title: Imido transfer of sulfonylimino-lambda3-bromane makes possible the synthesis of sulfonylimino-lambda3-iodanes.
abstract: Sulfonylimino-lambda(3)-bromane functions as a reactive nitrenoid, because of the hyperleaving group ability of aryl-lambda(3)-bromanyl groups, and undergoes transimidations to iodobenzenes at room temperature under metal-free conditions probably via an S(N)2-type nitrenoid transition state, yielding sulfonylimino-lambda(3)-iodanes.
authors.affiliation: Graduate School of Pharmaceutical Sciences, University of Tokushima, 1-78 Shomachi, Tokushima 770-8505, Japan. mochiai@ph.tokushima-u.ac.jp
authors.forename: Masahito
authors.initials: M
authors.lastname: Ochiai
authors.forename: Aiko
authors.initials: A
authors.lastname: Nakano
authors.forename: Akira
authors.initials: A
authors.lastname: Yoshimura
authors.forename: Kazunori
authors.initials: K
authors.lastname: Miyamoto
authors.forename: Satoko
authors.initials: S
authors.lastname: Hayashi
authors.forename: Waro
authors.initials: W
authors.lastname: Nakanishi
mesh_terms: D054879:Halogenation; D007094:Imides / Q000737:chemistry*; D007097:Imines / Q000737:chemistry*; D015394:Molecular Structure; D013450:Sulfones / Q000737:chemistry*
chemical_list: D007094:Imides; D007097:Imines; D013450:Sulfones; C540083:sulfonylimino-lambda3-bromane