First example of an enantiopure planar chiral ligand built on a (eta5-cyclohexadienyl)Mn(CO)3 scaffold.
The synthesis of (eta5-cyclohexadienyl)Mn(CO)3-based planar chiral ligands is realized by an efficient lithiation/electrophilic quench procedure, and the coordinating properties of one of them are highlighted together with its optical resolution.
Cetiner
Derya
D
UPMC Univ Paris 06, UMR CNRS 7611, Laboratoire de Chimie Organique, Institut de Chimie Moléculaire (FR 2769), Case 181, 4 place Jussieu, F-75252, Paris Cedex 05, France.
Jacques
Béatrice
B
Payet
Elina
E
Chavarot-Kerlidou
Murielle
M
Rose-Munch
Françoise
F
Rose
Eric
E
Tranchier
Jean-Philippe
JP
Herson
Patrick
P