Respiratory and dermal exposure to organophosphorus flame retardants and tetrabromobisphenol A at five work environments.
Organophosphorus compounds (OPs) and tetrabromobisphenol A (TBBPA) are widely utilized as flame retardants (FRs) in plastics, textiles, rubbers, and building materials. Eight OPs and TBBPA were quantified by GC/MS from air samples collected from a furniture workshop, a circuit board factory, two electronics dismantling facilities, a computer classroom, and offices and social premises. In addition, dermal exposure was assessed with patch and hand wash samples at some workplaces. Triphenyl phosphate, tris(2-chloroethyl) phosphate, and tris(2-chloroisopropyl) phosphate were typical contaminants of the workplaces, whereas TBBPA, tricresyl phosphate, tri-n-butyl phosphate, and tris(2-ethylhexyl) phosphate were rather site-specific. The highest geometric mean of total FRs in the air samples was measured in personal samples atthe electronics dismantling facilities (2.9 and 3.8 microg/m3), whereas the stationary sample results from the other environments ranged between 90 and 720 ng/m3. Stationary samplings underestimated the personal exposure at three out of four work places where comparisons were made. Dermal exposure was shown for the first time at these occupational settings. The geometric mean of totalFR levels in patch samples ranged between 1.5 and 24 ng/cm2 and in hand wash samples between 3.5 and 34 microg/ two hands. The health effects of the measured FR levels remain unknown.
Mäkinen
Maija S E
MS
Department of Environmental Science, University of Kuopio, P.O. Box 1627, 70211 Kuopio, Finland. maija.makinen@uku.fi
Mäkinen
Milja R A
MR
Koistinen
Jaana T B
JT
Pasanen
Anna-Liisa
AL
Pasanen
Pertti O
PO
Kalliokoski
Pentti J
PJ
Korpi
Anne M
AM
D002138:Calibration; D005411:Flame Retardants / Q000633:toxicity*; D008401:Gas Chromatography-Mass Spectrometry; D006801:Humans; D016273:Occupational Exposure; D009943:Organophosphorus Compounds / Q000633:toxicity*; D011786:Quality Control; D012137:Respiratory System / Q000187:drug effects*; D012867:Skin / Q000187:drug effects*
D005411:Flame Retardants; D009943:Organophosphorus Compounds