title: [Not Available].
abstract: By the use of a hydrogen electrode, two glass electrodes and a spectrophotometric method, the dissociation constants of 26 acids and bases in dimethylformamide have been determined. An acidity scale was defined from pH = 0 to pH = 16. The results obtained by the different methods are in good agreement. The hydrogen electrode can be used for voltammetry as well as for acid-base titrations in DMF. The beginning of the DMF acidity scale can be related to that of the water acidity scale by means of two non-thermodynamic assumptions which do not lead to the same result. Strehlow's approach seems more reasonable than the other.
authors.affiliation: Laboratoire de Chimie Analytique de la Faculté des Sciences associé au C.N.R.S., 10 rue Vauquelin, Paris V(o) France.
authors.forename: G
authors.initials: G
authors.lastname: Demange-Guerin