Family behaviour of Raman-active phonon frequencies of single-wall nanotubes of C, BN and BC3.
Using a symmetry-based force-constant model of the lattice dynamics, the Raman-active phonon frequencies are calculated for almost 200 single-wall nanotubes of C, BN and BC(3). The n+m=constant family behaviour is found in most branches and these three kinds of nanotubes display different diameter and chirality dependence in different branches. In these branches, vibration modes that C, BN and BC(3) nanotubes have in common are presented in detail. For a particular family, the phonon frequency at Gamma point changes regularly with the chiral angle. Therefore, we may distinguish among single-wall nanotubes with similar diameter and different chiral angle.
School of Science, Henan University of Science and Technology, Luoyang 471003, China.
Hui
H
Wang
Xuewei
X
Cao
Min
M
Feng
Yufang
Y
Wang
Qinghua
Q
Jin
Datong
D
Ding
Guoxiang
G
Lan
D002244:Carbon / Q000737:chemistry*; D004563:Electrochemistry; D008422:Materials Testing / Q000379:methods; D053768:Metal Nanoparticles / Q000737:chemistry; D008954:Models, Biological; D008956:Models, Chemical; D008958:Models, Molecular; D043942:Nanotubes / Q000737:chemistry*; D013059:Spectrum Analysis, Raman; D014732:Vibration
D002244:Carbon