title: Continuous biosynthesis of biodiesel from waste cooking palm oil in a packed bed reactor: optimization using response surface methodology (RSM) and mass transfer studies.
abstract: This study aimed to develop an optimal continuous procedure of lipase-catalyzes transesterification of waste cooking palm oil in a packed bed reactor to investigate the possibility of large scale production further. Response surface methodology (RSM) based on central composite rotatable design (CCRD) was used to optimize the two important reaction variables packed bed height (cm) and substrate flow rate(ml/min) for the transesterification of waste cooking palm oil in a continuous packed bed reactor. The optimum condition for the transesterification of waste cooking palm oil was as follows: 10.53 cm packed bed height and 0.57 ml/min substrate flow rate. The optimum predicted fatty acid methyl ester (FAME) yield was 80.3% and the actual value was 79%. The above results shows that the RSM study based on CCRD is adaptable for FAME yield studied for the current transesterification system. The effect of mass transfer in the packed bed reactor has also been studied. Models for FAME yield have been developed for cases of reaction control and mass transfer control. The results showed very good agreement compatibility between mass transfer model and the experimental results obtained from immobilized lipase packed bed reactor operation, showing that in this case the FAME yield was mass transfer controlled.
authors.affiliation: School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, Seri Ampangan, 14300 Nibong Tebal, Pulau Pinang, Malaysia.
authors.forename: Siti Fatimah Abdul
authors.initials: SF
authors.lastname: Halim
authors.forename: Azlina Harun
authors.initials: AH
authors.lastname: Kamaruddin
authors.forename: W J N
authors.initials: WJ
authors.lastname: Fernando
mesh_terms: D000465:Algorithms; D001674:Bioelectric Energy Sources; D019149:Bioreactors; D002175:Candida / Q000201:enzymology*; D003198:Computer Simulation; D004800:Enzymes, Immobilized; D005511:Food Handling; D005656:Fungal Proteins; D005742:Gasoline; D007220:Industrial Waste / Q000517:prevention & control; D008049:Lipase / Q000737:chemistry*; D008954:Models, Biological; D000073878:Palm Oil; D010938:Plant Oils / Q000737:chemistry*; D011786:Quality Control
chemical_list: D004800:Enzymes, Immobilized; D005656:Fungal Proteins; D005742:Gasoline; D007220:Industrial Waste; D010938:Plant Oils; D000073878:Palm Oil; C093667:Novozyme 435; D008049:Lipase