Removal of tartrazine from aqueous solutions by strongly basic polystyrene anion exchange resins.
The removal of tartrazine from aqueous solutions onto the strongly basic polystyrene anion exchangers of type 1 (Amberlite IRA-900) and type 2 (Amberlite IRA-910) was investigated. The experimental data obtained at 100, 200, 300 and 500 mg/dm(3) initial concentrations at 20 degrees C were applied to the pseudo-first order, pseudo-second order and Weber-Morris kinetic models. The calculated sorption capacities (q(e,cal)) and the rate constant of the first order adsorption (k(1)) were determined. The pseudo-second order kinetic constants (k(2)) and capacities were calculated from the plots of t/q(t) vs. t, 1/q(t) vs. 1/t, 1/t vs. 1/q(t) and q(t)/t vs. q(t) for type 1, type 2, type 3 and type 4 of the pseudo-second order expression, respectively. The influence of phase contact time, solution pH and temperature on tartrazine removal was also discussed. The FTIR spectra of pure anion exchangers and those loaded with tartrazine were recorded, too.
Wawrzkiewicz
Monika
M
Department of Inorganic Chemistry, Maria Curie-Sklodowska University, Faculty of Chemistry, Lublin, M Sklodowska Sq 2, Poland. m.wawrzkiewicz@op.pl
Hubicki
Zbigniew
Z
D000327:Adsorption; D000837:Anion Exchange Resins / Q000737:chemistry*; D007700:Kinetics; D011137:Polystyrenes; D012996:Solutions; D017550:Spectroscopy, Fourier Transform Infrared; D013645:Tartrazine / Q000302:isolation & purification*; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*
D000837:Anion Exchange Resins; D011137:Polystyrenes; D012996:Solutions; D014874:Water Pollutants, Chemical; D013645:Tartrazine