Dynamic structural changes of pentacopper(II) chains supported by N6-donor ligands.
Elastic pentacopper molecular chains, [Cu5(panapy)4X2] (X=Cl (), Br ()) and [Cu5(panapy)4]X'2 (X'=BF4 (), PF6 ()), were prepared using a naphthyridine-modulated N6-donor ligand, panapy2-, and showed magnetically coupled, dynamic rearrangement of five Cu(II) ions switched by the presence/absence of halide termination.
Takemura
Yukie
Y
Department of Chemistry, Faculty of Science, Nara Women's University, Kitauoya-higashi-machi, Nara, 630-8506, Japan.
Nakajima
Takayuki
T
Tanase
Tomoaki
T
Usuki
Miho
M
Takenaka
Hiroe
H
Goto
Eri
E
Mikuriya
Masahiro
M