4-(pyridin-2-yl)thiazol-2-yl thioglycosides as bidentate ligands for oligosaccharide synthesis via temporary deactivation.
This study focusses on a new concept for oligosaccharide synthesis based on 4-(pyridin-2-yl)thiazol-2-yl thioglycosides that can either act as effective glycosyl donors or can be deactivated by stable bidentate complexation with palladium(II) bromide.
Pornsuriyasak
Papapida
P
Department of Chemistry and Biochemistry, University of Missouri-St. Louis, St. Louis, Missouri 63121, USA.
Rath
Nigam P
NP
Demchenko
Alexei V
AV
D001965:Bromides / Q000737:chemistry; D002240:Carbohydrate Sequence; D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D008969:Molecular Sequence Data; D015394:Molecular Structure; D009844:Oligosaccharides / Q000138:chemical synthesis* / Q000737:chemistry; D010165:Palladium / Q000737:chemistry; D013865:Thioglycosides / Q000737:chemistry*
D001965:Bromides; D008024:Ligands; D009844:Oligosaccharides; D013865:Thioglycosides; D010165:Palladium