title: Transport and transformation of sulfadiazine in soil columns packed with a silty loam and a loamy sand.
abstract: Concerning the transport of the veterinary antibiotic sulfadiazine (SDZ) little is known about its possible degradation during transport. Also its sorption behaviour is not yet completely understood. We investigated the transport of SDZ in soil columns with a special emphasis on the detection of transformation products in the outflow of the soil columns and on modelling of the concentration distribution in the soil columns afterwards. We used disturbed soil columns near saturation, packed with a loamy sand and a silty loam. SDZ was applied as a 0.57 mg L(-1) solution at a constant flow rate of 0.25 cm h(-1) for 68 h. Breakthrough curves (BTC) of SDZ and its transformation products 4-(2-iminopyrimidin-1(2H)-yl)aniline and 4-hydroxy-SDZ were measured for both soils. For the silty loam we additionally measured a BTC for an unknown transformation product which we only detected in the outflow samples of this soil. After the leaching experiments the (14)C-concentration was quantified in different layers of the soil columns. The transformation rates were low with mean SDZ mass fractions in the outflow samples of 95% for the loamy sand compared to 97% for the silty loam. The formation of 4-(2-iminopyrimidin-1(2H)-yl)aniline appears to be light dependent and did probably not occur in the soils, but afterwards. In the soil columns most of the (14)C was found near the soil surface. The BTCs in both soils were described well by a model with one reversible (kinetic) and one irreversible sorption site. Sorption kinetics played a more prominent role than sorption capacity. The prediction of the (14)C -concentration profiles was improved by applying two empirical models other than first order to predict irreversible sorption, but also these models were not able to describe the (14)C concentration profiles correctly. Irreversible sorption of sulfadiazine still is not well understood.
authors.affiliation: Agrosphere Institute, ICG 4, Forschungszentrum Jülich GmbH, Leo Brandt Str., 52425 Jülich, Germany. m.unold@fz-juelich.de
authors.forename: M
authors.initials: M
authors.lastname: Unold
authors.forename: R
authors.initials: R
authors.lastname: Kasteel
authors.forename: J
authors.initials: J
authors.lastname: Groeneweg
authors.forename: H
authors.initials: H
authors.lastname: Vereecken
mesh_terms: D000327:Adsorption; D000900:Anti-Bacterial Agents / Q000737:chemistry*; D002250:Carbon Radioisotopes; D004787:Environmental Pollution; D012822:Silicon Dioxide / Q000737:chemistry*; D012987:Soil; D013411:Sulfadiazine / Q000737:chemistry*; D014872:Water Movements
chemical_list: D000900:Anti-Bacterial Agents; D002250:Carbon Radioisotopes; D012987:Soil; D013411:Sulfadiazine; D012822:Silicon Dioxide