Reversible phase transfer of (CdSe/ZnS) quantum dots between organic and aqueous solutions.
Ttrioctylphosphine oxide (TOPO) stabilized CdSe/ZnS quantum dots (QD) were modified with 6-ferrocenyl-1-hexanethiol (FcHT) or 11-ferrocenyl-1-undecanethiol (FcUT) via ligand exchange. The presence of ferrocenyl thiol ligands on the surface of the QDs was proven by diffusion ordered NMR spectroscopy. Upon replacement of the initial TOPO ligand with ferrocene derivatives the emission of the QDs decreased. Phase transfer of ferrocene-modified QDs from organic solvents into water was achieved by complexation reactions with beta-cyclodextrin (beta-CD). The QDs coated with ferrocene thiols are soluble in nonpolar solvents and are transferred into the aqueous phase upon formation of host-guest complexes between the ferrocene units and the cavity of beta-CD. The reversibility of the phase transfer was probed by the addition of naphthalene and adamantane derivatives to the aqueous phase containing QD-[Fc-CD] adduct.
Dorokhin
Denis
D
Materials Science and Technology of Polymers, University of Twente, Enschede, The Netherlands.
Tomczak
Nikodem
N
Han
Mingyong
M
Reinhoudt
David N
DN
Velders
Aldrik H
AH
Vancso
G Julius
GJ
D019187:Cadmium Compounds / Q000737:chemistry; D005296:Ferrous Compounds / Q000737:chemistry; D000075163:Metallocenes; D045663:Quantum Dots; D018036:Selenium Compounds / Q000737:chemistry; D012996:Solutions; D013440:Sulfides / Q000737:chemistry; D017967:Zinc Compounds / Q000737:chemistry; D047392:beta-Cyclodextrins / Q000737:chemistry
D019187:Cadmium Compounds; D005296:Ferrous Compounds; D000075163:Metallocenes; D018036:Selenium Compounds; D012996:Solutions; D013440:Sulfides; D017967:Zinc Compounds; D047392:beta-Cyclodextrins; C058667:cadmium selenide; C031238:zinc sulfide; C004998:ferrocene