A unique chair-shaped hexanuclear Cu(I) metallamacrocyclic C2H4 adduct encapsulating a BF4- anion.
Three novel Cu(I)-C2H4 adducts bearing 4-(2-pyridyl)pyrimidine were self-assembled, and the roles of anion and solvent were proved in the formation process.
Maekawa
Masahiko
M
Research Institute for Science and Technology, Kinki University, Kowakae, Higashi-Osaka, Osaka, Japan. maekawa@rist.kindai.ac.jp
Nabei
Atsuhiro
A
Tominaga
Toshi
T
Sugimoto
Kunihisa
K
Minematsu
Toshie
T
Okubo
Takashi
T
Kuroda-Sowa
Takayoshi
T
Munakata
Megumu
M
Kitagawa
Susumu
S
D000838:Anions; D001880:Boranes / Q000737:chemistry*; D001895:Boron / Q000737:chemistry*; D002621:Chemistry / Q000379:methods; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray / Q000379:methods; D005030:Ethylenes / Q000737:chemistry; D005459:Fluorides / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008670:Metals / Q000737:chemistry; D008956:Models, Chemical; D008968:Molecular Conformation; D015394:Molecular Structure; D011108:Polymers / Q000737:chemistry; D012997:Solvents / Q000737:chemistry; D013818:Thermogravimetry
D000838:Anions; D001880:Boranes; D005030:Ethylenes; D008670:Metals; D011108:Polymers; D012997:Solvents; D003300:Copper; C021274:boron trifluoride; C036216:ethylene; D001895:Boron; D005459:Fluorides