Determination of gallium by square-wave voltammetry anodic stripping, based on the electrocatalytic action of 2,2'-bipyridine in dimethylsulphoxide: comparison with an aqueous NaSCN/NaClO(4) electrolyte.
Deposition potential, deposition time, square-wave frequency, 2,2'-bipyridine concentration, and gallium concentration have been studied in detail, for the determination of trace concentration levels of the metal by square-wave voltammetry anodic stripping analysis, in dimethylsulphoxide. Optimum conditions have been found for gallium(III) determination and results compared to those obtained in 0.5M NaSCN + 4.2M NaClO(4) aqueous electrolyte by obtaining calibration graphs for the range 1 x 10(-8)M-1 x 10(-5)M gallium. Accuracy (+/- 3%) and precision (4-6% SD) of this method were assessed with both 4 x 10(-8)M and 4 x 10(-7)M gallium solutions used as synthetic samples. The efficiency of solvent extraction of gallium with di-isopropyl ether was found to be 99.98% at a 4 x 10(-7)M gallium concentration. The proposed method was applied to the determination of the gallium content in rock mineral samples (using the above mentioned solvent extraction procedure), are compared to those obtained with the NaSCNNaClO(4) based electrolyte. No statistically significant difference was observed. Analytical procedures followed are given in detail.
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