Advanced piezoresistance of extended metal-insulator core-shell nanoparticle assemblies.
Assembled metal-insulator nanoparticles with a core-shell geometry provide access to materials containing a large number (>10(6)) of tunneling barriers. We demonstrate the production of ceramic coated metal nanoparticles exhibiting an exceptional pressure-sensitive conductivity. We further show that graphene bi- and trilayers on 20 nm copper nanoparticles are insulating in such a core-shell geometry and show a similar pressure-dependent conductivity. This demonstrates that core-shell metal-insulator assemblies offer a route to alternative sensing materials.
Athanassiou
E K
EK
Institute for Chemical and Bioengineering, ETH Zürich, Zurich, Switzerland.
Krumeich
F
F
Grass
R N
RN
Stark
W J
WJ