Activation of hydrocarbon C-H bonds by iodosylbenzene: how does it compare with iron(IV)-oxo oxidants?
Combined experimental and theoretical studies on the reactivity of iodosylbenzene (PhIO) show that PhIO is capable of activating weak C-H bonds of hydrocarbons via a hydrogen abstraction mechanism.
Kim
Soo Jeong
SJ
Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750, Korea.
Latifi
Reza
R
Kang
Hye Yeon
HY
Nam
Wonwoo
W
de Visser
Sam P
SP
D002244:Carbon / Q000737:chemistry*; D006838:Hydrocarbons / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D007462:Iodobenzenes / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D016877:Oxidants / Q000737:chemistry*
D006838:Hydrocarbons; D007462:Iodobenzenes; D016877:Oxidants; D002244:Carbon; D006859:Hydrogen; D007501:Iron; C037276:iodosobenzene