Exceptionally high H2 storage by a metal-organic polyhedral framework.
The desolvated polyhedral framework material NOTT-112 shows an excess H(2) uptake of 7.07 wt% between 35 and 40 bar at 77 K, and a total H(2) uptake of 10 wt% at 77 bar and 77 K.
Yan
Yong
Y
School of Chemistry, University of Nottingham, University Park, Nottingham, UKNG7 2RD.
Lin
Xiang
X
Yang
Sihai
S
Blake
Alexander J
AJ
Dailly
Anne
A
Champness
Neil R
NR
Hubberstey
Peter
P
Schröder
Martin
M
D006859:Hydrogen / Q000737:chemistry*; D008670:Metals / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D013696:Temperature
D008670:Metals; D009942:Organometallic Compounds; C539833:triaqua(1,3,5-tris(3',5'-dicarboxy(1,1'-biphenyl)-4-yl)benzene)tricopper(II); D006859:Hydrogen