title: Magnetic spongelike behavior of 3D ferrimagnetic {[Mn(II)(imH)]2[Nb(IV)(CN)8]}n with Tc = 62 K.
abstract: Fully reversible room temperature dehydration of 3D {Mn(II)2(imH)2(H2O)4[Nb(IV)(CN)8] x 4 H2O}n (1; imH = imidazole) of Tc = 25 K results in the formation of 3D ferrimagnet {[Mn(II)(imH)]2[Nb(IV)(CN)8]}n (2), with Tc = 62 K, the highest ever known for octacyanometalate-based compounds. The dramatic magnetostructural modifications in 2 provide the first example of magnetic spongelike behavior in an octacyanometallate-based assembly.
authors.affiliation: Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Kraków, Poland. pinkowic@chemia.uj.edu.pl
authors.forename: Dawid
authors.initials: D
authors.lastname: Pinkowicz
authors.forename: Robert
authors.initials: R
authors.lastname: Podgajny
authors.forename: Maria
authors.initials: M
authors.lastname: Bałanda
authors.forename: Magdalena
authors.initials: M
authors.lastname: Makarewicz
authors.forename: Bartłomiej
authors.initials: B
authors.lastname: Gaweł
authors.forename: Wiesław
authors.initials: W
authors.lastname: Łasocha
authors.forename: Barbara
authors.initials: B
authors.lastname: Sieklucka