title: Ammonium salts as an inexpensive and convenient nitrogen source in the Cu-catalyzed amination of aryl halides at room temperature.
abstract: Convenient and inexpensive ammonium salts such as NH(4)Cl and aqueous NH(3) solution are found to be readily utilized in the Cu-catalyzed room temperature N-arylation of aryl halides, providing N-unprotected aniline derivatives in high yields.
authors.affiliation: Department of Chemistry and School of Molecular Science (BK21), Korea Advanced Institute of Science and Technology, Daejeon, 305-701, Republic of Korea.
authors.forename: Jinho
authors.initials: J
authors.lastname: Kim
authors.forename: Sukbok
authors.initials: S
authors.lastname: Chang
mesh_terms: D000641:Ammonia / Q000737:chemistry; D000643:Ammonium Chloride / Q000737:chemistry*; D000814:Aniline Compounds / Q000138:chemical synthesis*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*
chemical_list: D000814:Aniline Compounds; D000643:Ammonium Chloride; D000641:Ammonia; D003300:Copper