One single catalyst, Pd(OAc)2, for two sequential very different steps: allylic alcohol oxidation-Heck reaction. Access to functionalised alpha,beta-unsaturated ketones.
A single addition of the catalyst, Pd(OAc)(2), was realised to mediate two transformations as different as allylic alcohol oxidation under O(2) and C-C bond formation of the Heck type, to give substituted alpha,beta-unsaturated ketones without intermediate purification.
Batt
Frédéric
F
Université de Lyon, Université Lyon 1, ICBMS, équipe Cheops, CNRS, UMR 5246, Bât. Raulin, 43 Bd du 11 Nov. 1918, 69622 Villeurbanne cedex, France.
Gozzi
Christel
C
Fache
Fabienne
F