Direct role of structural dynamics in electron-lattice coupling of superconducting cuprates.
The mechanism of electron pairing in high-temperature superconductors is still the subject of intense debate. Here, we provide direct evidence of the role of structural dynamics, with selective atomic motions (buckling of copper-oxygen planes), in the anisotropic electron-lattice coupling. The transient structures were determined using time-resolved electron diffraction, following carrier excitation with polarized femtosecond heating pulses, and examined for different dopings and temperatures. The deformation amplitude reaches 0.5% of the c axis value of 30 A when the light polarization is in the direction of the copper-oxygen bond, but its decay slows down at 45 degrees. These findings suggest a selective dynamical lattice involvement with the anisotropic electron-phonon coupling being on a time scale (1-3.5 ps depending on direction) of the same order of magnitude as that of the spin exchange of electron pairing in the high-temperature superconducting phase.
Carbone
Fabrizio
F
Physical Biology Center for Ultrafast Science and Technology, Arthur Amos Noyes Laboratory of Chemical Physics, California Institute of Technology, Pasadena, CA 91125, USA.
Yang
Ding-Shyue
DS
Giannini
Enrico
E
Zewail
Ahmed H
AH