Rotational molecular dynamics of laser-manipulated bromotrifluoromethane studied by x-ray absorption.
We present a computational study of the rotational molecular dynamics of bromotrifluoromethane (CF(3)Br) molecules in gas phase. The rotation is manipulated with an off-resonant 800 nm laser. The molecules are treated as rigid rotors. Frequently, we use a computationally efficient linear rotor model for CF(3)Br, which we compare with selected results for full symmetric-rotor computations. The expectation value (cos(2) theta)(t) is discussed. Especially, the transition from impulsive to adiabatic alignment, the temperature dependence of the maximally achievable alignment, and its intensity dependence are investigated. In a next step, we examine resonant x-ray absorption as an accurate tool to study laser manipulation of molecular rotation. Specifically, we investigate the impact of the x-ray pulse duration on the signal (particularly its temporal resolution) and study the temperature dependence of the achievable absorption. Most importantly, we demonstrated that using picosecond x-ray pulses, one can accurately measure the expectation value (cos(2) theta)(t) for impulsively aligned CF(3)Br molecules. We point out that a control of the rotational dynamics opens up a novel way to imprint shapes onto long x-ray pulses on a picosecond time scale. For our computations, we determine the dynamic polarizability tensor of CF(3)Br using ab initio molecular linear-response theory in conjunction with wave function models of increasing sophistication: Coupled-cluster singles (CCS), second-order approximate coupled-cluster singles and doubles (CC2), and coupled-cluster singles and doubles (CCSD).
Buth
Christian
C
Argonne National Laboratory, Argonne, Illinois 60439, USA. christian.buth@web.de
Santra
Robin
R