title: Reactor model development: the removal performance of ferrous-catalysed photo-oxidation process by examining the reaction parameters.
abstract: The removal performance of the ferrous catalysed photo-oxidation process was investigated through the examination of major process parameters including pH levels and dosages of ferrous (Fe(2+)) and hydrogen peroxide (H(2)O(2)). A common used herbicide, alachlor, was used as a target compound in the degradation process. In the study, alachlor was found to be effectively degraded by hydroxyl radicals (HO) which were generated by UV/Fe(2+)/H(2)O(2) in the oxidation process. It was interesting to find that the pattern of reaction kinetics of alachlor varied depending on the initial concentrations of Fe(2+) and H(2)O(2). An optimum H(2)O(2) dosage was determined. This was practically useful because the overdose of H(2)O(2) would cause the process retardation. The conventional pseudo-first-order kinetics and two-stage first-order kinetics were observed at lower and higher Fe(2+) concentrations, respectively. Models were proposed and used to stimulate the kinetic process. Thus, design charts were established for determining the reaction time (i.e., reactor sizing) required for predetermined removal performance of alachlor under different concentrations of H(2)O(2) and Fe(2+).
authors.affiliation: Department of Civil and Structural Engineering, Research Centre for Environmental Technology and Management, The Hong Kong Polytechnic University, Hunghom, Kowloon, Hong Kong.
authors.forename: K H
authors.initials: KH
authors.lastname: Chan
authors.forename: W
authors.initials: W
authors.lastname: Chu
mesh_terms: D000081:Acetamides / Q000737:chemistry* / Q000528:radiation effects; D002384:Catalysis; D005296:Ferrous Compounds / Q000737:chemistry; D006540:Herbicides / Q000737:chemistry; D006861:Hydrogen Peroxide / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D017665:Hydroxyl Radical / Q000737:chemistry; D007700:Kinetics; D008956:Models, Chemical; D010083:Oxidants, Photochemical / Q000737:chemistry; D010084:Oxidation-Reduction; D055668:Photochemical Processes; D014466:Ultraviolet Rays
chemical_list: D000081:Acetamides; D005296:Ferrous Compounds; D006540:Herbicides; D010083:Oxidants, Photochemical; C000188:alachlor; D017665:Hydroxyl Radical; D006861:Hydrogen Peroxide