A ladder based on paddlewheel diruthenium(II, II) rails connected by TCNQ rungs: a polymorph of the hexagonal 2-D network phase.
The slow diffusion reaction of [Ru(2)(O(2)CCF(3))(4)(THF)(2)] with TCNQ in CH(2)Cl(2)/4-chlorotoluene, respectively, leads to the formation of ladder chain composed of [Ru(2)] rails and TCNQ rungs in a 2 : 1 ratio.
Motokawa
Natsuko
N
Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza-Aoba, Aoba-ku, Sendai, Miyagi, 980-8578, Japan.
Oyama
Tomomi
T
Matsunaga
Satoshi
S
Miyasaka
Hitoshi
H
Sugimoto
Kunihisa
K
Yamashita
Masahiro
M
Lopez
Nazario
N
Dunbar
Kim R
KR