Diastereoisomeric bisphosphite ligands in the hydroformylation of octenes: rhodium catalysis and HP-NMR investigations.
Diastereoisomeric hydroformylation catalysts show differences for the catalyst preformation pathway and a strongly reduced n-octene hydroformylation activity for the (S,S,R)-isomer.
Selent
Detlef
D
Leibniz-Institut für Katalyse an der Universität Rostock e.V., A.-Einstein-Str., 29a, 18059, Rostock, Germany. detlef.selent@catalysis.de
Baumann
Wolfgang
W
Wiese
Klaus-Diether
KD
Börner
Armin
A