Aqueous suspensions of carbon nanotubes: surface oxidation, colloidal stability and uranium sorption.
The objective of this study is to obtain information on the behaviour of carbon nanotubes (CNTs) as potential carriers of pollutants in the case of accidental CNT release to the environment and on the properties of CNTs as a potential adsorbent material in water purification. The effects of acid treatment of CNTs on (i) the surface properties, (ii) the colloidal stability and (iii) heavy metal sorption are investigated, the latter being exemplified by uranium(VI) sorption. There is a pronounced influence of surface treatment on the behaviour of the CNTs in aqueous suspension. Results showed that acid treatment increases the amount of acidic surface groups on the CNTs. Therefore, acid treatment has an increasing effect on the colloidal stability of the CNTs and on their adsorption capacity for U(VI). Another way to stabilise colloids of pristine CNTs in aqueous suspension is the addition of humic acid.
Schierz
A
A
Forschungszentrum Dresden-Rossendorf eV, Institute of Radiochemistry, Dresden, Germany. schierz@chem.sc.edu
Zänker
H
H
D000327:Adsorption; D003102:Colloids; D006812:Humic Substances; D008422:Materials Testing; D008855:Microscopy, Electron, Scanning; D037742:Nanotubes, Carbon / Q000737:chemistry*; D010084:Oxidation-Reduction; D013499:Surface Properties; D014501:Uranium; D014874:Water Pollutants, Chemical / Q000737:chemistry*; D014875:Water Pollutants, Radioactive
D003102:Colloids; D006812:Humic Substances; D037742:Nanotubes, Carbon; D014874:Water Pollutants, Chemical; D014875:Water Pollutants, Radioactive; D014501:Uranium