Thiazepine moiety-controlled regioselective rearrangements of 7-oxanorbornadiene derivatives.
We have discovered thiazepine moiety-controlled regioselective skeletal rearrangements of 7-oxanorbornadiene derivatives (2, 7 and 12) with high regioselectivity and/or diastereoselectivity in the presence of Brønsted acid.
Ding
Hanfeng
H
Department of Chemistry, Zhejiang University, Hangzhou, China.
Zhang
Yiping
Y
Yao
Weijun
W
Xu
Duanjun
D
Ma
Cheng
C
D006572:Heterocyclic Compounds, Bridged-Ring / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D013237:Stereoisomerism; D013841:Thiazepines / Q000737:chemistry*
D006572:Heterocyclic Compounds, Bridged-Ring; D013841:Thiazepines