Study of the factors which affect the reaction of the ferrous ion with tripyridyltriazine.
The reaction of tripyridyltriazine with iron(II) has been studied. The acid dissociation constant and water solubility of the ligand have been determined. The formation constant of the chelate has also been evaluated. An explanation of the change in molar absorptivity of the chelate when dissolved in water or nitrobenzene is offered. The analytical implication of these constants is discussed.
Buchanan
E B
EB
Department of Chemistry, University of Iowa, Iowa City, Iowa 52240, U.S.A.
Crichton
D
D
Bacon
J R
JR