High-valent manganese(v)-oxo porphyrin complexes in hydride transfer reactions.
Hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) analogues to trans-dioxomanganese(v) porphyrin complexes proceeds via proton-coupled electron transfer, followed by rapid electron transfer.
Lee
Jung Yoon
JY
Department of Chemistry and Nano Science, Centre for Biomimetic Systems, Ewha Womans University, Seoul, 120-750, Korea.
Lee
Yong-Min
YM
Kotani
Hiroaki
H
Nam
Wonwoo
W
Fukuzumi
Shunichi
S