Analytical applications of the amine-carbon disulphide reaction in acetonitrile.
The ease with which carbon disulphide transforms primary and secondary amines in acetonitrile medium into the corresponding monoalkylammonium monoalkyldithiocarbamates and dialkylammonium dialkyldithiocarbamates respectively and the simplicity and reliability of potentiometric and spectrophotometric determination of dithiocarbamates with copper(I) perchlorate in the same medium, provide simple, accurate and reliable methods for the determination of primary and secondary amines and of organic isothiocyanates.
Verma
B C
BC
Chemistry Department, Himachal Pradesh University, Shimla-5, India.
Chauhan
S
S
Sharma
N
N
Sharma
U
U
Sharma
D K
DK
Sood
A
A