title: Synthesis of D-trigalacturonic acid methylglycoside and conformational comparison with its sulfur analogue.
abstract: D-Trigalacturonic acid methylglycoside (3) was synthesized to evaluate the previously synthesized sulfur analogue 1 by comparison. The NOE experiments revealed that both 3 and 1 took on a similar conformation around their glycosyl linkage.
authors.affiliation: Faculty of Agriculture and Life Science, Hirosaki University, Japan.
authors.forename: Kazunori
authors.initials: K
authors.lastname: Yamamoto
authors.forename: Yu
authors.initials: Y
authors.lastname: Sato
authors.forename: Ayumi
authors.initials: A
authors.lastname: Ishimori
authors.forename: Kazuo
authors.initials: K
authors.lastname: Miyairi
authors.forename: Toshikatsu
authors.initials: T
authors.lastname: Okuno
authors.forename: Nobuaki
authors.initials: N
authors.lastname: Nemoto
authors.forename: Hiroki
authors.initials: H
authors.lastname: Shimizu
authors.forename: Shunichi
authors.initials: S
authors.lastname: Kidokoro
authors.forename: Masaru
authors.initials: M
authors.lastname: Hashimoto
mesh_terms: D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D013455:Sulfur / Q000737:chemistry*; D014312:Trisaccharides / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D014312:Trisaccharides; C532380:trigalacturonic acid methylglycoside; D013455:Sulfur