9,10,19,20-Tetraarylporphycenes.
meso-Tetraarylporphycenes, structural isomers of meso-tetraarylporphyrins, were synthesized by the acid-catalyzed oxidative coupling reaction for the first time which is an alternative synthetic methodology to the traditional McMurry coupling reaction. The structure of the macrocycle and Ni(II) complex are characterized by single-crystal X-ray diffraction analyses where both form 1-D supramolecular assembly.
Anju
K S
KS
Photosciences and Photonics Section, Chemical Sciences and Technology Division, National Institute for Interdisciplinary Science and Technology (NIIST-CSIR), Trivandrum-695019, Kerala, India.
Ramakrishnan
S
S
Thomas
Ajesh P
AP
Suresh
Eringathodi
E
Srinivasan
Alagar
A
D018360:Crystallography, X-Ray; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry; D010165:Palladium / Q000737:chemistry; D011166:Porphyrins / Q000138:chemical synthesis* / Q000737:chemistry*; D013237:Stereoisomerism; D014961:X-Ray Diffraction
D011166:Porphyrins; C051407:porphycene; D010165:Palladium; D009532:Nickel