Synthesis of trifluoromethanesulfinamidines and -sulfanylamides.
Fluorinated moieties constitute important substituents used in many applications to modify the properties of molecules. The action of DAST onto Ruppert's reagent yields to a not isolable intermediate that can then react with various primary amines to give trifluoromethanesulfinamidines and trifluoromethanesulfanylamides. Such compounds were unknown until now and constitute interesting new families of fluorinated molecules.
Ferry
Aurélien
A
ICBMS, Université Lyon 1, CNRS, Laboratoire SERCOF, 43 boulevard du 11 novembre 1918, Villeurbanne, F-69622 France.
Billard
Thierry
T
Langlois
Bernard R
BR
Bacqué
Eric
E
D000577:Amides / Q000737:chemistry*; D002625:Chemistry, Organic / Q000379:methods*; D005459:Fluorides / Q000138:chemical synthesis*; D005461:Fluorine / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008956:Models, Chemical; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry; D013455:Sulfur / Q000737:chemistry
D000577:Amides; D005461:Fluorine; D013455:Sulfur; D009584:Nitrogen; D005459:Fluorides