title: Hydrogen-bonded ferroelectrics based on metal-organic coordination.
abstract: Metal-organic coordination (MOC)-type ferroelectrics, cobalt(II) (R)-2-methylpiperazine (MPPA) trichloride [Co(II)Cl(3)(H-MPPA)], was constructed through hydrogen bonds. It is a good ferroelectric candidate with a P(s) = 6.8 microC.cm(-2) as high as almost twice that of triglycine sulfate (P(s) = 3.5 microC.cm(-2)) and significantly larger than that of KH(2)PO(4) at the low-temperature ferroelectric phase Fdd2. [Co(II)Cl(3)(H-MPPA)] is the first example of ferroelectric MOC that can really reach the spontaneous polarization status and opens up a new avenue to explore novel MOC-based ferroelectrics.
authors.affiliation: Ordered Matter Science Research Center, Southeast University, Nanjing 211189, People's Republic of China.
authors.forename: Heng-Yun
authors.initials: HY
authors.lastname: Ye
authors.forename: Da-Wei
authors.initials: DW
authors.lastname: Fu
authors.forename: Yi
authors.initials: Y
authors.lastname: Zhang
authors.forename: Wen
authors.initials: W
authors.lastname: Zhang
authors.forename: Ren-Gen
authors.initials: RG
authors.lastname: Xiong
authors.forename: Songping D
authors.initials: SD
authors.lastname: Huang