Hydrocracking of used cooking oil for biofuels production.
Hydrocracking of used cooking oil is studied as a potential process for biofuels production. In this work several parameters are considered for evaluating the effectiveness of this technology, including hydrocracking temperature, liquid hourly space velocity (LHSV) and days on stream (DOS). Conversion and total biofuels production is favored by increasing temperature and decreasing LHSV. However moderate reaction temperatures and LHSVs are more attractive for diesel production, whereas higher temperatures and smaller LHSVs are more suitable for gasoline production. Furthermore heteroatom (S, N and O) removal increases as hydrocracking temperature increases, with de-oxygenation being particularly favorable. Saturation, however, is not favored with temperature indicating the necessity of a pre-treatment step prior to hydrocracking to enable saturation of the double bonds and heteroatom removal. Finally the impact of extended operation (catalyst life) on product yields and qualities indicates that all reactions are affected yet at different rates.
Bezergianni
Stella
S
Chemical Process Engineering Research Institute, Center for Research and Technology Hellas, Thermi, Thessaloniki, Greece. sbezerg@cperi.certh.gr
Kalogianni
Aggeliki
A
D001674:Bioelectric Energy Sources; D019149:Bioreactors; D001966:Bromine / Q000737:chemistry; D002244:Carbon / Q000032:analysis; D002384:Catalysis; D003247:Conservation of Natural Resources / Q000379:methods*; D003296:Cooking; D005742:Gasoline; D006859:Hydrogen / Q000032:analysis; D009821:Oils / Q000737:chemistry*; D010865:Pilot Projects; D013696:Temperature
D005742:Gasoline; D009821:Oils; D002244:Carbon; D006859:Hydrogen; D001966:Bromine