title: 2,2':6',2''-Terpyridine meets 2,6-bis(1H-1,2,3-triazol-4-yl)pyridine: tuning the electro-optical properties of ruthenium(II) complexes.
abstract: The synthesis of a series of heteroleptic ruthenium(ii)-complexes containing both, 2,2':6',2''-terpyridine and 2,6-bis(1H-1,2,3-triazol-4-yl)pyridine, is reported for the first time. The provided complexes feature photophysical and electrochemical properties in between those known for the respective homoleptic complexes. The flexibility with respect to lateral functional groups to be introduced into the complexes underlines the high potential for further functionalization steps.
authors.affiliation: Friedrich-Schiller-University Jena, Laboratory of Organic and Macromolecular Chemistry, Humboldtstr. 10, 07743 Jena, Germany.
authors.forename: Benjamin
authors.initials: B
authors.lastname: Schulze
authors.forename: Christian
authors.initials: C
authors.lastname: Friebe
authors.forename: Martin D
authors.initials: MD
authors.lastname: Hager
authors.forename: Andreas
authors.initials: A
authors.lastname: Winter
authors.forename: Richard
authors.initials: R
authors.lastname: Hoogenboom
authors.forename: Helmar
authors.initials: H
authors.lastname: Görls
authors.forename: Ulrich S
authors.initials: US
authors.lastname: Schubert
mesh_terms: D018360:Crystallography, X-Ray; D004563:Electrochemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010777:Photochemistry; D011725:Pyridines / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D014230:Triazoles / Q000737:chemistry*
chemical_list: C517923:(2,2'-6',2'')-terpyridine; D009942:Organometallic Compounds; D011725:Pyridines; D014230:Triazoles; D012428:Ruthenium