title: Formation and cation distribution in supported manganese ferrite nanoparticles: an X-ray absorption study.
abstract: Extended X-ray absorption fine structure (EXAFS) and X-ray absorption near-edge structure (XANES) techniques at both Fe and Mn K-edges were used to investigate the formation of MnFe(2)O(4) nanoparticles embedded in a silica aerogel matrix as a function of calcination temperature (at 450, 750 and 900 degrees C). Up to 450 degrees C, two separated highly-disordered phases of iron and manganese are present. With increasing the temperature (to 750 and 900 degrees C), the structure of aerogel nanoparticles becomes progressively similar to that of the spinel structure MnFe(2)O(4) (jacobsite). Quantitative determination of cations distribution in the spinel structure shows that aerogels calcined at 750 and 900 degrees C have a degree of inversion i = 0.20. A pure jacobsite sample synthesised by co-precipitation and used as a reference compound shows a much higher degree of inversion (i = 0.70). The different distribution of iron and manganese cations in the octahedral and tetrahedral sites in pure jacobsite and in the aerogels can be ascribed to partial oxidation of Mn(2+) to Mn(3+) in pure jacobsite, confirmed by XANES analysis, probably due to the synthesis conditions.
authors.affiliation: Dipartimento di Scienze Chimiche and INSTM, Università di Cagliari, S.P. Monserrato-Sestu Km 0.700, I-09042, Monserrato, Cagliari, Italy.
authors.forename: Daniela
authors.initials: D
authors.lastname: Carta
authors.forename: Maria Francesca
authors.initials: MF
authors.lastname: Casula
authors.forename: Gavin
authors.initials: G
authors.lastname: Mountjoy
authors.forename: Anna
authors.initials: A
authors.lastname: Corrias
mesh_terms: D000042:Absorption; D002412:Cations / Q000737:chemistry; D005290:Ferric Compounds / Q000737:chemistry*; D005782:Gels / Q000737:chemistry; D008345:Manganese / Q000737:chemistry*; D053768:Metal Nanoparticles / Q000737:chemistry*; D013057:Spectrum Analysis; D013696:Temperature; D014961:X-Ray Diffraction
chemical_list: D002412:Cations; D005290:Ferric Compounds; D005782:Gels; C001215:ferrite; D008345:Manganese