Chiral-layered metal phosphonate formed via spontaneous resolution showing dehydration-induced antiferromagnetic to ferromagnetic transformation.
Metal phosphonates M (II){(2-C 5H 4N)CH 2NHCH 2PO 3} (H 2O) [M = Mn ( 1), Cd ( 2)] with chiral-layered structures are obtained by spontaneous resolution using achiral starting materials. The magnetic behavior of 1 is transformed from antiferromagnetic to ferromagnetic upon dehydration.
Hou
Shou-Zeng
SZ
State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, People's Republic of China.
Cao
Deng-Ke
DK
Li
Yi-Zhi
YZ
Zheng
Li-Min
LM