title: Structural and spatial considerations in the N,N'-diacyl- and bis(alkoxycarbonyl)bispidinone series.
abstract: Diamidic and dicarbamic bispidinones show trans-cis isomerism, the relative population in solution of the cis form increasing with solvent polarity. The mutual proximity of the two amide functions in 4a has no impact on the barrier to isomerization. The system represents a peculiar case of planar chirality posing a challenge to its specification.
authors.affiliation: Department of Chemistry, Bar-Ilan University, Ramat-Gan 52900, Israel.
authors.forename: Shlomo
authors.initials: S
authors.lastname: Levinger
authors.forename: Yifat
authors.initials: Y
authors.lastname: Sharabi-Ronen
authors.forename: Alexander
authors.initials: A
authors.lastname: Mainfeld
authors.forename: Amnon
authors.initials: A
authors.lastname: Albeck