Interaction of cobalt(II) chloride with 2-nitroso-1-naphthol in a 96:4 benzene-ethanol solution.
The cobalt(II) chloride-2-nitroso-1-naphthol system has been studied spectrophotometrically in a 96:4 (v v ) benzene-ethanol solution. Two species have been found, the M:L complexation ratios of which are 1:1 and 1:2. The concentration quotients of the formation equilibria are K(1) = 1.2 x 10(3) and K(2) = 1.4 x 10(4) respectively. The first step of the reaction is accompanied by a configurational change from a tetrahedral to an octahedral structure.
Carunchio
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V
Institute of Analytical Chemistry, University of Rome, Rome, Italy.
Bondoli
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A
Fogaroli
M A
MA