Syntheses and photophysical properties of optical-active blue-phosphorescent iridium complexes bearing asymmetric tridentate ligands.
Novel blue-phosphorescent iridium complexes bearing 1-(2-pyridyl)-3-(N-methylimidazol-2-yl)-4,6-difluorobenzene(LH) as an asymmetric tridentate ligand have been optically resolved into a pair of enantiomers that exhibits opposite circularly polarized luminescence (CPL) spectra.
Ashizawa
Misa
M
Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27 Kasuga, Bunkyo-ku, Tokyo, Japan.
Yang
Lifen
L
Kobayashi
Katsuaki
K
Sato
Hisako
H
Yamagishi
Akihiko
A
Okuda
Fumio
F
Harada
Takunori
T
Kuroda
Reiko
R
Haga
Masa-Aki
MA
D007495:Iridium / Q000737:chemistry*; D008024:Ligands; D008163:Luminescent Measurements; D015394:Molecular Structure; D055095:Optics and Photonics; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010777:Photochemistry
D008024:Ligands; D009942:Organometallic Compounds; D007495:Iridium