title: Extractive concentration of platinum-group elements and their determination by atomic-absorption spectrophotometry.
abstract: The extraction of Pt, Pd, Ir, Rh, Ru, Ag, Au, Co, Cu, Ni and Fe with n-octylaniline has been investigated. Noble metals are extracted 10(3)-10(4) times better than Cu, Ni, Co and Fe. A method of determination of Pt, Pd, Ir, Rh and Ru is proposed. They are first separated from Cu, Ni, Co and Fe by means of extraction (and then determined, in either the aqueous or organic phase, by atomic-absorption spectrophotometry. The atomic absorption of platinum metals (with the exception of Pd) is affected by other elements of the platinum group and by non-noble metals. La(NO(3))(3) and Nd(NO(3))(3) lower the limit of detection for Pt, Rh, Ir and Ru and inhibit the effect of Co, Cu, Ni, Fe, Bi, Zn, Na, etc. on their determination. Lanthanum and neodymium chlorides and sulphates produce a similar effect but only on the determination of Pt and Rh. The coefficient of variation of the determination, in both phases, is within 2-6.8%.
authors.affiliation: Institute of Inorganic Chemistry, Siberian Division of the Academy of Sciences, Novosibirsk, U.S.S.R.
authors.forename: A A
authors.initials: AA
authors.lastname: Vasilyeva
authors.forename: I G
authors.initials: IG
authors.lastname: Yudelevich
authors.forename: L M
authors.initials: LM
authors.lastname: Gindin
authors.forename: T V
authors.initials: TV
authors.lastname: Lanbina
authors.forename: R S
authors.initials: RS
authors.lastname: Shulman
authors.forename: I L
authors.initials: IL
authors.lastname: Kotlarevsky
authors.forename: V N
authors.initials: VN
authors.lastname: Andrievsky