title: [Investigation of concentration levels of chromium(VI) in bottled mineral and spring waters by high performance ion chromatography technique with application of postcolumn reaction with 1,5-diphenylcarbazide and VIS detection].
abstract: The aim of this work was optimization and validation of the method of determination of Cr(VI) existing in the form of chromate(VI) in mineral and spring waters by High Performance Ion Chromatography (HPIC) technique with application of postcolumn reaction with 1,5-diphenylcarbazide and VIS detection. Optimization of the method performed with the use of initial apparatus parameters and chromatographic conditions from the Method 218.6 allowed to lowering detection limit for Cr(VI) from 400 ng/l to 2 ng/l. Thanks to very low detection limit achieved it was possible to determine of Cr(VI) concentrations in 25 mineral and spring waters presented at Polish market. In the cases of four mineral and spring waters analyzed, determined Cr(VI) concentrations were below of quantification limit (< 4 ng/l) but simultaneously in another mineral and spring waters the concentrations of chromium(VI) were determined in the range of 5.6 - 1281 ng/l. The fact of existence of different Cr(VI) concentrations in investigated waters could be connected with secondary contamination of mineral and spring waters by chromium coming from metal installations and fittings. One should be underlined that even the highest determined concentration level of chromium(VI) was below of the maximum admissible concentration of total chromium presented in Polish Decree of Minister of Health from April 29th 2004. Therefore after taking into account determined in this work concentration of Cr(VI), the consumption of all waters analyzed in this study does not lead to essential human health risk.
authors.affiliation: Zakład Higieny Komunalnej, Narodowy Instytut Zdrowia Publicznego - Państwowy Zaklad Higieny, 00-791 Warszawa, ul. Chocimska 24. dswiecicka@pzh.gov.pl
authors.forename: Dorota
authors.initials: D
authors.lastname: Swiecicka
authors.forename: Sławomir
authors.initials: S
authors.lastname: Garboś
mesh_terms: D002274:Carcinogens, Environmental / Q000032:analysis*; D002851:Chromatography, High Pressure Liquid / Q000379:methods; D002857:Chromium / Q000032:analysis*; D004160:Diphenylcarbazide; D004784:Environmental Monitoring / Q000379:methods; D006801:Humans; D011044:Poland; D014867:Water / Q000737:chemistry*; D014881:Water Supply / Q000032:analysis
chemical_list: D002274:Carcinogens, Environmental; D014867:Water; D002857:Chromium; C074702:chromium hexavalent ion; D004160:Diphenylcarbazide