Characterization and photocatalytic property of Pd/TiO2 with the oxidation of gaseous benzene.
Increasing environmental pollution caused by the volatile organic compounds due to their toxicity is a matter of great concern. So it is crucial to develop processes which can destroy these compounds effectively. It has been found that the photocatalytic activity of TiO(2) towards the decomposition of gaseous benzene can be greatly enhanced by loading Pd on the surface of TiO(2). The results show that the optimum palladium loading is 0.25wt.%. The prepared photocatalysts were characterized by XRD, UV-vis diffuse reflectance and XPS. XRD results indicate that no peaks of Pd are detected in the 2theta region from 10 degrees to 90 degrees . Pd/TiO(2) absorbs much more light than TiO(2) in the visible light region. The XPS spectrum shows that there are Ti, O, C and Pd elements on the surface of the Pd/TiO(2), the binding energy values of Ti2p of 0.25%Pd/TiO(2) transfer to a lower value. In addition, the photocatalytic performance of 0.25%Pd/TiO(2) was investigated, the result illustrates that 0.25%Pd/TiO(2) demonstrates 2.32 times the photocatalytic activity of pure TiO(2). The reason of promotion of photocatalytic performance was discussed.
Zhong
Jun Bo
JB
College of Chemistry and Pharmaceutical Engineering, Sichuan University of Science and Engineering, Zi gong 643000, PR China. junbozhong@163.com
Lu
Yan
Y
Jiang
Wei Dong
WD
Meng
Qing Ming
QM
He
Xi Yang
XY
Li
Jian Zhang
JZ
Chen
Yao Qiang
YQ