Structure and properties of [Cr(III)F(NCMe)5](BF4)2.MeCN: a nonaqueous source of Cr(III)F2+ and a building block for new Prussian-blue-like magnetic materials.
[Cr (III)F(NCMe) 5](BF 4) 2.MeCN ( 1) was synthesized from a prolonged dissolution of [Cr (III)(NCMe) 6](BF 4) 3 in MeCN via fluoride abstraction from BF 4 (-). Complex 1 exhibits a crystal field splitting, Delta o, of 17 470 cm (-1) and is a nonaqueous source of Cr (III)F (2+). The reaction of 1 with (NEt 4) 3[Cr (III)(CN) 6] formed a new Prussian-blue-like magnetic material of (NEt 4) 0.04[Cr (III)F] 1.54[Cr (III)(CN) 6](BF 4) 0.12.0.10(MeCN) ( 2) composition. Complex 2 magnetically orders at a critical temperature, T c, of 85 K and at 2 K exhibits magnetic hysteresis with a coercive field, H cr, of 60 Oe and a remanent magnetization, M rem, of 1880 emuOe/mol.
Nelson
Kendric J
KJ
Department of Chemistry, University of Utah, 315 South 1400 East, Room 2124, Salt Lake City, Utah 84112-0850, USA.
Dipasquale
Antonio G
AG
Rheingold
Arnold L
AL
Daniels
Matthew C
MC
Miller
Joel S
JS