title: Phosphite-derivatized ruthenium-carbohydrate complexes in the catalytic hydration of nitriles. short communication.
abstract: The synthesis of metal complexes with bioligands is one option to introduce chirally defined ligands to catalysts. Herein, the hydration of nitriles to the corresponding carboxamides by use of ruthenium(II) complexes is described, which were obtained by attaching derivatives of the 3,5,6-bicyclophosphite-alpha-D-glucofuranoside ligand.
authors: University of Vienna, Institute of Inorganic Chemistry, Waehringer Strasse 42, A-1090 Vienna, (phone: +43-1-4277-52609; fax: +43-1-4277-52680).|Current Address: Department of Chemistry, University of Sargodha, Pakistan.
authors: Shaheen M
authors: SM
authors: Ashraf
authors: University of Vienna, Institute of Inorganic Chemistry, Waehringer Strasse 42, A-1090 Vienna, (phone: +43-1-4277-52609; fax: +43-1-4277-52680).
authors: Isabella
authors: I
authors: Berger
authors: University of Vienna, Institute of Inorganic Chemistry, Waehringer Strasse 42, A-1090 Vienna, (phone: +43-1-4277-52609; fax: +43-1-4277-52680).|Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne.
authors: Alexey A
authors: AA
authors: Nazarov
authors: University of Vienna, Institute of Inorganic Chemistry, Waehringer Strasse 42, A-1090 Vienna, (phone: +43-1-4277-52609; fax: +43-1-4277-52680).|Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne.
authors: Christian G
authors: CG
authors: Hartinger
authors: Chemistry Department, Moscow Pedagogical State University, Nesvizhskii per. 3, 119021 Moscow, Russia.
authors: Mikhail P
authors: MP
authors: Koroteev
authors: Chemistry Department, Moscow Pedagogical State University, Nesvizhskii per. 3, 119021 Moscow, Russia.
authors: Eduard E
authors: EE
authors: Nifant'ev
authors: University of Vienna, Institute of Inorganic Chemistry, Waehringer Strasse 42, A-1090 Vienna, (phone: +43-1-4277-52609; fax: +43-1-4277-52680).
authors: Bernhard K
authors: BK
authors: Keppler
mesh_terms: D000085:Acetates / Q000138:chemical synthesis / Q000737:chemistry; D000577:Amides / Q000138:chemical synthesis / Q000737:chemistry; D002241:Carbohydrates / Q000737:chemistry*; D002384:Catalysis; D005960:Glucosides / Q000737:chemistry*; D008024:Ligands; D008968:Molecular Conformation; D009570:Nitriles / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D017905:Phosphites / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D013237:Stereoisomerism; D014867:Water / Q000737:chemistry
chemical_list: D000085:Acetates; D000577:Amides; D002241:Carbohydrates; D005960:Glucosides; D008024:Ligands; D009570:Nitriles; D009942:Organometallic Compounds; D017905:Phosphites; D014867:Water; D012428:Ruthenium