Carborane-based metal-organic frameworks as highly selective sorbents for CO(2) over methane.
Separation of CO(2)/CH(4) mixtures was studied in carborane-based metal-organic framework materials with and without coordinatively unsaturated metal sites; high selectivities for CO(2) over CH(4) ( approximately 17) are obtained, especially in the material with open metal sites.
Bae
Youn-Sang
YS
Department of Chemical and Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA.
Farha
Omar K
OK
Spokoyny
Alexander M
AM
Mirkin
Chad A
CA
Hupp
Joseph T
JT
Snurr
Randall Q
RQ