Nonlinear optical and ferroelectric properties of a 3-D Cd(II) triazolate complex with a novel (6(3))2(6(10) x 8(5)) topology.
A novel 3-D (3,6)-connected topological architecture, obtained by reacting Cd(ClO4)2 x 6H2O with Htrtr (Htrtr = 3-(1,2,4-triazole-4-yl)-1H-1,2,4-triazole) under solvothermal conditions, presents a non-centrosymmetric polar packing arrangement, resulting in a strong second harmonic generation (SHG) response and ferroelectric property.
Zhou
Wei-Wei
WW
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, PR China.
Chen
Jiu-Tong
JT
Xu
Gang
G
Wang
Ming-Sheng
MS
Zou
Jian-Ping
JP
Long
Xi-Fa
XF
Wang
Guo-Jian
GJ
Guo
Guo-Cong
GC
Huang
Jin-Shun
JS