title: Use of zeo-karb 226 and dowex a-l in the analysis of high-purity zinc and zinc-base alloys for Tl and In.
abstract: Utility of Zeo-Karb 226 and Dowex A-l for the separation of Tl and In at 5-ppm level from high-purity zinc and zinc-base alloys has been investigated. With Zeo-Karb 226 (NH(4)(+)), T1(+) is conveniently separated from these materials and also from many other cations, with l.0M ammonium nitrate as the eluent. It is subsequently determined with Rhodamine B. This separation principle is also applied to the analysis of Pb-Tl alloys. Both Tl and In (along with Fe) are preconcentrated on Zeo-Karb 226(H(+)) from a solution of the sample at pH 3.0. Suitable methods of subsequent determination of Tl and In are described. In the case of Dowex A-1(H(+)), Tl(+), In(3+), Fe(3+) and Cu(2+) are retained from a solution of the sample at pH 2.0. An o-phenanthroline solution at pH 2.0 elutes all but traces of Cu(2+). In(3+) along with Fe(3+) is eluted with l.0M hydrochloric acid. Finally, Tl is eluted with 2.0M hydrochloric acid containing sulphurous acid.
authors.affiliation: Analytical Chemistry Division, Bhabha Atomic Research Centre, Bombay-400 085, India.
authors.forename: S G
authors.initials: SG
authors.lastname: Iyer
authors.forename: P K
authors.initials: PK
authors.lastname: Padmanabhan
authors.forename: L D
authors.initials: LD
authors.lastname: Nair
authors.forename: C
authors.initials: C
authors.lastname: Venkateswarlu