title: A study of uniformity of elements deposition on glass fiber filters after collection of airborne particulate matter (PM-10), using a high-volume sampler.
abstract: A study was conducted to evaluate the homogeneity of the distribution of metals and metalloids deposited on glass fiber filters collected using a high-volume sampler equipped with a PM-10 sampling head. The airborne particulate matter (APM)-loaded glass fiber filters (with an active surface of about 500cm(2)) were weighed and then each filter was cut in five small discs of 6.5cm of diameter. Each disk was mineralized by acid-assisted microwave (MW) digestion using a mixture of nitric, perchloric and hydrofluoric acids. Analysis was performed by axial view inductively coupled plasma optical emission spectrometry (ICP OES) and the elements considered were: Al, As, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Sb, Ti and V. The validation of the procedure was performed by the analysis of the standard reference material NIST 1648, urban particulate matter. As a way of comparing the possible variability in trace elements distribution in a particular filter, the mean concentration for each element over the five positions (discs) was calculated and each element concentration was normalized to this mean value. Scatter plots of the normalized concentrations were examined for all elements and all sub-samples. We considered that an element was homogeneously distributed if its normalized concentrations in the 45 sub-samples were within +/-15% of the mean value ranging between 0.85 and 1.15. The study demonstrated that the 12 elements tested showed different distribution pattern. Aluminium, Cu and V showed the most homogeneous pattern while Cd and Ni exhibited the largest departures from the mean value in 13 out of the 45 discs analyzed. No preferential deposition was noticed in any sub-sample.
authors.affiliation: Comisión Nacional de Energía Atómica, Unidad de Actividad Combustibles Nucleares, Centro Atómico Constituyentes, Av. Gral. Paz 1499, B1650KNA-San Martín, Pcia. de Buenos Aires, Argentina.
authors.forename: Julieta
authors.initials: J
authors.lastname: Marrero
authors.forename: Raúl Jiménez
authors.initials: RJ
authors.lastname: Rebagliati
authors.forename: Darío
authors.initials: D
authors.lastname: Gómez
authors.forename: Patricia
authors.initials: P
authors.lastname: Smichowski