Conversion of dechlorodauricumine into miharumine by a cell-free preparation from cultured roots of Menispermum dauricum.
Dechlorodauricumine (5) and dechloroacutumine (6) were converted to miharumine (7) and dechloroacutumidine (8), respectively, by a cell-free preparation from cultured roots of Menispermum dauricum in the presence of FAD. The structures of 7 and 8 were elucidated on the basis of spectroscopic analyses and chemical conversion.
Hori
Rieko
R
Graduate School of Agricultural Science, Kobe University, Rokkodai, Nada, Japan.
Sugimoto
Gen
G
Matsui
Miharu
M
Yamauchi
Yasuo
Y
Takikawa
Hirosato
H
Sugimoto
Yukihiro
Y
D000470:Alkaloids / Q000737:chemistry / Q000378:metabolism*; D002474:Cell-Free System; D009682:Magnetic Resonance Spectroscopy; D031603:Menispermum / Q000254:growth & development* / Q000378:metabolism*; D018517:Plant Roots / Q000254:growth & development* / Q000378:metabolism*; D013141:Spiro Compounds / Q000737:chemistry / Q000378:metabolism*
D000470:Alkaloids; D013141:Spiro Compounds; C522929:dechlorodauricumine; C539724:miharumine