A DFT study of the single electron reduction and silylation of the U-O bond of the uranyl dication in a macrocyclic environment.
A DFT study of the reduction and silylation of the uranyl U-O bond in a macrocyclic complex shows the importance of the initial dipotassiation in THF solution, and a slightly downhill reaction pathway for the oxo group functionalisation.
Laboratoire de Physique et Chimie des Nano-objets, INSA, Université Paul Sabatier, 135 avenue de Rangueil, 31077 Toulouse Cedex, France.
Ahmed
A
Yahia
Polly L
PL
Arnold
Jason B
JB
Love
Laurent
L
Maron