Safe, facile radical-based reduction and hydrosilylation reactions in a microreactor using tris(trimethylsilyl)silane.
A highly efficient system for tris(trimethylsilyl)silane (TTMSS) mediated deoxygenation, dehalogenation and hydrosilylation reactions is described in a microstructured device; this convenient platform enables the scale up of radical-based processes.
Odedra
Arjan
A
Laboratory for Organic Chemistry, Swiss Federal Institute of Technology (ETH) Zurich, Wolfgang-Pauli-Strasse 10, 8093 Zurich, Switzerland.
Geyer
Karolin
K
Gustafsson
Tomas
T
Gilmour
Ryan
R
Seeberger
Peter H
PH
D000480:Alkynes / Q000737:chemistry; D008832:Microchemistry / Q000295:instrumentation / Q000379:methods*; D010084:Oxidation-Reduction; D012821:Silanes / Q000737:chemistry*
D000480:Alkynes; D012821:Silanes; C510691:tris(trimethylsilyl)silane