title: Graft copolymerization onto cellulose-based filter paper and its further development as silver nanoparticles loaded antibacterial food-packaging material.
abstract: The present work describes ceric ammonium nitrate (CAN) initiated graft copolymerization of acrylamide onto cellulose-based filter paper followed by entrapment of silver nanoparticles. The copolymerization was carried out in aqueous solution, containing 2M acrylamide monomer and 16mM N,N'-methylene bisacrylamide (MB) crosslinker. The optimum initiation time and grafting reaction temperature were found to be 15min and 30 degrees C, respectively. The silver nanoparticles were loaded into grafted filter paper by equilibration in silver nitrate solution followed by citrate reduction. The formation of silver nanoparticles has been confirmed by TEM and SAED analysis. The novel nano silver loaded filter paper has been investigated for its antimicrobial properties against E.coli. This newly developed material shows strong antibacterial property and thus offers its candidature for possible use as antibacterial food-packaging material.
authors.affiliation: Department of Chemistry, Government Model Science College, Jabalpur, India. rasika_81@rediffmail.com
authors.forename: Rasika
authors.initials: R
authors.lastname: Tankhiwale
authors.forename: S K
authors.initials: SK
authors.lastname: Bajpai
mesh_terms: D000178:Acrylamides / Q000737:chemistry; D000900:Anti-Bacterial Agents / Q000138:chemical synthesis* / Q000494:pharmacology; D002482:Cellulose / Q000737:chemistry*; D002563:Cerium / Q000737:chemistry; D004926:Escherichia coli / Q000187:drug effects; D018857:Food Packaging / Q000379:methods*; D053768:Metal Nanoparticles; D046529:Microscopy, Electron, Transmission; D010209:Paper; D012834:Silver
chemical_list: D000178:Acrylamides; D000900:Anti-Bacterial Agents; D002563:Cerium; D012834:Silver; D002482:Cellulose; C021221:N,N'-methylenebisacrylamide; C004653:ceric ammonium nitrate