title: Spectroscopy in separated flames-IV: application of the nitrogen-separated air-acetylene flame in flame-emission and atomic-fluorescence spectroscopy.
abstract: The primary and secondary combination zones of an air-acetylene flame have been separated by a stream of nitrogen flowing parallel to the flame to prevent access of atmospheric oxygen to its base. The flame is very stable over a wide range of fuel-air mixture strengths, and organic solvents may be aspirated without difficulty. The low flame background enables thermal-emission and atomic-fluorescence measurements to be made with high sensitivity. Bismuth, for example, has been determined in the range 5-200 ppm by its thermal emission at 306.8 nm, with a detection limit of 2 ppm in aqueous solution, and in the range 1-10 ppm with a detection limit of 0.3 ppm in 50% ethanolic solution. Zinc and cadmium have been determined at 213.9 nm and 228.8 nm by atomic-fluorescence spectroscopy in this flame with detection limits of 2 x 10(-4) ppm and 5 x 10(-4) ppm respectively, vapour-discharge lamps being used as sources of excitation. The results obtained represent a considerable improvement over those available by the same methods in a conventional air-acetylene flame.
authors.affiliation: Chemistry Department, Imperial College, London S.W. 7, U.K.
authors.forename: R S
authors.initials: RS
authors.lastname: Hobbs
authors.forename: G F
authors.initials: GF
authors.lastname: Kirkbright
authors.forename: M
authors.initials: M
authors.lastname: Sargent
authors.forename: T S
authors.initials: TS
authors.lastname: West