Facile photoinduced charge separation through a cyanoacetylide bridge in a heterobimetallic Fe(II)-Re(I) complex.
Photoinduced Fe-to-bpy charge transfer in [{Cp(dppe)Fe}(mu-C[triple bond]CC[triple bond]N){Re(CO)(3)(bpy)}]PF(6) has been observed by ps-TRIR spectroscopy, supported by UV-Vis/IR spectroelectrochemistry and DFT calculations.
Smith
Mark E
ME
Department of Chemistry, Durham University, South Rd, Durham, UK DH1 3LE.
Flynn
Emma L
EL
Fox
Mark A
MA
Trottier
Alexandre
A
Wrede
Eckart
E
Yufit
Dmitri S
DS
Howard
Judith A K
JA
Ronayne
Kate L
KL
Towrie
Michael
M
Parker
Anthony W
AW
Hartl
Frantisek
F
Low
Paul J
PJ