Ionothermal synthesis of crystalline, condensed, graphitic carbon nitride.
Herein we report the synthesis of a crystalline graphitic carbon nitride, or g-C(3)N(4), obtained from the temperature-induced condensation of dicyandiamide (NH(2)C(=NH)NHCN) by using a salt melt of lithium chloride and potassium chloride as the solvent. The proposed crystal structure of this g-C(3)N(4) species is based on sheets of hexagonally arranged s-heptazine (C(6)N(7)) units that are held together by covalent bonds between C and N atoms which are stacked in a graphitic, staggered fashion, as corroborated by powder X-ray diffractometry and high-resolution transmission electron microscopy.
Bojdys
Michael J
MJ
Max Planck Institute of Colloids and Interfaces, Research Campus Golm, Am Mühlenberg 1, 14476 Potsdam/Golm, Germany.
Müller
Jens-Oliver
JO
Antonietti
Markus
M
Thomas
Arne
A
D003460:Crystallization; D018360:Crystallography, X-Ray; D006108:Graphite / Q000737:chemistry*; D046529:Microscopy, Electron, Transmission; D008958:Models, Molecular; D015394:Molecular Structure; D009570:Nitriles / Q000737:chemistry; D009584:Nitrogen / Q000737:chemistry*; D010316:Particle Size; D011108:Polymers / Q000737:chemistry*; D033362:Powder Diffraction; D013499:Surface Properties; D013696:Temperature
D009570:Nitriles; D011108:Polymers; D006108:Graphite; D009584:Nitrogen