Manganese(III)-promoted reactions for formation of carbon-heteroatom bonds.
Manganese(III) reagent is an important one- electron oxidant for initiation of free-radical reactions and formation of carbon-carbon bonds. The reactions are usually carried out under mild conditions, have high regio- and stereo-selectivities, and good functional group tolerance. Summarized in this article are the developments of manganese (III)-based reactions for the formation of carbon-heteroatom bonds including carbon-oxygen, carbon-phosphorus, carbon-sulfur, and carbon-nitrogen bonds, and their applications for the synthesis of related heterocyclic systems.
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Jiangsu, China.
Xiang-Qiang
XQ
Pan
Jian-Ping
JP
Zou
Wei
W
Zhang
D002244:Carbon / Q000737:chemistry*; D008345:Manganese / Q000737:chemistry*; D009584:Nitrogen / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry; D013455:Sulfur / Q000737:chemistry
D008345:Manganese; D013455:Sulfur; D002244:Carbon; D009584:Nitrogen; D010100:Oxygen