Sorption of p-nitrophenol by anion-cation modified palygorskite.
A series of anion-cation modified palygorskites were prepared by microwave irradiation, and characterized with FT-IR. Compared with natural palygorskite, the p-nitrophenol sorption capacity with anion-cation modified palygorskite was significantly improved. The maximum sorption capacity (137.74 mg g(-1)) was obtained with the mass ratio 1:4 and 3:10 of hexadecyltrimethylammonium bromide to sodium dodecyl sulfate and the surfactant to palygorskite of at 313 K. The sorption equilibrium was in accordance with the Langmuir isothermal sorption equations. Thermodynamic function calculated showed that the sorption was a spontaneous and exothermic process. Free energy of the sorption increased with the increase of the temperature. The sorption of p-nitrophenol followed the pseudo-second-order process (sorption rate constant: 0.00453 mg(-1)min(-1)).
Chang
Yue
Y
College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, Gansu, China. cy1126@nwnu.edu.cn
Lv
Xueqian
X
Zha
Fei
F
Wang
Yonggang
Y
Lei
Ziqiang
Z
D000327:Adsorption; D000838:Anions; D002412:Cations; D000077286:Cetrimonium; D002593:Cetrimonium Compounds / Q000737:chemistry; D007700:Kinetics; D017616:Magnesium Compounds / Q000737:chemistry*; D009596:Nitrophenols / Q000737:chemistry*; D017655:Silicon Compounds / Q000737:chemistry*; D012967:Sodium Dodecyl Sulfate / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D013501:Surface-Active Agents / Q000737:chemistry; D013816:Thermodynamics
D000838:Anions; D002412:Cations; D002593:Cetrimonium Compounds; D017616:Magnesium Compounds; D009596:Nitrophenols; D017655:Silicon Compounds; D013501:Surface-Active Agents; D012967:Sodium Dodecyl Sulfate; C026325:attapulgite; C024836:4-nitrophenol; D000077286:Cetrimonium