title: Scope of the Suzuki-Miyaura cross-coupling reactions of potassium heteroaryltrifluoroborates.
abstract: A wide variety of bench-stable potassium heteroaryltrifluoroborates were prepared, and general reaction conditions were developed for their cross-coupling to aryl and heteroaryl halides. The cross-coupled products were obtained in good to excellent yields. This method represents an efficient and facile installation of heterocyclic building blocks onto preexisting organic substructures.
authors.affiliation: Roy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323, USA. gmolandr@sas.upenn.edu
authors.forename: Gary A
authors.initials: GA
authors.lastname: Molander
authors.forename: Belgin
authors.initials: B
authors.lastname: Canturk
authors.forename: Lauren E
authors.initials: LE
authors.lastname: Kennedy
mesh_terms: D001881:Borates / Q000138:chemical synthesis / Q000737:chemistry*; D005663:Furans / Q000138:chemical synthesis; D006571:Heterocyclic Compounds / Q000138:chemical synthesis*; D007546:Isoquinolines / Q000138:chemical synthesis / Q000737:chemistry; D017680:Potassium Compounds / Q000737:chemistry; D011725:Pyridines / Q000138:chemical synthesis / Q000737:chemistry
chemical_list: D001881:Borates; D005663:Furans; D006571:Heterocyclic Compounds; D007546:Isoquinolines; D017680:Potassium Compounds; D011725:Pyridines; C098759:fluoroboric acid