title: Phosphinates as new electrophilic partners for cross-coupling reactions.
abstract: The use of enol phosphinates as electrophiles for cross-coupling reactions has been explored. Both boronic acids (Suzuki-Miyaura reaction) and stannanes (Stille reaction) couple efficiently with lactam derived phosphinates.
authors.affiliation: Department of Chemistry, University of Durham, Science Laboratories, South Road, Durham, UK DH1 3LE.
authors.forename: Jun
authors.initials: J
authors.lastname: Guo
authors.forename: John D
authors.initials: JD
authors.lastname: Harling
authors.forename: Patrick G
authors.initials: PG
authors.lastname: Steel
authors.forename: Tom M
authors.initials: TM
authors.lastname: Woods
mesh_terms: D002384:Catalysis; D003432:Cross-Linking Reagents / Q000737:chemistry*; D007769:Lactams / Q000737:chemistry; D010721:Phosphinic Acids / Q000737:chemistry*; D028561:Transition Elements / Q000737:chemistry
chemical_list: D003432:Cross-Linking Reagents; D007769:Lactams; D010721:Phosphinic Acids; D028561:Transition Elements