Preparation of a polypyrrole electrode modified with a nickel phthalocyanine complex. Application to the determination of an antioxidant (propylgallate) in foods.
In this paper a study of the electrocatalytic oxidation of propylgallate (PG) by using a polypyrrole electrode modified with tetrasulfonate nickel (II) phthalocyanine complex (Pt/PPy/NiPcTs) was carried out. Several parameters of this polymeric electrode, such as: (a) its stability in hydroorganic solution, by using an indium tin oxide (ITO) electrode and spectrophotometry; and (b) its thickness using electrochemical techniques, have been studied. In addition, several parameters affecting the PG voltammetric peak, such as pH, methanol water ratio, potential scan rate and analyte concentration, were considered. Finally, the developed method was applied to the determination of PG in spiked potato flakes and cornflakes, showing its validity.
de la Fuente
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Department of Analytical Chemistry, Faculty of Sciences, University of Valladolid, Valladolid, Spain.
Acuña
J A
JA
Vázquez
M D
MD
Tascón
M L
ML
Gómez
M I
MI
Batanero
P S
PS