An investigation of the diethyldithio-carbamates of palladium, including the determination of their stability constants.
The reaction of palladium with copper diethyldithio-carbamate has been studied and two complexes isolated: palladium diethyldithiocarbamate and palladium chloride diethyldithiocarbamate. The spectra of both complexes have been examined. The extraction constants and partition coefficients between chloroform and water have been determined, the former by the use of other strong complexing reagents as masking agents for palladium. The stability constants and the exchange constant for the two complexes have been calculated.
Briscoe
G B
GB
Department of Chemistry, The University of Aston in Birmingham, Gosta Green, Birmingham 4, England.
Humphries
S
S