title: Copper-TBAF catalyzed arylation of amines and amides with aryl trimethoxysilane.
abstract: A copper-catalyzed C-N bond forming reaction among aryl siloxane and primary, secondary amines as well as amides has been described. The reaction was conducted in the presence of P(C6F5)3 and 4 A molecular sieves in CH2Cl2 at room temperature under O2. A catalytic amount of TBAF was employed to activate aryl siloxanes.
authors.affiliation: College of Chemistry & Materials Engineering, Wenzhou University, Mid. Xueyuan Rd., Wenzhou 325027, P. R. China.
authors.forename: Baoda
authors.initials: B
authors.lastname: Lin
authors.forename: Miaochang
authors.initials: M
authors.lastname: Liu
authors.forename: Zhishi
authors.initials: Z
authors.lastname: Ye
authors.forename: Jinchang
authors.initials: J
authors.lastname: Ding
authors.forename: Huayue
authors.initials: H
authors.lastname: Wu
authors.forename: Jiang
authors.initials: J
authors.lastname: Cheng
mesh_terms: D000577:Amides / Q000737:chemistry*; D000588:Amines / Q000737:chemistry*; D002384:Catalysis; D003300:Copper; D006841:Hydrocarbons, Aromatic / Q000737:chemistry*; D012821:Silanes
chemical_list: D000577:Amides; D000588:Amines; D006841:Hydrocarbons, Aromatic; D012821:Silanes; D003300:Copper; C071717:trimethoxysilane