title: Direct observation of space charge induced hydrogen ion insertion in nanoscale anatase TiO2.
abstract: Space charge induced 2H+ densities up to 2H+ (0.17)TiO2 are observed directly using neutron diffraction on two different nanoscale particle sizes of anatase TiO2 immersed in sulfuric acid, and consistent with experimental evidence modelling shows that these ions show rapid self diffusion.
authors.affiliation: Fundamental Aspects of Materials and Energy, Department of Radiation, Radionuclides, and Reactors, Faculty of Applied Sciences, Delft University of Technology, Mekelweg 15, 2629JB, Delft, The Netherlands.
authors.forename: Wing K
authors.initials: WK
authors.lastname: Chan
authors.forename: Wouter J H
authors.initials: WJ
authors.lastname: Borghols
authors.forename: Fokko M
authors.initials: FM
authors.lastname: Mulder
mesh_terms: D008958:Models, Molecular; D049329:Nanostructures / Q000737:chemistry*; D011522:Protons; D014025:Titanium / Q000737:chemistry*
chemical_list: D011522:Protons; C009495:titanium dioxide; D014025:Titanium