Oxidative C-H and C-C bond cleavage by a (2,2'-bipyridine)copper(I) chloride complex.
Acetonitrile is easily oxygenated at ambient reaction conditions to copper(II) oxalate [Cu(bpy)(ox)] n mediated by copper(I) chloride in the presence of 3,5-di-tert-butylcatechol and 2,2'-bipyridine. In the case of other nitriles (e.g., propionitrile), instead, the unusual and selective 1,4-extradiol cleavage of 3,5-di-tert-butylcatechol occurs to give copper(II) tert-butylmaleate [Cu(bma)(bpy)(H2O)]n in good yield.
Csonka
Róbert
R
Department of Chemistry, University of Pannonia, H-8200 Veszprem, Hungary.
Kaizer
József
J
Giorgi
Michel
M
Réglier
Marius
M
Hajba
László
L
Mink
János
J
Speier
Gábor
G