Pentacoordinate organoantimony compounds that isomerize by turnstile rotation.
Two stereoisomers of pentacoordinate antimony compounds (stiboranes) with a new rigid tridentate ligand were synthesized, and the isomerization was found to proceed by the turnstile rotation (TR) mechanism with the tridentate ligand as a trio and the two monodentate ligands as a pair.
Matsukawa
Shiro
S
Department of Chemistry, Graduate School of Science, Hiroshima University, Kagamiyama, Higashi-Hiroshima, Japan.
Yamamichi
Hideaki
H
Yamamoto
Yohsuke
Y
Ando
Kaori
K
D000965:Antimony / Q000737:chemistry*; D007536:Isomerism; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D013816:Thermodynamics
D009942:Organometallic Compounds; D000965:Antimony