Extractive fluorimetric determination of ultratraces of lead with cryptand 2.2.2 and eosin.
A new speetrofluorimetric method for determination of ultratraces of lead is based on solvent extraction into chloroform of the ion-pair formed between the positively-charged cryptate of lead with cryptand 2.2.2 and the eosinate anion. The detection limit for lead is 1 ng ml , and the linear working range is from the detection limit to 250 ng ml . The relative standard deviation is 3.7% at the 100 ng ml level. The method is highly selective for the extraction and determination of lead in the presence of other cations, and has been tested for direct determination of lead contamination in soft drinks. Aggregation of the extracted ion-pair in the organic phase has been demonstrated in fundamental extraction studies.
Gomis
D B
DB
Departamento de Química Analitica, Facultad de Química, Universidad de Oviedo, Oviedo, Spain.
Alonso
E F
EF
Sanz-Medel
A
A