Highly stable dendritic trityl radicals as oxygen and pH probe.
Novel dendritic trityl radicals (DTR1 and DTR2) with a TAM radical core, PAMAM branching and carboxylate exterior surface exhibit high stability towards oxidoreductants as evidenced by their electrochemical and EPR properties, offering potential application as dual oxygen and pH probe.
Liu
Yangping
Y
Center for Biomedical EPR Spectroscopy and Imaging, The Davis Heart and Lung Research Institute, The Division of Cardiovascular Medicine, Department of Internal Medicine, College of Medicine, The Ohio State University, Columbus, OH 43210, USA.
Villamena
Frederick A
FA
Zweier
Jay L
JL
D050091:Dendrimers / Q000138:chemical synthesis / Q000737:chemistry*; D004563:Electrochemistry; D004566:Electrodes; D004578:Electron Spin Resonance Spectroscopy; D005609:Free Radicals / Q000138:chemical synthesis / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D015394:Molecular Structure; D010100:Oxygen / Q000032:analysis*; D013237:Stereoisomerism; D013438:Sulfhydryl Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D013499:Surface Properties; D014320:Triphenylmethyl Compounds / Q000138:chemical synthesis / Q000737:chemistry*
D050091:Dendrimers; D005609:Free Radicals; D013438:Sulfhydryl Compounds; D014320:Triphenylmethyl Compounds; D010100:Oxygen