Phosphite-derivatized ruthenium-carbohydrate complexes in the catalytic hydration of nitriles. short communication.
The synthesis of metal complexes with bioligands is one option to introduce chirally defined ligands to catalysts. Herein, the hydration of nitriles to the corresponding carboxamides by use of ruthenium(II) complexes is described, which were obtained by attaching derivatives of the 3,5,6-bicyclophosphite-alpha-D-glucofuranoside ligand.
Ashraf
Shaheen M
SM
University of Vienna, Institute of Inorganic Chemistry, Waehringer Strasse 42, A-1090 Vienna, (phone: +43-1-4277-52609; fax: +43-1-4277-52680).|Current Address: Department of Chemistry, University of Sargodha, Pakistan.
Berger
Isabella
I
University of Vienna, Institute of Inorganic Chemistry, Waehringer Strasse 42, A-1090 Vienna, (phone: +43-1-4277-52609; fax: +43-1-4277-52680).
Nazarov
Alexey A
AA
University of Vienna, Institute of Inorganic Chemistry, Waehringer Strasse 42, A-1090 Vienna, (phone: +43-1-4277-52609; fax: +43-1-4277-52680).|Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne.
Hartinger
Christian G
CG
University of Vienna, Institute of Inorganic Chemistry, Waehringer Strasse 42, A-1090 Vienna, (phone: +43-1-4277-52609; fax: +43-1-4277-52680).|Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne.
Koroteev
Mikhail P
MP
Chemistry Department, Moscow Pedagogical State University, Nesvizhskii per. 3, 119021 Moscow, Russia.
Nifant'ev
Eduard E
EE
Chemistry Department, Moscow Pedagogical State University, Nesvizhskii per. 3, 119021 Moscow, Russia.
Keppler
Bernhard K
BK
University of Vienna, Institute of Inorganic Chemistry, Waehringer Strasse 42, A-1090 Vienna, (phone: +43-1-4277-52609; fax: +43-1-4277-52680).
D000085:Acetates / Q000138:chemical synthesis / Q000737:chemistry; D000577:Amides / Q000138:chemical synthesis / Q000737:chemistry; D002241:Carbohydrates / Q000737:chemistry*; D002384:Catalysis; D005960:Glucosides / Q000737:chemistry*; D008024:Ligands; D008968:Molecular Conformation; D009570:Nitriles / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D017905:Phosphites / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D013237:Stereoisomerism; D014867:Water / Q000737:chemistry
D000085:Acetates; D000577:Amides; D002241:Carbohydrates; D005960:Glucosides; D008024:Ligands; D009570:Nitriles; D009942:Organometallic Compounds; D017905:Phosphites; D014867:Water; D012428:Ruthenium