Semiconducting neutral microstructures fabricated by coordinative self-assembly of intramolecular charge-transfer tetrathiafulvalene derivatives.
A new class of tetrathiafulvalene (TTF)-based microstructures fabricated by coordinative self-assembly has been successfully prepared by a solution process. The morphology of the TTF coordination polymers is readily tuned by the variation of metal ions. Upon incorporation of Pb(2+) and Zn(2+) ions, one-dimensional (1D) wirelike microstructures and spherical polymer particles were achieved, respectively. These results indicate that the coordinative approach pursued in this work, in which the building blocks of 1 are linked in a coordination polymer chain by association with metal ions, is an efficient and versatile approach to produce more mechanically robust micro- and nanometer-sized coordination polymer materials. More interestingly, the neutral coordination polymers are conductive and magnetic at room temperature without external manipulation. Such conductivity is reminiscent of the behavior of the neutral conductive TTF in single crystals.
Geng
Yan
Y
Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
Wang
Xiao-Jun
XJ
Chen
Bin
B
Xue
Hai
H
Zhao
Yao-Peng
YP
Lee
Shuittong
S
Tung
Chen-Ho
CH
Wu
Li-Zhu
LZ