Asymmetric recognition and sequential ring opening of 2-substituted-N-nosylaziridines with (DHQD)2AQN and TMSNu.
A new method for asymmetric ring opening of terminal aziridines using a chiral amine, (DHQD)(2)AQN, is described; the reaction is based on the asymmetric recognition of aziridines using (DHQD)(2)AQN and on sequential ring opening using TMSNu.
Minakata
Satoshi
S
Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871, Japan. minakta@chem.eng.osaka-u.ac.jp
Murakami
Yuta
Y
Satake
Masamitsu
M
Hidaka
Ikumasa
I
Okada
Yuriko
Y
Komatsu
Mitsuo
M
D000588:Amines / Q000737:chemistry*; D001388:Aziridines / Q000737:chemistry*
D000588:Amines; D001388:Aziridines