title: Four- and five-membered cobaltacycles by regioselective cyclometallation of benzyl sulfide derivatives via Co(v) intermediates.
abstract: C-H activation through the coordination of a benzyl sulfide anchoring group with a C-S bond cleavage at a Co(v) center constitutes a regiospecific access to four- and five-membered metallacycles under mild conditions.
authors.affiliation: Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Petersenstrasse 18, D-64287, Darmstadt, Germany. metallacycle@gmail.com
authors.forename: Robert
authors.initials: R
authors.lastname: Beck
authors.forename: Markus
authors.initials: M
authors.lastname: Frey
authors.forename: Sebnem
authors.initials: S
authors.lastname: Camadanli
authors.forename: Hans-Friedrich
authors.initials: HF
authors.lastname: Klein
mesh_terms: D001593:Benzyl Compounds / Q000737:chemistry*; D003035:Cobalt / Q000737:chemistry*; D018360:Crystallography, X-Ray; D003500:Cyclization; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D013237:Stereoisomerism; D013440:Sulfides / Q000737:chemistry*
chemical_list: D001593:Benzyl Compounds; D009942:Organometallic Compounds; D013440:Sulfides; D003035:Cobalt; C016367:benzyl sulfide