Substoichiometric separation in activation analysis: extraction of co-ordinatively-unsolvated salts.
The necessary conditions have been examined for the use of extraction of coordinatively-unsolvated salts for substoichiometric separations in activation analysis, especially the influence of interfering ions and of the concentration of the carrier. A study has been made of the substoichiometric extraction of halide ions, oxyanions and anionic metal complexes by means of the tetraphenylarsonium ion into chloroform and dichloroethane, and of the extraction of alkali metal ions into nitrobenzene with tetraphenylborate. Substoichiometric extraction can be combined with neutron-activation analysis for the determination of traces of iodine, caesium, rubidium, manganese, rhenium, chromium, thallium, gold, gallium and tantalum.
Alimarin
I P
IP
V.I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Academy of Sciences, Moscow, U.S.S.R.
Perezhogin
G A
GA