A supramolecular proposal of lignin structure and its relation with the wood properties.
In spite of the great importance of cellulose the lignin is considered the second most abundant substance of the wood. However, little attention has been given it, mainly to wood properties. The lignin as well as other structural compounds (cellulose and hemicelluloses), has obviously an important role on the wood properties, probably due its composition and existent bonds. In general lignins have beta-O-4 (Alkyl Aril Ether) as majoritary bond. This bond in a continued structure form big molecules with spiral conformation as virtual model. Based on this idea, lignins that have high/low beta-O-4 content may have differentiated spiraled structures,suggesting different behaviors on the wood properties,which shows that the lignins (Guaicyl:Syringyl (GS)) of angiosperms, for example, which have higher beta-O-4 content would present higher spiral conformation than gymnosperms lignins(HG). On the other hand HG lignins have chance of being more anchored on the matrix compound than GS lignins. In this context, the beta-O-4 bonds of lignins possibly affect the wood properties, therefore, it is considered relevant for wood technology science discussion.
Abreu
Heber S
HS
Departamento de Produtos Florestais, Instituto de Florestas, Universidade Federal Rural do Rio de Janeiro, Seropédica, RJ, Brasil, 23851-070. Abreu@ufrrj.br
Latorraca
João V F
JV
Pereira
Regina P W
RP
Monteiro
Maria Beatriz O
MB
Abreu
Fábio A
FA
Amparado
Kelysson F
KF
D008031:Lignin / Q000737:chemistry*; D015394:Molecular Structure; D014934:Wood / Q000737:chemistry*
D008031:Lignin