title: Synthesis of N-confused tetraphenylporphyrin rhodium complexes having versatile metal oxidation states.
abstract: A variety of N-confused tetraphenylporphyrin rhodium complexes were synthesized, and their structures and physical properties were investigated. Depending on the reaction conditions, the rhodium(I), -(III), and -(IV) complexes were produced, which exemplified the versatile coordination mode of N-confused porphyrin ligands.
authors.affiliation: Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan.
authors.forename: Alagar
authors.initials: A
authors.lastname: Srinivasan
authors.forename: Motoki
authors.initials: M
authors.lastname: Toganoh
authors.forename: Teppei
authors.initials: T
authors.lastname: Niino
authors.forename: Atsuhiro
authors.initials: A
authors.lastname: Osuka
authors.forename: Hiroyuki
authors.initials: H
authors.lastname: Furuta
mesh_terms: D000042:Absorption; D004578:Electron Spin Resonance Spectroscopy; D008024:Ligands; D008665:Metalloporphyrins / Q000138:chemical synthesis* / Q000737:chemistry; D010084:Oxidation-Reduction; D012238:Rhodium / Q000737:chemistry*; D013696:Temperature
chemical_list: D008024:Ligands; D008665:Metalloporphyrins; D012238:Rhodium