title: Acid-base bifunctional catalytic surfaces for nucleophilic addition reactions.
abstract: This article illustrates the modification of oxide surfaces with organic amine functional groups to create acid-base bifunctional catalysts, summarizing our previous reports and also presenting new data. Immobilization of organic amines as bases on inorganic solid-acid surfaces afforded highly active acid-base bifunctional catalysts, which enabled various organic transformations including C--C coupling reactions, though these reactions did not proceed with either the homogeneous amine precursors or the acidic supports alone. Spectroscopic characterization, such as by solid-state MAS NMR and FTIR, revealed not only the interactions between acidic and basic sites but also bifunctional catalytic reaction mechanisms.
authors.affiliation: Department of Chemistry, Graduate School of Science, The University of Tokyo, Hong, Bunkyo-ku, Japan.
authors.forename: Ken
authors.initials: K
authors.lastname: Motokura
authors.forename: Mizuki
authors.initials: M
authors.lastname: Tada
authors.forename: Yasuhiro
authors.initials: Y
authors.lastname: Iwasawa