Gold(I)-catalyzed intramolecular hydroamination of unactivated C==C bonds with alkyl ammonium salts.
A mixture of (5)AuCl [ = PCy2[2-(2,6-C6H3(OMe)2)C6H4]] and AgOTf catalyzes the intramolecular hydroamination of unactivated C==C bonds with primary and secondary ammonium salts.
Bender
Christopher F
CF
French Family Science Center, Duke University, Durham, North Carolina, USA.
Widenhoefer
Ross A
RA
D000475:Alkenes / Q000737:chemistry*; D000588:Amines / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D006046:Gold / Q000737:chemistry*; D008024:Ligands; D008956:Models, Chemical; D009942:Organometallic Compounds / Q000737:chemistry*; D000644:Quaternary Ammonium Compounds / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry
D000475:Alkenes; D000588:Amines; D008024:Ligands; D009942:Organometallic Compounds; D000644:Quaternary Ammonium Compounds; D012997:Solvents; D002244:Carbon; D006046:Gold