Solvent dependent asymmetric hydrogenation with self-assembled catalysts: a combined catalytic, NMR- and IR-study.
For the first time the hydrogen bond based structure of self-aggregated Rh-phosphine complexes in fluorinated alcohols was directly determined, which gives a rationale for the high enantioselectivity observed in the asymmetric hydrogenation.
Shuklov
Ivan A
IA
Leibniz-Institut für Katalyse an der Universität Rostock e.V., A.-Einstein-Str., 29a, 18059, Rostock, Germany.
Dubrovina
Natalia V
NV
Barsch
Enrico
E
Ludwig
Ralf
R
Michalik
Dirk
D
Börner
Armin
A