title: Ionisation of the zinc--iodine bond of alkylzinc iodides in dimethylformamide from theory and experiment.
authors.affiliation: Department of Chemistry, The University of Sheffield, Dainton Building, Sheffield, S3 7HF UK, Fax: (+44) 114 222 9303.
authors.forename: Lorenzo
authors.initials: L
authors.lastname: Caggiano
authors.affiliation: Department of Chemistry, The University of Sheffield, Dainton Building, Sheffield, S3 7HF UK, Fax: (+44) 114 222 9303.
authors.forename: Richard F W
authors.initials: RFW
authors.lastname: Jackson
authors.affiliation: Department of Chemistry, The University of Sheffield, Dainton Building, Sheffield, S3 7HF UK, Fax: (+44) 114 222 9303.
authors.forename: Anthony J H M
authors.initials: AJHM
authors.lastname: Meijer
authors.affiliation: Department of Chemistry, The University of Sheffield, Dainton Building, Sheffield, S3 7HF UK, Fax: (+44) 114 222 9303.
authors.forename: Barry T
authors.initials: BT
authors.lastname: Pickup
authors.affiliation: Department of Chemistry, The University of Sheffield, Dainton Building, Sheffield, S3 7HF UK, Fax: (+44) 114 222 9303.
authors.forename: Karl A
authors.initials: KA
authors.lastname: Wilkinson
references.citation: P. Knochel, R. D. Singer, Chem. Rev. 1993, 93, 2117-2188.
references.citation: P. Knochel, P. Jones in Organozinc Reagents: A Practical Approach, Oxford University Press, Oxford, 1999.
references.citation: H. P. Knoess, M. T. Furlong, M. J. Rozema, P. Knochel, J. Org. Chem. 1991, 56, 5974-5978.
references.citation: R. F. W. Jackson, I. Rilatt, P. J. Murray, Org. Biomol. Chem. 2004, 2, 110-113.
references.citation: R. F. W. Jackson, I. Rilatt, P. J. Murray, Chem. Commun. 2003, 1242-1243.
references.citation: A. J. Blake, J. Shannon, J. C. Stephens, S. Woodward, Chem. Eur. J. 2007, 13, 2462-2472.
references.citation: A. Cote, A. B. Charette, J. Am. Chem. Soc. 2008, 130, 2771-2772.
references.citation: R. Duddu, M. Eckhardt, M. Furlong, H. P. Knoess, S. Berger, P. Knochel, Tetrahedron 1994, 50, 2415-2432.
references.citation: I. Rilatt, L. Caggiano, R. F. W. Jackson, Synlett 2005, 2701-2719.
references.citation: C. S. Dexter, C. Hunter, R. F. W. Jackson, J. Elliott, J. Org. Chem. 2000, 65, 7417-7421.
references.citation: R. F. W. Jackson, R. J. Moore, C. S. Dexter, J. Elliot, C. E. Mowbray, J. Org. Chem. 1998, 63, 7875-7884.
references.citation: D. Bellus, B. Klingert, R. W. Lang, G. Rihs, J. Organomet. Chem. 1988, 339, 17-22.
references.citation: R. M. Fabicon, H. G. Richey, Organometallics 2001, 20, 4018-4023.
references.citation: S. Miertus, E. Scrocco, J. Tomasi, Chem. Phys. 1981, 55, 117-129.
references.citation: J. Tomasi, M. Persico, Chem. Rev. 1994, 94, 2027-2094.
references.citation: R. Cammi, J. Tomasi, J. Comput. Chem. 1995, 16, 1449-1458.
references.citation: V. B. Di Marco, G. G. Bombi, Mass Spectrom. Rev. 2006, 25, 347-379.
references.citation: N. G. Tsierkezos, D. Schroder, H. Schwarz, J. Phys. Chem. A 2003, 107, 9575-9581.
references.citation: W. Henderson, B. K. Nicholson, L. J. McCaffrey, Polyhedron 1998, 17, 4291-4313.
references.citation: M. Uchiyama, T. Furuyama, M. Kobayashi, Y. Matsumoto, K. Tanaka, J. Am. Chem. Soc. 2006, 128, 8404-8405.
references.citation: S. Sakamoto, T. Imamoto, K. Yamaguchi, Org. Lett. 2001, 3, 1793-1795.
references.citation: H. C. Brown, K. Murray, J. Am. Chem. Soc. 1959, 81, 4108-4109.
references.citation: H. C. Brown in Hydroboration, W. A. Benjamin, New York, 1962, p. 66.
references.citation: Gaussian 03 (Revision C.02), M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, J. A. Montgomery, Jr., T. Vreven, K. N. Kudin, J. C. Burant, J. M. Millam, S. S. Iyengar, J. Tomasi, V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega, G. A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, M. Klene, X. Li, J. E. Knox, H. P. Hratchian, J. B. Cross, V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, P. Y. Ayala, K. Morokuma, G. A. Voth, P. Salvador, J. J. Dannenberg, V. G. Zakrzewski, S. Dapprich, A. D. Daniels, M. C. Strain, O. Farkas, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. V. Ortiz, Q. Cui, A. G. Baboul, S. Clifford, J. Cioslowski, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, M. Challacombe, P. M. W. Gill, B. Johnson, W. Chen, M. W. Wong, C. Gonzalez, J. A. Pople, Gaussian, Inc., Wallingford, CT, 2004.
references.citation: A. D. Becke, J. Chem. Phys. 1993, 98, 5648-5652.
references.citation: S. F. Boys, F. Bernardi, Mol. Phys. 1970, 19, 553.