Photodegradation of rhodamine B under visible light by bimetal codoped TiO2 nanocrystals.
In the search for efficient photocatalysts working under visible light, we have investigated the effect of metal ions (Bi/Co, Fe/Co) codoping on the photocatalytic activity of TiO(2) prepared by stearic acid gel method. UV-vis spectra revealed that doped Co enhanced the absorbency of TiO(2) under visible light, and Bi/Co codoped TiO(2) showed higher absorbance than Fe/Co codoped TiO(2). The photoreaction based on the prepared samples for photodegradation of 20mg/l rhodamine B solution was examined. The results showed that Fe(0.1%)/Co(0.4%) codoped TiO(2) had the highest photoactivity among all as-prepared samples under visible light, though less absorbency of visible light, indicating that the photoactivity not only benefits from absorbency but also relates to the cooperative effect of the two dopants.
Wang
Zhuyi
Z
College of Chemistry, Jilin University, Changchun, China.
Chen
Cheng
C
Wu
Fengqing
F
Zou
Bo
B
Zhao
Meng
M
Wang
Jinxing
J
Feng
Caihui
C
D002384:Catalysis; D005456:Fluorescent Dyes / Q000528:radiation effects; D008027:Light; D008670:Metals; D053758:Nanoparticles; D055668:Photochemical Processes; D012235:Rhodamines / Q000528:radiation effects*; D014025:Titanium / Q000737:chemistry*
D005456:Fluorescent Dyes; D008670:Metals; D012235:Rhodamines; C009495:titanium dioxide; D014025:Titanium; C029773:rhodamine B