title: Supramolecular photochirogenesis with cyclodextrin-silica composite. enantiodifferentiating photocyclodimerization of 2-anthrancenecarboxylate with mesoporous silica wall-capped gamma-cyclodextrin.
abstract: gamma-Cyclodextrin (CD) immobilized on a mesoporous silica wall to cap one of the CD portals switched the product distribution of photocyclodimerization of 2-anthrancenecarboxylate from head-to-tail to head-to-head with a significant enhancement of the enantiopurity of the chiral head-to-head product.
authors.affiliation: School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240, P R China.
authors.forename: Huibin
authors.initials: H
authors.lastname: Qiu
authors.forename: Cheng
authors.initials: C
authors.lastname: Yang
authors.forename: Yoshihisa
authors.initials: Y
authors.lastname: Inoue
authors.forename: Shunai
authors.initials: S
authors.lastname: Che