title: Kinetic resolution of indolines by pd-catalyzed asymmetric allylic amination.
abstract: The kinetic resolution of indolines was realized via a Pd-catalyzed allylic substitution reaction by using Trost's chiral ligand L10, affording optically active indolines and N-allylated indolines in high yields and high enantioselectivities with an S factor up to 59, which provided the first example for the kinetic resolution of nucleophiles via a transition-metal-catalyzed allylic substitution reaction.
authors.affiliation: State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China.
authors.forename: Xue Long
authors.initials: XL
authors.lastname: Hou
authors.forename: Bao Hui
authors.initials: BH
authors.lastname: Zheng