Synthesis of the originally proposed structures of elatenyne and an enyne from Laurencia majuscula.
A bidirectional synthesis of the originally proposed structures for the natural products elatenyne and a chloroenyne from Laurencia majuscula is described along with a reassessment of the structures of the halogenated enynes based upon a 13C NMR chemical shift/structure correlation.
Sheldrake
Helen M
HM
Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK.
Jamieson
Craig
C
Pascu
Sofia I
SI
Burton
Jonathan W
JW
D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry; D000480:Alkynes / Q000138:chemical synthesis* / Q000737:chemistry; D001688:Biological Products / Q000138:chemical synthesis; D005663:Furans / Q000138:chemical synthesis* / Q000737:chemistry; D044722:Laurencia / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D013237:Stereoisomerism
D000475:Alkenes; D000480:Alkynes; D001688:Biological Products; D005663:Furans; C535059:elatenyne