title: Exploration of the "traceless" reductive ligation of S-nitrosothiols.
abstract: The first "traceless" reductive ligation of S-nitrosothiols using phosphine ester/thioester conjugates is reported. Experiments also show that stable thioimidate compounds could be formed in the reaction between S-nitrosothiols and some phosphine-thioester substrates.
authors.affiliation: Department of Chemistry, Washington State University, Pullman, Washington 99164, USA.
authors.forename: Jiming
authors.initials: J
authors.lastname: Zhang
authors.forename: Hua
authors.initials: H
authors.lastname: Wang
authors.forename: Ming
authors.initials: M
authors.lastname: Xian
mesh_terms: D007096:Imidoesters / Q000138:chemical synthesis / Q000737:chemistry; D010084:Oxidation-Reduction; D026403:S-Nitrosothiols / Q000737:chemistry*
chemical_list: D007096:Imidoesters; D026403:S-Nitrosothiols