title: Adsorption effect on the degradation of 4,6-o-dinitrocresol and p-nitrophenol in a montmorillonite clay slurry by AFT.
abstract: The adsorption and degradation of 4,6-o-dinitrocresol (DNOC) and p-nitrophenol (PNP) in SWy-2 montmorillonite clay slurry were investigated. The pH and type of cation of the slurry were varied. Results showed that adsorption of DNOC and PNP increased at lower pH values, and when pH < pKa(4.4) of DNOC, DNOC was almost completely adsorbed on the clay under given experimental conditions. The specific cation also had a significant effect on adsorption, which was dramatically enhanced in the presence of K+ and NH4+, compared with the presence of Na+ or Ca2+. Anodic Fenton treatment (AFT) degradation of DNOC and PNP in the clay slurry was studied, and it was found that DNOC degradation rates were greatly affected by the initial pH and the types of electrolytes. Due to the higher adsorption, the degradation rate substantially decreased in the clay slurry system in the presence of K+ and low pH, with a large amount of DNOC residue remaining after 60 min treatment. AFT degradation of PNP was completed within 30 min treatment. Based on LC-MS data, a DNOC degradation pathway was proposed. Overall, the results showed the inhibition effect of adsorption on the degradation of nitroaromatic compounds in montmorillonite clay slurry by AFT, providing important implications for water and soil remediation.
authors.affiliation: Graduate Field of Environmental Toxicology, Cornell University, 209 MVR Hall, Ithaca, NY 14853, USA.
authors.forename: Peng
authors.initials: P
authors.lastname: Ye
authors.forename: Ann T
authors.initials: AT
authors.lastname: Lemley
mesh_terms: D000327:Adsorption; D000538:Aluminum Silicates / Q000737:chemistry* / Q000302:isolation & purification; D001546:Bentonite / Q000737:chemistry*; D002853:Chromatography, Liquid; D000077215:Clay; D004138:Dinitrocresols / Q000737:chemistry*; D004566:Electrodes; D004573:Electrolytes / Q000737:chemistry; D006861:Hydrogen Peroxide / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007501:Iron / Q000737:chemistry*; D013058:Mass Spectrometry; D009584:Nitrogen / Q000032:analysis; D009596:Nitrophenols / Q000737:chemistry*; D012722:Sewage; D013696:Temperature; D013997:Time Factors; D014961:X-Ray Diffraction
chemical_list: D000538:Aluminum Silicates; D004138:Dinitrocresols; D004573:Electrolytes; C045076:Fenton's reagent; D009596:Nitrophenols; D012722:Sewage; D001546:Bentonite; C024132:4,6-dinitro-o-cresol; D006861:Hydrogen Peroxide; D007501:Iron; D009584:Nitrogen; D000077215:Clay; C024836:4-nitrophenol