title: Nitridogermanate nitrides Sr7[GeN4]N2 and Ca7[GeN4]N2: synthesis employing sodium melts, crystal structure, and density-functional theory calculations.
abstract: The alkaline earth nitridogermanate nitrides AE(7)[GeN(4)]N(2) (AE = Ca, Sr) have been synthesized using a Na flux technique in sealed Ta tubes. According to single-crystal X-ray diffraction the isotypic compounds crystallize in space group Pbcn (No. 60) with Z = 4, (Sr(7)[GeN(4)]N(2): a = 1152.6(2), b = 658.66(13), c = 1383.6(3) pm, V = 1050.5(4) x 10(6) pm(3), R1 = 0.049; Ca(7)[GeN(4)]N(2): a = 1082.6(2), b = 619.40(12), c = 1312.1(3) pm, V = 879.8(3) x 10(6) pm(3), R1 = 0.016). Owing to the high N/Ge ratio, the compounds contain discrete N(3-) ions coordinated by six AE(2+) besides discrete [GeN(4)](8-) tetrahedrons. One of the AE(2+) ion is coordinated by only four N(3-) ions, which is rather an unusual low coordination number for Sr(2+). Together with the isolated [GeN(4)](8-) tetrahedrons, these Sr(2+) ions form chains of alternating cation centered edge sharing tetrahedrons. The electronic structure and chemical bonding in Sr(7)[GeN(4)]N(2) has been analyzed employing linear muffin-tin orbital (LMTO) band structure calculations.
authors.affiliation: Ludwig-Maximilians-Universität München, Department Chemie and Biochemie, Lehrstuhl für Anorganische Festkörperchemie, Butenandtstrasse 5-13 (D), D-81377 München, Germany.
authors.forename: Sebastian C
authors.initials: SC
authors.lastname: Junggeburth
authors.forename: Oliver
authors.initials: O
authors.lastname: Oeckler
authors.forename: Dirk
authors.initials: D
authors.lastname: Johrendt
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Schnick