title: Geological emission of methane from the Yakela condensed oil/gas field in Talimu Basin, Xinjiang, China.
abstract: A static flux chamber method was applied to study natural emissions of methane into the atmosphere in the Yakela condensed oil/gas field in Talimu Basin, Xinjiang, China. Using an online method, which couples a gas chromatography/high-temperature conversion/isotope ratio mass spectrometry (GC/C/MS) together, the 13C/12C ratios of methane in the flux chambers were measured. The results demonstrated that methane gases were liable to migrate from deep oil/gas reservoir to the surface through microseepage and pervasion, and that a part of the migrated methane that remained unoxidized could emit into the atmosphere. Methane emission rates varied less in the oil/gas field because the whole region was homogeneous in geology and geography, with a standard deviation of less than 0.02 mg/(m2 x h). These were the differences in methane emission flux in the day and at night in the oil/gas field. The maximum methane emission flux reached 0.15 mg/(m2 x h) at 5:00-6:00 early in the morning, and then decreased gradually. The minimum was shown 0.10 mg/(m2 x h) at 17:00-18:00 in the afternoon, and then increased gradually. The daily methane released flux of the study area was 2.89 mg/(m2 x d), with a standard deviation of 0.43 mg/(m2 x d), using the average methane flux of every hour in a day for all chambers. delta13C of methane increased with the increase of methane concentration in the flux chambers, further indicating that the pyrogenetic origin of methane was come from deep oil/gas reservoirs.
authors.affiliation: Department of Environmental Engineering and Science, Hangzhou Dianzi University, Hangzhou 310018, China. Tang_jhjh@tom.com
authors.forename: Junhong
authors.initials: J
authors.lastname: Tang
authors.forename: Zhengyu
authors.initials: Z
authors.lastname: Bao
authors.forename: Wu
authors.initials: W
authors.lastname: Xiang
authors.forename: Qinghong
authors.initials: Q
authors.lastname: Gou
mesh_terms: D000393:Air Pollutants / Q000737:chemistry*; D002247:Carbon Isotopes; D002681:China; D002940:Circadian Rhythm; D005844:Geology; D008697:Methane / Q000737:chemistry*; D010578:Petroleum / Q000032:analysis*
chemical_list: D000393:Air Pollutants; D002247:Carbon Isotopes; D010578:Petroleum; D008697:Methane