[(OtBu)(2)C(6)H(3)](3)Ge(+) a free germyl cation with aryl ligands.
The reaction of Ar(3)GeBr (Ar = 2,6-(OtBu)(2)C(6)H(3)), which is the side product of the synthesis of the metalloid germanium cluster compound Ge(8)Ar(6), with the silver salt of the weakly coordinating anion (WCA) [Al(OR(f))(4)](-) (R(f) = C(CF(3))(3)) gives the free germyl cation Ar(3)Ge(+). Quantum chemical calculations open an insight into the bonding situation of this first free cation exhibiting aryl ligands and a first reaction leading to Ar(3)GeOH is presented.
Schenk
Christian
C
Institut für Anorganische Chemie der Universität Karlsruhe (TH), Engesserstr., Geb. 30.45, D-76131 Karlsruhe, Germany.
Drost
Christian
C
Schnepf
Andreas
A
D002412:Cations / Q000737:chemistry; D018360:Crystallography, X-Ray; D005857:Germanium / Q000737:chemistry*; D006841:Hydrocarbons, Aromatic / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D011789:Quantum Theory; D013237:Stereoisomerism
D002412:Cations; D006841:Hydrocarbons, Aromatic; D008024:Ligands; D009942:Organometallic Compounds; D005857:Germanium