Automated synthesis of lipomannan backbone alpha(1-6) oligomannoside via glycosyl phosphates: glycosyl tricyclic orthoesters revisited.
Glycosyl tricyclic orthoesters provide a versatile basis for the efficient generation of glycosyl phosphates, which are used in the automated synthesis of lipomannan backbone alpha(1-6) hexa-mannoside.
Liu
Xinyu
X
Laboratory for Organic Chemistry, Swiss Federal Institute of Technology, ETH Zürich, HCI F315, Wolfgang-Pauli Strasse 10, Zürich 8093, Switzerland.
Wada
Reiko
R
Boonyarattanakalin
Siwarutt
S
Castagner
Bastien
B
Seeberger
Peter H
PH
D000438:Alcohols / Q000737:chemistry*; D001331:Automation; D002851:Chromatography, High Pressure Liquid; D005947:Glucose / Q000737:chemistry*; D008070:Lipopolysaccharides / Q000737:chemistry*; D008362:Mannosides / Q000138:chemical synthesis; D009844:Oligosaccharides / Q000138:chemical synthesis* / Q000737:chemistry; D010710:Phosphates / Q000737:chemistry*
D000438:Alcohols; D008070:Lipopolysaccharides; D008362:Mannosides; D009844:Oligosaccharides; D010710:Phosphates; C059688:alkoxyl radical; C064351:lipomannan; C028569:oligomannoside; D005947:Glucose