Langmuir-Blodgett films of diazobenzene molecules.
Langmuir-Blodgett (LB) films from diazobenzene Sudan III have been investigated using surface potential measurements as a function of number of layers and deposition pressures, with the surface potential data being related to molecular dipole moments obtained from theoretical electronic structure calculations. The surface potential increased with the number of layers for SIII LB films, and then tended to saturate. Results from density functional theory (DFT) and UV-vis spectroscopy indicated that the increase is due to addition of layers with oriented molecular dipoles, with the saturation tendency being attributed to a decrease in the amount of material deposited in each layer. The surface potential increased with the surface pressure used for deposition, probably owing to a higher contribution from the vertical component of the dipole moment as a closer molecular packing, which is associated with decreasing conformational entropy, was reached.
Silva
Josmary R
JR
Instituto Universitário do Araguaia, Universidade Federal de Mato Grosso, 78698-000 Pontal do Araguaia, Mato Grosso, Brazil.
de Souza
Nara C
NC
Fernandes
Vânia C
VC
Homem-de-Mello
Paula
P
Oliveira
Osvaldo N
ON