title: Flow-injection determination of iodide ion in nuclear emergency tablets, using boron-doped diamond thin film electrode.
abstract: The electrochemical determination of iodide was studied at boron-doped diamond thin film electrodes (BDD) using cyclic voltammetry (CV) and flow-injection (FI) analysis, with amperometric detection. Cyclic voltammetry of iodide was conducted in a phosphate buffer pH 5. Experiments were performed using glassy carbon (GC) electrode as a comparison. Well-defined oxidation waves of the quasi-reversible cyclic voltammograms were observed at both electrodes. Voltammetric signal-to-background ratios (S/B) were comparable. However, the GC electrode gives much greater in the background current as usual. The potential sweep rate dependence exhibited that the peak current of iodide oxidation at 1mM varied linearly (r(2) = 0.998) with the square root of the scan rate, from 0.01 to 0.30Vs(-1). This result indicates that the reaction is a diffusion-controlled process with negligible adsorption on BDD surface, at this iodide concentration. Results of the flow-injection analysis show a highly reproducible amperometric response. The linear working range was observed up to 200muM (r(2) = 0.999). The detection limit, as low as 0.01muM (3sigma of blank), was obtained. This method was successfully applied for quantification of iodide contents in nuclear emergency tablets.
authors.affiliation: Department of Chemistry, Faculty of Science, Chulalongkorn University, Patumwan, Bangkok 10330, Thailand.
authors.forename: O
authors.initials: O
authors.lastname: Chailapakul
authors.forename: M
authors.initials: M
authors.lastname: Amatatongchai
authors.forename: P
authors.initials: P
authors.lastname: Wilairat
authors.forename: K
authors.initials: K
authors.lastname: Grudpan
authors.forename: D
authors.initials: D
authors.lastname: Nacapricha