title: Measurements of OC and EC in coarse particulate matter in the southeastern United States.
abstract: The organic carbon (OC) and elemental carbon (EC) content of filter-based, 24-hr integrated particulate matter with aerodynamic diameters between 2.5 and 10 microm (PM10-2.5) was measured at two urban and two rural locations in the southeastern United States. On average, total carbon (OC + EC) comprised approximately 30% of PM10-2.5 mass at these four sites. Carbonate carbon was measured on a subset of samples from three sites and was found to be undetectable at a rural site in central Alabama, less than 2% of PM10-2.5 at an urban site in Georgia, and less than 10% of PM10-2.5 at an urban-industrial site in Alabama. Manual scanning electron microscopy (SEM) and computer-controlled SEM (CCSEM) along with energy dispersive X-ray spectroscopy (EDS) were used to identify individual carbonaceous particles in a selected subset of samples collected at one rural site and one urban-industrial site in Alabama. CCSEM results showed that biological material (e.g., fungal spores, pollen, and vegetative detritus) accounted for 60-70% of the carbonaceous mass in PM10-2.5 samples with concentrations in the range of 2-16 microg/m3. Samples with higher PM10-2.5 concentrations (25-42 microg/m3) at the urban-industrial site were found by manual SEM to have significant amounts of unidentified carbonaceous material, likely originating from local industrial activities. Both filter-based OC and EC concentrations and SEM-identified biological material tended to have higher concentrations during warmer months. Upper limits for organic mass (OM) to OC ratios (OM/OC) are estimated for PM10-2.5 samples at 2.1 for urban sites and 2.6-2.7 for rural sites.
authors.affiliation: Atmospheric Research & Analysis, Inc., Cary, NC 27513, USA. ericedge@gte.net
authors.forename: Eric S
authors.initials: ES
authors.lastname: Edgerton
authors.forename: Gary S
authors.initials: GS
authors.lastname: Casuccio
authors.forename: Rick D
authors.initials: RD
authors.lastname: Saylor
authors.forename: Traci L
authors.initials: TL
authors.lastname: Lersch
authors.forename: Benjamin E
authors.initials: BE
authors.lastname: Hartsell
authors.forename: John J
authors.initials: JJ
authors.lastname: Jansen
authors.forename: D Alan
authors.initials: DA
authors.lastname: Hansen
mesh_terms: D000397:Air Pollution / Q000032:analysis*; D002244:Carbon / Q000032:analysis* / Q000737:chemistry; D004784:Environmental Monitoring; D008855:Microscopy, Electron, Scanning; D010316:Particle Size; D052638:Particulate Matter / Q000032:analysis* / Q000737:chemistry; D011058:Pollen / Q000648:ultrastructure; D015144:Southeastern United States
chemical_list: D052638:Particulate Matter; D002244:Carbon