title: Na3PbII[B(O3POH)4]: an alkali-metal lead borophosphate with heterocubane-like units Na3PbO4.
abstract: Na 3Pb (II)[B(O 3POH) 4] was synthesized under hydrothermal conditions. The crystal structure determination from single-crystal X-ray diffraction data ( I4 1/ a, Z = 4, a = 6.9182(8) A, c = 27.309 (3) A, V = 1307.0(3) A (3)) revealed the presence of [B(O 3POH) 4] (5-) oligomers and heterocubane-like units Na 3PbO 4 with mixed-occupied metal cation sites.
authors.affiliation: Max-Planck-Institut für Chemische Physik fester Stoffe, Nöthnitzer Strasse 40, 01187 Dresden, Germany.
authors.forename: Stefan
authors.initials: S
authors.lastname: Hoffmann
authors.forename: Harold B Tanh
authors.initials: HB
authors.lastname: Jeazet
authors.forename: Prashanth W
authors.initials: PW
authors.lastname: Menezes
authors.forename: Yurii
authors.initials: Y
authors.lastname: Prots
authors.forename: Rüdiger
authors.initials: R
authors.lastname: Kniep