title: Phenol removal onto novel activated carbons made from lignocellulosic precursors: influence of surface properties.
abstract: The adsorption of phenol from dilute aqueous solutions onto new activated carbons (AC) was studied. The novel activated carbon was produced from lignocellulosic (LC) precursors of rapeseed and kenaf. Samples oxidised with nitric acid in liquid phase were also studied. The results have shown the significant potential of rapeseed and kenaf for the activated carbon production. The activated carbons produced by carbon dioxide activation were mainly microporous with BET apparent surface area up to 1350 m(2)g(-1) and pore volume 0.5 cm(3)g(-1). The effects of concentration (0.1-2 mM) and pH (3-13) were studied. The phenol adsorption isotherms at 25 degrees C followed the Freundlich model with maximum adsorption capacities of approximately 80 and 50 mg g(-1) for the pristine and oxidised activated carbons, respectively. The influence of pH on the adsorption has two trends for pH below and above 10. It was possible to conclude that when phenol is predominantly in the molecular form the most probable mechanism is based on the pi-pi dispersion interaction between the phenol aromatic ring and the delocalised pi electrons present in the activated carbon aromatic structure. When phenolate is the major component the electrostatic repulsion that occurs at high pH values is the most important aspect of the adsorption mechanism.
authors.affiliation: Centro de Química de Evora & Departmento de Química, Universidade de Evora, Rua Romão Ramalho number 59, Evora, Portugal. jvn@uevora.pt
authors.forename: J M Valente
authors.initials: JM
authors.lastname: Nabais
authors.forename: J A
authors.initials: JA
authors.lastname: Gomes
authors.lastname: Suhas
authors.forename: P J M
authors.initials: PJ
authors.lastname: Carrott
authors.forename: C
authors.initials: C
authors.lastname: Laginhas
authors.forename: S
authors.initials: S
authors.lastname: Roman
mesh_terms: D000327:Adsorption; D029741:Brassica rapa; D002245:Carbon Dioxide; D002606:Charcoal / Q000737:chemistry*; D031584:Hibiscus; D006863:Hydrogen-Ion Concentration; D008031:Lignin / Q000737:chemistry*; D017942:Nitric Acid / Q000737:chemistry; D010636:Phenols / Q000302:isolation & purification*; D016062:Porosity; D055672:Static Electricity; D013499:Surface Properties; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*
chemical_list: D010636:Phenols; D014874:Water Pollutants, Chemical; C036909:lignocellulose; D002245:Carbon Dioxide; D002606:Charcoal; D017942:Nitric Acid; D008031:Lignin