title: Compressibility of water in magma and the prediction of density crossovers in mantle differentiation.
abstract: Hydrous silicate melts appear to have greater compressibility relative to anhydrous melts of the same composition at low pressures (<2GPa); however, at higher pressures, this difference is greatly reduced and becomes very small at pressures above 5GPa. This implies that the pressure effect on the partial molar volume of water in silicate melt ( partial differentialV-H2O/ partial differentialP) is highly dependent on pressure regime. Thus, H2O can be thought of as the most compressible 'liquid oxide' component in silicate melt at low pressure, but at high pressure its compressibility resembles that of other liquid oxide components. A best-fit curve to the data on V-H2O from various studies allows calculation of hydrous melt compression curves relevant to high-pressure planetary differentiation. From these compression curves, crystal-liquid density crossovers are predicted for the mantles of the Earth and Mars. For the Earth, trapped dense hydrous melts may reside atop the 410km discontinuity, and, although not required to be hydrous, atop the core-mantle boundary (CMB), in accord with seismic observations of low-velocity zones in these regions. For Mars, a density crossover at the base of the upper mantle is predicted, which would produce a low-velocity zone at a depth of approximately 1200km. If perovskite is stable at the base of the Martian mantle, then density crossovers or trapped dense hydrous melts are unlikely to reside there, and long-lived, melt-induced, low-velocity regions atop the CMB are not predicted.
authors.affiliation: Department of Earth and Planetary Sciences, University of New Mexico, Albuquerque, NM 87131, USA. agee@unm.edu
authors.forename: Carl B
authors.initials: CB
authors.lastname: Agee
mesh_terms: D018534:Earth, Planet; D019419:Evolution, Planetary; D008903:Minerals; D011312:Pressure; D017640:Silicates; D014867:Water
chemical_list: D008903:Minerals; D017640:Silicates; D014867:Water