Ruthenium-catalyzed synthesis of functionalized 1,3-dienes.
Functionalized 1,3-diene derivatives have been prepared by regioselective allylation of various nucleophiles with 1,3-dienic carbonates in the presence of a (N,O-carboxylate) allylruthenium precatalyst.
Achard
Mathieu
M
UMR 6226, CNRS-Universite de Rennes 1, Sciences Chimiques-Catalyse et Organometalliques, Campus de Beaulieu, 35042 Rennes Cedex, France.
Derrien
Nolwenn
N
Zhang
Hui-Jun
HJ
Demerseman
Bernard
B
Bruneau
Christian
C
D000466:Alkadienes / Q000138:chemical synthesis* / Q000737:chemistry; D000478:Alkylation; D002384:Catalysis; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D013237:Stereoisomerism
D000466:Alkadienes; D009942:Organometallic Compounds; D012428:Ruthenium