Application of simplified complementary tristimulus colorimetry to chemical kinetics in solution-I: analysis of reaction mixtures and determination of first- or pseudo first-order rate constants.
A graphical method is described which allows estimation of the number of reacting light-absorbing species from the plots of complementary colour points which are obtained with the use of simplified complementary tristimulus colorimetry (SCTS method) from absorption spectra of a series of kinetics solutions. It is shown that the mole function of the reactant or the product at any time can be calculated from the complementary colour points, so that the rate constant can also be determined. The present method has some advantages over the common approach to the determination or reaction rates in presence of a colour impurity.
Tawa
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R
Department of Analytical Chemistry, Kyoto College of Pharmacy, Yamashina-ku, Kyoto, Japan.
Hirose
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S