Facile intramolecular C(sp3)-H bond activation with PdII.
The treatment of bis(4-tert-butylthiazolyl)isoindoline (4-tBuBTI) with palladium acetate results in the exclusive formation of an organometallic PdII compound with C-H activated t-butyl group and a hemilabile S-coordinated thiazole donor in cis-position.
Bröring
Martin
M
Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse, 35043 Marburg, Germany. Martin.Broering@chemie.uni-marburg.de
Kleeberg
Christian
C