Ligand-mediated decarbonylation as an efficient synthetic method to Re(I) and Re(II) dicarbonyl complexes.
A novel synthetic method based on a ligand-mediated decarbonylation reaction of complexes of the common fac-[Re(CO)3]+ core efficiently yields Re(I) and Re(II) dicarbonyl species.
Zobi
Fabio
F
Institute of Inorganic Chemistry, University of Zürich, Winterturerstrasse 190, CH-8057 Zürich, Switzerland. fzobi@aci.uzh.ch
Spingler
Bernhard
B
Alberto
Roger
R