title: Deacidification of high free fatty acid-containing rice bran oil by non-conventional reesterification process.
abstract: Rice bran (Oryza sativa) oil is known for containing higher amount of free fatty acid (FFA) generated by hydrolytic enzyme. This FFA causes heavy neutral oil losses due to saponification and emulsification since it produces large amount of soap in the conventional alkali refining process. In the present study the FFA of degummed rice bran oil (RBO) was significantly reduced by reesterifying it with glycerol. The reesterification process was carried out by varying the temperature and amount of excess glycerol using 0.2% catalyst (SnCl(2)). The maximum efficiency of the process could be attained at 200 degrees C using 70% excess glycerol and the maximum reduction in acid value (from 24.3 to 3.0) of RBO was observed within 4 h. The reesterified RBO was used to prepare stand oil and varnish and their performance characteristics were compared with those of the products obtained from dehydrated castor oil (DCO).
authors.affiliation: Department of Industrial Chemistry (Oils, Fats & Waxes), ISTAR, Vallabh Vidyanagar, India. sibban_singh@yahoo.co.in
authors.forename: Sibban
authors.initials: S
authors.lastname: Singh
authors.forename: R P
authors.initials: RP
authors.lastname: Singh
mesh_terms: D001709:Biotechnology / Q000379:methods; D002384:Catalysis; D002621:Chemistry / Q000379:methods; D004951:Esterification; D005227:Fatty Acids / Q000378:metabolism*; D005504:Food Analysis; D005990:Glycerol / Q000737:chemistry; D006868:Hydrolysis; D012275:Oryza / Q000378:metabolism; D010938:Plant Oils / Q000378:metabolism*; D000073879:Rice Bran Oil; D012997:Solvents / Q000737:chemistry; D013696:Temperature; D017971:Tin Compounds / Q000737:chemistry
chemical_list: D005227:Fatty Acids; D010938:Plant Oils; D012997:Solvents; D017971:Tin Compounds; C023599:stannous chloride; D000073879:Rice Bran Oil; D005990:Glycerol