Synthesis and response of new microsensor coatings-II Acridinium betaines and anionic surfactants.
Four acridinium betaines and two ionic surfactants were synthesized, and evaluated as chemical microsensor coatings by exposure to vapors of chloroethyl ethyl sulfide (CEES) and dimethyl methylphosphonate (DMMP). Two of the acridinium betaines showed selective and reversible responses (of 9.8 and 6.8 kHz) as SAW (surface acoustic wave) coatings in the detection of CEES vapor: there appears to be a connection between the long alkyl chain (C-12 and C-14) in the acridinium molecules and the response. Response times were generally less than 30 sec but desorption was significantly slower. The ionic surfactant coatings show small SAW changes (> 0.5 kHz) in response to DMMP vapor, and somewhat greater responses (20- and 68-fold), as chemiresistors, to CEES vapor. In each case the response occurred within 3 min, with return nearly to baseline levels within 6 min of cessation of exposure to the vapor. The responses were reproducible within +/- 5%.
Katritzky
A R
AR
Department of Chemistry, University of Florida, Gainesville, FL 32611, U.S.A.
Offerman
R J
RJ
Aurrecoechea
J M
JM
Savage
G P
GP