title: Ion-exchanger ultraviolet spectrophotometry for uranium(VI).
abstract: A sensitive method based on solid-phase spectrophotometry has been developed for the microdetermination of uranium(VI) in water samples. Uranium is sorbed on the anion-exchanger QAE-Sephadex from thiocyanate solution and the absorbance of the exchanger is measured at 300 nm. This method is about 30 times more sensitive than solution spectrophotometry. Absorption spectra of various metals in the anion-exchanger phase are presented and their interferences discussed. A procedure for the cation-exchange separation of uranium from accompanying elements before spectral measurement of uranium is proposed.
authors.affiliation: Institute of Analytical Chemistry, University of Vienna, Währingerstrasse 38, A-1090 Vienna, Austria.
authors.forename: H
authors.initials: H
authors.lastname: Waki
authors.forename: J
authors.initials: J
authors.lastname: Korkisch