title: 1-phosphabarrelene complexes of palladium and their use in Suzuki-Miyaura coupling reactions.
abstract: A bulky 1-phosphabarrelene, , was obtained from the reaction of a phosphinine with benzyne; two palladium complexes of were successfully employed in the Suzuki-Miyaura coupling of several aryl chlorides with phenylboronic acid at a relatively low catalyst loading, and activated aryl chlorides were coupled at room temperature in the absence of strong bases.
authors.affiliation: Laboratoire Hétéroéléments et Coordination, Ecole Polytechnique, CNRS, 91128 Palaiseau, France.
authors.forename: Matthias
authors.initials: M
authors.lastname: Blug
authors.forename: Clément
authors.initials: C
authors.lastname: Guibert
authors.forename: Xavier-Frederic
authors.initials: XF
authors.lastname: Le Goff
authors.forename: Nicolas
authors.initials: N
authors.lastname: Mézailles
authors.forename: Pascal
authors.initials: P
authors.lastname: Le Floch