[M(III)(bpym)(CN)(4)](-): a suitable building block to design ferrimagnetic cyano-bridged heterobimetallic chains (M = Fe, Cr; bpym = 2,2'-bypyrimidine).
Two cyano-bridged M(III)Mn(III) [M = Fe () and Cr ()] ferrimagnetic chains are reported; exhibits metamagnetism with two critical fields of 1250 G and 2.0 T which correspond to the overcoming by the applied dc field of the inter- and intrachain magnetic interactions, respectively.
Visinescu
Diana
D
Departament de Química Inorgànica/Instituto de Ciencia Molecular (ICMol), Facultat de Química de la Univeristat de València, Edificio de Institutos s/n, Paterna, 46980, València, Spain.
Toma
Luminita Marilena
LM
Lloret
Francesc
F
Fabelo
Oscar
O
Ruiz-Pérez
Catalina
C
Julve
Miguel
M