title: An enantiopure N,N,S scorpionate ligand derived from (+)-camphor.
abstract: Reductive S-S bond cleavage of a disulfide precursor obtained from a pyridine-catalyzed Peterson-type reaction starting from camphorpyrazole , thionyl chloride and 2-methyl-2-(methyldithio)propionaldehyde yields 2,2'-bis(camphorpyrazol-1-yl)-2-methylpropane-2-thiol (HSiprbpm3cam, ); the first zinc complexes bearing this ligand exhibit kappa3 coordination of the ligand.
authors.affiliation: Inorganic Chemistry, Department of Chemistry and Pharmacy & Inter-disciplinary Center for Molecular Materials (ICMM), Universität Erlangen-Nürnberg, Egerlandstrasse 1, 91058, Erlangen, Germany.
authors.forename: Tom
authors.initials: T
authors.lastname: Godau
authors.forename: Florian
authors.initials: F
authors.lastname: Platzmann
authors.forename: Frank W
authors.initials: FW
authors.lastname: Heinemann
authors.forename: Nicolai
authors.initials: N
authors.lastname: Burzlaff
mesh_terms: D002164:Camphor / Q000737:chemistry*; D008024:Ligands; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D008024:Ligands; D009942:Organometallic Compounds; D002164:Camphor