FeNCN and Fe(NCNH)2: synthesis, structure, and magnetic properties of a nitrogen-based pseudo-oxide and -hydroxide of divalent iron.
Iron man challenge: Iron carbodiimide, FeNCN, and its precursor iron (bis)monohydrocyanamide, Fe(NCNH)(2), have been synthesized and physically characterized. Both FeNCN and Fe(NCNH)(2) exhibit nitrogen-mediated antiferromagnetic superexchange interactions with reduced magnetic moments very similar, but not identical, to the correlated 3d oxides.
Liu
Xiaohui
X
Institute of Inorganic Chemistry, RWTH Aachen University, 52056 Aachen, Germany.
Stork
Ludwig
L
Speldrich
Manfred
M
Lueken
Heiko
H
Dronskowski
Richard
R