title: Investigation of the [Cp*Mo(PMe3)3H]n+ (n = 0, 1) redox pair: dynamic processes on very different time scales.
abstract: The compound [Cp*Mo(PMe3)3H] (1) is reversibly oxidized at E1/2 = -1.40 V vs ferrocene in MeCN. Its oxidation with Cp2FePF6 yields thermally stable [Cp*Mo(PMe3)3H]PF6 (2), which has been isolated and characterized by IR and EPR spectroscopy and by single-crystal X-ray diffraction. The 1H and 31P NMR spectra of 1 show two types of PMe3 ligands in a 1:2 ratio at low temperature, but only one average signal at room temperature, with activation parameters of DeltaH++ = 11.7(3) kcal mol-1 and DeltaS++ = -3(1) eu for the exchange process. Although only one species is evidenced by NMR for 1 and by EPR for 2, the solution IR spectra of each complex show two bands in the v(Mo-H) region (1, major at 1794 cm-1 and minor at ca. 1730 cm-1; 2, ca. 1800 and 1770 cm-1 with approximately equal intensity), the position and relative intensity being little dependent on the solvent. A thorough DFT investigation suggests that these are different rotamers involving different relative orientations of the Cp* ring and the PMe3 ligands in these complexes. This ring rotation process is very rapid on the NMR and EPR time scale but slow on the IR time scale. The X-ray data and the theoretical calculations suggest the presence of weak Mo-H...F interactions in compound 2. The possibility of PMe3 dissociation, as well as other intramolecular rearrangements, for 1 and 2 is excluded by experimental and computational studies. Protonation of 1 yields [Cp*Mo(PMe3)3H2]+ (3), which also reveals a dynamic process interconverting the two inequivalent H ligands and the three PMe3 ligands (two sets in a 1:2 ratio in the frozen structure) on the NMR time scale (activation parameters of DeltaH++ = 9.3(1) kcal/mol and DeltaS++ = -4.1(4) eu). A DFT study suggests that this exchange process occurs via a low-energy symmetric dihydride intermediate and not through a dihydrogen complex.
authors.affiliation: LCC (Laboratoire de Chimie de Coordination), CNRS, 205 route de Narbonne, F-31077 Toulouse, France.
authors.forename: Miguel
authors.initials: M
authors.lastname: Baya
authors.forename: Pavel A
authors.initials: PA
authors.lastname: Dub
authors.forename: Jennifer
authors.initials: J
authors.lastname: Houghton
authors.forename: Jean-Claude
authors.initials: JC
authors.lastname: Daran
authors.forename: Natalia V
authors.initials: NV
authors.lastname: Belkova
authors.forename: Elena S
authors.initials: ES
authors.lastname: Shubina
authors.forename: Lina M
authors.initials: LM
authors.lastname: Epstein
authors.forename: Agustí
authors.initials: A
authors.lastname: Lledós
authors.forename: Rinaldo
authors.initials: R
authors.lastname: Poli