Hydrostatic pressure effect on the phase transitions of a closed-loop type block copolymer by using 2D FTIR correlation spectroscopy.
The effect of hydrostatic pressure (P) on the phase transitions of polystyrene-block-poly(n-pentyl methacrylate) copolymer [PS-b-PnPMA] was investigated with FTIR spectroscopy at various temperatures. The experiments were performed by using a specially designed pressure cell optimized for low-pressure regime (<100 bar) with a higher resolution ( approximately 1 bar). The size of the closed loop consisting of both the lower disorder-to-order transition (LDOT) and the upper order-to-disorder transition (UODT) measured by FTIR spectroscopy becomes smaller with increasing P, consistent with results obtained from birefringence measurement. At lower temperatures with increasing P, the PS main chains are found to move before the PnPMA main chains. This is because the mobility of the PnPMA main chains is restricted due to the cluster formation of the alkyl side chain. At higher temperatures, the PnPMA block chains are more mobile than the PS block chains due to their larger specific volumes. The results indicate that the LDOT is mainly affected by a favorable directional interaction between PS and PnPMA blocks due to the cluster formation of the alkyl side chain, whereas the UODT depends on the combinatorial entropy.
Kim
Hye Jeong
HJ
National Creative Research Center for Block Copolymer Self-Assembly, Department of Chemical Engineering, Department of Chemistry, Pohang University of Science and Technology, Kyungbuk 790-784, Korea.
Kim
Seung Bin
SB
Kim
Jin Kon
JK
Jung
Young Mee
YM