Fluorescence enhancement of ruthenium complex on silver using different chain length carboxylic acid terminated thiols: distance and metal concentration study.
The fluorescence enhancement of ruthenium complex (Ru(bpy)3(2+)) was studied on silver surface deposited by simple Tollens mirror reaction. The plasmon effects on spacer distance, silver concentration, and deposition methods were examined. Silver nanoparticles prepared were coated with different chain length carboxylic acid-terminated thiols as spacers. This leads to development of distance between Ag and Ru dye being varied from 4 to 23 A. Effect of different silver deposition methods on the emission spectra was also studied using metal evaporator deposition method. The results show that Ag concentration, Ag film roughness, and specific distance between metal and dye should be tuned for a maximum increase in fluorescence.
Chaudhari
Nitin K
NK
Department of Advanced Materials Chemistry BK21 Research Team, Korea University, Jochiwon, Chungnam 339-700, Korea.
Kim
Minsik
M
Kim
Hwan Kyu
HK
Choi
Seong-Ho
SH
Yoon
Kuk Ro
KR
Lee
Kwang-Sup
KS
Yu
Jong-Sung
JS
D002264:Carboxylic Acids / Q000737:chemistry*; D002621:Chemistry / Q000379:methods; D005227:Fatty Acids / Q000737:chemistry; D005453:Fluorescence; D005456:Fluorescent Dyes / Q000737:chemistry / Q000494:pharmacology; D053768:Metal Nanoparticles / Q000737:chemistry*; D008956:Models, Chemical; D053758:Nanoparticles / Q000737:chemistry; D036103:Nanotechnology / Q000379:methods*; D012428:Ruthenium / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D013050:Spectrometry, Fluorescence / Q000379:methods; D013059:Spectrum Analysis, Raman / Q000379:methods; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D014466:Ultraviolet Rays
C505222:11-mercaptoundecanoic acid; D002264:Carboxylic Acids; D005227:Fatty Acids; D005456:Fluorescent Dyes; D013438:Sulfhydryl Compounds; D012834:Silver; D012428:Ruthenium