title: Mesoscopic donor-acceptor multilayer by ultrahigh-vacuum codeposition of Zn-tetraphenyl-porphyrin and C70.
abstract: The peculiar electrochemical and photophysical properties of porphyrin and fullerene molecules make them promising candidates for the construction of two- and three-dimensional organic-based materials. An important question is how pristine fullerene and porphyrin will organize when deposited on surfaces via in vacuum molecular beam evaporation. Here we show that codeposition of C(70) and Zn-tetraphenyl-porphyrin (ZnTPP) induces the self-assembly of electron-rich flat aromatic molecules at the curved surface of C(70), thus enhancing the chromophore interaction and forming a supramolecular multilayer donor-acceptor structure. While the ground-state electronic spectra almost reflect a simple summation of ZnTPP and C(70) components, the excited-state electrons at the porphyrin macrocycle can rapidly delocalize to the fullerene. The excited charge transfer time scale is faster than 1-2 fs, as shown by resonant photoemission for the core-excited charges.
authors.affiliation: Sincrotrone Trieste S.C.p.A., s.s. 14 km 163.5 in Area Science Park, 34012 Trieste, Italy.
authors.forename: Paolo
authors.initials: P
authors.lastname: Vilmercati
authors.forename: Carla
authors.initials: C
authors.lastname: Castellarin-Cudia
authors.forename: Ralph
authors.initials: R
authors.lastname: Gebauer
authors.forename: Prasenjit
authors.initials: P
authors.lastname: Ghosh
authors.forename: Silvano
authors.initials: S
authors.lastname: Lizzit
authors.forename: Luca
authors.initials: L
authors.lastname: Petaccia
authors.forename: Cinzia
authors.initials: C
authors.lastname: Cepek
authors.forename: Rosanna
authors.initials: R
authors.lastname: Larciprete
authors.forename: Alberto
authors.initials: A
authors.lastname: Verdini
authors.forename: Luca
authors.initials: L
authors.lastname: Floreano
authors.forename: Alberto
authors.initials: A
authors.lastname: Morgante
authors.forename: Andrea
authors.initials: A
authors.lastname: Goldoni