[Acidites et complexes des acides (alkyl-et aminoalkyl-) phosphoniques-IV: acides aminoalkylphosphoniques R(1)R(2)N(CH(2))(n)CR(3)R(4)PO(3)H(2)].
The acids under study differed from one another in length of the carbon chain [N + H(3)(CH(2))(n)PO(3)H(-) for n = 1, 2, 3], substitution on the nitrogen atom [R(1)R(2)N + HCH(2)PO(3)H(-) for R(1) = H; R(2) = Me, Et and R(1) = R(2)= Me, Et] or extent of branching on the carbon atom adjacent to functional groups [N + H(3)CR(3)R(4)PO(3)H(-) for R(3) = H; R(4) = Me, Et, nPr, iPr, nBu and R(3) = R(4) = Me]. Acidity constants and overall stability constants of complexes formed with Ca(II), Mg(II), Co(II), Ni(II), Cu(II), Zn(II) were obtained with the multiparametric refinement programs MUPROT and MUCOMP, applied to potentiometric data, obtained at 25 degrees , in a 0.1M potassium nitrate medium. In the most general case, the existing species are MHA(+), MA, M(OH)A(-), MH(2)A(2), MHA(-)(2) and MA(2-)(2), where A(2-) stands for the fully ionized ligand; preliminary examination of results points out some predominant microscopic forms.
Wozniak
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Laboratoire de Physico-chimie des Solutions, Ecole Nationale Supérieure de Chimie de Lille, B.P. 40, 59650 Villeneuve d'Ascq, France.
Nowogrocki
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