title: [(CyPF-(t)Bu)PdCl2]: an air-stable, one-component, highly efficient catalyst for amination of heteroaryl and aryl halides.
abstract: An air- and moisture-stable palladium catalyst, [(CyPF-(t)Bu)PdCl2] (1), for coupling of heteroaryl chlorides, bromides, and iodides with a variety of primary amines is described. Most of these reactions occurred in high yield with 0.001-0.05 mol % catalyst loading. The reactions tolerated a wide range of functional groups.
authors: Department of Chemistry, University of Illinois, 600 South Mathews Avenue, Urbana, Illinois 61801, USA.
authors: Qilong
authors: Q
authors: Shen
authors: John F
authors: JF
authors: Hartwig
mesh_terms: D000388:Air; D000586:Amination; D002384:Catalysis; D006219:Halogens / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*
chemical_list: D006219:Halogens; D009942:Organometallic Compounds; D010165:Palladium