title: C-F activation at rhodium boryl complexes: formation of 2-fluoroalkyl-1,3,2-dioxaborolanes by catalytic functionalization of hexafluoropropene.
abstract: Fluorinated building blocks by C-F bond cleavage: Catalytic C-F activation reactions that give novel dioxaborolanes have been developed (see scheme). The reactions proceed at room temperature, and catalytic intermediates are presumably rhodium hydride and boryl species.
authors.affiliation: Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Strasse 2, 12489 Berlin, Germany. thomas.braun@chemie.hu-berlin.de
authors.forename: Thomas
authors.initials: T
authors.lastname: Braun
authors.forename: Marcel Ahijado
authors.initials: MA
authors.lastname: Salomon
authors.forename: Kai
authors.initials: K
authors.lastname: Altenhöner
authors.forename: Michael
authors.initials: M
authors.lastname: Teltewskoi
authors.forename: Silke
authors.initials: S
authors.lastname: Hinze