Preparation of active and robust palladium nanoparticle catalysts stabilized by diamine-functionalized mesoporous polymers.
A two-step chemical modification process is designed for synthesizing novel diamine-functionalized mesopolymers, which combine the advantage of organic polymers and mesoporous materials, and serve as an efficient scaffold for supporting highly dispersed, catalytically active and robust Pd nanoparticles (NPs).
Xing
Rong
R
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, North Zhongshan Rd. 3663, Shanghai 200062, China.
Liu
Yueming
Y
Wu
Haihong
H
Li
Xiaohong
X
He
Mingyuan
M
Wu
Peng
P
D002384:Catalysis; D003959:Diamines / Q000737:chemistry*; D053768:Metal Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D046529:Microscopy, Electron, Transmission; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D016062:Porosity; D020005:Propanols / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared; D014867:Water / Q000737:chemistry; D014961:X-Ray Diffraction
D003959:Diamines; D011108:Polymers; D020005:Propanols; D014867:Water; C006463:allyl alcohol; D010165:Palladium