title: Revisiting prussian blue analogues with solid-state MAS NMR spectroscopy: spin density and local structure in [Cd3{Fe(CN)6}2] x 15 H2O.
abstract: No legendary Prussian order! The distribution of vacancies in Prussian blue analogues is not random, and the spin density on the Cd(2+) ion varies depending on the number of paramagnetic ions in its surroundings. This conclusion follows from (113)Cd solid-state magic-angle spinning NMR studies of [Cd(3){Fe/Co(CN)(6)}(2)] x 15 H(2)O, where the presence of small but significant spin density on the observed (113)Cd nucleus leads to improved spectral resolution.
authors.affiliation: Institut Parisien de Chimie Moléculaire, Université Pierre et Marie Curie-Paris6, UMR 7071, Paris 75252, France.
authors.forename: Alexandrine
authors.initials: A
authors.lastname: Flambard
authors.forename: Frank H
authors.initials: FH
authors.lastname: Köhler
authors.forename: Rodrigue
authors.initials: R
authors.lastname: Lescouëzec