1D Infinite silver(i) chains reside in the big cavities built by the novel p-sulfonatocalix[4]arene-trisilver blocks.
A novel luminescent inclusion complex, {[(C4AS)(2)Ag(3)(mu-2,2'-bpy)(2)(2,2'-bpy)(2)] [Ag(5)(mu-2,2'-bpy)(4)(2,2'-bpy)(4)].20H(2)O}(n) () (2,2'-bpy = 2,2'-bipyridine, C4AS = p-sulfonatocalix[4]arene), with an unusual framework is reported: the parallel 1D infinite silver(i) chains separated by the water belts reside in the big cavities of the p-sulfonatocalix[4]arene-trisilver blocks.
Xiong
Kecai
K
Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China.
Wu
Mingyan
M
Zhang
Qingfu
Q
Wei
Wei
W
Yang
Ming
M
Jiang
Feilong
F
Hong
Maochun
M