Microwave synthesis of electrically conductive gold nanowires on DNA scaffolds.
Biological molecules, in particular DNA, have shown great potential to be used as interconnects of nanodevices and computational elements. In this research, we synthesized electrically conductive gold nanowires for the first time exploiting an electroless and microwave heating method for 120-180 s. Our results indicate that DNA serves as a reducing and nonspecific capping agent for the growth of nanowires. The current voltage ( I- V) characteristics of the Au nanowires are continuous, exhibiting Ohmic behavior having low contact resistance with the gold electrodes. The nanowires have a diameter of 10-15 nm in solution and of 20-30 nm in immobilized DNA with resistivity comparable to pure metals. The method is highly selective with deposition confined to the DNA itself. The nanowires we fabricated can be used as building blocks for functional nanodevices, sensors, and optoelectronics.
Kundu
Subrata
S
Materials Science and Mechanical Engineering, Texas A&M University, College Station, Texas 77843-3123, USA. skundu@tamu.edu
Liang
Hong
H
D004247:DNA / Q000737:chemistry*; D004553:Electric Conductivity; D004560:Electricity; D004563:Electrochemistry / Q000379:methods; D006046:Gold / Q000737:chemistry*; D053768:Metal Nanoparticles / Q000737:chemistry*; D046529:Microscopy, Electron, Transmission / Q000379:methods; D008872:Microwaves; D049329:Nanostructures; D036103:Nanotechnology / Q000379:methods*; D053770:Nanowires / Q000737:chemistry; D012984:Software; D013056:Spectrophotometry, Ultraviolet / Q000379:methods; D014466:Ultraviolet Rays; D014961:X-Ray Diffraction
D006046:Gold; D004247:DNA