Production of biodiesel from bioethanol and Brassica carinata oil: oxidation stability study.
In the present work the synthesis from bioethanol and Brassica carinata, as alternative vegetable oil, using KOH as catalyst, has been developed and optimized by application of the factorial design and response surface methodology (RSM). Temperature and catalyst concentration were found to have significant influence on conversion. A second-order model was obtained to predict conversions as a function of temperature and catalyst concentration. The maximum yield of ester (98.04%) was obtained working with an initial concentration of catalyst (1.5%) and an operation temperature of (35 degrees C). Results show that the acid value, peroxide value, and viscosity, increased while the iodine value decreased with increasing storage time of the biodiesel sample. Fatty acid ethyl esters (biodiesel) from B. carinata oil were very stable because they did not demonstrate rapid increase in peroxide value, acid value, and viscosity with increasing storage time to a period of 12 months.
Bouaid
Abderrahim
A
Chemical Engineering Department, Faculty of Chemistry, University of Complutense, Madrid, Spain.
Martinez
Mercedes
M
Aracil
Jose
J
D000143:Acids; D001674:Bioelectric Energy Sources; D001937:Brassica / Q000378:metabolism*; D002384:Catalysis; D004952:Esters; D000431:Ethanol / Q000378:metabolism*; D010084:Oxidation-Reduction; D010545:Peroxides; D010938:Plant Oils / Q000378:metabolism*; D013696:Temperature; D014783:Viscosity
D000143:Acids; D004952:Esters; D010545:Peroxides; D010938:Plant Oils; D000431:Ethanol