title: Neptunium(vi) chain and neptunium(vi/v) mixed valence cluster complexes.
abstract: The synthesis of [Np(VI)O(2)Cl(2)(thf)](n) offers the potential for more detailed exploration of neptunyl(vi) chemistry, while the synthesis of the mixed valence cluster complex [{Np(VI)O(2)Cl(2)}{Np(V)O(2)Cl(thf)(3)}(2)] allows molecular neptunyl(v) 'cation-cation' interactions to be probed.
authors.affiliation: Centre for Radiochemistry Research, School of Chemistry, The University of Manchester, Oxford Road, Manchester, UK M13 9PL.
authors.forename: Stéphanie M
authors.initials: SM
authors.lastname: Cornet
authors.forename: L Jonas L
authors.initials: LJ
authors.lastname: Häller
authors.forename: Mark J
authors.initials: MJ
authors.lastname: Sarsfield
authors.forename: David
authors.initials: D
authors.lastname: Collison
authors.forename: Madeleine
authors.initials: M
authors.lastname: Helliwell
authors.forename: Iain
authors.initials: I
authors.lastname: May
authors.forename: Nikolas
authors.initials: N
authors.lastname: Kaltsoyannis