title: Metal extraction from water and organic solvents into fluorous solvents by fluorinated beta-diketone and its application to the colorimetric analysis of metal ions.
abstract: A metal extraction system using fluorous solvents has been developed. Perfluorinated beta-diketone, 1,1,1,5,5,6,6,6-octafluoro-2,4-hexanedione (C(6)F(8)betaDK) dissolves in the fluorous solvent FC-72 and can extract transition metal ions from water into FC-72. The extraction efficiency in the FC-72 system is comparable to that of chloroform. By using the immiscibility of FC-72 with conventional organic solvents, metal extraction was also achieved from acetonitrile and dioxane. Metal ions extracted into FC-72 can be readily stripped using 1 M nitric acid. We succeeded in a colorimetric assay of metal ion concentration in water and in organic solvents by contacting each solvent with FC-72 containing C(6)F(8)betaDK. Iron ions with different concentrations (0 - 0.1 mM) in water or acetonitrile are completely extracted into FC-72 to form a Fe(3+)-C(6)F(8)betaDK complex, which can be detected by spectrophotometry due to its absorption in the UV-vis region. We have demonstrated that fluorous solvents would be promising candidates for a novel separation and analytical medium for metal ions.
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, Kyushu University, Fukuoka 819-0395, Japan.
authors.forename: Kazunori
authors.initials: K
authors.lastname: Nakashima
authors.forename: Tatsuo
authors.initials: T
authors.lastname: Maruyama
authors.forename: Fukiko
authors.initials: F
authors.lastname: Kubota
authors.forename: Masahiro
authors.initials: M
authors.lastname: Goto