Preparation of azafullerene derivatives from fullerene-mixed peroxides and single crystal X-ray structures of azafulleroid and azafullerene.
Azafullerene was prepared by addition of hydroxylamine to a cage-opened fullerendione derivative and subsequent PCl5 induced rearrangement processes. X-ray structures were obtained for the azafullerene and its azafulleroid precursor.
Zhang
Gaihong
G
Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
Huang
Shaohua
S
Xiao
Zuo
Z
Chen
Quan
Q
Gan
Liangbing
L
Wang
Zheming
Z