title: P,N-Containing cyclophanes with large helical hydrophobic cavities: prospective precursors for the design of a molecular reactor.
abstract: The highly effective self-assembly process between 2,4,6-tris(isopropyl)phenylphosphine or mesitylphosphine, formaldehyde and 1,4-bis(alpha-(4'-aminophenyl)isopropyl)benzene results in the formation of a novel type of heterocyclophane which is able to encapsulate organic molecules as well as being a potential ligand for transition metals inside the intramolecular cavity. Compounds of this type can be regarded as potential precursors for a new kind of molecular reactors.
authors.affiliation: A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan Scientific Center, Kazan, Russian Federation.
authors.forename: A A
authors.initials: AA
authors.lastname: Karasik
authors.forename: D V
authors.initials: DV
authors.lastname: Kulikov
authors.forename: A S
authors.initials: AS
authors.lastname: Balueva
authors.forename: S N
authors.initials: SN
authors.lastname: Ignat'eva
authors.forename: O N
authors.initials: ON
authors.lastname: Kataeva
authors.forename: P
authors.initials: P
authors.lastname: Lönnecke
authors.forename: A V
authors.initials: AV
authors.lastname: Kozlov
authors.forename: S K
authors.initials: SK
authors.lastname: Latypov
authors.forename: E
authors.initials: E
authors.lastname: Hey-Hawkins
authors.forename: O G
authors.initials: OG
authors.lastname: Sinyashin