Bis(zinc porphyrin) bridged by benzo orthocarbonates as a conformational switch under regulation of DABCO and a Cu+ ion.
A tweezer-type bis(zinc porphyrin) bridged by benzo orthocarbonates was synthesized and applied as a molecular conformational switch under regulation of DABCO and a Cu(+) ion. The switch property has been confirmed by (1)H NMR, UV-vis spectral titration, and HR-MS spectra method.
Zhou
Zaichun
Z
School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China.
Cao
Chenzhong
C
Yin
Zhiqing
Z
Liu
Qiuhua
Q