Solvent-ligated copper(II) complexes for the homopolymerization of 2-methylpropene.
Copper(II) complexes with weakly coordinating counter anions can be utilized as highly efficient catalysts for the synthesis of poly(2-methylpropene) ("polyisobutene") with a high content of terminal double bonds. These copper(II) compounds are significantly more active than the manganese(II) complexes described previously, can be applied in chlorine-free solvents such as toluene, are easily accessible, and can be handled at room temperature and in laboratory atmospheres for brief periods, but they are sensitive to excess water, thereby losing their catalytic activity. Replacing the acetonitrile ligands by benzonitrile ligands improves the solubility and catalytic activity in nonpolar and nonchlorinated solvents. However, the benzonitrile copper(II) compounds have lower thermal stability than their acetonitrile congeners.
Li
Yang
Y
Molecular Catalysis, Fakultät für Chemie der Technische Universität München, Lichtenbergstrasse 4, Garching, Germany.
Voon
Lih Ting
LT
Yeong
Hui Yee
HY
Hijazi
Ahmed K
AK
Radhakrishnan
Narayanan
N
Köhler
Klaus
K
Voit
Brigitte
B
Nuyken
Oskar
O
Kühn
Fritz E
FE