Application of platinum gauze activated by hydrogen to the adsorption separation of silver traces and their determination by aas or spectrophotometry.
A method ("electrosorption") has been developed for separation of silver from copper by its deposition through internal electrolysis with hydrogen adsorbed on a platinum surface. The silver can then be stripped and determined by atomic-absorption spectrometry or the dithizone method. The activation of the platinum surface with adsorbed hydrogen can be achieved either electrolytically or by passing hydrogen gas through the solution in which the platinum is immersed. The method of electrosorption has been successfully applied to determination of trace levels of silver in copper metal.
Boguszewska
Z
Z
Department of Analytical Chemistry, Technical University of Warsaw, 00-664 Warsaw, ul. Noakowskiego 3, Poland.
Krasiejko
M
M
Palmowska-Kuś
B
B