Kinetic evidence for a charge-transfer mechanism in the interaction of ammonia with 2,4-dinitrophenylhydrazine in dimethylsulphoxide.
Kinetic evidence is adduced to show that charge-transfer is involved in the interaction of ammonia with 2,4-dinitrophenylhydrazine in dimethylsulphoxide. The charge-transfer mechanism is further confirmed by the linear relation between the ionization potential and molar absorptivity of the complex for three aliphatic amines.
Qureshi
P M
PM
Department of Chemistry, Aligarh Muslim University, Aligarh-202001, India.
Singh
S B
SB
Iqbal
S
S
Kamoonpuri
M
M
Khan
I A
IA