An end-on azide-bridged antiferromagnetic single-chain magnet involving spin canting and field-induced two-step magnetic transitions.
Two-step magnetic transitions: An azide-bridged 1D Mn(III) coordination polymer with a unique single end-on mode was prepared; it displayed atypical antiferromagnetic couplings and field-induced two-step magnetic transitions (see figure). The spin-canted phenomenon in the antiferromagnetic chain complex plays a pivotal role in establishing the slow magnetic relaxation.
Yoon
Jung Hee
JH
Department of Chemistry, Korea University, Seoul 136-713, Korea.
Ryu
Dae Won
DW
Kim
Hyoung Chan
HC
Yoon
Sung Won
SW
Suh
Byoung Jin
BJ
Hong
Chang Seop
CS