Preparation of a spontaneous resolution chiral fluorescent system using 2-anthracenecarboxylic acid.
A spontaneous resolution chiral fluorescent system is prepared by using 2-anthracenecarboxylic acid, and racemic (rac)-1-phenylethylamine or rac-1-cyclohexylethylamine. Although chiral functional organic materials are usually prepared using chiral molecules, in this system, a chiral organic fluorophore, which exhibits fluorescence in the solid state, is prepared from achiral and rac molecules.
Imai
Yoshitane
Y
Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan. y-imai@apch.kindai.ac.jp
Kamon
Kensaku
K
Murata
Katuzo
K
Harada
Takunori
T
Nakano
Yoko
Y
Sato
Tomohiro
T
Fujiki
Michiya
M
Kuroda
Reiko
R
Matsubara
Yoshio
Y
D000042:Absorption; D000588:Amines / Q000737:chemistry; D000873:Anthracenes / Q000737:chemistry*; D002264:Carboxylic Acids / Q000737:chemistry*; D002942:Circular Dichroism; D018360:Crystallography, X-Ray; D005453:Fluorescence; D013237:Stereoisomerism; D013997:Time Factors
C476641:2-anthracenecarboxylate; D000588:Amines; D000873:Anthracenes; D002264:Carboxylic Acids