Once cleaved C-C bond was reformed: reversible C-C bond cleavage of dihydroindenyltitanium complexes.
The once cleaved carbon-carbon bond of the Cp moiety in 2 was recombined in indene products. Aslo, we propose a novel mechanism for the cleavage of the carbon-carbon bond of the Cp moiety.
Takahashi
Tamotsu
T
Catalysis Research Center and Graduate School of Life Sciences, Hokkaido University, and SORST, Japan Science and Technology Agency, Kita-ku, Sapporo 001-0021, Japan. Tamotsu@cat.hokudai.ac.jp
Song
Zhiyi
Z
Hsieh
Yi-Fang
YF
Nakajima
Kiyohiko
K
Kanno
Ken-ichiro
K
D002244:Carbon / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D007192:Indenes / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*
D007192:Indenes; D009942:Organometallic Compounds; D002244:Carbon; D006859:Hydrogen; D014025:Titanium