Isolation and absolute stereochemistry of optically active sydonic acid from Glonium sp. (Hysteriales, Ascomycota).
Optically active sydonic acid (1) was isolated for the first time from a culture broth of Glonium sp. The absolute stereochemistry was established to be (S) by comparing the circular dichroism (CD) spectrum with that of (+)-curcutetraol after conversion into (+)-sydonol (2).
Kudo
Shinji
S
Faculty of Agriculture and Life Science, Hirosaki University.
Murakami
Takanori
T
Miyanishi
Junsuke
J
Tanaka
Kazuaki
K
Takada
Noboru
N
Hashimoto
Masaru
M
D000143:Acids / Q000737:chemistry; D001203:Ascomycota / Q000737:chemistry*; D002942:Circular Dichroism; D015394:Molecular Structure; D009904:Optical Rotation; D012717:Sesquiterpenes / Q000737:chemistry*; D013237:Stereoisomerism
D000143:Acids; D012717:Sesquiterpenes