title: Pyrolysis of latex gloves in the presence of Y-zeolite.
abstract: In this study we have investigated the possibility of processing waste rubber gloves using pyrolysis. Y-zeolite catalyst was employed to upgrade the pyrolysis products to give higher yields of valuable aromatic compounds such as toluene and xylenes. The composition of the pyrolysis products was determined using gas chromatography with linked mass spectrometry (GC-MS), gas chromatograph equipped with a flame ionization detector (GC-FID), gas chromatograph fitted with dual thermal conductivity detectors (GC-TCD), and Fourier Transform Infra-Red Spectrometry (FT-IR). It was found that when rubber gloves were pyrolysed in the absence of a catalyst, the pyrolysis oil consisted mainly of limonene and oligomers of polyisoprene. When Y-zeolite was added to the reaction system, the yields of toluene, xylene, methylbenzenes, ethylbenzenes, and naphthalenes increased dramatically. The Y-zeolite also catalysed the decomposition of limonene, which was absent from the catalytic pyrolysis products. The presence of the Y-zeolite catalyst also increased the yield of hydrocarbon gases. The tests were carried out at both 380 degrees C and 480 degrees C and it was found that the higher reaction temperature led to increased yields of all the major compounds, both in the presence and absence of the Y-zeolite catalyst.
authors.affiliation: Energy and Environmental Technology Applied Research Group, Coventry University, Coventry CV1 5FB, UK. w.j.hall@hotmail.co.uk
authors.forename: William J
authors.initials: WJ
authors.lastname: Hall
authors.forename: Norasalwa
authors.initials: N
authors.lastname: Zakaria
authors.forename: Paul T
authors.initials: PT
authors.lastname: Williams
mesh_terms: D002384:Catalysis; D002849:Chromatography, Gas; D005932:Gloves, Surgical; D017745:Incineration; D007840:Latex; D013818:Thermogravimetry; D017641:Zeolites / Q000737:chemistry*
chemical_list: D007840:Latex; D017641:Zeolites