title: Determination of submicrogram amounts of Mercury(II) with 5-(2'-carbomethoxyphenyl)azo-8-quinolinol in presence of anionic surfactant by derivative spectrophotometry.
abstract: A new sensitive, rapid and selective method is proposed for the determination of mercury in submicrogram level. Mercury(II) forms an insoluble complex with 5-(2'-carbomethoxyphenyl)azo-8-quinolinol in aqueous medium at pH 4-4.8 which can be made soluble by the action of anionic surfactant. The dissolution of the complex results in an orange red colour which is stable for at least 20 hr. The molar absorptivity and Sandell's sensitivity are at 512 nm 8.00 x 10(4) l. mol(-1) . cm(-1) and 0.0025 mug/cm(2), respectively. Derivative spectrophotometry is used to achieve selectivity.
authors.affiliation: Chemical Laboratory, Regional Centre for Exploration and Research, Atomic Minerals Division, Department of Atomic Energy, Assam Rifles (P.O.), Shillong 793011, India.
authors.forename: R
authors.initials: R
authors.lastname: Saran
authors.forename: T S
authors.initials: TS
authors.lastname: Baul