Covalent surface modification of a metal-organic framework: selective surface engineering via Cu(I)-catalyzed Huisgen cycloaddition.
A Zn-cornered, mixed-ligand, metal-organic framework (MOF) bearing TMS-protected acetylenes has been constructed and its surface decorated with organic molecules via'click chemistry', in a demonstration of selective post-synthesis functionalization.
Gadzikwa
Tendai
T
Department of Chemistry, Northwestern University, Evanston, IL 60208-3113, USA.
Lu
Guang
G
Stern
Charlotte L
CL
Wilson
Scott R
SR
Hupp
Joseph T
JT
Nguyen
Sonbinh T
ST
D000480:Alkynes / Q000737:chemistry; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D003500:Cyclization; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D010316:Particle Size; D013499:Surface Properties; D015032:Zinc / Q000737:chemistry*
D000480:Alkynes; D008024:Ligands; D009942:Organometallic Compounds; D003300:Copper; D015032:Zinc