title: Molecular actuator: redox-controlled clam-like motion in a bichromophoric electron donor.
abstract: The one-electron oxidation of tetramethoxydibenzobicyclo[4.4.1]undecane (4) prompts it to undergo a clam-like electromechanical actuation into a cofacially pi-stacked conformer as established by (i) electrochemical analysis, (ii) by the observation of the intense charge-resonance transition in the near IR region in its cation radical spectrum, and (iii) by X-ray crystallographic characterization of the isolated cation radical salt (4(+*) SbCl(6)(-)).
authors.affiliation: Department of Chemistry, Marquette University, P.O. Box 1881, Milwaukee, Wisconsin 53201, USA.
authors.forename: Vincent J
authors.initials: VJ
authors.lastname: Chebny
authors.forename: Ruchi
authors.initials: R
authors.lastname: Shukla
authors.forename: Sergey V
authors.initials: SV
authors.lastname: Lindeman
authors.forename: Rajendra
authors.initials: R
authors.lastname: Rathore