title: Olefin isomerisation versus hydrozirconation: a case of a stable beta-hydrogen-containing Zr-alkyl derivative.
abstract: Details of the olefin isomerisation mechanism followed by monohydride constrained-geometry zirconium complexes have been clarified using the allyldimethylsilylcyclopentadienyl zirconium hydride model compound. DFT calculations on the model systems agree with the experimental results.
authors.affiliation: Departamento de Química Inorgánica, Facultad de Química, Universidad Alcalá, Campus Universitario, E-28871 Alcalá de Henares, Madrid, Spain.
authors.forename: Cristina E
authors.initials: CE
authors.lastname: Petrisor
authors.forename: Luis Manuel
authors.initials: LM
authors.lastname: Frutos
authors.forename: Obis
authors.initials: O
authors.lastname: Castaño
authors.forename: Marta E G
authors.initials: ME
authors.lastname: Mosquera
authors.forename: Eva
authors.initials: E
authors.lastname: Royo
authors.forename: Tomás
authors.initials: T
authors.lastname: Cuenca