title: Improved path integration method for estimating the intrinsic viscosity of arbitrarily shaped particles.
abstract: In previous work, we have established that the intrinsic viscosity [eta] of an object is nearly proportional to the average electrical polarizability tensor alphae = tr(alphae)/3 of a conducting object having the same shape, or equivalently, to the intrinsic conductivity [sigma]=alphae/V , which characterizes the conductivity of a dilute mixture of randomly oriented conducting objects (V being the volume of the object). This hydrodynamic-electrostatic analogy is useful because alphae can be determined accurately and efficiently by numerical path integration for objects of arbitrary shape. Here, we show that the uncertainty in [eta] can be reduced to a relatively small value (< 1.5% relative uncertainty) by utilizing additional information from the full tensor alphae, rather than just its average. Specifically, we determine the exact constant of proportionality between [eta] and [sigma] for triaxial ellipsoids as a function of the ratios of the eigenvalues of alphae and apply this relation to particles of general shape. In addition to an improved estimation of [eta] , the ratios of the components of alphae provide useful measures of particle anisotropy. We also present an improved method for applying the technique to flexible particles, which requires performing a conformational ensemble average. Conformational averages of alphae generate systematic errors that can be avoided by performing the conformational average at an earlier stage in the computation.
authors.affiliation: Department of Chemistry and Chemical Biology, Stevens Institute of Technology, Hoboken, New Jersey 07030, USA.
authors.forename: Marc L
authors.initials: ML
authors.lastname: Mansfield
authors.forename: Jack F
authors.initials: JF
authors.lastname: Douglas