An enantiopure N,N,S scorpionate ligand derived from (+)-camphor.
Reductive S-S bond cleavage of a disulfide precursor obtained from a pyridine-catalyzed Peterson-type reaction starting from camphorpyrazole , thionyl chloride and 2-methyl-2-(methyldithio)propionaldehyde yields 2,2'-bis(camphorpyrazol-1-yl)-2-methylpropane-2-thiol (HSiprbpm3cam, ); the first zinc complexes bearing this ligand exhibit kappa3 coordination of the ligand.
Godau
Tom
T
Inorganic Chemistry, Department of Chemistry and Pharmacy & Inter-disciplinary Center for Molecular Materials (ICMM), Universität Erlangen-Nürnberg, Egerlandstrasse 1, 91058, Erlangen, Germany.
Platzmann
Florian
F
Heinemann
Frank W
FW
Burzlaff
Nicolai
N
D002164:Camphor / Q000737:chemistry*; D008024:Ligands; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D008024:Ligands; D009942:Organometallic Compounds; D002164:Camphor