title: A green process to prepare chromic oxide green pigment.
abstract: A hydrogen reduction and activated sintering process was proposed to prepare chromic oxide green pigment. Through ICP, XRD, SEM, FT-IR, UV, and CIE-L*a*b* colorimetric analysis, key factors and mechanism that influenced preparation of chromic oxide green pigment were studied. The results revealed that lower hydrogen reduction temperature, suitable addition of Al and Ba, were beneficial to obtaining the high quality chromic oxide green pigment. Typically, when the hydrogen reduction temperature was kept at 450-500 degrees C, physicochemical properties and color performance of the prepared chromic oxide green pigment doped with about 0.1-0.2 wt % Al and 0.2-0.5 wt % Ba conformed to commercial pigment standards. Additionally, characteristics of the green process were discussed. About 90 wt % KOH was reused directly and about 90 wt % Cr(VI) was conversed to Cr(III) directly from potassium chromate to chromic oxide green pigment. Integrating the proprietary green metallurgical process from chromite ore to potassium chromate of this laboratory, more than 99 wt % Cr(VI) could be conversed to Cr(III) compounds and about 99 wt % KOH could be recycled to use. The whole green process, ranging from chromite ore to chromic oxide green pigment, eventually not only provided the possibility for producing the high quality chromic oxide green pigment, but could reach comprehensive utilization of resources, inner recycle of KOH, and zero emission of Cr(VI).
authors.affiliation: Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, PR China.
authors.forename: Ping
authors.initials: P
authors.lastname: Li
authors.forename: Hong-Bin
authors.initials: HB
authors.lastname: Xu
authors.forename: Shi-Li
authors.initials: SL
authors.lastname: Zheng
authors.forename: Yi
authors.initials: Y
authors.lastname: Zhang
authors.forename: Zuo-Hu
authors.initials: ZH
authors.lastname: Li
authors.forename: Yu-Lan
authors.initials: YL
authors.lastname: Bai
mesh_terms: D002152:Calorimetry, Differential Scanning; D015392:Chemistry, Inorganic / Q000379:methods*; D017608:Chromium Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D004396:Coloring Agents / Q000138:chemical synthesis* / Q000737:chemistry; D004583:Electrons; D006859:Hydrogen / Q000737:chemistry; D008855:Microscopy, Electron, Scanning; D010084:Oxidation-Reduction; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature; D014961:X-Ray Diffraction
chemical_list: D017608:Chromium Compounds; D004396:Coloring Agents; D006859:Hydrogen; C023600:chromic oxide