title: Determination of rate constants and reaction orders with an open-closed flow-injection configuration.
abstract: A new, very useful application of open-closed configurations to kinetic studies is reported. The multipeak recordings provided by the manifold used, which features a single conventional photometric detector, were used to calculate the rate constants and reaction orders of a chemical system, namely the ligand displacement reaction between the cobalt(II)-EGTA complex and PAR.
authors.affiliation: Department of Analytical Chemistry, Faculty of Sciences, University of Córdoba, 14004 Córdoba, Spain.
authors.forename: S D
authors.initials: SD
authors.lastname: Kolev
authors.forename: A
authors.initials: A
authors.lastname: Rios
authors.forename: M D
authors.initials: MD
authors.lastname: de Castro
authors.forename: M
authors.initials: M
authors.lastname: Valcarcel