P,N-Containing cyclophanes with large helical hydrophobic cavities: prospective precursors for the design of a molecular reactor.
The highly effective self-assembly process between 2,4,6-tris(isopropyl)phenylphosphine or mesitylphosphine, formaldehyde and 1,4-bis(alpha-(4'-aminophenyl)isopropyl)benzene results in the formation of a novel type of heterocyclophane which is able to encapsulate organic molecules as well as being a potential ligand for transition metals inside the intramolecular cavity. Compounds of this type can be regarded as potential precursors for a new kind of molecular reactors.
Karasik
A A
AA
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan Scientific Center, Kazan, Russian Federation.
Kulikov
D V
DV
Balueva
A S
AS
Ignat'eva
S N
SN
Kataeva
O N
ON
Lönnecke
P
P
Kozlov
A V
AV
Latypov
S K
SK
Hey-Hawkins
E
E
Sinyashin
O G
OG