[{(eta(5)-C(5)Me(5))(2)Sm}(4)P(8)]: a molecular polyphosphide of the rare-earth elements.
[{(eta(5)-C(5)Me(5))(2)Sm}(4)P(8)], a molecular polyphosphide of the rare-earth elements having a realgar core structure, was synthesized by a one-electron redox reaction of divalent samarocen and white phosphorus.
Nikolaev Institute of Inorganic Chemistry SB RAS, Prosp. Lavrentieva 3, 630090 Novosibirsk, Russia.
Sergey N
SN
Konchenko
Nikolay A
NA
Pushkarevsky
Michael T
MT
Gamer
Ralf
R
Köppe
Hansgeorg
H
Schnöckel
Peter W
PW
Roesky