Ligand influence on the formation of P/Se semiconductor materials from metal-organic complexes.
The complexes [Ni{(SeP(i)Pr(2))(2)N}(2)] (2), [Ni(Se(2)P(i)Pr(2))(2)] (), and [Co(Se(2)P(i)Pr(2))(2)] (4) were synthesised and the X-ray single crystal structures of (1) and (2) were determined. Thin films of nickel selenide, cobalt selenide and cobalt phosphide have been deposited by the chemical vapour deposition method using imidodiselenophosphinato-nickel(ii) (1), -cobalt(ii) [Co{(SeP(i)Pr(2))(2)N}(2)] (3), diselenophosphinato-nickel(ii) (2), -cobalt(ii) (4) and diselenocarbamato-nickel(ii) [Ni(Se(2)CNEt(2))(2)] (5), and -cobalt(iii) [Co(Se(2)CNEt(2))(3)] (6) precursors.
Panneerselvam
Arunkumar
A
The School of Chemistry and The School of Materials, The University of Manchester, Oxford Road, Manchester, UKM13 9PL.
Nguyen
Chinh Q
CQ
Waters
John
J
Malik
Mohammad A
MA
O'Brien
Paul
P
Raftery
James
J
Helliwell
Madeleine
M