title: Rhodium-catalyzed enantioselective desymmetrization of bicyclic hydrazines with alkynylboronic esters.
abstract: The first successful asymmetric transfer of rhodium-alkynyl species to symmetrical strained alkenes has been realized starting from bicyclic hydrazines and alkynylboronic esters.
authors.affiliation: Dipartimento di Chimica Bioorganica e Biofarmacia, Università di Pisa, Via Bonanno 33, 56126, Pisa, Italy.
authors.forename: Stefano
authors.initials: S
authors.lastname: Crotti
authors.forename: Ferruccio
authors.initials: F
authors.lastname: Bertolini
authors.forename: Franco
authors.initials: F
authors.lastname: Macchia
authors.forename: Mauro
authors.initials: M
authors.lastname: Pineschi
mesh_terms: D001897:Boronic Acids / Q000737:chemistry*; D001643:Bridged Bicyclo Compounds / Q000737:chemistry*; D002384:Catalysis; D004952:Esters / Q000737:chemistry*; D006834:Hydrazines / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism; D013379:Substrate Specificity
chemical_list: D001897:Boronic Acids; D001643:Bridged Bicyclo Compounds; D004952:Esters; D006834:Hydrazines; D012238:Rhodium