Molecular adsorption of H2 on small cationic nickel clusters.
An H2 molecule can bind molecularly on Ni4+ but it binds exclusively dissociatively on Ni5+ and Ni6+ and the adsorption behavior correlates with the relative reactivity of the metal clusters towards H2.
Swart
Ingmar
I
Gruene
Philipp
P
Fielicke
André
A
Meijer
Gerard
G
Weckhuysen
Bert M
BM
de Groot
Frank M F
FM
D000327:Adsorption; D002412:Cations / Q000737:chemistry; D003198:Computer Simulation; D006859:Hydrogen / Q000737:chemistry*; D008956:Models, Chemical; D009532:Nickel / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013499:Surface Properties
D002412:Cations; D009532:Nickel; D006859:Hydrogen