2,2':6',2''-Terpyridine meets 2,6-bis(1H-1,2,3-triazol-4-yl)pyridine: tuning the electro-optical properties of ruthenium(II) complexes.
The synthesis of a series of heteroleptic ruthenium(ii)-complexes containing both, 2,2':6',2''-terpyridine and 2,6-bis(1H-1,2,3-triazol-4-yl)pyridine, is reported for the first time. The provided complexes feature photophysical and electrochemical properties in between those known for the respective homoleptic complexes. The flexibility with respect to lateral functional groups to be introduced into the complexes underlines the high potential for further functionalization steps.
Schulze
Benjamin
B
Friedrich-Schiller-University Jena, Laboratory of Organic and Macromolecular Chemistry, Humboldtstr. 10, 07743 Jena, Germany.
Friebe
Christian
C
Hager
Martin D
MD
Winter
Andreas
A
Hoogenboom
Richard
R
Görls
Helmar
H
Schubert
Ulrich S
US
D018360:Crystallography, X-Ray; D004563:Electrochemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010777:Photochemistry; D011725:Pyridines / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D014230:Triazoles / Q000737:chemistry*
C517923:(2,2'-6',2'')-terpyridine; D009942:Organometallic Compounds; D011725:Pyridines; D014230:Triazoles; D012428:Ruthenium