Fourier-transform microwave spectroscopy of the CCCCl radical.
Pure rotational spectra of the CCCCl radical in a supersonic jet have been observed for the first time by Fourier-transform microwave spectroscopy. The radical was produced by a pulsed electric discharge in a C(2)H(2) and CCl(4) mixture diluted to 0.3% and 0.2% with Ne, respectively. Transitions with spin and hyperfine splittings were observed for two isotopologs, CCC(35)Cl and CCC(37)Cl, in the region from 11.4 GHz for N=2-1 to 34.2 GHz for N=6-5. The molecular constants including the hyperfine coupling constants due to the Cl nucleus have been determined precisely. From the rotational analyses and high-level ab initio calculations, the molecular structure of the CCCCl radical is concluded to be bent in the ground electronic state.
Yoshikawa
Takashi
T
Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo 153-8902, Japan.
Sumiyoshi
Yoshihiro
Y
Endo
Yasuki
Y