title: Synthesis of orthorhombic Mo-V-Sb oxide species by assembly of pentagonal Mo6O21 polyoxometalate building blocks.
abstract: Mix and match: The pentagonal [Mo(6)O(21)](n-) polyoxomolybdate building block assembles with other sources of Mo, V, and Sb ions to form an orthorhombic Mo-V-Sb oxide. The first single-crystal X-ray analysis of an orthorhombic Mo-V-based oxide, a promising catalyst for light alkane selective oxidation known as the "M1 phase", revealed the structure of the compound.
authors.affiliation: Catalysis Research Center, Hokkaido University, N-21, W-10, Sapporo, 001-0021, Japan. sadakane09@hiroshima-u.ac.jp
authors.forename: Masahiro
authors.initials: M
authors.lastname: Sadakane
authors.forename: Keiko
authors.initials: K
authors.lastname: Yamagata
authors.forename: Katsunori
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authors.lastname: Kodato
authors.forename: Keisuke
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authors.lastname: Endo
authors.forename: Koshiro
authors.initials: K
authors.lastname: Toriumi
authors.forename: Yoshiki
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authors.lastname: Ozawa
authors.forename: Tomoji
authors.initials: T
authors.lastname: Ozeki
authors.forename: Takuro
authors.initials: T
authors.lastname: Nagai
authors.forename: Yoshio
authors.initials: Y
authors.lastname: Matsui
authors.forename: Norihito
authors.initials: N
authors.lastname: Sakaguchi
authors.forename: William D
authors.initials: WD
authors.lastname: Pyrz
authors.forename: Douglas J
authors.initials: DJ
authors.lastname: Buttrey
authors.forename: Douglas A
authors.initials: DA
authors.lastname: Blom
authors.forename: Thomas
authors.initials: T
authors.lastname: Vogt
authors.forename: Wataru
authors.initials: W
authors.lastname: Ueda