title: Catalytic conversion of 1,2-dichlorobenzene using V2O5/TiO2 catalysts by a thermal decomposition process.
abstract: This study examined the catalytic oxidation of 1,2-dichlorobenzene on V(2)O(5)/TiO(2) nanoparticles. The V(2)O(5)/TiO(2) nanoparticles were synthesized by the thermal decomposition of vanadium oxytripropoxide and titanium tetraisopropoxide. The effects of the synthesis conditions, such as the synthesis temperature and precursor heating temperature, were investigated. The specific surface areas of V(2)O(5)/TiO(2) nanoparticles increased with increasing synthesis temperature and decreasing precursor heating temperature. The catalytic oxidation rate of the V(2)O(5)/TiO(2) catalyst formed by thermal decomposition process at a catalytic reaction temperature of 150 and 200 degrees C was 46% and 95%, respectively. As a result, it was concluded that the V(2)O(5)/TiO(2) catalysts synthesized by a thermal decomposition process showed good performance for 1,2-DCB decomposition at a lower temperature.
authors.affiliation: Department of Mechanical Engineering, Graduate School of Hanyang University, Seoul 133-791, Republic of Korea.
authors.forename: Sungmin
authors.initials: S
authors.lastname: Chin
authors.forename: Jongsoo
authors.initials: J
authors.lastname: Jurng
authors.forename: Jae-Heon
authors.initials: JH
authors.lastname: Lee
authors.forename: Seung-Jae
authors.initials: SJ
authors.lastname: Moon
mesh_terms: D000393:Air Pollutants / Q000378:metabolism*; D002384:Catalysis; D002722:Chlorobenzenes / Q000378:metabolism*; D053768:Metal Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D013696:Temperature; D014025:Titanium / Q000737:chemistry*; D017968:Vanadium Compounds / Q000737:chemistry*; D018505:Waste Management / Q000379:methods*; D014961:X-Ray Diffraction
chemical_list: D000393:Air Pollutants; D002722:Chlorobenzenes; D017968:Vanadium Compounds; C009495:titanium dioxide; C004726:2-dichlorobenzene; C066075:vanadium pentoxide; D014025:Titanium