2,3-Heteroaromatic ring-fused cyclohexanones via heteroaromatic homo-Nazarov cyclization of donor-acceptor substituted cyclopropanes.
Heteroaryl 2-silylmethyl-substituted cyclopropyl ketones rearrange under Lewis acid conditions via heteroaromatic homo-Nazarov cyclization to form 2,3-heteroaromatic ring fused 4-t-butyldiphenylsilylmethyl-substituted cyclohexanones.
Yadav
Veejendra K
VK
Department of Chemistry, Indian Institute of Technology, Kanpur, 208016, India. vijendra@iitk.ac.in
Kumar
Naganaboina Vijaya
NV
D003500:Cyclization; D003512:Cyclohexanones / Q000138:chemical synthesis*; D003521:Cyclopropanes / Q000737:chemistry*; D006571:Heterocyclic Compounds / Q000138:chemical synthesis*; D007202:Indicators and Reagents; D014297:Trimethylsilyl Compounds / Q000737:chemistry
D003512:Cyclohexanones; D003521:Cyclopropanes; D006571:Heterocyclic Compounds; D007202:Indicators and Reagents; D014297:Trimethylsilyl Compounds; C030797:cyclopropane