Nanometre-sized titanium dioxide-catalyzed reactions of nitric oxide with aliphatic cyclic and aromatic amines.
Activated on the surface of nanometre-sized TiO2, NO gas can easily react with aliphatic cyclic amines and aryl free radicals at RT under atmospheric pressure to offer NONOates and cupferron sodiums, respectively.
Huang
Zhangjian
Z
Center of Drug Discovery, Department of Inorganic Chemistry, China Pharmaceutical University, Nanjing 210009, PR China.
Zhang
Yihua
Y
Fang
Lei
L
Zhang
Zhiguo
Z
Lai
Yisheng
Y
Ding
Ye
Y
Cao
Fengqi
F
Zhang
Ji
J
Peng
Sixun
S
D000588:Amines / Q000737:chemistry*; D002384:Catalysis; D009682:Magnetic Resonance Spectroscopy; D053768:Metal Nanoparticles; D009569:Nitric Oxide / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*; D014961:X-Ray Diffraction
D000588:Amines; C009495:titanium dioxide; D009569:Nitric Oxide; D014025:Titanium