ScorpoPhos: a novel phosphine-nitrogen ligand containing a tris(pyrazolyl)borate ligand core.
A new tris(pyrazolyl)borate ligand bearing phosphine donor groups appended to the 3-position of the pyrazolyl rings is reported, and the hemilabile behaviour of this tris-N,P ligand in coordination with K+, Tl+ and Cu+ ions is investigated.
Kealey
Steven
S
Department of Chemistry, Imperial College London, South Kensington, London, UK SW7 2AZ.
Long
Nicholas J
NJ
Miller
Philip W
PW
White
Andrew J P
AJ
Gee
Antony D
AD
D001896:Boron Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D002412:Cations; D003300:Copper / Q000737:chemistry; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D008956:Models, Chemical; D009584:Nitrogen / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000138:chemical synthesis*; D010472:Perchlorates / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D011188:Potassium / Q000737:chemistry; D013793:Thallium / Q000737:chemistry
D001896:Boron Compounds; D002412:Cations; D008024:Ligands; D009943:Organophosphorus Compounds; D010472:Perchlorates; D010720:Phosphines; D003300:Copper; D013793:Thallium; C044646:phosphine; D009584:Nitrogen; D011188:Potassium