Isothermal decomposition of hydroxylamine and hydroxylamine nitrate in aqueous solutions in the temperature range 80-160 degrees C.
Hydroxylamine (HA) and hydroxylamine nitrate (HAN) have been involved independently in several tragic accidents, which incurred numerous fatalities and injuries. Following these incidents, adiabatic calorimetry and computational chemistry research was conducted on those compounds, suggesting potential reaction pathways of their decomposition, but the mechanism of their unstable behavior, still have not been completely understood. In the present work, isothermal decomposition tests were performed accompanied with HPLC, ion chromatography and UV analyses in the temperature range 80-160 degrees C. Condition-dependent autocatalytic decompositions were demonstrated for HA and HAN, and an intermediate formation has been observed that is most likely responsible for their autocatalytic behavior. These findings corroborate previously reported computational chemistry results.
Liu
Lijun
L
Chemical Engineering Department, Mary Kay O'Connor Process Safety Center, Texas A&M University, College Station, TX 77843-3122, United States.
Papadaki
Maria
M
Pontiki
Eleni
E
Stathi
Panagiota
P
Rogers
William J
WJ
Mannan
M Sam
MS
D000056:Accident Prevention; D019811:Hydroxylamine / Q000737:chemistry*; D009566:Nitrates / Q000737:chemistry*; D012996:Solutions; D013696:Temperature; D014867:Water
D009566:Nitrates; D012996:Solutions; D014867:Water; D019811:Hydroxylamine