title: The rheology of hard sphere suspensions at arbitrary volume fractions: An improved differential viscosity model.
abstract: We propose a simple and general model accounting for the dependence of the viscosity of a hard sphere suspension at arbitrary volume fractions. The model constitutes a continuum-medium description based on a recursive-differential method where correlations between the spheres are introduced through an effective volume fraction. In contrast to other differential methods, the introduction of the effective volume fraction as the integration variable implicitly considers interactions between the spheres of the same recursive stage. The final expression for the viscosity scales with this effective volume fraction, which allows constructing a master curve that contains all the experimental situations considered. The agreement of our expression for the viscosity with experiments at low- and high-shear rates and in the high-frequency limit is remarkable for all volume fractions.
authors.affiliation: Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Apdo. Postal 70-360, 04510 México Distrito Federal, Mexico. cmendoza@iim.unam.mx
authors.forename: Carlos I
authors.initials: CI
authors.lastname: Mendoza
authors.forename: I
authors.initials: I
authors.lastname: Santamaría-Holek