title: Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo(11)V(7)}: [Mo(VI)(11)V(V)(5)V(IV)(2)O(52)(mu(9)-SO(3))](7-).
abstract: A polyoxomolybdenum/vanadium-sulfite {M(18)} cluster-based compound, [Mo(VI)(11)V(V)(5)V(IV)(2)O(52)(mu(9)-SO(3))](7-), is reported that exhibits a unique structural motif, arising from the incorporation of five V(V) and two V(IV) ions into a {M(18)} cluster framework templated by SO(3)(2-); this cluster compostion was first identified using cryospray mass spectrometry.
authors.affiliation: WestCHEM, Department of Chemistry, The University of Glasgow, Glasgow, Scotland, UK G12 8QQ.
authors.forename: Haralampos N
authors.initials: HN
authors.lastname: Miras
authors.forename: Daniel J
authors.initials: DJ
authors.lastname: Stone
authors.forename: Eric J L
authors.initials: EJ
authors.lastname: McInnes
authors.forename: Raphael G
authors.initials: RG
authors.lastname: Raptis
authors.forename: Peter
authors.initials: P
authors.lastname: Baran
authors.forename: George I
authors.initials: GI
authors.lastname: Chilas
authors.forename: Michael P
authors.initials: MP
authors.lastname: Sigalas
authors.forename: Themistoklis A
authors.initials: TA
authors.lastname: Kabanos
authors.forename: Leroy
authors.initials: L
authors.lastname: Cronin