Hyperpolarized carbon-carbon intermolecular multiple quantum coherences.
Intermolecular multiple quantum coherences (iMQCs) can provide unique contrast with sub-voxel resolution. However, the characteristic growth rate of iMQCs mostly limits these effects to either hydrogen or hydrogen-coupled systems for thermally polarized samples. Hyperpolarization techniques such as dynamic nuclear polarization (DNP) allow for significant increases in the carbon signal (even more signal than that from hydrogen), making carbon iMQCs achievable. We present the first intermolecular multiple quantum signal between two carbon nuclei.
Jenista
Elizabeth R
ER
Center for Molecular and Biomolecular Imaging, 2220 French Family Science Center, Duke University, Durham, NC 27708, USA. elizabeth.specht@duke.edu
Branca
Rosa T
RT
Warren
Warren S
WS
D002244:Carbon / Q000737:chemistry*; D002247:Carbon Isotopes / Q000032:analysis / Q000737:chemistry; D003198:Computer Simulation; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D008956:Models, Chemical; D011789:Quantum Theory; D055672:Static Electricity
D002247:Carbon Isotopes; D002244:Carbon