Adsorption properties of aluminum magnesium mixed hydroxide for the model anionic dye Reactive Brilliant Red K-2BP.
The use of aluminum magnesium mixed metal hydroxide (MMH) as adsorbent to remove Reactive Brilliant Red K-2BP (RBR K-2BP), as a model anionic dye, from aqueous solution was investigated. MMH was prepared by coprecipitation and was characterized by XRD, TEM and average particle diameter. Adsorption experiments were carried out as a function of pH, contact time, concentration of dye, adsorbent dosage, and temperature. The results showed that MMH was particularly effective to remove RBR K-2BP, and that the effective pH range for the dye removal was between 4.0 and 11.0, but at pHs lower than 4, dissolution of MMH took place. A significant decline of dye adsorption occurred at pHs above the isoelectric point (IEP). The adsorption of RBR K-2BP on MMH reached equilibrium within 4h. The appropriate adsorbent dosage was 1000 mg/L. The interaction between the surface sites of MMH and the dye ions may be a combination of both anion exchange and surface complexation. Three kinetic models have been evaluated to fit the experimental data. It was shown that the pseudo-second-order model best described the adsorption kinetics of RBR K-2BP on MMH. The equilibrium isotherm showed that the adsorption of RBR K-2BP onto MMH was consistent with the Langmuir and Freundlich equations. And the saturated adsorption capacity of MMH for RBR K-2BP was 657.5mg/g. The adsorption process was endothermic in nature. MMH displayed superior treatment efficiency to the industrial dye effluents from a printing and dyeing plant with a removal efficiency of 93.8-96.7% for colored materials and 77.9-83.6% for COD.
Li
Yujiang
Y
School of Environmental Science & Engineering, Shandong University, Jinan, PR China. yujiang@sdu.edu.cn
Gao
Baoyu
B
Wu
Tao
T
Wang
Biao
B
Li
Xia
X
D000327:Adsorption; D000536:Aluminum Hydroxide / Q000737:chemistry*; D001391:Azo Compounds / Q000302:isolation & purification*; D006863:Hydrogen-Ion Concentration; D008276:Magnesium Hydroxide / Q000737:chemistry*; D013696:Temperature; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods*
D001391:Azo Compounds; D014874:Water Pollutants, Chemical; C525123:reactive brilliant red K-BP; D000536:Aluminum Hydroxide; D008276:Magnesium Hydroxide