15N NMR coordination shifts in Pd(II), Pt(II), Au(III), Co(III), Rh(III), Ir(III), Pd(IV), and Pt(IV) complexes with pyridine, 2,2'-bipyridine, 1,10-phenanthroline, quinoline, isoquinoline, 2,2'-biquinoline, 2,2':6', 2'-terpyridine and their alkyl or aryl derivatives.
The 15N NMR data for 105 complexes of Pd(II), Pt(II), Au(III), Co(III), Rh(III), Ir(III), Pd(IV), and Pt(IV) complexes with simple azines such as pyridine, 2,2'-bipyridine, 1,10-phenanthroline, quinoline, isoquinoline, 2,2'-biquinoline, 2,2':6', 2''-terpyridine and their alkyl or aryl derivatives have been reviewed. The 15N NMR coordination shifts, i.e. the differences between the 15N chemical shifts of the same nitrogen in the molecules of the complex and the ligand (Delta(15N) (coord) = delta(15N) (compl)--delta(15N) (lig)), have been related to some structural features of the reviewed coordination compounds, like the type of the central ion and the character of auxiliary ligands (mainly in trans position). These Delta(15N) (coord) parameters are negative, their absolute magnitudes (ca 30-150 ppm) generally increasing in the metal order Au(III) < Pd(II) < Pt(II) and Rh(III) < Co(III) < Pt(IV) < Ir(III), as well as with the enhanced trans influence of the other donor atoms (H, C << Cl < N).
Faculty of Chemistry, Nicholas Copernicus University, Gagarina 7, PL-87100 Toruń, Poland. leszekp@chem.uni.torun.pl
Leszek
L
Pazderski
D006571:Heterocyclic Compounds / Q000737:chemistry*; D008279:Magnetic Resonance Imaging / Q000379:methods*; D019216:Metals, Heavy / Q000737:chemistry*; D009587:Nitrogen Isotopes; D009942:Organometallic Compounds / Q000737:chemistry*; D010618:Phenanthrolines / Q000737:chemistry; D011725:Pyridines / Q000737:chemistry; D011804:Quinolines / Q000737:chemistry
D006571:Heterocyclic Compounds; D019216:Metals, Heavy; D009587:Nitrogen Isotopes; D009942:Organometallic Compounds; D010618:Phenanthrolines; D011725:Pyridines; D011804:Quinolines; C037219:quinoline