Photoluminescent Mn4 single-molecule magnet.
The synthesis of [Mn(4)(anca)(4)(Hmdea)(2)(mdea)(2)].2CHCl(3) (1) is reported along with room temperature fluorescence, UV-vis, and NMR spectra. Direct current magnetization versus field data reveal a S = 8 ground state. Quantized steps in temperature- and field-dependent magnetization versus field hysteresis loops confirm single-molecule magnet behavior.
Beedle
Christopher C
CC
Department of Chemistry and Biochemistry, University of California at San Diego, La Jolla, California 92093-0358, USA.
Stephenson
Casey J
CJ
Heroux
Katie J
KJ
Wernsdorfer
Wolfgang
W
Hendrickson
David N
DN