Snowman-like silver alkynyl cluster consolidated by templating chloride and peripheral trifluoroacetates.
A novel nonadecanuclear silver double cage was isolated, in which a square antiprism and a pentacapped pentagonal prism templated by a chloride ion share a tetragonal face to form a snowman-like cluster that is held together by bridging alkynyl groups and trifluoroacetates.
Bian
Shu-Dan
SD
Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen, 361005, People's Republic of China.
Wang
Quan-Ming
QM