A porous coordination polymer with accessible metal sites and its complementary coordination action.
Broken switch: Guest-accessible metal sites are generated on the pore surface of a porous coordination polymer (see figure) through the complementary coordination-bond rearrangement in a single-crystal-to-single-crystal fashion, which is triggered by the removal of coordinated water.
Sakamoto
Hirotoshi
H
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
Matsuda
Ryotaro
R
Bureekaew
Sareeya
S
Tanaka
Daisuke
D
Kitagawa
Susumu
S