title: Relaying stereochemistry through aromatic ureas: 1,9 and 1,15 remote stereocontrol.
abstract: The well-defined conformation of an N,N'-diarylurea allows a chiral sulfinyl substituent to influence diastereoselectivity in the formation of new stereogenic centres up to 14 bond lengths away.
authors.affiliation: School of Chemistry, University of Manchester, Oxford Road, Manchester, UK M13 9PL. Clayden@man.ac.uk
authors.forename: Jonathan
authors.initials: J
authors.lastname: Clayden
authors.forename: Mark
authors.initials: M
authors.lastname: Pickworth
authors.forename: Lyn H
authors.initials: LH
authors.lastname: Jones
mesh_terms: D018360:Crystallography, X-Ray; D008956:Models, Chemical; D008968:Molecular Conformation; D013237:Stereoisomerism; D013696:Temperature; D014508:Urea / Q000737:chemistry*
chemical_list: D014508:Urea