Unusual luminescence enhancement of metallogels of alkynylplatinum(II) 2,6-bis(N-alkylbenzimidazol-2'-yl)pyridine complexes upon a gel-to-sol phase transition at elevated temperatures.
A series of alkynylplatinum(II) complexes of 2,6-bis(N-alkylbenzimidazol-2'-yl)pyridine has been synthesized and characterized by (1)H NMR, IR, FAB mass spectrometry, and elemental analysis; the photophysical properties have also been investigated. All the complexes have been shown to exhibit interesting gelation properties. Scanning electron microscopy (SEM) of the xerogels showed a network of fibrous structures, typical of morphologies of organogels/metallogels. Interestingly, two of the complexes were found to show strong luminescence enhancement upon a gel-to-sol phase transition upon increasing the temperature. This unusual behavior is rarely encountered, as it represents a sharp contrast to that exhibited by other typical thermotropic organogels and metallogels reported so far. Variable-temperature UV-vis and luminescence spectroscopies were performed to probe the gel-to-sol phase transition. Concentration-dependent, variable-temperature, and time-resolved emission studies in dilute benzene solution have also been made to provide further insights into the spectroscopic origin in the sol forms. A quantitative treatment of the system based on the Birks scheme has been performed.
Centre for Carbon-Rich Molecular and Nano-Scale Metal-Based Materials Research, Department of Chemistry, and HKU-CAS Joint Laboratory on New Materials, The University of Hong Kong, Pokfulam Road, Hong Kong.
Anthony Yiu-Yan
AY
Tam
Keith Man-Chung
KM
Wong
Vivian Wing-Wah
VW
Yam
D005782:Gels / Q000737:chemistry; D049449:Luminescence; D009944:Organoplatinum Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D044367:Phase Transition; D011725:Pyridines / Q000737:chemistry*; D013696:Temperature
D005782:Gels; D009944:Organoplatinum Compounds; D011725:Pyridines