Novel three-dimensional 3d-4f microporous magnets exhibiting selective gas adsorption behavior.
Three microporous Ln-Co-pyta heterometallic compounds [Ln4Co3(pyta)6(H2O)9].5H2O (Ln = Sm (1), Eu (2), Gd (3); H3pyta = 2,4,6-pyridinetricarboxylic acid) have interesting selective adsorption abilities towards H2/N2 and CO2/N2 because of size-selective effects; magnetic analysis reveals that has a ferromagnetic behavior.
Li
Cui-Jin
CJ
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry/State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, 510275 Guangzhou, PR China.
Lin
Zhuo-Jia
ZJ
Peng
Meng-Xia
MX
Leng
Ji-Dong
JD
Yang
Ming-Mei
MM
Tong
Ming-Liang
ML
D000327:Adsorption; D005740:Gases / Q000737:chemistry*; D008280:Magnetics; D008958:Models, Molecular; D008968:Molecular Conformation; D016062:Porosity
D005740:Gases