The Brosimum allene: a structural revision.
Insight derived from a synthetic model, calculated (13)C NMR data, and comparison to experimental data indicate that the proposed allenic structure A, originally assigned to an isolate from Brosimum acutifolium Huber, should be revised to B, a natural product and nonallenic substance, mururin C.
Hu
Gaojie
G
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08854, USA.
Liu
Kai
K
Williams
Lawrence J
LJ
D000466:Alkadienes / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D029586:Moraceae / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry
D000466:Alkadienes; D012997:Solvents; C025947:propadiene