Phosphine-free palladium(II)-catalyzed arylation of naphthalene and benzene with aryl iodides.
A phosphine-free arylation of naphthalene and benzene with aryl iodides to give biaryls in moderate to good yields is carried out in the presence of catalytic Pd(OAc)2 and stoichiometric CF3CO2 Ag in TFE or/and TFA.
Qin
Chunxia
C
Department of Chemistry, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240, China.
Lu
Wenjun
W
D001554:Benzene / Q000737:chemistry*; D001713:Biphenyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D006847:Hydrocarbons, Iodinated / Q000737:chemistry*; D015394:Molecular Structure; D009281:Naphthalenes / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D010720:Phosphines; D013237:Stereoisomerism
D001713:Biphenyl Compounds; D006847:Hydrocarbons, Iodinated; D009281:Naphthalenes; D010720:Phosphines; C031721:naphthalene; D010165:Palladium; C044646:phosphine; D001554:Benzene