Synthesis and structure of a ferrocenylboron dication.
Treatment of the borane Br 2BFc (Fc = ferrocenyl) with the Lewis base 4-methylpyridine and Na[BAr (f) 4] [Ar (f) = 3,5-(CF 3) 2C 6H 3] afforded the boron dication [FcB(NC 5H 4-4-Me) 3][BAr (f) 4] 2. This compound is a rare example of a structurally characterized boron dication.
Braunschweig
Holger
H
Institut für Anorganische Chemie and Institut für Organische Chemie, Julius-Maximilians Universität Würzburg, 97074 Würzburg, Germany. h.braunschweig@mail.uni-wuerzburg.de
Kaupp
Martin
M
Lambert
Christoph
C
Nowak
Dörte
D
Radacki
Krzysztof
K
Schinzel
Sandra
S
Uttinger
Katharina
K