title: Tunable coordination of a tropos phosphite for fine-tuning of the Rh catalyzed asymmetric addition of phenylboronic acid to cyclohexenone.
abstract: Using the deoxycholic acid derived tropos biphenylphosphite as a Rh(i) chiral ligand different complexes are obtained, depending on the Rh : L molar ratio, that give rise to the formation of different chiral products in the asymmetric addition of phenylboronic acid to cyclohexenone.
authors.affiliation: Dipartimento di Chimica e Chimica Industriale Università di Pisa, Via Risorgimento 35, 56126, Pisa, Italy. iuliano@dcci.unipi.it
authors.forename: Anna
authors.initials: A
authors.lastname: Iuliano
authors.forename: Sarah
authors.initials: S
authors.lastname: Facchetti
authors.forename: Tiziana
authors.initials: T
authors.lastname: Funaioli