Synthesis and application of alkenylstannanes derived from base-sensitive cyclopropenes.
In the presence of stoichiometric potassium fluoride, a range of base-sensitive cyclopropenes undergo direct stannylation using (pentafluoroethyl)tributylstannane. The resulting stannylcyclopropenes serve as precursors to a variety of tetrasubstituted cyclopropenes that might otherwise be difficult to access using alternative methods.
Fordyce
Euan A F
EA
School of Chemistry, University of Edinburgh, The King's Buildings, West Mains Road, Edinburgh, EH9 3JJ, United Kingdom.
Luebbers
Thomas
T
Lam
Hon Wai
HW
D000475:Alkenes / Q000737:chemistry*; D003521:Cyclopropanes / Q000737:chemistry*; D013379:Substrate Specificity; D017971:Tin Compounds / Q000138:chemical synthesis* / Q000737:chemistry
D000475:Alkenes; D003521:Cyclopropanes; D017971:Tin Compounds; C031525:stannane; C021985:cyclopropene