Negative differential mobility of weakly driven particles in models of glass formers.
We study the response of probe particles to weak constant driving in kinetically constrained models of glassy systems, and show that the probe's response can be nonmonotonic and give rise to negative differential mobility: increasing the applied force can reduce the probe's drift velocity in the force direction. Other significant nonlinear effects are also demonstrated, such as the enhancement with increasing force of the probe's fluctuations away from the average path, a phenomenon known in other contexts as giant diffusivity. We show that these results can be explained analytically by a continuous-time random walk approximation where there is decoupling between persistence and exchange times for local displacements of the probe. This decoupling is due to dynamic heterogeneity in the glassy system, which also leads to bimodal distributions of probe particle displacements. We discuss the relevance of our results to experiments.
Jack
Robert L
RL
Department of Chemistry, University of California, Berkeley, California 94720, USA.
Kelsey
David
D
Garrahan
Juan P
JP
Chandler
David
D