Application of bamboo charcoal as solid-phase extraction adsorbent for the determination of atrazine and simazine in environmental water samples by high-performance liquid chromatography-ultraviolet detector.
In this article, a new method for the determination of triazine herbicides atrazine and simazine in environment aqueous samples was developed. It was based on solid-phase extraction (SPE) using bamboo charcoal as adsorbent and high-performance liquid chromatography-ultraviolet detector (HPLC-UV) for the enrichment and determination of atrazine and simazine at trace level. Related important factors influencing the extraction efficiency, such as the kind of eluent and its volume, flow rate of the sample, pH of the sample, and volume of the sample, were investigated and optimized in detail. Under the optimal conditions, the experimental results showed that excellent linearity was obtained over the range of 0.5-30 microg L(-1) with correlation coefficients 0.9991 and 0.9982, for atrazine and simazine, respectively; and the relative standard deviations of two analytes were 8.3, 8.7%, respectively. The proposed method was successfully applied to the analysis of tap water and well water samples. And satisfactory spiked recoveries were obtained in the range of 75.2-107.1%. The above results indicated that the developed method was an excellent alternative for the routine analysis in environmental field.
Zhao
Ru-Song
RS
Key laboratory for Applied Technology of Sophisticated Analytical Instruments of Shandong province, Analysis and Test Center, Shandong Academy of Sciences, Jinan, Shandong 250014, China. zhaors1976@126.com
Yuan
Jin-Peng
JP
Jiang
Ting
T
Shi
Jun-Bo
JB
Cheng
Chuan-Ge
CG
D000327:Adsorption; D001280:Atrazine / Q000032:analysis*; D002606:Charcoal; D002851:Chromatography, High Pressure Liquid / Q000379:methods*; D006540:Herbicides / Q000032:analysis; D006863:Hydrogen-Ion Concentration; D031787:Sasa; D012839:Simazine / Q000032:analysis*; D052616:Solid Phase Extraction / Q000379:methods*; D013056:Spectrophotometry, Ultraviolet / Q000379:methods*; D014466:Ultraviolet Rays; D014867:Water / Q000032:analysis* / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000032:analysis
D006540:Herbicides; D014874:Water Pollutants, Chemical; D014867:Water; D002606:Charcoal; D001280:Atrazine; D012839:Simazine