Long-distance ferromagnetic coupling through spin polarization in a linear heterotrinuclear iron(III)-copper(II)-iron(III) complex derived from 5-ferrocenyl-2-aminotropone.
A novel hetrotrinuclear complex composed of two ferrocenium-ion moieties and copper complex of 2-aminotropones showed relatively strong intramolecular ferromagnetic coupling in the solid states owing to spin polarization mechanism.
Miyake
Yoshihiro
Y
Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, Hachioji, Tokyo, 192-0397, Japan.
Watanabe
Sayaka
S
Aono
Satoshi
S
Nishinaga
Tohru
T
Miyazaki
Akira
A
Enoki
Toshiaki
T
Miyasaka
Hitoshi
H
Otani
Hiroyuki
H
Iyoda
Masahiko
M