title: Simultaneous spectrophotometric determination of cadmium, copper and zinc.
abstract: A method for the simultaneous spectrophotometric determination of cadmium, copper and zinc based on the formation of their complexes with 1,5-bis(di-2-pyridylmethylene)thiocarbonohydrazide is proposed. The absorption curves of these complexes overlap severely in the scanning range 380-480 nm. The analyte concentrations are calculated by a least squares fit of the pure spectra to the mixture spectra. A linear determination range of 0.1-1.7 mug/ml for cadmium, 0.1-1.3 mug/ml for copper and 0.2-1.2 mug/ml for zinc were obtained. The effect of interference was studied. The method has been applied to the determination of these metal ions in various type of materials.
authors.affiliation: Department of Analytical Chemistry, Faculty of Sciences, University of Málaga, 29071 Málaga, Spain.
authors.forename: A M
authors.initials: AM
authors.lastname: Rodriguez
authors.forename: A G
authors.initials: AG
authors.lastname: de Torres
authors.forename: J M
authors.initials: JM
authors.lastname: Pavon
authors.forename: C B
authors.initials: CB
authors.lastname: Ojeda