Cerium(IV)-containing oxomolybdenum cluster with a unique Ce6Mo9O38 core structure.
Interaction of [Ce(L(OEt))(2)(NO(3))(2)] (L(OEt)(-) = [Co(eta(5)-C(5)H(5)){P(O)(OEt)(2)}(3)](-)) with (NH(4))(6)[Mo(7)O(24)] in water affords the cerium(iv)-containing oxomolybdenum cluster [H(4)(CeL(OEt))(6)Mo(9)O(38)], which exhibits a unique Ce(6)Mo(9)O(38) core structure.
Yi
Xiao-Yi
XY
Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China.
Y Sung
Herman H
HH
Williams
Ian D
ID
Leung
Wa-Hung
WH