title: Microporous vanadyl-arsenate with the template incorporated exhibiting sorption and catalytic properties.
abstract: (C(5)H(14)N(2))[(VO)(3)(AsO(4))(HAsO(4))(2)(OH)].3H(2)O behaves as a microporous organically templated compound, with reversible adsorption and desorption of N(2) at 77 K, and as an extremely efficient catalyst that catalyzes selective sulfoxide formation from organic sulfides, under mild conditions.
authors.affiliation: Dpto. de Mineralogía y Petrología, Facultad de Ciencia y Tecnología, Universidad del País Vasco, Apdo. 644, Bilbao, 48080, Spain.
authors.forename: Teresa
authors.initials: T
authors.lastname: Berrocal
authors.forename: José L
authors.initials: JL
authors.lastname: Mesa
authors.forename: José L
authors.initials: JL
authors.lastname: Pizarro
authors.forename: Begoña
authors.initials: B
authors.lastname: Bazán
authors.forename: Marta
authors.initials: M
authors.lastname: Iglesias
authors.forename: Andrés T
authors.initials: AT
authors.lastname: Aguayo
authors.forename: María I
authors.initials: MI
authors.lastname: Arriortua
authors.forename: Teófilo
authors.initials: T
authors.lastname: Rojo
mesh_terms: D000327:Adsorption; D001149:Arsenates / Q000737:chemistry*; D002384:Catalysis; D008958:Models, Molecular; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D016062:Porosity; D012451:Safrole / Q000031:analogs & derivatives / Q000138:chemical synthesis / Q000737:chemistry; D013440:Sulfides / Q000737:chemistry; D013499:Surface Properties; D013997:Time Factors; D017968:Vanadium Compounds / Q000737:chemistry*
chemical_list: D001149:Arsenates; D009942:Organometallic Compounds; D013440:Sulfides; D017968:Vanadium Compounds; D009584:Nitrogen; C025657:arsenic acid; D012451:Safrole; C005746:sulfoxide