Rhodium-catalysed cyclisation reaction of allenynes with arylboronic acids.
Allenynes having malonate-based tethers reacted with arylboronic acids in the presence of a rhodium(I) catalyst to sequentially form three carbon-carbon bonds, and arylated bicyclic skeletons were constructed in a stereoselective manner.
Miura
Tomoya
T
Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto, Japan.
Ueda
Keita
K
Takahashi
Yusuke
Y
Murakami
Masahiro
M
D000466:Alkadienes / Q000737:chemistry; D000480:Alkynes / Q000737:chemistry*; D001897:Boronic Acids / Q000737:chemistry*; D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000138:chemical synthesis / Q000737:chemistry; D002384:Catalysis; D003500:Cyclization; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
D000466:Alkadienes; D000480:Alkynes; D001897:Boronic Acids; D019086:Bridged Bicyclo Compounds, Heterocyclic; D009942:Organometallic Compounds; D012238:Rhodium