Concurrent anion...pi interactions between a perchlorate ion and two pi-acidic aromatic rings, namely pentafluorophenol and 1,3,5-triazine.
The rational design of a ligand containing two electron-poor pi-rings, i.e. a triazine and a pentafluorophenoxy groups, has allowed the preparation of a copper complex where both the anticipated anion...pi interactions are present.
Götz
Rens J
RJ
Leiden Institute of Chemistry, PO Box 9502, RA Leiden, The Netherlands.
Robertazzi
Arturo
A
Mutikainen
Ilpo
I
Turpeinen
Urho
U
Gamez
Patrick
P
Reedijk
Jan
J
D003300:Copper / Q000737:chemistry*; D005464:Fluorobenzenes / Q000737:chemistry*; D010472:Perchlorates / Q000737:chemistry*; D010636:Phenols / Q000737:chemistry*; D014227:Triazines / Q000737:chemistry*; D014961:X-Ray Diffraction; D005466:Fluorocarbons
D003300:Copper; D005464:Fluorobenzenes; D010472:Perchlorates; D010636:Phenols; D014227:Triazines; C085539:2,3,4,5,6-pentafluorophenol; D005466:Fluorocarbons; C494474:perchlorate