title: Extreme rate acceleration by axial thiolate coordination on the isomerization of endoperoxide catalyzed by iron porphyrin.
authors.affiliation: Graduate School of Pharmaceutical Sciences, Nagoya City University, 3-1 Tanabe-dori, Mizuho-ku, Nagoya 467-8603, Japan.
authors.forename: Takehiro
authors.initials: T
authors.lastname: Yamane
authors.forename: Kohei
authors.initials: K
authors.lastname: Makino
authors.forename: Naoki
authors.initials: N
authors.lastname: Umezawa
authors.forename: Nobuki
authors.initials: N
authors.lastname: Kato
authors.forename: Tsunehiko
authors.initials: T
authors.lastname: Higuchi
mesh_terms: D002384:Catalysis; D003577:Cytochrome P-450 Enzyme System / Q000737:chemistry; D006427:Hemin / Q000031:analogs & derivatives* / Q000737:chemistry; D007536:Isomerism; D044262:Prostaglandin H2 / Q000096:biosynthesis / Q000737:chemistry*
chemical_list: C032548:hemin dimethyl ester; D044262:Prostaglandin H2; D006427:Hemin; D003577:Cytochrome P-450 Enzyme System