Synthesis, spectroscopic characterization and magnetic properties of homo- and heterodinuclear complexes of transition and non-transition metal ions with a new Schiff base ligand.
Four homodinuclear complexes of Ni(II)-Ni(II), Cu(II)-Cu(II), Co(II)-Co(II) and Co(III)-Co(II) and five heterodinuclear complexes of Co(III)-Zn(II), Co(III)-Cu(II), Co(III)-Ni(II), Cu(II)-Zn(II) and Zn(II)-Cu(II) with the octadentate Schiff base compartmental ligand 1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaoctane-1,8-diamine (H4fsatrien) have been synthesized. The complexes have been characterized with the help of elemental analyses, molecular weights, molar conductances, magnetic susceptibilities and spectroscopic (UV-vis, IR, ESR) data. Cryomagnetic data also helped to elucidate the structural features of the Cu(II) complexes.
Sarkar
Saikat
S
Department of Chemistry, Santipur College, Santipur 741404, West Bengal, India. saikat_s@rediffmail.com
Biswas
Susobhan
S
Dey
Kamalendu
K
D018360:Crystallography, X-Ray / Q000379:methods; D004578:Electron Spin Resonance Spectroscopy; D007477:Ions; D008024:Ligands; D008280:Magnetics; D008670:Metals / Q000737:chemistry*; D008956:Models, Chemical; D008968:Molecular Conformation; D008970:Molecular Weight; D012545:Schiff Bases / Q000737:chemistry*; D013053:Spectrophotometry / Q000379:methods*; D013055:Spectrophotometry, Infrared / Q000379:methods; D013056:Spectrophotometry, Ultraviolet / Q000379:methods; D028561:Transition Elements / Q000737:chemistry; D015032:Zinc / Q000737:chemistry
D007477:Ions; D008024:Ligands; D008670:Metals; D012545:Schiff Bases; D028561:Transition Elements; D015032:Zinc