Titration of vanadium(IV) with cerium(IV) sulphate, with ferroin as indicator, in aqueous acetone as facile reaction medium An analytical and mechanistic study.
A new procedure for the titration of vanadium(IV) with cerium(IV) sulphate, with ferroin as indicator, in aqueous acetone medium is reported. A differential determination of iron(II) and vanadium(IV) is also possible. A probable mechanism for the fast ferriin-vanadium(IV) reaction in acetone medium is given.
Sriramam
K
K
Department of Chemistry, Nagarjuna University, Nagarjuna Nagar, 522 510 (A.P.) India.
Sarma
B S
BS
Sundar
B S
BS
Sastry
N R
NR