The iron centre of the cluster-free hydrogenase (Hmd): low-spin Fe(II) or low-spin Fe(0)?
Infrared data for mono-iron complexes possessing two cis-CO together with Mössbauer data for the enzyme and a model complex support the assignment that the iron centre of the cluster-free hydrogenase Hmd is low-spin Fe(II).
Wang
Xiufeng
X
Department of Chemistry/Institute for Advanced Study, Nanchang University, Nanchang, 330031, China. xiaoming.liu@ncu.edu.cn.
Li
Zhimei
Z
Zeng
Xirui
X
Luo
Qiuyan
Q
Evans
David J
DJ
Pickett
Christopher J
CJ
Liu
Xiaoming
X
D003067:Coenzymes / Q000737:chemistry / Q000378:metabolism; D006864:Hydrogenase / Q000737:chemistry* / Q000378:metabolism; D007501:Iron / Q000737:chemistry*; D008024:Ligands; D010084:Oxidation-Reduction; D011725:Pyridines / Q000737:chemistry; D013055:Spectrophotometry, Infrared
D003067:Coenzymes; D008024:Ligands; D011725:Pyridines; D007501:Iron; D006864:Hydrogenase