Multicomponent analysis in luminescence spectroscopy.
Multicomponent analysis of absorption spectra (infrared or electronic spectra) by factor analysis is a suitable method to use. The algorithm of factor analysis is now available for luminescence spectroscopy. The first possibility, as in absorption spectroscopy, is to determine pure components emission spectra for a unique set of spectra of mixtures in overdetermined conditions. On the other hand, it is also possible to extract pure components emission and excitation spectra of the only data corresponding to the 3D fluorescent spectrum of a single mixture. The results are evaluated in respect to noise level and concentrations ratio on both simulated and real spectra.
Dalibart
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LSMC URA 124, Universite Bordeaux I, 351 Cours de la Liberation, 33405 Talence Cedex, France.