Nanoporous crystals of calixarene/porphyrin supramolecular complex functionalized by diffusion and coordination of metal ions.
A highly nanoporous material has been obtained by self-assembly of calixarene and porphyrin building blocks. This supramolecular zeolite-like structure was successively functionalized by diffusion and coordination of metal ions to form a new bifunctionalized nanoporous material containing a porphyrinic pigment together with a metal center.
De Zorzi
Rita
R
Centro di Eccellenza in Biocristallografia, Dipartimento di Scienze Chimiche, Università di Trieste, Viale Giorgeri 1, 34127 Trieste, Italy.
Guidolin
Nicol
N
Randaccio
Lucio
L
Purrello
Roberto
R
Geremia
Silvano
S
D047250:Calixarenes / Q000737:chemistry*; D002712:Chlorides / Q000737:chemistry*; D018360:Crystallography, X-Ray; D004058:Diffusion; D008958:Models, Molecular; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry*; D009532:Nickel / Q000737:chemistry*; D010636:Phenols / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry*; D012964:Sodium / Q000737:chemistry; D017641:Zeolites / Q000737:chemistry; D017967:Zinc Compounds / Q000737:chemistry*
D002712:Chlorides; D010636:Phenols; D011166:Porphyrins; D017967:Zinc Compounds; C121325:calix(4)arene; D047250:Calixarenes; D017641:Zeolites; C021096:tetra(4-N-methylpyridyl)porphine; C022838:nickel chloride; D009532:Nickel; C016837:zinc chloride; D012964:Sodium