Phosphinates as new electrophilic partners for cross-coupling reactions.
The use of enol phosphinates as electrophiles for cross-coupling reactions has been explored. Both boronic acids (Suzuki-Miyaura reaction) and stannanes (Stille reaction) couple efficiently with lactam derived phosphinates.
Guo
Jun
J
Department of Chemistry, University of Durham, Science Laboratories, South Road, Durham, UK DH1 3LE.
Harling
John D
JD
Steel
Patrick G
PG
Woods
Tom M
TM
D002384:Catalysis; D003432:Cross-Linking Reagents / Q000737:chemistry*; D007769:Lactams / Q000737:chemistry; D010721:Phosphinic Acids / Q000737:chemistry*; D028561:Transition Elements / Q000737:chemistry
D003432:Cross-Linking Reagents; D007769:Lactams; D010721:Phosphinic Acids; D028561:Transition Elements