Synthesis of FF8181-A.
Both enantiomers of FF8181-A were synthesized through optical resolution from the known Diels-Alder reaction product in 15 steps. The absolute configuration of the natural product was determined to be 1S,5S,5aS,9aS,9bS.
Kobayashi
Noriaki
N
Department of Applied Biological Chemistry, Graduate School of Agricultural and Life Sciences, The University of Tokyo, Tokyo, Japan.
Kuniyoshi
Hidenobu
H
Ishigami
Ken
K
Watanabe
Hidenori
H
D002210:Caprylates / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009930:Organic Chemicals / Q000138:chemical synthesis* / Q000737:chemistry; D012717:Sesquiterpenes / Q000138:chemical synthesis* / Q000737:chemistry
D002210:Caprylates; C534016:FF8181-A; D009930:Organic Chemicals; D012717:Sesquiterpenes