Calculation of the Cu(II)-thiosemicarbazone complex formation constants by a modification of the deford and hume method applicable to quasi-reversible and irreversible processes.
Six cupric thiosemicarbazonates have been studied by differential pulse polarography and their formation constants calculated by the DeFord and Hume method and by a modification of this method applicable to quasi-reversible and irreversible processes. Comparison of the values found by both procedures shows the validity of the suggested modification.
Argüeso
M
M
Department of Analytical Chemistry, Faculty of Sciences, University of Cordoba, Cordoba, Spain.
de Castro
M D
MD
Valcárcel
M
M