Solution phase, solid state, and theoretical investigations on the MacMillan imidazolidinone.
A combination of solution phase NMR, X-ray crystallographic studies, and DFT calculations provide a consistent structural conformation for iminium ions derived from the MacMillan imidazolidinone.
Brazier
John B
JB
School of Chemistry, Main Building, Cardiff University, Park Place, Cardiff, CF10 3AT, United Kingdom.
Evans
Gareth
G
Gibbs
Timothy J K
TJ
Coles
Simon J
SJ
Hursthouse
Michael B
MB
Platts
James A
JA
Tomkinson
Nicholas C O
NC
D002384:Catalysis; D018360:Crystallography, X-Ray; D003500:Cyclization; D048289:Imidazolidines / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008956:Models, Chemical; D008958:Models, Molecular; D015394:Molecular Structure; D012996:Solutions
D048289:Imidazolidines; D012996:Solutions