title: Imidazolylsulfonates: electrophilic partners in cross-coupling reactions.
abstract: Aryl imidazolylsulfonates participate as electrophilic coupling partners in palladium-mediated cross-coupling reactions. The aryl imidazolylsulfonates display good stability while maintaining good reactivity in a variety of palladium-catalyzed coupling reactions. Imidazolylsulfonates are a practical and economic alternative to triflates.
authors.affiliation: Synthetic Chemistry, Chemical & Physical Sciences, Schering-Plough Corporation, 1011 Morris Avenue, Union, New Jersey 07083, USA.
authors.forename: Jennifer
authors.initials: J
authors.lastname: Albaneze-Walker
authors.forename: Ravinder
authors.initials: R
authors.lastname: Raju
authors.forename: Jennifer A
authors.initials: JA
authors.lastname: Vance
authors.forename: Andrew J
authors.initials: AJ
authors.lastname: Goodman
authors.forename: Michael R
authors.initials: MR
authors.lastname: Reeder
authors.forename: Jing
authors.initials: J
authors.lastname: Liao
authors.forename: Mathew T
authors.initials: MT
authors.lastname: Maust
authors.forename: Patrick A
authors.initials: PA
authors.lastname: Irish
authors.forename: Peter
authors.initials: P
authors.lastname: Espino
authors.forename: David R
authors.initials: DR
authors.lastname: Andrews
mesh_terms: D001190:Arylsulfonates / Q000737:chemistry*; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D007093:Imidazoles / Q000737:chemistry*; D008698:Mesylates / Q000737:chemistry; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*
chemical_list: D001190:Arylsulfonates; D007093:Imidazoles; D008698:Mesylates; D010165:Palladium