Effect of natural organic matter on the reduction of nitroaromatics by Fe(II) species.
Uncertainty still exists regarding the role(s) of natural organic matter in the reduction of chemicals in anoxic environments. This work studied the effect of Suwannee river humic acid (SRHA) on the reduction of nitrobenzenes in goethite suspensions by Fe(II) species. The pseudo-first-order rate constant for the reduction of p-cyanonitrobenzene (k(CNNB)) was different for the first 3 half-lives in systems where Fe(II)aq and dissolved SRHA were equilibrated in reverse orders with goethite in suspensions. k(CNNB) and the reduction capacity of the system having SRHA added after Fe(II)aq was equilibrated with goethite was lower than that of the system for which the components were added in the reverse order. SRHA decreased the reduction capacity of the former system by oxidizing and/or complexing the surface-associated Fe(II), Fe(II)(surf), and/or hindering the access of CNNB to Fe(II)(surf). The log k(CNNB) increased linearlywith increasing concentrations of Fe(II)aq, which decreased as a result of increasing concentrations of SRHA in the system. Different k(CNNB)'s were observed for systems in which Fe(II)aq was equilibrated with goethite/SRHA suspensions for 24 and 48 h, suggesting sorbed SRHA oxidized and/or complexed Fe(II)aq. Findings suggest the concentration of Fe(II)aq and accessible Fe(ll)(surf) will influence the reduction rates of nitroaromatics in anoxic environments.
Colón
Dalizza
D
National Exposure Research Laboratory, U.S. Environmental Protection Agency, 960 College Station Road, Athens, Georgia 30605-2720, USA. colon.dalizza@epa.gov
Weber
Eric J
EJ
Anderson
James L
JL
D005296:Ferrous Compounds / Q000737:chemistry*; D006812:Humic Substances; D017672:Nitrogen Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction
D005296:Ferrous Compounds; D006812:Humic Substances; D017672:Nitrogen Compounds