title: Heteroatom-controlled kinetics of switchable polyoxometalate frameworks.
abstract: The framework materials [W(72)Mn(II/III)(12)O(268)X(7)](52-/40-) undergo heteroatom (X)-controlled reversible SC-SC redox reactions whereby the Ge-templated framework reduction is fast and reoxidation is slow. The opposite trend is set for the Si-templated framework, and these processes can be followed optically, spectroscopically and crystallographically.
authors.affiliation: WestCHEM Department of Chemistry, Joseph Black Building, University of Glasgow, University Avenue, Glasgow G12 8QQ, UK.
authors.forename: Johannes
authors.initials: J
authors.lastname: Thiel
authors.forename: Chris
authors.initials: C
authors.lastname: Ritchie
authors.forename: Carsten
authors.initials: C
authors.lastname: Streb
authors.forename: De-Liang
authors.initials: DL
authors.lastname: Long
authors.forename: Leroy
authors.initials: L
authors.lastname: Cronin