title: Use of modified sorbent for the separation and preconcentration of chromium species from industrial waste water.
abstract: A simple and sensitive method based on solid phase extraction (SPE) on acetyl acetone modified XAD-16 has been established for separation of Cr (III) and Cr (VI) from and industrial water samples. Two forms of chromium showed different exchange capacities at different pH values, viz. Cr (III) selectively retained at pH 5-7 whereas Cr (VI) retained at pH 1. Hence complete separation of the two forms of chromium is possible. Retained species were eluted with 5 mL of 2 mol L(-1) HNO(3) and 2 mol L(-1) NaOH. The detection limit of 0.02 and 0.014 microg mL(-1) was achieved for Cr (III) and Cr (VI), respectively, with an enrichment factor of 100 and 140. Various kinetic and thermodynamic parameters were also determined. The metal ion concentration was measured by atomic Absorption Spectroscopy. The possible retention mechanism is also discussed. The method was successfully applied for the speciation of chromium in industrial water samples.
authors.affiliation: National Center of Excellence in Analytical Chemistry, University of Sindh, Jamshoro, Pakistan.
authors.forename: Jamil-ur-Rahman
authors.initials: JU
authors.lastname: Memon
authors.forename: Saima Q
authors.initials: SQ
authors.lastname: Memon
authors.forename: M I
authors.initials: MI
authors.lastname: Bhanger
authors.forename: M Y
authors.initials: MY
authors.lastname: Khuhawar
mesh_terms: D000327:Adsorption; D002852:Chromatography, Ion Exchange / Q000379:methods*; D002857:Chromium / Q000302:isolation & purification*; D007220:Industrial Waste; D052616:Solid Phase Extraction; D013054:Spectrophotometry, Atomic; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*
chemical_list: D007220:Industrial Waste; D014874:Water Pollutants, Chemical; D002857:Chromium