Silver-catalysed Doyle-Kirmse reaction of allyl and propargyl sulfides.
The silver-catalysed Doyle-Kirmse reaction of propargyl and allyl sulfides with diazo compounds is disclosed. The carbon-carbon bond forming process proceeds with a range of substituents and functionality under mild conditions.
Davies
Paul W
PW
School of Chemistry, University of Birmingham, Edgbaston, Birmingham, UK B15 2TT.
Albrecht
Sébastien J-C
SJ
Assanelli
Giulio
G
D000480:Alkynes / Q000737:chemistry*; D000498:Allyl Compounds / Q000737:chemistry*; D001391:Azo Compounds / Q000737:chemistry; D002384:Catalysis; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D013237:Stereoisomerism; D013440:Sulfides / Q000138:chemical synthesis* / Q000737:chemistry*
D000480:Alkynes; D000498:Allyl Compounds; D001391:Azo Compounds; D009942:Organometallic Compounds; D013440:Sulfides; D012834:Silver