title: Electron-transfer-catalyzed dimerization of trans-anethole: detection of the distonic tetramethylene radical cation intermediate by extractive electrospray ionization mass spectrometry.
abstract: The desolvating droplets of EESI were used as microreactor for the mass spectrometric study of short-lived transients of reactions in condensed liquid phase in the millisecond time region. The electron-transfer-catalyzed dimerization of trans-anethole was investigated and the intermediates in the radical cation chain reaction were isolated and characterized by MS-MS. The distonic tetramethylene radical cation 3(o)(*+) was detected as intermediate, and its cyclization to give the cyclobutane radical cation 3(c)(*+) was observed giving strong evidence that the reaction takes place stepwise.
authors.affiliation: Institut für Reine and Angewandte Chemie der Universität Oldenburg, P.O. Box 2503, 26111, Germany.
authors.forename: Cesar A
authors.initials: CA
authors.lastname: Marquez
authors.forename: Haoyang
authors.initials: H
authors.lastname: Wang
authors.forename: Francesco
authors.initials: F
authors.lastname: Fabbretti
authors.forename: Jürgen O
authors.initials: JO
authors.lastname: Metzger