title: Determination of NH(3) gas by combination of nanosized LaCoO(3) converter with chemiluminescence detector.
abstract: Combination of a novel NH(3) converter based on nanosized materials with chemiluminescence (CL) detector for the determination of NH(3) gas was demonstrated in this paper. NH(3) gas is oxidized on different nanosized catalysts to produce NO(x), which can react with luminol to generate CL emission. Eight nanosized materials were investigated as catalyst, and CL was detected from seven of them. The nanosized LaCoO(3) was chosen as the catalyst for preparing the converter because of its higher activity than others. Under the optimized conditions, the linear range of CL intensity versus concentration of NH(3) gas is 0.04-10 ppm (r=0.9951, n=14) with the detection limit of 0.014 ppm. The method offers advantages of long lifetime of the converter, fast response and high selectivity to NH(3). There was no response while the foreign substances, such as hydrogen, oxygen, nitrogen, formaldehyde, acetone and gasoline passing through the CL detection system, and the interference of CCl(4), ethanol, ethylene and toluene was insignificant.
authors.affiliation: Department of Chemistry, Analysis Center, Tsinghua University, Beijing 100084, China.
authors.forename: Jinjun
authors.initials: J
authors.lastname: Shi
authors.forename: Ruoxue
authors.initials: R
authors.lastname: Yan
authors.forename: Yongfa
authors.initials: Y
authors.lastname: Zhu
authors.forename: Xinrong
authors.initials: X
authors.lastname: Zhang