Construction of a three-dimensional polynuclear zinc compound based on unique metallophthalocyanine-like subunits.
A polynuclear zinc compound, [Zn(7)(BTA)(7)(OABDC)(mu(3)-OH)(2)(mu(2)-OH)(2).H(2)O] (1), has been prepared by using benzotriazole (HBTA) and 5-oxyacetatoisophthalic acid (H(3)OABDC) as ligands under hydrothermal conditions. For compound 1, an unprecedented metallophthalocyanine-like "Zn(2)(mu(3)-OH)(2) subset [Zn(4)BTA(4)]" subunit is constructed from eta(3)-BTA ligands and Zn atoms and further linked via mu(2)-OH, outer four-connected Zn atoms, and 5-oxyacetateisophthalic acid to form a novel three-dimensional framework.
Shao
Kui-Zhan
KZ
Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun 130024, People's Republic of China.
Zhao
Ya-Hui
YH
Wang
Xin-Long
XL
Lan
Ya-Qian
YQ
Wang
De-Jun
DJ
Su
Zhong-Min
ZM
Wang
Rong-Shun
RS