GaCl3-assisted cyclization reactions in hypersilyl(trimethylsilyl)aminodichlorophosphine.
Hypersilyl(trimethylsilyl)aminodichlorophosphine, (hyp)N(SiMe3)PCl2, was treated with GaCl3, which resulted in the formation of an interesting novel bicycle, composed of a four-membered SiNP2 ring and a five-membered P2Ga2Cl ring. In the presence of Me3SiN3, the same reaction provided access to a cyclo-2-phospha-4-sila-1,3-diazenium tetrachlorogallate. The free chloro-cyclo-phosphasiladiazane was obtained by the addition of nucleophilic bases.
Villinger
Alexander
A
Abteilung Anorganische Chemie, Institut für Chemie, Universität Rostock, Albert-Einstein-Strasse 3a, 18059 Rostock, Germany.
Westenkirchner
Andrea
A
Wustrack
Ronald
R
Schulz
Axel
A