title: Catalytic electrochemistry of a [NiFeSe]-hydrogenase on TiO2 and demonstration of its suitability for visible-light driven H2 production.
abstract: A [NiFeSe]-hydrogenase able to produce H(2) in the presence of O(2) forms the basis of a hybrid enzyme-TiO(2) nanoparticle system with a co-attached synthetic Ru photosensitiser for visible-light driven H(2) production at room temperature from neutral water under non-strictly anaerobic conditions on the bench.
authors.affiliation: Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, UK OX1 3QR.
authors.forename: Erwin
authors.initials: E
authors.lastname: Reisner
authors.forename: Juan C
authors.initials: JC
authors.lastname: Fontecilla-Camps
authors.forename: Fraser A
authors.initials: FA
authors.lastname: Armstrong
mesh_terms: D002384:Catalysis; D004563:Electrochemistry; D006859:Hydrogen / Q000737:chemistry*; D006864:Hydrogenase / Q000737:chemistry* / Q000528:radiation effects; D008027:Light; D053768:Metal Nanoparticles / Q000737:chemistry*; D010084:Oxidation-Reduction; D014025:Titanium / Q000737:chemistry*
chemical_list: C009495:titanium dioxide; D006859:Hydrogen; D014025:Titanium; C058560:nickel-iron-selenium hydrogenase; D006864:Hydrogenase