Beta-cyclodextrin-cross-linked polymer as solid phase extraction material coupled with inductively coupled plasma mass spectrometry for the analysis of trace Co(II).
A sensitive method for the separation/analysis of Co(II) was described. The beta-cyclodextrin cross-linked polymer (beta-CDCP) was synthesized and used as solid phase extraction material (SPE) to separate/pre-concentrate trace cobalt coupled with inductively coupled plasma mass spectrometry (ICP-MS) for the analysis of Co(II). The method was based on alpha-pyridylazo-beta-naphthol (PAN) as the complexing agent for Co(II)-PAN at neutral condition and the adsorption behavior of Co(II)-PAN on beta-CDCP was studied. Further, p-octylpolyethylene-glycolphenyl ether (Triton X-100) as environment-friendly eluant was used. The linear range, detection limit (DL) and the relative standard deviation (R.S.D.) was 5.0-160.0 ng/mL, 5.84 ng/L and 2.27% (n=3, c=30.0 ng/mL) respectively. The enhancement factor was 10. Moreover, the beta-CDCP could be used repeatedly and offered better recovery and estimation of standard samples.
Zhu
Xiashi
X
Department of Chemistry, Yangzhou University, Yangzhou 225002, PR China. xszhu@yzu.edu.cn
Wu
Min
M
Gu
Ying
Y
D003035:Cobalt / Q000032:analysis* / Q000302:isolation & purification; D013058:Mass Spectrometry / Q000379:methods*; D009281:Naphthalenes; D011108:Polymers / Q000138:chemical synthesis*; D011725:Pyridines; D052616:Solid Phase Extraction; D047392:beta-Cyclodextrins
D009281:Naphthalenes; D011108:Polymers; D011725:Pyridines; D047392:beta-Cyclodextrins; C495514:naphthalene-(1,2'-pyridylazo)-2-naphthol; D003035:Cobalt