Unusual temperature dependence of salt effects for "on water" Wittig reaction: hydrophobicity at the interface.
An unusual variation with temperature of the salt effects in aqueous Wittig reaction is observed, suggesting that hydrophobic acceleration of reactions comprising "on water" reactants is fundamentally different from that for reactions with small non-polar solutes.
Tiwari
Shraeddha
S
Physical Chemistry Division, National Chemical Laboratory, Pune, India 411008.
Kumar
Anil
A