AlCl3-catalyzed tandem acetylation of hydroarylated [60]fullerenes.
The AlCl3-catalyzed acetylation of 1,2-hydrophenylated [60]fullerenes, HC60-Ar, proceeded via a sequential manner involving the acetylation at the hydrogenated fullerene carbon, the following intramolecular cyclization with the adjacent aryl group, the facile loss of water, and the second acetylation of the generated indenylidene double bond. However, the similar reaction of the hydrobiphenylated analogue brought about the normal acetylation at the terminal aromatic ring prior to the same sequential reactions as did hydrophenylated fullerenes.
Kokubo
Ken
K
Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan. kokubo@chem.eng.osaka-u.ac.jp
Tochika
Shinya
S
Kato
Mai
M
Sol
Yui
Y
Oshima
Takumi
T
D000107:Acetylation; D000438:Alcohols / Q000138:chemical synthesis; D000077410:Aluminum Chloride; D017607:Aluminum Compounds / Q000737:chemistry*; D001555:Benzene Derivatives / Q000737:chemistry; D001713:Biphenyl Compounds / Q000737:chemistry; D002384:Catalysis; D002712:Chlorides / Q000737:chemistry*; D003500:Cyclization; D037741:Fullerenes / Q000737:chemistry*; D007659:Ketones / Q000138:chemical synthesis
D000438:Alcohols; D017607:Aluminum Compounds; D001555:Benzene Derivatives; D001713:Biphenyl Compounds; D002712:Chlorides; D037741:Fullerenes; D007659:Ketones; D000077410:Aluminum Chloride; C069837:fullerene C60