title: A thermal 6pi electrocyclization strategy towards taiwaniaquinoids. First enantiospecific synthesis of (-)-taiwaniaquinone G.
abstract: The first route towards taiwaniaquinoid terpenes bearing an A/B trans-configuration has been developed through a sequence which includes a thermal 6pi electrocyclization.
authors.affiliation: Departamento de Química Orgánica, Facultad de Ciencias, Instituto de Biotecnología, Universidad de Granada, 18071 Granada, Spain. eamt@ugr.es
authors.forename: Enrique
authors.initials: E
authors.lastname: Alvarez-Manzaneda
authors.forename: Rachid
authors.initials: R
authors.lastname: Chahboun
authors.forename: Eduardo
authors.initials: E
authors.lastname: Cabrera
authors.forename: Esteban
authors.initials: E
authors.lastname: Alvarez
authors.forename: Ali
authors.initials: A
authors.lastname: Haidour
authors.forename: Jose Miguel
authors.initials: JM
authors.lastname: Ramos
authors.forename: Ramón
authors.initials: R
authors.lastname: Alvarez-Manzaneda
authors.forename: Mohammed
authors.initials: M
authors.lastname: Hmamouchi
authors.forename: Hakima
authors.initials: H
authors.lastname: Es-Samti
mesh_terms: D003500:Cyclization; D004224:Diterpenes / Q000138:chemical synthesis* / Q000737:chemistry; D004583:Electrons; D013237:Stereoisomerism; D013696:Temperature
chemical_list: D004224:Diterpenes; C539836:taiwaniaquinone G