title: Passive air sampling of polychlorinated biphenyls and organochlorine pesticides at the Korean Arctic and Antarctic research stations: implications for long-range transport and local pollution.
abstract: To assess levels and patterns of polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) in polar regions, XAD-resin based passive air samplers were deployed for one year at the Korean polar research stations at Ny-Alesund, Norway (2005-2006) and King George Island, Antarctica (2004-2005). Backward trajectories suggest that these stations are affected by long-range transport from source regions in Northern Europe and Russia and the southern tip of South America, respectively. Relatively high levels of PCB-11, averaging 60 pg x m(-3), were observed in Antarctica, suggesting an unusual source of PCB-11 to the Southern Hemisphere. Reflecting the hemispheric distribution of global PCB emissions, the average level of sigma205PCB (excluding three mono-CBs and PCB-11) was five times higher in the Arctic (95 pg x m(-3)) than in the Antarctic (19 pg x m(-3)). Levels of sigma9PCB at Ny-Alesund were similarto those reported for other Arctic sites, while levels at King George Island were lower than at other sites on the Antarctic Peninsula but 1 order of magnitude higher than background levels measured at a more remote Antarctic site. Light homologues were predominant in all samples (except for one Arctic sample), consistent with the hypothesis of global fractionation and predictions of long-range transport potential. Dominance of heavy PCBs on the roof of the main building at Ny-Alesund and a concentration gradient with distance from the main building at King George Island strongly indicated the influence of local sources. OCP levels were also influenced by long-range transport but not by local sources. This study highlights the feasibility of using passive air sampling to assess both long-range transport and local pollution in remote regions.
authors.affiliation: School of Environmental Science and Engineering, Pohang University of Science and Technology (POSTECH), San 31, Hyoja-dong, Nam-gu, Pohang 790-784, Republic of Korea.
authors.forename: Sung-Deuk
authors.initials: SD
authors.lastname: Choi
authors.forename: Song-Yee
authors.initials: SY
authors.lastname: Baek
authors.forename: Yoon-Seok
authors.initials: YS
authors.lastname: Chang
authors.forename: Frank
authors.initials: F
authors.lastname: Wania
authors.forename: Michael G
authors.initials: MG
authors.lastname: Ikonomou
authors.forename: Young-Jun
authors.initials: YJ
authors.lastname: Yoon
authors.forename: Byong-Kwon
authors.initials: BK
authors.lastname: Park
authors.forename: Sungmin
authors.initials: S
authors.lastname: Hong
mesh_terms: D000388:Air / Q000032:analysis*; D000397:Air Pollution; D000864:Antarctic Regions; D001110:Arctic Regions; D003198:Computer Simulation; D004784:Environmental Monitoring; D005843:Geography; D007723:Korea; D010575:Pesticides / Q000032:analysis*; D011078:Polychlorinated Biphenyls / Q000032:analysis*; D014186:Transportation; D014919:Wind
chemical_list: D010575:Pesticides; D011078:Polychlorinated Biphenyls