Solid phase extraction of gold(III) on silica gel modified with benzoylthiourea prior to its determination by flame atomic absorption spectrometry.
A new method has been developed for the determination of gold based on separation and preconcentration using silica gel modified with benzoylthiourea. The optimum experimental parameters for preconcentration of gold, such as acid concentration, sample flow rate, eluent and matrix ions, have been investigated. Gold could be quantitatively retained in the 0.25-2.0 mol L(-1) HCl and HNO(3) concentrations, and then eluted completely with 0.5 mol L(-1) thiourea in 1.0 mol L(-1) HCl. The sorption capacity of gold(III) is 0.92 +/- 0.04 mmol g(-1) with a high enrichment factor of 267. The relative standard deviation of the method, RSD%, was found as 1.2% for 0.1 microg mL(-1). The detection limit for gold was 1.4 microg L(-1). The validation of the proposed method was checked by the analysis of certified reference soil materials. The presented procedure was applied to the determination of gold in some environmental samples.
Bozkurt
Serap Seyhan
SS
Faculty of Science and Arts, Chemistry Department, Dokuz Eylul University, Kaynaklar Campus, 35160, Izmir, Turkey.
Merdivan
Melek
M
D006046:Gold / Q000737:chemistry*; D010670:Phenylthiourea / Q000031:analogs & derivatives* / Q000737:chemistry; D058428:Silica Gel; D012822:Silicon Dioxide / Q000737:chemistry*; D052616:Solid Phase Extraction; D013054:Spectrophotometry, Atomic / Q000379:methods*
D058428:Silica Gel; D010670:Phenylthiourea; D006046:Gold; D012822:Silicon Dioxide; C037877:benzylthiourea