Application of the zone-melting technique to metal chelate systems-VI A new apparatus for zone-melting chromatography.
An improved apparatus has been constructed for zone-melting chromatography. An essential feature of the apparatus is that the length of the molten zone can be kept constant during a zone-melting operation, by employing heating and cooling compartments which are separated from each other by double partition plates. Each compartment is heated or cooled with jets of hot or cold air. The apparatus is suitable for organic materials melting in the range between 40 degrees and 180 degrees . The distribution of metal ion along the column after zone melting of copper acetylacetonate in 2-methoxynaphthalene was a smooth curve. The plot of the position of maximum concentration, x(max), against the number of zone passes, n, gave a relationship in accordance with theoretical prediction.
Maeda
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S
Department of Organic Synthesis, Faculty of Engineering, Kyushu University, Fukuoka 812, Japan.
Kobayashi
H
H
Ueno
K
K