Synthesis and characterization of highly functionalized symmetric aromatic hexa-ol intermediates from oleic acid.
A novel highly functionalized aromatic hexa-ol was synthesized by palladium-catalyzed cyclotrimerization of an alkyne fatty acid ester followed by LAH reduction. This polyol product is a novel monomer made from a renewable lipid raw material for the production of polyurethanes, polyesters and polyamides.
Song
Dong
D
Alberta Lipid Utilization Program, Department of Agricultural Food and Nutritional Science, 4-10 Agriculture/Forestry Centre, University of Alberta, Edmonton, Alberta T6G 2P5, Canada.
Narine
Suresh S
SS
D000480:Alkynes / Q000737:chemistry; D002384:Catalysis; D002627:Chemistry, Physical / Q000379:methods; D003998:Dicarboxylic Acids / Q000737:chemistry; D004952:Esters / Q000737:chemistry; D005231:Fatty Acids, Unsaturated / Q000737:chemistry; D008055:Lipids / Q000737:chemistry; D008956:Models, Chemical; D009757:Nylons / Q000737:chemistry*; D019301:Oleic Acid / Q000737:chemistry*; D011091:Polyesters / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D011140:Polyurethanes / Q000737:chemistry*
D000480:Alkynes; D003998:Dicarboxylic Acids; D004952:Esters; D005231:Fatty Acids, Unsaturated; D008055:Lipids; D009757:Nylons; D011091:Polyesters; D011108:Polymers; D011140:Polyurethanes; C024617:polyol; D019301:Oleic Acid