One-dimensional counterion gas between charged surfaces: exact results compared with weak- and strong-coupling analyses.
We evaluate exactly the statistical integral for an inhomogeneous one-dimensional (1D) counterion-only Coulomb gas between two charged boundaries and from this compute the effective interaction, or disjoining pressure, between the bounding surfaces. Our exact results are compared to the limiting cases of weak and strong couplings which are the same for 1D and three-dimensional (3D) systems. For systems with a large number of counterions it is found that the weak-coupling (mean-field) approximation for the disjoining pressure works perfectly and that fluctuations around the mean-field in 1D are much smaller than in 3D. In the case of few counterions it works less well and strong-coupling approximation performs much better as it takes into account properly the discreteness of the counterion charges.
Dean
David S
DS
Laboratoire de Physique Théorique (IRSAMC), Université de Toulouse, UPS, Toulouse, France. dean@irsamc.ups-tlse.fr
Horgan
Ron R
RR
Naji
Ali
A
Podgornik
Rudolf
R
D005740:Gases / Q000737:chemistry*; D007477:Ions; D008956:Models, Chemical; D015233:Models, Statistical; D055672:Static Electricity
D005740:Gases; D007477:Ions