Remarkable bromination and blue emission of 9-anthracenyl Pt(II) complexes.
Contrary to expectations, molecular bromine addition to trans-Pt(Br)(9-anthracenyl)(PEt(3))(2) does not result in Pt oxidation or Pt-C bond cleavage but rather in selective multiple bromination of the anthracenyl ligand. The resulting complexes are highly photoluminescent in the blue region due to triplet-triplet annihilation induced delayed fluorescence from the anthracene.
Wang
Bao-Yu
BY
University of Missouri, Columbia, Missouri 65211, USA.
Karikachery
Alice Raphael
AR
Li
Yunjing
Y
Singh
Anupam
A
Lee
Han Baek
HB
Sun
Wenfang
W
Sharp
Paul R
PR