Ruthenium-catalyzed direct arylations of N-aryl 1,2,3-triazoles with aryl chlorides as electrophiles.
Ring ring ring: Ruthenium-catalyzed direct arylations of N-aryl 1,2,3-triazoles with chlorides as arylating reagents proceed efficiently with an in situ generated complex derived from phosphane PCy(3) in N-methyl-2-pyrrolidone (NMP) as solvent.
Ackermann
Lutz
L
Institut für Organische und Biomolekulare Chemie, Georg-August-Universität, Göttingen, Germany. lutz.ackermann@chemie.uni-goettingen.de
Born
Robert
R
Vicente
Rubén
R
D002384:Catalysis; D002712:Chlorides / Q000737:chemistry; D055772:Green Chemistry Technology / Q000379:methods; D006841:Hydrocarbons, Aromatic / Q000737:chemistry*; D012428:Ruthenium; D012997:Solvents; D014230:Triazoles / Q000737:chemistry*
D002712:Chlorides; D006841:Hydrocarbons, Aromatic; D012997:Solvents; D014230:Triazoles; D012428:Ruthenium