[Effect of concomitant substances and addition order on the adsorption of Tween 80 on sand].
Adsorption of Tween 80 on sand was investigated, and the effect of inorganic salts (CaCl2), anionic surfactant (SDS) and lignosulphonates (sodium lignosulphonate or ammonium lignosulphonate) on the adsorption of Tween 80 on sand were evaluated at 25 degrees C. The results show that saturated adsorption amount of Tween 80 on sand enhance when CaCl2 or SDS is added into flushing solution of Tween 80. And the adsorption of Tween 80 on sand increase with the increase of molar fraction of CaCl2 or SDS in mixed flushing solution. And adsorption amount of Tween 80 on sand also enhance when SDS is added into sand firstly. The effects of mixing ratios and addition order of lignosulphonates on adsorption of Tween 80 were considered. The results show that with the increase of molar fraction of lignosulphonates in mixing flushing solution, adsorption amount of Tween 80 on sand decrease. The adsorption amount of Tween 80 reduce 20%-75% due to the exist of ammonium lignosulphonate is superior to sodium lignosulphonate (10%-60%) when mix the lignosulphonates-Tween 80 at the total mass ratios of 1:10, while the adsorption amount of Tween 80 reduce 70%-90% at the total mass ratios of 1:2. Lignosulphonates added into sand firstly is more efficient than that together. Therefore,use of lignosulphonates as a preflush can reduce the adsorption of surfactants on sand and is a better method to applied in in situ flushing.
College of Environment and Resource, Jilin University, Changchun 130026, China. xuweimeibanfa@163.com
Wei
W
Xu
Yong-sheng
YS
Zhao
Sui
S
Li
Ning
N
Dai
D000327:Adsorption; D000838:Anions / Q000737:chemistry; D002122:Calcium Chloride / Q000737:chemistry*; D008031:Lignin / Q000031:analogs & derivatives / Q000737:chemistry; D011136:Polysorbates / Q000737:chemistry*; D012822:Silicon Dioxide; D012989:Soil Pollutants / Q000737:chemistry*; D013501:Surface-Active Agents / Q000737:chemistry*; D018505:Waste Management / Q000379:methods
D000838:Anions; D011136:Polysorbates; D012989:Soil Pollutants; D013501:Surface-Active Agents; D012822:Silicon Dioxide; C001545:lignosulfuric acid; D008031:Lignin; D002122:Calcium Chloride