[Synthesis of sterols oxygenated in the terminal fragment of their side chains].
Methods of stereoselective synthesis of oxysterols are considered by the examples of (25R)-26-hydroxycholesterol, (24S)-24,25-epoxycholesterol, and (24S)-24-hydroxycholesterol containing functional groups in the terminal fragments of their side chains. Special attention is paid to the problems of construction of chiral centers C24 and C25.
Antonchik
A V
AV
Zhabinskiĭ
V N
VN
Khripach
V A
VA
D002784:Cholesterol / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry; D006888:Hydroxycholesterols / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D006888:Hydroxycholesterols; C007042:cholest-5-ene-3 beta,26-diol; C044563:24-hydroxycholesterol; C028358:24,25-epoxycholesterol; D002784:Cholesterol