Nanoparticle-supported and magnetically recoverable palladium (Pd) catalyst: a selective and sustainable oxidation protocol with high turnover number.
A magnetic nanoparticle-supported Pd catalyst was readily prepared from inexpensive starting materials and shown to catalyze various oxidation reactions with high turnover number (TON) and excellent selectivity. The ease of recovery using an external magnetic field, high activity, and the intrinsic stability of the catalyst make this protocol economic and sustainable.
Polshettiwar
Vivek
V
Sustainable Technology Division, National Risk Management Research Laboratory, U. S. Environmental Protection Agency, MS 443, Cincinnati, Ohio 45268, USA. polshettiwar.vivek@epa.gov
Varma
Rajender S
RS
D000438:Alcohols / Q000737:chemistry; D002384:Catalysis; D007501:Iron / Q000737:chemistry; D008280:Magnetics; D046529:Microscopy, Electron, Transmission; D008956:Models, Chemical; D008968:Molecular Conformation; D015394:Molecular Structure; D053758:Nanoparticles / Q000737:chemistry*; D036103:Nanotechnology / Q000379:methods*; D010100:Oxygen / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature; D014961:X-Ray Diffraction
D000438:Alcohols; D010165:Palladium; D007501:Iron; D010100:Oxygen