title: Interaction of ionic liquids with polysaccharides, 8 - synthesis of cellulose sulfates suitable for polyelectrolyte complex formation.
abstract: Water-soluble CS with different DS were synthesized by homogeneous conversion of cellulose (microcrystalline cellulose and spruce sulfite pulp) with different sulfating agents in the ionic liquids BMIMCl, AMIMCl and EMIMAc. N,N-Dimethylformamide was used as a dipolar aprotic co-solvent in order to improve the miscibility of the reaction mixture. The CS prepared by the new homogeneous reaction pathway were studied towards the formation of PEC capsules. CS obtained from SSP formed mechanically stable PEC capsules with PolyDADMAC. Exploiting this method, the microencapsulation of glucose oxidase was studied and enzyme activity tests were performed with encapsulated GOD.
authors.affiliation: Center of Excellence for Polysaccharide Research, Friedrich Schiller University of Jena, Jena, Germany.
authors.forename: Martin
authors.initials: M
authors.lastname: Gericke
authors.forename: Tim
authors.initials: T
authors.lastname: Liebert
authors.forename: Thomas
authors.initials: T
authors.lastname: Heinze
mesh_terms: D001709:Biotechnology / Q000379:methods*; D017690:Cell Transplantation / Q000379:methods*; D002482:Cellulose / Q000031:analogs & derivatives* / Q000737:chemistry; D004573:Electrolytes / Q000737:chemistry*; D015394:Molecular Structure; D011108:Polymers / Q000737:chemistry*
chemical_list: D004573:Electrolytes; D011108:Polymers; D002482:Cellulose; C020254:cellulose sulfate