Crystal structures, thermal decompositions and sensitivity properties of [Cu(ethylenediamine)2(nitroformate)2] and [Cd(ethylenediamine)3](nitroformate)2.
Two new coordination compounds [Cu(ethylenediamine)(2)(nitroformate)(2)] and [Cd(ethylenediamine)(3)](nitroformate)(2) were synthesized and characterized through elemental analysis, IR and UV spectra. Their crystal structures were determined through X-ray single crystal diffraction. The first compound crystallizes in the triclinic space group P1; the second one crystallizes in the orthorhombic space group Pbca. For the first compound, central Cu(II) ion is hexa-coordinated with two ethylenediamine ligand molecules and two nitroformate anions to form the centrosymmetric octahedral structure. For the second one, central Cd(II) ion is hexa-coordinated with three ethylenediamine ligand molecules to form the slightly distorted octahedra. Through hydrogen bonds, molecules are linked together to form the three-dimensional packing diagrams. Thermal decomposition mechanisms of these two compounds were predicted through DSC, TG-DTG and FTIR analyses. In addition, the impact sensitivity, friction sensitivity and flame sensitivity were measured. All observed properties show that the first one has high energy, good thermal stability and moderate flame sensitivity.
Yang
Li
L
State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Haidian, Beijing, PR China.
Zhang
Jin
J
Zhang
Tonglai
T
Zhang
Jianguo
J
Cui
Yan
Y
D002104:Cadmium; D003300:Copper; D018360:Crystallography, X-Ray; D005029:Ethylenediamines / Q000737:chemistry*; D053834:Explosive Agents / Q000737:chemistry*; D006358:Hot Temperature; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*
D005029:Ethylenediamines; D053834:Explosive Agents; D009942:Organometallic Compounds; D002104:Cadmium; C031234:ethylenediamine; D003300:Copper