Molecular absorption spectrometry (MAS) by electrothermal evaporation in a graphite furnace-IX Determination of traces of bromide by mas of AlBr after liquid-liquid extraction of bromide with triphenyltin hydroxide.
The determination of traces of bromide by molecular absorption spectrometry (MAS) of AlBr (with electrothermal volatilization) is described. It is possible to determine 25 ng of bromide. Many problems are caused by various matrices, so an extraction method for separation (and also preconcentration) was developed. The combination of bromide extraction with triphenyltin hydroxide, stripping with 0.025M barium hydroxide and determination of the extracted bromide by MAS of AlBr (after addition of aluminium ions) gives a very sensitive and selective method for determination of traces of bromide in micro or macro samples, in the presence of large amounts of other species, including chloride and iodide.
Dittrich
K
K
Department of Chemistry, Karl-Marx University Leipzig, 7010 Leipzig, D.D.R.
Spivakov
B Y
BY
Shkinev
V M
VM
Vorob'eva
G A
GA