Electrically-controlled near-infrared chiroptical switching of enantiomeric dinuclear ruthenium complexes.
Enantiomerically pure dinuclear ruthenium complexes with 1,2-dicarbonylhydrazide as a bridging ligand are optically active in the visible and near infrared spectral regions depending on the oxidation states of the metal centers and are useful as an electrochemically driven near infrared chiroptical switch.
Li
Duo
D
Department of Chemistry, Carleton University, 1125 Colonel By Drive, Ottawa, Ontario, Canada K1S 5B6.
Wang
Zhi Yuan
ZY
Ma
Dongge
D