title: Influence of the temperature, volume and type of solution in the mercury vaporization of dental amalgam residue.
abstract: One of the qualitative methods for the identification of mercury vapor is what it occurs as a way of chemical reaction between palladium chloride and metallic mercury. Palladium chloride ribbons with yellowish coloration put in contact with the vaporized mercury of dental amalgam residue, liberates palladium and forms mercury chloride in your surface, and starts to have black coloration; this form identify the presence of the mercury vapor in the system. This work studies the influence of temperature, volume and type of barrier-solution in the vaporization of mercury during the period of storage of dental amalgam residues, aiming to establish the best conditions for storage of these residues. It was found that for all tested solutions, the longest storage times without any occurrence of mercury vaporization were obtained in the lowest temperatures tested and the largest solution volumes of barrier-solution. The radiographic effluent presented bigger efficacy in the reduction of the volatilization, increasing the period when the residue was stored, however the analysis of this solution after the vaporization test showed the presence of organic mercury. These results show that water is the most efficient barrier against the vaporization of mercury, since it did not result in organic mercury formation in the effluent solution from the storage process.
authors.affiliation: Department of Chemical Engineering, State University of Maringá, Maringá - PR, Brazil. raqueldc_eng@yahoo.com.br
authors.forename: Raquel Dalla
authors.initials: RD
authors.lastname: Costa
authors.forename: Eneida Sala
authors.initials: ES
authors.lastname: Cossich
authors.forename: Célia Regina Granhen
authors.initials: CR
authors.lastname: Tavares
mesh_terms: D000395:Air Pollutants, Occupational / Q000032:analysis / Q000737:chemistry*; D016902:Air Pollution, Indoor / Q000032:analysis / Q000517:prevention & control; D003723:Dental Amalgam / Q000737:chemistry* / Q000592:standards; D008628:Mercury / Q000032:analysis / Q000737:chemistry*; D012449:Safety; D012996:Solutions; D013696:Temperature; D013997:Time Factors; D014835:Volatilization
chemical_list: D000395:Air Pollutants, Occupational; D012996:Solutions; D003723:Dental Amalgam; D008628:Mercury