title: Fluoride-free cross coupling using vinyldisiloxanes.
abstract: Vinyldisiloxanes equilibrate with the corresponding silanolates under basic conditions and subsequently undergo palladium catalysed cross coupling with aryl/heteroaryl iodides and bromides.
authors.affiliation: Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK CB2 1EW.
authors.forename: Hannah F
authors.initials: HF
authors.lastname: Sore
authors.forename: Christine M
authors.initials: CM
authors.lastname: Boehner
authors.forename: Simon J F
authors.initials: SJ
authors.lastname: MacDonald
authors.forename: David
authors.initials: D
authors.lastname: Norton
authors.forename: David J
authors.initials: DJ
authors.lastname: Fox
authors.forename: David R
authors.initials: DR
authors.lastname: Spring
mesh_terms: D002384:Catalysis; D006842:Hydrocarbons, Brominated / Q000737:chemistry; D006847:Hydrocarbons, Iodinated / Q000737:chemistry; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry; D012833:Siloxanes / Q000737:chemistry*; D013237:Stereoisomerism; D013267:Stilbenes / Q000138:chemical synthesis / Q000737:chemistry
chemical_list: D006842:Hydrocarbons, Brominated; D006847:Hydrocarbons, Iodinated; D012833:Siloxanes; D013267:Stilbenes; D010165:Palladium