An unprecedented lanthanide phosphinidene halide: synthesis, structure and reactivity.
The synthesis and structural characterization of an unprecedented lanthanide phosphinidene species [(THF)(3)(I)Nd(mu-PC(6)H(3)-2,6-(i)Pr(2))](2) are described; the phosphinidene moiety in this complex reacts as a carbene.
Cui
Peng
P
Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, 200032, China.
Chen
Yaofeng
Y
Xu
Xin
X
Sun
Jie
J