title: Novel measurements of refractive index, density and mid-infrared integrated band strengths for solid O(2), N(2)O and NO(2):N(2)O(4) mixtures.
abstract: We present novel measurements of the refractive index, density and integrated band strengths of mid-infrared features of solid N(2)O at 16K and of NO(2) and N(2)O(4) in two frozen NO(2):N(2)O(4) mixtures deposited at 16 and 60K. The refractive index and density measurements were performed also for frozen O(2) deposited at 16K. In this case, the integrated band strength values could not be determined since O(2) is a homonuclear molecule and therefore its fundamental mode is not infrared active. The solid samples were analysed by infrared spectroscopy in the 8000/800cm(-1) range. The sample thickness was measured by the interference curve obtained using a He-Ne laser operating at 543nm. The refractive index at this laser wavelength was obtained, by numerical methods, from the measured amplitude of the interference curve. The density values were obtained using the Lorentz-Lorenz relation. Integrated band strength values were then obtained by a linear fit of the integrated band intensities plotted versus column density values. The astrophysical relevance of these novel measurements is briefly discussed.
authors.affiliation: Department of Physics & Astronomy, Catania University, Via S. Sofia 64, I-95123 Catania, Italy. dfu@oact.inaf.it
authors.forename: D
authors.initials: D
authors.lastname: Fulvio
authors.forename: B
authors.initials: B
authors.lastname: Sivaraman
authors.forename: G A
authors.initials: GA
authors.lastname: Baratta
authors.forename: M E
authors.initials: ME
authors.lastname: Palumbo
authors.forename: N J
authors.initials: NJ
authors.lastname: Mason
mesh_terms: D019443:Cosmic Dust; D009589:Nitrogen Oxides / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D012031:Refractometry / Q000379:methods*; D013055:Spectrophotometry, Infrared / Q000379:methods*
chemical_list: D019443:Cosmic Dust; D009589:Nitrogen Oxides; D010100:Oxygen