title: Electrodeposited polyaniline as a fiber coating for solid-phase microextraction of organochlorine pesticides from water.
abstract: The study on the performance of polyaniline as a fiber coating for solid-phase microextraction (SPME) purposes has been reported. Polyaniline coatings were directly electrodeposited on the surface of a stainless steel wire and applied for the extraction of some organochlorine pesticides (OCPs) from water samples. Analyses were performed using GC-electron capture detection (GC-ECD). The results obtained show that polyaniline fiber coating is suitable for the successful extraction of organochlorine compounds. This behavior is most probably due to the porous surface structure of polyaniline film, which provides large surface areas and allowed for high extraction efficiency. Experimental parameters such as adsorption and desorption conditions were studied and optimized. The optimized method has an acceptable linearity, with a concentration range of 1-5000 ng/L. Single fiber repeatability and fiber-to-fiber reproducibility were less than 12 and 17%, respectively. High environmental resistance and lower cost are among the advantages of polyaniline fibers over commercially available SPME fibers. The developed method was applied to the analysis of real water samples from Yangtse River and Tianmu Lake.
authors.affiliation: Department of Environmental Science and Engineering, Fudan University, Shanghai, China. lixiang@fudan.edu.cn
authors.forename: Xiang
authors.initials: X
authors.lastname: Li
authors.forename: Ming
authors.initials: M
authors.lastname: Zhong
authors.forename: Jianmin
authors.initials: J
authors.lastname: Chen
mesh_terms: D000814:Aniline Compounds / Q000737:chemistry*; D004563:Electrochemistry; D004595:Electroplating / Q000295:instrumentation / Q000379:methods*; D006843:Hydrocarbons, Chlorinated / Q000032:analysis*; D010575:Pesticides / Q000032:analysis*; D015203:Reproducibility of Results; D052617:Solid Phase Microextraction / Q000295:instrumentation / Q000379:methods*; D013232:Steel / Q000737:chemistry; D013499:Surface Properties; D013696:Temperature; D013997:Time Factors; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D000814:Aniline Compounds; D006843:Hydrocarbons, Chlorinated; D010575:Pesticides; D014874:Water Pollutants, Chemical; C416807:polyaniline; D013232:Steel