title: Kinetic spectrofluorimetric determination of silver, based on its catalytic effect on the oxidation of pyrocatechol-1-aldehyde 2-pyridylhydrazone by peroxodisulphate in the presence of 1,10-phenanthroline as activator.
abstract: A kinetic fluorimetric method for the determination of silver is described, based on its catalytic effect on the oxidation of pyrocatechol-1-aldehyde 2-pyridylhydrazone by peroxodisulphate. In aqueous solution silver concentrations of 0.2-0.8 mug ml can be determined, and 10-80 ng ml in the presence of 1,10-phenanthroline as activator. The fluorescent species obtained (lambda(ex) 357 nm, lambda(em) 445 nm) results from oxidation of the reagent. The kinetic parameters and the interferences are reported, and the method is applied to the determination of silver in developed panchromatic plates.
authors.affiliation: Department of Analytical Chemistry, University of La Laguna, La Laguna, Tenerife, Spain.
authors.forename: A M
authors.initials: AM
authors.lastname: Afonso
authors.forename: J J
authors.initials: JJ
authors.lastname: Santana
authors.forename: F G
authors.initials: FG
authors.lastname: Montelongo