Cu(I)-catalyzed asymmetric diamination of conjugated dienes.
A Cu(I)-catalyzed asymmetric diamination for a variety of conjugated dienes and a triene with encouraging ee's has been effectively achieved using (R)-DTBM-SEGPHOS as a chiral ligand and di- tert-butyldiaziridinone as the nitrogen source.
Du
Haifeng
H
Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA.
Zhao
Baoguo
B
Yuan
Weicheng
W
Shi
Yian
Y