Axial chirality control of tropos BIPHEP-Rh complexes by chiral dienes: synergy effect in catalytic asymmetric hydrogenation.
Diastereopure tropos Rh complexes bearing not only BIPHEP but also chiral dienes can be employed as highly enantioselective hydrogenation catalysts for an olefinic substrate.
Aikawa
Kohsuke
K
Department of Applied Chemistry, Tokyo Institute of Technology, Tokyo, 152-8552, Japan.
Takabayashi
Yūki
Y
Kawauchi
Susumu
S
Mikami
Koichi
K