An improved method for the synthesis of zirconium (CCC-N-heterocyclic carbene) pincer complexes and applications in hydroamination.
Upon heating Zr(NMe(2))(4), 1,3-bis(N-butyl-imidazolium)benzene diiodide and toluene analytically pure Zr pincer complex was obtained, which was found to be an intramolecular hydroamination catalyst.
Cho
Joon
J
Department of Chemistry and Biochemistry, University of Mississippi, Mississippi 38677, USA.
Hollis
T Keith
TK
Helgert
Theodore R
TR
Valente
Edward J
EJ
D000586:Amination; D000588:Amines / Q000737:chemistry*; D006571:Heterocyclic Compounds / Q000737:chemistry*; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D009942:Organometallic Compounds / Q000138:chemical synthesis*; D015040:Zirconium / Q000737:chemistry*
D000588:Amines; D006571:Heterocyclic Compounds; D009942:Organometallic Compounds; C030011:carbene; D015040:Zirconium; D008697:Methane