A heterometallic, heterovalent Cu(I)/Sn(II/IV)/S cluster with an unprecedented Cu4Sn core and stannacyclopentane units.
[(Ph3PCu(I))6{(CH2)4Sn(IV)S2}6Cu(I)4Sn(II)], a walnut-type, heterometallic, heterovalent cluster, as confirmed by density functional theory calculations, was obtained under reductive solvothermal conditions and features an unprecedented metalloid core within a metal sulfide shell and an organic surface.
Nayek
Hari Pada
HP
Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse, D-35043 Marburg, Germany.
Massa
Werner
W
Dehnen
Stefanie
S