Selective iodinated dipyrrolyldiketone BF2 complexes as potential building units for oligomeric systems.
Selective iodination at the alpha-pyrrole positions of dipyrrolyldiketone BF(2) complexes is a key procedure to afford mono- and bisiodinated derivatives as the starting materials of the coupling reactions for various utility molecules and covalently linked oligomer systems. Iodination can also be applied to the phenylene-bridging receptor dimer to obtain the derivatives selectively iodinated at the terminal alpha-pyrrole position(s).
Maeda
Hiromitsu
H
College of Pharmaceutical Sciences, Institute of Science and Engineering, Ritsumeikan University, Kusatsu, 525-8577, Japan. maedahir@ph.ritsumei.ac.jp
Haketa
Yohei
Y
D000838:Anions / Q000737:chemistry*; D001896:Boron Compounds / Q000737:chemistry*; D018360:Crystallography, X-Ray; D019281:Dimerization; D006860:Hydrogen Bonding; D007455:Iodine / Q000737:chemistry*; D007659:Ketones / Q000138:chemical synthesis / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D015394:Molecular Structure; D011758:Pyrroles / Q000737:chemistry*; D000644:Quaternary Ammonium Compounds / Q000737:chemistry; D021241:Spectrometry, Mass, Electrospray Ionization; D019032:Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization
D000838:Anions; D001896:Boron Compounds; D007659:Ketones; D011758:Pyrroles; D000644:Quaternary Ammonium Compounds; D007455:Iodine; C009405:tetrabutylammonium