Benzo-1,3,2-diazaphospholide and benzo-1,3,2-diazaphospholium: an isoelectronic aromatic anion-cation pair.
Isoelectronic benzo-1,3,2-diazaphospholium cations and benzo-1,3,2-diazaphospholide anions were prepared from the same phosphazane precursor; both species display according to computational studies similar aromaticity as the neutral benzo-1,3,2-diazaphosphole but are chemically more stable due to their ionic nature.
Schmid
Dirk
D
Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70550 Stuttgart, Germany.
Loscher
Sebastian
S
Gudat
Dietrich
D
Bubrin
Denis
D
Hartenbach
Ingo
I
Schleid
Thomas
T
Benko
Zoltán
Z
Nyulászi
László
L