title: Atomic-absorption determination of beryllium in liquid environmental samples.
abstract: A method is described for the atomic-absorption determination of beryllium in liquid environmental samples after separation by solvent extraction and cation-exchange. The beryllium is first isolated from natural waters and beverages by chloroform extraction of its acetylacetonate from a solution at pH 7 and containing EDTA. The chloroform extract is then mixed in the ratio of 3:6:1 with tetrahydrofuran and methanol containing nitric acid, and passed through a column of Dowex 50 x 8 (H(+)-form). After removal of acetylacetone, chloroform and tetrahydrofuran by washing the resin bed with methanol-HNO(3), beryllium is eluted with 6M hydrochloric acid and determined by atomic-absorption spectroscopy. The method was successfully applied to determine beryllium in tap-, river- and sea-water samples, mineral waters and wines. Beryllium contents in the range from < 0.01 to 2.3 microg/l were found in these materials.
authors.affiliation: Institute for Analytical Chemistry, Analysis of Nuclear Raw Materials Division, University of Vienna, Währingerstrasse 38, A-1090 Vienna, Austria.
authors.forename: J
authors.initials: J
authors.lastname: Korkisch
authors.forename: A
authors.initials: A
authors.lastname: Sorio
authors.forename: I
authors.initials: I
authors.lastname: Steffan