A nanoporous chiral metal-organic framework material that exhibits reversible guest adsorption.
Assembly of the novel homochiral ligand L(S) (where L(S) is 1,4-benzylidene-bis(S,S)-4-yl-3,5-bis(1-hydroxyethyl)-1,2,4-triazole) and AgNO3 generates a robust, porous, chiral and cationic framework that exhibits reversible guest adsorption.
Iremonger
Simon S
SS
School of Chemistry, University o f Sydney, Sydney, NSW 2006, Australia.
Southon
Peter D
PD
Kepert
Cameron J
CJ
D000327:Adsorption; D001597:Benzylidene Compounds / Q000737:chemistry*; D008024:Ligands; D008956:Models, Chemical; D015394:Molecular Structure; D049329:Nanostructures / Q000737:chemistry*; D016062:Porosity; D012835:Silver Nitrate / Q000737:chemistry*; D013237:Stereoisomerism; D014230:Triazoles / Q000737:chemistry*
C542726:1,4-benzylidene-bis(S,S)-4-yl-3,5-bis(1-hydroxyethyl)-1,2,4-triazole; D001597:Benzylidene Compounds; D008024:Ligands; D014230:Triazoles; D012835:Silver Nitrate