Hetero-arylboroxines: the first rational synthesis, X-ray crystallographic and computational analysis.
A novel series of hetero-arylboroxines were synthesized and structurally characterized by X-ray diffraction, NMR and computational analysis. The solid-state structures of the hetero-arylboroxines represent the first report of AB(2)-type hetero-arylboroxines.
Iovine
Peter M
PM
Department of Chemistry and Biochemistry, University of San Diego, 5998 Alcala Park, San Diego, CA 92110, USA. piovine@sandiego.edu
Gyselbrecht
Charles R
CR
Perttu
Emily K
EK
Klick
Cole
C
Neuwelt
Alexander
A
Loera
Jason
J
DiPasquale
Antonio G
AG
Rheingold
Arnold L
AL
Kua
Jeremy
J
D000465:Algorithms; D000812:Anhydrides / Q000138:chemical synthesis*; D001897:Boronic Acids / Q000138:chemical synthesis*; D006844:Hydrocarbons, Cyclic / Q000138:chemical synthesis*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D008956:Models, Chemical; D014961:X-Ray Diffraction / Q000379:methods*
D000812:Anhydrides; D001897:Boronic Acids; D006844:Hydrocarbons, Cyclic