title: Carborane-based metal-organic frameworks as highly selective sorbents for CO(2) over methane.
abstract: Separation of CO(2)/CH(4) mixtures was studied in carborane-based metal-organic framework materials with and without coordinatively unsaturated metal sites; high selectivities for CO(2) over CH(4) ( approximately 17) are obtained, especially in the material with open metal sites.
authors.affiliation: Department of Chemical and Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA.
authors.forename: Youn-Sang
authors.initials: YS
authors.lastname: Bae
authors.forename: Omar K
authors.initials: OK
authors.lastname: Farha
authors.forename: Alexander M
authors.initials: AM
authors.lastname: Spokoyny
authors.forename: Chad A
authors.initials: CA
authors.lastname: Mirkin
authors.forename: Joseph T
authors.initials: JT
authors.lastname: Hupp
authors.forename: Randall Q
authors.initials: RQ
authors.lastname: Snurr