title: Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal-organic framework Ni2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction.
abstract: The microporous metal-organic framework Ni(2)(dhtp) (H(4)dhtp=2,5-dihydroxyterephthalic acid) shows distinct end-on CO(2) coordination to coordinatively unsaturated nickel sites giving rise to high CO(2) adsorption capacity at sub-atmospheric pressures and ambient temperatures.
authors.affiliation: SINTEF Materials & Chemistry, P.O. Box 124 Blindern, N-0314, Oslo, Norway.
authors.forename: Pascal D C
authors.initials: PD
authors.lastname: Dietzel
authors.forename: Rune E
authors.initials: RE
authors.lastname: Johnsen
authors.forename: Helmer
authors.initials: H
authors.lastname: Fjellvåg
authors.forename: Silvia
authors.initials: S
authors.lastname: Bordiga
authors.forename: Elena
authors.initials: E
authors.lastname: Groppo
authors.forename: Sachin
authors.initials: S
authors.lastname: Chavan
authors.forename: Richard
authors.initials: R
authors.lastname: Blom