Switched role of fullerene in the Diels-Alder reaction: facile addition of dienophiles to the conjugated fullerene diene moiety.
The isolated cyclopentadiene moiety in a fullerene multi-adduct derivative reacts readily with dienophiles to form [4 + 2] cycloaddition products.
Yao
Jiayao
J
Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, China.
Xiao
Zuo
Z
Zhang
Jianxin
J
Yang
Xiaobing
X
Gan
Liangbing
L
Zhang
Wen-Xiong
WX
D037741:Fullerenes / Q000737:chemistry*
D037741:Fullerenes