Development of a nitrate ion-selective electrode based on an Urushi matrix membrane and its application to the direct measurement of nitrate-nitrogen in upland soils.
A solid-state nitrate ion-selective electrode based on an Urushi matrix membrane was developed. Urushi, a natural oriental lacquer, has excellent mechanical strength and binding affinity for metal electrodes. Using the same technique for a dip-coating ion-selective electrode, an electrode was prepared by coating and hardening a sensing membrane on the metal base. The effects of the metal electrode on the electrode potential stability, the liquid-membrane components and the oven temperature for hardening of membrane were studied. The sensing membrane, consisting of 27.5 wt.% of o-nitrophenyl octyl ether. 27.5 wt.% of tri-n-octylmethylammonium nitrate and 45 wt.% of raw Urushi latex, was coated with a thickness of 0.5 mm on a silver disc which was plated with Ag/AgCl, then plated with copper and hardened in the oven at 80 degrees C for 50 h. A semi-logarithmic calibration curve of potential versus nitrate ion concentration was obtained over the range 6-60 000 mg l(-1) NO(3)(poststaggered-). The slope of the linear part of the curve was -56 mV per decade change in NO(3)(poststaggered-) concentration. Compared with a PVC matrix nitrate ion-selective electrode, the Urushi matrix nitrate ion-selective electrode was superior in terms of hardness and mechanical strength of the membrane, short response time and long life. The combination of an Urushi matrix nitrate ion-selective electrode with a porous PTFE junction reference electrode, air-tight structured KCl solution chamber and a temperature sensor was applied to field measurements of nitrate-nitrogen concentrations in upland soils. The values obtained for upland soils containing 30-50% of water were good agreement with those for soil solution.
Ito
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S
Applied R & D Department, DKK Corporation, 4-13-14, Kichijoji Kitamachi, Musashino, Tokyo 180, Japan; Department of Applied Chemistry, Nagoya Institute of Technology, Gokiso, Showa, Nagoya 466, Japan.
Baba
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K
Asano
Y
Y
Takesako
H
H
Wada
H
H