Polymerization of cyclic esters initiated by carnitine and tin (II) octoate.
Low-molecular weight poly(epsilon-caprolactone), polylactides and copolymers of epsilon-caprolactone and lactides were obtained by the polymerization of cyclic esters in the presence of a carnitine/SnOct(2) system. Their structures were proven by means of MALDI-TOF, IR and NMR studies. Effects of temperature, reaction time and carnitine dosage on the polymerization process were examined.
Sobczak
Marcin
M
Department of Inorganic and Analytical Chemistry, Faculty of Pharmacy, Medical University of Warsaw, ul. Banacha 1, 02-097 Warsaw, Poland. marcin.sobczak@wum.edu.pl
Kolodziejski
Waclaw
W
D001672:Biocompatible Materials / Q000138:chemical synthesis / Q000737:chemistry; D002331:Carnitine / Q000138:chemical synthesis / Q000737:chemistry*; D004952:Esters / Q000138:chemical synthesis / Q000737:chemistry*; D006801:Humans; D015394:Molecular Structure; D008970:Molecular Weight; D011091:Polyesters / Q000138:chemical synthesis / Q000737:chemistry; D011108:Polymers / Q000138:chemical synthesis / Q000737:chemistry*; D013057:Spectrum Analysis / Q000379:methods; D017971:Tin Compounds / Q000737:chemistry*
D001672:Biocompatible Materials; D004952:Esters; D011091:Polyesters; D011108:Polymers; D017971:Tin Compounds; C016240:polycaprolactone; C033616:poly(lactide); D002331:Carnitine