Fluorous Lewis acids and phase transfer catalysts.
The new phase-separation and immobilization technique known as fluorous biphase system (FBS) has become an active topic among researchers in both industry and academia. A series of fluorous biphasic reactions catalyzed by Lewis acid-type metal perfluorooctanesulfonates and metal bis(perfluorooctanesulfonyl)amides are reviewed in this paper. The recent development of fluorous phase transfer catalyst (PTC) is also discussed.
Cai
Chun
C
Chemical Engineering College, Nanjing University of Science & Technology, Nanjing, 210094, China. c.cai@mail.njust.edu.cn
Yi
Wen-Bin
WB
Zhang
Wei
W
Shen
Ming-Gui
MG
Hong
Mei
M
Zeng
Li-Yan
LY
D017738:Alkanesulfonic Acids / Q000737:chemistry*; D000577:Amides / Q000737:chemistry*; D002384:Catalysis; D005461:Fluorine / Q000737:chemistry*; D005466:Fluorocarbons / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry; D044367:Phase Transition
D017738:Alkanesulfonic Acids; D000577:Amides; D005466:Fluorocarbons; D009942:Organometallic Compounds; D005461:Fluorine; C076994:perfluorooctane sulfonic acid