Topotactic intercalation of a bulky organic anion (thiacalix[4]arene) into LDH through an osmotic swelling/restoration reaction in formamide.
Utilizing the osmotic swelling of LDH in formamide, for the first time, the bulky thiacalix[4]arene anion is introduced, leading to the recovery of LDH layers, and the hexagonal prism morphology of the precursor is well retained.
Huang
Gailing
G
College of Chemistry, Beijing Normal University, Beijing 100875, China.
Ma
Shulan
S
Zhao
Xinhua
X
Yang
Xiaojing
X
Ooi
Kenta
K