A rare ligand bridged ferromagnetically coupled MnIV3 complex with a ground spin state of S = 9/2.
An exclusively chelating ligand bridged high-valent [MnIV3] complex has been synthesized, in which all Mn(IV) ions are ferromagnetically-coupled to exhibit an S(T) = 9/2 spin ground state.
Pathmalingam
Thushan
T
Department of Chemistry, University of Ottawa, 10 Marie-Curie, Ottawa, ON, CanadaK1N6N5.
Gorelsky
Serge I
SI
Burchell
Tara J
TJ
Bédard
Anne-Catherine
AC
Beauchemin
André M
AM
Clérac
Rodolphe
R
Murugesu
Muralee
M