Cyanide-bridged one-dimensional ferromagnetic Ru(III)Mn(III) coordination polymer exhibiting a field-induced magnetic phase transition.
A cyanide-linked Ru(III)(4d)-Mn(III)(3d) bimetallic chain complex (1) was prepared by the self-assembly of a ruthenium(III) bicyanide and a Mn(III) Schiff base. Ferromagnetic couplings between the magnetic centers are present within a chain, while antiferromagnetic interactions between chains (T(N) = 2.5 K) transmit. Complex 1 also shows a field-induced magnetic phase transition.
Yoon
Jung Hee
JH
Department of Chemistry, Korea University, Seoul 136-713, Korea.
Yoo
Houng Sik
HS
Kim
Hyoung Chan
HC
Yoon
Sung Won
SW
Suh
Byoung Jin
BJ
Hong
Chang Seop
CS