title: Application of an unsteady state environmental distribution model to a decadal time series of PAH concentrations in Central Europe.
abstract: To explain observed decadal trends in concentrations of polycyclic aromatic hydrocarbons (PAHs) in soil at the Kosetice observatory, Czech Republic, an environmental distribution model for persistent organic pollutants (POPs) based on the fugacity approach was developed. Weekly air concentrations were used as input data for the unsteady state model and concentrations in soil were calculated. In general, agreement between measured and predicted soil concentrations of PAHs was observed. Temporal trends in PAH concentrations in Kosetice can be related to changes in residential heating. Predicted soil concentrations of volatile PAHs namely acenaphthylene, fluorene and phenanthrene are in better correspondence with observed data than concentrations of less volatile PAHs i.e. dibenzo(ah)anthracene, benzo(a)pyrene and benzo(ghi)perylene. These discrepancies between model results and field data are probably a result of a simplified description of degradation and aging processes in soil. The results from our dynamic multicompartmental model confirmed our hypothesis about unsteady state conditions between the air and soil, and suggested that a commonly used simple steady state model should be only applied as a predictive tool in a small region when local sources and sinks are well described.
authors.affiliation: Research Centre for Environmental Chemistry and Ecotoxicology RECETOX, Faculty of Science, Masaryk University, Kamenice 126/3, 625 00 Brno, Czech Republic.
authors.forename: Jirí
authors.initials: J
authors.lastname: Komprda
authors.forename: Klára
authors.initials: K
authors.lastname: Kubosová
authors.forename: Alice
authors.initials: A
authors.lastname: Dvorská
authors.forename: Martin
authors.initials: M
authors.lastname: Scheringer
authors.forename: Jana
authors.initials: J
authors.lastname: Klánová
authors.forename: Ivan
authors.initials: I
authors.lastname: Holoubek
mesh_terms: D000388:Air / Q000032:analysis*; D000393:Air Pollutants / Q000032:analysis; D018153:Czech Republic; D008954:Models, Biological; D011084:Polycyclic Aromatic Hydrocarbons / Q000032:analysis*; D012987:Soil / Q000032:analysis*; D012989:Soil Pollutants / Q000032:analysis; D013997:Time Factors; D014835:Volatilization
chemical_list: D000393:Air Pollutants; D011084:Polycyclic Aromatic Hydrocarbons; D012987:Soil; D012989:Soil Pollutants