Homogeneous nucleation rate measurements in supersaturated water vapor.
The rate of homogeneous nucleation in supersaturated vapors of water was studied experimentally using a thermal diffusion cloud chamber. Helium was used as a carrier gas. Our study covers a range of nucleation rates from 3x10(-1) to 3x10(2) cm(-3) s(-1) at four isotherms: 290, 300, 310, and 320 K. The molecular content of critical clusters was estimated from the slopes of experimental data. The measured isothermal dependencies of nucleation rate of water on saturation ratio were compared with the prediction of the classical theory of homogeneous nucleation, the empirical prediction of Wolk et al. [J. Chem. Phys. 117, 10 (2002)], the scaled model of Hale [Phys. Rev. A 33, 4156 (1986)], and the former nucleation onset data.
Brus
David
D
Laboratory of Aerosol Chemistry and Physics, Institute of Chemical Process Fundamentals AS CR, v.v.i., Rozvojova 135, CZ-16502 Prague, Czech Republic. brus@icpf.cas.cz
Zdímal
Vladimír
V
Smolík
Jirí
J