Self-assembling squares with amino acid-decorated bipyridines: heterochiral self-sorting of dynamically interconverting diastereomers.
Heterochiral self-sorting into only one stereoisomer is observed when metallo-supramolecular squares self-assemble from amino acid-substituted, dynamically interconverting bipyridine stereoisomers and dpppM(OTf)(2) corners (M = Pd, Pt).
Rang
Alexander
A
Institut für Chemie und Biochemie der Freien Universität, Takustr. 3, D-14195, Berlin, Germany.
Nieger
Martin
M
Engeser
Marianne
M
Lützen
Arne
A
Schalley
Christoph A
CA
D000596:Amino Acids / Q000737:chemistry*; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy / Q000379:methods / Q000592:standards; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010165:Palladium / Q000737:chemistry; D010984:Platinum / Q000737:chemistry; D011725:Pyridines / Q000737:chemistry*; D012015:Reference Standards; D013237:Stereoisomerism
D000596:Amino Acids; D008024:Ligands; D009942:Organometallic Compounds; D011725:Pyridines; D010984:Platinum; D010165:Palladium