title: Simultaneous determination of copper and lead in seawater using optimised thin-mercury film electrodes in situ plated in thiocyanate media.
abstract: In the present work the anodic stripping voltammetric (ASV) methodology using a thin mercury film electrode in situ plated in thiocyanate media was re-assessed in order to allow the simultaneous determination of copper and lead in seawater. Under previously suggested conditions [6], i.e. using a concentration of thiocyanate of 5mM, the ASV peaks of copper and lead overlapped due to the formation of a stable copper(I)-thiocyanate species, limiting the analytical determinations. Therefore, the best value for the thiocyanate concentration was re-evaluated: for 0.05mM a trade-off between good resolution of the copper and lead peaks and high reproducibility of the mercury film formation/removing processes was achieved. In this media, the ASV peaks for Pb and Cu occurred, separated by 140mV. Also, the in situ thin mercury film electrode was produced and removed with good repeatability, which was confirmed by the relative standard deviation values for the ASV determinations: 0.5% for Pb and 2.0% for Cu (10 replicate determinations in a solution with metal concentrations 1.5x10(-8)M for lead and 2.2x10(-8)M for copper). The optimised methodology was successfully applied to the determination of copper in the presence of lead, in certified seawater (NASS-5).
authors.affiliation: Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal.
authors.forename: Helena M
authors.initials: HM
authors.lastname: Carapuça
authors.forename: Sandra C C
authors.initials: SC
authors.lastname: Monterroso
authors.forename: Luciana S
authors.initials: LS
authors.lastname: Rocha
authors.forename: Armando C
authors.initials: AC
authors.lastname: Duarte