Highly regioselective simultaneous introduction of phosphino and seleno groups into unsaturated bonds by the novel combination of (Ph2P)2 and (PhSe)2 upon photoirradiation.
A novel combination of tetraphenyldiphosphine and diphenyl diselenide under photoirradiation conditions attains simultaneous introduction of diphenylphosphino and phenylseleno groups into carbon-carbon unsaturated bonds such as terminal alkynes or allenes, regioselectively.
Kawaguchi
Shin-ichi
S
Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan.
Shirai
Takamune
T
Ohe
Takashi
T
Nomoto
Akihiro
A
Sonoda
Motohiro
M
Ogawa
Akiya
A