From dioxime oxalates to dihydropyrroles and phenanthridines via iminyl radicals.
Dioxime oxalates are useful precursors for the clean generation of iminyl radicals by sensitised UV photolysis and can be adapted for serviceable preparations of 3,4-dihydro-2H-pyrroles and phenanthridines.
Portela-Cubillo
Fernando
F
University of St. Andrew, School of Chemistry, Fife, UK KY 16 9ST.
Scanlan
Eoin M
EM
Scott
Jackie S
JS
Walton
John C
JC
D004578:Electron Spin Resonance Spectroscopy; D005609:Free Radicals; D007097:Imines / Q000737:chemistry*; D010070:Oxalates / Q000737:chemistry*; D010617:Phenanthridines / Q000737:chemistry*; D011758:Pyrroles / Q000737:chemistry*
D005609:Free Radicals; D007097:Imines; D010070:Oxalates; D010617:Phenanthridines; D011758:Pyrroles; C013231:pyrroline