Sandwiched sodium and half-sandwiched copper carbonyl complexes featuring polyfluorinated tris(triazolyl)borate [HB(3,5-(CF(3))(2)Tz)(3)](-).
Fluorinated tris(triazolyl)borate [HB(3,5-(CF(3))(2)Tz)(3)](-) (Tz = triazolyl) affords the isolation of [Na(THF)(6)]{[HB(3,5-(CF(3))(2)Tz)(3)](2)Na} with a ligand sandwiched sodium ion and a copper carbonyl complex [HB(3,5-(CF(3))(2)Tz)(3)]CuCO with a high C-O stretching frequency.
Kou
Xiaodi
X
Department of Chemistry and Biochemistry, The University of Texas at Arlington, Arlington, Texas 76019, USA.
Wu
Jiang
J
Cundari
Thomas R
TR
Dias
H V Rasika
HV