title: Isocyanide-based two-step three-component keteneimine formation.
abstract: The addition of isocyanides to acyl chlorides (Isocyanide-Nef reaction) leads to imidoyl chlorides which can later be treated with trialkylphosphites to afford new keteneimines in a Perkow-type reaction. The whole sequence may be performed without any solvent, and the resulting keteneimine may easily be converted to phosphorylated tetrazoles and triazoles.
authors.affiliation: Laboratoire Chimie et Procedes, Ecole Nationale Superieure de Techniques Avancees, 32 Bd Victor, 75739 Paris Cedex 15, France.
authors.forename: Didier
authors.initials: D
authors.lastname: Coffinier
authors.forename: Laurent
authors.initials: L
authors.lastname: El Kaim
authors.forename: Laurence
authors.initials: L
authors.lastname: Grimaud