Rotational spectrum and equilibrium structure of silanethione, H2Si=S.
Unsubstituted silanethione, H(2)Si=S, has been characterized experimentally for the first time by means of rotational spectroscopy; the equilibrium structure of this fundamental molecule has been evaluated through a combination of experimental data from a total of ten isotopologues and results of high-level coupled-cluster calculations.
Thorwirth
Sven
S
Max-Planck-Institut für Radioastronomie, Auf dem Hügel 69, Bonn, Germany. sthorwirth@mpifr-bonn.mpg.de
Gauss
Jürgen
J
McCarthy
Michael C
MC
Shindo
François
F
Thaddeus
Patrick
P