title: Banana peel: a green and economical sorbent for the selective removal of Cr(VI) from industrial wastewater.
abstract: This study describes the use of banana peel, a commonly produced fruit waste, for the removal of Cr(VI) from industrial wastewater. The parameters pH, contact time, initial metal ion concentration, and temperature were investigated and the conditions resulting in rapid and efficient adsorption (95% within 10 min) were determined. The binding of metal ions was found to be pH dependent with the optimal sorption occurring at pH 2. The retained species were eluted with 5 mL of 2M H(2)SO(4). To elucidate the mechanism of the process, total amounts of chromium and Cr(VI) were analyzed using flame atomic absorption and ultraviolet-visible (UV-vis) spectroscopic techniques, respectively. The Langmuir and Dubinin-Radushkevich (D-R) isotherms were used to describe the partitioning behavior for the system at different temperatures. Kinetics and thermodynamics of Cr(VI) removal by banana peel were also studied. The influence of diverse ions on the sorption behavior revealed that only Fe(II) ions (of those tested) suppressed the sorption of Cr(VI) ions to some extent. The method was applied for the removal of Cr(VI) from industrial wastewater.
authors.affiliation: National Center of Excellence in Analytical Chemistry, University of Sindh, Jamshoro, Sindh, Pakistan. memon.jamil@gmail.com
authors.forename: Jamil R
authors.initials: JR
authors.lastname: Memon
authors.forename: Saima Q
authors.initials: SQ
authors.lastname: Memon
authors.forename: Muhammad I
authors.initials: MI
authors.lastname: Bhanger
authors.forename: Adel
authors.initials: A
authors.lastname: El-Turki
authors.forename: Keith R
authors.initials: KR
authors.lastname: Hallam
authors.forename: Geoffrey C
authors.initials: GC
authors.lastname: Allen
mesh_terms: D000327:Adsorption; D001673:Biodegradation, Environmental; D002857:Chromium / Q000032:analysis / Q000737:chemistry / Q000302:isolation & purification*; D006863:Hydrogen-Ion Concentration; D007220:Industrial Waste; D007477:Ions; D007700:Kinetics; D008670:Metals / Q000737:chemistry; D028521:Musa; D013499:Surface Properties; D013816:Thermodynamics; D014874:Water Pollutants, Chemical / Q000032:analysis*; D018508:Water Purification / Q000379:methods*
chemical_list: D007220:Industrial Waste; D007477:Ions; D008670:Metals; D014874:Water Pollutants, Chemical; D002857:Chromium