Laser-induced atomic fragment fluorescence spectroscopy: a facile technique for molecular spectroscopy of spin-forbidden states.
Spectra of spin-forbidden and spin-allowed transitions in the mixed b (3)Pi(u) approximately A (1)Sigma(u)(+) state of Na(2) are measured separately by two-photon excitation using a single tunable dye laser. The two-photon excitation produces Na(*)(3p) by photodissociation, which is easily and sensitively detected by atomic fluorescence. At low laser power, only the A (1)Sigma(u)(+) state is excited, completely free of triplet excitation. At high laser power, photodissociation via the intermediate b (3)Pi(u) triplet state becomes much more likely, effectively "switching" the observations from singlet spectroscopy to triplet spectroscopy with only minor apparatus changes. This technique of perturbation-assisted laser-induced atomic fragment fluorescence may therefore be especially useful as a general vehicle for investigating perturbation-related physics pertinent to the spin-forbidden states, as well as for studying allowed and forbidden states of other molecules.
Zhang
Qun
Q
Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China. qunzh@ustc.edu.cn
Chen
Yang
Y
Keil
Mark
M