The multi-vicinal fluoroalkane motif: an examination of 2,3,4,5-tetrafluorohexane stereoisomers.
Three unique diastereoisomers of 2,3,4,5-tetrafluorohexane have been prepared, compounds intermediate between hexane and perfluorohexane in their degree of fluorination, and they show very different conformational behaviour and physical properties.
Hunter
Luke
L
Centre for Biomolecular Sciences and School of Chemistry, University of St Andrews, St Andrews, United Kingdom.
Kirsch
Peer
P
Hamilton
John T G
JT
O'Hagan
David
D
D018360:Crystallography, X-Ray; D017611:Fluorine Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D006586:Hexanes / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D008968:Molecular Conformation; D015394:Molecular Structure; D009281:Naphthalenes / Q000138:chemical synthesis* / Q000737:chemistry; D010777:Photochemistry; D011714:Pyrans / Q000737:chemistry; D013237:Stereoisomerism; D013450:Sulfones / Q000737:chemistry; D014466:Ultraviolet Rays
D017611:Fluorine Compounds; D006586:Hexanes; D009281:Naphthalenes; D011714:Pyrans; D013450:Sulfones