New optical supramolecular compound constructed from a polyoxometalate cluster and an organic substrate.
A new optical supramolecular compound constructed from a polyoxometalate cluster and an organic substrate [(H3O)(C12H10N3)2(PW12O40)] (1) has been synthesized via a hydrothermal reaction and has been structurally characterized by X-ray diffraction. The solid-state diffuse reflectance, IR, and photoluminescence spectra of the title compound indicate that there is an interaction between the alpha-PW12O40 and the organic substrate. The light-yellow title compound shows a certain second-order nonlinear optical response of I(2omega) = 2I(KDP)(2omega).
Xie
Yi-Ming
YM
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 35002, China.
Zhang
Qi-Sheng
QS
Zhao
Zhen-Guo
ZG
Wu
Xiao-Yuan
XY
Chen
Shan-Ci
SC
Lu
Can-Zhong
CZ