Reactions of iridium hydride pincer complexes with dioxygen: new dioxygen complexes and reversible O2 binding.
The reaction of molecular oxygen with iridium pincer hydride complexes, ((tBu)PCP)Ir(H)(X) [(tBu)PCP = kappa(3)-C(6)H(3)(CH(2)P(t)Bu(2))(2), X = Ph, H, CCPh], results in O(2) induced reductive elimination and formation of the novel dioxygen complexes ((tBu)PCP)Ir(O(2))(n) [n = 1 (), 2 ()].
Bridget Williams
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Department of Chemistry, University of Washington, Box 351700, Seattle, Washington, 98195-1700, USA.
Kaminsky
Werner
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Mayer
James M
JM
Goldberg
Karen I
KI