Long-range solid-state ordering and high geometric distortions induced in phthalocyanines by small fluoroalkyl groups.
Electron-withdrawing alpha-CF(3) groups sterically induce severe geometric distortions and long-range solid-state ordering in protio and catalytically active micro-oxo iron phthalocyanine.
Gorun
Sergiu M
SM
Department of Chemistry & Environmental Science, New Jersey Institute of Technology, Newark, New Jersey 07102, USA. gorun@njit.edu
Rathke
Jerome W
JW
Chen
Michael J
MJ