Kinetic and equilibrium studies on the removal of Cd2+ ions from water using polyacrylamide grafted rice (Oryza sativa) husk and (Tectona grandis) saw dust.
The increase in the use of heavy metals has resulted in an increased flux of metallic substances into the aquatic environment which poses a danger to human health. The present work relates to the removal of cadmium ions by treatment with polyacrylamide grafted rice (Oryza sativa) husk/saguan (Tectona grandis) saw dust. The drinking water guideline value recommended by WHO for cadmium is 0.005 ppm.The adsorbent has been prepared by treatment of rice husk/saw dust with acrylamide. Removal has been studied at various pH values for different times of contact and adsorbate concentrations and is found to be pH-dependent, maximum removal occurs at pH 9 and at a contact time of 180 min for both the adsorbents. The results were found to be consistent with both the Langmuir and Freundlich isotherm models. The value of n (rate constant) determined at pH 9 has been found to be 1 (within experimental limits). This is further substantiated by applying the Lagergren model. The intra-particle diffusion constants were determined by the Morris-Weber model. Continuous flow column studies have also been undertaken and the breakthrough characteristics were determined. Desorption has been affected with 0.5M HCl. The results suggest that both polyacrylamide grafted rice husk/saw dust can be used as efficient and cost effective adsorbents for cadmium ion removal.
Sharma
Neeta
N
Department of Chemical Engineering and Technology, Panjab University, Chandigarh 160014, India. neetachem@hotmail.com
Kaur
Kulwinder
K
Kaur
Sumanjit
S
D000180:Acrylic Resins; D000327:Adsorption; D002104:Cadmium / Q000302:isolation & purification*; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D012275:Oryza; D014873:Water Pollutants / Q000302:isolation & purification; D018508:Water Purification / Q000379:methods*; D000099166:Polyacrylamides
D000180:Acrylic Resins; D002104:Cadmium; D014873:Water Pollutants; D000099166:Polyacrylamides