title: Synthesis of amidines using N-allyl ynamides. A palladium-catalyzed allyl transfer through an ynamido-pi-allyl complex.
abstract: A de novo transformation of N-allyl-N-sulfonyl ynamides to amidines is described featuring a palladium-catalyzed N-to-C allyl transfer via ynamido-palladium-pi-allyl complexes.
authors.affiliation: Division of Pharmaceutical Sciences and Department of Chemistry, University of Wisconsin, Madison, Wisconsin 53705, USA.
authors.forename: Yu
authors.initials: Y
authors.lastname: Zhang
authors.forename: Kyle A
authors.initials: KA
authors.lastname: DeKorver
authors.forename: Andrew G
authors.initials: AG
authors.lastname: Lohse
authors.forename: Yan-Shi
authors.initials: YS
authors.lastname: Zhang
authors.forename: Jian
authors.initials: J
authors.lastname: Huang
authors.forename: Richard P
authors.initials: RP
authors.lastname: Hsung
mesh_terms: D000578:Amidines / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D007093:Imidazoles / Q000737:chemistry; D007783:Lactones / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*
chemical_list: D000578:Amidines; D007093:Imidazoles; D007783:Lactones; D010165:Palladium