Diversity of catalysis by an imido-hydrido complex of molybdenum. Mechanism of carbonyl hydrosilylation and silane alcoholysis.
New Imido hydride complex 1 catalyzes a variety of silylation reactions that proceed via initial substrate activation but not silane addition.
Peterson
Erik
E
Chemistry Department, Brock University, 500 Glenridge Avenue, St. Catharines, ON, L2S 3A1, Canada.
Khalimon
Andrey Y
AY
Simionescu
Razvan
R
Kuzmina
Lyudmila G
LG
Howard
Judith A K
JA
Nikonov
Georgii I
GI