title: The electronic absorption spectra of pyridine azides, solvent-solute interaction.
abstract: The electronic absorption spectra of: 2-, 3-, and 4-azidopyridines have been investigated in a wide variety of polar and non-polar solvents. According to Onsager model, the studied spectra indicate that the orientation polarization of solvent dipoles affects the electronic spectrum much stronger than the induction polarization of solvent dipoles. The effect of solvent dipole moment predominates that of solvent refractive index in determining the values of band maxima of an electronic spectrum. The spectra of azidopyridines differ basically from these of pyridine or mono-substituted pyridine. Results at hand indicate that the azide group perturbs the pyridine ring in the case of 3-azidopyridine much more than it does in the case of 2-azidopyridine. This result agrees with the predictions of the resonance theory. Although the equilibrium <==> azide tetrazole is well known, yet the observed spectra prove that such an equilibrium does not exist at the studied conditions. The spectra of the studied azidopyridines are characterized by the existence of overlapping transitions. Gaussian analysis is used to obtain nice, resolved spectra. All the observed bands correspond to pi-->pi* transitions, n-->pi* may be overlapped with the stronger pi-->pi* ones.
authors.affiliation: Department of Chemistry, Faculty of Science, University of Cairo, Giza, Egypt. aboeittah@yahoo.com
authors.forename: Rafie H
authors.initials: RH
authors.lastname: Abu-Eittah
authors.forename: Mahmoud K
authors.initials: MK
authors.lastname: Khedr
mesh_terms: D000042:Absorption; D001386:Azides / Q000737:chemistry* / Q000493:pharmacokinetics; D004583:Electrons; D004735:Energy Transfer / Q000502:physiology; D008954:Models, Biological; D011725:Pyridines / Q000737:chemistry* / Q000493:pharmacokinetics; D012996:Solutions / Q000737:chemistry / Q000493:pharmacokinetics*; D012997:Solvents / Q000737:chemistry / Q000493:pharmacokinetics*; D013055:Spectrophotometry, Infrared; D013057:Spectrum Analysis
chemical_list: D001386:Azides; D011725:Pyridines; D012996:Solutions; D012997:Solvents; C538834:azidopyridine