Synthesis of N-confused tetraphenylporphyrin rhodium complexes having versatile metal oxidation states.
A variety of N-confused tetraphenylporphyrin rhodium complexes were synthesized, and their structures and physical properties were investigated. Depending on the reaction conditions, the rhodium(I), -(III), and -(IV) complexes were produced, which exemplified the versatile coordination mode of N-confused porphyrin ligands.
Srinivasan
Alagar
A
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan.
Toganoh
Motoki
M
Niino
Teppei
T
Osuka
Atsuhiro
A
Furuta
Hiroyuki
H
D000042:Absorption; D004578:Electron Spin Resonance Spectroscopy; D008024:Ligands; D008665:Metalloporphyrins / Q000138:chemical synthesis* / Q000737:chemistry; D010084:Oxidation-Reduction; D012238:Rhodium / Q000737:chemistry*; D013696:Temperature
D008024:Ligands; D008665:Metalloporphyrins; D012238:Rhodium