title: Giant pores in a chromium 2,6-naphthalenedicarboxylate open-framework structure with MIL-101 topology.
abstract: Large, larger, ... Replacement of 1,4-benzenedicarboxylate by 2,6-naphthalenedicarboxylate in the MIL-101 structure leads to an isoreticular mesoporous framework containing cages with diameters of 39 and 46 A. High-throughput methods are employed to determine appropriate reaction conditions. The microcrystalline compound is characterized by molecular simulation techniques, powder X-ray diffraction, N(2)-sorption, and TEM investigations.
authors.affiliation: Institute of Inorganic Chemistry, Christian-Albrechts-University, Max-Eyth-Strasse 2, 24118 Kiel, Germany.
authors.forename: Andreas
authors.initials: A
authors.lastname: Sonnauer
authors.forename: Frank
authors.initials: F
authors.lastname: Hoffmann
authors.forename: Michael
authors.initials: M
authors.lastname: Fröba
authors.forename: Lorenz
authors.initials: L
authors.lastname: Kienle
authors.forename: Viola
authors.initials: V
authors.lastname: Duppel
authors.forename: Matthias
authors.initials: M
authors.lastname: Thommes
authors.forename: Christian
authors.initials: C
authors.lastname: Serre
authors.forename: Gérard
authors.initials: G
authors.lastname: Férey
authors.forename: Norbert
authors.initials: N
authors.lastname: Stock