Iron-catalyzed 1,4-addition of alpha-olefins to dienes.
A new intermolecular, stereo- and regioselective iron-catalyzed 1,4-addition of alpha-olefins to 1,3-dienes using as low as 1 mol % of an iminopyridine-ferrous chloride complex was developed. Importantly, both double bonds of the linear 1,4-diene addition products are obtained with absolute stereocontrol.
Moreau
Benoît
B
Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, USA.
Wu
Jessica Y
JY
Ritter
Tobias
T
D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D007501:Iron / Q000737:chemistry*; D013237:Stereoisomerism; D013379:Substrate Specificity
D000475:Alkenes; D007501:Iron