title: Photoluminescent Mn4 single-molecule magnet.
abstract: The synthesis of [Mn(4)(anca)(4)(Hmdea)(2)(mdea)(2)].2CHCl(3) (1) is reported along with room temperature fluorescence, UV-vis, and NMR spectra. Direct current magnetization versus field data reveal a S = 8 ground state. Quantized steps in temperature- and field-dependent magnetization versus field hysteresis loops confirm single-molecule magnet behavior.
authors.affiliation: Department of Chemistry and Biochemistry, University of California at San Diego, La Jolla, California 92093-0358, USA.
authors.forename: Christopher C
authors.initials: CC
authors.lastname: Beedle
authors.forename: Casey J
authors.initials: CJ
authors.lastname: Stephenson
authors.forename: Katie J
authors.initials: KJ
authors.lastname: Heroux
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Wernsdorfer
authors.forename: David N
authors.initials: DN
authors.lastname: Hendrickson