title: Runoff and leaching of metolachlor from Mississippi River alluvial soil during seasons of average and below-average rainfall.
abstract: The movement of the herbicide metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)acetamide] via runoff and leaching from 0.21 ha plots planted to corn on Mississippi River alluvial soil (Commerce silt loam) was measured for a 6-year period, 1995-2000. The first three years received normal rainfall (30 year average); the second three years experienced reduced rainfall. The 4-month periods prior to application plus the following 4 months after application were characterized by 1039 +/- 148 mm of rainfall for 1995-1997 and by 674 +/- 108 mm for 1998-2000. During the normal rainfall years 216 +/- 150 mm of runoff occurred during the study seasons (4 months following herbicide application), accompanied by 76.9 +/- 38.9 mm of leachate. For the low-rainfall years these amounts were 16.2 +/- 18.2 mm of runoff (92% less than the normal years) and 45.1 +/- 25.5 mm of leachate (41% less than the normal seasons). Runoff of metolachlor during the normal-rainfall seasons was 4.5-6.1% of application, whereas leaching was 0.10-0.18%. For the below-normal periods, these losses were 0.07-0.37% of application in runoff and 0.22-0.27% in leachate. When averages over the three normal and the three less-than-normal seasons were taken, a 35% reduction in rainfall was characterized by a 97% reduction in runoff loss and a 71% increase in leachate loss of metolachlor on a percent of application basis. The data indicate an increase in preferential flow in the leaching movement of metolachlor from the surface soil layer during the reduced rainfall periods. Even with increased preferential flow through the soil during the below-average rainfall seasons, leachate loss (percent of application) of the herbicide remained below 0.3%. Compared to the average rainfall seasons of 1995-1997, the below-normal seasons of 1998-2000 were characterized by a 79% reduction in total runoff and leachate flow and by a 93% reduction in corresponding metolachlor movement via these routes. An added observation in the study was that neither runoff of rainfall nor runoff loss of metolachlor was influenced by the presence of subsurface drains, compared to the results from plots without such drains that were described in an earlier paper.
authors.affiliation: Soil and Water Research, Agricultural Research Service, U.S. Department of Agriculture, 4115 Gourrier Avenue, Baton Rouge, Louisiana 70808, USA.
authors.forename: Lloyd M
authors.initials: LM
authors.lastname: Southwick
authors.forename: Timothy W
authors.initials: TW
authors.lastname: Appelboom
authors.forename: James L
authors.initials: JL
authors.lastname: Fouss
mesh_terms: D000081:Acetamides / Q000008:administration & dosage / Q000032:analysis*; D006540:Herbicides / Q000032:analysis*; D011891:Rain; D045483:Rivers / Q000737:chemistry*; D012621:Seasons; D012987:Soil / Q000032:analysis*; D014874:Water Pollutants, Chemical / Q000032:analysis
chemical_list: D000081:Acetamides; D006540:Herbicides; D012987:Soil; D014874:Water Pollutants, Chemical; C051786:metolachlor