Spirastrellolide B: the synthesis of southern (C9-C25) region.
A combination of "chiron" and "asymmetric" approaches is utilized to construct the southern (C 9-C 25) region of marine natural product spirastrellolide B. The key functionalities are derived from d-glucose and Sharpless asymmetric epoxidation and dihydroxylation.
Chandrasekhar
Srivari
S
Organic Division-I, Indian Institute of Chemical Technology, Hyderabad, India. srivaric@iict.res.in
Rambabu
Chegondi
C
Reddy
Annareddy Syamprasad
AS