Matrix isolation and EPR spectroscopy of septet 3,5-difluoropyridyl-2,4,6-trinitrene.
Septet 3,5-difluoropyridyl-2,4,6-trinitrene along with quintet 2-azido-3,5-difluoropyridyl-4,6-dinitrene, quintet 4-azido-3,5-difluoropyridyl-2,6-dinitrene, triplet 2,6-diazido-3,5-difluoropyridyl-4-nitrene, and triplet 2,4-diazido-3,5-difluoropyridyl-6-nitrene have been obtained by photolysis of 2,4,6-triazido-3,5-difluoropyridine in solid argon at 4 K. The electronic and magnetic properties of the matrix-isolated nitrenes were studied using electron paramagnetic resonance (EPR) spectroscopy in combination with density functional theory (DFT) calculations. The fine-structure parameters of the nitrenes were determined with high accuracy from computer spectral simulations. All signals in the EPR spectra of the nitrenes randomly oriented in the solid phase were unambiguously assigned on the basis of eigenfield calculations of the Zeeman energy levels and angular dependencies of resonance fields from the direction of the applied magnetic field.
Chapyshev
Sergei V
SV
Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russia. chap@icp.ac.ru
Grote
Dirk
D
Finke
Christopher
C
Sander
Wolfram
W
D003198:Computer Simulation; D004578:Electron Spin Resonance Spectroscopy / Q000379:methods; D004583:Electrons; D007097:Imines / Q000737:chemistry* / Q000528:radiation effects; D008280:Magnetics; D008956:Models, Chemical; D015394:Molecular Structure; D010782:Photolysis; D011725:Pyridines / Q000737:chemistry* / Q000528:radiation effects; D014466:Ultraviolet Rays
C532717:3,5-difluoropyridyl-2,4,6-trinitrene; D007097:Imines; D011725:Pyridines