title: A unique chair-shaped hexanuclear Cu(I) metallamacrocyclic C2H4 adduct encapsulating a BF4- anion.
abstract: Three novel Cu(I)-C2H4 adducts bearing 4-(2-pyridyl)pyrimidine were self-assembled, and the roles of anion and solvent were proved in the formation process.
authors.affiliation: Research Institute for Science and Technology, Kinki University, Kowakae, Higashi-Osaka, Osaka, Japan. maekawa@rist.kindai.ac.jp
authors.forename: Masahiko
authors.initials: M
authors.lastname: Maekawa
authors.forename: Atsuhiro
authors.initials: A
authors.lastname: Nabei
authors.forename: Toshi
authors.initials: T
authors.lastname: Tominaga
authors.forename: Kunihisa
authors.initials: K
authors.lastname: Sugimoto
authors.forename: Toshie
authors.initials: T
authors.lastname: Minematsu
authors.forename: Takashi
authors.initials: T
authors.lastname: Okubo
authors.forename: Takayoshi
authors.initials: T
authors.lastname: Kuroda-Sowa
authors.forename: Megumu
authors.initials: M
authors.lastname: Munakata
authors.forename: Susumu
authors.initials: S
authors.lastname: Kitagawa
mesh_terms: D000838:Anions; D001880:Boranes / Q000737:chemistry*; D001895:Boron / Q000737:chemistry*; D002621:Chemistry / Q000379:methods; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray / Q000379:methods; D005030:Ethylenes / Q000737:chemistry; D005459:Fluorides / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008670:Metals / Q000737:chemistry; D008956:Models, Chemical; D008968:Molecular Conformation; D015394:Molecular Structure; D011108:Polymers / Q000737:chemistry; D012997:Solvents / Q000737:chemistry; D013818:Thermogravimetry
chemical_list: D000838:Anions; D001880:Boranes; D005030:Ethylenes; D008670:Metals; D011108:Polymers; D012997:Solvents; D003300:Copper; C021274:boron trifluoride; C036216:ethylene; D001895:Boron; D005459:Fluorides