title: Determination of 3-amino-1,2,4-triazole (amitrole) in environmental waters by capillary electrophoresis.
abstract: 3-Amino-1,2,4-triazole (amitrole) is a widely used pesticide, with many difficulties to be analyzed at the regulatory level in drinking water, because its high solubility in water. This paper describes a simple and fast method for the simultaneous determination of amitrole and atrazin-2-hydroxy, principal degradation product of s-triazines, by capillary zone electrophoresis. Separation and determination of these herbicides in water samples was performed in 0.02 mol l(-1) phosphate buffer at pH 3.2. The method allows determination of the amitrole and atrazin-2-hydroxy in water samples in concentration lower than 100 mug l(-1). The detection limits using a previous preconcentration step of amitrole in Alberche River (Comunidad Autónoma de Madrid, Spain) and drinking water spiked samples was of 4 mug l(-1).
authors.affiliation: Departamento de Quimica Analitica y Análisis Instrumental, Facultad de Ciencias, Universidad Autónoma de Madrid, 28049 Madrid, Spain.
authors.forename: M
authors.initials: M
authors.lastname: Chicharro
authors.forename: A
authors.initials: A
authors.lastname: Zapardiel
authors.forename: E
authors.initials: E
authors.lastname: Bermejo
authors.forename: M
authors.initials: M
authors.lastname: Moreno