Synthesis of 2-deoxy cyclic and linear oligosaccharides by oligomerization of monomers.
Cyclic and linear oligosaccharides constituted with 2-deoxy sugar units are synthesized by an oligomerization reaction involving activated thioglycoside monomers, consisting of a 2-deoxy sugar unit. The oligomerization promoter plays an important role in the formation of either the cyclic- or the linear oligosaccharides. Encapsulation abilities of a 2-deoxy cyclic hexamer with p-nitrophenol, by a (1)H NMR method, showed complexation of the guest molecule with the host molecule.
Paul
Somak
S
Department of Organic Chemistry, Indian Institute of Science, Bangalore 560 012, India.
Raghothama
Srinivasarao
S
Jayaraman
Narayanaswamy
N
D003505:Cyclodextrins / Q000737:chemistry; D003837:Deoxy Sugars / Q000737:chemistry; D006027:Glycosides / Q000737:chemistry*; D006031:Glycosylation; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D009844:Oligosaccharides / Q000138:chemical synthesis* / Q000737:chemistry*
D003505:Cyclodextrins; D003837:Deoxy Sugars; D006027:Glycosides; D009844:Oligosaccharides