title: Syntheses, structures and properties of seven isomorphous 1D Ln3+complexes Ln(BTA)(HCOO)(H2O)3 (H2BTA = bis(tetrazoly)amine, Ln = Pr, Gd, Eu, Tb, Dy, Er, Yb) and two 3D Ln3+ complexes Ln(HCOO)3 (Ln = Pr, Nd).
abstract: Seven isomorphous 1D chain Ln3+ complexes Ln(BTA)(HCOO)(H2O)3 (Ln = Pr (1), Gd (2), Eu (3), Tb (4) Dy (5), Er (6) and Yb (7)), and two formate coordinating and bridging 3D Ln3+ complexes Ln(HCOO)3 (Ln = Pr (8) and Nd (9)) have been synthesized and characterized by single crystal X-ray diffraction analysis. Although the Ln3+ ions in 1-7 have different radius, the trivalent lanthanide ions in 1-7 show the same coordinated environment. The well-defined single crystal structures of 8 and 9 are first samples for formate-bridged Ln3+ metallic complexes. The luminescent properties of solid samples of 2-5 at room temperature and the magnetic property of 2 have been also reported and discussed in this paper.
authors.affiliation: Department of Chemistry, Guangzhou University, Guangzhou, 510006, P. R. China.
authors.forename: Jiao-Min
authors.initials: JM
authors.lastname: Lin
authors.forename: Yang-Fan
authors.initials: YF
authors.lastname: Guan
authors.forename: Dong-Yao
authors.initials: DY
authors.lastname: Wang
authors.forename: Wen
authors.initials: W
authors.lastname: Dong
authors.forename: Xiu-Teng
authors.initials: XT
authors.lastname: Wang
authors.forename: Song
authors.initials: S
authors.lastname: Gao