A new approach to separation and pre-concentration of some trace metals with co-precipitation method using a triazole.
A new co-precipitation method was developed to separate and pre-concentrate Fe(3+), Cu(2+), Cr(3+), Zn(2+), and Pb(2+) ions using an organic co-precipitant, 3-benzyl-4-p-nitrobenzylidenamino-4,5-dihydro-1,2,4-triazole-5-on (BPNBAT) without adding any carrier element, following flame atomic absorption spectrometric (FAAS) determinations. Effect of some analytical conditions, such as pH of the solution, quantity of the co-precipitant, standing time, centrifugation rate and time, sample volume, and interference of concomitant ions were investigated over the recovery yields of the metal ions. The recoveries of the analyte ions were in the range of 95-102%. The detection limits, corresponding to three times the standard deviation of the blank, were found to be in the range of 0.3-2.0 microg L(-1). The precision of the method, evaluated as the relative standard deviation (R.S.D.) obtained after analyzing a series of 10 replicates, was between 1.6% and 6.0% for the trace metal ions. The method was validated by analyzing two certified reference materials and spiked addition. The proposed procedure was applied for the trace metal ions in some environmental samples.
Bulut
Volkan Numan
VN
Department of Chemistry, Faculty of Arts & Sciences, Karadeniz Technical University, 61080 Trabzon, Turkey.
Duran
Celal
C
Gundogdu
Ali
A
Soylak
Mustafa
M
Yildirim
Nuri
N
Elci
Latif
L
D011232:Chemical Precipitation; D015203:Reproducibility of Results; D013054:Spectrophotometry, Atomic; D014131:Trace Elements / Q000032:analysis / Q000302:isolation & purification*; D014230:Triazoles / Q000737:chemistry*
D014131:Trace Elements; D014230:Triazoles