Synthesis of poly(3-hexylthiophene) grafted TiO2 nanotube composite.
A composite of poly(3-hexylthiophene) (P3HT) grafted on TiO(2) nanotubes was synthesized. It was characterized using XRD, TEM, TGA, FTIR and XPS. Cyclic voltammetry (CV) was used to elucidate the electrochemical behavior and evaluate the HOMO and LUMO energy levels. Photoluminescence (PL) measurements show that the emission intensity of P3HT mixed with TiO(2) nanotubes was one third of that of random P3HT, while that of P3HT grafted onto TiO(2) nanotubes was 10% of random P3HT. The results show that the P3HT grafted onto TiO(2) nanotubes is more efficient in photoinduced charge transfer than a physical mixture of P3HT and TiO(2) nanotubes, indicating this composite has potential for the fabricating hybrid organic-inorganic solid state solar cells.
Lu
Ming-De
MD
Photovoltaics Technology Center, Industrial Technology Research Institute, Chutung 31040, Taiwan.
Yang
Sze-Ming
SM
D000327:Adsorption; D004563:Electrochemistry; D049449:Luminescence; D043942:Nanotubes / Q000737:chemistry*; D010316:Particle Size; D013053:Spectrophotometry; D017550:Spectroscopy, Fourier Transform Infrared; D013499:Surface Properties; D013696:Temperature; D013876:Thiophenes / Q000138:chemical synthesis* / Q000737:chemistry; D014025:Titanium / Q000737:chemistry*; D014961:X-Ray Diffraction; D014965:X-Rays
D013876:Thiophenes; C507295:poly(3-hexylthiophene); C009495:titanium dioxide; D014025:Titanium