Carboxylic multi-walled carbon nanotubes as immobilized stationary phase in capillary electrochromatography.
Carboxylic multi-walled carbon nanotubes (c-MWNT) have been immobilized into a fused-silica capillary for capillary electrochromatography. The c-MWNT were successfully incorporated after the silanization and coupling with glutaraldehyde on the inner surface of the capillary. The electrochromatographic features of the c-MWNT immobilized stationary phase have been evaluated for the analysis of different compounds of pharmaceutical interest. The results indicated high electrochromatographic resolution, good capillary efficiency and retention factors. In addition, highly reproducible results between runs, days and capillaries were obtained.
Department of Analytical Chemistry, University of Córdoba, Córdoba, Spain.
Lorena
L
Sombra
Yolanda
Y
Moliner-Martínez
Soledad
S
Cárdenas
Miguel
M
Valcárcel
D053801:Capillary Electrochromatography / Q000295:instrumentation* / Q000379:methods; D019075:Electrophoresis, Capillary / Q000379:methods; D037742:Nanotubes, Carbon / Q000737:chemistry*; D015203:Reproducibility of Results; D012821:Silanes / Q000737:chemistry
D037742:Nanotubes, Carbon; D012821:Silanes