Extraction chromatographic studies of metal ions using N,N,N',N'-tetraoctyl diglycolamide as the stationary phase.
N,N,N',N'-tetraoctyl diglycolamide (TODGA) has been used as the stationary phase in the extraction chromatographic separation of actinides and other metal ions from pure nitric acid as well as from simulated high-level waste (SHLW). Chromosorb-W was found to be a better support material amongst the different solid supports evaluated viz. chromosorb-W, chromosorb-102, XAD-4 and XAD-7. Uptake profiles of various metal ions, such as U(VI), Pu(IV), Am(III), Eu(III), Fe(III), Sr(II) and Cs(I) were obtained as a function of acidity by batch studies using TODGA/chromosorb-W. Effect of macro concentration of Nd, Fe and U suggested that the uptake of Am(III) is mainly influenced by the presence of trivalent lanthanide ions. Breakthrough capacity of the resin material for Am(III) in presence of macro amount of Eu(III) was determined in the successive cycles of loading and elution. Loading capacity of the column was found to be 20mg of Eu/g of the resin material. Elution studies of Am(III) suggested that 0.01M EDTA was effective amongst different eluents used.
Ansari
S A
SA
Radiochemistry Division, Bhabha Atomic Research Centre, Mumbai 400 085, India.
Pathak
P N
PN
Husain
M
M
Prasad
A K
AK
Parmar
V S
VS
Manchanda
V K
VK