Preconcentration of nickel and cadmium by TiO2 nanotubes as solid-phase extraction adsorbents coupled with flame atomic absorption spectrometry.
TiO(2) nanotubes, a new nanomaterial, are often used in the photocatalysis. Due to its relatively large specific surface areas it should have a higher enrichment capacity. However, very few applications in the enrichment of pollutants were found. This paper described a new procedure to investigate the trapping power of TiO(2) nanotubes with cadmium and nickel in water samples as the model analytes and flame atomic absorption spectrometry for the analysis. The possible parameters influencing the enrichment were optimized. Under the optimal SPE conditions, the method detection limits and precisions (R.S.D., n=6) were 0.25 ngmL(-1) and 2.2% for cadmium, 1 ngmL(-1) and 2.6% for nickel, respectively. The established method has been successfully applied to analyze four realworld water samples, and satisfactory results were obtained. The spiked recoveries were in the range of 90.2-99.2% for them. All these indicated that TiO(2) nanotubes had great potential in environmental field.
Zhou
Qing-Xiang
QX
School of Chemistry and Environmental Sciences, Henan Normal University, Henan Key Laboratory for Environmental Pollution Control, Key Laboratory for Yellow River and Huaihe River Water Environment and Pollution Control, Xinxiang, China.
Zhao
Xin-Ning
XN
Xiao
Jun-Ping
JP
D002104:Cadmium / Q000032:analysis*; D004785:Environmental Pollutants / Q000032:analysis*; D043942:Nanotubes / Q000737:chemistry; D009532:Nickel / Q000032:analysis*; D052616:Solid Phase Extraction / Q000379:methods; D013054:Spectrophotometry, Atomic / Q000379:methods; D014025:Titanium
D004785:Environmental Pollutants; D002104:Cadmium; C009495:titanium dioxide; D009532:Nickel; D014025:Titanium