Dissociation constants and ultraviolet spectra of the conjugate acids of oximes.
A spectrophotometric method was used to determine the acid dissociation constants of the conjugate acids of dimethylglyoxime and biacetyl monoxime. The dissociation constant, the acidity function and the absorbance of a mixture of protonated and unprotonated oxime were utilized to obtain the ultraviolet spectra of the protonated oxime.
Ellefsen
P R
PR
Department of Chemistry, Case Institute of Technology, Cleveland, Ohio 44106, U.S.A.
Gordon
L
L