title: Flotation-spectrophotometric method for determining palladium by means of the ion-association complex of pentabromopalladate(II) with Rhodamine 6G.
abstract: The conditions for the formation of a suitable coloured palladium ion-association complex with a basic dye have been examined, and a spectrophotometric method developed for the determination of palladium with bromide and Rhodamine 6G (R6G). Benzene is used for flotation and dimethylformamide for dissolution of the ion-association complex. The molar absorptivity is 3.0 x 10(5) l. mole(-1).cm(-1) at 53Onm. Beer's law is obeyed up to a palladium concentration of 0.3 mug/ml. The composition of the complex is [R6G(+)](3)[PdBr(3-)(5)]. Platinum interferes severely but other platinum metals interfere to a lesser degree. The method has been applied to the determination of traces of palladium in metallic platinum after a preliminary separation with nickel dimethylglyoximate as collector.
authors.affiliation: Department of Analytical Chemistry, Technical University, Warsaw, Poland.
authors.forename: Z
authors.initials: Z
authors.lastname: Marczenko
authors.forename: M
authors.initials: M
authors.lastname: Jarosz