title: CAN-mediated highly regio- and stereoselective oxidation of vinylidenecyclopropanes: a novel method for the synthesis of unsymmetrical divinyl ketone and functional enone derivatives.
abstract: CAN-mediated oxidative rearrangement of various vinylidenecyclopropanes under mild conditions generates unsymmetrical divinyl ketone and functional enone derivatives in moderate to good yields with excellent regio- and stereoselectivities. The reaction mechanism was investigated on the basis of an oxygen-18 tracer experiment.
authors.affiliation: Department of Chemistry, Zhejiang University (Xixi Campus), Hangzhou 310028, People's Republic of China.
authors.forename: Chenliang
authors.initials: C
authors.lastname: Su
authors.forename: Xian
authors.initials: X
authors.lastname: Huang
authors.forename: Qingyang
authors.initials: Q
authors.lastname: Liu