Solute migration caused by excited state absorptions.
Using the Z-scan technique, we find that migration of chloroaluminum phthalocyanine in liquid ethanol can be induced by the absorption of a 19 ps laser pulse with energy exceeding a threshold but not by that of a 2.8 ns pulse depositing more energy at the solute molecules. Considering each solute molecule as an oscillator confined within a potential well, we explain, in accordance with the five-energy-band model, that solute molecules excited by a 19 ps pulse retain more translational excess energy to overcome the potential well barrier compared with those excited by a 2.8 ns pulse of equal energy. Therefore, they are more likely to migrate out of the laser beam center, weakening the solution's absorption that we detect in the Z-scan measurements. Furthermore, we theoretically infer that the 19 ps pulse-induced solute migration tends to be nonquasistatic and experimentally verify that it cannot be attributed to the Soret effect, a quasistatic process.
Chang
Che-Kai
CK
Department of Physics, National Chung Cheng University, Min-Hsiung, Chia-Yi 621, Taiwan.
Li
Yi-Ci
YC
Chen
Chen-Wei
CW
Lee
Li-Shu
LS
Tang
Jaw-Luen
JL
Wang
Chi-Chen
CC
Leu
Chang-Chi
CC
Wei
Tai-Huei
TH
Huang
Tzer-Hsiang
TH
Song
Yinglin
Y