title: Thiazepine moiety-controlled regioselective rearrangements of 7-oxanorbornadiene derivatives.
abstract: We have discovered thiazepine moiety-controlled regioselective skeletal rearrangements of 7-oxanorbornadiene derivatives (2, 7 and 12) with high regioselectivity and/or diastereoselectivity in the presence of Brønsted acid.
authors.affiliation: Department of Chemistry, Zhejiang University, Hangzhou, China.
authors.forename: Hanfeng
authors.initials: H
authors.lastname: Ding
authors.forename: Yiping
authors.initials: Y
authors.lastname: Zhang
authors.forename: Weijun
authors.initials: W
authors.lastname: Yao
authors.forename: Duanjun
authors.initials: D
authors.lastname: Xu
authors.forename: Cheng
authors.initials: C
authors.lastname: Ma
mesh_terms: D006572:Heterocyclic Compounds, Bridged-Ring / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D013237:Stereoisomerism; D013841:Thiazepines / Q000737:chemistry*
chemical_list: D006572:Heterocyclic Compounds, Bridged-Ring; D013841:Thiazepines