title: Mechanistically inspired design of Fe(III)-TAML peroxide-activating catalysts.
abstract: Recent broad-ranging mechanistic studies of FeIII-TAML peroxide activators enable a strategy for designing catalysts with improved (i) hydrolytic and (ii) operational stabilities, (iii) faster activation of H2O2 and other peroxides, and (iv) a pH of highest activity closer to 7. Combining all items of insight leads to [Fe{1-NO2C6H3-3,4-(NCOCMe2NCO)2CF2}(OH2)]- (1a) which exhibits the most desirable technical performance in its class.
authors: Institute for Green Science, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213, USA.
authors: Delia-Laura
authors: DL
authors: Popescu
authors: Arani
authors: A
authors: Chanda
authors: Matthew J
authors: MJ
authors: Stadler
authors: Sujit
authors: S
authors: Mondal
authors: Jacqui
authors: J
authors: Tehranchi
authors: Alexander D
authors: AD
authors: Ryabov
authors: Terrence J
authors: TJ
authors: Collins
mesh_terms: D002384:Catalysis; D005290:Ferric Compounds / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D047029:Lactams, Macrocyclic / Q000737:chemistry*; D008958:Models, Molecular; D010545:Peroxides / Q000737:chemistry*
chemical_list: D005290:Ferric Compounds; D047029:Lactams, Macrocyclic; D010545:Peroxides; D006861:Hydrogen Peroxide