title: Mononuclear Ti[triple bond]N complexes formed by the facile multiple deprotonation of H3N x B(C6F5)3: the importance of chloride ligands.
abstract: The crystalline ion-pair [TiCl(NMe(2))(2)(NMe(2)H)(2)](+)[TiCl(2){NB(C(6)F(5))(3)}(NMe(2)H)(2)](-), in which the anion has a triply bonded nitridoborate ligand, is formed through the multiple activation of H(3)N x B(C(6)F(5))(3) when treated with [Ti(NMe(2))(3)Cl].
authors.affiliation: Wolfson Materials and Catalysis Centre, School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich, UK NR4 7TJ.
authors.forename: Anna-Marie
authors.initials: AM
authors.lastname: Fuller
authors.forename: William
authors.initials: W
authors.lastname: Clegg
authors.forename: Ross W
authors.initials: RW
authors.lastname: Harrington
authors.forename: David L
authors.initials: DL
authors.lastname: Hughes
authors.forename: Simon J
authors.initials: SJ
authors.lastname: Lancaster