title: Determination of lead in wine and rum samples by flow injection-hydride generation-atomic absorption spectrometry.
abstract: A method for direct determination of lead in wine and rum samples was developed, using a flow injection hydride generation system coupled to an atomic absorption spectrometer with flame-quartz atomizer (FI-HG-AAS). Lead hyride (PbH(4)) was generated using potassium ferricyanide (K(3)Fe(CN)(6)), as oxidant and sodium tetrahydroborate (NaBH(4)) as reductant. Samples were acidified to 0.40% (v/v) HCl for wine and to 0.30% (v/v) HCl for rum, which were then mixed on-line with 3% (m/v) K(3)Fe(CN)(6) solution in 0.03% (v/v) HCl prior to reaction with 0.2% (m/v) alkaline NaBH(4) solution. Lead contents of a rum and two different red wine samples were determined by FI-HG-AAS agreed with those obtained by ICP-MS. The analytical figures of merit of method developed were determined. The calibration curve was linear up to 8.0 microg L(-1) Pb with a regression coefficient of 0.998. The relative error was lower than 4.58%. The relative standard deviation (n=7) was better than 12%. A detection limit of 0.16 microg L(-1) was achieved for a sample volume of 170 microL.
authors.affiliation: Department of Chemistry, University of Pamukkale, Denizli TR-20020, Turkey. elci@pau.edu.tr
authors.forename: Latif
authors.initials: L
authors.lastname: Elçi
authors.forename: Zikri
authors.initials: Z
authors.lastname: Arslan
authors.forename: Julian F
authors.initials: JF
authors.lastname: Tyson
mesh_terms: D000434:Alcoholic Beverages / Q000032:analysis*; D017022:Flow Injection Analysis / Q000379:methods*; D007854:Lead / Q000032:analysis*; D012680:Sensitivity and Specificity; D013054:Spectrophotometry, Atomic / Q000379:methods*; D014920:Wine / Q000032:analysis*
chemical_list: D007854:Lead