Metallopeptoids.
N-substituted glycine peptoid oligomers bearing hydroxyquinoline ligands form complexes with Cu(ii) and Co(ii) in which the chiral helical secondary structure of the foldamers is enhanced upon metal binding and establishes a stereogenic environment for metal coordination.
Maayan
Galia
G
Department of Chemistry and the Molecular Design Institute, New York University, New York, New York 10003-6688, USA.
Ward
Michael D
MD
Kirshenbaum
Kent
K
D002851:Chromatography, High Pressure Liquid; D003035:Cobalt / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D006912:Hydroxyquinolines / Q000737:chemistry*; D008958:Models, Molecular; D009842:Oligopeptides / Q000138:chemical synthesis* / Q000737:chemistry; D011487:Protein Conformation; D019032:Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization; D013056:Spectrophotometry, Ultraviolet
D006912:Hydroxyquinolines; D009842:Oligopeptides; D003035:Cobalt; D003300:Copper