Highly electron-donating 3,3'-diaryl-1,1'-bi(isobenzofuran)s synthesized by photochemical exocyclic [2 + 2 + 2] cycloaddition.
Facile photochemical exocyclic [2 + 2 + 2] cycloaddition produced a series of electron-donating 1,1'-bi(isobenzofuran)s having various aryl groups at the 3,3' positions. The 1,1'-bi(isobenzofuran) skeleton with a highly coplanar structure is a useful building unit to construct the narrow bandgap pi-conjugated systems with low oxidation potentials.
Zhang
Hongyu
H
Department of Chemistry, Graduate School of Science, Nagoya University, Furo, Chikusa, Nagoya 464-8602, Japan.
Wakamiya
Atsushi
A
Yamaguchi
Shigehiro
S
D001572:Benzofurans / Q000138:chemical synthesis* / Q000737:chemistry; D018360:Crystallography, X-Ray; D003500:Cyclization; D004583:Electrons; D008956:Models, Chemical; D008958:Models, Molecular; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010777:Photochemistry; D013237:Stereoisomerism
D001572:Benzofurans