Ultrasound-induced switching of sheetlike coordination polymer microparticles to nanofibers capable of gelating solvents.
We herein demonstrate a new gelation mechanism based on a readily available coordination polymer {Zn(bibp)(2)(OSO(2)CF(3))(2)}(n), in which ultrasound changes the morphology of the material from sheetlike microparticles into nanofibers, resulting in the immobilization of organic solvents.
Zhang
Shiyong
S
Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Hospital, Sichuan University, Chengdu 610064, People's Republic of China.
Yang
Shuaijun
S
Lan
Jingbo
J
Tang
Yurong
Y
Xue
Ying
Y
You
Jingsong
J
D005782:Gels / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008855:Microscopy, Electron, Scanning; D008958:Models, Molecular; D049329:Nanostructures / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010316:Particle Size; D012997:Solvents / Q000737:chemistry; D014465:Ultrasonics; D014961:X-Ray Diffraction; D015032:Zinc / Q000737:chemistry*
D005782:Gels; D009942:Organometallic Compounds; D012997:Solvents; D015032:Zinc