title: Bidirectional chemo-switching of spin state in a microporous framework.
abstract: The ins and outs of spin: Using the microporous coordination polymer {Fe(pz)[Pt(CN)(4)]} (1, pz=pyrazine), incorporating spin-crossover subunits, two-directional magnetic chemo-switching is achieved at room temperature. In situ magnetic measurements following guest vapor injection show that most guest molecules transform 1 from the low-spin (LS) state to the high-spin (HS) state, whereas CS(2) uniquely causes the reverse HS-to-LS transition.
authors.affiliation: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan. ohba@sbchem.kyoto-u.ac.jp
authors.forename: Masaaki
authors.initials: M
authors.lastname: Ohba
authors.forename: Ko
authors.initials: K
authors.lastname: Yoneda
authors.forename: Gloria
authors.initials: G
authors.lastname: Agustí
authors.forename: M Carmen
authors.initials: MC
authors.lastname: Muñoz
authors.forename: Ana B
authors.initials: AB
authors.lastname: Gaspar
authors.forename: José A
authors.initials: JA
authors.lastname: Real
authors.forename: Mikio
authors.initials: M
authors.lastname: Yamasaki
authors.forename: Hideo
authors.initials: H
authors.lastname: Ando
authors.forename: Yoshihide
authors.initials: Y
authors.lastname: Nakao
authors.forename: Shigeyoshi
authors.initials: S
authors.lastname: Sakaki
authors.forename: Susumu
authors.initials: S
authors.lastname: Kitagawa