Heterogeneously hybridized porous coordination polymer crystals: fabrication of heterometallic core-shell single crystals with an in-plane rotational epitaxial relationship.
MOF on MOF: Core-shell porous coordination polymer (PCP) crystals are fabricated at the single-crystal level by epitaxial growth in solution. Synchrotron X-ray diffraction measurements unveiled the structural relationship between the shell crystal and the core crystal, where in-plane rotational epitaxial growth compensates the difference in lattice constant.
Furukawa
Shuhei
S
ERATO Kitagawa Integrated Pores Project (Japan), Kyoto Research Park Bldg #3, Shimogyo-ku, Kyoto 600-8815, Japan.
Hirai
Kenji
K
Nakagawa
Keiji
K
Takashima
Yohei
Y
Matsuda
Ryotaro
R
Tsuruoka
Takaaki
T
Kondo
Mio
M
Haruki
Rie
R
Tanaka
Daisuke
D
Sakamoto
Hirotoshi
H
Shimomura
Satoru
S
Sakata
Osami
O
Kitagawa
Susumu
S