title: Spectrophotometric determination of trace amounts of iron(III) by extraction of the mixed-ligand iron-fluoride-purpurin complex.
abstract: The characteristics of the mixed-ligand iron(III)-fluoride-purpurin complex, including optimum conditions of formation and extraction into methyl isobutyl ketone are described. A procedure for determination of trace amounts of iron in fluoride medium (0.5M) with purpurin (1,2,4,-trihydroxy-anthraquinone) in methyl isobutyl ketone is given. The method is suitable for determining iron in the presence of large amounts of aluminium, cyanide, phosphate and nickel.
authors.affiliation: Department of Analytical Chemistry, Faculty of Sciences, University of Extremadura, Badajoz, Spain.
authors.forename: M R
authors.initials: MR
authors.lastname: Ceba
authors.forename: A A
authors.initials: AA
authors.lastname: Ramirez
authors.forename: J J
authors.initials: JJ
authors.lastname: Nevado