title: Determination of uranium, iron, copper, and nickel in rock and water samples by MEKC.
abstract: A micellar electrokinetic capillary chromatographic (MEKC) procedure has been developed for the separation and determination of dioxouranium (VI), iron(III), copper(II), and nickel(II) using bis(salicylaldehyde)propylenediimine (H2SA2Pn) as chelating reagent with a total run time of <3 min. Sodium dodecyl sulphate (SDS) was used as micellar medium at pH 8.1 with sodium tetraborate buffer (0.1 M). Uncoated fused silica capillary with effective length 38.8 cmx75 microm id was used with an applied voltage of 30 kV and photo-diode array detection at 228 nm. Linear calibrations were established within 0.045-1000 microg/mL of each element with detection limit within 15-122 ng/mL. The method was applied to the analysis of spring water and rock samples. The presence of uranium in rock and spring water samples was established within 1.58-1739.3 microg/g and 0.047-0.712 microg/mL with relative standard deviation within 0.9-2.1% and 1.3-2.6% respectively. Uranium ore and water samples were also assayed by the standard addition technique. Recovery of uranium was >98% with RSD up to 2.7%. Copper, nickel, and iron in their combined matrix were concurrently determined within RSD 0.6-3.6% (n=5) and the results obtained were compared with those of flame AAS.
authors.affiliation: High Tech Central Resource Laboratory, University of Sindh, Jamshoro, Pakistan. ma_mirza64@yahoo.com
authors.forename: Muhammad Aslam
authors.initials: MA
authors.lastname: Mirza
authors.forename: Muhammad Yar
authors.initials: MY
authors.lastname: Khuhawar
authors.forename: Rafee
authors.initials: R
authors.lastname: Arain
mesh_terms: D001881:Borates / Q000737:chemistry; D002138:Calibration; D020374:Chromatography, Micellar Electrokinetic Capillary / Q000295:instrumentation / Q000379:methods; D003300:Copper / Q000032:analysis*; D005618:Fresh Water / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007501:Iron / Q000032:analysis*; D008823:Micelles; D008903:Minerals / Q000737:chemistry*; D009532:Nickel / Q000032:analysis*; D010087:Oxides / Q000032:analysis*; D015203:Reproducibility of Results; D012967:Sodium Dodecyl Sulfate / Q000737:chemistry; D012997:Solvents / Q000737:chemistry; D013997:Time Factors; D014501:Uranium / Q000032:analysis*
chemical_list: D001881:Borates; D008823:Micelles; D008903:Minerals; D010087:Oxides; D012997:Solvents; C510902:dioxouranium(VI); D012967:Sodium Dodecyl Sulfate; D014501:Uranium; D003300:Copper; D009532:Nickel; D007501:Iron