Reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds.
Reactions of a neutral silyleneruthenium complex with ketones and aldehydes, and isolation of their agostic intermediates are reported, where an alpha-H abstraction or hydrosilylation of the carbonyl compounds occurs depending on the substituents of the substrates.
Ochiai
Mitsuyoshi
M
Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai, 980-8578, Japan.
Hashimoto
Hisako
H
Tobita
Hiromi
H