title: Catalytic determination of ultratrace amounts of ruthenium with oscillopolarographic detection.
abstract: The oscillopolarographic behaviour of Methyl Red in sodium hydroxide medium has been studied, and the results show that the wave at -0.79 V is an irreversible two-electron adsorption wave. A very sensitive and selective catalytic reaction-oscillopolarographic method for the determination of Ru down to 3 ng/l. is described, based on the Ru(III)-catalysed redox reaction of Methyl Red and potassium periodate in hydrochloric acid medium. Potassium thiocyanate is used to quench the reaction and the oscillopolarography is then performed with sodium hydroxide as the supporting electrolyte. The influence of 41 foreign ions has been examined. Ruthenium in ore samples has been determined by the method, with satisfactory results.
authors.affiliation: Laboratory of Instrumental Analysis, Department of Chemistry, Guangxi Normal University, Guilin, People's Republic of China.
authors.forename: J
authors.initials: J
authors.lastname: Zhi-Liang