Assembly of an R3N5(2-) chain by cycloaddition of a hydrazinediide and an azide at zirconium and its thermal fragmentation.
Breaking the chain: Reaction of a zirconium hydrazinediide with organoazides gives 2-pentazene-1,4-diyl complexes, such as [Zr(N(2) (TBS)N(py)){N(Ad)N(3)NPh(2)}] (C gray, N blue, Si green, Zr turquoise), by formal [2+3] cycloaddition. Bonding within the N(5) chain is investigated using density functional calculations. These complexes thermally eject N(2) to give side-on bonded diazenides.
Gehrmann
Thorsten
T
Anorganisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany.
Lloret Fillol
Julio
J
Wadepohl
Hubert
H
Gade
Lutz H
LH