title: Numerical model for a watering plan to wash out organic matter from the municipal solid waste incinerator bottom ash layer in closed system disposal facilities.
abstract: Bottom ash from municipal solid waste incineration (MSWI) is a main type of waste that is landfilled in Japan. The long-term elution of organic matter from the MSWI bottom ash layers is a concern because maintenance and operational costs of leachate treatment facilities are high. In closed system disposal facilities (CSDFs), which have a roof to prevent rainfall from infiltrating into the waste layers, water must be supplied artificially and its quantity can be controlled. However, the quantity of water needed and how to apply it (the intensity, period and frequency) have not been clearly defined. In order to discuss an effective watering plan, this study proposes a new washout model to clarify a fundamental mechanism of total organic carbon (TOC) elution behavior from MSWI bottom ash layers. The washout model considers three phases: solid, immobile water and mobile water. The parameters, including two mass transfer coefficients of the solid-immobile water phases and immobile-mobile water phases, were determined by one-dimensional column experiments for about 2 years. The intensity, period and frequency of watering and other factors were discussed based on a numerical analysis using the above parameters. As a result, our washout model explained adequately the elution behavior of TOC from the MSWI bottom ash layer before carbonation occurred (pH approximately 8.3). The determined parameters and numerical analysis suggested that there is a possibility that the minimum amount of water needed for washing out TOC per unit weight of MSWI bottom ash layer could be determined, which depends on the two mass transfer coefficients and the depth of the MSWI bottom ash layer. Knowledge about the fundamental mechanism of the elution behavior of TOC from the MSWI bottom ash layer before carbonation occurs, clarified by this study, will help an effective watering plan in CSDFs.
authors.affiliation: Laboratory of Sound Material-Cycle Systems Planning, Graduate School of Engineering, Hokkaido University, N13, W8, Kita-ku, Sapporo, 060-8628 Hokkaido, Japan. k-ishii@eng.hokudai.ac.jp
authors.forename: Kazuei
authors.initials: K
authors.lastname: Ishii
authors.forename: Toru
authors.initials: T
authors.lastname: Furuichi
authors.forename: Noboru
authors.initials: N
authors.lastname: Tanikawa
mesh_terms: D004785:Environmental Pollutants / Q000737:chemistry; D004787:Environmental Pollution / Q000517:prevention & control; D017745:Incineration / Q000295:instrumentation* / Q000379:methods* / Q000592:standards; D007564:Japan; D008962:Models, Theoretical; D009930:Organic Chemicals / Q000737:chemistry*; D014867:Water / Q000737:chemistry*
chemical_list: D004785:Environmental Pollutants; D009930:Organic Chemicals; D014867:Water