title: Addition of hydrogen or ammonia to a low-valent group 13 metal species at 25 degrees C and 1 atmosphere.
abstract: Mild-mannered: The low-valent aryl gallium(I) species :GaAr' (Ar' = 2,6-(2,6-iPr(2)C(6)H(3))(2)C(6)H(3)) undergoes addition to H(2) or NH(3) at room temperature and one atmosphere of pressure to afford 1 or 2 (see scheme), which were characterized by X-ray crystallography and NMR and IR spectroscopy.
authors.affiliation: Department of Chemistry, University of California, One Shields Avenue, Davis, CA 95616, USA.
authors.forename: Zhongliang
authors.initials: Z
authors.lastname: Zhu
authors.forename: Xinping
authors.initials: X
authors.lastname: Wang
authors.forename: Yang
authors.initials: Y
authors.lastname: Peng
authors.forename: Hao
authors.initials: H
authors.lastname: Lei
authors.forename: James C
authors.initials: JC
authors.lastname: Fettinger
authors.forename: Eric
authors.initials: E
authors.lastname: Rivard
authors.forename: Philip P
authors.initials: PP
authors.lastname: Power