Charge and orbital correlations at and above the Verwey phase transition in magnetite.
The subtle interplay among electronic degrees of freedom (charge and orbital orderings), spin and lattice distortion that conspire at the Verwey transition in magnetite (Fe3O4) is still a matter of controversy. Here, we provide compelling evidence that these electronic orderings are manifested as a continuous phase transition at the temperature where a spin reorientation takes place at around 130 K, i.e., well above TV approximately 121 K. The Verwey transition seems to leave the orbital ordering unaffected whereas the charge ordering development appears to be quenched at this temperature and the temperature dependence below TV is controlled by the lattice distortions. Finally, we show that the orbital ordering does not reach true long range (disorder), and the correlation length along the c-direction is limited to 100 angstroms.
Lorenzo
J E
JE
Institut Néel CNRS-UJF, BP 166X,F-38052 Grenoble Cedex 09, France.
Mazzoli
C
C
Jaouen
N
N
Detlefs
C
C
Mannix
D
D
Grenier
S
S
Joly
Y
Y
Marin
C
C
D055598:Chemical Phenomena; D052203:Ferrosoferric Oxide / Q000737:chemistry*; D014961:X-Ray Diffraction
D052203:Ferrosoferric Oxide