Enantioselective synthesis of cyclopropylcarboxamides using s-BuLi-sparteine-mediated metallation.
Enantioselective synthesis of cyclopropylcarboxamides is possible by asymmetric metallation of prochiral starting cyclopropanes using s-BuLi-sparteine.
Lauru
Stephanie
S
School of Chemistry, The University of Nottingham, University Park, Nottingham, UK.
Simpkins
Nigel S
NS
Gethin
David
D
Wilson
Claire
C
D000577:Amides / Q000737:chemistry*; D002384:Catalysis; D018360:Crystallography, X-Ray; D003521:Cyclopropanes / Q000737:chemistry*; D008094:Lithium / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D013034:Sparteine / Q000737:chemistry*; D013237:Stereoisomerism
D000577:Amides; D003521:Cyclopropanes; D013034:Sparteine; D008094:Lithium