Temperature-triggered gate opening for gas adsorption in microporous manganese formate.
Microporous manganese formate shows temperature-triggered gate opening for nitrogen and argon adsorption, which is not due to a structural change of the framework but due to dynamic opening of the pore aperture and/or sufficient kinetic energy of the adsorbates to overcome a diffusion barrier above a critical temperature.
Kim
Hyunuk
H
National Creative Research Initiative Center for Smart Supramolecules (CSS) and Department of Chemistry, Pohang University of Science and Technology (POSTECH), Pohang, 790-784, Korea. kkim@postech.ac.kr
Samsonenko
Denis G
DG
Yoon
Minyoung
M
Yoon
Ji Woong
JW
Hwang
Young Kyu
YK
Chang
Jong-San
JS
Kim
Kimoon
K
D000327:Adsorption; D018360:Crystallography, X-Ray; D005561:Formates / Q000737:chemistry*; D005740:Gases / Q000737:chemistry; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D016062:Porosity; D013499:Surface Properties; D013696:Temperature
D005561:Formates; D005740:Gases; D009942:Organometallic Compounds; D008345:Manganese