydrated solid that was incubated at 4 degrees C for a period about 10 min. This indicates structural changes of the hydrated solid during the incubation at 4 degrees C and in the melting process. Corresponding to the nanostructure changes, broad endothermic peaks were observed at temperatures from 13 to 22 degrees C for the former hydrated solid and at temperatures from 15 to 21 degrees C for the latter hydrated solid in difference scanning calorimetry measurements. The structure change at temperatures below 13 degrees C is considered to be athermal from the fact that no endothermic peak is observed there. Large dielectric dispersions at frequencies at about 10 kHz were observed for the suspensions of hydrated solids but not for the solutions of dissolved solids. It was found that the electric conductance of the hydrated solid suspensions was much lower than that of the solutions of dissolved solids. The observed electric properties indicate that an amount of the free chloride ion is very small and that the chloride ions binding to the ammonium groups are movable in the hydrated solids by responding to an applied electric field. The electric conductance of suspension of the hydrated solid being incubated at 4 degrees C for 10 min was 4 times as large as that of a suspension of the hydrated solid being incubated at the same temperature for 24 h. This indicates that the structural change of the OTAC hydrated solid at 4 degrees C is related to the chloride ion binding to the hydrated solid. The experimental results described above suggest that the lamella in the hydrated solid of OTAC is undulated and that the wavelength of undulation increases with the incubation at a temperature much lower than the melting temperature.
Sasaki
Shigeo
S
Department of Chemistry, Faculty of Sciences, Kyushu University, 33 Hakozaki, Higashi ku, Fukuoka 812, Japan. Shigeo-ssk@chem.kyushu-univ.jp