Reductive elimination of C6F5-C6F5 in the reaction of bis(pentafluorophenyl)palladium(II) complexes with protic acids.
Reductive elimination of C6F5-C6F5 from cis-[Pd(C6F5)2L] (L = cod, bpy, and dppb) was promoted by Brønsted acids. HNO3 is a convenient acid for the formation of C6F5-C6F5 from [Pd(C6F5)2(cod)]. The products are controlled by the auxiliary ligand.
Koizumi
Take-aki
TA
Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Yokohama 226-8503, Japan.
Yamazaki
Atsuko
A
Yamamoto
Takakazu
T