title: Pyrolysis of methyl tert-butyl ether (MTBE). 1. Experimental study with molecular-beam mass spectrometry and tunable synchrotron VUV photoionization.
abstract: An experimental study of methyl tert-butyl ether (MTBE) pyrolysis (3.72% MTBE in argon) has been performed at low pressure (267 Pa) within the temperature range from 700 to 1420 K. The pyrolysis process was detected with the tunable synchrotron vacuum ultraviolet (VUV) photoionization and molecular-beam mass spectrometry (MBMS). About thirty intermediates are identified from near-threshold measurements of photoionization mass spectrum and photoionization efficiency spectrum. Among them, H2, CO, CH4, CH3OH and C4H8 are the major pyrolysis products. The radicals such as methyl, methoxy, propargyl, allyl, C4H5 and C4H7 are detected. The isomers of pyrolysis products are identified as well, i.e., propyne and allene, 1,2,3-butatriene and vinylacetylene, isobutene and 1-butene, propanal and acetone. Furthermore, the mole fractions of the pyrolysis products have been evaluated under various temperatures. Meanwhile, the initial formation temperatures of different pyrolysis products can be obtained. This work is anticipated to present a new experimental method for pyrolysis study and help understand the pyrolysis and combustion chemistry of MTBE and other oxygenated fuels.
authors.affiliation: National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029, PR China.
authors.forename: Taichang
authors.initials: T
authors.lastname: Zhang
authors.forename: Jing
authors.initials: J
authors.lastname: Wang
authors.forename: Tao
authors.initials: T
authors.lastname: Yuan
authors.forename: Xin
authors.initials: X
authors.lastname: Hong
authors.forename: Lidong
authors.initials: L
authors.lastname: Zhang
authors.forename: Fei
authors.initials: F
authors.lastname: Qi
mesh_terms: D013058:Mass Spectrometry / Q000295:instrumentation / Q000379:methods*; D008738:Methyl Ethers / Q000737:chemistry* / Q000528:radiation effects*; D010777:Photochemistry; D011312:Pressure; D017356:Synchrotrons; D013696:Temperature; D014466:Ultraviolet Rays; D014618:Vacuum
chemical_list: D008738:Methyl Ethers; C043243:methyl tert-butyl ether