[Micro-FTIR study on structure of macerals from Jurassic coals in Northwestern China].
Jurassic coal in Northwest China is rich in resources and it is a necessary premise to reveal the chemical structure characteristics of the coal macerals in this region before the coal is put into reasonable and efficient use. Micro-FTIR technique was used to investigate the chemical composition and structures of vitrinite semifusinite and fusinite from Jurassic coal in Northwestern China. The results show that vitrinite and semifusinite have more aliphatic hydrogen, but fusinite has more aromatic hydrogen and C=O structure. The aliphatic hydrogen in semifusinite is higher than that in fusinite and it is this structure characteristic of semifusinite that led to the richer inertinite but higher reactivity of the Northwestern China coal. Not only vitrinite but also semifusinite and fusinite with weaker reducibility have less aliphatic hydrogen and more C=O structures than those with stronger reducibility. The different intensity of oxidation in the process of coalification is one of the causes that led to different type of reducibility.
Research Group for Physical Chemistry of Minerals and Environmental Geochemistry, Department of Earth Science and Engineering, Taiyuan University of Technology, China. ycchz@126.com
Hai-Zhou
HZ
Chang
Fan-Gui
FG
Zeng
Wen-Ying
WY
Li
Jun
J
Li
Jian-Bo
JB
Jia
Ke-Chang
KC
Xie