Modular chiral dendritic monodentate phosphoramidite ligands for Rh(II)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity.
Modular chiral dendrimers with monodentate phosphoramidite ligands located at the core were synthesized and applied in the Rh-catalyzed asymmetric hydrogenations, afforded unprecedented enhancement of enantioselectivity.
Zhang
Feng
F
Beijing National Laboratory for Molecular Sciences, Center for Chemical Biology, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, PR China.
Li
Yong
Y
Li
Zhi-Wei
ZW
He
Yan-Mei
YM
Zhu
Shou-Fei
SF
Fan
Qing-Hua
QH
Zhou
Qi-Lin
QL
D002384:Catalysis; D050091:Dendrimers / Q000138:chemical synthesis* / Q000737:chemistry; D006865:Hydrogenation; D008024:Ligands; D015394:Molecular Structure; D009943:Organophosphorus Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
D050091:Dendrimers; D008024:Ligands; D009943:Organophosphorus Compounds; C434331:phosphoramidite; D012238:Rhodium