title: A regio- and stereocontrolled approach to pyranosyl C-nucleoside synthesis.
abstract: Six novel diastereomerically pure C-nucleosides have been synthesized from nonchiral starting materials, using the ene/intramolecular Sakurai cyclization reaction demonstrating a simple, general, and stereocontrolled approach to pyranosyl C-nucleosides.
authors.affiliation: Respiratory CEDD, Stevenage SG12NY, UK.
authors.forename: Philip
authors.initials: P
authors.lastname: Redpath
authors.forename: Simon
authors.initials: S
authors.lastname: Macdonald
authors.forename: Marie E
authors.initials: ME
authors.lastname: Migaud
mesh_terms: D008968:Molecular Conformation; D009705:Nucleosides / Q000138:chemical synthesis*; D011714:Pyrans / Q000138:chemical synthesis*; D013237:Stereoisomerism
chemical_list: D009705:Nucleosides; D011714:Pyrans