title: Generation of nitrene by the photolysis of N-substituted iminodibenzothiophene.
abstract: To evaluate the ability of dibenzothiophene N-substituted sulfilimines as photochemical nitrene sources, their photolyses in the presence of several trapping reagents, such as sulfides, olefins, and phosphorus compounds, were performed. In the reactions, the corresponding imino-transfer compounds, namely sulfilimines, aziridines, and iminophosphoranes, were formed in good yields, indicating dibenzothiophene N-tosyl and N-acylsulfilimines have a potent nature as nitrogen sources.
authors: Department of Material Systems Engineering and Life Science, Faculty of Engineering, University of Toyama, 3190 Gofuku, Toyama 930-8555, Japan. morita@eng.u-toyama.ac.jp
authors: Hiroyuki
authors: H
authors: Morita
authors: Atsushi
authors: A
authors: Tatami
authors: Tetsuo
authors: T
authors: Maeda
authors: Byung Ju
authors: BJ
authors: Kim
authors: Wataru
authors: W
authors: Kawashima
authors: Toshiaki
authors: T
authors: Yoshimura
authors: Hitoshi
authors: H
authors: Abe
authors: Takeshi
authors: T
authors: Akasaka
mesh_terms: D001388:Aziridines / Q000138:chemical synthesis / Q000737:chemistry / Q000528:radiation effects; D007097:Imines / Q000138:chemical synthesis / Q000737:chemistry / Q000528:radiation effects*; D015394:Molecular Structure; D010753:Phosphoranes / Q000138:chemical synthesis / Q000737:chemistry / Q000528:radiation effects; D010777:Photochemistry; D010782:Photolysis; D013237:Stereoisomerism; D013876:Thiophenes / Q000737:chemistry* / Q000528:radiation effects*; D014466:Ultraviolet Rays
chemical_list: D001388:Aziridines; D007097:Imines; D010753:Phosphoranes; D013876:Thiophenes; C532722:iminodibenzothiophene; C017621:phenylnitrene