Synthesis and isolation of a stable, axially-chiral seven-membered N-heterocyclic carbene.
A chiral seven-membered N-heterocyclic carbene (NHC) has been synthesized from its phenol adduct (NHC-HOPh) by a novel base-induced alpha-elimination method, and its donor strength has been determined from the IR stretching frequencies of the NHC-Rh(CO)(2)Cl complex.
Scarborough
Christopher C
CC
Guzei
Ilia A
IA
Stahl
Shannon S
SS
D018360:Crystallography, X-Ray; D006571:Heterocyclic Compounds / Q000737:chemistry*; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry / Q000302:isolation & purification*; D012238:Rhodium / Q000737:chemistry; D013237:Stereoisomerism
D006571:Heterocyclic Compounds; D009942:Organometallic Compounds; C030011:carbene; D012238:Rhodium; D008697:Methane