Evaluation of perchlorate tolerant photo-cured calcium selective electrodes for use in flow injection potentiometry.
A photo-cured membrane selective to calcium, based on the calcium bis [4-(1',1',3',3'-tetramethylbutyl)phenyl]phosphate ionophore and incorporating the lipophilic additive, potassium tetraki(4-chlorophenyl)borate, that can tolerate up to 200 nM perchlorate ionic background in the flow injection potentiometry mode has been previously reported (T. Dimitrakopoulos, J.R. Farrell and P.J. Ives, Electroanalysis, 8 (1996) 391). Improvements in the electrode slope and sensitivity of the previously described photo-cured calcium membrane-based electrode were achieved when anhydrous calcium chloride salt was dissolved into the pre-cured membrane composition and then photo-cured. Similar to the previously reported photo-cured calcium ion-selective electrode (ISE), the improved photo-cured calcium ISE can measure calcium in a high perchlorate background in the flow injection potentiometric mode.
Di Benedetto
L T
LT
Department of Physical Sciences, University of Tasmania, P.O. Box 1214, Launceston, Tas., 7250, Australia.
Dimitrakopoulos
T
T
Farrell
J R
JR
Iles
P J
PJ