The effect of complex stoichiometry in supramolecular chirality transfer to zinc bisporphyrin systems.
The self-assembly of Zn-bisporphyrin tweezers induced by coordination to enantiopure 1,2-diaminocyclohexane features supramolecular chirality induction and inversion processes that are exclusively controlled by the stoichiometry of the assembled complexes.
Etxebarria
Juan
J
Institute of Chemical Research of Catalonia (ICIQ), Avgda. Països Catalans 16, 43007, Tarragona, Spain.
Vidal-Ferran
Anton
A
Ballester
Pablo
P
D002942:Circular Dichroism; D046911:Macromolecular Substances / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D011166:Porphyrins / Q000737:chemistry*; D013057:Spectrum Analysis; D013237:Stereoisomerism; D015032:Zinc / Q000737:chemistry*
D046911:Macromolecular Substances; D011166:Porphyrins; D015032:Zinc