title: Titanocene(III) chloride-mediated reductions of oxazines, hydroxamic acids, and N-hydroxy carbamates.
abstract: Titanocene(III) chloride (Cp(2)TiCl), generated in situ, reduces N-O bonds of various substrates in good to excellent yields (72-95%). Reactions may be performed with stoichiometric Cp(2)TiCl or with catalytic Cp(2)TiCl.
authors.affiliation: Department of Chemistry and Biochemistry, University of Notre Dame, 251 Nieuwland Science Hall, Notre Dame, Indiana 46545, USA.
authors.forename: Cara
authors.initials: C
authors.lastname: Cesario
authors.forename: Lawrence P
authors.initials: LP
authors.lastname: Tardibono
authors.forename: Marvin J
authors.initials: MJ
authors.lastname: Miller
mesh_terms: D002219:Carbamates / Q000737:chemistry*; D002384:Catalysis; D002712:Chlorides / Q000737:chemistry*; D006877:Hydroxamic Acids / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010078:Oxazines / Q000737:chemistry*; D010084:Oxidation-Reduction; D013237:Stereoisomerism
chemical_list: D002219:Carbamates; D002712:Chlorides; D006877:Hydroxamic Acids; D009942:Organometallic Compounds; D010078:Oxazines; C406884:titanocene