Scope of the Suzuki-Miyaura cross-coupling reaction of potassium trifluoroboratoketohomoenolates.
Potassium trifluoroboratoketohomoenolates were prepared in good yields from either the corresponding alpha,beta-unsaturated compounds or methyl ketones. These organoboron reagents were effectively cross-coupled with various aryl and heteroaryl chlorides.
Molander
Gary A
GA
Roy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323, USA. gmolandr@sas.upenn.edu
Jean-Gérard
Ludivine
L
D001555:Benzene Derivatives / Q000138:chemical synthesis*; D001896:Boron Compounds / Q000737:chemistry*; D002722:Chlorobenzenes / Q000737:chemistry*; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D017680:Potassium Compounds / Q000737:chemistry
D001555:Benzene Derivatives; D001896:Boron Compounds; D002722:Chlorobenzenes; D007659:Ketones; D017680:Potassium Compounds