Reactions of Ar'CrCrAr' with N2O or N3(1-Ad): complete cleavage of the Cr-Cr quintuple interaction.
Reaction of Ar'CrCrAr' (Ar' = C(6)H(3)-2,6-(C(6)H(3)-2,6-Pr(i)(2))(2)) with heterocumulene reagents N(2)O or N(3)(1-Ad) resulted in Ar'Cr(micro-O)(2)Cr(O)Ar' or Ar'Cr(micro(2):eta(1),eta(3)-N(3)(1-Ad))CrAr' which have no metal-metal bonding.
Department of Chemistry, University of California, Davis, California 95616, USA.
Chengbao
C
Ni
Bobby D
BD
Ellis
Gary J
GJ
Long
Philip P
PP
Power