title: A two-step spin crossover mononuclear iron(II) complex with a [HS-LS-LS] intermediate phase.
abstract: The two-step spin crossover of a new mononuclear iron(ii) complex is studied by magnetic, crystallographic and calorimetric methods revealing two successive first-order phase transitions and an ordered intermediate phase built by the repetition of the unprecedented [HS-LS-LS] motif.
authors.affiliation: Leiden Institute of Chemistry, Leiden University, RA2300, Leiden, The Netherlands.
authors.forename: Sylvestre
authors.initials: S
authors.lastname: Bonnet
authors.forename: Maxime A
authors.initials: MA
authors.lastname: Siegler
authors.forename: José Sánchez
authors.initials: JS
authors.lastname: Costa
authors.forename: Gábor
authors.initials: G
authors.lastname: Molnár
authors.forename: Azzedine
authors.initials: A
authors.lastname: Bousseksou
authors.forename: Anthony L
authors.initials: AL
authors.lastname: Spek
authors.forename: Patrick
authors.initials: P
authors.lastname: Gamez
authors.forename: Jan
authors.initials: J
authors.lastname: Reedijk
mesh_terms: D018360:Crystallography, X-Ray; D005296:Ferrous Compounds / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D044367:Phase Transition; D011789:Quantum Theory; D013696:Temperature
chemical_list: D005296:Ferrous Compounds; D008024:Ligands