title: Synthesis and light-emitting properties of disubstituted polyacetylenes carrying chromophoric naphthylethynylphenyl pendants.
abstract: Poly(1-phenyl-1-alkyne)s bearing chromophoric pendants and containing alkyl spacers (-{(C 6H 5)CC[(CH 2) m OCOC 6H 4CCNp]} n - [P 1( m) ( m = 3, 4, 9); Np = 1-naphthyl]) were synthesized, and the effects of structural variations on the optical properties, especially electroluminescence, of the polymers were investigated. The monomers were prepared in high yields by esterification and coupling reactions of n-phenyl-( n - 1)-alkyn-1-ols. Selective polymerizations of the 1-phenyl-1-alkyne unit of the monomers were effected by WCl 6-Ph 4Sn catalyst, affording polymers with high molecular weights ( M w up to 63 000) in high yields (up to 83%). Structures and properties of the polymers were characterized and evaluated by IR, NMR, TGA, UV, PL, and EL analyses. All the polymers are thermally very stable, losing almost no weight when heated up to 400 degrees C. Photoexcitation of the polymer solutions induces strong blue light emission at 460 nm, with quantum yields up to 98%. No aggregation quenching was observed when the polymers were fabricated into solid films. Multilayer EL devices with the configuration of ITO/P 1( m):PVK/BCP/Alq 3/LiF/Al were fabricated, which emitted blue light with luminance up to 498 cd/m (2). The device performance varied with the spacer length ( m), with P 1(4) giving the highest external quantum efficiency of 0.47%. The value was further enhanced to 0.86% by optimizing the layer thickness and inserting a hole-injection layer.
authors.affiliation: Department of Chemistry and Center for Display Research, The Hong Kong University of Science & Technology (HKUST), Clear Water Bay, Kowloon, Hong Kong, China.
authors.forename: Jacky W Y
authors.initials: JW
authors.lastname: Lam
authors.forename: Anjun
authors.initials: A
authors.lastname: Qin
authors.forename: Yongqiang
authors.initials: Y
authors.lastname: Dong
authors.forename: Yuning
authors.initials: Y
authors.lastname: Hong
authors.forename: Cathy K W
authors.initials: CK
authors.lastname: Jim
authors.forename: Jianzhao
authors.initials: J
authors.lastname: Liu
authors.forename: Yuping
authors.initials: Y
authors.lastname: Dong
authors.forename: Hoi Sing
authors.initials: HS
authors.lastname: Kwok
authors.forename: Ben Zhong
authors.initials: BZ
authors.lastname: Tang