Pentaarylfullerenes as noncoordinating cyclopentadienyl anions.
The first example of an early-transition-metal complex involving a pentaarylfullerene was prepared. Instead of half-sandwich complexes, solvent separated ion pairs were obtained in which the pentaarylfullerene moiety acts as noncoordinating cyclopentadienyl anion.
Bouwkamp
Marco W
MW
Molecular Inorganic Chemistry Department, Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands. m.w.bouwkamp@rug.nl
Meetsma
Auke
A