Spectrophotometric determination of the protolytic dissociation constants of the new chromogenic reagent "palladiazo"-I Investigations with sodium hydroxide, perchloric acid and different aqueous buffer solutions.
The "palladiazo" reagent has been subjected to a detailed spectrophotometric investigation in concentrated perchloric acid, different aqueous buffers and concentrated sodium hydroxide solutions. K(1)-K(10) and (1)-(10) values corresponding to the instability constants of the protolytic equilibria involved and to the molar absorptivities at 540 and 630 run of the different proton complex species of the system have been calculated by a number of analytical and graphical spectrophotometric methods. Special attention has been paid to the study of the complicated phenomena implied by the interaction of the reagent with perchloric acid, which has been shown to give rise to alteration of the initial isomeric composition of the reagent and to the formation of addition and/or oxidation products derived from side-reactions undergone by the reagent with the medium. All the instability constants and molar absorptivities, which have been determined by several methods, are tabulated for comparison.
Pérez-Butsamante
J A
JA
Consejo Superior de Investigaciones Científicas, Departamento de Química Analítica, Universidad de Madrid, Facultad de Ciencias, Ciudad Universitaria, Madrid (3), Spain.
Burriel-Martí
F
F