Mercury or silver atoms bridging trinuclear titanium imido-nitrido systems.
The imido-nitrido complex [{Ti(eta(5)-C(5)Me(5))(mu-NH)}(3)(mu(3)-N)] entraps mercury(ii) or silver(i) halides MX(n) to give cube-type adducts [X(n)M{(mu(3)-NH)(3)Ti(3)(eta(5)-C(5)Me(5))(3)(mu(3)-N)}] which react with alkali metal bis(trimethylsilyl)amide reagents to afford [M(2){(mu(3)-N)(n)(mu(3)-NH)(2-n)Ti(3)(eta(5)-C(5)Me(5))(3)(mu-NH)(mu(3)-N)}(2)] (M = Hg, n = 2; M = Ag, n = 1) where two [Ti(3)N(4)] cores are linked by two mercury or silver atoms in a linear geometry.
Martín
Avelino
A
Departamento de Química Inorgánica, Universidad de Alcalá, 28871, Alcalá de Henares-Madrid, Spain.
Martínez-Espada
Noelia
N
Mena
Miguel
M
Mosquera
Marta E G
ME
Pérez-Redondo
Adrián
A
Yélamos
Carlos
C