Manganese(III)-promoted reactions for formation of carbon-heteroatom bonds.
Manganese(III) reagent is an important one- electron oxidant for initiation of free-radical reactions and formation of carbon-carbon bonds. The reactions are usually carried out under mild conditions, have high regio- and stereo-selectivities, and good functional group tolerance. Summarized in this article are the developments of manganese (III)-based reactions for the formation of carbon-heteroatom bonds including carbon-oxygen, carbon-phosphorus, carbon-sulfur, and carbon-nitrogen bonds, and their applications for the synthesis of related heterocyclic systems.
Pan
Xiang-Qiang
XQ
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Jiangsu, China.
Zou
Jian-Ping
JP
Zhang
Wei
W
D002244:Carbon / Q000737:chemistry*; D008345:Manganese / Q000737:chemistry*; D009584:Nitrogen / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry; D013455:Sulfur / Q000737:chemistry
D008345:Manganese; D013455:Sulfur; D002244:Carbon; D009584:Nitrogen; D010100:Oxygen