title: Formation of a coordinated 2-aminoethylidene ligand and its rearrangement by deprotonation into a phosphinoallyl ligand containing a pyrrolidin-2-yl ring.
abstract: The activation of 1,1-diphenyl-2-propyn-1-ol by the metallic fragment [(eta (5)-C 5Me 5)Ru(dippae)] (+) {dippae = 1,2-bis[(diisopropylphosphanyl)amino]ethane}, followed by dehydration, produces a cationic complex that, by deprotonation and rearrangement, leads to a neutral complex with a phosphinoallyl ligand containing a pyrrolidin-2-yl ring.
authors: Departamento de CMIM y Química Inorgánica, Facultad de Ciencias, Universidad de Cádiz, Campus del Río San Pedro, Puerto Real 11510, Spain.
authors: M Carmen
authors: MC
authors: Puerta
authors: Pedro
authors: P
authors: Valerga
authors: M Dolores
authors: MD
authors: Palacios