title: Molecular adsorption of H2 on small cationic nickel clusters.
abstract: An H2 molecule can bind molecularly on Ni4+ but it binds exclusively dissociatively on Ni5+ and Ni6+ and the adsorption behavior correlates with the relative reactivity of the metal clusters towards H2.
authors.forename: Ingmar
authors.initials: I
authors.lastname: Swart
authors.forename: Philipp
authors.initials: P
authors.lastname: Gruene
authors.forename: André
authors.initials: A
authors.lastname: Fielicke
authors.forename: Gerard
authors.initials: G
authors.lastname: Meijer
authors.forename: Bert M
authors.initials: BM
authors.lastname: Weckhuysen
authors.forename: Frank M F
authors.initials: FM
authors.lastname: de Groot
mesh_terms: D000327:Adsorption; D002412:Cations / Q000737:chemistry; D003198:Computer Simulation; D006859:Hydrogen / Q000737:chemistry*; D008956:Models, Chemical; D009532:Nickel / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013499:Surface Properties
chemical_list: D002412:Cations; D009532:Nickel; D006859:Hydrogen