title: Advanced piezoresistance of extended metal-insulator core-shell nanoparticle assemblies.
abstract: Assembled metal-insulator nanoparticles with a core-shell geometry provide access to materials containing a large number (>10(6)) of tunneling barriers. We demonstrate the production of ceramic coated metal nanoparticles exhibiting an exceptional pressure-sensitive conductivity. We further show that graphene bi- and trilayers on 20 nm copper nanoparticles are insulating in such a core-shell geometry and show a similar pressure-dependent conductivity. This demonstrates that core-shell metal-insulator assemblies offer a route to alternative sensing materials.
authors.affiliation: Institute for Chemical and Bioengineering, ETH Zürich, Zurich, Switzerland.
authors.forename: E K
authors.initials: EK
authors.lastname: Athanassiou
authors.forename: F
authors.initials: F
authors.lastname: Krumeich
authors.forename: R N
authors.initials: RN
authors.lastname: Grass
authors.forename: W J
authors.initials: WJ
authors.lastname: Stark