title: PARAFAC analysis of the quenching of EEM of fluorescence of glutathione capped CdTe quantum dots by Pb(II).
abstract: Glutathione capped CdTe quantum dots (QD) were synthesised using a simple experimental procedure and two samples were subjected of study (QD550 and QD600). The maximum of the excitation and emission spectra and the emission full width of half maximum of these two QD were: QD550, 307, 550 and 37 nm; QD600, 307, 600 and 39 nm. The steady state fluorescence properties of the two QD undergo variation when the pH of the aqueous solution is varied and are characterised by different apparent pKa: QD550, 5.2+/-0.1; QD600, 6.3+/-0.3. The fluorescence intensity of the QD550 is markedly quenched by the presence of micromolar quantities of Pb(II) ion (Stern-Volmer constant of about 7x10(5) M(-1)). PARAFAC analysis of the excitation emission matrices (EEM) of QD550 acquired as function of the Pb(II) ion showed that only one linearly independent component describes the quenching of the QD550 by the Pb(II) ion allowing robust estimation of the excitation and emission spectra and of the quenching profiles.
authors.affiliation: Centro de Investigação em Química, Departamento de Química, Faculdade de Ciências da Universidade do Porto, Rua Campo Alegre 687, 4169-007, Porto, Portugal.
authors.forename: Helena
authors.initials: H
authors.lastname: Gonçalves
authors.forename: Conceição
authors.initials: C
authors.lastname: Mendonça
authors.forename: Joaquim C G
authors.initials: JC
authors.lastname: Esteves da Silva
mesh_terms: D019187:Cadmium Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D005163:Factor Analysis, Statistical; D005453:Fluorescence; D005978:Glutathione / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007854:Lead / Q000032:analysis*; D008163:Luminescent Measurements / Q000295:instrumentation / Q000379:methods; D010316:Particle Size; D045663:Quantum Dots; D012680:Sensitivity and Specificity; D013050:Spectrometry, Fluorescence / Q000295:instrumentation / Q000379:methods; D013499:Surface Properties; D013691:Tellurium / Q000737:chemistry*; D013997:Time Factors
chemical_list: D019187:Cadmium Compounds; D007854:Lead; D005978:Glutathione; D013691:Tellurium; C028337:cadmium telluride