Synthesis, electronic properties, and X-ray structural characterization of tetrarylbenzo[1,2-b:4,5-b']difuran cation radicals.
Electroactive tetraarylbenzo[1,2- b:4,5- b']difuran (BDF) and model diarylbenzofuran derivatives are synthesized and their structures are established by X-ray crystallography. Isolation and X-ray crystallographic characterization of the robust cation-radical salts of BDF derivatives confirm that a single charge in the BDFs is stabilized largely by the benzodifuran and coplanar alpha-aryl groups lying on the longitudinal axis. These findings suggest that the linear arrays of BDFs may allow the construction of molecular wires suitable for long-range electron transport.
Shukla
Ruchi
R
Department of Chemistry, Marquette University, P.O. Box 1881, Milwaukee, Wisconsin 53201, USA.
Wadumethrige
Shriya H
SH
Lindeman
Sergey V
SV
Rathore
Rajendra
R
D001572:Benzofurans / Q000138:chemical synthesis* / Q000737:chemistry*; D002412:Cations / Q000138:chemical synthesis / Q000737:chemistry; D018360:Crystallography, X-Ray; D004563:Electrochemistry; D004583:Electrons; D005609:Free Radicals / Q000138:chemical synthesis / Q000737:chemistry; D008958:Models, Molecular; D010084:Oxidation-Reduction
D001572:Benzofurans; D002412:Cations; D005609:Free Radicals