Coordination of arsine ligands as a general synthetic approach to rare examples of arsenic-antimony and arsenic-bismuth bonds.
Tertiary arsines form stable adducts with trichlorostibine and with cationic antimony and bismuth centers, defining coordination chemistry as a general synthetic approach to the formation of rare As-Sb and As-Bi bonds. A series of compounds containing As-Sb and As-Bi bonds define key milestones in the systematic development of interpnictogen compounds.
Conrad
Eamonn
E
Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, B3H 4J3 Canada.
Burford
Neil
N
McDonald
Robert
R
Ferguson
Michael J
MJ