Ortho-lithiation of free ferrocenyl alcohols: a new method for the synthesis of planar chiral ferrocene derivatives.
An ortho-metalation method for free ferrocenyl alcohols has been developed, which allows preparation of planar chiral ferrocene derivatives with high yields and diastereoselectivities.
Ueberbacher
Bernhard J
BJ
Institute of Organic Chemistry, Graz University of Technology, Stremayrgasse 16, 8010 Graz, Austria. Bernhard.ueberbacher@tugraz.at
Griengl
Herfried
H
Weber
Hansjörg
H
D000438:Alcohols / Q000138:chemical synthesis*; D005296:Ferrous Compounds / Q000138:chemical synthesis*; D008094:Lithium / Q000737:chemistry*; D000075163:Metallocenes; D009942:Organometallic Compounds / Q000737:chemistry; D013237:Stereoisomerism
D000438:Alcohols; D005296:Ferrous Compounds; D000075163:Metallocenes; D009942:Organometallic Compounds; C046771:butyllithium; D008094:Lithium; C004998:ferrocene