title: Origins of the double asymmetric induction on proline-catalyzed aldol reactions.
abstract: Computational studies to elucidate the origin of the double asymmetric induction on proline-catalyzed aldol reaction have been performed using HF/6-31G(d) calculations. The computed transition structures explain the experimental data obtained.
authors.affiliation: Instituto de Química Orgánica General, CSIC, Juan de la Cierva 3, 28006 Madrid, Spain.
authors.forename: Félix
authors.initials: F
authors.lastname: Calderón
authors.forename: Elisa G
authors.initials: EG
authors.lastname: Doyagüez
authors.forename: Paul Ha-Yeon
authors.initials: PH
authors.lastname: Cheong
authors.forename: Alfonso
authors.initials: A
authors.lastname: Fernández-Mayoralas
authors.forename: K N
authors.initials: KN
authors.lastname: Houk
mesh_terms: D000447:Aldehydes / Q000737:chemistry*; D002384:Catalysis; D007659:Ketones / Q000737:chemistry; D011392:Proline / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000447:Aldehydes; D007659:Ketones; C116609:3-hydroxybutanal; D011392:Proline