title: Fluorous Lewis acids and phase transfer catalysts.
abstract: The new phase-separation and immobilization technique known as fluorous biphase system (FBS) has become an active topic among researchers in both industry and academia. A series of fluorous biphasic reactions catalyzed by Lewis acid-type metal perfluorooctanesulfonates and metal bis(perfluorooctanesulfonyl)amides are reviewed in this paper. The recent development of fluorous phase transfer catalyst (PTC) is also discussed.
authors.affiliation: Chemical Engineering College, Nanjing University of Science & Technology, Nanjing, 210094, China. c.cai@mail.njust.edu.cn
authors.forename: Chun
authors.initials: C
authors.lastname: Cai
authors.forename: Wen-Bin
authors.initials: WB
authors.lastname: Yi
authors.forename: Wei
authors.initials: W
authors.lastname: Zhang
authors.forename: Ming-Gui
authors.initials: MG
authors.lastname: Shen
authors.forename: Mei
authors.initials: M
authors.lastname: Hong
authors.forename: Li-Yan
authors.initials: LY
authors.lastname: Zeng
mesh_terms: D017738:Alkanesulfonic Acids / Q000737:chemistry*; D000577:Amides / Q000737:chemistry*; D002384:Catalysis; D005461:Fluorine / Q000737:chemistry*; D005466:Fluorocarbons / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry; D044367:Phase Transition
chemical_list: D017738:Alkanesulfonic Acids; D000577:Amides; D005466:Fluorocarbons; D009942:Organometallic Compounds; D005461:Fluorine; C076994:perfluorooctane sulfonic acid