The green approaches for the synthesis of N-dehydroabietic alpha-aminophosphonates.
Three kinds of O,O-diethyl N-dehydroabietic aminoarylmethylphosphonates were synthesized from natural product derivatives by two steps of solvent-free reactions through imines intermediates and their structures were characterized by IR, (1)H NMR and (31)P NMR spectroscopy. The solvent-free reactions afforded good yields of N-dehydroabietic imines and alpha-aminophosphonates although the strong space block of dehydroabietylamine to amino group. The green approaches resulted negligible waste and the reactions were environment friendly without using noxious solvents.
Rao
Xiaoping
X
Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing 210042, China.
Song
Zhanqian
Z
Yao
Xujie
X
Gao
Hong
H
Ye
Baihui
B
D045784:Abietanes / Q000737:chemistry; D007097:Imines / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D063065:Organophosphonates / Q000138:chemical synthesis* / Q000737:chemistry*
D045784:Abietanes; D007097:Imines; D063065:Organophosphonates; C013913:dehydroabietic acid