Binuclear organometallic ruthenium complexes of a Schiff base expanded porphyrin.
The synthesis of binuclear organometallic ruthenium complexes of an expanded porphyrin-type macrocycle is reported; pyrrolic hydrogen bonding donors were found to interact with ancillary ligands in the primary coordination sphere and to stabilize coordinated dioxygen in an eta(2)-fashion.
Cuesta
Luciano
L
Department of Chemistry and Biochemistry, University of Texas, 1 University Station A5300, Austin, TX 78712-0165, USA.
Tomat
Elisa
E
Lynch
Vincent M
VM
Sessler
Jonathan L
JL
D006860:Hydrogen Bonding; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis*; D011166:Porphyrins / Q000737:chemistry*; D017975:Ruthenium Compounds / Q000737:chemistry*; D012545:Schiff Bases / Q000737:chemistry*; D014961:X-Ray Diffraction
D009942:Organometallic Compounds; D011166:Porphyrins; D017975:Ruthenium Compounds; D012545:Schiff Bases