Unexpected nucleophilic behaviour of free-radicals generated from alpha-iodoketones.
The unexpected nucleophilic reactivity of free-radicals generated from alpha-iodoketones is reported; two different procedures, either employing tin or the more environmentally acceptable ethylsulfone-based coupling reagent have been developed.
De Dobbeleer
Corinne
C
Université catholique de Louvain, Département de Chimie, Bâtiment Lavoisier, Place Louis Pasteur 1, B-1348 Louvain-la-Neuve, Belgium.
Pospísil
Jirí
J
De Vleeschouwer
Freija
F
De Proft
Frank
F
Markó
István E
IE
D005609:Free Radicals / Q000737:chemistry*; D007455:Iodine / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*
D005609:Free Radicals; D007659:Ketones; D007455:Iodine