title: Effect of pH, ionic strength, dissolved organic carbon, time, and particle size on metals release from mine drainage impacted streambed sediments.
abstract: Acid-mine drainage (AMD) input to a stream typically results in the stream having a reduced pH, increased concentrations of metals and salts, and decreased biological productivity. Removal and/or treatment of these AMD sources is desired to return the impacted stream(s) to initial conditions, or at least to conditions suitable for restoration of the aquatic ecosystem. Some expected changes in the water chemistry of the stream following removal of AMD input include an increase in pH, a decrease in ionic strength, and an increase in dissolved organic carbon (DOC) concentrations from increased biological activity in the absence of toxic metals concentrations. These changes in water chemistry may cause the existing contaminated bed sediments to become a source of metals to the stream water. Streambed sediments, collected from North Fork Clear Creek (NFCC), Colorado, currently impacted by AMD, were assessed for the effects of pH, ionic strength, DOC concentration, time, and particle size on metals release using a factorial design. The design included two levels for each chemical parameter (ionic strength = 40 and 80% lower than ambient; pH = 6 and 8; and DOC = 1 and 3 mg/l higher than ambient), ten sampling times (from zero to 48 h), and two size fractions of sediments (63 microm < or = x < 2 mm and < 63 microm). Greater concentrations of metals were released from the smaller sized sediments compared with the larger, with the exception of Cu. A mild acid digestion (0.6M HCl) evaluated the amount of each metal that could be removed easily from each of the sediment size fractions. Release of all metals over all time points, treatments, and from both sediment sizes was less than 1% of the extractable concentrations, with the exception of Mn, which ranged from 4 to 7% from the smaller sized sediment. Greater percentages of the 0.6M HCl-extractable concentrations of Cu, Fe, and Zn were released from the larger sized sediment, while this was true for release of Cd and Mn from the smaller sized sediment. Thus, at least for Cd and Mn, the observed higher concentrations released from the smaller sized sediment with each treatment solution is not simply a function of these particles having higher concentrations available for release, but that these metals also are more readily released from the smaller sediment particles versus the larger. DOC concentration strongly influenced the release of Cu; ionic strength strongly influenced the release of Cd, Mn, and Zn; and interaction effects were observed with the release of Cu, Mn, and Zn from the larger size fraction and with the release of Zn from the smaller size fraction. Overall, results suggest that the expected changes in water chemistry following removal/treatment of the AMD sources would result in a release of metals from the existing sediments, with a greater effect on the release of Cu and Fe, than on the release of Cd, Mn, and Zn.
authors.affiliation: U.S. EPA Office of Research and Development, National Risk Management Research Laboratory, Land Remediation and Pollution Control Division, 26 W. Martin Luther King Drive, Cincinnati, OH 45268, USA. butler.barbara@epa.gov
authors.forename: Barbara A
authors.initials: BA
authors.lastname: Butler
mesh_terms: D002244:Carbon / Q000737:chemistry*; D003120:Colorado; D005843:Geography; D019015:Geologic Sediments / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D008670:Metals / Q000302:isolation & purification*; D008906:Mining; D009930:Organic Chemicals / Q000737:chemistry; D009994:Osmolar Concentration; D010316:Particle Size; D011786:Quality Control; D045483:Rivers / Q000737:chemistry*; D012995:Solubility; D012996:Solutions; D013997:Time Factors; D014867:Water / Q000592:standards; D014874:Water Pollutants, Chemical / Q000737:chemistry*
chemical_list: D008670:Metals; D009930:Organic Chemicals; D012996:Solutions; D014874:Water Pollutants, Chemical; D014867:Water; D002244:Carbon