Studies on the adsorption behavior of trace amounts of 90Sr2+, 140La3+, 60Co2+, Ni2+ and Zr4+ cations on synthesized inorganic ion exchangers.
Three inorganic ion exchangers namely potassium zinc hexacyanoferrate(II) (PZF), magnesium oxide-polyacrylonitrile composite (MgO-PAN) and ammonium molybdophosphate (AMP) were synthesized. The physicochemical properties of these ion exchangers were determined using different techniques including inductively coupled plasma (ICP), CHNSO elemental analysis, infrared spectroscopy (IR), X-ray diffraction (XRD), thermogravimetric (TGA) and pH - titration curve analysis. The solubility of the synthesized ion exchangers in different acidic and alkaline media, their thermal stability and the effect of gamma irradiation were investigated. It was observed that the exchange capacity of the ion exchangers depend upon the pH value of the solution used. Furthermore, the adsorption of (90)Sr(2+), (140)La(3+), (60)Co(2+) and the distribution coefficient of these ion exchangers for Ni(2+)and Zr(4+) were studied. The effect of parameters such as pH and contact time on the adsorption was also investigated and the optimum conditions for separation of these ions were determined.
Nilchi
A
A
Nuclear Science and Technology Research Institute, Nuclear Science Research School, J. I. H. Research Laboratories, Tehran, Iran. anilchi@aeoi.org.ir
Hadjmohammadi
M R
MR
Rasouli Garmarodi
S
S
Saberi
R
R
D000327:Adsorption; D003035:Cobalt / Q000302:isolation & purification; D006863:Hydrogen-Ion Concentration; D007474:Ion Exchange; D007475:Ion Exchange Resins / Q000138:chemical synthesis* / Q000592:standards; D007811:Lanthanum / Q000302:isolation & purification; D019216:Metals, Heavy / Q000302:isolation & purification*; D009532:Nickel / Q000302:isolation & purification; D013324:Strontium / Q000302:isolation & purification; D015040:Zirconium / Q000302:isolation & purification
D007475:Ion Exchange Resins; D019216:Metals, Heavy; D003035:Cobalt; D007811:Lanthanum; D009532:Nickel; D015040:Zirconium; D013324:Strontium