Stability constants of chloro-complexes of cadmium(II) in sea-water medium.
Potentiometry with ion-selective electrodes and anodic stripping voltammetry were used to measure the stability constants for cadmium chloro-complexes at 20 +/- 0.1 degrees in synthetic sea-water and at an ionic strength of 0.700 (NaClO(4) + NaCl). The values of beta(ML) and beta(ML(2)) obtained by the two methods are in good agreement.
Simoes
M L
ML
Centro de Química Estrutural, Complexo Interdisciplinar, Lisboa, Portugal.
Vaz
M C
MC
da Silva
J J
JJ