Residue-free wines: fate of some quinone outside inhibitor (QoI) fungicides in the winemaking process.
The fate of three fungicide residues (fenamidone, pyraclostrobin, and trifloxystrobin) from vine to wine was studied to evaluate the decay ratio and the influence of the technological process. The aim of this work was to identify pesticides that can degrade rapidly or be eliminated together with byproduct (lees and cake) of the winemaking process to obtain wine free of residues. The disappearance rate on grapes was calculated as pseudo-first-order kinetics, and the half-life (t(1/2)) was in the range from 5.4 +/- 1.9 to 12.2 +/- 1.2 days. The mechanism of dissipation of the three quinone outside inhibitor (QoI) fungicides was studied using different model systems. It was observed that the main mechanism responsible for disappearance was photodegradation. For active ingredients (ai) the half-lives of fenamidone, pyraclostrobin, and trifloxystrobin were 10.2 +/- 0.8, 20.1 +/- 0.1, and 8.6 +/- 1.0 h, respectively, whereas for formulation higher half-lives were observed when epicuticular waxes were present (from 13.8 +/- 0.2 to 26.6 +/- 0.1 h). After winemaking, fenamidone, pyraclostrobin, and trifloxystrobin residues were not detected in the wine, but they were present in the cake and lees. This was due to the adsorption of pesticide residues to the solid parts, which are always eliminated at the end of the alcoholic fermentation. The data obtained in these experiments suggest that these three active ingredients could be used in a planning process to obtain residue-free wines.
Garau
Vincenzo Luigi
VL
Dipartimento di Tossicologia, Universita di Cagliari, Cagliari, Italy. vlgarau@unica.it
De Melo Abreu
Susana
S
Caboni
Pierluigi
P
Angioni
Alberto
A
Alves
Arminda
A
Cabras
Paolo
P
D000085:Acetates / Q000032:analysis / Q000737:chemistry; D002219:Carbamates / Q000032:analysis / Q000737:chemistry; D005638:Fruit / Q000737:chemistry; D005659:Fungicides, Industrial / Q000032:analysis* / Q000737:chemistry*; D006207:Half-Life; D006358:Hot Temperature; D048288:Imidazolines / Q000032:analysis / Q000737:chemistry; D007097:Imines / Q000032:analysis / Q000737:chemistry; D008689:Methacrylates / Q000032:analysis / Q000737:chemistry; D010777:Photochemistry; D011720:Pyrazoles / Q000032:analysis / Q000737:chemistry; D000073739:Strobilurins; D027843:Vitis / Q000737:chemistry; D014920:Wine / Q000032:analysis*
D000085:Acetates; D002219:Carbamates; D005659:Fungicides, Industrial; D048288:Imidazolines; D007097:Imines; D008689:Methacrylates; D011720:Pyrazoles; D000073739:Strobilurins; C513428:pyrachlostrobin; C540355:fenamidone; C467051:trifloxystrobin