N-bridged diiron phthalocyanine catalyzes oxidation of benzene with H2O2 via benzene oxide with NIH shift evidenced by using 1,3,5-[D3]benzene as a probe.
Kudrik
Evgeny V
EV
Institut de Recherches sur la Catalyse et l'Environnement de Lyon, UMR 5256, CNRS-Université Lyon 1, 2 avenue A. Einstein, Villeurbanne Cedex, France.
Sorokin
Alexander B
AB
D001554:Benzene / Q000737:chemistry*; D002384:Catalysis; D005296:Ferrous Compounds / Q000737:chemistry*; D008401:Gas Chromatography-Mass Spectrometry; D006861:Hydrogen Peroxide / Q000737:chemistry*; D007211:Indoles / Q000737:chemistry*; D015335:Molecular Probes; D010084:Oxidation-Reduction
D005296:Ferrous Compounds; D007211:Indoles; D015335:Molecular Probes; C493990:iron phthalocyanine; D006861:Hydrogen Peroxide; D001554:Benzene