Giant pores in a chromium 2,6-naphthalenedicarboxylate open-framework structure with MIL-101 topology.
Large, larger, ... Replacement of 1,4-benzenedicarboxylate by 2,6-naphthalenedicarboxylate in the MIL-101 structure leads to an isoreticular mesoporous framework containing cages with diameters of 39 and 46 A. High-throughput methods are employed to determine appropriate reaction conditions. The microcrystalline compound is characterized by molecular simulation techniques, powder X-ray diffraction, N(2)-sorption, and TEM investigations.
Sonnauer
Andreas
A
Institute of Inorganic Chemistry, Christian-Albrechts-University, Max-Eyth-Strasse 2, 24118 Kiel, Germany.
Hoffmann
Frank
F
Fröba
Michael
M
Kienle
Lorenz
L
Duppel
Viola
V
Thommes
Matthias
M
Serre
Christian
C
Férey
Gérard
G
Stock
Norbert
N