Development of a surface acoustic wave gas sensor for organophosphorus nerve agents employing lanthanide compounds as the chemical interface.
The results of a study dealing with surface acoustic wave gas sensors for organophosphorus compounds such as nerve agents are described. Several lanthanum coordination compounds were applied as the chemical interface. The various sensors prepared were challenged with both the nerve agent sarin and the simulant dimethyl methylphosphonate. Many aspects were studied, such as sensitivity, selectivity, reversibility and response rate as well as the effect of temperature and structural features. Detection limits down to 0.1 ppm were found. Response rates require further improvement. Degradation phenomena were observed which in some cases yielded irreversible responses. The selectivity for organophosphorus compounds was found to be promising.
Nieuwenhuizen
M S
MS
TNO Prins Maurits Laboratory, P.O. Box 45, 2280 AA Rijswijk, The Netherlands.
Harteveld
J L
JL