title: Seasonal and diurnal variation of PM2.5 apparent particle density in urban air in Augsburg, Germany.
abstract: The apparent particle density of particulate matter with aerodynamic diameter < 2.5 microm (rho2.5) was determined at an urban site in Augsburg, Germany and its correlation with chemical composition and meteorological conditions was investigated. rho2.5 showed strong day-to-day variation from 1.05 to 2.36 g cm(-3) (5 to 95% percentile), and nearly 64% of the daily variability could be explained by a multiple variable regression model. A minimum in the morning and afternoon (about 1.5 g cm(-3)), and a maximum (near 1.8 g cm(-3)) during midday was observed. The minima represent fresh primary aerosol emissions, which were related to traffic soot particles with low density due to their agglomerate structure, especially observed in the early morning hours of weekdays. The maximum is likely due to increased secondary particle production and the presence of more aged particles with the built-up of the convectively mixed boundary layer. rho2.5 has the potential to serve as a crude tracer for chemical composition and atmospheric processing and might play an important role when considering the associations between health effects and ambient particles.
authors.affiliation: Helmholtz Zentrum München, German Research Center for Environmental Health, Institute of Epidemiology, 85764 Neuherberg, Germany. mike.pitz@hs-augsburg.de
authors.forename: Mike
authors.initials: M
authors.lastname: Pitz
authors.forename: Otmar
authors.initials: O
authors.lastname: Schmid
authors.forename: Joachim
authors.initials: J
authors.lastname: Heinrich
authors.forename: Wolfram
authors.initials: W
authors.lastname: Birmili
authors.forename: Jüurgen
authors.initials: J
authors.lastname: Maguhn
authors.forename: Ralf
authors.initials: R
authors.lastname: Zimmermann
authors.forename: H Erich
authors.initials: HE
authors.lastname: Wichmann
authors.forename: Annette
authors.initials: A
authors.lastname: Peters
authors.forename: Josef
authors.initials: J
authors.lastname: Cyrys