title: Asymmetric Pauson-Khand-type reaction mediated by Rh(I) catalyst at ambient temperature.
abstract: An efficient asymmetric PKR mediated by Rh(I) catalyst at ambient temperature was developed. The reaction utilizing a Rh(I) catalyst bearing a (R)-3,5-diMeC4H4-BINAP ligand at 18-20 degrees C under a reduced partial pressure of CO (0.1 atm) provided PKR products in high chemical yield as well as high enantioselectivity.
authors.affiliation: Department of Chemistry, Korea University, Seoul, 136-701, Korea.
authors.forename: Dong Eun
authors.initials: DE
authors.lastname: Kim
authors.forename: In Su
authors.initials: IS
authors.lastname: Kim
authors.forename: Virginie
authors.initials: V
authors.lastname: Ratovelomanana-Vidal
authors.forename: Jean-Pierre
authors.initials: JP
authors.lastname: Genêt
authors.forename: Nakcheol
authors.initials: N
authors.lastname: Jeong