Hydrated HCl clusters, HCl(H2O)(1-3), in helium nanodroplets: studies of free OH vibrational stretching modes.
In this work, infrared laser spectroscopy in helium droplets is used to study the solvation of HCl with small water clusters. Clusters of HCl(H(2)O)(n) with n = 1-3 and (HCl)(2)H(2)O have been identified in the free OH stretching spectral range of 3680-3820 cm(-1). The assignment of the infrared vibrational bands of the clusters is aided by ab initio calculations.
Skvortsov
Dmitry
D
Department of Chemistry, University of Southern California, Los Angeles, California 90089, USA.
Lee
Seung Jun
SJ
Choi
Myong Yong
MY
Vilesov
Andrey F
AF