title: Cross-sectional silica exposure measurements at two Zambian copper mines of Nkana and Mufulira.
abstract: We measured the quartz content of 20 bulk settled dust and 200 respirable dust samples in a cross-sectional dust exposure assessment that is part of an epidemiological study to ascertain the risk of nonmalignant respiratory diseases among Zambian copper miners. Dust samples were collected from the copper mines of Mopani Copper Mine plc (Mufulira and Nkana Mines). Analytical measurements employed NIOSH Method 0600 for gravimetric analysis of respirable dust and NIOSH Method 7500 for quartz analysis in bulk and respirable dust samples. The measured quartz content of respirable dust showed that 59% and 26% of Mufulira and Nkana Mine samples, respectively, were above the calculated U.S. Occupational Safety and Health Administration permissible exposure limit. The mean intensities of respirable dust exposure at Mufulira and Nkana were 0.992 mg/m3 (range 0-7.674) and 0.868 mg/m3 (range 0-6.944), respectively while the mean intensities of respirable quartz at Mufulira and Nkana were 0.143 mg/m3 (range 0-1.302) and 0.060 mg/m3 (range 0-0.317), respectively. These results indicate weak dust monitoring at these mines which may increase the risk of nonmalignant disease in many miners. Since Zambian mining regulations do not have crystalline silica exposure limits, these results accord with the recommendation that Zambian mining houses and the government establish crystalline silica analysis laboratory capacity and adopt dust mass concentration occupational exposure limits for more protective dust monitoring of workers.
authors.affiliation: University of Michigan, School of Public Health, Department of Environmental Health Sciences, 1420 Washington Heights Ann Arbor, MI 48109-2029, USA. phayumbu@umich.edu
authors.forename: Patrick
authors.initials: P
authors.lastname: Hayumbu
authors.forename: Thomas G
authors.initials: TG
authors.lastname: Robins
authors.forename: Rosa
authors.initials: R
authors.lastname: Key-Schwartz
mesh_terms: D000395:Air Pollutants, Occupational / Q000032:analysis* / Q000633:toxicity; D003300:Copper; D003430:Cross-Sectional Studies; D004391:Dust / Q000032:analysis; D004784:Environmental Monitoring; D062665:Epidemiological Monitoring; D006801:Humans; D019570:Inhalation Exposure / Q000009:adverse effects / Q000032:analysis*; D008452:Maximum Allowable Concentration; D008906:Mining; D009314:National Institute for Occupational Safety and Health, U.S.; D016273:Occupational Exposure / Q000009:adverse effects / Q000032:analysis*; D016272:Occupational Health; D011791:Quartz / Q000032:analysis; D018570:Risk Assessment; D012822:Silicon Dioxide / Q000032:analysis* / Q000633:toxicity; D012829:Silicosis / Q000453:epidemiology* / Q000209:etiology; D020711:Threshold Limit Values; D014481:United States; D015024:Zambia
chemical_list: D000395:Air Pollutants, Occupational; D004391:Dust; D011791:Quartz; D012822:Silicon Dioxide; D003300:Copper