title: Sonochemical reaction of fullerene[C60] with several 2'-azidoethyl per-O-acetyl glycosides.
abstract: Cycloadditive reaction of fullerene[C60] with various 2'-azidoethyl per-O-acetyl glycopyranoside of D-mannose, D-galactose, D-glucose, D-xylose and D-maltose, respectively gave the glycosyl fullerene[C60] derivatives 2a-2e such as alpha-D-mannosyl fullerene[C60] under ultrasonication. Based on analyses using 1H- and 13C-NMR, UV-vis, FT-IR, and FAB-MS spectroscopies of the glycosyl fullerene[C60] derivatives, the products were composed of a mixture of [5,6]- and [6,6]-junction isomers which were predominantly the closed [5,6]-junction isomer.
authors.affiliation: School of General Education, Kangnam University, Yongin 449-702, South Korea.
authors.forename: Shinsook
authors.initials: S
authors.lastname: Yoon
authors.forename: Sung Ho
authors.initials: SH
authors.lastname: Hwang
authors.forename: Weon Bae
authors.initials: WB
authors.lastname: Ko