Investigations into the effectiveness of deuterium as a "protecting group" for C-H bonds in radical reactions involving hydrogen atom transfer.
Competition experiments have been carried out to determine the extent to which deuterium can be used as a protecting group for carbon-hydrogen bonds in radical-based intramolecular hydrogen atom transfer processes.
Wood
Mark E
ME
School of Biosciences (originally Department of Chemistry), University of Exeter, Geoffrey Pope Building, Stocker Road, Exeter, EX4 4QD, UK. m.e.wood@exeter.ac.uk
Bissiriou
Sabine
S
Lowe
Christopher
C
Windeatt
Kim M
KM
D002244:Carbon / Q000737:chemistry*; D003903:Deuterium / Q000737:chemistry*; D005609:Free Radicals / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D006860:Hydrogen Bonding; D007700:Kinetics; D008958:Models, Molecular; D015394:Molecular Structure; D009025:Morpholines / Q000737:chemistry; D011759:Pyrrolidines / Q000737:chemistry; D013816:Thermodynamics
D005609:Free Radicals; D009025:Morpholines; D011759:Pyrrolidines; D002244:Carbon; D006859:Hydrogen; D003903:Deuterium; C032519:pyrrolidine