title: Intermolecular electron-transfer catalyzed on nanoparticle surfaces.
abstract: Surface-functionalized nanoparticles enhance the rate of electron transfer (ET) between Cyt c(Fe(2+)) and Co(phen)(3)(3+) by a factor of 10(5) through simultaneous electrostatic binding of an ET donor and acceptor.
authors.affiliation: Department of Chemistry, University of Massachusetts, Amherst, Massachusetts 01003, USA.
authors.forename: Adrienne M
authors.initials: AM
authors.lastname: Carver
authors.forename: Mrinmoy
authors.initials: M
authors.lastname: De
authors.forename: Halil
authors.initials: H
authors.lastname: Bayraktar
authors.forename: Subinoy
authors.initials: S
authors.lastname: Rana
authors.forename: Vincent M
authors.initials: VM
authors.lastname: Rotello
authors.forename: Michael J
authors.initials: MJ
authors.lastname: Knapp
mesh_terms: D002384:Catalysis; D045304:Cytochromes c / Q000737:chemistry; D004579:Electron Transport; D007700:Kinetics; D053758:Nanoparticles / Q000737:chemistry*; D055672:Static Electricity
chemical_list: D045304:Cytochromes c