Highly fluorescent rigid supramolecular polymeric nanowires constructed through multiple hydrogen bonds.
Supramolecular polymeric nanowires 1(n) constructed by a 3D shape-persistent hexaacid 1 through multiple hydrogen bonding interactions was developed. Single molecular nanoires were also obtained from its highly dilute solution.Hexaacid 1 containing pi-conjugated chromophores successfully self-assembled to afford these nanofibers with high solid quantum efficiency (22%), which provides us a pathway to fabricate optoelectronic devices using these highly fluorescent nanofibers.
Luo
Jia
J
Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry, Peking University, China.
Lei
Ting
T
Wang
Lei
L
Ma
Yuguo
Y
Cao
Yong
Y
Wang
Jian
J
Pei
Jian
J
D001555:Benzene Derivatives / Q000737:chemistry*; D002264:Carboxylic Acids / Q000737:chemistry*; D006860:Hydrogen Bonding; D008163:Luminescent Measurements; D018625:Microscopy, Atomic Force; D053770:Nanowires / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D014961:X-Ray Diffraction
D001555:Benzene Derivatives; D002264:Carboxylic Acids; D011108:Polymers