PtCl2-catalyzed tandem triple migration reaction toward (Z)-1,5-dien-2-yl esters.
A novel method for the selective synthesis of (Z)-1,5-dien-2-yl esters has been developed though Pt(II)-catalyzed tandem 1,2-acyl and 1,2-hydride migration, along with an allyl migration reaction of propargylic carboxylates with electronically unbiased internal alkynes. The unusual selectivity of 1,2-acyloxy migration was realized.
Ji
Ke-Gong
KG
State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, PR China.
Shu
Xing-Zhong
XZ
Chen
Jin
J
Zhao
Shu-Chun
SC
Zheng
Zhao-Jing
ZJ
Lu
Li
L
Liu
Xue-Yuan
XY
Liang
Yong-Min
YM