Effect of metal dilution on the light-induced spin transition in [Fe(x)Zn(1-x)(phen)2(NCS)2] (phen = 1,10-phenanthroline).
The thermal and light-induced spin transitions in [Fe(x)Zn(1-x)(phen)2(NCS)2] (phen = 1,10-phenantholine) have been investigated by magnetic susceptibility, photomagnetism and diffuse reflectivity measurements. These complexes display a thermal spin transition and undergo the light-induced excited spin state trapping (LIESST) effect at low temperatures. For each compound, the thermal spin transition temperature, T1/2, and the relaxation temperature of the photo-induced high-spin state, T(LIESST), have been systematically determined. It appears that T1/2 decreases with the metal dilution while T(LIESST) remains unchanged. This behaviour is discussed on the basis of the kinetic study governing the photo-induced back conversion.
Baldé
Chérif
C
ICMCB, CNRS, Université Bordeaux, 87 Av. Doc. A. Schweitzer, F-33608 Pessac, France.
Desplanches
Cédric
C
Wattiaux
Alain
A
Guionneau
Philippe
P
Gütlich
Philipp
P
Létard
Jean-François
JF