Green composite films prepared from cellulose, starch and lignin in room-temperature ionic liquid.
A series of novel biobased composite films derived from cellulose, starch and lignin were prepared from an ionic liquid (IL), 1-allyl-3-methylimidazolium chloride (AmimCl) by coagulating in a nonsolvent condition. The ionic liquid can be recycled with a high yield and purity after the green film was prepared. The uniform design method was applied to investigate mechanical properties of the biobased composite films. The effect of each component and their associated interactive effects were investigated. The experimental results showed that contents of cellulose, lignin and starch had a significant influence on the mechanical properties of composite films. The composite films showed relatively excellent mechanical properties in dry and wet states owing to the mutual property supplement of different components. The composite films were characterized via FT-IR, X-ray diffraction (XRD) and scanning electron microscope (SEM). Their thermal stability and gas permeability were also investigated, and the results showed that the composite films had good thermal stability and high gas barrier capacity and give a CO(2):O(2) permeability ratio close to 1.
Wu
Rong-Lan
RL
Center for Degradable and Flame-Retardant Polymeric Materials, College of Chemistry, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610064, China.
Wang
Xiu-Li
XL
Li
Fang
F
Li
Hui-Zhang
HZ
Wang
Yu-Zhong
YZ
D001704:Biopolymers / Q000737:chemistry*; D001709:Biotechnology / Q000379:methods; D002482:Cellulose / Q000737:chemistry*; D007093:Imidazoles / Q000737:chemistry; D052578:Ionic Liquids / Q000737:chemistry*; D008031:Lignin / Q000737:chemistry*; D010539:Permeability; D012997:Solvents / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared; D013213:Starch / Q000737:chemistry*; D013696:Temperature; D013718:Tensile Strength
D001704:Biopolymers; D007093:Imidazoles; D052578:Ionic Liquids; D012997:Solvents; D002482:Cellulose; D013213:Starch; D008031:Lignin