Osmotic pressure and polymer size in semidilute polymer solutions under good-solvent conditions.
We consider the lattice Domb-Joyce model at a value of the coupling for which scaling corrections approximately vanish and determine the universal scaling functions associated with the osmotic pressure and the polymer size for semidilute polymer solutions (c/c( *)<or=10, where c is the concentration of the solution and c( *) is the overlap concentration) in good-solvent conditions. Our result for the osmotic pressure agrees with previous renormalization-group calculations (the relative difference is less than 1%) but differs significantly from previous numerical determinations in which polymers were modeled as lattice self-avoiding walks. We show that for c/c( *) greater than or approximately equal 6 simulations of lattice self-avoiding walks give results that are affected by strong scaling corrections even for chain lengths as large as 1000: The self-avoiding walk model is therefore unsuitable for the determination of universal properties of polymer solutions deep in the semidilute regime.
Pelissetto
Andrea
A
Dipartimento di Fisica, Universita degli Studi di Roma La Sapienza and INFN, Sezione di Roma I, Piazzale A. Moro 2, I-00185 Roma, Italy. andrea.pelissetto@roma1.infn.it