Photoinduced intercomponent processes in multichromophoric species made of Pt(II)-terpyridine-acetylide and dipyrromethene-BF2 subunits.
A new multicomponent species made of Pt(II) terpyridine and difluoroborondipyrromethene (bodipy) dyes is synthesized and its absorption, redox, and emission properties are reported; photoinduced energy transfer from the Pt-based (3)MLCT state to the bodipy triplet occurs both at room temperature and at 77 K.
Nastasi
Francesco
F
Dipartimento di Chimica Inorganica, Chimica Analitica e Chimica Fisica, Università di Messina, Via Sperone 31, Messina, Italy.
Puntoriero
Fausto
F
Campagna
Sebastiano
S
Diring
Stéphane
S
Ziessel
Raymond
R
D004735:Energy Transfer; D005456:Fluorescent Dyes / Q000737:chemistry*; D049449:Luminescence; D015394:Molecular Structure; D009944:Organoplatinum Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010084:Oxidation-Reduction; D010777:Photochemistry; D011162:Porphobilinogen / Q000031:analogs & derivatives* / Q000737:chemistry; D011726:Pyridinium Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry; D014466:Ultraviolet Rays
D005456:Fluorescent Dyes; D009944:Organoplatinum Compounds; D011726:Pyridinium Compounds; C507544:dipyrromethene; D011162:Porphobilinogen; D012428:Ruthenium