Noncovalent interactions of Ni+ with N-donor ligands (pyridine, 4,4'-dipyridyl, 2,2'-dipyridyl, and 1,10-phenanthroline): collision-induced dissociation and theoretical studies.
Kinetic-energy-dependent collision-induced dissociation (CID) of complexes of a variety of N-donor ligands (N-L) with Ni(+), Ni(+)(N-L)(x), is studied using guided ion beam tandem mass spectrometry. The N-donor ligands investigated include: pyridine, 4,4'-dipyridyl, 2,2'-dipyridyl, and 1,10-phenanthroline. For most of the Ni(+)(N-L)(x) complexes, CID results in endothermic loss of a single neutral N-L ligand as the primary dissociation pathway. Sequential dissociation of additional N-L ligands is observed at elevated energies for the pyridine and 4,4'-dipyridyl complexes containing more than one ligand. The cross-section thresholds for the primary dissociation pathways are interpreted to yield 0 and 298 K bond dissociation energies (BDEs) of the Ni(+)(N-L)(x) complexes after accounting for the effects of multiple ion-neutral collisions, the kinetic and internal energy distributions of the reactants, and their lifetimes for dissociation. Density functional theory calculations at the B3LYP/6-311+G(2d,2p)//B3LYP/6-31G* level are performed to obtain model structures, molecular parameters, and energetics for the neutral N-L ligands and the Ni(+)(N-L)(x) complexes. In general, theory is found to overestimate the strength of binding to the first N-L ligand, and underestimate the strength of binding to additional ligands. Trends in the sequential BDEs of the Ni(+)(N-L)(x) complexes are examined and compared to complexes of Ni(+), to several other ligands previously investigated. The trends in the sequential BDEs are primarily determined by the valence electronic configuration and the effects of sd-hybridization of Ni(+) but are also influenced by repulsive ligand-ligand interactions. Natural bond orbital analyses indicate that the binding in these complexes is primarily noncovalent.
Rannulu
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Department of Chemistry, Wayne State University, Detroit, Michigan 48202, USA.
Rodgers
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MT