title: Axial 4,4',6,6'-tetrakis-trifluoromethyl-biphenyl-2,2'-diamine (TF-BIPHAM): resolution and applications in asymmetric hydrogenation.
abstract: The racemic TF-BIPHAM was resolved for the first time, and the effectiveness of the resolved diamine was demonstrated by highly enantioselective hydrogenation of alpha-aryl enamides and alpha-dehydroamino acid esters using readily accessible bis(aminophosphine) ligands.
authors.affiliation: College of Chemistry and Molecular Sciences, Wuhan University, 430072, China. cjwang@whu.edu.cn
authors.forename: Chun-Jiang
authors.initials: CJ
authors.lastname: Wang
authors.forename: Feng
authors.initials: F
authors.lastname: Gao
authors.forename: Gang
authors.initials: G
authors.lastname: Liang