title: Modular chiral dendritic monodentate phosphoramidite ligands for Rh(II)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity.
abstract: Modular chiral dendrimers with monodentate phosphoramidite ligands located at the core were synthesized and applied in the Rh-catalyzed asymmetric hydrogenations, afforded unprecedented enhancement of enantioselectivity.
authors.affiliation: Beijing National Laboratory for Molecular Sciences, Center for Chemical Biology, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, PR China.
authors.forename: Feng
authors.initials: F
authors.lastname: Zhang
authors.forename: Yong
authors.initials: Y
authors.lastname: Li
authors.forename: Zhi-Wei
authors.initials: ZW
authors.lastname: Li
authors.forename: Yan-Mei
authors.initials: YM
authors.lastname: He
authors.forename: Shou-Fei
authors.initials: SF
authors.lastname: Zhu
authors.forename: Qing-Hua
authors.initials: QH
authors.lastname: Fan
authors.forename: Qi-Lin
authors.initials: QL
authors.lastname: Zhou
mesh_terms: D002384:Catalysis; D050091:Dendrimers / Q000138:chemical synthesis* / Q000737:chemistry; D006865:Hydrogenation; D008024:Ligands; D015394:Molecular Structure; D009943:Organophosphorus Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D050091:Dendrimers; D008024:Ligands; D009943:Organophosphorus Compounds; C434331:phosphoramidite; D012238:Rhodium