title: Synthesis of trifluoromethanesulfinamidines and -sulfanylamides.
abstract: Fluorinated moieties constitute important substituents used in many applications to modify the properties of molecules. The action of DAST onto Ruppert's reagent yields to a not isolable intermediate that can then react with various primary amines to give trifluoromethanesulfinamidines and trifluoromethanesulfanylamides. Such compounds were unknown until now and constitute interesting new families of fluorinated molecules.
authors.affiliation: ICBMS, Université Lyon 1, CNRS, Laboratoire SERCOF, 43 boulevard du 11 novembre 1918, Villeurbanne, F-69622 France.
authors.forename: Aurélien
authors.initials: A
authors.lastname: Ferry
authors.forename: Thierry
authors.initials: T
authors.lastname: Billard
authors.forename: Bernard R
authors.initials: BR
authors.lastname: Langlois
authors.forename: Eric
authors.initials: E
authors.lastname: Bacqué
mesh_terms: D000577:Amides / Q000737:chemistry*; D002625:Chemistry, Organic / Q000379:methods*; D005459:Fluorides / Q000138:chemical synthesis*; D005461:Fluorine / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008956:Models, Chemical; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry; D013455:Sulfur / Q000737:chemistry
chemical_list: D000577:Amides; D005461:Fluorine; D013455:Sulfur; D009584:Nitrogen; D005459:Fluorides