title: Synthesis, optical, and electronic properties of soluble poly-p-phenylene oligomers as models for molecular wires.
abstract: A homologous series of soluble poly-p-phenylenes containing up to eight phenylene moieties (PP(2)-PP(8)) with branched iso-alkyl (or bis-n-alkylmethyl) groups has been synthesized and the structure-property relationship with regards to various optical and electronic properties established. All electronic and optoelectronic properties of poly-p-phenylenes followed a 1/n relationship (where n is number of phenylene moieties) with the increasing number of phenylene moieties. The low-energy electronic transition of the PP(2)-PP(7) cation radicals, generated either by laser-flash photolysis or by chemical oxidation, varied as well according to the inverse (1/n) relationship. The observed inverse relationship of all measured electronic and optoelectronic properties against the increasing number of phenylene units in various PP(n)'s, as well as X-ray crystallography of both neutral and a cation-radical salt of a representative tetra-p-phenylene oligomer allows us to demonstrate that the effective conjugation length in poly-p-phenylenes is, in part, controlled by the increasing number of interactions of ortho hydrogens which may prevent simultaneous planarization of the continuous arrays of a large number of phenylene moieties.
authors.affiliation: Marquette University, Department of Chemistry, P.O. Box 1881, Milwaukee, Wisconsin 53201-1881, USA.
authors.forename: Moloy
authors.initials: M
authors.lastname: Banerjee
authors.forename: Ruchi
authors.initials: R
authors.lastname: Shukla
authors.forename: Rajendra
authors.initials: R
authors.lastname: Rathore