title: Carbon and chlorine isotope fractionation during aerobic oxidation and reductive dechlorination of vinyl chloride and cis-1,2-dichloroethene.
abstract: The study investigated carbon and chlorine isotope fractionation during aerobic oxidation and reductive dechlorination of vinyl chloride (VC) and cis-1,2-dichloroethene (cDCE). The experimental data followed a Rayleigh trend. For aerobic oxidation, the average carbon isotope enrichment factors were -7.2 per thousand and -8.5% for VC and cDCE, respectively, while average chlorine isotope enrichment factors were only -0.3 per thousand for both compounds. These values are consistent with an initial transformation by epoxidation for which a significant primary carbon isotope effect and only a small secondary chlorine isotope effect is expected. For reductive dechlorination, larger carbon isotope enrichment factors of -25.2 per thousand for VC and -18.5 per thousand for cDCE were observed consistent with previous studies. Although the average chlorine isotope enrichmentfactors were larger than those of aerobic oxidation (-1.8 per thousand for VC, -1.5 per thousand for cDCE), they were not as large as typically expected for a primary chlorine isotope effect suggesting that no cleavage of C-Cl bonds takes place during the initial rate-limiting step. The ratio of isotope enrichment factors for chlorine and carbon were substantially different for the two reaction mechanisms suggesting that the reaction mechanisms can be differentiated at the field scale using a dual isotope approach.
authors.affiliation: Centre for Hydrogeology, University of Neuchâtel, Rue Emile Argand 11, CH-2009 Neuchâtel, Switzerland.
authors.forename: Y
authors.initials: Y
authors.lastname: Abe
authors.forename: R
authors.initials: R
authors.lastname: Aravena
authors.forename: J
authors.initials: J
authors.lastname: Zopfi
authors.forename: O
authors.initials: O
authors.lastname: Shouakar-Stash
authors.forename: E
authors.initials: E
authors.lastname: Cox
authors.forename: J D
authors.initials: JD
authors.lastname: Roberts
authors.forename: D
authors.initials: D
authors.lastname: Hunkeler
mesh_terms: D000332:Aerobiosis; D001673:Biodegradation, Environmental; D002247:Carbon Isotopes; D005591:Chemical Fractionation; D002713:Chlorine / Q000378:metabolism*; D004000:Dichloroethylenes / Q000378:metabolism*; D004787:Environmental Pollution; D054879:Halogenation; D007700:Kinetics; D010084:Oxidation-Reduction; D014752:Vinyl Chloride / Q000378:metabolism*
chemical_list: D002247:Carbon Isotopes; D004000:Dichloroethylenes; D002713:Chlorine; D014752:Vinyl Chloride; C035384:1,2-dichloroethylene