Control of vertex geometry, structure dimensionality, functionality, and pore metrics in the reticular synthesis of crystalline metal-organic frameworks and polyhedra.
Metal-organic polyhedra and frameworks (MOPs and MOFs) were prepared by linking square units M2(CO2)4 (M = Cu and Zn) with a variety of organic linkers designed to control the dimensionality (periodicity) and topology of the resulting structures. We describe the preparation, characterization, and crystal structures of 5 new MOPs and 11 new MOFs (termed MOP-14, -15, -17, -23, -24 and MOF-114, -115, -116, -117, -118, -119, -222, -601, -602, -603, -604) and show how their structures are related to the shape and functionality of the building blocks. The gas uptake behaviors of MOP-23 and MOF-601 to -603 are also presented as evidence that these structures have permanent porosity and rigid architectures.
Furukawa
Hiroyasu
H
Department of Chemistry and Biochemistry, Center for Reticular Chemistry at the California NanoSystems Institute, University of California, Los Angeles, California 90095-1569, USA. furukawa@chem.ucla.edu
Kim
Jaheon
J
Ockwig
Nathan W
NW
O'Keeffe
Michael
M
Yaghi
Omar M
OM