Diffusion coefficients and complex equilibria in solution-III Graphical evaluation of formation constants from diffusion coefficients.
The values of the individual diffusion coefficients of the complexes participating in a metal-ligand system of equilibria may be estimated when provisional values of the formation constants have been calculated from diffusion currents. In this paper a new graphical method, involving average diffusion coefficients observed for metal-ligand systems, is described. The method is applied to four such systems, chosen for the particular characteristics shown by them.
Crow
D R
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Department of Physical Sciences, The Polytechnic, Wolverhampton, England.