Cyclic single-molecule magnet in heterospin system.
The 2:2 complex of Co-carbene is generated by photolysis of [Co(hfpip)2(D2py2(TBA))]2, 1, having a cyclic structure functioning as a single-molecule magnet with Ueff = 96 K and Hc = 10 kOe at 1.9 K after annealing at 70 K.
Yoshihara
Daisuke
D
Graduate School of Pharmaceutical Sciences, Kyushu University, 3-1-1 Maidashi, Higashi-ku, Fukuoka, 812-8582 Japan.
Karasawa
Satoru
S
Koga
Noboru
N
D001391:Azo Compounds / Q000737:chemistry; D003461:Crystallography; D008280:Magnetics; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry
D001391:Azo Compounds; D009942:Organometallic Compounds; D011725:Pyridines