Acceleration of catalytic activity of calcium oxide for biodiesel production.
This research was aimed at studying the acceleration of the catalytic activity of calcium oxide (CaO) for developing an effective heterogeneous catalyst for biodiesel production by the transesterification of plant oil with methanol. CaO was activated by pretreatment with methanol and was used for the transesterification reaction. The activation and transesterification reaction conditions were examined. The obtained optimal reaction conditions were 0.1-g CaO, 3.9-g methanol, 15-g rapeseed oil, and 1.5-h activation time at room temperature that provided methyl ester in approximately 90% yield within a reaction time of 3h at 60 degrees C. The activation mechanism was also investigated, and the proposed mechanism is as follows. By pretreatment with methanol, a small amount of CaO gets converted into Ca(OCH(3))(2) that acts as an initiating reagent for the transesterification reaction and produces glycerin as a by-product. Subsequently, a calcium-glycerin complex, formed due to the reaction of CaO with glycerin, functions as the main catalyst and accelerates the transesterification reaction.
Kawashima
Ayato
A
Environmental Science for Industry, Faculty of Agriculture, Ehime University, 3-5-7 Tarumi, Matsuyama, Ehime 790-8566, Japan. a-kawa@agr.ehime-u.ac.jp
Matsubara
Koh
K
Honda
Katsuhisa
K
D001674:Bioelectric Energy Sources; D017610:Calcium Compounds / Q000737:chemistry*; D002384:Catalysis; D004951:Esterification; D005229:Fatty Acids, Monounsaturated; D005742:Gasoline; D000432:Methanol / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry*; D010938:Plant Oils / Q000737:chemistry*; D000074262:Rapeseed Oil
D017610:Calcium Compounds; D005229:Fatty Acids, Monounsaturated; D005742:Gasoline; D010087:Oxides; D010938:Plant Oils; D000074262:Rapeseed Oil; C016538:lime; D000432:Methanol