Determination of iridium in mafic rocks by atomic absorption.
Iridium is determined in mineralized mafic rocks by atomic absorption after fire-assay concentration into a gold bead. Inter-element interferences in the atomic-absorption determination are removed and Ir sensitivity is increased by buffering the solutions with a mixture of copper and sodium sulphates. Substantial amounts of Ag, Al, Au, Bi, Ca, Cd, Co, Cr, Fe, Ho, Hg, K, La, Mg, Mn, Mo, Ni, Pb, Te, Ti, V, Y, Zn and platinum metals can be tolerated in the atomic-absorption determination. The sensitivity and detection limits are 3.2 and 0.25 ppm of Ir, respectively.
Grimaldi
F S
FS
U.S. Geological Survey, Washington, D.C., U.S.A.
Schnepfe
M M
MM