Development of palladium-carbene catalysts for telomerization and dimerization of 1,3-dienes: from basic research to industrial applications.
The following account summarises recent developments in the area of palladium-catalysed telomerisation and dimerisation reactions of 1,3-dienes. The most active types of catalyst, palladium-carbene complexes, were tested in pilot plant and proved to be industrially viable.
Clement
Nicolas D
ND
Leibniz-Institut für Katalyse an der Universität Rostock e.V., Albert-Einstein-Strasse 29a, Rostock, Germany.
Routaboul
Lucie
L
Grotevendt
Anne
A
Jackstell
Ralf
R
Beller
Matthias
M
D000466:Alkadienes / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D002617:Chemical Industry / Q000379:methods*; D018360:Crystallography, X-Ray; D019281:Dimerization; D006865:Hydrogenation; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D010865:Pilot Projects
D000466:Alkadienes; D009942:Organometallic Compounds; C030011:carbene; D010165:Palladium; D008697:Methane