title: Titrimetric determination of silicon dissolved in concentrated HF-HNO3-etching solutions.
abstract: The wet chemical etching of silicon by concentrated HF-HNO(3) mixtures in solar and semiconductor wafer fabrication requires the strict control of the etching conditions. Surface morphology and etch rates are mainly affected by the amount of dissolved silicon, that is continuously enriched in the etching solution with each etching run. A fast and robust method for the titrimetric determination of the total dissolved silicon content out of the concentrated etching solution is presented. This method is based on the difference between the two equivalence points of the total amount of acid and the hydrolysis of the hexafluorosilicic anion. This approach allows a silicon determination directly from the etching process in spite of the presence of dissolved nitric oxides in the etching solution. The influences of different acid mixing ratios and of the etching solution density depending on the silicon content is considered and discussed in detail.
authors.affiliation: Leibniz-Institute for Solid State and Materials Research Dresden (IFW Dresden), Dresden, Germany. a.henssge@ifw-dresden.de
authors.forename: Antje
authors.initials: A
authors.lastname: Henssge
authors.forename: Jörg
authors.initials: J
authors.lastname: Acker
authors.forename: Constanze
authors.initials: C
authors.lastname: Müller