Ruthenium-catalyzed synthesis of functionalized dienes from propargylic esters: formal cross-coupling of two carbenes.
Cross-coupling carbenes: The coupling of a propargylic ester with a diazoalkane in the presence of [RuCl(cod)Cp*] catalyst leads to the formation of functionalized conjugated dienes with high stereoselectivity. The reaction involves the cross-coupling of a vinylcarbene fragment, arising from a ruthenium-catalyzed propargylic ester rearrangement, with a diazoalkane carbene.
Vovard-Le Bray
Chloé
C
Laboratoire "Catalyse et Organométalliques", Institut Sciences Chimiques de Rennes, UMR 6226, CNRS-Université de Rennes, Campus de Beaulieu, 35042 Rennes, France.
Dérien
Sylvie
S
Dixneuf
Pierre H
PH