title: Study of the supramolecular cooperativity in the multirecognition mechanism of cyclodextrins/cucurbituril/disubstituted diimidazolium bromides.
abstract: N, N'-Disubstituted methylenediimidazolium bromide salts substituted with two aromatic groups present two different binding sites. In the binary complexes with cyclodextrins (CDs) or cucurbit[7]uril (CB[7]), the macrocycle is always positioned on the external aromatic residues. In the ternary complexes, CB[7] is positioned around the diimidazolium cation, where the external aromatic residue is included in the CD's cavity. The unfavored position of the CB[7] on the cationic site in the ternary complex is the result of its cooperative supramolecular interaction with the cyclodextrin. The obtained ternary complexes possess different interfacial properties, compared to those of the binary complexes. We demonstrate these hypotheses by NMR spectroscopy, ESI-HRMS spectrometry, molecular modeling simulation, and surface tension measurements.
authors.affiliation: Department of Chemistry, Université de Montréal, C.P. 6128 Succursale Centre-ville, Montréal, Québec, H3C 3J7, Canada.
authors.forename: Loïc
authors.initials: L
authors.lastname: Leclercq
authors.forename: Nadim
authors.initials: N
authors.lastname: Noujeim
authors.forename: Samantha
authors.initials: S
authors.lastname: H Sanon
authors.forename: Andreea R
authors.initials: AR
authors.lastname: Schmitzer