Photoresponsive peptoid oligomers bearing azobenzene side chains.
N-Substituted glycine peptoid oligomers were synthesized to incorporate a photoresponsive azobenzene side chain. The ability of this side chain to undergo reversible photoisomerization was established, and the cis- to trans-azobenzene thermal isomerization of this side chain was investigated. Circular dichroism studies indicated that trans- to cis-azobenzene isomerization does not significantly alter the backbone conformation in a series of peptoids thought to have well-defined structures.
Shah
Neel H
NH
Department of Chemistry, New York University, 100 Washington Square East, New York, NY 10003-6688, USA.
Kirshenbaum
Kent
K
D001391:Azo Compounds / Q000737:chemistry*; D040761:Biomimetic Materials / Q000138:chemical synthesis* / Q000737:chemistry; D002942:Circular Dichroism; D007536:Isomerism; D007700:Kinetics; D034444:Peptoids / Q000138:chemical synthesis* / Q000737:chemistry; D010777:Photochemistry
D001391:Azo Compounds; D034444:Peptoids; C009850:azobenzene