Two-step regio- and stereoselective synthesis of cis-vinylstannanes.
Herein we describe a novel stereoselective synthesis of cis-vinylstannanes employing the widely established Li/Te exchange pathway. In contrast to previously reported methods of cis-selective hydrostannation (i.e., ZrCl4), this method demonstrates compatibility toward oxygenated substrates.
Mirzayans
Paul Malek
PM
School of Molecular and Microbial Sciences, University of Queensland, Brisbane, 4072 Queensland, Australia.
Pouwer
Rebecca H
RH
Williams
Craig M
CM