An iron carbonyl pyridonate complex related to the active site of the [Fe]-hydrogenase (Hmd).
A mononuclear iron bis(carbonyl) pyridonate complex (1), which exhibits several common structural features with the active site of the iron-sulfur cluster-free [Fe]-hydrogenase, was synthesized and characterized. Spectroscopic data of 1 suggests a 2+ oxidation state for the Fe ion in the [Fe]-hydrogenase. Complex 1 serves as a precursor to other hydrogenase models.
Obrist
Blaise V
BV
Laboratory of Inorganic Synthesis and Catalysis, Institute of Chemical Sciences and Engineering, Ecole Polytechnique Federale de Lausanne, ISIC-LSCI, BCH 3305, Lausanne CH 1015, Switzerland.
Chen
Dafa
D
Ahrens
Anne
A
Schünemann
Volker
V
Scopelliti
Rosario
R
Hu
Xile
X