Molecular organization, structural orientation, and surface topography of monoacylated beta-cyclodextrins in monolayers at the air-aqueous interface.
The surface behavior of monoacylated beta-cyclodextrins, with hydrocarbon chains of 16, 14, and 10 carbons, has been assessed by the measurement of the surface pressure, surface (dipole) potential, optical reflectivity, and surface topography in monolayers at the air-water interface. For all the derivatives studied, the intermolecular organization adopted along compression-decompression isotherms reveals a rich variety of packing states which imply profound reorganization of the hydrophobic and hydrophilic moieties of the beta-cyclodextrin derivatives in the film, depending on the lateral surface pressure. The intermolecular arrangements are consistent with the adoption of a different and defined orientation of the cyclic oligosaccharide unit, relative to the interfacial plane and the aqueous subphase. This is different from the behavior of the per-substituted derivatives, and none of the changes exhibited by the monosubstituted forms are consistent with the oligosaccharide ring remaining in a fixed orientation along the interface when the surface pressure is varied.
Vico
Raquel V
RV
Departamento de Quimica Biologica, Centro de Investigaciones en Quimica Biologica de Cordoba, Facultad de Ciencias Quimicas, Universidad Nacional de Cordoba, Haya de la Torre y Medina Allende, Ciudad Universitaria, Cordoba, Argentina.
Silva
O Fernando
OF
de Rossi
Rita H
RH
Maggio
Bruno
B
D000179:Acrylates / Q000737:chemistry*; D000388:Air; D006838:Hydrocarbons / Q000737:chemistry; D008854:Microscopy, Electron; D008958:Models, Molecular; D015394:Molecular Structure; D011312:Pressure; D013499:Surface Properties; D014867:Water / Q000737:chemistry*; D047392:beta-Cyclodextrins / Q000737:chemistry*
D000179:Acrylates; D006838:Hydrocarbons; D047392:beta-Cyclodextrins; D014867:Water; C036658:acrylic acid