title: An unusual anionic copper(I) cyanide 3D framework encapsulating a cationic copper(II) complex as a guest.
abstract: From the reaction of CuICN with conc-NH4OH, a host-guest type 3D network complex , [[CuII(NH3)4(H2O)](H2O)@[CuI3(CN)5]]n was isolated and characterised. A unique cationic complex guest [CuII(NH3)4(H2O)]2+ is encapsulated in the anionic host cage [CuI3(CN)5]2-.
authors.affiliation: Research Institute of Natural Science and Department of Chemistry (BK21), Gyeongsang National University, Jinju, 660-701, South Korea. kmpark@gnu.ac.kr
authors.forename: Ki-Min
authors.initials: KM
authors.lastname: Park
authors.forename: Sanjina
authors.initials: S
authors.lastname: Lee
authors.forename: Youngjin
authors.initials: Y
authors.lastname: Kang
authors.forename: Suk-Hee
authors.initials: SH
authors.lastname: Moon
authors.forename: Shim Sung
authors.initials: SS
authors.lastname: Lee