Effect of TMEDA on iron-catalyzed coupling reactions of ArMgX with alkyl halides.
A new reaction mechanism for the iron-catalyzed cross-coupling reaction of ArMgX with alkyl halides using (TMEDA)FeAr(2) and (TMEDA)Fe(Ar)Br is proposed on the basis of the isolation and reaction of these organoiron intermediates.
Noda
Daisuke
D
Institute for Materials Chemistry and Engineering and Graduate School of Engineering Sciences, Kyushu University, Kasuga, Fukuoka 816-8580, Japan.
Sunada
Yusuke
Y
Hatakeyama
Takuji
T
Nakamura
Masaharu
M
Nagashima
Hideo
H