Potentiometric and visual titrations with bromamine-B.
Bromamine-B is proposed as an oxidimetric titrant for potentiometric and visual end-point titrations of arsenic(II), hexacyanoferrate(II), antimony(III), hydroquinone, semicarbazide hydrochloride, isonicotinic acid hydrazide, hydrazine sulphate, ascorbic acid, phenylhydrazine hydrochloride and metol. Quinoline Yellow, naphthidine, dimethylnaphthidinedisulphonic acid, o-dianisidine, diphenylbenzidine, Variamine Blue, alpha-naphthoflavone, Amaranth, Methyl Orange and Methyl Red are proposed as indicators in macro and micro titrations of the reductants with bromamine-B. The transition potentials of Quinoline Yellow, naphthidine, dimethylnaphthidinedisulphonic acid, and o-dianisidine in the titration of ascorbic acid are reported. Arsenic(III) and hexacyanoferrate(II) are suggested for the standardization of bromamine-B solutions.
Gowda
H S
HS
Department of Post-graduate Studies & Research in Chemistry, University of Mysore, Manasa Gangotri, Mysore-570006, India.
Ahmed Khan
H N
HN