Oxidative decarboxylative synthesis of 2-H-imidazolines from glyoxylic acid and 1,2-diamines.
A novel method to prepare 2-H-imidazolines from glyoxylic acid monohydrate and 1,2-diamines is described; the key reaction of this method is the oxidative decarboxylation of the 2-carboxy imidazolidines by NBS.
Murai
Kenichi
K
Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamada-oka, Suita, Osaka 565-0871, Japan.
Morishita
Maiko
M
Nakatani
Ryo
R
Fujioka
Hiromichi
H
Kita
Yasuyuki
Y
D002264:Carboxylic Acids / Q000737:chemistry*; D003959:Diamines / Q000737:chemistry*; D048288:Imidazolines / Q000138:chemical synthesis* / Q000737:chemistry; D010084:Oxidation-Reduction
D002264:Carboxylic Acids; D003959:Diamines; D048288:Imidazolines