title: Inductively coupled plasma-sector field mass spectrometry with a high-efficiency sample introduction system for the determination of Pu isotopes in settling particles at femtogram levels.
abstract: An analytical method for the determination of plutonium concentration and its isotope ratio ((240)Pu/(239)Pu) for settling particle samples by inductively coupled plasma mass spectrometry (ICP-MS) is presented. The generally used approach for Pu preconcentration by increasing the amount of samples is not applicable because of the small size of settling particle samples available for the analysis for Pu isotopes. Efforts were made to improve the sensitivity of a sector-field ICP-MS (SF-ICP-MS) and reduce the (238)UH(+) interference for Pu analysis by combining a high-efficiency sample introduction system (APEX-Q). An extremely low detection limit of 0.07 fg Pu was achieved, which allowed the determination of Pu isotope ratio at femtogram levels. The precision and accuracy of (240)Pu/(239)Pu isotope ratio analysis were carefully examined with a certified Pu isotope standard (NBS-947) and an ocean sediment reference material (IAEA-368). Simple anion-exchange chromatography for the separation and purification of Pu was combined with the APEX-Q/SF-ICP-MS system to determine Pu isotopes in settling particles collected in the East China Sea continental margin. The obtained results supported a previous observation on the lateral transport of Pu containing particles in this continental margin.
authors.affiliation: Nakaminato Laboratory for Marine Radioecology, National Institute of Radiological Sciences, Isozaki-cho, Hitachinaka, Ibaraki, Japan. jzheng@nirs.go.jp
authors.forename: Jian
authors.initials: J
authors.lastname: Zheng
authors.forename: Masatoshi
authors.initials: M
authors.lastname: Yamada