title: C-C bond-forming desulfurizations of sulfoximines.
abstract: Highly substituted, enantiomerically pure azaheterocyclic ring systems play an important role in medicinal chemistry as potential peptide mimetics. Metalated 2-alkenyl sulfoximines offer an efficient entry to this class of compounds. In this paper, we describe a new means to remove the sulfonimidoyl auxiliary with concomitant formation of a C-C double bond.
authors: Clemens-Schöpf-Insitut für Organische Chemie and Biochemie, Petersenstrasse 22, Technische Universität, 64287 Darmstadt, Germany. re@punk.oc.chemie.tu-darmstadt.de
authors: M
authors: M
authors: Reggelin
authors: S
authors: S
authors: Slavik
authors: P
authors: P
authors: Bühle
mesh_terms: D002244:Carbon / Q000737:chemistry*; D008717:Methionine Sulfoximine / Q000031:analogs & derivatives* / Q000737:chemistry*; D013455:Sulfur / Q000737:chemistry*
chemical_list: D008717:Methionine Sulfoximine; D013455:Sulfur; D002244:Carbon