Mesostructured material based on [Re6Te8(CN)6]4- cluster and Mn(2+): a rational synthesis of hexagonal nonoxidic mesoscale material.
A new nonoxidic mesostructured material with highly ordered hexagonal symmetry, [C(16)H(33)N(CH(3))(3)](3)Mn(0.5)[Re(6)Te(8)(CN)(6)], has been obtained through supramolecular assembly of [Re(6)Te(8)(CN)(6)](4-) clusters in the presence of a transition metal cation, Mn(2+), with cetyltrimethylammonium bromide as a liquid crystal template under hydrothermal conditions.
Vien
Vo
V
Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750, Korea.
Suh
Min-Jung
MJ
Huh
Seong
S
Kim
Youngmee
Y
Kim
Sung-Jin
SJ
D002412:Cations; D050866:Liquid Crystals / Q000737:chemistry; D008345:Manganese / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D012211:Rhenium / Q000737:chemistry*; D013691:Tellurium / Q000737:chemistry*; D013696:Temperature; D014961:X-Ray Diffraction
D002412:Cations; D009942:Organometallic Compounds; D008345:Manganese; D012211:Rhenium; D013691:Tellurium