title: Coupling centrifuge modeling and laser ablation inductively coupled plasma mass spectrometry to determine contaminant retardation in clays.
abstract: Quantifying the retardation (Rd) of reactive solutes as they migrate through low-permeability clay-rich media is difficult, thus motivating this study to assess the viability of combining centrifuge modeling and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) techniques. An influent solution containing Cl-, trace metals, and lanthanide species flowed at 1.0 mL x h(-1) through an undisturbed clay-rich core sample (33 mm diameter x 50 mm long) mounted in a UFA Beckman centrifuge operating at 3000 rpm (N factor = 876 g). During the 87 day experiment the hydraulic conductivity of the core was 3.4 x 10(-10) m x s(-1). Effluent breakthrough data indicate the Rd of Tl to be 10; incomplete breakthrough (non-steady-state) data for 145Nd and 171Yb suggest Rd values of >>75 and >>85, respectively. At the completion of the transport experiment, longitudinal sections of the core solid were analyzed for 145Nd and 171Yb using a Cetac laser ablation system coupled with an ICP-MS. The longitudinal core sections yielded Rd values of >10000 for 145Nd and 171Yb. This study demonstrates coupling these techniques can provide Rd values for a wide range of reactive solutes with relatively rapid testing of small-scale, low hydraulic conductivity core samples.
authors.affiliation: Department of Geological Sciences, University of Saskatchewan, Saskatoon, Saskatchewan, S7N 5E2, Canada. w.timms@wrl.unsw.edu.au
authors.forename: Wendy
authors.initials: W
authors.lastname: Timms
authors.forename: M Jim
authors.initials: MJ
authors.lastname: Hendry
authors.forename: Jason
authors.initials: J
authors.lastname: Muise
authors.forename: Robert
authors.initials: R
authors.lastname: Kerrich