Spectrophotometric determination of ruthenium with 8-quinolinol.
A spectrophotometric method is described for the determination of 2-80 mug of ruthenium. The method involves oxidation of ruthenium to ruthenate, addition of 8-quinolinol, adjustment of the pH to 4-6.5, digestion of the complex formed at 85 degrees for 30 min, extraction with chloroform, and measurement of absorbance at 430 nm. Almost all other metals and excess of reagent are removed by washing the extract. About 98 % of (106)Ru tracer was recovered.
Hashitani
H
H
Analytical Chemistry Laboratory, Japan Atomic Energy Research Institute, Tokai, Ibaraki, Japan.
Katsuyama
K
K
Motojima
K
K