title: Pentacoordinate organoantimony compounds that isomerize by turnstile rotation.
abstract: Two stereoisomers of pentacoordinate antimony compounds (stiboranes) with a new rigid tridentate ligand were synthesized, and the isomerization was found to proceed by the turnstile rotation (TR) mechanism with the tridentate ligand as a trio and the two monodentate ligands as a pair.
authors.affiliation: Department of Chemistry, Graduate School of Science, Hiroshima University, Kagamiyama, Higashi-Hiroshima, Japan.
authors.forename: Shiro
authors.initials: S
authors.lastname: Matsukawa
authors.forename: Hideaki
authors.initials: H
authors.lastname: Yamamichi
authors.forename: Yohsuke
authors.initials: Y
authors.lastname: Yamamoto
authors.forename: Kaori
authors.initials: K
authors.lastname: Ando
mesh_terms: D000965:Antimony / Q000737:chemistry*; D007536:Isomerism; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D013816:Thermodynamics
chemical_list: D009942:Organometallic Compounds; D000965:Antimony