title: Ligand influence on the formation of P/Se semiconductor materials from metal-organic complexes.
abstract: The complexes [Ni{(SeP(i)Pr(2))(2)N}(2)] (2), [Ni(Se(2)P(i)Pr(2))(2)] (), and [Co(Se(2)P(i)Pr(2))(2)] (4) were synthesised and the X-ray single crystal structures of (1) and (2) were determined. Thin films of nickel selenide, cobalt selenide and cobalt phosphide have been deposited by the chemical vapour deposition method using imidodiselenophosphinato-nickel(ii) (1), -cobalt(ii) [Co{(SeP(i)Pr(2))(2)N}(2)] (3), diselenophosphinato-nickel(ii) (2), -cobalt(ii) (4) and diselenocarbamato-nickel(ii) [Ni(Se(2)CNEt(2))(2)] (5), and -cobalt(iii) [Co(Se(2)CNEt(2))(3)] (6) precursors.
authors.affiliation: The School of Chemistry and The School of Materials, The University of Manchester, Oxford Road, Manchester, UKM13 9PL.
authors.forename: Arunkumar
authors.initials: A
authors.lastname: Panneerselvam
authors.forename: Chinh Q
authors.initials: CQ
authors.lastname: Nguyen
authors.forename: John
authors.initials: J
authors.lastname: Waters
authors.forename: Mohammad A
authors.initials: MA
authors.lastname: Malik
authors.forename: Paul
authors.initials: P
authors.lastname: O'Brien
authors.forename: James
authors.initials: J
authors.lastname: Raftery
authors.forename: Madeleine
authors.initials: M
authors.lastname: Helliwell