Hydride-bromide exchange at an NHC-a new route to brominated alanes and gallanes.
The reaction of [MH(3)(Quinuclidine)] (M = Al or Ga) with an air stable dibrominated N-heterocyclic carbene (NHC) affords the hydride-bromide exchange product [MBr(2)H(NHC)].
Alexander
Sean G
SG
School of Chemistry and Physics, University of Adelaide, Adelaide, SA 5005, Australia.
Cole
Marcus L
ML
Furfari
Samantha K
SK
Kloth
Marc
M