Generation of a triplet diradical from a donor-acceptor cross conjugate upon acid-induced electron transfer.
Enhancement of the electron acceptor ability of a para-quinodiimine unit by double protonation leads to the proton-induced intramolecular electron transfer from the donor unit to the cross-conjugated acceptor, giving rise to ground state triplet diradical reversibly.
Sandberg
Mats O
MO
Department of Basic Science, Graduate School of Arts & Sciences, The University of Tokyo, Komaba, Meguro-Ku, Tokyo 153-8902, Japan.
Nagao
Osami
O
Wu
Zhikun
Z
Matsushita
Michio M
MM
Sugawara
Tadashi
T
D000143:Acids; D004578:Electron Spin Resonance Spectroscopy; D004579:Electron Transport / Q000502:physiology*; D005609:Free Radicals; D011143:Polyvinyl Chloride / Q000737:chemistry; D011522:Protons; D012996:Solutions; D013056:Spectrophotometry, Ultraviolet; D014269:Trifluoroacetic Acid
D000143:Acids; D005609:Free Radicals; D011522:Protons; D012996:Solutions; D011143:Polyvinyl Chloride; D014269:Trifluoroacetic Acid