title: Safe, facile radical-based reduction and hydrosilylation reactions in a microreactor using tris(trimethylsilyl)silane.
abstract: A highly efficient system for tris(trimethylsilyl)silane (TTMSS) mediated deoxygenation, dehalogenation and hydrosilylation reactions is described in a microstructured device; this convenient platform enables the scale up of radical-based processes.
authors.affiliation: Laboratory for Organic Chemistry, Swiss Federal Institute of Technology (ETH) Zurich, Wolfgang-Pauli-Strasse 10, 8093 Zurich, Switzerland.
authors.forename: Arjan
authors.initials: A
authors.lastname: Odedra
authors.forename: Karolin
authors.initials: K
authors.lastname: Geyer
authors.forename: Tomas
authors.initials: T
authors.lastname: Gustafsson
authors.forename: Ryan
authors.initials: R
authors.lastname: Gilmour
authors.forename: Peter H
authors.initials: PH
authors.lastname: Seeberger
mesh_terms: D000480:Alkynes / Q000737:chemistry; D008832:Microchemistry / Q000295:instrumentation / Q000379:methods*; D010084:Oxidation-Reduction; D012821:Silanes / Q000737:chemistry*
chemical_list: D000480:Alkynes; D012821:Silanes; C510691:tris(trimethylsilyl)silane