title: Extraordinary circularly polarized luminescence activity exhibited by cesium tetrakis(3-heptafluoro-butylryl-(+)-camphorato) Eu(III) complexes in EtOH and CHCl3 solutions.
abstract: The largest CPL activity ever measured was observed for cesium tetrakis(3-heptafluoro-butylryl-(+)-camphorato) Eu(III) complexes in EtOH and CHCl3 solutions substantiating the stereospecific formation of chiral Delta-SAPR-(C4) configuration with the aid of Cs+...FC (fluorocarbon) interactions more clearly than the exciton CD spectra.
authors.affiliation: Department of Chemistry, San José State University, San José, California 95192-0101, USA.
authors.forename: Jamie L
authors.initials: JL
authors.lastname: Lunkley
authors.forename: Dai
authors.initials: D
authors.lastname: Shirotani
authors.forename: Kazuaki
authors.initials: K
authors.lastname: Yamanari
authors.forename: Sumio
authors.initials: S
authors.lastname: Kaizaki
authors.forename: Gilles
authors.initials: G
authors.lastname: Muller
mesh_terms: D002586:Cesium / Q000737:chemistry*; D002725:Chloroform / Q000737:chemistry*; D002942:Circular Dichroism / Q000379:methods; D000431:Ethanol / Q000737:chemistry*; D005063:Europium / Q000737:chemistry*; D049449:Luminescence; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D012996:Solutions / Q000737:chemistry
chemical_list: D009942:Organometallic Compounds; D012996:Solutions; D002586:Cesium; D000431:Ethanol; D005063:Europium; D002725:Chloroform