Reduction-induced switching of single-molecule conductance of fullerene derivatives.
The effect of electrochemical reduction on the single-molecule conductance of fullerene C60 derivatives was studied by scanning tunneling microscopy. Three types of C60 derivatives were synthesized, a monoadduct having an amino-terminated linker and two bisadducts having two linkers at different positions (trans2 and trans3). Each C60 derivative was immobilized on a gold surface by an amino-gold linkage, confirmed by infrared reflection-absorption spectroscopy. The immobilized C60 derivatives showed reversible and multiple reduction peaks in the cyclic voltammogram in dimethylformamide (DMF) at almost the same potentials as those in solution, showing the redox properties of the molecules are intact on gold. Single-molecule conductances of the bisadducts, which can span between a scanning tunneling microscopy (STM) tip made of gold and substrate with the two linkers, were determined by the STM break-junction measurements in water and DMF. The conductances were 6.1+/-4.5 nS in water and 4.9+/-1.7 nS in DMF for the trans2 bisadduct and 8.4+/-3.4 nS in water and 7.9 nS+/-2.8 in DMF for the trans3 bisadduct. By using a potential-controlled STM setup, the tunneling current through a single molecule was recorded with sweeping the potentials of the tip and substrate. The trans2 bisadduct showed significant changes in the current when the reductions of the C60 moiety occur. Some current curves showed multiple peaks, and the other curves showed stepwise increase and decrease at the C60 reduction and subsequent reoxidation. Statistical analysis afforded stepwise switching of the conductance as the average behavior and suggested that the electron tunneling through the C60 derivative is enhanced as it accepts electrons.
Morita
Tomoyuki
T
Biodesign Institute, Department of Chemistry and Biochemistry, Arizona State University, Tempe, Arizona 85287, USA. morita@peptide.polym.kyoto-u.ac.jp
Lindsay
Stuart
S
D004126:Dimethylformamide / Q000737:chemistry; D004553:Electric Conductivity; D004563:Electrochemistry; D037741:Fullerenes / Q000737:chemistry*; D006046:Gold / Q000737:chemistry; D016252:Microscopy, Scanning Tunneling; D010084:Oxidation-Reduction; D000644:Quaternary Ammonium Compounds / Q000737:chemistry; D012972:Sodium Hydroxide / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared
D037741:Fullerenes; D000644:Quaternary Ammonium Compounds; D012972:Sodium Hydroxide; D006046:Gold; D004126:Dimethylformamide; C009405:tetrabutylammonium; C069837:fullerene C60