title: Characterizing ammonia emissions from swine farms in eastern North Carolina: part 1--conventional lagoon and spray technology for waste treatment.
abstract: Ammonia (NH3) fluxes from waste treatment lagoons and barns at two conventional swine farms in eastern North Carolina were measured. The waste treatment lagoon data were analyzed to elucidate the temporal (seasonal and diurnal) variability and to derive regression relationships between NH3 flux and lagoon temperature, pH and ammonium content of the lagoon, and the most relevant meteorological parameters. NH3 fluxes were measured at various sampling locations on the lagoons by a flowthrough dynamic chamber system interfaced to an environmentally controlled mobile laboratory. Two sets of open-path Fourier transform infrared (FTIR) spectrometers were also used to measure NH3 concentrations for estimating NH3 emissions from the animal housing units (barns) at the lagoon and spray technology (LST) sites. Two different types of ventilation systems were used at the two farms. Moore farm used fan ventilation, and Stokes farm used natural ventilation. The early fall and winter season intensive measurement campaigns were conducted during September 9 to October 11, 2002 (lagoon temperature ranged from 21.2 to 33.6 degrees C) and January 6 to February 2, 2003 (lagoon temperature ranged from 1.7 to 12 degrees C), respectively. Significant differences in seasonal NH3 fluxes from the waste treatment lagoons were found at both farms. Typical diurnal variation of NH3 flux with its maximum value in the afternoon was observed during both experimental periods. Exponentially increasing flux with increasing surface lagoon temperature was observed, and a linear regression relationship between logarithm of NH3 flux and lagoon surface temperature (T1) was obtained. Correlations between lagoon NH3 flux and chemical parameters, such as pH, total Kjeldahl nitrogen (TKN), and total ammoniacal nitrogen (TAN) were found to be statistically insignificant or weak. In addition to lagoon surface temperature, the difference (D) between air temperature and the lagoon surface temperature was also found to influence the NH3 flux, especially when D > 0 (i.e., air hotter than lagoon). This hot-air effect is included in the statistical-observational model obtained in this study, which was used further in the companion study (Part II), to compare the emissions from potential environmental superior technologies to evaluate the effectiveness of each technology.
authors.affiliation: Department of Marine, Earth, and Atmospheric Sciences, North Carolina State University, Raleigh, NC 27695-8208, USA. viney_aneja@ncsu.edu
authors.forename: Viney P
authors.initials: VP
authors.lastname: Aneja
authors.forename: S Pal
authors.initials: SP
authors.lastname: Arya
authors.forename: D-S
authors.initials: DS
authors.lastname: Kim
authors.forename: Ian C
authors.initials: IC
authors.lastname: Rumsey
authors.forename: H L
authors.initials: HL
authors.lastname: Arkinson
authors.forename: H
authors.initials: H
authors.lastname: Semunegus
authors.forename: K S
authors.initials: KS
authors.lastname: Bajwa
authors.forename: D A
authors.initials: DA
authors.lastname: Dickey
authors.forename: L A
authors.initials: LA
authors.lastname: Stefanski
authors.forename: L
authors.initials: L
authors.lastname: Todd
authors.forename: K
authors.initials: K
authors.lastname: Mottus
authors.forename: W P
authors.initials: WP
authors.lastname: Robarge
authors.forename: C M
authors.initials: CM
authors.lastname: Williams
mesh_terms: D000383:Agriculture; D000395:Air Pollutants, Occupational / Q000032:analysis*; D000641:Ammonia / Q000032:analysis*; D000818:Animals; D004784:Environmental Monitoring; D009657:North Carolina; D013552:Swine / Q000502:physiology*; D014865:Waste Disposal, Fluid / Q000379:methods*
chemical_list: D000395:Air Pollutants, Occupational; D000641:Ammonia