Molecular recognition of pyridine N-oxides in water using calix[4]pyrrole receptors.
The incorporation of four carboxylic acids or four amino groups to the upper rim of an aryl extended calix[4]pyrrole produces water-soluble receptors which are able to effectively bind aromatic N-oxides in water by a combination of hydrogen bonding, pi-pi, CH-pi, and hydrophobic interactions.
Verdejo
Begoña
B
Institute of Chemical Research of Catalonia (ICIQ), Avgda. Paisos Catalans 16, 43007 Tarragona, Spain.
Gil-Ramírez
Guzmán
G
Ballester
Pablo
P
D047250:Calixarenes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D011166:Porphyrins / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*; D014867:Water / Q000737:chemistry*
D011166:Porphyrins; D011725:Pyridines; C469811:calix(4)pyrrole; D014867:Water; D047250:Calixarenes; C013229:pyridine N-oxide