The self-assembly and magnetic properties of a Ni(II)8(micro4-hydroxo)6 cube with micro2-pyrazolate as an exogeneous ancillary ligand.
A novel octanuclear hydroxonickel(II) complex possessing a unprecedented cube molecular structure with eight Ni(II) ions at each vertex, six micro4-OH- groups closing each face and twelve exo-bidentate pyrazolate ligands (micro2-pz) spanning each edge, has been synthesized and its magnetic properties investigated.
Xu
Jing-Yuan
JY
College of Pharmacy, Tianjin Medical University, Tianjin 300070, PR China.
Qiao
Xin
X
Song
Hai-Bin
HB
Yan
Shi-Ping
SP
Liao
Dai-Zheng
DZ
Gao
Song
S
Journaux
Yves
Y
Cano
Joan
J
D006900:Hydroxylation; D008024:Ligands; D008280:Magnetics; D008958:Models, Molecular; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D011720:Pyrazoles / Q000737:chemistry; D013237:Stereoisomerism
D008024:Ligands; D011720:Pyrazoles; C031280:pyrazole; D009532:Nickel