Luminol chemiluminescence under interaction with heteropoly acids.
Interaction of luminol with phosphomolybdic, phosphovanadomolybdic and silicomolybdic acids was studied by examination of chemiluminescence spectra, measurement of ESR spectra, investigation of reaction order, and elucidation of inhibition effects. A scheme of the reaction mechanism is proposed.
Zui
Oleg
O
A.V. Dumansky Institute of Colloid Chemistry and Water Chemistry of the National Academy of Sciences of Ukraine, 03680 Kyiv-142, Vernadsky Prospect 42, Ukraine. olegzuy@hotmail.com
Takahashi
Hiroki
H
Hori
Toshitaka
T
Hinoue
Teruo
T
D000143:Acids; D015392:Chemistry, Inorganic; D004578:Electron Spin Resonance Spectroscopy; D007700:Kinetics; D008163:Luminescent Measurements / Q000379:methods*; D008165:Luminol; D008982:Molybdenum / Q000737:chemistry*; D010756:Phosphoric Acids / Q000737:chemistry*
D000143:Acids; D010756:Phosphoric Acids; D008165:Luminol; D008982:Molybdenum; C003125:phosphomolybdic acid