[Sulfide removal from wastewater by nanoscale iron].
Influencing factors, adsorption isotherm, adsorption kinetics and preliminary discussion on the mechanism of sulfide adsorption by nanoscale iron prepared in laboratory were studied using manual simulation sulfide wastewater. Experimental results indicate that the removal efficiency of S2- increases with increasing iron dosage and decreases with increasing initial S2- concentration and pH values. The removal efficiency of S2- is 100% when initial concentration is less than 100 mg x L(-1) and are 87.34%, 65.80% and 44.61% at pH 2, 7 and 13. The temperature at 25 degrees C favors the maximum adsorption of S2- with 19.17 mg x g(-1) of equilibrium adsorption quantity and the adsorption capacity decreas at higher or lower temperature. The adsorption data fit well to the Langmuir equation and the Freundlich equation. The sulfide adsorption follows the pseudo second order equation with the maximum initial sorption rate(h) is 1.575 3 mg x (g x mg)(-1) at 25 degrees C and the adsorption rate constant increases with the increasing of temperature. The activation energy(Ea) is 8.22 kJ x mol(-1). The mechanism of sulfide removal is being sorbed onto the iron nanoparticles via formation of surface compleses, FeOSH and iron sulfides (FeS, FeS2, FeSn).
Xi
Hong-bo
HB
School of Water Resources and Environment, China University of Geosciences, Beijing 100083, China. xhongbwl@yahoo.cn
Yang
Qi
Q
Shang
Hai-tao
HT
Hao
Chun-bo
CB
Li
Zhi-ling
ZL
D000327:Adsorption; D005296:Ferrous Compounds / Q000737:chemistry; D007501:Iron / Q000737:chemistry*; D053768:Metal Nanoparticles / Q000737:chemistry*; D013440:Sulfides / Q000737:chemistry / Q000302:isolation & purification*; D014865:Waste Disposal, Fluid / Q000379:methods*
D005296:Ferrous Compounds; D013440:Sulfides; C020748:ferrous sulfate; D007501:Iron