Proton- and reductant-assisted dioxygen activation by a nonheme iron(II) complex to form an oxoiron(IV) intermediate.
Thibon
Aurore
A
Institut de Chimie Moléculaire et des Matériaux d'Orsay, UMR CNRS 8182, Laboratoire de Chimie Inorganique, Université Paris Sud 11, 91405 Orsay Cedex, France.
England
Jason
J
Martinho
Marlène
M
Young
Victor G
VG
Frisch
Jonathan R
JR
Guillot
Régis
R
Girerd
Jean-Jacques
JJ
Münck
Eckard
E
Que
Lawrence
L
Banse
Frédéric
F
D006418:Heme / Q000737:chemistry; D006571:Heterocyclic Compounds / Q000737:chemistry; D007501:Iron / Q000737:chemistry*; D008024:Ligands; D009942:Organometallic Compounds / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D011522:Protons
D006571:Heterocyclic Compounds; D008024:Ligands; D009942:Organometallic Compounds; D011522:Protons; C024560:cyclam; D006418:Heme; D007501:Iron; D010100:Oxygen