Tuning the shape of nanoparticles to control their catalytic properties: selective hydrogenation of 1,3-butadiene on Pd/Al2O3.
Shape-controlled Pd nanoparticles supported on powder alumina are more efficient for selective butadiene hydrogenation to butene when they exhibit high fractions of (111) facets.
Piccolo
Laurent
L
IRCELYON, UMR 5256 CNRS and Université Claude Bernard-Lyon 1, 2 Avenue Albert Einstein, 69626, Villeurbanne Cedex, France. laurent.piccolo@ircelyon.univ-lyon1.fr
Valcarcel
Ana
A
Bausach
Marta
M
Thomazeau
Cécile
C
Uzio
Denis
D
Berhault
Gilles
G
D000475:Alkenes / Q000138:chemical synthesis / Q000737:chemistry; D000537:Aluminum Oxide / Q000737:chemistry*; D002070:Butadienes / Q000737:chemistry*; D002384:Catalysis; D006865:Hydrogenation; D053768:Metal Nanoparticles / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D010316:Particle Size; D013997:Time Factors
D000475:Alkenes; D002070:Butadienes; D010165:Palladium; C031763:1,3-butadiene; D000537:Aluminum Oxide; C058602:1-butene