title: TiO₂ supported over SBA-15: an efficient photocatalyst for the pesticide degradation using solar light.
abstract: Photocatalytic degradation and mineralization of pesticides are studied over TiO(2) supported mesoporous SBA-15 composite system using solar light. TiO(2) is immobilized over SBA-15 by solid sate dispersion method. The catalysts are characterized by XRD, surface area, UV-Vis diffused reflectance spectra, SEM and TEM. The detailed photocatalytic degradation studies are carried out over TiO(2), SBA-15 and different TiO(2) wt% supported SBA-15. The activity evaluation parameters such as catalyst amount, pH, and pollutant initial concentration are studied taking isoproturon as a model compound and established conditions for pesticide degradation. The optimum degradation is achieved over 10 wt% TiO(2)/SBA-15 within 30 min and the reaction is following pseudo-first order kinetics. The isoproturon mineralization is monitored with TOC reduction and it takes around 9h for disappearance. The commercial pesticide solutions containing imidacloprid and phosphamidon are also successfully degraded over these composites with the established conditions. The data indicates that 10 wt% TiO(2)/SBA-15 composite is an effective and highly active system for the pesticide degradations.
authors.affiliation: Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology, Hyderabad 500607, India.
authors.forename: M V
authors.initials: MV
authors.lastname: Phanikrishna Sharma
authors.forename: V
authors.initials: V
authors.lastname: Durga Kumari
authors.forename: M
authors.initials: M
authors.lastname: Subrahmanyam
mesh_terms: D002384:Catalysis; D052918:Environmental Restoration and Remediation / Q000379:methods*; D006863:Hydrogen-Ion Concentration; D010575:Pesticides / Q000032:analysis / Q000737:chemistry*; D010671:Phenylurea Compounds / Q000032:analysis / Q000737:chemistry; D055668:Photochemical Processes; D012822:Silicon Dioxide / Q000737:chemistry*; D013472:Sunlight; D014025:Titanium / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000737:chemistry*
chemical_list: D010575:Pesticides; D010671:Phenylurea Compounds; C509969:SBA-15; D014874:Water Pollutants, Chemical; C009495:titanium dioxide; C028904:isoproturon; D012822:Silicon Dioxide; D014025:Titanium