Emission spectra of nitrous oxide supported acetylene flames at atmospheric pressure.
The emission spectra of a premixed flame of acetylene supported by nitrous oxide have been recorded under different fuel-gas mixture conditions. The emission spectra in these flames of a series of metals, for which it is difficult to obtain a significant population of ground state atoms for atomic absorption spectroscopy in more conventional flames, have also been studied. The red secondary zone which is present in the fuel-rich flames shows emission attributable to long-lived CN and NH species which form a strongly reducing atmosphere to inhibit refractory oxide formation from elements such as molybdenum, titanium and aluminium introduced into the flame. An attempt has also been made to explain some of the reactions which may occur between the flame species above the primary reaction zone.
Kirkbright
G F
GF
Chemistry Department, Imperial College, London S.W.7 UK.
Peters
M K
MK
West
T S
TS