Radical, one-step approach to o-chlorophenyl thioethers from xanthates. A rapid access to vinylsilanes.
Xanthates have been readily converted into o-chlorophenyl thioethers using a one-step procedure conducted under radical conditions. In some selected cases, these aryl thioethers were successfully oxidized to the corresponding sulfoxides and sulfenic acid elimination afforded the corresponding vinylsilanes.
Corbet
Matthieu
M
Laboratoire de Synthèse Organique, CNRS UMR 7652, Département de Chimie, Ecole Polytechnique, 91128 Palaiseau, France.
Ferjancić
Zorana
Z
Quiclet-Sire
Béatrice
B
Zard
Samir Z
SZ
D015394:Molecular Structure; D012821:Silanes / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism; D013440:Sulfides / Q000138:chemical synthesis* / Q000737:chemistry; D013457:Sulfur Compounds / Q000737:chemistry*; D013871:Thiones / Q000737:chemistry*; D014753:Vinyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry
D012821:Silanes; D013440:Sulfides; D013457:Sulfur Compounds; D013871:Thiones; D014753:Vinyl Compounds; C476909:vinylsilane