Determination of haloethers in water with dynamic hollow fiber liquid-phase microextraction using GC-FID and GC-ECD.
Dynamic hollow fiber liquid-phase microextraction (HF-LPME) coupled with gas chromatography with flame ionization detection (GC-FID) and GC-electron capture detecion (GC-ECD) was used for quantification of toxic haloethers in lake water. The analytes were extracted from 5ml of aqueous sample using 4microl of organic solvent through a porous polypropylene hollow fiber. The effects on extraction performance of solvent selection, agitation rate, extraction time, extraction temperature, concentration of salt added and volumes of solvent for extraction and injection were optimized. The proposed method provided a good average enrichment factor of up to 231-fold, reasonable reproducibility ranging from 9 to 12% (n=3), and good linearity (R(2)> or =0.9973) for spiked water samples. Method detection limits (MDLs) ranged from 0.55 to 4.30microg/l for FID and 0.11-0.34microg/l for ECD (n=7).
Chiang
Jing-Shan
JS
Department of Chemistry, National Tsing Hua University, Hsinchu 30043, Taiwan.
Huang
Shang-Da
SD