Controlled generation of acentric and homochiral coordination compounds from a versatile asymmetric ligand 4-(1H-1,2,4-triazol-3-yl)-4H-1,2,4-triazole.
Luminescent acentric and homochiral coordination compounds, which possess new topological networks, multiple helical structures and NLO properties, have been generated through the control of a versatile asymmetric ligand as well as inorganic anions, and this suggests a new protocol for preparing acentric and chiral materials.
Zhang
Rui-Bo
RB
Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
Zhang
Jian
J
Li
Zhao-Ji
ZJ
Qin
Ye-Yan
YY
Cheng
Jian-Kai
JK
Yao
Yuan-Gen
YG
D008024:Ligands; D015394:Molecular Structure; D013237:Stereoisomerism; D014230:Triazoles / Q000737:chemistry*
D008024:Ligands; D014230:Triazoles