Diazaphospholidine terminated polyhedral oligomeric silsesquioxanes in the hydroformylation of vinyl acetate.
The poorly active, monodentate SemiEsphos phosphine has been turned into an active ligand for rhodium catalysed vinyl acetate hydroformylation by attachment to the periphery of a polyhedral oligomeric silsesquioxane.
Vautravers
Nicolas R
NR
School of Chemistry, University of St. Andrews, St. Andrews, Fife, UK KY16 9ST.
Cole-Hamilton
David J
DJ