Reductive quenching of pyridine linked porphyrins by phenol: a case of proton coupled electron transfer.
PCET is reported for free-base meso-(pyridyl)porphyrins, a pure organic system in dichloromethane solution, by employing UV/Vis and fluorescence spectroscopic techniques.
Prashanthi
Suthari
S
Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology, Uppal Road, Tarnaka, 500607, Hyderabad, India.
Bangal
Prakriti Ranjan
PR
D004579:Electron Transport; D010084:Oxidation-Reduction; D019800:Phenol / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry*; D011522:Protons; D011725:Pyridines / Q000737:chemistry*
D011166:Porphyrins; D011522:Protons; D011725:Pyridines; D019800:Phenol; C023666:pyridine