title: Asymmetric multifunctional organocatalytic Michael addition of nitroalkanes to alpha,beta-unsaturated ketones.
abstract: Cinchona alkaloid derived primary amine thioureas organocatalyzed Michael addition of nitroalkanes to enones in good yield and up to 98% ee and offered a new way to construct quaternary stereocenters from enones and nitroalkanes.
authors.affiliation: Dalian Institute of Chemical Physics, Graduate School of the Chinese Academy of Sciences, Chinese Academy of Science, 457 Zhongshan Road, Dalian, 116023, China.
authors.forename: Pengfei
authors.initials: P
authors.lastname: Li
authors.forename: Yongcan
authors.initials: Y
authors.lastname: Wang
authors.forename: Xinmiao
authors.initials: X
authors.lastname: Liang
authors.forename: Jinxing
authors.initials: J
authors.lastname: Ye
mesh_terms: D000473:Alkanes / Q000737:chemistry*; D002384:Catalysis; D002930:Cinchona Alkaloids / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D009574:Nitro Compounds / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000473:Alkanes; D002930:Cinchona Alkaloids; D007659:Ketones; D009574:Nitro Compounds