title: Simultaneous determination of decachlorobiphenyl, octachloronaphthalene and decachloro-1,4-dihydronaphthalene in mixtures, by HPLC.
abstract: Gas-liquid chromatography cannot distinguish between octachloronaphthalene and decachloro-1,4-dihydronaphthalene, because of the dechlorination of the latter during the chromatographic separation. High-pressure liquid chromatography on S50DS in the reverse-phase mode, with methanol as the solvent, has been successfully used in analytical (both qualitative and quantitative) and semi-preparative applications, involving the major products of the perchlorination of PCBs and PCNs: decachlorobiphenyl, octachloronaphthalene and decachloro-1,4-dihydronaphthalene.
authors.affiliation: Department of Inorganic and Analytical Chemistry, La Trobe University, Bundoora, Victoria 3083, Australia.
authors.forename: Z
authors.initials: Z
authors.lastname: Ivanov
authors.forename: R J
authors.initials: RJ
authors.lastname: Magee
authors.forename: L
authors.initials: L
authors.lastname: Markovec