Functionalization of hexakis methanofullerene malonate crown-ethers: promising octahedral building blocks for molecular networks.
Hexaazido and hexaiodo macrocyclic methanofullerenes undergo high-yielding sixfold click reactions or sixfold Heck, Sonogashira and Suzuki cross-coupling reactions, respectively, to yield all organic building blocks for higher molecular architectures.
Pierrat
Philippe
P
Institut für organische Chemie, Universität Karlsruhe (TH), Fritz-Haber-Weg 6, 76131, Karlsruhe, Germany.
Vanderheiden
Sylvia
S
Muller
Thierry
T
Bräse
Stefan
S