title: Asymmetric synthesis of 4- and 5-substituted pipecolic esters by ring-closing metathesis and palladium-catalyzed formate reduction.
abstract: Asymmetric synthesis of 4- and 5-substituted pipecolic esters was achieved by the sequence of allylation, ring-closing metathesis, and palladium-catalyzed formate reduction.
authors.affiliation: Department of Chemistry, National Central University, 300 Jhong-Da Rd. Jhong-Li, Taoyuan, Taiwan.
authors.forename: Chong-Si
authors.initials: CS
authors.lastname: Sun
authors.forename: Yu-Shiang
authors.initials: YS
authors.lastname: Lin
authors.forename: Duen-Ren
authors.initials: DR
authors.lastname: Hou
mesh_terms: D000498:Allyl Compounds / Q000737:chemistry; D002384:Catalysis; D003500:Cyclization; D004952:Esters / Q000138:chemical synthesis*; D005561:Formates / Q000737:chemistry*; D008956:Models, Chemical; D010084:Oxidation-Reduction; D010165:Palladium / Q000737:chemistry*; D010875:Pipecolic Acids / Q000138:chemical synthesis*
chemical_list: D000498:Allyl Compounds; D004952:Esters; D005561:Formates; D010875:Pipecolic Acids; D010165:Palladium