title: Mercury or silver atoms bridging trinuclear titanium imido-nitrido systems.
abstract: The imido-nitrido complex [{Ti(eta(5)-C(5)Me(5))(mu-NH)}(3)(mu(3)-N)] entraps mercury(ii) or silver(i) halides MX(n) to give cube-type adducts [X(n)M{(mu(3)-NH)(3)Ti(3)(eta(5)-C(5)Me(5))(3)(mu(3)-N)}] which react with alkali metal bis(trimethylsilyl)amide reagents to afford [M(2){(mu(3)-N)(n)(mu(3)-NH)(2-n)Ti(3)(eta(5)-C(5)Me(5))(3)(mu-NH)(mu(3)-N)}(2)] (M = Hg, n = 2; M = Ag, n = 1) where two [Ti(3)N(4)] cores are linked by two mercury or silver atoms in a linear geometry.
authors.affiliation: Departamento de Química Inorgánica, Universidad de Alcalá, 28871, Alcalá de Henares-Madrid, Spain.
authors.forename: Avelino
authors.initials: A
authors.lastname: Martín
authors.forename: Noelia
authors.initials: N
authors.lastname: Martínez-Espada
authors.forename: Miguel
authors.initials: M
authors.lastname: Mena
authors.forename: Marta E G
authors.initials: ME
authors.lastname: Mosquera
authors.forename: Adrián
authors.initials: A
authors.lastname: Pérez-Redondo
authors.forename: Carlos
authors.initials: C
authors.lastname: Yélamos