title: Effect of pH on the conditional reduction potential of the tris(1,10-phenanthroline)iron(III,II) couple.
abstract: The half-wave potential for reduction of tris(1,10-phenanthroline)iron(II) at a rotated platinum electrode is constant from pH 0 to 11. The value is 1.06 V at 25.0 degrees and ionic strength 1.0 and is equal to the conditional reduction potential of the tris(1,10-phenanthroline)iron(III,II) couple, as demonstrated by cyclic voltammetry.
authors.affiliation: Department of Chemistry, University of Minnesota, Duluth, Minnesota 55812, U.S.A.
authors.forename: D P
authors.initials: DP
authors.lastname: Poe
authors.forename: J A
authors.initials: JA
authors.lastname: Adamczak