Eta3-diphosphavinylcarbene: a P2 analogue of the Dötz intermediate.
Do the twist: The reaction of in situ generated phosphinidenes with phosphaalkynes is a facile route to the new metal-coordinated eta(3)-diphosphavinylcarbene 1, which shows facile ligand-exchange reactions and undergoes an unprecedented rearrangement that involves phosphinidene complex 2 and eta(3)-phosphaalkenylphosphinidene complex 3, the 1,3 isomer of 1.
Aktas
Halil
H
Department of Chemistry and Pharmaceutical Sciences, VU University Amsterdam, De Boelelaan 1083, 1081 HV Amsterdam, The Netherlands.
Slootweg
J Chris
JC
Ehlers
Andreas W
AW
Lutz
Martin
M
Spek
Anthony L
AL
Lammertsma
Koop
K
D010758:Phosphorus / Q000737:chemistry*; D014753:Vinyl Compounds / Q000138:chemical synthesis / Q000737:chemistry*
D014753:Vinyl Compounds; C540997:eta3-diphosphavinylcarbene; C516829:vinylcarbene; D010758:Phosphorus