Enhanced fluid flow through nanoscale carbon pipes.
Recent experimental and theoretical studies demonstrate that pressure driven flow of fluids through nanoscale ( d < 10 nm) carbon pores occurs 4 to 5 orders of magnitude faster than predicted by extrapolation from conventional theory. Here, we report experimental results for flow of water, ethanol, and decane through carbon nanopipes with larger inner diameters (43 +/- 3 nm) than previously investigated. We find enhanced transport up to 45 times theoretical predictions. In contrast to previous work, in our systems, decane flows faster than water. These nanopipes were composed of amorphous carbon deposited from ethylene vapor in alumina templates using a single step fabrication process.
Whitby
Max
M
Chemistry Department, Imperial College, South Kensington, London SW7 2AZ, United Kingdom.
Cagnon
Laurent
L
Thanou
Maya
M
Quirke
Nick
N