Arylation and vinylation of alpha-diazocarbonyl compounds with boroxines.
An alternative approach for alpha-arylation and alpha-vinylation of carbonyl compounds is described: reaction between aryl- or vinylboroxines with alpha-diazocarbonyl compounds leads to the formation of alpha-arylated or alpha-vinylated carbonyl compounds under mild conditions.
Peng
Cheng
C
Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.
Zhang
Wei
W
Yan
Guobing
G
Wang
Jianbo
J
D001896:Boron Compounds / Q000737:chemistry*; D002384:Catalysis; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D014753:Vinyl Compounds
D001896:Boron Compounds; D007659:Ketones; D014753:Vinyl Compounds