Binary stacks of [CuC6F5]4 with arenes.
Formation of the first binary stacks of an intact organocopper aggregate with the arenes naphthalene and 2,2'-bithiophene is reported; crystallographic data suggest that the supramolecular assembly process is supported by Cu-pi, Cu-S, and perfluoroarene-arene pi-interactions.
Doshi
Ami
A
Department of Chemistry, Rutgers University-Newark, 73 Warren Street, Newark, NJ 07102, USA.
Venkatasubbaiah
Krishnan
K
Rheingold
Arnold L
AL
Jäkle
Frieder
F
D047250:Calixarenes / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D046911:Macromolecular Substances / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009281:Naphthalenes / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D013876:Thiophenes / Q000737:chemistry*
D046911:Macromolecular Substances; D009281:Naphthalenes; D009942:Organometallic Compounds; D013876:Thiophenes; D047250:Calixarenes; C031721:naphthalene; D003300:Copper