title: Novel three-dimensional 3d-4f microporous magnets exhibiting selective gas adsorption behavior.
abstract: Three microporous Ln-Co-pyta heterometallic compounds [Ln4Co3(pyta)6(H2O)9].5H2O (Ln = Sm (1), Eu (2), Gd (3); H3pyta = 2,4,6-pyridinetricarboxylic acid) have interesting selective adsorption abilities towards H2/N2 and CO2/N2 because of size-selective effects; magnetic analysis reveals that has a ferromagnetic behavior.
authors.affiliation: MOE Key Laboratory of Bioinorganic and Synthetic Chemistry/State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, 510275 Guangzhou, PR China.
authors.forename: Cui-Jin
authors.initials: CJ
authors.lastname: Li
authors.forename: Zhuo-Jia
authors.initials: ZJ
authors.lastname: Lin
authors.forename: Meng-Xia
authors.initials: MX
authors.lastname: Peng
authors.forename: Ji-Dong
authors.initials: JD
authors.lastname: Leng
authors.forename: Ming-Mei
authors.initials: MM
authors.lastname: Yang
authors.forename: Ming-Liang
authors.initials: ML
authors.lastname: Tong
mesh_terms: D000327:Adsorption; D005740:Gases / Q000737:chemistry*; D008280:Magnetics; D008958:Models, Molecular; D008968:Molecular Conformation; D016062:Porosity
chemical_list: D005740:Gases