2-Trimethylsilylcorannulenyl trifluoromethanesulfonate: an efficient precursor for 1,2-didehydrocorannulene.
2-Trimethylsilylcorannulenyl trifluoromethanesulfonate, prepared from bromocorannulene, provides a means for generating of 1,2-didehydrocorannulene (corannulyne) under very mild conditions as demonstrated by the high-yield formation of its adducts with dienes.
Sygula
Andrzej
A
Department of Chemistry, Mississippi State University, Mail Stop 9573, Mississippi State, Mississippi 39762, USA. asygula@chemistry.msstate.edu
Sygula
Renata
R
Kobryn
Lesya
L