Nanoparticles of iron(II) spin-crossover.
We report the synthesis of spin crossover 69 nm spherical nanoparticles of [Fe(NH2-trz)3](Br)2.3H2O.0.03(surfactant) (NH2trz = 4-amino-1,2,4-triazole, surfactant = Lauropal), prepared by the reverse micelle technique, which exhibit at room temperature a thermal hysteresis characterized by magnetic, diffuse reflectivity and Raman studies.
Forestier
Thibaut
T
ICMCB, CNRS, Université Bordeaux 1, 87 Av. Doc. A. Schweitzer, F-33608, Pessac, France.
Mornet
Stéphane
S
Daro
Nathalie
N
Nishihara
Taishi
T
Mouri
Shin-ichiro
S
Tanaka
Koichiro
K
Fouché
Olivier
O
Freysz
Eric
E
Létard
Jean-François
JF
D005296:Ferrous Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D008024:Ligands; D008280:Magnetics; D008823:Micelles; D046529:Microscopy, Electron, Transmission / Q000379:methods; D015394:Molecular Structure; D053758:Nanoparticles / Q000737:chemistry*; D010316:Particle Size; D011092:Polyethylene Glycols / Q000737:chemistry; D013059:Spectrum Analysis, Raman / Q000379:methods; D013499:Surface Properties; D013501:Surface-Active Agents / Q000138:chemical synthesis / Q000737:chemistry*; D013696:Temperature; D014230:Triazoles / Q000138:chemical synthesis / Q000737:chemistry*
D005296:Ferrous Compounds; D008024:Ligands; D008823:Micelles; D013501:Surface-Active Agents; D014230:Triazoles; D011092:Polyethylene Glycols; C533754:4-amino-1,2,4-triazole