title: PtCl2-catalyzed tandem triple migration reaction toward (Z)-1,5-dien-2-yl esters.
abstract: A novel method for the selective synthesis of (Z)-1,5-dien-2-yl esters has been developed though Pt(II)-catalyzed tandem 1,2-acyl and 1,2-hydride migration, along with an allyl migration reaction of propargylic carboxylates with electronically unbiased internal alkynes. The unusual selectivity of 1,2-acyloxy migration was realized.
authors.affiliation: State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, PR China.
authors.forename: Ke-Gong
authors.initials: KG
authors.lastname: Ji
authors.forename: Xing-Zhong
authors.initials: XZ
authors.lastname: Shu
authors.forename: Jin
authors.initials: J
authors.lastname: Chen
authors.forename: Shu-Chun
authors.initials: SC
authors.lastname: Zhao
authors.forename: Zhao-Jing
authors.initials: ZJ
authors.lastname: Zheng
authors.forename: Li
authors.initials: L
authors.lastname: Lu
authors.forename: Xue-Yuan
authors.initials: XY
authors.lastname: Liu
authors.forename: Yong-Min
authors.initials: YM
authors.lastname: Liang