Microelectrode arrays and ceric ammonium nitrate: a simple strategy for developing new site-selective synthetic methods.
Conditions for a site-selective ceric ammonium nitrate oxidation have been developed. The reactions proceed nicely on both 1K- and 12K-microelectrode arrays. The procedure for developing the reactions was very simple and demonstrated that the same reagents used for a solution-phase reaction can be used for a related site-selective reaction on a microelectrode array.
Kesselring
David
D
Department of Chemistry, Washington University, St. Louis, Missouri 63130, USA.
Maurer
Karl
K
Moeller
Kevin D
KD
D002563:Cerium / Q000737:chemistry*; D020650:Combinatorial Chemistry Techniques / Q000379:methods*; D007202:Indicators and Reagents / Q000737:chemistry; D008839:Microelectrodes; D008956:Models, Chemical; D017646:Organosilicon Compounds / Q000737:chemistry; D010084:Oxidation-Reduction; D011721:Pyrenes / Q000737:chemistry; D012996:Solutions / Q000737:chemistry; D012997:Solvents / Q000737:chemistry
D007202:Indicators and Reagents; D017646:Organosilicon Compounds; D011721:Pyrenes; D012996:Solutions; D012997:Solvents; D002563:Cerium; C030984:pyrene; C004653:ceric ammonium nitrate