Formation of dodecaphenylporphodimethene via facile protonation of saddle-distorted dodecaphenylporphyrin.
A saddle-distorted dodecaphenylporphyrin undergoes protonation followed by two-electron reduction by SnCl(2) to give a roof-shaped dodecaphenylporphodimethene which exhibits reversible one-electron reduction and oxidation behaviour in benzonitrile to allow us to observe an ESR spectrum of pi-cation radical in the course of electrochemical oxidation.
Kojima
Takahiko
T
Department of Material and Life Science, Osaka University, Suita, Osaka 565-0871, Japan. kojima@chem.eng.osaka-u.ac.jp
Hanabusa
Kakeru
K
Ohkubo
Kei
K
Shiro
Motoo
M
Fukuzumi
Shunichi
S
D018360:Crystallography, X-Ray; D004563:Electrochemistry; D004578:Electron Spin Resonance Spectroscopy; D008958:Models, Molecular; D010084:Oxidation-Reduction; D011166:Porphyrins / Q000138:chemical synthesis* / Q000737:chemistry; D013057:Spectrum Analysis
D011166:Porphyrins