The role of short-range diffusion in solvent-assisted mechanochemical synthesis of metal complexes.
The role of short-range diffusion in solvent-assisted mechanochemical synthesis is demonstrated in studies of a polymorphic transition and a ligand dissociation reaction involving copper(I) thiocyanate complexes.
Bowmaker
Graham A
GA
Department of Chemistry, University of Auckland, Private Bag 92019, Auckland, New Zealand. ga.bowmaker@auckland.ac.nz
Hanna
John V
JV
Hart
Robert D
RD
Skelton
Brian W
BW
White
Allan H
AH
D002621:Chemistry / Q000379:methods; D003300:Copper / Q000737:chemistry; D004058:Diffusion; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D008670:Metals / Q000737:chemistry*; D008968:Molecular Conformation; D015394:Molecular Structure; D012997:Solvents / Q000737:chemistry*; D013055:Spectrophotometry, Infrared / Q000379:methods; D013499:Surface Properties; D013861:Thiocyanates / Q000737:chemistry
D008024:Ligands; D008670:Metals; D012997:Solvents; D013861:Thiocyanates; D003300:Copper; C028631:cuprous thiocyanate