Automatic screening method for the preconcentration and determination of N-nitrosamines in water.
A screening method was developed to discriminate among water samples contaminated or uncontaminated with N-nitrosamines in order to reduce the use of expensive instruments such as chromatographs. The system is based on the preconcentration of the analytes onto a sorbent column, elution and derivatization to form nitrite, then formation of a coloured product (Griess reaction) and photometric detection. The limit of detection achieved for 100ml of sample volume was 0.2mug/l and the sample frequency 3h(-1). The reliability of the proposed method of the N-nitrosamines was established at five concentrations (between 0.5 and 3 times the limit of detection). For a level concentration of 0.6mug/l (three times the limit of detection), the percentage of false negatives is 0%. The method was applied to the screening of several water samples (river, pond, well, tap and waste) with a positive response only for waste water samples.
Jurado-Sánchez
Beatriz
B
Department of Analytical Chemistry, Campus de Rabanales, University of Córdoba, E-14071 Córdoba, Spain.
Ballesteros
Evaristo
E
Gallego
Mercedes
M