Synthesis of new copper(I) complexes with tris(2-pyridyl) ligands. Applications to carbene and nitrene transfer reactions.
New copper(I) complexes with tris(2-pyridyl)methane (TPC), tris(2-pyridyl)methoxymethane (TPM) and tris(2-pyridyl)amine (TPN) ligands have been synthesized and characterized, including structural determinations by X-ray diffraction of some examples. Their activity as catalysts in carbene and nitrene transfer reactions was studied.
Pérez
Julio
J
Departamento de Química Orgánica e Inorgánica-IUQOEM, Facultad de Química, C/Julián Clavería, n degrees 8, Universidad de Oviedo-CSIC, 33006 Oviedo, Spain. japm@uniovi.es
Morales
Dolores
D
García-Escudero
Luis A
LA
Martínez-García
Héctor
H
Miguel
Daniel
D
Bernad
Pablo
P