Deprotection of homoallyl ((h)Allyl) derivatives of phenols, alcohols, acids, and amines.
The homoallyl moiety, (h)Allyl, is presented as a general protecting group for several functionalities. It can be chemoselectively removed via a sequential, one-pot cross-metathesis/elimination sequence.
Lipshutz
Bruce H
BH
Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, USA. lipshutz@chem.ucsb.edu
Ghorai
Subir
S
Leong
Wendy Wen Yi
WW
D000143:Acids / Q000737:chemistry*; D000438:Alcohols / Q000737:chemistry*; D000498:Allyl Compounds / Q000737:chemistry*; D000588:Amines / Q000737:chemistry*; D004952:Esters / Q000737:chemistry; D015394:Molecular Structure; D010636:Phenols / Q000737:chemistry*
D000143:Acids; D000438:Alcohols; D000498:Allyl Compounds; D000588:Amines; D004952:Esters; D010636:Phenols