A new approach for Fe(III)EDTA reduction in NO(x) scrubber solution using bio-electro reactor.
A new process for the removal of NO(x) by a combined Fe(II)EDTA absorption and microbial reduction has been demonstrated, in which part of the Fe(II)EDTA will be oxidized by oxygen in the flue gas to form Fe(III)EDTA. In former studies, strain FR-2 has been found to reduce Fe(III)EDTA efficiently. Otherwise, it has been reported that bio-electro reactor could efficiently provide a chance for simultaneous denitrification and metal ion removal. Therefore, a use of bio-electro reactor is suggested to promote the reduction of Fe(III)EDTA by strain FR-2 in this paper. The results showed that the concentration of Fe(III)EDTA decreased rapidly when electric current was applied, and that as the current density rose, the Fe(III)EDTA reduction rate increased while followed by a decrease afterward. The formation of the biofilm on the electrode was observed by ESEM (Environmental Scan Electro-Microscope). In addition, the Fe(III)EDTA reduction rate obviously decreased with the existence of NaNO(2).
Mi
Xu-Hong
XH
Department of Environmental Engineering, Zhejiang University (Yuquan Campus), Hangzhou, Zhejiang 310027, China.
Gao
Lin
L
Zhang
Shi-Han
SH
Cai
Ling-Lin
LL
Li
Wei
W
D019149:Bioreactors / Q000382:microbiology*; D004492:Edetic Acid / Q000378:metabolism; D004563:Electrochemistry / Q000295:instrumentation / Q000379:methods*; D004926:Escherichia coli / Q000145:classification* / Q000378:metabolism*; D005290:Ferric Compounds / Q000378:metabolism*; D009569:Nitric Oxide / Q000737:chemistry* / Q000378:metabolism*; D010084:Oxidation-Reduction; D012996:Solutions; D013045:Species Specificity
D005290:Ferric Compounds; D012996:Solutions; D009569:Nitric Oxide; D004492:Edetic Acid; C019179:Fe(III)-EDTA