title: One-pot synthesis of peroxo-titania nanopowder and dual photochemical oxidation in aqueous methanol solution.
abstract: A sol-gel hydrothermal method was developed to synthesize peroxo-titania powders and their photooxidation performances were conducted in aqueous methanol solution under visible light irradiation. Three kinds of peroxo-titania were developed using TiO(2) and H(2)O(2) containing precursor sol with different dispersion mediums such as NH(3) aq NaOH aq, or pure water. Peroxo-titania powder prepared with NH(3) aq showed highest photooxidation activity. Moreover, we found unique photofunctional properties: together with formaldehyde production, the photo-excited electron also triggers oxygen evolution, although by TiO(2) (Degussa P-25) photocatalysis H(2) evolution was observed from the same solution.
authors.affiliation: Photocatalytic Materials Center, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan.
authors.forename: Muthukonda Venkatakrishnan
authors.initials: MV
authors.lastname: Shankar
authors.forename: Tetsuya
authors.initials: T
authors.lastname: Kako
authors.forename: Defa
authors.initials: D
authors.lastname: Wang
authors.forename: Jinhua
authors.initials: J
authors.lastname: Ye