The binary silver nitrogen anion [Ag(N3)2]-.
The reaction of silver azide with triphenylsulfonium or tetraphenylphosphonium azide results in the formation of the binary silver-nitrogen compound, the novel diazido-argentate(I) anion [Ag(N(3))(2)](-). The crystal structures of both salts of this anion show different cation dependent azide coordination spheres around silver.
Klapötke
Thomas M
TM
Department of Chemistry and Biochemistry, Ludwig-Maximilian University of Munich, Butenandtstrasse 5-13(D), D-81377 Munich, Germany.
Krumm
Burkhard
B
Scherr
Matthias
M