title: Intermolecular contact-tuned magnetic nature in one-dimensional 3d-5d bimetallic systems: from a metamagnet to a single-chain magnet.
abstract: Assembling [W(CN) 6(bpy)] (-) and magnetic anisotropic Mn Schiff bases produced two Mn (III)(3d)-W (V)(5d) bimetallic chains. Modulation of the types and degrees of interchain pi-pi interactions in the one-dimensional coordination polymers leads to the variation of the magnetic behavior from a metamagnetic character to a single-chain magnet property.
authors.affiliation: Department of Chemistry, Korea University, Seoul 136-713, Korea.
authors.forename: Seok Woo
authors.initials: SW
authors.lastname: Choi
authors.forename: Hyun Young
authors.initials: HY
authors.lastname: Kwak
authors.forename: Jung Hee
authors.initials: JH
authors.lastname: Yoon
authors.forename: Hyoung Chan
authors.initials: HC
authors.lastname: Kim
authors.forename: Eui Kwan
authors.initials: EK
authors.lastname: Koh
authors.forename: Chang Seop
authors.initials: CS
authors.lastname: Hong
mesh_terms: D015082:2,2'-Dipyridyl / Q000031:analogs & derivatives / Q000737:chemistry; D000588:Amines / Q000737:chemistry; D016880:Anisotropy; D003486:Cyanides / Q000737:chemistry; D003510:Cyclohexanes / Q000737:chemistry; D008280:Magnetics; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D009281:Naphthalenes / Q000737:chemistry; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D014414:Tungsten / Q000737:chemistry*
chemical_list: D000588:Amines; D003486:Cyanides; D003510:Cyclohexanes; D009281:Naphthalenes; D009942:Organometallic Compounds; D008345:Manganese; D015082:2,2'-Dipyridyl; D014414:Tungsten