Ferrimagnetic [CoII3(micro3-OH)2(RCO2)4] chains embedded in a laminar hybrid material exhibiting single-chain magnet behaviour.
The ligand, benzophenone-2,4'-dicarboxylate, was used as a polytopic linker and magnetic separator to bridge the inorganic hydroxide-bridged cobat(ii) chain motifs into a laminar inorganic-organic hybrid materials with nearest inter-chain Co(ii)Co(ii) distance of ca. 8.14 A, which exhibits single-chain magnet behaviour.
Hu
Sheng
S
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry/State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, P. R. China.
Yun
Lei
L
Zheng
Yan-Zhen
YZ
Lan
Yan-Hua
YH
Powell
Annie K
AK
Tong
Ming-Liang
ML
D003035:Cobalt / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008024:Ligands; D008280:Magnetics; D009942:Organometallic Compounds / Q000737:chemistry*
D008024:Ligands; D009942:Organometallic Compounds; D003035:Cobalt