A new series of dendrimers containing two ferrocenyl units and a Fréchet dendron around a triazine nucleus.
The preparation and characterization of a new series of dendrimers containing two identical aminoferrocenyl units and a Fréchet dendron around a triazine nucleus is described. A sizable degree of electronic communication between the two redox active ferrocenyl residues was detected in dichloromethane solution containing tetrabutylammonium tetra(pentafluorophenyl)borate as the supporting electrolyte. Binding of glutarimide via hydrogen bonding interactions to all the dendrimers was easily detected by using (1)H NMR spectroscopic and voltammetric techniques.
Xu
Dongmei
D
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Suzhou University, Suzhou 215123, Jiangsu, China.
Wang
Wei
W
Gesua
Daniel
D
Kaifer
Angel E
AE