title: Cooperativity between pi-pi and H-bonding interactions-a supramolecular complex formed by C60 and exTTF.
abstract: A highly stable supramolecular complex from C60 and exTTF (Ka approximately 10(6) M(-1)) has been achieved by means of pi-pi and H-bonding interactions; experimental evidence reveals the formation of a radical-ion pair (tau = 9.3 ps) upon photoexcitation.
authors.affiliation: Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Complutense, 28040 Madrid, Spain.
authors.forename: José
authors.initials: J
authors.lastname: Santos
authors.forename: Bruno
authors.initials: B
authors.lastname: Grimm
authors.forename: Beatriz M
authors.initials: BM
authors.lastname: Illescas
authors.forename: Dirk M
authors.initials: DM
authors.lastname: Guldi
authors.forename: Nazario
authors.initials: N
authors.lastname: Martín
mesh_terms: D043844:Crown Ethers / Q000138:chemical synthesis / Q000737:chemistry*; D037741:Fullerenes / Q000737:chemistry*; D006860:Hydrogen Bonding; D015394:Molecular Structure; D010777:Photochemistry; D013056:Spectrophotometry, Ultraviolet
chemical_list: D043844:Crown Ethers; D037741:Fullerenes