A new route for substitution of the bridging acetate on the oxo-centered triruthenium acetate cluster.
Deacetoxylation of the oxo-centered triruthenium acetate cluster by acetyl chloride or triethylsilyl chloride led to the formation of a versatile precursor [Ru(3)O(OAc)(5)(Cl)(4-methylpyridine)(2)(CNt-Bu)], whose chloro ligand was readily substituted by other bridging ligands, i.e. alkoxides, carboxylates or sulfides.
Yuge
Hidetaka
H
Department of Chemistry, School of Science, Kitasato University, Kitasato, Sagamihara, Kanagawa, 228-8555, Japan.
Asahi
Shin-ichiro
S
Miyamoto
T Ken
TK
D000085:Acetates / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry; D012428:Ruthenium / Q000737:chemistry*; D013237:Stereoisomerism
D000085:Acetates; D008024:Ligands; D009942:Organometallic Compounds; D011725:Pyridines; D012428:Ruthenium