title: Spin glass behavior of isolated, geometrically frustrated tetrahedra of iron atoms in the intermetallic La(21)Fe(8)Sn(7)C(12).
abstract: Metal flux synthesis in a low-melting eutectic mixture of lanthanum and nickel has produced a family of complex intermetallic carbide phases. La(21)Fe(8)M(7)C(12) (M = Sn, Bi, Sb, Te, Ge) has a new cubic structure featuring tetrahedra of iron atoms capped with carbon on each edge. These tetrahedra are surrounded by a La/M framework and are therefore isolated from each other. The antiferromagnetic coupling of the iron atoms is frustrated by their ideal tetrahedral arrangement; this is evidenced by magnetic susceptibility measurements on the La(21)Fe(8)Sn(7)C(12) analogue. Deviations from Curie-Weiss behavior begin at 100 K; variation in field-cooled vs zero-field-cooled behavior is seen at 5 K indicative of magnetic ordering. AC susceptibility data indicate that the temperature of this transition is frequency-dependent, behavior characteristic of spin glass systems.
authors.affiliation: Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida 32306, USA.
authors.forename: Evan M
authors.initials: EM
authors.lastname: Benbow
authors.forename: Naresh S
authors.initials: NS
authors.lastname: Dalal
authors.forename: Susan E
authors.initials: SE
authors.lastname: Latturner