title: Hydrogen evolution on nano-particulate transition metal sulfides.
abstract: The hydrogen evolution reaction (HER) on carbon supported MoS2 nanoparticles is investigated and compared to findings with previously published work on Au(111) supported MoS2. An investigation into MoS2 oxidation is presented and used to quantify the surface concentration of MoS2. Other metal sulfides with morphologies similar to MoS2 such as WS2, cobalt-promoted WS2, and cobalt-promoted MoS2 were also investigated in the search for improved HER activity. Experimental findings are compared to density functional theory (DFT) calculated values for the hydrogen binding energies (deltaGH) on each system.
authors.affiliation: Center for Individual Nanoparticle Functionality (CINF), Department of Physics, Technical University of Denmark, Lyngby DK-2800, Denmark.
authors.forename: Jacob
authors.initials: J
authors.lastname: Bonde
authors.forename: Poul G
authors.initials: PG
authors.lastname: Moses
authors.forename: Thomas F
authors.initials: TF
authors.lastname: Jaramillo
authors.forename: Jens K
authors.initials: JK
authors.lastname: Nørskov
authors.forename: Ib
authors.initials: I
authors.lastname: Chorkendorff
mesh_terms: D002384:Catalysis; D003198:Computer Simulation; D004563:Electrochemistry / Q000379:methods*; D004566:Electrodes; D004579:Electron Transport; D006859:Hydrogen / Q000737:chemistry*; D008956:Models, Chemical; D053758:Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D010084:Oxidation-Reduction; D013440:Sulfides / Q000737:chemistry*; D013499:Surface Properties; D028561:Transition Elements / Q000737:chemistry*
chemical_list: D013440:Sulfides; D028561:Transition Elements; D006859:Hydrogen