title: Regiocontrolled addition of arylboronic acids to allenes using palladium and platinum catalysts.
abstract: Studies about the regiocontrolled addition of arylboronic acids to allenes using a palladium or a platinum catalyst have been described. The selectivity of the reaction can be altered by the choice of the metal reagent and base. Contrary to the formation of endo-olefinic products in the reactions using hydroxopalladium complex, predominant production of exo-olefinic products was observed by the reaction with hydroxoplatinum complex.
authors.affiliation: Graduate School of Pharmaceutical Sciences, The University of Tokushima, Tokushima, Japan. yoshida@ph.tokushima-u.ac.jp
authors.forename: Masahiro
authors.initials: M
authors.lastname: Yoshida
authors.forename: Kennosuke
authors.initials: K
authors.lastname: Matsuda
authors.forename: Yasunobu
authors.initials: Y
authors.lastname: Shoji
authors.forename: Takahiro
authors.initials: T
authors.lastname: Gotou
authors.forename: Masataka
authors.initials: M
authors.lastname: Ihara
authors.forename: Kozo
authors.initials: K
authors.lastname: Shishido
mesh_terms: D000466:Alkadienes / Q000737:chemistry*; D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D010165:Palladium / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000466:Alkadienes; D001897:Boronic Acids; D010984:Platinum; C025947:propadiene; D010165:Palladium