Powder study of poly[(mu(2)-2,2-dimethylpropane-1,3-diyl diisocyanide)-mu(2)-iodido-silver(I)].
In order to explore the chemistry of the bidentate ligand 2,2-dimethylpropane-1,3-diyl diisocyanide and to investigate the effect of counter-ions on the polymeric structure of (2,2-dimethylpropane-1,3-diyl diisocyanide)silver(I) complexes, the title polymeric compound, [AgI(C(7)H(10)N(2))](n), was synthesized by treatment of 2,2-dimethylpropane-1,3-diyl diisocyanide with AgI. X-ray powder diffraction studies show, as expected, a polymeric structure, similar to the very recently reported Cl(-) and NO(3)(-) analogues [AgX(C(7)H(10)N(2))](n) (X = Cl(-) or NO(3)(-)). In the title structure, the Ag(I) centre is bridged to two adjacent Ag(I) neighbours by bidentate 2,2-dimethylpropane-1,3-diyl diisocyanide ligands via the NC groups to form [Ag{CNCH(2)C(CH(3))(2)CH(2)NC}](n) chains. The iodide counter-ions crosslink the Ag(I) centres of the chains to form a two-dimensional polymeric {[Ag{CNCH(2)C(CH(3))(2)CH(2)NC}]I}(n) network. This study also shows that this bidentate ligand forms similar polymeric structures on treatment with AgX, regardless of the nature of the counter-ion X(-), and also has a strong tendency to form polymeric complexes rather than dimeric or trimeric ones.
Rukiah
Mwaffak
M
Department of Chemistry, Atomic Energy Commission of Syria (AECS), PO Box 6091, Damascus, Syrian Arab Republic. mrukiah@aec.org.sy
Al-Ktaifani
Mahmoud
M