Growth and characterization of a new metal-organic nonlinear optical bis (thiourea) cadmium zinc chloride single crystals.
A new semiorganic nonlinear optical bis (thiourea) cadmium zinc chloride (BTCZC) crystal has been synthesized. BTCZC single crystals were grown from aqueous solution by slow evaporation technique. The solubility of BTCZC has been determined for various temperatures. Single crystal X-ray diffraction (XRD) study has been carried out to identify the lattice parameters. Fourier transform infrared (FTIR) studies confirm the various functional groups present in the grown crystal. The transmission and absorption spectra of this crystal show that the lower cut off wavelength lies at 260 nm. The thermal analyses confirmed that the crystal is stable up to 201 degrees C. The nonlinear optical (NLO) property of the grown crystal has been confirmed by Kurtz-powder second harmonic generation (SHG) test.
Kirubavathi
K
K
Department of Physics, Thanthai Hans Roever College, Perambalur 621212, Tamilnadu, India.
Selvaraju
K
K
Kumararaman
S
S
D002104:Cadmium / Q000737:chemistry*; D002712:Chlorides / Q000737:chemistry*; D003460:Crystallization; D008422:Materials Testing; D008670:Metals / Q000737:chemistry; D008956:Models, Chemical; D055095:Optics and Photonics; D012995:Solubility; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature; D013890:Thiourea / Q000737:chemistry*; D014466:Ultraviolet Rays; D014961:X-Ray Diffraction; D017967:Zinc Compounds / Q000737:chemistry*
D002712:Chlorides; D008670:Metals; D017967:Zinc Compounds; D002104:Cadmium; C016837:zinc chloride; D013890:Thiourea