Ruthenium-catalyzed hydroarylations of methylenecyclopropanes: mild C-H bond functionalizations with conservation of cyclopropane rings.
Ring conservation was observed in the first catalytic intermolecular hydroarylation of methylenecyclopropanes via C-H bond functionalization, a remarkable reactivity mode for a transformation proceeding through (cyclopropylcarbinyl)metal intermediates.
Kozhushkov
Sergei I
SI
Institut für Organische and Biomolekulare Chemie der Georg-August-Universität Göttingen, Tammannstrasse 2, 37077 Göttingen, Germany.
Yufit
Dmitry S
DS
Ackermann
Lutz
L
D002384:Catalysis; D018360:Crystallography, X-Ray; D003521:Cyclopropanes / Q000138:chemical synthesis / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D013237:Stereoisomerism
D003521:Cyclopropanes; D008024:Ligands; D009942:Organometallic Compounds; C508672:methylenecyclopropane; D012428:Ruthenium