New chromogens of the ferroin type-V Pyridylpyrimidines, bidiazines and other substituted derivatives of diazines.
Spectrophotometric studies of the reactions of iron(II), copper(I) and cobalt(II) with 33 new compounds have demonstrated that the chromogenic properties of diazyl groups are inferior to those of triazyl or pyridyl groups when incorporated into the ferroin chromophore group. The metal complexes of the diazyl derivatives are less stable than those of the corresponding pyridyl and triazyl derivatives. Conditional formation constants of the iron(II) chelates of some representative diazyl derivatives indicate that pyridazyl groups impart greater stabilities than pyrimidyl or pyrazyl groups. Five of the new chromogens have structures that suggest they can chelate iron(II) without steric hindrance, either as bidentate or as terdenate ligands. Although the terdentate mode would ordinarily be expected, two of the five were found to act preferably as bidentate ligands.
Schilt
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Department of Chemistry Northern Illinois University Dekalb, Illinois 60115, U.S.A.
Dunbar
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