title: The effects of pressure on valence tautomeric transitions of dinuclear cobalt complexes.
abstract: The effects of pressure on valence trautomeric transition behavior of two complexes, [{Co(tpa)}2(dhbq)].(PF6)3 (.(PF6)3) and [{Co(dpqa)}2(dhbq)](PF6)3 (II x (PF6)3) (tpa = tris(2-pyridylmethyl)amine, dpqa = di(2-pyridylmethyl)-N-(quinolin-2-ylmethyl)amine and dhbq = deprotonated 2,5-dihydroxy-1,4-benzoquinone), in the light of changes of magnetic susceptibilities were investigated; the results show that external pressure makes the SC + ET transition process of the two complexes into a general SC process only.
authors.affiliation: State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, Xiamen University, Xiamen, 361005, People's Republic of China.
authors.forename: Bao
authors.initials: B
authors.lastname: Li
authors.forename: Feng-Lei
authors.initials: FL
authors.lastname: Yang
authors.forename: Jun
authors.initials: J
authors.lastname: Tao
authors.forename: Osamu
authors.initials: O
authors.lastname: Sato
authors.forename: Rong-Bin
authors.initials: RB
authors.lastname: Huang
authors.forename: Lan-Sun
authors.initials: LS
authors.lastname: Zheng