title: FeNCN and Fe(NCNH)2: synthesis, structure, and magnetic properties of a nitrogen-based pseudo-oxide and -hydroxide of divalent iron.
abstract: Iron man challenge: Iron carbodiimide, FeNCN, and its precursor iron (bis)monohydrocyanamide, Fe(NCNH)(2), have been synthesized and physically characterized. Both FeNCN and Fe(NCNH)(2) exhibit nitrogen-mediated antiferromagnetic superexchange interactions with reduced magnetic moments very similar, but not identical, to the correlated 3d oxides.
authors.affiliation: Institute of Inorganic Chemistry, RWTH Aachen University, 52056 Aachen, Germany.
authors.forename: Xiaohui
authors.initials: X
authors.lastname: Liu
authors.forename: Ludwig
authors.initials: L
authors.lastname: Stork
authors.forename: Manfred
authors.initials: M
authors.lastname: Speldrich
authors.forename: Heiko
authors.initials: H
authors.lastname: Lueken
authors.forename: Richard
authors.initials: R
authors.lastname: Dronskowski