Hexa- and octagold chains from flexible tetragold molecular units supported by linear tetraphosphine ligands.
A flexible building block: Flexible tetragold(I) chain complexes supported by a new single methylene-bridged tetraphosphine ligand were synthesized and further transformed into discrete linear octagold(I) {Au(8)} and cyclic hexagold(I) {Au(6)} structures by reaction with KI and NaAuCl(4), respectively (see picture, Au purple, Cl dark green, PF(6) light green, I pink). The tetragold complexes are also luminescent at room temperature.
Takemura
Yukie
Y
Department of Chemistry, Faculty of Science, Nara Women's University, Kitauoya-higashi-machi, Nara, 630-8506, Japan.
Takenaka
Hiroe
H
Nakajima
Takayuki
T
Tanase
Tomoaki
T
D018360:Crystallography, X-Ray; D006046:Gold / Q000737:chemistry*; D008024:Ligands; D010720:Phosphines / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet
D008024:Ligands; D010720:Phosphines; D006046:Gold; C044646:phosphine