title: Diborylenetetraaminoperylenes (DIBOTAP): a new class of highly fluorescent functional polycyclic aromatic hydrocarbons with N-B-N units.
abstract: A new class of N-B-N functionalized perylenes derived from N,N',N",N"'-diborylene-3,4,9,10-tetraaminoperylene (DIBOTAP) is readily accessible via several synthetic routes; they display intense green fluorescence and undergo two electrochemically reversible one-electron oxidation steps at approximately -0.2 V and 0.3 V (vs. SCE).
authors.affiliation: Anorganisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, Heidelberg, Germany.
authors.forename: Till
authors.initials: T
authors.lastname: Riehm
authors.forename: Gabriele
authors.initials: G
authors.lastname: De Paoli
authors.forename: Hubert
authors.initials: H
authors.lastname: Wadepohl
authors.forename: Luisa
authors.initials: L
authors.lastname: De Cola
authors.forename: Lutz H
authors.initials: LH
authors.lastname: Gade
mesh_terms: D001895:Boron / Q000737:chemistry*; D003198:Computer Simulation; D018360:Crystallography, X-Ray; D004563:Electrochemistry; D004583:Electrons; D005453:Fluorescence; D008956:Models, Chemical; D008958:Models, Molecular; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry*; D010084:Oxidation-Reduction; D010569:Perylene / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry; D011084:Polycyclic Aromatic Hydrocarbons / Q000138:chemical synthesis / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: C534286:N,N',N'',N'''-diborylene-3,4,9,10-tetraaminoperylene; D011084:Polycyclic Aromatic Hydrocarbons; D010569:Perylene; D009584:Nitrogen; D001895:Boron