Stripping voltammetry with collection at a rotating ring-disk electrode.
A new electroanalytical technique is described, called "stripping voltammetry with collection." The technique involves the use of a rotating ring-disk electrode and is an improvement over traditional voltammetric stripping at a single electrode in that it is characterized by a lower limit of detection and that the period of deposition before stripping can be shorter. The use of the technique is illustrated by the determination of 10(-10)M Ag(+) in 0.1 M H(2)SO(4) by use of a ring-disk electrode having a disk electrode constructed of glassy carbon and a ring electrode constructed of platinum.
Johnson
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Department of Chemistry, Iowa State University, Ames, Iowa 50010, USA.
Allen
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