title: Preparation, characterization, and catalytic studies of magnesium complexes supported by NNO-tridentate Schiff-base ligands.
abstract: A series of magnesium benzyl alkoxides, [LMg(mu-OBn)](2) (1-8), supported by NNO-tridentate Schiff-base ligands are prepared by the reactions of Mg(OBn)(2) with one molar equivalent of related Schiff-base ligands (L(1)H-L(8)H) in toluene. The molecular structures of compounds 2, 3, 7, and 8 are characterized by X-ray structure determination. All of these compounds are crystallized as penta-coordinated dimers, and the central magnesium atoms are bridged by the oxygen atoms of benzyl alkoxides. The catalytic activities of complexes 1-8 toward the ring-opening polymerization of l-lactide are investigated. Experimental results indicate that the reactivity of [LMg(mu-OBn)](2) (1-8) is dramatically affected by the electronic effect of the substituents on the Schiff-base ligands, and 4 has the highest activity among them.
authors.affiliation: Department of Chemistry, National Chung Hsing University, Taichung 402, Taiwan, Republic of China.
authors.forename: Wen-Chou
authors.initials: WC
authors.lastname: Hung
authors.forename: Chu-Chieh
authors.initials: CC
authors.lastname: Lin