Synthesis of beta-D-arabinofuranosides: stereochemical differentiation between D- and L-enantiomers.
The glycosylation of 3,5-O-di-tert-butylsilylene-protected d-thioarabinofuranosides with a range of glycosyl acceptors using NIS/AgOTf as promoters proceeded in a stereoselective manner to give the corresponding beta-D-arabinofuranosides in high yields.
Wang
Yingxi
Y
Centre for Synthesis and Chemical Biology, UCD School of Chemistry and Chemical Biology, University College Dublin, Belfield, Dublin 4, Ireland.
Maguire-Boyle
Samuel
S
Dere
Ravindra T
RT
Zhu
Xiangming
X
D001089:Arabinose / Q000138:chemical synthesis* / Q000737:chemistry; D002240:Carbohydrate Sequence; D006031:Glycosylation; D013237:Stereoisomerism; D013379:Substrate Specificity
D001089:Arabinose