title: Fate of anilide and aniline herbicides in plant-materials-amended soils.
abstract: The fate of herbicides trifluralin, pendimethalin, alachlor and metolachlor in paddy field soils amended with plant materials was investigated. The plant materials were purple sesbania, vegetable soybean and rice straw. The investigation was performed at two temperatures (25 and 40 degrees C) and two soil water moistures (60 and 90% water-holding capacity). The results showed linear and Freudlich equations described the adsorption of amide compound to soil. Adsorption coefficient (K(d)) fit to linear equation were in general greater in plant material-amended soils than in non-amended soil, especially in soil amending with rice straw. Increasing temperature and soil water moisture content shortened the half-lives of compounds in various treated soils. The movement of compounds in the soil columns showed the maximum distribution of aniline type compound, trifluralin and pendimethalin, appeared at the upper top of 0 to 5 and 0 to 10 cm of soil column, respectively, and of anilide type, alachlor and metolachlor, were distributed at 0 to 25 cm of the soil column. The mobility of chemicals in the different treated soils was simulated by the behavior assessment model (BAM). There was no significant difference among different plant material incubated soils on dissipation and mobility of compounds in soils.
authors.affiliation: Department of Agricultural Chemistry, National Taiwan University, Taipei, Taiwan.
authors.forename: Jui-Hung
authors.initials: JH
authors.lastname: Yen
authors.forename: Pi-Wen
authors.initials: PW
authors.lastname: Tsai
authors.forename: Wen-Ching
authors.initials: WC
authors.lastname: Chen
authors.forename: Yei-Shung
authors.initials: YS
authors.lastname: Wang
mesh_terms: D000081:Acetamides; D000813:Anilides / Q000032:analysis* / Q000378:metabolism / Q000633:toxicity; D000814:Aniline Compounds / Q000032:analysis* / Q000378:metabolism / Q000633:toxicity; D001673:Biodegradation, Environmental; D006540:Herbicides / Q000032:analysis* / Q000378:metabolism / Q000633:toxicity; D006813:Humidity; D018570:Risk Assessment; D012988:Soil Microbiology; D012989:Soil Pollutants / Q000032:analysis* / Q000378:metabolism / Q000633:toxicity; D013696:Temperature; D013997:Time Factors
chemical_list: D000081:Acetamides; D000813:Anilides; D000814:Aniline Compounds; D006540:Herbicides; D012989:Soil Pollutants; C000188:alachlor; C023650:aniline; C051786:metolachlor