Synthesis of covalently linked binuclear clamshell phthalocyanine by double-click reaction.
A novel covalently linked binuclear phthalocyanine 1 was synthesized by the "double-click" reaction. The UV-vis and fluorescence spectra and electrochemistry revealed that the geometry of 1 is a closed clamshell conformation in which a strong electronic interaction is observed between the two Pc moieties.
Yoshiyama
Hideyuki
H
Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan.
Shibata
Norio
N
Sato
Takefumi
T
Nakamura
Shuichi
S
Toru
Takeshi
T