title: Adsorptive removal of Erythrosine dye onto activated low cost de-oiled mustard.
abstract: The present paper is aimed to investigate and develop cheap adsorption methods for colour removal from wastewater using waste material de-oiled mustard as adsorbent. De-oiled mustard, a biosorbent, was successfully utilized for removing a water-soluble xanthene dye, Erythrosine from wastewater. Kinetic studies of adsorption of Erythrosine at de-oiled mustard were carried out at 30 degrees C, using aqueous solutions with 5 x 10(-5)M concentration of Erythrosine. The adsorption process followed a pseudo-first order model. The equilibrium process can be well described by both Freundlich and Langmuir models, at 30, 40 and 50 degrees C. Free energy of adsorption (DeltaG degrees ), enthalpy (DeltaH degrees ), and entropy (DeltaS degrees ) changes were calculated to predict the nature of adsorption. The estimated values for DeltaG degrees were -12.81 x 10(3) and -12.57 x 10(3) over activated carbon and activated de-oiled mustard at 203 K (30 degrees C), indicate toward a spontaneous process. The positive value for DeltaH degrees indicates that the adsorption of Erythrosine dye to de-oiled mustard is an endothermic process.
authors.affiliation: Department of Environmental Chemistry, Jiwaji University, Gwalior, India. rajeevjain54@yahoo.co.in
authors.forename: Rajeev
authors.initials: R
authors.lastname: Jain
authors.forename: Shalini
authors.initials: S
authors.lastname: Sikarwar
mesh_terms: D000327:Adsorption; D004396:Coloring Agents / Q000302:isolation & purification; D004923:Erythrosine / Q000302:isolation & purification*; D007700:Kinetics; D008956:Models, Chemical; D009149:Mustard Plant / Q000737:chemistry*; D010938:Plant Oils / Q000737:chemistry*; D013696:Temperature; D013816:Thermodynamics
chemical_list: D004396:Coloring Agents; D010938:Plant Oils; D004923:Erythrosine; C027793:mustard oil