title: Simultaneous determination of iron(III) and vanadium(V) by use of a kinetic-spectrophotometric and rapid mixing flow system.
abstract: The quantitative spectrophotometric determination of V(V) by its catalytic effect on the oxidation of chromotropic acid [the disodium salt of 4,5-dihydroxynaphthalene-2,7-disulphonic acid (CS)] by potassium bromate has been adapted to a flow system employing a rapid sample and reagent introduction manifold, in which valves and carrier streams are omitted without decreasing the precision or increasing the sample consumption relative to flow-injection analysis (FIA). Measurements are made at 420 nm. Coexisting Fe(III) can be determined simultaneously at the same wavelength by its more rapid colour chelate formation with CS. An accurate determination of V(V) and Fe(III) in the mixture was developed with a sample throughput of about 60 hr.
authors.affiliation: Department of Chemistry, Peking University, Beijing 100871, People's Republic of China.
authors.forename: H B
authors.initials: HB
authors.lastname: He
authors.forename: Y X
authors.initials: YX
authors.lastname: Ci
authors.forename: W B
authors.initials: WB
authors.lastname: Chang
authors.forename: W L
authors.initials: WL
authors.lastname: Gong