Kagomé type extra-large microporous solid based on a paddle-wheel Cu2+ dimer.
A robust extra-large microporous coordination polymer with a Kagomé type structure was synthesized by carboxylate/amine multifunctional ligand with a Cu2+ cluster and the hexagonal 1D channels (approximately 15 A) showed type I and IV adsorption isotherms for gas molecules.
Horike
Satoshi
S
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
Hasegawa
Shinpei
S
Tanaka
Daisuke
D
Higuchi
Masakazu
M
Kitagawa
Susumu
S