Phenanthroline unit as a building block for carbohydrate receptors.
An acyclic receptor 1, containing phenanthroline- and aminopyridine-based recognition sites, has been established as a powerful carbohydrate receptor. Compared to the previously described acyclic receptors, compound 1 shows significantly higher binding affinities as well as selectivities, which are quite different from those of the earlier systems. The phenanthroline unit has been established as a valuable building block for the construction of effective and selective carbohydrate receptors.
Mazik
Monika
M
Institut für Organische Chemie der Technischen Universität Braunschweig, Hagenring 30, 38106 Braunschweig, Germany. m.mazik@tu-bs.de
Hartmann
Andrè
A
D001665:Binding Sites; D002241:Carbohydrates / Q000737:chemistry*; D005643:Fucose; D005697:Galactosides; D005960:Glucosides; D009682:Magnetic Resonance Spectroscopy; D010618:Phenanthrolines / Q000737:chemistry*; D013329:Structure-Activity Relationship; D017186:Titrimetry
D002241:Carbohydrates; D005697:Galactosides; D005960:Glucosides; D010618:Phenanthrolines; D005643:Fucose