Synthetic studies toward pectenotoxin 2. Part I. Stereocontrolled access to the C10-C22 fragment.
A highly stereocontrolled and efficient synthesis for a fully functionalized C 10-C 22 fragment of pectenotoxin 2 is described using a convergent sequence involving a stereoselective methylation of beta-hydroxyketone as a key step.
Aho
Jatta E
JE
Department of Chemistry, Helsinki University of Technology, POB 6100, FI-02015 TKK, Finland.
Salomäki
Elina
E
Rissanen
Kari
K
Pihko
Petri M
PM