title: Blue shifting C-H...O hydrogen bonded complexes between chloroform and small cyclic ketones: ring-size effects on stability and spectral shifts.
abstract: Blue-shifting C-H...O hydrogen bonded complexes between chloroform and three small cyclic ketones (cyclohexanone, cyclopentanone, and cyclobutanone) have been identified by use of FTIR spectroscopy in CCl(4) solution at room temperature. The shifts of the C-H stretching fundamental of chloroform (nu(C-H)) in the said three complexes are +1, +2, and +5 cm(-1), respectively, and the complexation results in enhancement of the nu(C-H) transition intensity in all three cases. The 1:1 stoichiometry of the complexes is suggested by identifying distinct isosbestic points between the carbonyl stretching (nu(C=O)) fundamentals of the monomers and corresponding complexes for spectra measured with different chloroform to ketone concentrations. The nu(C=O) bands in the three complexes are red-shifted by 8, 19, and 6 cm(-1), and apparently have no correlation with the respective blue shifts of the nu(C-H) bands. Spectral analysis reveals that the complex with cyclohexanone is most stable, and the stability decreases with the ring size of the cyclic ketones. A qualitative explanation of the relative stabilities of the complexes is presented by correlating the hydrogen bond acceptor abilities of the carbonyl groups with the ring size of the cyclic ketones. Quantum mechanical calculations at the DFT/B3LYP/6-311++G(d,p) and MP2/6-31+G(d) levels were performed for predictions of the shapes of the complexes, electronic structure parameters of C-H (donor) and C=O (acceptor) groups, intermolecular interaction energies, spectral shifts, and evolution of those properties when the hydrogen bond distance between the donor-acceptor moieties is scanned. The results show that the binding energies of the complexes are correlated with the dipole moments, proton affinity, and n(O) --> sigma*(C-H) hyperconjugative charge transfer abilities of the three ketones. NBO analysis reveals that the blue shifting of the nu(C-H) transition in a complex is the net effect of hyperconjugation and repolarization/rehybridization of the bond under the influence of the electric field of carbonyl oxygen.
authors.affiliation: Department of Physical Chemistry and Raman Center for Atomic Molecular and Optical Sciences, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700032, India.
authors.forename: Anamika
authors.initials: A
authors.lastname: Mukhopadhyay
authors.forename: Moitrayee
authors.initials: M
authors.lastname: Mukherjee
authors.forename: Prasenjit
authors.initials: P
authors.lastname: Pandey
authors.forename: Amit K
authors.initials: AK
authors.lastname: Samanta
authors.forename: Biman
authors.initials: B
authors.lastname: Bandyopadhyay
authors.forename: Tapas
authors.initials: T
authors.lastname: Chakraborty