The solubility of alkali-metal fluorides in non-aqueous solvents with and without crown ethers, as determined by flame emission spectrometry.
The solubilities of LiF, NaF, KF, RbF and CsF in acetonitrile, acetone, tetrahydrofuran, dimethylformamide, benzene and cyclohexane have been determined with and without a crown ether (usually 0.1 M 18-crown-6) present. Flame emission spectrometry was the determination method. Three procedures, selected according to the miscibility of the solvent with water, and the solubility of the fluoride, are described. Samples, standards and blanks were matrix-matched. The precision varied between 1 and 10% RSD. Although extensive drying procedures were applied, moisture present in the solvents and salts had some effect on the results.
Wynn
D A
DA
Chemistry Department, Marquette University, Milwaukee, WI 53233, USA.
Roth
M M
MM
Pollard
B D
BD