Analysis of polycyclic aromatic hydrocarbons in solid matrixes by solid-phase microextraction coupled to a direct extraction device.
Analysis of polycyclic aromatic hydrocarbons (PAHs) standards in model systems was carried out by solid-phase microextraction (SPME) coupled to a direct extraction device (DED) and subsequent gas chromatography/mass spectrometry (GC/MS). PAHs standard was added to gelatine systems at different concentrations. Extraction process was carried out by SPME-DED at 25 degrees C for 60min. Polydimethylsiloxane 100microm (PDMS 100microm), divinylbenzene/polydimethylsiloxane 65microm (DVB/PDMS 65microm) and polyacrilate 85microm (PA 85microm) SPME fibres were tested. SPME-DED satisfactorily extracted PAHs with a molecular weight (MW) lower than 206 from the gelatine system. All fibres showed a good reproducibility (residual standard deviation (RSD) between 5.24% and 18.25%), linearity (regression coefficients between 0.8959 and 0.9983) and limit of detection (LOD) (between 0.008 and 0.138ng mL(-1)). Presence of PAHs in different smoked meat products was also tested by SPME-DED. Different low MW PAHs were satisfactorily detected from all the foodstuffs studied. SPME-DED appears as a rapid, non-destructive technique for primary screening of low MW PAHs in solid matrixes.
Martin
Diana
D
Food Science, Facultad de Veterinaria UEx., Campus Universitario s/n, 10071 Caceres, Spain.
Ruiz
Jorge
J