The first metal-organic framework (MOF) of Imazethapyr and its SHG, piezoelectric and ferroelectric properties.
Hydrothermal reaction of H-Imazethapyr (2-(4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl)-5-ethyl-3-pyridinecarboxylic acid) with Cd(ClO4)2.6H2O offers a diamond-like MOF Cd(Imazethapyr)2 in which it crystallizes in a non-centrosymmetric space group (Fdd2) belonging to polar point group (C2v). MOF displays a strong SHG response, and good ferroelectric and piezoelectric properties.
Fu
Da-Wei
DW
Ordered Matter Science Research Center, Southeast University, Nanjing, 211189, P. R. China.
Zhang
Wen
W
Xiong
Ren-Gen
RG
D002104:Cadmium / Q000737:chemistry*; D004553:Electric Conductivity; D008958:Models, Molecular; D015394:Molecular Structure; D009539:Nicotinic Acids / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*
D009539:Nicotinic Acids; D009942:Organometallic Compounds; D002104:Cadmium; C093630:imazethapyr