adj-Diazuliporphyrins, a new family of dicarbaporphyrinoids with unprecedented mesoionic characteristics.
A diazulenylmethane dialdehyde reacted with dipyrrylmethanes in the presence of HCl or HBr, followed by oxidation with FeCl(3), to give aromatic adj-diazuliporphyrins. The free base structures must exist as mesoionic species, although these porphyrinoids were isolated as salts of the monoprotonated macrocycles. Reaction with Pd(OAc)(2) gave an unprecedented zwitterionic palladium(II) complex that was characterized by X-ray crystallography.
Zhang
Zhenjun
Z
Department of Chemistry, Illinois State University, Normal, Illinois 61790-4160, USA.
Ferrence
Gregory M
GM
Lash
Timothy D
TD
D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D011166:Porphyrins / Q000138:chemical synthesis / Q000737:chemistry*
D009942:Organometallic Compounds; D011166:Porphyrins; D010165:Palladium