A simple route to chiral phosphinous acid-boranes.
We report a simple one-pot synthesis of enantiomerically enriched alkyl- and arylphenylphosphinous acid-borane starting from readily available (R(P))-(-)-menthylhydrogenophenylphosphinate and organolithium reagents.
Moraleda
Delphine
D
Université Aix-Marseille, Institut des Sciences Moléculaires de Marseille, ECM, CNRS, UMR 6263, Av. Escadrille Normandie Niemen, Marseille Cedex 20, 13397.
Gatineau
David
D
Martin
David
D
Giordano
Laurent
L
Buono
Gérard
G