Insertion of amides into a polyoxometalate.
POM alert: The incorporation of an amide oxygen atom into the framework of the Dawson-type polyoxometalate (POM) cluster [P(2)V(3)W(15)O(62)](9-) (see picture) allows the communication of electronic effects between the organic and the inorganic parts of the molecule, including fine-tuning of the redox properties of the entire hybrid POM by the organic components, and transmission of the POM's electron-attracting properties to the organic moiety.
Li
Joaquim
J
UPMC Univ Paris 06, CNRS UMR 7201, Institut Parisien de Chimie Moléculaire, 4 place Jussieu, 75005 Paris, France.
Huth
Inga
I
Chamoreau
Lise-Marie
LM
Hasenknopf
Bernold
B
Lacôte
Emmanuel
E
Thorimbert
Serge
S
Malacria
Max
M