title: Solvent dependent asymmetric hydrogenation with self-assembled catalysts: a combined catalytic, NMR- and IR-study.
abstract: For the first time the hydrogen bond based structure of self-aggregated Rh-phosphine complexes in fluorinated alcohols was directly determined, which gives a rationale for the high enantioselectivity observed in the asymmetric hydrogenation.
authors.affiliation: Leibniz-Institut für Katalyse an der Universität Rostock e.V., A.-Einstein-Str., 29a, 18059, Rostock, Germany.
authors.forename: Ivan A
authors.initials: IA
authors.lastname: Shuklov
authors.forename: Natalia V
authors.initials: NV
authors.lastname: Dubrovina
authors.forename: Enrico
authors.initials: E
authors.lastname: Barsch
authors.forename: Ralf
authors.initials: R
authors.lastname: Ludwig
authors.forename: Dirk
authors.initials: D
authors.lastname: Michalik
authors.forename: Armin
authors.initials: A
authors.lastname: Börner