Biaryl phosphite-oxazolines from hydroxyl aminoacid derivatives: highly efficient modular ligands for Ir-catalyzed hydrogenation of alkenes.
High enantioselectivities and activities are achieved in the Ir-catalyzed hydrogenation of several unfunctionalized olefins using modular biaryl phosphite-oxazoline ligands from hydroxyl aminoacid derivatives; the presence of a biaryl phosphite group is crucial to this success.
Diéguez
Montserrat
M
Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, C/ Marcelli Domingo s/n, Tarragona, Spain. montserrat.dieguez@urv.cat
Mazuela
Javier
J
Pàmies
Oscar
O
Verendel
J Johan
JJ
Andersson
Pher G
PG
D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D007495:Iridium / Q000737:chemistry*; D008024:Ligands; D010080:Oxazoles / Q000737:chemistry*
D000475:Alkenes; D008024:Ligands; D010080:Oxazoles; D007495:Iridium