Extreme rate acceleration by axial thiolate coordination on the isomerization of endoperoxide catalyzed by iron porphyrin.
Yamane
Takehiro
T
Graduate School of Pharmaceutical Sciences, Nagoya City University, 3-1 Tanabe-dori, Mizuho-ku, Nagoya 467-8603, Japan.
Makino
Kohei
K
Umezawa
Naoki
N
Kato
Nobuki
N
Higuchi
Tsunehiko
T
D002384:Catalysis; D003577:Cytochrome P-450 Enzyme System / Q000737:chemistry; D006427:Hemin / Q000031:analogs & derivatives* / Q000737:chemistry; D007536:Isomerism; D044262:Prostaglandin H2 / Q000096:biosynthesis / Q000737:chemistry*
C032548:hemin dimethyl ester; D044262:Prostaglandin H2; D006427:Hemin; D003577:Cytochrome P-450 Enzyme System