title: Eta3-diphosphavinylcarbene: a P2 analogue of the Dötz intermediate.
abstract: Do the twist: The reaction of in situ generated phosphinidenes with phosphaalkynes is a facile route to the new metal-coordinated eta(3)-diphosphavinylcarbene 1, which shows facile ligand-exchange reactions and undergoes an unprecedented rearrangement that involves phosphinidene complex 2 and eta(3)-phosphaalkenylphosphinidene complex 3, the 1,3 isomer of 1.
authors.affiliation: Department of Chemistry and Pharmaceutical Sciences, VU University Amsterdam, De Boelelaan 1083, 1081 HV Amsterdam, The Netherlands.
authors.forename: Halil
authors.initials: H
authors.lastname: Aktas
authors.forename: J Chris
authors.initials: JC
authors.lastname: Slootweg
authors.forename: Andreas W
authors.initials: AW
authors.lastname: Ehlers
authors.forename: Martin
authors.initials: M
authors.lastname: Lutz
authors.forename: Anthony L
authors.initials: AL
authors.lastname: Spek
authors.forename: Koop
authors.initials: K
authors.lastname: Lammertsma
mesh_terms: D010758:Phosphorus / Q000737:chemistry*; D014753:Vinyl Compounds / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: D014753:Vinyl Compounds; C540997:eta3-diphosphavinylcarbene; C516829:vinylcarbene; D010758:Phosphorus