title: Stereoselective synthesis of cis-beta-methyl- and phenyl-substituted alkenylboronates by platinum-catalyzed dehydrogenative borylation.
abstract: Changing places: Intramolecular B(pin)/H exchange took place in the presence of a platinum-phosphane catalyst, giving synthetically useful cis-beta-methyl-substituted alkenylboronates stereoselectively (see scheme; B(pin) = 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl).
authors.affiliation: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Kyoto 615-8510, Japan.
authors.forename: Toshimichi
authors.initials: T
authors.lastname: Ohmura
authors.forename: Yuta
authors.initials: Y
authors.lastname: Takasaki
authors.forename: Hideki
authors.initials: H
authors.lastname: Furukawa
authors.forename: Michinori
authors.initials: M
authors.lastname: Suginome