Diffusion coefficients and complex equilibria in solution-II Approximate evaluation of formation constants.
It is shown, for four systems containing complexes of widely differing stabilities, that a very fair assessment of the values of formation constants is obtainable from the data pairs Deltai(d) log [X] (the pseudo-formation curve). This is seen as a preliminary exercise to the more precise analysis which is possible in terms of mean diffusion coefficients which feature in equations reported earlier.
Crow
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Department of Physical Sciences, The Polytechnic, Wolverhampton, England.