The effects of pressure on valence tautomeric transitions of dinuclear cobalt complexes.
The effects of pressure on valence trautomeric transition behavior of two complexes, [{Co(tpa)}2(dhbq)].(PF6)3 (.(PF6)3) and [{Co(dpqa)}2(dhbq)](PF6)3 (II x (PF6)3) (tpa = tris(2-pyridylmethyl)amine, dpqa = di(2-pyridylmethyl)-N-(quinolin-2-ylmethyl)amine and dhbq = deprotonated 2,5-dihydroxy-1,4-benzoquinone), in the light of changes of magnetic susceptibilities were investigated; the results show that external pressure makes the SC + ET transition process of the two complexes into a general SC process only.
Li
Bao
B
State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, Xiamen University, Xiamen, 361005, People's Republic of China.
Yang
Feng-Lei
FL
Tao
Jun
J
Sato
Osamu
O
Huang
Rong-Bin
RB
Zheng
Lan-Sun
LS