Concerted attack of frustrated Lewis acid-base pairs on olefinic double bonds: a theoretical study.
A computational approach reveals cooperative action of the preorganized acidic and basic centers of the frustrated P(t-Bu)(3)/B(C(6)F(5))(3) Lewis pair on olefinic bonds as the key to the observed regioselective addition reaction.
Stirling
András
A
Chemical Research Center of HAS, Pusztaszeri út 59-67, H-1025 Budapest, Hungary.
Hamza
Andrea
A
Rokob
Tibor András
TA
Pápai
Imre
I