A small cationic donor-acceptor iridium complex with a long-lived charge-separated state.
A cationic cyclometalated iridium complex with a triarylamine donor attached to the primary ligand sphere showed long-lived (0.04 and 1.7 micros) charge-separated states after photoexcitation which are due to a combined Marcus inverted region effect and spin-selection rules.
Geiss
Barbara
B
Institut für Organische Chemie, Am Hubland, Würzburg, 97074, Germany.
Lambert
Christoph
C