CO2 coordination by inorganic polyoxoanion in water.
Two inorganic polyoxoanions react with carbon dioxide in aqueous solution to yield two polymeric chainlike complexes, where an activated CO2 molecule covalently bonds to polyoxoanions in a linear mu-eta1,eta1-OCO style. For the first time, the CO2 coordination is realized by an economic and environmentally friendly approach.
Gao
Guanggang
G
Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, PR China.
Li
Fengyan
F
Xu
Lin
L
Liu
Xizheng
X
Yang
Yanyan
Y