C-F activation at rhodium boryl complexes: formation of 2-fluoroalkyl-1,3,2-dioxaborolanes by catalytic functionalization of hexafluoropropene.
Fluorinated building blocks by C-F bond cleavage: Catalytic C-F activation reactions that give novel dioxaborolanes have been developed (see scheme). The reactions proceed at room temperature, and catalytic intermediates are presumably rhodium hydride and boryl species.
Braun
Thomas
T
Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Strasse 2, 12489 Berlin, Germany. thomas.braun@chemie.hu-berlin.de
Salomon
Marcel Ahijado
MA
Altenhöner
Kai
K
Teltewskoi
Michael
M
Hinze
Silke
S