Aqueous olefin metathesis.
According to popular belief, oxygen and water are the natural enemies of organometallic reactions and therefore must be excluded rigorously from the reaction vessel. This belief is founded in the case of the highly reactive nucleophilic metal alkylidene complexes that were used in early catalytic olefin metathesis. However, owing to the high stability of the ruthenium carbene complexes introduced by Grubbs, metathesis in water has become reality.
Burtscher
Daniel
D
Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland.
Grela
Karol
K