Hot-injection procedures for the rapid analysis of biological samples by electrothermal atomic-absorption spectrometry.
The combination of palladium/hydrogen matrix-modification and injection of samples into a graphite tube at 120 degrees has allowed the accurate determination of copper, iron, lead and nickel in biological reference materials (urine, milk powder and bovine liver). Palladium modification allowed the use of a standard ashing temperature of 1000 degrees for all four elements. Direct aqueous calibration was applied without the need for standard additions. The total heating cycle, from the start of sample injection, took 45 sec.
Kunwar
U K
UK
Department of Pure & Applied Chemistry, University of Strathclyde, Cathedral Street, Glasgow G1 1XL, U.K.
Littlejohn
D
D
Halls
D J
DJ