Mononuclear Ti[triple bond]N complexes formed by the facile multiple deprotonation of H3N x B(C6F5)3: the importance of chloride ligands.
The crystalline ion-pair [TiCl(NMe(2))(2)(NMe(2)H)(2)](+)[TiCl(2){NB(C(6)F(5))(3)}(NMe(2)H)(2)](-), in which the anion has a triply bonded nitridoborate ligand, is formed through the multiple activation of H(3)N x B(C(6)F(5))(3) when treated with [Ti(NMe(2))(3)Cl].
Fuller
Anna-Marie
AM
Wolfson Materials and Catalysis Centre, School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich, UK NR4 7TJ.
Clegg
William
W
Harrington
Ross W
RW
Hughes
David L
DL
Lancaster
Simon J
SJ