Microscopic dissociation processes of some tyrosine derivatives.
The macroscopic and microscopic thermodynamic quantities relating to the dissociation of o-, m- and p-tyrosine, tyrosinol and tyramine have been determined at 25 degrees and I = 0.2 (KCl). The effects of the substituents are reflected unambiguously only in the DeltaG values and are due to changes in the solute-solvent interaction.
Kiss
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Department of Inorganic and Analytical Chemistry, Lajos Kossuth University, H-4010 Debrecen, Hungary.
Tóth
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