title: The importance of solvent reorganisation in the effect of an ionic liquid on a unimolecular substitution process.
abstract: Temperature dependent rate studies demonstrate an enthalpic benefit and an entropic cost associated with the change in the rate of a unimolecular substitution process on addition of a high proportion of an ionic liquid, the latter effect being supported by molecular dynamics simulations.
authors.affiliation: School of Chemistry, University of New South Wales, Sydney, NSW, 2052, Australia.
authors.forename: Hon Man
authors.initials: HM
authors.lastname: Yau
authors.forename: Susan A
authors.initials: SA
authors.lastname: Barnes
authors.forename: James M
authors.initials: JM
authors.lastname: Hook
authors.forename: Tristan G A
authors.initials: TG
authors.lastname: Youngs
authors.forename: Anna K
authors.initials: AK
authors.lastname: Croft
authors.forename: Jason B
authors.initials: JB
authors.lastname: Harper