Use of enantiomerically pure 7-azabicyclo[2.2.1]heptan-2-ol as a chiral template for the synthesis of aminocyclitols.
Using enantiopure 7-azabicyclo[2.2.1]heptane-2-ol, the synthesis of cis- as well as trans-2-aminocyclohexanols, dihydroconduramine E-1, and ent-conduramine F-1 has been described.
Pandey
Ganesh
G
Division of Organic Chemistry and Centre for Material Characterization, National Chemical Laboratory, Pune 411008, India. gp.pandey@ncl.res.in
Tiwari
Keshri Nath
KN
Puranik
V G
VG
D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry; D053961:Azabicyclo Compounds / Q000737:chemistry*; D018360:Crystallography, X-Ray; D054812:Cyclitols / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D008968:Molecular Conformation; D013237:Stereoisomerism
D000588:Amines; D053961:Azabicyclo Compounds; D054812:Cyclitols