Bolineol, a novel co-metabolite of strobilurins A, F and G from Bolinea lutea.
A mycelial co-metabolite of strobilurin A, F and G from Bolinea lutea, which we have named bolineol, has been characterised for the first time. Bolineol (methyl 2-hydroxymethyl-3-methyl-6-phenyl-3Z,5E-hexadienoate) has a similar carbon skeleton to strobilurin A but differs in oxidation level. Its structure has been deduced from its spectral characteristics and those of its acetate. The known compound strobilurin F-1 (methyl 2-methoxymethylene-3-methyl-6-(3'-hydroxyphenyl)-3Z,5E-hexadienoate) has been detected in this organism for the first time and converted into its acetate, a new compound, the structure of which was assigned from its spectral data.
Bedford
Colin T
CT
Department of Chemistry, University College London (UCL), London, UK. c.t.bedford@ucl.ac.uk
Perry
David
D
Sharma
Rajnesh K
RK
D001203:Ascomycota / Q000378:metabolism*; D005231:Fatty Acids, Unsaturated / Q000737:chemistry / Q000302:isolation & purification* / Q000378:metabolism; D008689:Methacrylates / Q000737:chemistry / Q000378:metabolism; D015394:Molecular Structure; D019906:Nuclear Magnetic Resonance, Biomolecular; D013237:Stereoisomerism; D000073739:Strobilurins
D005231:Fatty Acids, Unsaturated; D008689:Methacrylates; D000073739:Strobilurins; C533823:bolineol; C065215:strobilurin F