NMR investigation of chlorophosphorylation products of N-vinylazoles.
The structure of novel phosphorus-containing N-vinylazoles prepared by action of phosphorus pentachloride has been studied by multinuclear (1)H, (13)C, (15)N, (31)P and two-dimensional (2D) NMR spectroscopy. N-vinyl-substituted 1,2-diazoles and 1,2,3-triazoles have undergone phosphorylation, exclusively, on double bond. N-vinylazoles-based hexa-coordinated phosphorus compounds have been synthesized for the first time. (31)P NMR spectroscopy provides the most convenient and unambiguous method for the investigation of E-Z-isomeric structures of phosphorylated enamines.
Larina
Lyudmila I
LI
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk 664033, Russian Federation. larina@irioch.irk.ru
Rozinov
Vladimir G
VG
Dmitrichenko
Mikhail Yu
MY
Es'kova
Lyudmila A
LA
D001393:Azoles / Q000138:chemical synthesis / Q000737:chemistry*; D007536:Isomerism; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D015394:Molecular Structure; D010759:Phosphorus Isotopes; D010766:Phosphorylation; D014753:Vinyl Compounds / Q000138:chemical synthesis / Q000737:chemistry*
D001393:Azoles; D010759:Phosphorus Isotopes; D014753:Vinyl Compounds