Cyclopropenyllithiums as a new source of 1,1-bismetalated cyclopropyl derivatives.
The allylmetalation of functionalised cyclopropenyllithium derivatives leads to the unique formation of 1,1-bismetalated cyclopropyl species that react selectively with different electrophiles.
Levin
Anat
A
The Mallat Family Laboratory of Organic Chemistry, Schulich Faculty of Chemistry, Technion-Israel Institute of Technology, Haifa, 32000, Israel.
Marek
Ilan
I
D003521:Cyclopropanes / Q000138:chemical synthesis* / Q000737:chemistry*; D008094:Lithium / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D013237:Stereoisomerism
D003521:Cyclopropanes; D009942:Organometallic Compounds; D008094:Lithium