Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo(11)V(7)}: [Mo(VI)(11)V(V)(5)V(IV)(2)O(52)(mu(9)-SO(3))](7-).
A polyoxomolybdenum/vanadium-sulfite {M(18)} cluster-based compound, [Mo(VI)(11)V(V)(5)V(IV)(2)O(52)(mu(9)-SO(3))](7-), is reported that exhibits a unique structural motif, arising from the incorporation of five V(V) and two V(IV) ions into a {M(18)} cluster framework templated by SO(3)(2-); this cluster compostion was first identified using cryospray mass spectrometry.
Miras
Haralampos N
HN
WestCHEM, Department of Chemistry, The University of Glasgow, Glasgow, Scotland, UK G12 8QQ.
Stone
Daniel J
DJ
McInnes
Eric J L
EJ
Raptis
Raphael G
RG
Baran
Peter
P
Chilas
George I
GI
Sigalas
Michael P
MP
Kabanos
Themistoklis A
TA
Cronin
Leroy
L