Principal component analysis-adaptive neuro-fuzzy inference systems (ANFISs) for the simultaneous spectrophotometric determination of three metals in water samples.
A spectrophotometric method for the simultaneous determination of Al(III), Co(II) and Ni(II) using Alizarin Red S as a chelating agent was developed. The parameters controlling the behavior of the system were investigated and optimum conditions were selected. The presence of non-linearities was checked using Mallows augmented partial residual plots. To take into account these non-linearities, a principal component analysis-adaptive neuro-fuzzy inference systems (PC-ANFISs) method was used for the analysis of ternary mixtures of Al(III), Co(II) and Ni(II) over the range of 0.05-0.90, 0.05-4.05 and 0.05-0.95 microg mL(-1), respectively. Absorbance data were collected between 370 and 700 nm. The method was applied to accurately and simultaneously determines the content of metal ions in several synthetic mixtures.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas, UNLP, CCT La Plata-CONICET, Diag. 113 y 64, C.C. 16, Suc.4, 1900, La Plata, Argentina. mohammad.godarzi@gmail.com
Mohammad
M
Goodarzi
Alejandro C
AC
Olivieri
Matheus P
MP
Freitas
D000465:Algorithms; D000535:Aluminum / Q000032:analysis*; D000880:Anthraquinones; D002138:Calibration; D002614:Chelating Agents; D003035:Cobalt / Q000032:analysis*; D009532:Nickel / Q000032:analysis*; D025341:Principal Component Analysis; D012680:Sensitivity and Specificity; D013053:Spectrophotometry / Q000379:methods*; D014867:Water / Q000032:analysis*
D000880:Anthraquinones; D002614:Chelating Agents; D014867:Water; C004468:Alizarin Red S; D003035:Cobalt; D009532:Nickel; D000535:Aluminum