title: Determination of bisphenol a and bisphenol B residues in canned peeled tomatoes by reversed-phase liquid chromatography.
abstract: Bisphenol A (BPA) and bisphenol B (BPB) concentrations were determined in peeled canned tomatoes of different brands bought in Italian supermarkets. Tomato samples analyzed were packaged in cans coated with either epoxyphenolic lacquer or low BADGE enamel. A solid phase extraction (SPE) was performed on C-18 Strata E cartridge followed by a step on Florisil cartridge. Detection and quantitation were performed by a reversed phase high-performance liquid chromatography (RP-HPLC) method with both UV and fluorescence detection (FD). On the total of 42 tested tomato samples, BPA was detected in 22 samples (52.4%), while BPB was detected in 9 samples (21.4%). BPA and BPB were simultaneously present in 8 of the analyzed samples. The levels of BPA found in this study are much lower than the European Union migration limits of 3 mg/kg food and reasonably unable to produce a daily intake exceeding the limit of 0.05 mg/kg body weight, established by European Food Safety Authority.
authors.affiliation: Dipartimento di Chimica Farmaceutica e Tossicologica, Università degli Studi di Napoli Federico II, Naples, Italy.
authors.forename: Lucia
authors.initials: L
authors.lastname: Grumetto
authors.forename: Domenico
authors.initials: D
authors.lastname: Montesano
authors.forename: Serenella
authors.initials: S
authors.lastname: Seccia
authors.forename: Stefania
authors.initials: S
authors.lastname: Albrizio
authors.forename: Francesco
authors.initials: F
authors.lastname: Barbato
mesh_terms: D001559:Benzhydryl Compounds; D002851:Chromatography, High Pressure Liquid / Q000379:methods*; D052244:Endocrine Disruptors / Q000032:analysis; D005506:Food Contamination / Q000032:analysis*; D005519:Food Preservation; D018551:Solanum lycopersicum / Q000737:chemistry*; D010636:Phenols / Q000032:analysis*; D015203:Reproducibility of Results; D000098923:Bisphenol B Compounds; D000098826:Bisphenol A Compounds
chemical_list: D001559:Benzhydryl Compounds; D052244:Endocrine Disruptors; D010636:Phenols; C492482:bisphenol B; D000098923:Bisphenol B Compounds; C006780:bisphenol A; D000098826:Bisphenol A Compounds