title: Determination of the rate of a fast exchanging coordinated molecule in a lanthanide(III) complex by proton NMR.
abstract: An elementary procedure is proposed and applied to study the exchange rate of a solvent or solute molecule bound to a complexed paramagnetic Ln(III) ion, other than Gd(III), from the measured longitudinal and transverse relaxation rates and paramagnetic resonance frequency shift at a given temperature.
authors.affiliation: Laboratoire de Reconnaissance Ionique et de Chimie de Coordination, INAC/SCIB (UMR_E 3 CEA-UJF), CEA-Grenoble, Grenoble Cedex 9, France. pascal-h.fries@cea.fr
authors.forename: Pascal H
authors.initials: PH
authors.lastname: Fries
authors.forename: Marion
authors.initials: M
authors.lastname: Giraud
authors.forename: Elie
authors.initials: E
authors.lastname: Belorizky