Pyrrolidinium ionic liquid crystals with pendant mesogenic groups.
New ionic liquid crystals (including ionic metallomesogens) based on the pyrrolidinium core are presented. N-Methylpyrrolidine was quaternized with different mesogenic groups connected to a flexible, omega-bromosubstituted alkyl spacer. The length of the flexible alkyl spacer between the cationic head group and the rigid mesogenic group was varied. The substituted pyrrolidinium cations were combined with bromide, bis(trifluoromethylsulfonyl)imide, tetrakis(2-thenoyltrifluoroacetonato)europate(III), and tetrabromouranyl anions. The influence of the type of mesogenic unit, the lengths of the flexible spacer and terminal alkyl chain, the size of the mesogenic group, and the type of anion on the thermotropic mesomorphic behavior was investigated. Furthermore, the phase behavior was thoroughly compared with the previously reported mesomorphism of N-alkyl-N-methylpyrrolidinium salts. Low-ordered smectic A phases of the de Vries type, smectic C phases, higher-ordered smectic F/I phases, as well as crystal smectic phases (E and G, J, H, or K) were observed and investigated by polarizing optical microscopy, differential scanning calorimetry, and powder X-ray diffraction.
Department of Chemistry, Katholieke Universiteit Leuven, Celestijnenlaan 200F, P.O. Box 2404, B-3001 Leuven, Belgium.
Karel
K
Goossens
Kathleen
K
Lava
Peter
P
Nockemann
Kristof
K
Van Hecke
Luc
L
Van Meervelt
Phil
P
Pattison
Koen
K
Binnemans
Thomas
T
Cardinaels