Minimization of the environmental impact in the unhairing of bovine hides.
This study tests an alternative method to the traditional unhairing method used during the process of tanning the hides. The new method is based on the substitution of sodium sulfide by hydrogen peroxide as an unhairing agent in both hair recovery and recirculation of the floats employed in the process. The properties of the hides obtained using the two methods have been compared and the results indicate that those hides have similar physical, chemical, and organoleptic properties. However, the differences existing from an environmental point of view are significant. These include reductions of water consumption (approx 70%), chemical oxygen demand (approx 35%), toxicity (98%) and total kjendhal nitrogen (50%). Also, the risk associated with the production of hydrogen sulfide is eliminated, which implies a great improvement in terms of safety for the workers. Given the large amounts of water and chemical pollution discharged in the process, the reductions in absolute values represent a significant improvement. A financial assessment was carried out to demonstrate that the proposed new system is 16% more economic than the traditional one.
Morera
Josep M
JM
Igualada Technical Engineering School (EUETII), Technical University of Catalonia (UPC), Plaça del Rei, 15, 08700-Igualada, Spain. jmmorera@euetii.upc.edu
Bacardit
Anna
A
Ollé
Lluís
L
Bartolí
Esther
E
Borràs
Maria D
MD
D000818:Animals; D002417:Cattle; D004787:Environmental Pollution / Q000517:prevention & control*; D006861:Hydrogen Peroxide / Q000737:chemistry; D007220:Industrial Waste / Q000517:prevention & control*; D013440:Sulfides / Q000737:chemistry; D013633:Tanning / Q000379:methods*
D007220:Industrial Waste; D013440:Sulfides; D006861:Hydrogen Peroxide; C033479:sodium sulfide