title: Photodegradation of the acaricide abamectin: a kinetic study.
abstract: The acaricide abamectin is a mixture of two colorless homologues in a molar ratio of at least 4:1 with the same structure of macrocyclic lactone. The kinetics of its degradation under direct (254 nm) and dye-sensitized (>400 nm) photoirradiation in methanol solution has been studied by UV-vis spectrophotometry, potentiometric detection of dissolved oxygen, stationary fluorescence, laser flash photolysis, and time-resolved detection of singlet molecular oxygen (O2((1)Delta(g))) phosphorescence. The results indicate that the degradation is very efficient under direct irradiation with UV light (254 nm), with a quantum yield of 0.23. On the contrary, under visible-light irradiation, using the natural pigment riboflavin or the synthetic dye rose bengal as sensitizers, the degradation is very inefficient and proceeds through a O2((1)Delta(g))-mediated mechanism, with a bimolecular rate constant for the overall O2((1)Delta(g)) quenching (the sum of physical and chemical quenching) of 5.5 x 10(5) M(-1) s(-1). This value is similar to those reported for the rate constants of the reactions of O2((1)Delta(g)) with isolated double bonds or conjugated dienes and points to similar processes in the case of abamectin.
authors.affiliation: Unidad Académica Río Gallegos, Universidad Nacional de la Patagonia Austral, 9400 Río Gallegos, Argentina.
authors.forename: Juan Pablo
authors.initials: JP
authors.lastname: Escalada
authors.forename: José
authors.initials: J
authors.lastname: Gianotti
authors.forename: Adriana
authors.initials: A
authors.lastname: Pajares
authors.forename: Walter A
authors.initials: WA
authors.lastname: Massad
authors.forename: Francisco
authors.initials: F
authors.lastname: Amat-Guerri
authors.forename: Norman A
authors.initials: NA
authors.lastname: García
mesh_terms: D000871:Anthelmintics / Q000737:chemistry*; D007559:Ivermectin / Q000031:analogs & derivatives* / Q000737:chemistry; D007700:Kinetics; D008027:Light; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry; D010777:Photochemistry; D010782:Photolysis; D012395:Rose Bengal; D013056:Spectrophotometry, Ultraviolet; D014466:Ultraviolet Rays
chemical_list: D000871:Anthelmintics; D012395:Rose Bengal; C048324:abamectin; D007559:Ivermectin; D010100:Oxygen