Coordination-driven self-assembly of functionalized supramolecular metallacycles.
Coordination-driven self-assembly that combines rigid ditopic Pt(II) metal acceptors and bis-pyridyl organic donors provides a facile means of synthesizing well-defined metallacycles of predetermined size and geometry. Functionalization of the component acceptor or donor building blocks allows for the preparation of multifunctional supramolecular materials wherein the stoichiometry and position of individual functional moieties can be precisely controlled. The design, self-assembly, and applications of polyfunctional supramolecules incorporating functional moieties with host-guest, photonic, materials, and self-organizational properties is discussed.
Northrop
Brian H
BH
University of Utah Department of Chemistry, 315 So. 1400 E., Salt Lake City, UT, USA. b.northrop@utah.edu
Yang
Hai-Bo
HB
Stang
Peter J
PJ
D043844:Crown Ethers / Q000138:chemical synthesis / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D017671:Platinum Compounds / Q000138:chemical synthesis / Q000737:chemistry
D043844:Crown Ethers; D009942:Organometallic Compounds; D017671:Platinum Compounds