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The basic computer program MICMAC has been developed to fit equilibrium constants to various types of experimental data with a microcomputer. The program uses the very efficient Gauss-Newton-Marquardt algorithm for non-linear least-squares multiparametric refinement. Highly interactive, convenient to use and of modular design, it allows for a rigorous weighting scheme, and it takes account of possible systematic errors. This program is useful for solving problems with several sets of experimental data. Some examples dealing with polarography, pH-metric titration and (13)C-NMR are given, illustrating the versatility of MICMAC. Comparison is made with some recently published programs.
Laouenan
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Laboratoire de Chimie Analytique, LA CNRS 322, Université de Bretagne Occidentale, 6, Avenue le Gorgeu, 29283 Brest-Cédex, France.
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