Acetate-driven polyoxometalate demetalation: an open-shell diiron polytungstate comprising two rotational Keggin isomers.
The effect of acetate concentration on the formation of {SiW10Fe2}-based complexes is demonstrated by the synthesis of an open-shell diiron tungstosilicate derivative featuring two rotational Keggin isomer units.
Botar
Bogdan
B
Institut für Festkörperforschung, Forschungszentrum Jülich GmbH, Jülich, Germany. b.botar@fz-juelich.de
Kögerler
Paul
P