Preparation of TiO2, CeO2, and ZrO2 hierarchical structures in "one-pot" reactions.
In this paper, a novel template of carbon foam is used in building hierarchical structures of TiO(2), CeO(2), and ZrO(2). They had multiscale morphologies, from nanowalls, nanoparticles to layer nanostructures. On a hundred-micron scale, the product was a sponge-like material constructed by nanowalls. On a hundred-nanometer scale, the electron microscope images showed that the nanowalls were porous and assembled by polycrystalline nanoparticles. Meanwhile, on one nanometer scale, many nanoparticles exhibited layer nanostructures with about 1.1 nm of thickness and spacing. In mechanism section, the process analysis and characterizations suggested that the hierarchical structures were the combined result of two templates in a "one-pot" reaction. The mesoporous nanowalls were derived from carbon foams, while the layer nanostructures were the replicas of graphite sheets. The method has potential utilizations in preparation of various adsorbent and catalyst.
Zhang
Hui
H
Key Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Graduate School of the Chinese Academy of Sciences, Changchun 130022, China.
Li
Hongfei
H
Li
Wei
W
Meng
Shulan
S
Li
Deqian
D
D002244:Carbon / Q000737:chemistry*; D002563:Cerium / Q000737:chemistry*; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure; D036103:Nanotechnology / Q000379:methods*; D016062:Porosity; D014025:Titanium / Q000737:chemistry*; D015040:Zirconium / Q000737:chemistry*
C009495:titanium dioxide; D002563:Cerium; C030583:ceric oxide; D002244:Carbon; D015040:Zirconium; D014025:Titanium; C028541:zirconium oxide