Hydroxylamine as an oxygen nucleophile. Chemical evidence from its reaction with a phosphate triester.
The reaction of hydroxylamine with 2,4-dinitrophenyl diethyl phosphate gives the O-phosphorylated product, which is rapidly converted to hydrazine and nitrogen gas in the presence of the excess of hydroxylamine.
Kirby
Anthony J
AJ
University Chemical Laboratory, Cambridge, UK CB2 1EW. ajk1@cam.ac.uk
Souza
Bruno S
BS
Medeiros
Michelle
M
Priebe
Jacks P
JP
Manfredi
Alex M
AM
Nome
Faruk
F