title: A Fenton-like degradation mechanism for 1,4-dioxane using zero-valent iron (Fe0) and UV light.
abstract: In this study, the degradation mechanism of 1,4-dioxane using zero-valent iron (Fe0) in the presence of UV light was investigated kinetically. The degradation of 1,4-dioxane in Fe0-only, photolysis, and combined Fe0 and UV reactions followed the kinetics of a pseudo-first-order model. The degradation rate constant (19 x 10(-4)min(-1)) in the combined reaction with UV-C (4.2 mW cm(-2)) and Fe0 (5 mg L(-1)) was significantly enhanced compared to Fe0-only (4.8 x 10(-4) min(-1)) and photolytic reactions (2.25 x 10(-4)min(-1)), respectively. The removal efficiency of 1,4-dioxane in combined reaction with Fe0 and UV within 4 h was enhanced by increasing UV intensity at UV-C region (34% at 4.2 mW cm(-2) and 89% at 16.9 mW cm(-2)) comparing with the removal in the combined reaction with Fe0 and UV-A (29% at 2.1 mW cm(-2), and 33% at 12.6 mW cm(-2)). It indicates that 1,4-dioxane was degraded mostly by OH radicals in the combined reaction. The degradation patterns in both Fe(0)-only and combined reactions were well fitted to the Langmuir-Hinshelwood model, implying that adsorption as well as the chemical reaction occurred. The transformation of Fe0 to Fe2+ and Fe3+ was observed in the Fe0-only and combined reactions, and the transformation rate of Fe0 was improved by UV irradiation. Furthermore, the reduction of Fe3+ was identified in the combined reaction, and the reduction rate was enhanced by an increase of UV energy. Our study demonstrated that the enhancement of 1,4-dioxane removal rate occurred via an increased supply of OH radicals from the Fenton-like reaction induced by the photolysis of Fe0 and H2O, and with producing less sludge.
authors.affiliation: Department of Environmental Health, School of Public Health, Seoul National University, 28 YeonGeon-Dong, Jongro-Gu,, Seoul 110-799, Republic of Korea.
authors.forename: Hyun-Seok
authors.initials: HS
authors.lastname: Son
authors.forename: Jong-Kwon
authors.initials: JK
authors.lastname: Im
authors.forename: Kyung-Duk
authors.initials: KD
authors.lastname: Zoh
mesh_terms: D004146:Dioxanes / Q000737:chemistry* / Q000528:radiation effects*; D006861:Hydrogen Peroxide / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D008956:Models, Chemical; D010782:Photolysis / Q000528:radiation effects; D014466:Ultraviolet Rays
chemical_list: D004146:Dioxanes; C045076:Fenton's reagent; D006861:Hydrogen Peroxide; D007501:Iron; C025223:1,4-dioxane