title: Selective capture of water using microporous adsorbents to increase the lifetime of lubricants.
abstract: Long live lubricants: The selective capture of water from lubricants using nanosized microporous aluminophosphate (AEI) and aluminosilicate materials was studied. Nearly 98 % of the moisture was removed from the lubricating oil under ambient conditions, resulting in a significant improvement in the lubricating service lifetime. Moreover, both the lubricant and the microporous sorbents can be recovered and reused.The selective capture of water from lubricants using nanosized microporous aluminophosphate and aluminosilicate materials was studied with an aim to increase the lifetime of the lubricating mineral oil. The amount of water present in oxidized lubricating oil before and after treatment with microporous materials was studied by FTIR spectroscopy and determined quantitatively using the Karl Fischer titration method. Nanosized aluminophosphate revealed a high selectivity for water without adsorbing other additives, in contrast to nanosized aluminosilicates which also adsorb polar oxidation products and ionic additives. About 98 % of the initial moisture could be removed from the lubricating oil under ambient conditions, resulting in a significant improvement in the lubricating service lifetime. Moreover, no by-products are formed during the process and both the lubricant and the sorbents can be recovered and reused, thus the method is environmentally friendly.
authors.affiliation: Laboratoire Catalyse & Spectrochimie, ENSICAEN-Université de Caen-CNRS, 6 boulevard du Maréchal Juin, Caen, France.
authors.forename: Eng-Poh
authors.initials: EP
authors.lastname: Ng
authors.forename: Luc
authors.initials: L
authors.lastname: Delmotte
authors.forename: Svetlana
authors.initials: S
authors.lastname: Mintova
mesh_terms: D000327:Adsorption; D054327:Lubricants / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D008899:Mineral Oil / Q000737:chemistry; D049329:Nanostructures / Q000737:chemistry; D016062:Porosity; D017550:Spectroscopy, Fourier Transform Infrared; D013997:Time Factors; D014867:Water / Q000032:analysis / Q000737:chemistry*
chemical_list: D054327:Lubricants; D014867:Water; D008899:Mineral Oil