The influence of the film thickness of nanostructured alpha-Fe2O3 on water photooxidation.
The present work shows the influence of the film thickness in the optical and photoelectrochemical properties of nanostructured alpha-Fe(2)O(3) thin film. We found that the film thickness has a strong influence on the optical absorption and the results here reported can help in the design of nanostructured alpha-Fe(2)O(3) with superior performance for water photo-oxidation. The results show that the optical property of the hematite film is affected by the film thickness, probably due to the stress induced by the strong interaction between film and substrate. This stress generates defects in the crystal lattice of the hematite film, increasing the (e(-))-(h(+)) recombination process.
Souza
Flavio Leandro
FL
LIEC-CDMDC, Department of Chemistry, UFSCar, São Carlos, SP, Rodovia Washington Luiz, km 235, C.P. 676, CEP 13565-905, São Carlos, SP, Brazil.
Lopes
Kirian Pimenta
KP
Longo
Elson
E
Leite
Edson Roberto
ER
D005290:Ferric Compounds / Q000737:chemistry*; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D055620:Optical Phenomena; D010083:Oxidants, Photochemical / Q000737:chemistry*; D010084:Oxidation-Reduction; D013053:Spectrophotometry; D014867:Water / Q000737:chemistry*
D005290:Ferric Compounds; D010083:Oxidants, Photochemical; D014867:Water; C000499:ferric oxide