title: Supported ATRP of fluorinated methacrylates in supercritical carbon dioxide: preparation of scCO2 soluble polymers with low catalytic residues.
abstract: Synthesis of poly(2,2,2-trifluoroethyl methacrylate) by supported ATRP was investigated in supercritical carbon dioxide using a copper salt ligated to a polymeric ligand immobilised onto silica; after polymerisation, fluorinated polymers with well defined molecular weight and low polydispersity were obtained.
authors.affiliation: Center for Education and Research on Macromolecules, University of Liège, Sart-Tilman, B6a, B-4000, Liège, Belgium.
authors.forename: Bruno
authors.initials: B
authors.lastname: Grignard
authors.forename: Cédric
authors.initials: C
authors.lastname: Calberg
authors.forename: Christine
authors.initials: C
authors.lastname: Jérôme
authors.forename: Wenxin
authors.initials: W
authors.lastname: Wang
authors.forename: Steven
authors.initials: S
authors.lastname: Howdle
authors.forename: Christophe
authors.initials: C
authors.lastname: Detrembleur