title: The self-assembly and magnetic properties of a Ni(II)8(micro4-hydroxo)6 cube with micro2-pyrazolate as an exogeneous ancillary ligand.
abstract: A novel octanuclear hydroxonickel(II) complex possessing a unprecedented cube molecular structure with eight Ni(II) ions at each vertex, six micro4-OH- groups closing each face and twelve exo-bidentate pyrazolate ligands (micro2-pz) spanning each edge, has been synthesized and its magnetic properties investigated.
authors.affiliation: College of Pharmacy, Tianjin Medical University, Tianjin 300070, PR China.
authors.forename: Jing-Yuan
authors.initials: JY
authors.lastname: Xu
authors.forename: Xin
authors.initials: X
authors.lastname: Qiao
authors.forename: Hai-Bin
authors.initials: HB
authors.lastname: Song
authors.forename: Shi-Ping
authors.initials: SP
authors.lastname: Yan
authors.forename: Dai-Zheng
authors.initials: DZ
authors.lastname: Liao
authors.forename: Song
authors.initials: S
authors.lastname: Gao
authors.forename: Yves
authors.initials: Y
authors.lastname: Journaux
authors.forename: Joan
authors.initials: J
authors.lastname: Cano
mesh_terms: D006900:Hydroxylation; D008024:Ligands; D008280:Magnetics; D008958:Models, Molecular; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D011720:Pyrazoles / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D008024:Ligands; D011720:Pyrazoles; C031280:pyrazole; D009532:Nickel