title: Insertion of amides into a polyoxometalate.
abstract: POM alert: The incorporation of an amide oxygen atom into the framework of the Dawson-type polyoxometalate (POM) cluster [P(2)V(3)W(15)O(62)](9-) (see picture) allows the communication of electronic effects between the organic and the inorganic parts of the molecule, including fine-tuning of the redox properties of the entire hybrid POM by the organic components, and transmission of the POM's electron-attracting properties to the organic moiety.
authors.affiliation: UPMC Univ Paris 06, CNRS UMR 7201, Institut Parisien de Chimie Moléculaire, 4 place Jussieu, 75005 Paris, France.
authors.forename: Joaquim
authors.initials: J
authors.lastname: Li
authors.forename: Inga
authors.initials: I
authors.lastname: Huth
authors.forename: Lise-Marie
authors.initials: LM
authors.lastname: Chamoreau
authors.forename: Bernold
authors.initials: B
authors.lastname: Hasenknopf
authors.forename: Emmanuel
authors.initials: E
authors.lastname: Lacôte
authors.forename: Serge
authors.initials: S
authors.lastname: Thorimbert
authors.forename: Max
authors.initials: M
authors.lastname: Malacria