Structure-property relationships in dimethacrylate networks based on Bis-GMA, UDMA and TEGDMA.
OBJECTIVE
In this work the influence of structural heterogeneity of poly(dimethacrylate)s on mechanical properties was investigated. Rigid aromatic dimethacrylate (Bis-GMA), triethylene glycol dimethacrylate (TEGDMA) and flexible aliphatic urethane dimethacrylate (UDMA) have been chosen for room-temperature homopolymerizations and copolymerizations induced by a camphorquinone/N,N-dimethylaminoethyl methacrylate photoinitiating system.


METHODS
The following mechanical properties of poly(dimethacrylate)s were investigated: flexural modulus, flexural strength, impact strength and hardness. Atomic force microscopy (AFM) and X-ray powder diffraction (XRPD) were used to describe the morphology of polymer networks.


RESULTS
AFM observations showed that the heterogeneity of networks is spatially organized due to the formation of microgels and their agglomeration. Observed agglomerates are unidirectionally oriented, parallel to the direction of polymerization shrinkage. Of all the investigated mechanical properties of poly(dimethacrylate)s, the impact resistance appeared to be the least. The origin of this brittleness could be the presence of heterogeneities which were quantitatively characterized by means of XRPD. The impact resistance was shown to be related to the size of network heterogeneities which is probably influenced by intermolecular interactions, such as hydrogen bonding.


CONCLUSIONS
Differences in monomer structure resulted in significantly different morphology and physical properties of the polymer networks which had been studied. The size and shape of heterogeneities affected the final mechanical properties of the polymers, especially impact resistance. In addition, the combined application of XRPD and AFM techniques can be a successful tool in the analysis of the dimethacrylate network morphology, and finally, in investigations on methacrylate-based dental materials.
Barszczewska-Rybarek
Izabela M
IM
Department of Physical Chemistry and Technology of Polymers, Silesian University of Technology, M. Strzody 9, 44-100 Gliwice, Poland. Izabela.Barszczewska-Rybarek@polsl.pl
D017438:Bisphenol A-Glycidyl Methacrylate; D003799:Dental Stress Analysis; D055119:Elastic Modulus; D005782:Gels / Q000737:chemistry; D006244:Hardness; D055115:Light-Curing of Dental Adhesives; D008689:Methacrylates; D018625:Microscopy, Atomic Force; D015394:Molecular Structure; D018583:Pliability; D011092:Polyethylene Glycols; D011109:Polymethacrylic Acids / Q000737:chemistry*; D011140:Polyurethanes; D055116:Self-Curing of Dental Resins; D014961:X-Ray Diffraction
D005782:Gels; D008689:Methacrylates; D011109:Polymethacrylic Acids; D011140:Polyurethanes; C097103:polyurethane dimethacrylate; C020946:triethylene glycol dimethacrylate; C030613:polymethacrylic acid; D011092:Polyethylene Glycols; D017438:Bisphenol A-Glycidyl Methacrylate