Structural studies in aqueous solution of new binuclear lanthanide luminescent peptide conjugates.
The synthesis, NMR and luminescent analysis of a novel polypeptide possessing a sensitising naphthalimide antenna at the amino terminus, and a model compound with a Trp moiety, and their Eu(iii) and Tb(iii) complexes are described.
Bonnet
Célia S
CS
Centre for Synthesis and Chemical Biology, Trinity College Dublin, Dublin 2, Ireland. gunnlaut@tcd.ie
Devocelle
Marc
M
Gunnlaugsson
Thorfinnur
T
D000042:Absorption; D000595:Amino Acid Sequence; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D049449:Luminescence; D009682:Magnetic Resonance Spectroscopy; D010455:Peptides / Q000138:chemical synthesis / Q000737:chemistry*; D012996:Solutions; D013050:Spectrometry, Fluorescence; D014867:Water / Q000737:chemistry*
D028581:Lanthanoid Series Elements; D010455:Peptides; D012996:Solutions; D014867:Water