Structural transition of gold nanoclusters: from the golden cage to the golden pyramid.
How nanoclusters transform from one structural type to another as a function of size is a critical issue in cluster science. Here we report a study of the structural transition from the golden cage Au(16)(-) to the pyramidal Au(20)(-). We obtained distinct experimental evidence that the cage-to-pyramid crossover occurs at Au(18)(-), for which the cage and pyramidal isomers are nearly degenerate and coexist experimentally. The two isomers are observed and identified by their different interactions with O(2) and Ar. The cage isomer is observed to be more reactive with O(2) and can be preferentially "titrated" from the cluster beam, whereas the pyramidal isomer has slightly stronger interactions with Ar and is favored in the Au(18)Ar(x)(-) van der Waals complexes. The current study allows the detailed structural evolution and growth routes from the hollow cage to the compact pyramid to be understood and provides information about the structure-function relationship of the Au(18)(-) cluster.
Department of Physics, Washington State University, 2710 University Drive, Richland, Washington 99354, USA.
Wei
W
Huang
Satya
S
Bulusu
Rhitankar
R
Pal
Xiao Cheng
XC
Zeng
Lai-Sheng
LS
Wang
D003198:Computer Simulation; D003460:Crystallization / Q000379:methods*; D006046:Gold / Q000737:chemistry*; D046911:Macromolecular Substances / Q000737:chemistry; D008956:Models, Chemical; D008958:Models, Molecular; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D036103:Nanotechnology / Q000379:methods*; D010316:Particle Size; D013499:Surface Properties
D046911:Macromolecular Substances; D006046:Gold