Synthesis of eta1-borazine complexes of palladium and platinum.
The eta(1)-borazine complexes trans-[(Cy(3)P)(2)M(Br)(Br(2)B(3)N(3)H(3))] (Cy = cyclohexyl) were prepared by oxidative addition of a B-Br bond of (BrBNH)(3) to [M(PCy(3))(2)] (M = Pd, Pt). Furthermore the platinum compound was converted into the T-shaped cationic complex trans-[(Cy(3)P)(2)Pt(Br(2)B(3)N(3)H(3))][BAr(f)(4)] [Ar(f) = 3,5-(CF(3))(2)C(6)H(3)] by addition of Na[BAr(f)(4)].
Braunschweig
Holger
H
Julius-Maximilians Universität Würzburg, Am Hubland, 97074, Würzburg, Germany. h.braunschweig@mail.uni-wuerzburg.de
Green
Helen
H
Radacki
Krzysztof
K
Uttinger
Katharina
K