title: Interfacial colloidal crystallization via tunable hydrogel depletants.
abstract: We demonstrate an approach using temperature-dependent hydrogel depletants to thermoreversibly tune colloidal attraction and interfacial colloidal crystallization. Total internal reflection and video microscopy are used to measure temperature-dependent depletion potentials between approximately 2 microm silica colloids and surfaces as mediated by approximately 0.2 microm poly-N-isopropylacrylamide (PNIPAM) hydrogel particles. Measured depletion potentials are modeled using the Asakura-Oosawa theory while treating PNIPAM depletants as swellable hard spheres. Monte Carlo simulations using the measured potentials predict reversible, quasi-2D crystallization and melting at approximately 27 degrees C in quantitative agreement with video microscopy images of measured microstructures (i.e., radial distribution functions) over the temperature range of interest (20-29 degrees C). Additional measurements of short-time self-diffusivities display excellent agreement with predicted diffusivities by considering multibody hydrodynamic interactions and using a swellable hard sphere model for the PNIPAM solution viscosity. Our findings demonstrate the ability to quantitatively measure, model, and manipulate kT-scale depletion attraction and phase behavior as a means of formally engineering interfacial colloidal crystallization.
authors.affiliation: Department of Chemical Engineering, Texas A & M University, College Station, Texas 77843, USA.
authors.forename: Gregory E
authors.initials: GE
authors.lastname: Fernandes
authors.forename: Daniel J
authors.initials: DJ
authors.lastname: Beltran-Villegas
authors.forename: Michael A
authors.initials: MA
authors.lastname: Bevan