Diastereoselective synthesis of chiral diporphyrins via intramolecular meso-meso oxidative coupling.
Diastereoselective syntheses of meso-meso linked diporphyrins were achieved via intramolecular chiral induction. The structures and conformations were analyzed by CD, UV, NMR, and computational calculations.
Ouyang
Qin
Q
State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China.
Zhu
Yi-Zhou
YZ
Li
Yun-Chao
YC
Wei
Hui-Bo
HB
Zheng
Jian-Yu
JY
D009682:Magnetic Resonance Spectroscopy; D008665:Metalloporphyrins / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D010084:Oxidation-Reduction; D011166:Porphyrins / Q000138:chemical synthesis* / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet; D013237:Stereoisomerism; D015032:Zinc / Q000737:chemistry
D008665:Metalloporphyrins; D011166:Porphyrins; D015032:Zinc