Formation of a thermally stable, porous coordination network via a crystalline-to-amorphous-to-crystalline phase transition.
A porous coordination network was cleanly obtained after a crystalline-to-amorphous-to-crystalline phase transition, and the crystal structure was unambiguously solved by ab initio powder X-ray diffraction. After the solid-state phase transition, the porous structure was remarkably stable up to 673 K and capable of reabsorbing various guest molecules, such as aromatic solvents and I(2).
Ohara
Kazuaki
K
Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
Martí-Rujas
Javier
J
Haneda
Tsuyoshi
T
Kawano
Masaki
M
Hashizume
Daisuke
D
Izumi
Fujio
F
Fujita
Makoto
M