STM insight into hydrogen-bonded bicomponent 1D supramolecular polymers with controlled geometries at the liquid-solid interface.
Bicomponent supramolecular polymers, consisting of two alternating molecules bridged through six H-bonds, are observed by STM at the solid-liquid interface. Control of the geometry of the 1D architecture was obtained by using two different connecting molecules with different conformational rigidity, affording either linear (see picture, left) or zigzag (right) motifs.
Ciesielski
Artur
A
ISIS/UMR CNRS 7006, Université Louis Pasteur, 8 Allée Gaspard Monge, 67000 Strasbourg, France.
Schaeffer
Gaël
G
Petitjean
Anne
A
Lehn
Jean-Marie
JM
Samorì
Paolo
P