title: Recombination of an Fe-Si-P linkage to an Fe-P-Si linkage through an isolable intermediate phosphasilaferracyclopropane.
abstract: Phosphasilaferracycle [Cp*(CO)Fe{kappa(2)Si,P-SiMe(2)PPh(2)}], prepared upon irradiation of [Cp*(CO)(2)FeSiMe(2)PPh(2)], was converted to [Cp*(CO)(2)FeP(Ph)SiMe(2)Ph] under mild conditions. The unusual recombination of the iron, silicon, and phosphorus cores could be achieved through a sequence of 1,2- and 1,3-group migrations in an FeSiP system.
authors.affiliation: Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan.
authors.forename: Masaaki
authors.initials: M
authors.lastname: Okazaki
authors.forename: Takahiko
authors.initials: T
authors.lastname: Yoshitomi
authors.forename: Junpei
authors.initials: J
authors.lastname: Naito
authors.forename: Akira
authors.initials: A
authors.lastname: Sato
authors.forename: Takashi
authors.initials: T
authors.lastname: Komuro
authors.forename: Hiromi
authors.initials: H
authors.lastname: Tobita