On the theory of thermometric titration.
The general equation defining the change in solution temperature DeltaT during a thermometric titration is DeltaT = T - T(0) = - AV 1 + BV where A and B are constants, V is the volume of titrant used to produce temperature T, and T(0) is the initial temperature. There is a linear relation between the inverse values of DeltaT and V: 1 Delta T = - a V - b where a = 1/A and b = B/A, both a and b being constants. A linear relation between DeltaT and V is usually a special case of this general relation, and is valid only over a narrow range of V. Graphs of 1/DeltaTvs. 1/V are more suitable for practical calculations than the usual graphs of DeltaTvs. V.
Piloyan
G O
GO
The Institute for Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry U.S.S.R. Academy of Sciences Staromonetny 35, Moscow 109017, U.S.S.R.
Dolinina
Y V
YV