Ring-opening reactions of difluoro(methylene)cyclopropanes with halogens and amines.
The distal and proximal bond of difluoro(methylene)cyclopropanes (F2MCPs) could be cleaved, respectively, under different conditions to give the corresponding ring-opening products. The reaction mechanisms are discussed.
Hang
Xiao-Chun
XC
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032 China.
Chen
Qing-Yun
QY
Xiao
Ji-Chang
JC