Magnetic properties of isotropic and anisotropic CoFe2O4-based ferrogels and their application as torsional and rotational actuators.
CoFe2O4-based ferrogels were prepared with both isotropic and anisotropic orientation of the magnetic anisotropy axis of the magnetic particles. In contrast to the superparamagnetic properties of the ferrofluid, the ferrogels exhibit hysteresis, indicating that (i) a significant fraction of magnetic particles has volumes beyond the critical value that allows Néelian relaxation, and (ii) a mechanical interaction between the particles and the polymer network exists, which prevents the particles from Brownian relaxation. The contribution of such particles was investigated by field cooling field warming and zero field cooling field warming measurements as well as temperature-dependent magnetization measurements. By application of an external field during gel polymerization, a magnetic texture was induced as confirmed by the angular dependence of mRmS and HC . The net-magnetic torque, exerted on the magnetic particles in an anisotropic ferrogel in combination with the soft elastic properties of the gel matrix enables the application as torsional soft actuator as demonstrated.
FR 7.3 Technische Physik, Geb. D2 2, Universität des Saarlandes, 66041 Saarbrücken, Germany. monz@mx.uni-saarland.de
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Monz
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Tschöpe
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Birringer