title: Novel 48-membered hexadecanuclear and 60-membered icosanuclear manganese metallamacrocycles.
abstract: Either an S 8 symmetrical 48-membered hexadecanuclear or an S 10 symmetrical 60-membered icosanuclear manganese metallamacrocycle was self-assembled using a manganese ion and a ditopic pentadentate ligand. This was either N-4-phenylbenzoylsalicylhydrazide (H 3pbshz) containing a rigid rod-shaped, bulky biphenyl residue as a terminal N-acyl group or N-3,3-diphenylpropionylsalicylhydrazide (H 3dppshz) containing a flexible beta-branched N-acyl group, but with two sterically bulky phenyl residues at the Cbeta position. The backbone of these metal-organic assemblies is a repeating unit consisting of a -[Mn-N-N-] link that extends to complete either the 48-membered cyclic structure involving 16 manganese(III) centers and 16 ditopic linker ligands or the 60-membered cyclic structure involving 20 manganese(III) centers and 20 ditopic linker ligands (depending on the ligand used). Even though the nuclearity of the metallamacrocycles was different, the successive manganese centers were in the same chiral sequence, ...(LambdaLambdaDeltaDelta)(LambdaLambdaDeltaDelta)....
authors.affiliation: Department of Chemistry and Applied Chemistry, College of Science and Technology, Hanyang University, Ansan, Kyunggi-do 426-791, Korea.
authors.forename: Wenlong
authors.initials: W
authors.lastname: Liu
authors.forename: Kyungjin
authors.initials: K
authors.lastname: Lee
authors.forename: Mira
authors.initials: M
authors.lastname: Park
authors.forename: Rohith P
authors.initials: RP
authors.lastname: John
authors.forename: Dohyun
authors.initials: D
authors.lastname: Moon
authors.forename: Yang
authors.initials: Y
authors.lastname: Zou
authors.forename: Xinfang
authors.initials: X
authors.lastname: Liu
authors.forename: Hyeong-Cheol
authors.initials: HC
authors.lastname: Ri
authors.forename: Ghyung Hwa
authors.initials: GH
authors.lastname: Kim
authors.forename: Myoung Soo
authors.initials: MS
authors.lastname: Lah