Improved hydrogen storage properties of a V decorated Mg nanoblade array.
An ultra-thin layer of V has been coated onto the surface of individual Mg nanoblades by dynamic shadowing growth. This 2.25 at% V decorated Mg nanoblade array can absorb and desorb hydrogen rapidly at temperatures T>or= 500 K after activation by one hydrogen cycle, with a low hydrogen absorption activation energy of 35.0+/-1.2 kJ per mol H(2) and a desorption activation energy of 65.0+/-0.3 kJ per mol H(2). The improved hydrogen sorption kinetics is attributed to both the catalytic effect of the V coating and the unique nanoblade morphology with a large surface area and small hydrogen diffusion length.
He
Yuping
Y
Department of Physics and Astronomy, and Nanoscale Science and Engineering Center, University of Georgia, Athens, GA 30602, USA. yphe@physast.uga.edu
Zhao
Yiping
Y