title: Automated synthesis of lipomannan backbone alpha(1-6) oligomannoside via glycosyl phosphates: glycosyl tricyclic orthoesters revisited.
abstract: Glycosyl tricyclic orthoesters provide a versatile basis for the efficient generation of glycosyl phosphates, which are used in the automated synthesis of lipomannan backbone alpha(1-6) hexa-mannoside.
authors.affiliation: Laboratory for Organic Chemistry, Swiss Federal Institute of Technology, ETH Zürich, HCI F315, Wolfgang-Pauli Strasse 10, Zürich 8093, Switzerland.
authors.forename: Xinyu
authors.initials: X
authors.lastname: Liu
authors.forename: Reiko
authors.initials: R
authors.lastname: Wada
authors.forename: Siwarutt
authors.initials: S
authors.lastname: Boonyarattanakalin
authors.forename: Bastien
authors.initials: B
authors.lastname: Castagner
authors.forename: Peter H
authors.initials: PH
authors.lastname: Seeberger
mesh_terms: D000438:Alcohols / Q000737:chemistry*; D001331:Automation; D002851:Chromatography, High Pressure Liquid; D005947:Glucose / Q000737:chemistry*; D008070:Lipopolysaccharides / Q000737:chemistry*; D008362:Mannosides / Q000138:chemical synthesis; D009844:Oligosaccharides / Q000138:chemical synthesis* / Q000737:chemistry; D010710:Phosphates / Q000737:chemistry*
chemical_list: D000438:Alcohols; D008070:Lipopolysaccharides; D008362:Mannosides; D009844:Oligosaccharides; D010710:Phosphates; C059688:alkoxyl radical; C064351:lipomannan; C028569:oligomannoside; D005947:Glucose