title: Temperature-triggered gate opening for gas adsorption in microporous manganese formate.
abstract: Microporous manganese formate shows temperature-triggered gate opening for nitrogen and argon adsorption, which is not due to a structural change of the framework but due to dynamic opening of the pore aperture and/or sufficient kinetic energy of the adsorbates to overcome a diffusion barrier above a critical temperature.
authors.affiliation: National Creative Research Initiative Center for Smart Supramolecules (CSS) and Department of Chemistry, Pohang University of Science and Technology (POSTECH), Pohang, 790-784, Korea. kkim@postech.ac.kr
authors.forename: Hyunuk
authors.initials: H
authors.lastname: Kim
authors.forename: Denis G
authors.initials: DG
authors.lastname: Samsonenko
authors.forename: Minyoung
authors.initials: M
authors.lastname: Yoon
authors.forename: Ji Woong
authors.initials: JW
authors.lastname: Yoon
authors.forename: Young Kyu
authors.initials: YK
authors.lastname: Hwang
authors.forename: Jong-San
authors.initials: JS
authors.lastname: Chang
authors.forename: Kimoon
authors.initials: K
authors.lastname: Kim
mesh_terms: D000327:Adsorption; D018360:Crystallography, X-Ray; D005561:Formates / Q000737:chemistry*; D005740:Gases / Q000737:chemistry; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D016062:Porosity; D013499:Surface Properties; D013696:Temperature
chemical_list: D005561:Formates; D005740:Gases; D009942:Organometallic Compounds; D008345:Manganese