Synthesis of optically active boron-silicon bifunctional cyclopropane derivatives through enantioselective copper(I)-catalyzed reaction of allylic carbonates with a diboron derivative.
Ito
Hajime
H
Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060-0810, Japan. hajito@sci.hokudai.ac.jp
Kosaka
Yuki
Y
Nonoyama
Kousuke
K
Sasaki
Yusuke
Y
Sawamura
Masaya
M
D001896:Boron Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D002254:Carbonates / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D003521:Cyclopropanes / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D012825:Silicon / Q000737:chemistry*; D013237:Stereoisomerism
D001896:Boron Compounds; D002254:Carbonates; D003521:Cyclopropanes; D003300:Copper; C030797:cyclopropane; D012825:Silicon