Supramolecular lone pair-pi/pi-pi/pi-anion assembly in a Mg(II)-malonate-2-aminopyridine-nitrate ternary system.
The solid-state structure of an alkaline-earth metal complex reveals the formation of a remarkable supramolecular framework based on concurrent lone pair-pi, pi-pi, and pi-anion interactions whose stability has been investigated by density functional theory.
Choudhury
Somnath Ray
SR
Department of Chemistry, Jadavpur University, Kolkata 700 032, India.
Dey
Biswajit
B
Das
Suranjana
S
Gamez
Patrick
P
Robertazzi
Arturo
A
Chan
Kai-Ting
KT
Lee
Hon Man
HM
Mukhopadhyay
Subrata
S