title: High pressure investigation of alpha-form and CH4-loaded beta-form of hydroquinone compounds.
abstract: The high pressure compression behaviors of two hydroquinone compounds have been investigated using a combination of in situ synchrotron x-ray powder diffraction and Raman spectroscopy up to ca. 7 GPa. The structural integrity of the alpha-form hydroquinone clathrate is maintained throughout the pressure range, whereas the CH(4)-loaded beta-form hydroquinone clathrate decomposes and transforms to a new high pressure phase near 5 GPa. The bulk modulus (K) and its pressure derivative (K(')) of the alpha-form and the CH(4)-loaded beta-form hydroquinones are measured to be 8.2(3) GPa and 8.4(4), and 10(1) GPa and 9(2), respectively, representing one of the most compressible classes of crystalline solids reported in the literature. The corresponding axial compression behaviors, however, show greater contrast between the two hydroquinone compounds; the elastic anisotropy of the alpha-form is only marginal, being K(a):K(c) = 1.08:1, whereas that of the CH(4)-loaded beta-form is rather drastic, being K(a):K(c) = 11.8:1. This is attributed to the different dimensionality of the hydrogen bonding networks between the two structures and might in turn explain the observed structural instability of the beta-form, compared to the alpha-form.
authors.affiliation: Department of Earth System Sciences, Yonsei University, Seoul 120-749, Republic of Korea.
authors.forename: Yongjae
authors.initials: Y
authors.lastname: Lee
authors.forename: Jong-Won
authors.initials: JW
authors.lastname: Lee
authors.forename: Hyun-Hwi
authors.initials: HH
authors.lastname: Lee
authors.forename: Dong Ryeol
authors.initials: DR
authors.lastname: Lee
authors.forename: Chi-Chang
authors.initials: CC
authors.lastname: Kao
authors.forename: Taro
authors.initials: T
authors.lastname: Kawamura
authors.forename: Yoshitaka
authors.initials: Y
authors.lastname: Yamamoto
authors.forename: Ji-Ho
authors.initials: JH
authors.lastname: Yoon