title: Effects of doping on an unusual smectic- C*alpha-smectic-C*FI2-smectic-C* phase sequence.
abstract: The compound 10OHF has a partially inverted phase sequence, unique among the series of nOHF homologous compounds and all other known liquid crystals, with the smectic-C*FI2 (SmC*FI2) phase occurring at higher temperature than the smectic-C* (SmC*) phase. We present ellipsometric data to identify the phase sequences of 9OHF, 10OHF, 11OHF, and 12OHF. Binary mixtures of 10OHF with C11, a compound with the typical phase sequence among the smectic phases, show that the unusual phase sequence of 10OHF stabilizes upon mixing and that SmC*FI2 predominates over SmC* throughout the entire mixing phase diagram. In thin films of some mixtures, surface interactions induce a reentrant SmC*FI2-SmC*-SmC*FI2 transition in the rest of the film.
authors.affiliation: School of Physics and Astronomy, University of Minnesota, Minneapolis, Minnesota 55455, USA and Department of Mathematics and Physics, Azusa Pacific University, Azusa, California 91702, USA.
authors.forename: B K
authors.initials: BK
authors.lastname: McCoy
authors.forename: Z Q
authors.initials: ZQ
authors.lastname: Liu
authors.forename: S T
authors.initials: ST
authors.lastname: Wang
authors.forename: Lidong
authors.initials: L
authors.lastname: Pan
authors.forename: Shun
authors.initials: S
authors.lastname: Wang
authors.forename: H T
authors.initials: HT
authors.lastname: Nguyen
authors.forename: R
authors.initials: R
authors.lastname: Pindak
authors.forename: C C
authors.initials: CC
authors.lastname: Huang