Structure and reactivity of a unique Y-shaped tricoordinate bis(silyl)platinum(II)-NHC complex.
Y not? A unique, three-coordinate Y-shaped bis(silyl)platinum(II) complex was isolated and characterized (see structure; C light gray, N blue, Si pink, Pt dark gray). DFT studies on a model system shed light on the nature of this unusual coordination mode for platinum(II).
Berthon-Gelloz
Guillaume
G
Département de Chimie, Université catholique de Louvain, Place Louis Pasteur 1, 1348 Louvain la Neuve, Belgium.
de Bruin
Bas
B
Tinant
Bernard
B
Markó
István E
IE