title: Tensile and tribological properties of high-crystallinity radiation crosslinked UHMWPE.
abstract: Osteolysis due to particulate wear debris associated with ultrahigh molecular weight polyethylene (UHMWPE) components of total joint replacement prostheses has been a major factor determining their in vivo lifetime. In recent years, radiation crosslinking has been employed to decrease wear rates in PE components, especially in acetabular cups of total hip replacement prostheses. A drawback of radiation crosslinking is that it leads to a crosslinked PE (or XPE) with lower mechanical properties compared with uncrosslinked PE. In contrast, high-crystallinity PEs are known to have several mechanical properties higher than conventional PE. In this study, we hypothesized that increasing the crystallinity of radiation crosslinked and remelted XPE would result in an increase in tensile properties without compromising wear resistance. High-pressure crystallization was performed on PE and XPE and analyzed for the resulting morphological alterations using differential scanning calorimeter, low voltage scanning electron microscopy, and ultrasmall angle X-ray scattering. Uniaxial tensile tests showed that high-pressure crystallization increased the tensile modulus and yield stress in both PE and XPE, decreased the ultimate strain and ultimate stress in PE but had no significant effect on ultimate strain or ultimate stress in XPE. Multidirectional wear tests demonstrated that high-pressure crystallization decreased the wear resistance of PE but had no effect on the wear resistance of XPE. In conclusion, this study shows that high-pressure crystallization can be effectively used to increase the crystallinity and modulus of XPE without compromising its superior wear resistance compared with PE.
authors.affiliation: Department of Orthopaedic Surgery, Brigham and Women's Hospital, Harvard Medical School, Boston, Massachusetts 02115, USA.
authors.forename: Alessandro
authors.initials: A
authors.lastname: Bistolfi
authors.forename: Mary Beth
authors.initials: MB
authors.lastname: Turell
authors.forename: Ying-Lung
authors.initials: YL
authors.lastname: Lee
authors.forename: Anuj
authors.initials: A
authors.lastname: Bellare
mesh_terms: D002152:Calorimetry, Differential Scanning; D003460:Crystallization; D008855:Microscopy, Electron, Scanning; D011095:Polyethylenes / Q000737:chemistry*; D013718:Tensile Strength
chemical_list: D011095:Polyethylenes; C111601:ultra-high molecular weight polyethylene