Study on mass transfer of isopropylbenzene and oxygen in a two-phase partitioning bioreactor in the presence of silicone oil.
A two-phase partitioning bioreactor to treat gas effluents polluted by volatile organic compound has been developed. In this work, both the mass transfer of isopropylbenzene (IPB) and oxygen have been considered in relation to their influence on the hydrodynamics of the reactor and the type of silicone oils used as a second phase. The synergistic effect of silicone oil and stirrer speed on the global oxygen mass transfer coefficient (KLa) and gas holdup (up to 12%) have been investigated. The addition of 10% of low viscosity silicone oil (10 cSt) in the reactor does not significantly affect the oxygen transfer rate. The very high solubility of IPB in the silicone oil leads to an enhancement of driving force term, especially for high fraction of silicone oil. However, it does not seem useful to exceed a volume fraction of 10% since KLa(IPB) decreases sharply at higher proportions of silicone oil. KLa(IPB) and KLaO2 evolve in the same way with the proportion of silicone oil. These results confirm the potentialities of our bioreactor to improve both the oxygen and pollutant gas transfer in the field of the treatment of gaseous pollutants, even for highly concentrated effluents.
Aldric
Jean-Marc
JM
Centre Wallon de Biologie Industrielle, Unité de Bio-industries, Faculté Universitaire des Sciences Agronomiques de Gembloux, Passage des déportés, 2, 5030 Gembloux, Belgium. aldric.jm@fsagx.ac.be
Lecomte
Jean-Paul
JP
Thonart
Philippe
P
D000393:Air Pollutants; D001555:Benzene Derivatives / Q000737:chemistry / Q000302:isolation & purification* / Q000378:metabolism; D019149:Bioreactors; D010100:Oxygen / Q000737:chemistry / Q000302:isolation & purification* / Q000378:metabolism; D012827:Silicone Oils / Q000737:chemistry*
D000393:Air Pollutants; D001555:Benzene Derivatives; D012827:Silicone Oils; C015763:cumene; D010100:Oxygen