A natural abundance 33S solid-state NMR study of layered transition metal disulfides at ultrahigh magnetic field.
Using a series of layered transition metal disulfides we demonstrate that the wide-line natural abundance solid-state NMR spectra of 33S in a less symmetric environment can readily be obtained at ultrahigh magnetic field of 21.1 T and that surprisingly these closely related materials display a wide range of 33S quadrupole coupling constant and chemical shift anisotropy values.
Sutrisno
Andre
A
Department of Chemistry, The University of Western Ontario, London, Ontario, Canada N6A 5B7.
Terskikh
Victor V
VV
Huang
Yining
Y
D016880:Anisotropy; D004220:Disulfides / Q000737:chemistry*; D004574:Electromagnetic Fields; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D013460:Sulfur Isotopes / Q000737:chemistry*; D028561:Transition Elements / Q000737:chemistry*
D004220:Disulfides; D013460:Sulfur Isotopes; D028561:Transition Elements