Fluoride-free cross coupling using vinyldisiloxanes.
Vinyldisiloxanes equilibrate with the corresponding silanolates under basic conditions and subsequently undergo palladium catalysed cross coupling with aryl/heteroaryl iodides and bromides.
Sore
Hannah F
HF
Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK CB2 1EW.
Boehner
Christine M
CM
MacDonald
Simon J F
SJ
Norton
David
D
Fox
David J
DJ
Spring
David R
DR
D002384:Catalysis; D006842:Hydrocarbons, Brominated / Q000737:chemistry; D006847:Hydrocarbons, Iodinated / Q000737:chemistry; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry; D012833:Siloxanes / Q000737:chemistry*; D013237:Stereoisomerism; D013267:Stilbenes / Q000138:chemical synthesis / Q000737:chemistry
D006842:Hydrocarbons, Brominated; D006847:Hydrocarbons, Iodinated; D012833:Siloxanes; D013267:Stilbenes; D010165:Palladium