The dewetting dynamics of the polymer thin film by solvent annealing.
The slippage effect of the polymer chains is investigated in the dewetting process of the polymer solution film. The solvent-induced dewetting is used in our experiments to study the dynamics of hole growth in the dewetting process of the polymer solution film. Our results show that in the case of the low molecular weight polystyrene (PS) film, the slippage effect of the polymer chains is not displayed and the radius of the holes is R approximately exp(t/tau); in the case of the higher molecular weight PS film, the slippage effect of the polymer chain is not valid in the case of the thin film and that is valid in the case of the thick film, and the dynamic process of hole growth divides into three stages (R approximately t, and then R approximately t(x) (23<x<1), finally, R approximately t). Besides, the solvent and substrate properties also influence the dewetting dynamics of the polymer solution film.
Xu
Lin
L
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, People's Republic of China.
Shi
Tongfei
T
An
Lijia
L