title: Determination of refractory elements in U(3)O(8) by carrier distillation emission spectrography.
abstract: An emission spectrographic method using carrier distillation for the determination of the refractory impurities Ta, Hf, Nb, Th, and W in uranium is described. Different carriers, such as Ga(2)O(3), AgCl, AgCl + LiF, and AgCl + NaF in various proportions, were investigated: a 1% NaF + 9% AgCl mixture as carrier at 10% of total charge arced was found to be the most suitable. Spectra were excited in a d.c. arc at 12 A and were photographed with 35-sec exposures. Palladium was used as an internal standard. The lowest limits of determination lie in the range 1-10 ppm for a 100-mg charge. The precision of the method is about 16% or better.
authors.affiliation: Radiochemistry Division, Bhabha Atomic Research Centre, Trombay, Bombay 400085, India.
authors.forename: A G
authors.initials: AG
authors.lastname: Dalvi
authors.forename: C S
authors.initials: CS
authors.lastname: Deodhar
authors.forename: T K
authors.initials: TK
authors.lastname: Sheshagiri
authors.forename: M S
authors.initials: MS
authors.lastname: Khalap
authors.forename: B D
authors.initials: BD
authors.lastname: Joshi