title: A large enhancement of photoinduced second harmonic generation in CdI2--Cu layered nanocrystals.
abstract: Photoinduced second harmonic generation (PISHG) in undoped as well as in various Cu-doped (0.05-1.2% Cu) CdI2 nanocrystals was measured at liquid nitrogen temperature (LNT). It was found that the PISHG increases with increasing Cu doping up to approximately 0.6% and then decreases almost to that for the undoped CdI2 for doping higher than approximately 1%. The values of the second-order susceptibility ranged from 0.50 to 0.67 pm V(-1) for the Cu-doped nanocrystals with a thickness of 0.5 nm. The Cu-doping dependence shown in a parabolic fashion suggests a crucial role of the Cu agglomerates in the observed effects. The PISHG in crystals with various nanosizes was also measured at LNT. The size dependence demonstrated the quantum-confined effect with a maximum PISHG for 0.5 nm and with a clear increase in the PISHG with decreasing thickness of the nanocrystal. The Raman scattering spectra at different pumping powers were taken for thin nanocrystals, and the phonon modes originating from interlayer phonons were observed in the spectra. The results were discussed within a model of photoinduced electron-phonon anharmonicity.
authors.affiliation: Nanoscale Science and Technology Centre, School of Biomolecular and Physical Sciences, Griffith University, Nathan, Brisbane, QLD 4111, Australia. m.miah@griffith.edu.au
authors.forename: M Idrish
authors.initials: MI
authors.lastname: Miah
mesh_terms: D019187:Cadmium Compounds / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D007454:Iodides / Q000737:chemistry*; D053758:Nanoparticles / Q000737:chemistry*; D010316:Particle Size; D010777:Photochemistry; D045663:Quantum Dots; D013499:Surface Properties; D013696:Temperature
chemical_list: D019187:Cadmium Compounds; D007454:Iodides; C073250:cadmium iodide; D003300:Copper