Microporous vanadyl-arsenate with the template incorporated exhibiting sorption and catalytic properties.
(C(5)H(14)N(2))[(VO)(3)(AsO(4))(HAsO(4))(2)(OH)].3H(2)O behaves as a microporous organically templated compound, with reversible adsorption and desorption of N(2) at 77 K, and as an extremely efficient catalyst that catalyzes selective sulfoxide formation from organic sulfides, under mild conditions.
Berrocal
Teresa
T
Dpto. de Mineralogía y Petrología, Facultad de Ciencia y Tecnología, Universidad del País Vasco, Apdo. 644, Bilbao, 48080, Spain.
Mesa
José L
JL
Pizarro
José L
JL
Bazán
Begoña
B
Iglesias
Marta
M
Aguayo
Andrés T
AT
Arriortua
María I
MI
Rojo
Teófilo
T
D000327:Adsorption; D001149:Arsenates / Q000737:chemistry*; D002384:Catalysis; D008958:Models, Molecular; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D016062:Porosity; D012451:Safrole / Q000031:analogs & derivatives / Q000138:chemical synthesis / Q000737:chemistry; D013440:Sulfides / Q000737:chemistry; D013499:Surface Properties; D013997:Time Factors; D017968:Vanadium Compounds / Q000737:chemistry*
D001149:Arsenates; D009942:Organometallic Compounds; D013440:Sulfides; D017968:Vanadium Compounds; D009584:Nitrogen; C025657:arsenic acid; D012451:Safrole; C005746:sulfoxide