Extraction of tetra-alkylammonium bromides into 1,2-dichloroethane + alkane mixtures.
The influence of an inert diluent on the extractability of tetradecyltrimethyl-, tetradecyl-triethyl-, decyltriethyl- and tetra-amylammonium bromides into 1,2-dichloroethane + n-alkane mixtures at 25 degrees has been determined. On the basis of the experimental data it is suggested that the bromide moiety of the ion-pair is solvated in the organic phase by 5-6 molecules of 1,2-dichloroethane.
Czapkiewicz
J
J
Institute of Chemistry, Jagiellonian University, 30060 Kraków, Poland.
Wolinska
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A