title: Tuning the structure and magnetism of azido-mediated Cu(II) systems by coligand modifications.
abstract: Through the use of a series of structurally related benzoates bearing different substituents as coligands, three new azido-copper compounds, [Cu(benzoate)(N(3))](n) (1), [Cu(2-methyl-benzoate)(N(3))](n) (2), and [Cu(1-naphthoate)(N(3))](n) (3), have been successfully obtained and structurally and magnetically characterized. Single-crystal structure analyses indicated that the uncoordinating substituents in the benzoates greatly affect the structure of the complexes. Complex 1 displays isolated ferromagnetic chains with the largest Cu-N-Cu angle in known carboxylate/end-on-azido mixed-bridged copper systems, while complexes 2 and 3 were 2D coordination polymers, containing mu-(1,1,3,3) and mu-(1,1,3) bridging azides and exhibiting new azido-copper networks with (4(4)) and (4.8(2)) topologies, respectively. Furthermore, 2 was a chiral complex obtained through spontaneous resolution. In the low-temperature range, both 2 and 3 showed spontaneous magnetization with characteristics of soft ferromagnetic magnetism with phase transition temperatures of 13 and 10 K, respectively.
authors.affiliation: Department of Chemistry, Nankai University, Tianjin 300071, P. R. China.
authors.forename: Jiong-Peng
authors.initials: JP
authors.lastname: Zhao
authors.forename: Bo-Wen
authors.initials: BW
authors.lastname: Hu
authors.forename: E C
authors.initials: EC
authors.lastname: Sañudo
authors.forename: Qian
authors.initials: Q
authors.lastname: Yang
authors.forename: Yong-Fei
authors.initials: YF
authors.lastname: Zeng
authors.forename: Xian-He
authors.initials: XH
authors.lastname: Bu