Palladium-catalyzed selenoacylation of allenes leading to the regioselective formation of functionalized allyl selenides.
Palladium-catalyzed regio- and stereoselective selenoacylation of allenes with selenol esters proceeded to produce functionalized allyl selenides with the acyl moiety at the inner carbon and the SePh group at the terminal carbon in high yields. A mechanism accounting for the observed regio- and stereoselectivities is proposed based on the results of DFT calculations.
Toyofuku
Masashi
M
Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.
Murase
Erika
E
Fujiwara
Shin-ichi
S
Shin-Ike
Tsutomu
T
Kuniyasu
Hitoshi
H
Kambe
Nobuaki
N