Synthesis, characterization and oxidizing properties of a diorgano tellurone carrying bulky aromatic substituents.
Bis(2,4,6-triisopropylphenyl) tellurone (Tip(2)TeO(2)) was prepared, fully characterized by spectroscopic and X-ray crystallographic analyses, as well as theoretical calculations, and found to be an effective oxidizing agent that was capable of converting alcohols into carbonyl compounds under mild reaction conditions.
Oba
Makoto
M
Department of Materials Chemistry, Tokai University, 317 Nishino, Numazu, Shizuoka, Japan.
Okada
Yasunori
Y
Nishiyama
Kozaburo
K
Shimada
Shigeru
S
Ando
Wataru
W
D000438:Alcohols / Q000737:chemistry*; D000447:Aldehydes / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D018360:Crystallography, X-Ray; D006841:Hydrocarbons, Aromatic / Q000737:chemistry*; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D010084:Oxidation-Reduction; D013691:Tellurium / Q000737:chemistry*
D000438:Alcohols; D000447:Aldehydes; D006841:Hydrocarbons, Aromatic; D007659:Ketones; D009942:Organometallic Compounds; D013691:Tellurium