Use of chitosan for chromium removal from exhausted tanning baths.
A novel approach, based on chitosan heavy-metal sequestrating ability, is proposed for chromium(III) removal from spent tanning liquor. Experimental results, obtained at lab-scale using real wastewater, are presented and discussed. Resulting efficiencies are extremely high, and strongly dependent on chitosan dose and pH value. Comparative analyses with other polysaccharides is also carried out showing that amine groups are more efficient than carboxyl and sulphate ones. Chromium recovery from sorption complexes and chitosan regeneration is finally proposed to optimize the whole process.
Cesaro
Raffaele
R
Department of Hydraulic and Environmental Engineering Girolamo Ippolito, University of Naples Federico II, via Claudio 21, 80125 Naples, Italy.
Fabbricino
Massimiliano
M
Lanzetta
Rosa
R
Mancino
Anna
A
Naviglio
Biagio
B
Parrilli
Michelangelo
M
Sartorio
Roberto
R
Tomaselli
Michele
M
Tortora
Gelsomina
G
D001494:Baths; D048271:Chitosan / Q000737:chemistry*; D002857:Chromium / Q000737:chemistry / Q000302:isolation & purification*; D007220:Industrial Waste / Q000517:prevention & control; D012037:Refuse Disposal / Q000379:methods; D013633:Tanning
D007220:Industrial Waste; D002857:Chromium; D048271:Chitosan