Carbon-fluorine reductive elimination from a high-valent palladium fluoride.
We have observed two high-valent arylpalladiumfluoride complexes that afford carbon-fluorine bond formation upon thermolysis.
Furuya
Takeru
T
Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts, USA.
Ritter
Tobias
T
D002244:Carbon; D002626:Chemistry, Pharmaceutical / Q000379:methods; D005459:Fluorides / Q000737:chemistry*; D005461:Fluorine; D054879:Halogenation; D006841:Hydrocarbons, Aromatic; D010165:Palladium / Q000737:chemistry*
D006841:Hydrocarbons, Aromatic; D005461:Fluorine; D010165:Palladium; D002244:Carbon; D005459:Fluorides