Fate and degradation of triasulfuron in soil and water under laboratory conditions.
The behavior and fate of triasulfuron (TRS) in water and soil systems were examined in laboratory studies. The degradation of TRS in both buffer solution and soil was highly pH-sensitive. The rate of degradation could be described with a pseudo first-order kinetic and was much faster at pH 4 than at pH 7 and 9. Aqueous hydrolysis occurred by cleavage of the sulfonylurea bridge to form 2-(2-chloroethoxy) benzenesulfonamide (CBSA) and [(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino] (AMMT). AMMT was unstable in aqueous solutions in any pH condition but it degraded more quickly at pH 4 and 9. CBSA did not degrade in aqueous solutions or in enriched cultures but it underwent a quick degradation in the soil. The rates of TRS degradation in sterile and non-sterile soils were similar, suggesting that microorganisms played a minimal role in the breakdown process. This hypothesis is supported by the results of studies on the degradation of TRS by enriched cultures during which the molecule underwent a prevalently chemical degradation.
Gennari
Mara
M
Universita degli Studi di Catania, Dipartimento di Scienze Agronomiche, Catania, Italy. mara.gennari@unito.it
Abbate
Cristina
C
Baglieri
Andrea
A
Negre
Michele
M
D000327:Adsorption; D001673:Biodegradation, Environmental; D006540:Herbicides / Q000032:analysis* / Q000378:metabolism; D006863:Hydrogen-Ion Concentration; D006868:Hydrolysis; D007700:Kinetics; D013058:Mass Spectrometry; D012989:Soil Pollutants / Q000032:analysis* / Q000378:metabolism; D013453:Sulfonylurea Compounds / Q000032:analysis* / Q000378:metabolism; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000378:metabolism; D000096926:Benzenesulfonamides
D006540:Herbicides; D012989:Soil Pollutants; D013453:Sulfonylurea Compounds; D014874:Water Pollutants, Chemical; C094039:triasulfuron; D000096926:Benzenesulfonamides