Transformation of a layered zinc phosphite to a three-dimensional open-framework structure with intersecting 16- and 12-ring channels.
A new layered zinc phosphite, H(2)tmdp x Zn(3)(HPO(3))(4) (tmdp = 4,4'-trimethylenedipiperidine), was prepared in a flux of phosphorous acid without the addition of water as a solvent. The compound could be transformed into a new three-dimensional open-framework zinc phosphite, Zn(2)(H(2)O)(4)(HPO(3))(2) x H(2)O, with intersecting 16- and 12-ring channels at room temperature.
Lin
Zhien
Z
Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse, D-35043 Marburg, Germany.
Nayek
Hari Pada
HP
Dehnen
Stefanie
S
D018360:Crystallography, X-Ray; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D017905:Phosphites / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry; D013696:Temperature
C520106:4,4-trimethylenedipyridine; D009942:Organometallic Compounds; D017905:Phosphites; D011725:Pyridines; C518868:zinc phosphite