title: Model systems for flavoenzyme activity: an investigation of the role functionality attached to the C(7) position of the flavin unit has on redox and molecular recognition properties.
abstract: We describe the role functionality attached to the C(7) position of a family of flavin derivatives has in tuning their redox and recognition properties and the subsequent exploitation of two of these derivatives as a three-component electrochemically controllable molecular switch.
authors.affiliation: Glasgow Centre for Physical Organic Chemistry, WestCHEM, Department of Chemistry, Joseph Black Building, University of Glasgow, Glasgow, UK G12 8QQ.
authors.forename: Stuart T
authors.initials: ST
authors.lastname: Caldwell
authors.forename: Louis J
authors.initials: LJ
authors.lastname: Farrugia
authors.forename: Shanika Gunatilaka
authors.initials: SG
authors.lastname: Hewage
authors.forename: Nadiya
authors.initials: N
authors.lastname: Kryvokhyzha
authors.forename: Vincent M
authors.initials: VM
authors.lastname: Rotello
authors.forename: Graeme
authors.initials: G
authors.lastname: Cooke
mesh_terms: D002244:Carbon / Q000737:chemistry*; D018360:Crystallography, X-Ray; D004563:Electrochemistry; D005415:Flavins / Q000737:chemistry*; D008954:Models, Biological; D015394:Molecular Structure; D010084:Oxidation-Reduction
chemical_list: D005415:Flavins; D002244:Carbon