Particle dispersibility and giant reduction in dynamic modulus of magnetic gels containing barium ferrite and iron oxide particles.
The particle dispersibility of barium ferrite and iron oxide magnetic particles in carrageenan gels was investigated, and the influence of the dispersibility on the giant reduction in the dynamic modulus of the gels was discussed. The gels containing barium ferrite demonstrated giant reductions in the storage Young's modulus on the order of 10 (5) Pa due to magnetization; however, small reductions in the storage modulus of less than 10 (4) Pa were observed for the gels containing iron oxide. The storage modulus of gels with barium ferrite did not follow the Krieger-Dougherty equation above volume fractions of 0.06, indicating the heterogeneous dispersion of the magnetic particles; however, the modulus of the gels with iron oxide satisfied the equation at all volume fractions, suggesting the random dispersion of the particles. It was noted that the gels with barium ferrite demonstrated enhanced nonlinear viscoelasticity and a large value of the loss tangent, while the gels with iron oxide exhibited weak nonlinear viscoelasticity and a small value of the loss tangent. Magnetic measurements indicated high values of remanent magnetization for barium ferrite and low values for iron oxide. After magnetization at 1 T, the magnetic gels with barium ferrite became elongated parallel to the magnetic field and shrunk perpendicular to the field. In contrast, the magnetic gels with iron oxide did not undergo a marked deformation. These results strongly indicate that the giant reduction in the storage modulus requires both enhanced nonlinear viscoelasticity and magnetostriction which originate from the particle dispersibility. The relationship between the dispersibility of magnetic particles and the giant reduction in the storage modulus is discussed using rheological and morphological data.
Mitsumata
Tetsu
T
Department of Polymer Science and Engineering, Graduate School of Engineering, Yamagata University, Yonezawa 992-8510, Japan. tetsu@yz.yamagata-u.ac.jp
Wakabayashi
Takashi
T
Okazaki
Takahiko
T