title: The anaerobic degradability of thermoplastic starch: polyvinyl alcohol blends: potential biodegradable food packaging materials.
abstract: A systematic study on the anaerobic degradability of a series of starch:polyvinyl alcohol (TPS:PVOH) blends was performed to determine their fate upon disposal in either anaerobic digesters or bioreactor landfills. The aims of the study were to measure the rate and extent of solubilisation of the plastics. The extent of substrate solubilisation on a COD basis reached 60% for a 90:10 (w/w) blend of TPS:PVOH, 40% for 75:25, 30% for 50:50 and 15% for PVOH only. The rate of substrate solubilisation was most rapid for the 90:10 blend (0.041 h(-1)) and decreased with the amount of starch in the blend in the following order 0.034 h(-1)(75:25); 0.023 h(-1)(50:50). The total solids that remained after 900 h were 10 wt.% (90:10); 23 wt.% (75:25); 55 wt.% (50:50); 90 wt.% (0:100). Starch containing substrates produced a higher concentration of volatile fatty acids (VFAs) and biogas, compared to the 0:100 substrate. The major outcome was that PVOH inhibited the degradation of the starch from the blend.
authors.affiliation: The Centre for High Performance Polymers, The University of Queensland, Queensland, Australia. m.russo@uq.edu.au
authors.forename: Melissa A L
authors.initials: MA
authors.lastname: Russo
authors.forename: Cathryn
authors.initials: C
authors.lastname: O'Sullivan
authors.forename: Beth
authors.initials: B
authors.lastname: Rounsefell
authors.forename: Peter J
authors.initials: PJ
authors.lastname: Halley
authors.forename: Rowan
authors.initials: R
authors.lastname: Truss
authors.forename: William P
authors.initials: WP
authors.lastname: Clarke
mesh_terms: D001421:Bacteria, Anaerobic / Q000378:metabolism*; D001673:Biodegradation, Environmental; D002245:Carbon Dioxide / Q000032:analysis; D002849:Chromatography, Gas; D005232:Fatty Acids, Volatile / Q000032:analysis; D018857:Food Packaging; D006859:Hydrogen / Q000032:analysis; D008697:Methane / Q000032:analysis; D011142:Polyvinyl Alcohol / Q000378:metabolism*; D012037:Refuse Disposal / Q000379:methods*; D013213:Starch / Q000378:metabolism*
chemical_list: D005232:Fatty Acids, Volatile; D002245:Carbon Dioxide; D006859:Hydrogen; D011142:Polyvinyl Alcohol; D013213:Starch; D008697:Methane