Nazarov-type reactions in water.
Different in water! We have developed Nazarov-type reactions in water. Different reaction courses compared with those in organic solvents are observed in water. In the presence of a scandium based, surfactant-type catalyst, water-trapping products are obtained exclusively. The results presented are unprecedented and provide a valuable extension to information available regarding organic reactions in water.
Kokubo
Masaya
M
Department of Chemistry, School of Science, The University of Tokyo, The HFRE Division, ERATO, JST, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Kobayashi
Shū
S
D002384:Catalysis; D003500:Cyclization; D009930:Organic Chemicals / Q000737:chemistry*; D012538:Scandium / Q000737:chemistry; D013501:Surface-Active Agents / Q000737:chemistry; D014867:Water / Q000737:chemistry*
D009930:Organic Chemicals; D013501:Surface-Active Agents; D014867:Water; D012538:Scandium