Novel luminescent metal-organic frameworks [Eu2L3(DMSO)2(MeOH)2] x 2 DMSO x 3 H2O and [Zn2L2(DMSO)2] x 1.6 H2O (L = 4,4'-ethyne-1,2-diyldibenzoate).
Novel metal-organic frameworks [Eu2L3(DMSO)2(MeOH)2] x 2 DMSO x 3 H2O, 1, and [Zn2L2(DMSO)2] x 1.6 H2O, 2, (L = 4,4'-ethyne-1,2-diyldibenzoate) have been synthesized and structurally characterized. Compound 1 is a 3D open framework while 2 features interpenetrating 2D sheets in the crystal lattice. Both compounds have been characterized with X-ray crystallography, elemental analysis, and thermogravimetric analysis. Compounds 1 and 2 are red and blue-green luminescent, respectively, in the solid state at ambient temperature. Thermogravimetric analysis implies that the extensive interpenetration stabilizes the lattice of 2, although it diminishes the porosity at the same time. The luminescence of 1 can be reversibly quenched and restored by the addition and removal of iodine.
Pham
Bich Tram Nguyen
BT
Davenport Chemical Research Laboratories, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada M5S 3H6.
Lund
Liisa M
LM
Song
Datong
D