A cavitand with a fluorous rim acts as an amine receptor.
A deep cavitand featuring eight trifluoroacetyl groups attached to the open end has been synthesized; these functions provide new chemical surfaces and constrict access to the cavitand, yet increase the rates of guest exchange.
Hooley
Richard J
RJ
The Skaggs Institute for Chemical Biology, The Scripps Research Institute, La Jolla, CA 92037, USA. richard.hooley@ucr.edu
Restorp
Per
P
Rebek
Julius
J
D000588:Amines / Q000737:chemistry*; D000081005:Cyclohexane Monoterpenes; D004872:Ergocalciferols / Q000737:chemistry; D004988:Ethers, Cyclic / Q000737:chemistry*; D017611:Fluorine Compounds / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008956:Models, Chemical; D015394:Molecular Structure; D012118:Resorcinols / Q000737:chemistry*; D013729:Terpenes / Q000737:chemistry
D000588:Amines; D000081005:Cyclohexane Monoterpenes; D004872:Ergocalciferols; D004988:Ethers, Cyclic; D017611:Fluorine Compounds; D012118:Resorcinols; D013729:Terpenes; C442939:cavitand; C409816:isopulegol