PF6(-) hydrolysis as a route to unique uranium phosphate materials.
An uranium phosphate fluoride with a unique pentameric secondary building unit is prepared under hydrothermal conditions with UO2(NO3)2 x 6H(2)O, PF6(-) and 4,4'-bipyridine; the single-crystal structure is determined.
Deifel
Nicholas P
NP
Department of Chemistry, The George Washington University, 725 21st Street NW, DC 20052, Washington, USA.
Holman
K Travis
KT
Cahill
Christopher L
CL