title: Adsorption of Ni(II) on oxidized multi-walled carbon nanotubes: effect of contact time, pH, foreign ions and PAA.
abstract: The adsorption of Ni(II) on oxidized multi-walled carbon nanotubes (MWCNTs) as a function of contact time, pH and foreign ions in the absence and presence of polyacrylic acid (PAA) was studied using batch technique. The results indicated that adsorption of Ni(II) on oxidized MWCNTs increased from zero to approximately 99% at pH 2-9, and then maintained the high level with increasing pH. Kinetic data showed that the adsorption process achieved equilibrium within 2h and experimental data were fitted well by the pseudo-second-order equation. A positive effect of PAA on Ni(II) adsorption was found at pH<8, whereas a negative effect was observed at pH>8. The effect of addition sequences of PAA/Ni(II) on the adsorption of Ni(II) to PAA-MWCNT hybrids were also studied. The results indicated that the adsorption of Ni(II) was influenced by addition sequences obviously. The adsorption of Ni(II) on oxidized MWCNTs may be mainly attributed to surface complexation and ion exchange. Oxidized MWCNTs are suitable material in the solidification and pre-concentration of Ni(II) from aqueous solutions.
authors.affiliation: Key Lab of Novel Thin Film Solar Cells, Institute of Plasma Physics, Chinese Academy of Sciences, P.O. Box 1126, 230031 Hefei, PR China.
authors.forename: Shitong
authors.initials: S
authors.lastname: Yang
authors.forename: Jiaxing
authors.initials: J
authors.lastname: Li
authors.forename: Dadong
authors.initials: D
authors.lastname: Shao
authors.forename: Jun
authors.initials: J
authors.lastname: Hu
authors.forename: Xiangke
authors.initials: X
authors.lastname: Wang
mesh_terms: D000180:Acrylic Resins; D000327:Adsorption; D006863:Hydrogen-Ion Concentration; D007477:Ions; D037742:Nanotubes, Carbon / Q000737:chemistry*; D009532:Nickel / Q000302:isolation & purification*; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods
chemical_list: D000180:Acrylic Resins; D007477:Ions; D037742:Nanotubes, Carbon; D014874:Water Pollutants, Chemical; C006903:carbopol 940; D009532:Nickel