EPR, mass, electronic, IR spectroscopic and thermal studies of bimetallic copper(II) complexes with tetradentate ligand, 1,4-diformyl piperazine bis(carbohydrazone).
The synthesis of novel bimetallic Cu(II) complexes with general stoichiometry [Cu(2)(H(2)L)X(2)(H(2)O)(2)], [Cu(2)(H(2)L)(CH(3)COO)(2)] and [Cu(2)(H(2)L)SO(4)(H(2)O)(2)] (where H(2)L=dideprotonated ligand and X=NO(3)(-) and Cl(-)) derived from tetradentate ligand obtained by the condensation of 1,4-diformyl piperazine with carbohydrazide has been discussed. The complexes were characterized by elemental analyses, molar conductance measurements, magnetic susceptibility measurements, IR, mass, UV, EPR spectral studies and thermogravimetric analyses. The value of magnetic moments indicates that the complexes are paramagnetic and show the antiferromagnetic interaction between the two metal centres. The complexes possess the square planar coordination environment. The values of covalency measurements, i.e., in-plane sigma-bonding alpha(2), in-plane pi-bonding beta(2) and orbital reduction factor k indicate the covalent nature of complexes.
Chandra
Sulekh
S
Department of Chemistry, Zakir Husain College (University of Delhi), J.L. Nehru Marg, New Delhi 110002, India. schandra_00@yahoo.com
Jain
Deepali
D
Sharma
Amit Kumar
AK
D003300:Copper / Q000737:chemistry*; D004055:Differential Thermal Analysis; D004578:Electron Spin Resonance Spectroscopy; D006835:Hydrazones / Q000138:chemical synthesis* / Q000737:chemistry; D006860:Hydrogen Bonding; D008024:Ligands; D046911:Macromolecular Substances / Q000138:chemical synthesis / Q000737:chemistry; D013058:Mass Spectrometry; D008954:Models, Biological; D010879:Piperazines / Q000138:chemical synthesis* / Q000737:chemistry*; D011108:Polymers / Q000138:chemical synthesis / Q000737:chemistry; D013055:Spectrophotometry, Infrared; D013818:Thermogravimetry
C538870:1,4-diformyl piperazine bis(carbohydrazone); D006835:Hydrazones; D008024:Ligands; D046911:Macromolecular Substances; D010879:Piperazines; D011108:Polymers; D003300:Copper