A new luminescent 3D metal-organic framework possessing a rare (3,5)-connected net which can be transformed from a 2D double layer.
Applying a nonplanar dicarboxylate ligand, a new 3D metal-organic framework, Zn(TBDC(1))(1/2)(TBDC(2))(1/2) (), possessing a rare (3,5)-connected net has been synthesized and characterized; complex can be formed from a 2D double layer by thermally liberating the coordinated water and dmf molecules, simultaneous with luminescence-increased changes.
He
Haiyan
H
Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, P. R. China.
Dai
Fangna
F
Sun
Daofeng
D
D008024:Ligands; D049449:Luminescence; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D010795:Phthalic Acids / Q000737:chemistry*; D014961:X-Ray Diffraction; D015032:Zinc / Q000737:chemistry*
C539573:2,3,5,6-tetramethyl-1,4-benzenedicarboxylic acid; D008024:Ligands; D009942:Organometallic Compounds; D010795:Phthalic Acids; D015032:Zinc