Synthesis of D-trigalacturonic acid methylglycoside and conformational comparison with its sulfur analogue.
D-Trigalacturonic acid methylglycoside (3) was synthesized to evaluate the previously synthesized sulfur analogue 1 by comparison. The NOE experiments revealed that both 3 and 1 took on a similar conformation around their glycosyl linkage.
Yamamoto
Kazunori
K
Faculty of Agriculture and Life Science, Hirosaki University, Japan.
Sato
Yu
Y
Ishimori
Ayumi
A
Miyairi
Kazuo
K
Okuno
Toshikatsu
T
Nemoto
Nobuaki
N
Shimizu
Hiroki
H
Kidokoro
Shunichi
S
Hashimoto
Masaru
M
D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D013455:Sulfur / Q000737:chemistry*; D014312:Trisaccharides / Q000138:chemical synthesis* / Q000737:chemistry
D014312:Trisaccharides; C532380:trigalacturonic acid methylglycoside; D013455:Sulfur