title: Kinetics of sorption of lead on bed sediments of River Hindon, India.
abstract: A number of low cost waste sorbent have been used for removal of heavy metals, however, few studies have been carried out on the sorption process on riverbed sediments in their natural state of occurrence. Stream sediments adsorb certain solutes from streams, thereby significantly changing the solute composition, but little is known about quantitatively describing sorption phenomena and rates of these processes. In the present investigation, sorption of lead ions on river bed sediments of river Hindon, a tributary of river Yamuna, India has been studied to demonstrate the role of bed sediments in controlling metal pollution. The effect of various operating variables, viz., initial concentration, solution pH, sediment dose, contact time and particle size has been studied. The sorption of lead ions increased with respect to pH and sorbent dose and decreased with sorbent particle size. Two important geochemical phases, iron and manganese oxide, also play important role in the sorption process. The sorption data were analysed using Langmuir and Freundlich isotherm models to determine the mechanistic parameters related to the sorption process. Further, although lead ions have more affinity for the fine fraction of the sediment, but the overall contribution of coarser fraction to sorption is more as compared to clay and silt fraction. The kinetic data suggest that the sorption of lead on bed sediments is an endothermic process, which is spontaneous at low temperature. The uptake of lead is controlled by both bulk and intraparticle diffusion mechanism.
authors.affiliation: National Institute of Hydrology, Roorkee, 247 667, India. mks@nih.ernet.in
authors.forename: M K
authors.initials: MK
authors.lastname: Sharma
authors.forename: C K
authors.initials: CK
authors.lastname: Jain
authors.forename: D C
authors.initials: DC
authors.lastname: Singhal
authors.forename: V K
authors.initials: VK
authors.lastname: Choubey
mesh_terms: D004784:Environmental Monitoring; D019015:Geologic Sediments / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007194:India; D007700:Kinetics; D007854:Lead / Q000032:analysis*; D008956:Models, Chemical; D010316:Particle Size; D045483:Rivers / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D014874:Water Pollutants, Chemical; D007854:Lead
references.citation: J Hazard Mater. 2003 Feb 28;97(1-3):219-43
references.pmid: 12573840
references.citation: J Hazard Mater. 2004 Oct 18;114(1-3):231-9
references.pmid: 15511595
references.citation: Environ Monit Assess. 2006 Jan;112(1-3):255-70
references.pmid: 16404544
references.citation: J Hazard Mater. 2006 Oct 11;137(3):1263-70
references.pmid: 16725256