Synthesis of fullerooxazoles: novel reactions of [60]fullerene with nitriles promoted by ferric perchlorate.
The ferric perchlorate-mediated reactions of C 60 with various nitriles in o-dichlorobenzene under nitrogen atmosphere afforded the rare fullerooxazoles, which would be difficult to prepare by other methods. A possible reaction mechanism for the formation of the fullerooxazoles was proposed.
Li
Fa-Bao
FB
Hefei National Laboratory for Physical Sciences at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China.
Liu
Tong-Xin
TX
Wang
Guan-Wu
GW