title: Radical, one-step approach to o-chlorophenyl thioethers from xanthates. A rapid access to vinylsilanes.
abstract: Xanthates have been readily converted into o-chlorophenyl thioethers using a one-step procedure conducted under radical conditions. In some selected cases, these aryl thioethers were successfully oxidized to the corresponding sulfoxides and sulfenic acid elimination afforded the corresponding vinylsilanes.
authors.affiliation: Laboratoire de Synthèse Organique, CNRS UMR 7652, Département de Chimie, Ecole Polytechnique, 91128 Palaiseau, France.
authors.forename: Matthieu
authors.initials: M
authors.lastname: Corbet
authors.forename: Zorana
authors.initials: Z
authors.lastname: Ferjancić
authors.forename: Béatrice
authors.initials: B
authors.lastname: Quiclet-Sire
authors.forename: Samir Z
authors.initials: SZ
authors.lastname: Zard
mesh_terms: D015394:Molecular Structure; D012821:Silanes / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism; D013440:Sulfides / Q000138:chemical synthesis* / Q000737:chemistry; D013457:Sulfur Compounds / Q000737:chemistry*; D013871:Thiones / Q000737:chemistry*; D014753:Vinyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D012821:Silanes; D013440:Sulfides; D013457:Sulfur Compounds; D013871:Thiones; D014753:Vinyl Compounds; C476909:vinylsilane