title: Polymer-immobilized catalyst for asymmetric hydrogenation of racemic alpha-(N-benzoyl-N-methylamino)propiophenone.
abstract: Asymmetric hydrogenation of alpha-(N-benzoyl-N-methylamino)propiophenone through dynamic kinetic resolution was performed by using a polymer-immobilized chiral diamine-ruthenium-BINAP-t-BuOK system in order to yield syn-beta-amide alcohol exclusively with nearly perfect enantioselectivity.
authors.affiliation: Department of Materials Science, Toyohashi University of Technology, Tempaku-cho, Toyohashi 441-8580, Japan.
authors.forename: Vinia Ipai
authors.initials: VI
authors.lastname: Chiwara
authors.forename: Naoki
authors.initials: N
authors.lastname: Haraguchi
authors.forename: Shinichi
authors.initials: S
authors.lastname: Itsuno
mesh_terms: D002384:Catalysis; D003959:Diamines / Q000737:chemistry; D006865:Hydrogenation; D007700:Kinetics; D008024:Ligands; D011108:Polymers / Q000737:chemistry*; D011427:Propiophenones / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D003959:Diamines; D008024:Ligands; D011108:Polymers; D011427:Propiophenones