Sintering of MSWI fly ash by microwave energy.
This study presents the sintering of municipal solid waste incineration (MSWI) fly ash assisted by microwave energy. The composition of fly ash was investigated by chemical sequential extraction and modified microwave digestion method. Effects of process time, container materials, aging time and salt contents were also discussed. The major elements of fly ash are Ca, Cl, Na, Si, K, Al, Mg, and Zn, and the metal species, Zn, Cr, Pb, Ca, and Cu, are mainly in the oxide phase. Under microwave processing, the fly ash was sintered into a glass-ceramics and the leaching concentrations of heavy metals were restrained. The stabilization efficiency increased with an increase in processing time in most of the cases. Better stabilization efficiency of fly ash was discovered by using the SiO(2) or Al(2)O(3) container than by using the graphite plate/SiC plate. The presence of salt in the fly ash could enhance the sintering and stabilization of fly ash. During the aging time of 0-30 days, negligible Pb in the sintered fly ash was leached out, and the leaching concentration was lower than the criterion.
Chou
Sun-Yu
SY
Research Center for Environmental Pollution Prevention and Control Technology, Graduate Institute of Environmental Engineering, National Taiwan University, Taipei 106, Taiwan, ROC.
Lo
Shang-Lien
SL
Hsieh
Ching-Hong
CH
Chen
Ching-Lung
CL
D002244:Carbon / Q000737:chemistry*; D060729:Coal Ash; D019216:Metals, Heavy; D008872:Microwaves; D052638:Particulate Matter / Q000737:chemistry*; D012722:Sewage / Q000737:chemistry*; D012995:Solubility; D014961:X-Ray Diffraction
D060729:Coal Ash; D019216:Metals, Heavy; D052638:Particulate Matter; D012722:Sewage; D002244:Carbon