title: New cut angle quartz crystal microbalance with low frequency-temperature coefficients in an aqueous phase.
abstract: In a traditional quartz crystal microbalance (QCM), an AT-cut (cut angle phi=35.25 degrees in yxl orientation) quartz wafer is employed because it has low frequency-temperature coefficients (dF/dT) at room temperature region. But when a QCM is in contact with a liquid phase, its frequency is also related to the properties of the liquid, which are temperature dependent. The value of dF/dT is about 20 Hz/ degrees C for a 9 MHz AT-cut QCM with one side facing water. In this work, a group of QCMs in new cut angles were prepared. The influence of the cut angle on the frequency-temperature characteristic, response sensitivities to surface mass loading and viscodensity of liquid were investigated. An intrinsically temperature-compensated QCM sensor that possesses low dF/dT values in aqueous solution was reported. When a 9 MHz QCM with phi=35.65 degrees was contacted with water with one side, its dF/dT value is close to zero at ca. 25 degrees C and its averaged value of |dF/dT| is only 0.6 Hz/ degrees C in the temperature range of 23-27 degrees C. The frequency responses to surface mass loading and viscodensity of liquid phase are very close among the QCMs with the cut angles in the range of 35.15-35.7 degrees . The intrinsically temperature-compensated QCM was applied to investigate the alternate adsorption processes of cationic polyelectrolyte and silica nanoparticle.
authors.affiliation: The Key Lab in Molecular and Nano Probes of the Ministry of Education of China, Shandong Normal University, Jinan, 250014, PR China. dzshen@sdnu.edu.cn
authors.forename: Dazhong
authors.initials: D
authors.lastname: Shen
authors.forename: Qi
authors.initials: Q
authors.lastname: Kang
authors.forename: Yu-E
authors.initials: YE
authors.lastname: Wang
authors.forename: Qiang
authors.initials: Q
authors.lastname: Hu
authors.forename: Junguo
authors.initials: J
authors.lastname: Du