Influence of roughness on capillary forces between hydrophilic surfaces.
Capillary forces have been measured by atomic force microscopy in the plate-sphere setup between gold, borosilicate glass, GeSbTe, titanium, and UV-irradiated amorphous titanium-dioxide surfaces. The force measurements were performed as a function contact time and surface roughness in the range 0.2-15 nm rms and relative humidity ranging between 2% and 40%. It is found that even for the lowest attainable relative humidity ( approximately 2%+/-1%) very large capillary forces are still present. The latter suggests the persistence of a nanometers-thick adsorbed water layer that acts as a capillary bridge between contacting surfaces. Moreover, we found a significantly different scaling behavior of the force with rms roughness for materials with different hydrophilicity as compared to gold-gold surfaces.
Department of Applied Physics, Materials Innovation Institute and Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands.
P J
PJ
van Zwol
G
G
Palasantzas
J Th M
JT
De Hosson