Diffusion NMR and trilinear analysis in the study of reaction kinetics.
Measurement of diffusion-weighted NMR spectra as a function of time allows the time-dependence of concentration and the isolated spectrum to be found for each component in a reaction, without prior assumptions about spectra, kinetics or diffusion behaviour, by data decomposition using the PARAFAC algorithm.
Nilsson
Mathias
M
School of Chemistry, University of Manchester, Oxford Road, Manchester, UK M13 9PL. mathias.nilsson@manchester.ac.uk
Khajeh
Maryam
M
Botana
Adolfo
A
Bernstein
Michael A
MA
Morris
Gareth A
GA
D004058:Diffusion; D007700:Kinetics; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D017711:Nonlinear Dynamics