title: Control of pore size and functionality in isoreticular zeolitic imidazolate frameworks and their carbon dioxide selective capture properties.
abstract: Five new crystalline zeolitic imidazolate frameworks (ZIFs), ZIF-78 to -82, were prepared from zinc(II) nitrate and mixtures of 2-nitroimidazole and five different functionalized imidazoles and were found to have the GME topology. These structures, along with three previously reported GME ZIFs, constitute a series of highly porous materials with Brunauer-Emmet-Teller surface areas ranging from 620 to 1730 m(2)/g. The pore diameters and apertures vary incrementally from 7.1 to 15.9 A and 3.8 to 13.1 A, respectively, and the functionalities decorating the pores vary from polar cyano- and nitro- groups to nonpolar alkyl groups. The variability expressed in these materials makes them highly attractive for study as gas-separation media. Selectivity values calculated for separation of CO(2) and CH(4) predict that the ZIFs with polar functionality, ZIF-78 (10.6:1) and -82 (9.6:1), retain CO(2) gas to a greater degree than the other members of the GME series and BPL-activated carbon. These predictions are borne out in dynamic breakthrough studies, which confirm the increased capacity of ZIF-78 and -82 and demonstrate the promise of this class of materials.
authors.affiliation: Center for Reticular Chemistry, Department of Chemistry and Biochemistry, University of California Los Angeles, 607 East Charles E. Young Drive, Los Angeles, California 90095, USA.
authors.forename: Rahul
authors.initials: R
authors.lastname: Banerjee
authors.forename: Hiroyasu
authors.initials: H
authors.lastname: Furukawa
authors.forename: David
authors.initials: D
authors.lastname: Britt
authors.forename: Carolyn
authors.initials: C
authors.lastname: Knobler
authors.forename: Michael
authors.initials: M
authors.lastname: O'Keeffe
authors.forename: Omar M
authors.initials: OM
authors.lastname: Yaghi