title: Prevenient dye-degradation mechanisms using UV/TiO2/carbon nanotubes process.
abstract: Photocatalysis research heavily emphasizes increasing photo-efficiency. This study presents the application of carbon nanotubes (CNTs) to increase the photocatalytic activity of TiO(2). It elucidates the effect of CNTs dose on the decolorization efficiency of aqueous azo dye, C.I. Reactive Red 2 (RR2), determines the effects of SO(4)(2-) formation and removal of total organic carbon (TOC), and measures the effects of various ultraviolet wavelengths. Scanning electron microscopy was used to elucidate the mixing phenomenon and the size of TiO(2) and CNTs; X-ray diffraction was used to determine crystallinity; a BET meter was used to measure surface area and a spectrophotometry was used to determine the decolorization of RR2. Experimental results indicated significant effects of photodegradation on the combination of TiO(2) with CNTs and electron transfer is higher for 410 nm irradiation than for 365 nm, revealing that solar light can be used. The electron transfer in the TiO(2)/CNTs composites reduced the electron/hole recombination and increased the photon efficiency and the prevenient dye-degradation mechanisms using UV/TiO(2)/CNTs were established.
authors.affiliation: Department of Safety Health and Environmental Engineering, National Yunlin University of Science and Technology, Douliu, Yunlin, Taiwan. kuocyr@ms35.hinet.net
authors.forename: Chao-Yin
authors.initials: CY
authors.lastname: Kuo
mesh_terms: D004396:Coloring Agents / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D008903:Minerals / Q000737:chemistry; D037742:Nanotubes, Carbon / Q000737:chemistry* / Q000648:ultrastructure; D014025:Titanium / Q000737:chemistry*; D014466:Ultraviolet Rays; D014961:X-Ray Diffraction
chemical_list: D004396:Coloring Agents; D008903:Minerals; D037742:Nanotubes, Carbon; C009495:titanium dioxide; D014025:Titanium