title: Probing the self-assembly of inorganic cluster architectures in solution with cryospray mass spectrometry: growth of polyoxomolybdate clusters and polymers mediated by silver(I) ions.
abstract: Cryospray mass spectrometry (CSI-MS) has been used to probe the mechanism of self-assembly of polyoxometalate clusters in solution. By using CSI-MS and electronic absorbance spectroscopy it was possible to monitor in real-time the self-assembly of polymeric chains based on [Ag 2Mo 8O 26] (2-) n building blocks. The role of the Ag (I) ion in the solution state rearrangement of molybdenum Lindqvist ({Mo 6}) into the silver-linked beta-octamolybdate ({Mo 8}) structure (( n-C 4H 9) 4N) 2 n [Ag 2Mo 8O 26] n ( 1) is revealed in unprecedented detail. A monoanionic series, in particular [AgMo m O 3 m+1 ] (-) where m = 2 to 4, and series involving mixed oxidation state polyoxomolybdate species, which illustrate the in-solution formation of the (Ag{Mo 8}Ag) building blocks, have been observed. CSI-MS detection of species with increasing metal nuclearity concomitant with increasing organic cation contribution supports the hypothesis that the organic cations used in the synthesis play an important structure-directing role in polyoxometalate (POM) growth in solution. A real-time decrease in [{Mo 6}] and associated increase in [{Mo 8}] have been observed using CSI-MS and electronic absorbance spectroscopy, and the rate of {Mo 6} interconversion to {Mo 8} was found to decrease on increasing the size of the countercation. This result can be attributed to the steric bulk of larger organic groups hindering {Mo 6} to {Mo 8} rearrangement and hindering the contact between silver cations and molybdenum anions.
authors.affiliation: Department of Chemistry, WestCHEM, The University of Glasgow, UK.
authors.forename: Elizabeth F
authors.initials: EF
authors.lastname: Wilson
authors.forename: Hamera
authors.initials: H
authors.lastname: Abbas
authors.forename: Bridgette J
authors.initials: BJ
authors.lastname: Duncombe
authors.forename: Carsten
authors.initials: C
authors.lastname: Streb
authors.forename: De-Liang
authors.initials: DL
authors.lastname: Long
authors.forename: Leroy
authors.initials: L
authors.lastname: Cronin