X-ray and hydrogen-bonding properties of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol.
The solid state structure of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol, C17H13N3O, shows that this Mannich base crystallizes forming intermolecular N...HO hydrogen bonds, rather than intramolecular ones. Factors contributing to this choice of hydrogen-bonding mode are discussed. The compound crystallizes in the monoclinic system, P2(1)/c space group, with lattice constants: a = 11.7934(9) A, b = 14.3002(14) A, c = 8.4444(8) A, beta = 106.243(5) deg, V = 1367.3(2) A(3), Z = 4, F(000) = 576, R(1) = 6.96%, wR(2) = 11.4%.
Rivera
Augusto
A
Departamento de Química, Universidad Nacional de Colombia, Ciudad Universitaria, Carrera 30 No. 45-03, Bogotá D.C., Colombia. ariverau@unal.edu.co
Duarte
Yorley
Y
González-Salas
Diego
D
Ríos-Motta
Jaime
J
Zaragoza
Guillermo
G