title: Enantio- and diastereoselective tandem zn-promoted brook rearrangement/ene-allene carbocyclization reaction.
abstract: The zinc-catalyzed addition of various alkynes to acylsilanes followed by a Zn-Brook rearrangement and either the Zn-ene-allene or Zn-yne-allene cyclization led to the enantio- and diastereoselective formation of carbocycles in a single-pot operation.
authors.affiliation: Mallat Family Laboratory of Organic Chemistry, Schulich Faculty of Chemistry, and the Lise Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, 32 000 Haifa, Israel.
authors.forename: Rozalia
authors.initials: R
authors.lastname: Unger
authors.forename: Fritz
authors.initials: F
authors.lastname: Weisser
authors.forename: Nicka
authors.initials: N
authors.lastname: Chinkov
authors.forename: Amnon
authors.initials: A
authors.lastname: Stanger
authors.forename: Theodore
authors.initials: T
authors.lastname: Cohen
authors.forename: Ilan
authors.initials: I
authors.lastname: Marek