1-Hydroxy-ethylidene-1,1-diphosphonic acid as a titrimetric agent.
1-Hydroxy-ethylidene-1,1-diphosphonic acid (HEDPHA) has been proposed as a highly selective titrimetric reagent for thorium. In the presence of 1,2-diaminocyelohexanetetra-acetic acid (DCTA) a soluble binuclear ternary complex, Th(2)(DCTA)(2)(HEDPHA), is formed. The determination of thorium is carried out in a slightly acidic medium, buffered with urotropine, with 0.025M HEDPHA, and Xylenol Orange as indicator. DCTA masks all bivalent metals, rare earths, scandium, yttrium, bismuth, iron, gallium and indium. Only zirconium, titanium, aluminium and large amounts of thallium(III) interfere.
Pribil
R
R
Laboratory for Analytical Chemistry, J. Heyrovský Polarographic Institute, Czechoslovak Academy of Sciences, Prague 1, Jilská 16, Czechoslovakia.
Veselý
V
V