Electrochemically and photochemically active Palladium(II) heterotopic metallacalix[3]arenes.
The cyclic trinuclear system, [(en)(3)Pd(3)(4,7-phen)(3)](6+), undergoes a ligand exchange reaction with 5-R-2-hydroxypyrimidine derivatives (HRpymo; R = ethynylferrocene, 5-(dimethylamino)-N-(2-propynyl)-1-naphthalene sulfonamide) to give [(en)(3)Pd(3)(4,7-phen)(2)(Rpymo)](5+), functional supramolecular receptors of mononucleotides.
Galindo
Miguel A
MA
Departamento de Química Inorgánica y Orgánica, Universidad de Granada, Av. Fuentenueva S/N, 18071, Granada, Spain.
Houlton
Andrew
A
Clegg
William
W
Harrington
Ross W
RW
Dobado
José
J
Santoyo-Gonzalez
Francisco
F
Linares
Fatima
F
Romero
M Angustias
MA
Navarro
Jorge A R
JA