title: Palladium(II)-catalyzed conjugate phosphination of electron-deficient acceptors.
abstract: A general protocol for the conjugate transfer of diphenyl-, dicyclohexyl-, and di-tert-butylphosphinyl groups from silylphosphines to cyclic and acyclic electron-deficient acceptors employing a bench-stable palladium(II) catalyst is reported. Several E and Z configured alpha,beta-unsaturated carbonyl and carboxyl acceptors (including imides) as well as nitroalkenes participate in this palladium(II)-catalyzed process in high chemical yields.
authors.affiliation: Organisch-Chemisches Institut, Westfälische Wilhelms-Universität, Corrensstrasse 40, D-48149 Münster, Germany.
authors.forename: Verena T
authors.initials: VT
authors.lastname: Trepohl
authors.forename: Susumu
authors.initials: S
authors.lastname: Mori
authors.forename: Kenichiro
authors.initials: K
authors.lastname: Itami
authors.forename: Martin
authors.initials: M
authors.lastname: Oestreich