Asymmetric Pauson-Khand-type reaction mediated by Rh(I) catalyst at ambient temperature.
An efficient asymmetric PKR mediated by Rh(I) catalyst at ambient temperature was developed. The reaction utilizing a Rh(I) catalyst bearing a (R)-3,5-diMeC4H4-BINAP ligand at 18-20 degrees C under a reduced partial pressure of CO (0.1 atm) provided PKR products in high chemical yield as well as high enantioselectivity.
Kim
Dong Eun
DE
Department of Chemistry, Korea University, Seoul, 136-701, Korea.
Kim
In Su
IS
Ratovelomanana-Vidal
Virginie
V
Genêt
Jean-Pierre
JP
Jeong
Nakcheol
N