Facile oxy-functionalization of a nucleophilic metal alkyl with a cis-dioxo metal species via a (2+3) transition state.
Conley
Brian L
BL
Department of Chemistry, University of Southern California, Los Angeles, CA 90089, USA.
Ganesh
Somesh K
SK
Gonzales
Jason M
JM
Ess
Daniel H
DH
Nielsen
Robert J
RJ
Ziatdinov
Vadim R
VR
Oxgaard
Jonas
J
Goddard
William A
WA
Periana
Roy A
RA
D000473:Alkanes / Q000737:chemistry*; D006900:Hydroxylation; D009992:Osmium / Q000737:chemistry*; D009993:Osmium Tetroxide / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D014867:Water / Q000737:chemistry
D000473:Alkanes; D014867:Water; D009992:Osmium; D009993:Osmium Tetroxide; D010100:Oxygen