Molecular encapsulation of a discrete (H2O)32 cluster with S6 symmetry in an organic crystalline supermolecule.
A discrete S6-symmetrical (H2O)32 cluster was encapsulated in the cavity of an organic co-crystalline supermolecule constructed by the co-crystallization of guanidinium and benzenetribenzoate ions through hydrogen bonds, pi-pi and cation-pi interactions.
Xu
Wen-Zhi
WZ
Beijing National Laboratory for Molecular Sciences, Research Center for Chemical Biology, Institute of Chemistry, Chinese Academy of Sciences, 100190, Beijing, China.
Sun
Junliang
J
Huang
Zhi-Tang
ZT
Zheng
Qi-Yu
QY
D001555:Benzene Derivatives / Q000737:chemistry*; D001565:Benzoates / Q000737:chemistry*; D002412:Cations; D003460:Crystallization; D019791:Guanidine / Q000737:chemistry*; D006860:Hydrogen Bonding; D015394:Molecular Structure; D014867:Water / Q000737:chemistry*
D001555:Benzene Derivatives; D001565:Benzoates; D002412:Cations; D014867:Water; D019791:Guanidine