Two edge-sharing MnII4MnIII6 supertetrahedra give an anisotropic S = 28 +/- 1 MnII6MnIII11 complex.
A complex with a [Mn(II)(6)Mn(III)(11)] core results via formal fusion of two isotropic Mn(II)(4)Mn(III)(6) supertetrahedra along a common edge leading to a high spin ground state anisotropic system showing Mvs. H hysteresis loops below 1 K.
Nayak
Sanjit
S
Institut für Anorganische Chemie der Universität Karlsruhe, 76131 Karlsruhe, Germany.
Beltran
Lianne M C
LM
Lan
Yanhua
Y
Clérac
Rodolphe
R
Hearns
Nigel G R
NG
Wernsdorfer
Wolfgang
W
Anson
Christopher E
CE
Powell
Annie K
AK