The preparation and structure of salty ice VII under pressure.
It is widely accepted that ice, no matter what phase, is unable to incorporate large amounts of salt into its structure. This conclusion is based on the observation that on freezing of salt water, ice expels the salt almost entirely as brine. Here, we show that this behaviour is not an intrinsic physico-chemical property of ice phases. We demonstrate by neutron diffraction that substantial amounts of dissolved LiCl can be built homogeneously into the ice VII structure if it is produced by recrystallization of its glassy (amorphous) state under pressure. Such 'alloyed' ice VII has significantly different structural properties compared with pure ice VII, such as an 8% larger unit cell volume, 5 times larger displacement factors, an absence of a transition to an ordered ice VIII structure and plasticity. Our study suggests that there could be a whole new class of 'salty' high-pressure ice forms.
Klotz
Stefan
S
IMPMC, CNRS-UMR 7590, Université P&M Curie, 75252 Paris, France. Stefan.Klotz@impmc.jussieu.fr
Bove
Livia E
LE
Strässle
Thierry
T
Hansen
Thomas C
TC
Saitta
Antonino M
AM
D007053:Ice; D015394:Molecular Structure; D011312:Pressure; D012965:Sodium Chloride / Q000737:chemistry*
D007053:Ice; D012965:Sodium Chloride