Spin-polarized structures and solid-state NMR spectroscopy of paramagnetic compounds.
On an atomic scale and with high sensitivity, solid-state NMR spectroscopy can provide information about the electronic spin density and coupling mechanisms in paramagnetic compounds. The picture shows how the hyperfine splitting collapses through relaxation. Insights into which compounds are suitable and which approximations have to be made are given.
Schmedt auf der Günne
Jörn
J
Department Chemie und Biochemie, Ludwig-Maximilians-Universität München, Butenandtstrasse 5-13 (Haus D), 81377 München, Germany. gunnej@cup.uni-muenchen.de