A non-classical copper carbonyl on a tri-alkene hydrocarbon support.
Two rare copper complexes, a tri-alkene adduct [Cu(ttt-cdt)(FSbF(5))] and a non-classical carbon monoxide complex [Cu(ttt-cdt)(CO)][SbF(6)] with a high CO stretching frequency ([small nu, Greek, macron](CO) = 2160 cm(-1)), have been isolated using trans,trans,trans-1,5,9-cyclododecatriene (ttt-cdt) ligand.
Fianchini
Mauro
M
Department of Chemistry and Biochemistry, The University of Texas at Arlington, Arlington, 76019, Texas, USA.
Cundari
Thomas R
TR
DeYonker
Nathan J
NJ
Dias
H V Rasika
HV