title: Enantiomerically pure bicyclo[3.3.1]nona-2,6-diene as the sole source of enantioselectivity in BIPHEP-Rh asymmetric hydrogenation.
abstract: In situ resolution of the rapidly racemising diphosphine BIPHEP and its relatives with the cationic Rh complex of (S,S)-bicyclonona-2,6-diene permits the asymmetric hydrogenation of dehydroamino esters.
authors.affiliation: Chemical Research Laboratory, 12 Mansfield Rd, Oxford, UKOX1 3TA. tpunni@iitg.ernet.in
authors.forename: Tharmalingam
authors.initials: T
authors.lastname: Punniyamurthy
authors.forename: Monika
authors.initials: M
authors.lastname: Mayr
authors.forename: Alexander S
authors.initials: AS
authors.lastname: Dorofeev
authors.forename: Carole J R
authors.initials: CJ
authors.lastname: Bataille
authors.forename: Silvia
authors.initials: S
authors.lastname: Gosiewska
authors.forename: Bao
authors.initials: B
authors.lastname: Nguyen
authors.forename: Andrew R
authors.initials: AR
authors.lastname: Cowley
authors.forename: John M
authors.initials: JM
authors.lastname: Brown