Homogeneous Ni-P/Al(2)O(3) nanocomposite coatings from stable dispersions in electroless nickel baths.
The dispersion stability of aluminum oxide colloidal particles stabilized with comb-polyelectrolytes in an electroless nickel (EN) solution was studied under plating conditions (80-90 degrees C). The nanodispersions which were stable at room temperature for several weeks flocculate rapidly as the temperature approached approximately 65 degrees C. Hydrotropes such as propylene glycol and urea are found to induce stability under plating conditions. A dependency of the critical flocculation temperature (CFT) on additives, comb-polyelectrolyte polyether side chain, and particle morphology is found. The codeposition of stabilized and nonstabilized nanoparticle dispersions resulted in very different particle density and distribution in the composite coatings. Highly homogeneous Ni-P/alumina nanocomposite coatings plated from stabilized baths with up to 50 vol% particle incorporation have been demonstrated.
de Hazan
Yoram
Y
Laboratory for High Performance Ceramics, Empa, Swiss Federal Laboratories for Materials Testing and Research, Uberlandstrasse 129, Dübendorf, Switzerland. yoram.dehazan@empa.ch
Werner
Dennis
D
Z'graggen
Markus
M
Groteklaes
Michael
M
Graule
Thomas
T