Stable Bis(diisopropylamino)cyclopropenylidene (BAC) as Ligand for Transition Metal Complexes.
Several nickel(0), palladium(II), and rhodium(I) complexes have been prepared using for the first time the stable bis(diisopropylamino)cyclopropenylidene (BAC). Based on single crystal X-ray diffraction studies and spectroscopic data, the structural and electronic properties of these complexes are discussed. Moreover, their similarities and differences with the analogous NHC complexes are emphasized.
Kuchenbeiser
Glenn
G
UCR-CNRS Joint Research Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403, USA.
Donnadieu
Bruno
B
Bertrand
Guy
G