Synthesis and analysis of resorcinol-acetone copolymer.
Synthesis and characterization of resorcinol-acetone copolymer is described. The polymer was prepared by trifluoroacetic acid-catalyzed polymerization of resorcinol with acetone. According to the (1)H-NMR, (13)C-NMR, and MALDI-TOF Mass spectra data, the obtained polymer had three types of repeating units: isopropylidene bridged-resorcinol, chromane ring, and spiro-shaped double chromane ring, indicating that polymerization proceeded via simultaneous addition-condensation and cyclization of resorcinol with acetone. The obtained polymer can be useful not only for the development of plastic materials such as thermosets, adhesives, and coatings but also for the synthesis of biomaterials such as antimicrobial agents, pesticides, and medicines.
Kobayashi
Ataru
A
Department of Organic & Polymeric Materials, Graduate School of Science & Engineering, Tokyo Institute of Technology, SORST, Japan.
Konishi
Gen-ichi
G
D000096:Acetone / Q000737:chemistry*; D002152:Calorimetry, Differential Scanning; D015394:Molecular Structure; D008970:Molecular Weight; D019906:Nuclear Magnetic Resonance, Biomolecular; D011108:Polymers / Q000138:chemical synthesis / Q000737:chemistry; D012118:Resorcinols / Q000737:chemistry*; D019032:Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization; D017550:Spectroscopy, Fourier Transform Infrared; D013818:Thermogravimetry; D014269:Trifluoroacetic Acid / Q000737:chemistry; D014297:Trimethylsilyl Compounds / Q000737:chemistry
D011108:Polymers; D012118:Resorcinols; D014297:Trimethylsilyl Compounds; D000096:Acetone; D014269:Trifluoroacetic Acid; C031389:resorcinol