title: An exceptionally rapid and selective hydrogenation of 2-cyclohexen-1-one in supercritical carbon dioxide.
abstract: Selective hydrogenation of 2-cyclohexen-1-one over Pt-MCM-41 proceeds at a very high rate and produces cyclohexanone with selectivity of 100% in a batch reactor; a marked increase in the reaction rate (TOF) from 2283 min(-1) to 5051 min(-1) is observed on increasing the pressure from 7 MPa to 14 MPa at 40 degrees C.
authors.affiliation: Research Center for Compact Chemical Process, AIST, Tohoku, 4-2-1 Nigatake, Miyagino-ku, Sendai, Japan. c-maya@aist.go.jp
authors.forename: Maya
authors.initials: M
authors.lastname: Chatterjee
authors.forename: Toshirou
authors.initials: T
authors.lastname: Yokoyama
authors.forename: Hajime
authors.initials: H
authors.lastname: Kawanami
authors.forename: Masahiro
authors.initials: M
authors.lastname: Sato
authors.forename: Toshishige
authors.initials: T
authors.lastname: Suzuki