Coordination networks derived from germanium(ii) thioether macrocyclic complexes-the first authenticated chalcogenoether complexes of Ge(ii).
Exocyclic coordination of macrocyclic thioethers to germanium(ii) halides leads to infinite chains (with weak GeX bridges between the chains) or sheet structures containing distorted octahedral Ge(ii) with [S(2)X(2) + X(2)] coordination and bridging thiacrowns.
Cheng
Fei
F
School of Chemistry, University of Southampton, Southampton, UKSO17 1BJ.
Hector
Andrew L
AL
Levason
William
W
Reid
Gillian
G
Webster
Michael
M
Zhang
Wenjian
W