title: Regio- and chemoselective magnesiation of protected uracils and thiouracils using TMPMgCl x LiCl and TMP(2)Mg x 2 LiCl.
abstract: Two successive regio- and chemoselective magnesiations using TMPMgCl x LiCl and TMP(2)Mg x 2 LiCl enable the full functionalization of protected uracils and thiouracils in good to excellent yields.
authors.affiliation: Department Chemie, Ludwig-Maximilians-Universität München, Butenandstr. 5-13, Haus F, 81377, München, Germany.
authors.forename: Marc
authors.initials: M
authors.lastname: Mosrin
authors.forename: Nadège
authors.initials: N
authors.lastname: Boudet
authors.forename: Paul
authors.initials: P
authors.lastname: Knochel
mesh_terms: D008274:Magnesium / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D013237:Stereoisomerism; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D013889:Thiouracil / Q000737:chemistry*; D014498:Uracil / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; D013438:Sulfhydryl Compounds; D014498:Uracil; D013889:Thiouracil; D008274:Magnesium