A terminal borylene ruthenium complex: from B-H activation to reversible hydrogen release.
Starting from RuHCl(H2)(PCy3)2, a terminal ruthenium mesitylborylene complex was obtained via double B-H bond activation of mesitylborane and concomitant release of dihydrogen, such a process being remarkably reversible.
Alcaraz
Gilles
G
Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 04, France.
Helmstedt
Ulrike
U
Clot
Eric
E
Vendier
Laure
L
Sabo-Etienne
Sylviane
S