Spin canting in an unprecedented three-dimensional pyrophosphate- and 2,2'-bipyrimidine-bridged cobalt(II) framework.
The three-dimensional cobalt(ii) compound of formula {[Co(2)(P(2)O(7))(bpym)(2)].12H(2)O}(n), where the pyrophosphate and 2,2'-bipyrimidine act as bridging ligands, is a new example of a spin-canted antiferromagnet with T(c) = 19 K.
Marino
Nadia
N
Dipartimento di Chimica, Università della Calabria, via P. Bucci 14/c, Rende, Cosenza, Italy.
Mastropietro
Teresa F
TF
Armentano
Donatella
D
De Munno
Giovanni
G
Doyle
Robert P
RP
Lloret
Francesc
F
Julve
Miguel
M