title: Mechanistic and kinetic insights into the thermally induced rearrangement of alpha-pinene.
abstract: The thermal rearrangement of alpha-pinene (1) is interesting from mechanistic as well as kinetic point of view. Carrier gas pyrolyses with 1 and its acyclic isomers ocimene (2) and alloocimene (3) were performed to investigate the thermal network of these hydrocarbons. Kinetic analysis of the major reaction steps allows for a deeper insight in the reaction mechanism. Thus it was possible to explain the racemization of 1, the formation of racemic limonene (4), and the absence of the primary pyrolysis product 2 in the reaction mixture resulting from thermal rearrangement of 1. Results supported the conclusion that the reactions starting with 1 involve biradical transition states.
authors.affiliation: Institute for Technical Chemistry and Environmental Chemistry, Friedrich-Schiller University Jena, Lessingstr. 12, D-07743 Jena, Germany. achim.stolle@uni-jena.de
authors.forename: Achim
authors.initials: A
authors.lastname: Stolle
authors.forename: Bernd
authors.initials: B
authors.lastname: Ondruschka
authors.forename: Matthias
authors.initials: M
authors.lastname: Findeisen