title: Growth and electrochromic properties of poly(3,4-ethylenedioxythiophene) layer on TiO2 nanoparticles.
abstract: The growth of the conductive layer on TiO2 nanoparticles was examined. Poly(3,4-ethylenedioxythiophene) (PEDOT) was deposited on the mesoporous TiO2 nanoparticle by the chemical polymerization of 3,4-ethylenedioxythiophene (EDOT) under oxidative conditions, to afford PEDOT coated particles having average diameter of -75 nm. The growth of PEDOT on TiO2 was confirmed by a field emission-scanning electron microscopy (FE-SEM) and electrochemistry. All-solid-state electrochromic devices were fabricated using the PEDOT-on-TiO2 coated electrode and the solid polymer electrolyte as the ion conduction layer. Evaluation of the optical and electrochromic (EC) response was performed by monitoring the intensity of absorbance at the absorption wavelength of 600 nm under different conditions of applied potential. A fast electrochromic response and an efficient EC process with a blue color change was observed from the device constructed with nano-structured PEDOT
authors.affiliation: Department of Chemical Engineering, Yonsei University, 134 Sinchon-Dong, Seodaemum-Gu, 120-749, Seoul, South Korea.
authors.forename: Jehoon
authors.initials: J
authors.lastname: Baek
authors.forename: Yuna
authors.initials: Y
authors.lastname: Kim
authors.forename: Eunkyoung
authors.initials: E
authors.lastname: Kim
mesh_terms: D000327:Adsorption; D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000737:chemistry*; D002384:Catalysis; D004563:Electrochemistry / Q000379:methods; D004583:Electrons; D008422:Materials Testing; D008855:Microscopy, Electron, Scanning; D008956:Models, Chemical; D036103:Nanotechnology / Q000379:methods*; D055095:Optics and Photonics; D010100:Oxygen / Q000737:chemistry; D011108:Polymers / Q000737:chemistry*; D013499:Surface Properties; D013997:Time Factors; D014025:Titanium / Q000737:chemistry*
chemical_list: D019086:Bridged Bicyclo Compounds, Heterocyclic; D011108:Polymers; C121383:poly(3,4-ethylene dioxythiophene); C009495:titanium dioxide; D014025:Titanium; D010100:Oxygen