Manganese catalysed asymmetric cis-dihydroxylation with H2O2.
High turnover enantioselective alkene cis-dihydroxylation is achieved with H(2)O(2) catalysed by manganese based complexes containing chiral carboxylato ligands.
de Boer
Johannes W
JW
Stratingh Institute for Chemistry, Faculty of Mathemathics and Natural Sciences, University of Groningen, Nijenborgh 4, Groningen 9747 AG, The Netherlands.
Browne
Wesley R
WR
Harutyunyan
Syuzanna R
SR
Bini
Laura
L
Tiemersma-Wegman
Theodora D
TD
Alsters
Paul L
PL
Hage
Ronald
R
Feringa
Ben L
BL
D000475:Alkenes / Q000737:chemistry; D002264:Carboxylic Acids / Q000737:chemistry; D002384:Catalysis; D006861:Hydrogen Peroxide / Q000737:chemistry*; D006900:Hydroxylation; D008024:Ligands; D008345:Manganese / Q000737:chemistry*; D008968:Molecular Conformation; D013237:Stereoisomerism; D013696:Temperature
D000475:Alkenes; D002264:Carboxylic Acids; D008024:Ligands; D008345:Manganese; D006861:Hydrogen Peroxide