Aqueous solution of UCl6(2-) in O2 saturated acidic medium: an efficient system to scavenge all primary radicals in spurs produced by irradiation.
Absorbance measurements find the yield of the oxidation of U(IV) to be (8.75 +/- 0.05) x 10(-7) mol J(-1) in the (60)Co gamma radiolysis of aqueous solutions containing 4.4 x 10(-3) mol L(-1) U(IV) in the presence of O(2) saturated 2 mol L(-1) Cl(-) at pH = 0. This high value of oxidation yield suggests that all primary radicals formed by water decomposition are scavenged in these solutions. Simulations using a nonhomogeneous stochastic kinetic track model agree with the experimental results and are used to explain the mechanism for scavenging radicals and oxidation of U(IV).
Atinault
E
E
De Waele
V
V
Fattahi
M
M
LaVerne
J A
JA
Pimblott
S M
SM
Mostafavi
M
M