Synthesis, characterization and real molecule DFT calculations for neutral organogallium(I) aryl dimers and monomers: weakness of gallium-gallium bonds in digallenes and digallynes.
A series of stable aryl gallium(I) terphenyl derivatives was synthesized and characterized spectroscopically, structurally and by density functional calculations. Dimeric structures with trans-bent planar CGaGaC core arrangements were observed for [(GaAr*-4-tBu)(2)] (7, Ar*-4-tBu = C(6)H(2)-2,6(C(6)H(2)-2,4,6-iPr(3))(2)-4-tBu) and [(GaAr*-4-CF(3))(2)] (8, Ar*-4-CF(3) = C(6)H(2)-2,6(C(6)H(2)-2,4,6-iPr(3))(2)-4-CF(3)), whereas monomeric structures featuring one coordinate gallium were observed for the more crowded complexes [:GaAr*-3,5-iPr(2)] (10, Ar*-3,5-iPr(2) = C(6)H-2,6(C(6)H(2)-2,4-6-iPr(3))(2)-3,5-iPr(2)) and [GaAr'-3,5-iPr(2)] (11, Ar'-3,5-iPr(2) = C(6)H-2,6(C(6)H(3)-2,6-iPr(2))(2)-3,5-iPr(2)). Complexes 7 and 8 dissociate to monomers in hydrocarbon solution and their electronic spectra closely resemble those of 10 and 11 as well as those of [Ar'GaGaAr'] (Ar' = C(6)H(3)-2,6(C(6)H(3)-2,6-iPr(3))(2)) and [(GaAr*)(n)] (Ar* = C(6)H(3)-2,6(C(6)H(2)-2,4,6-iPr(3))(2)). The calculations showed that the binding energies of the compounds are weak, resemble closed-shell interactions and average approximately 5 kcal mol(-1), as in [Ar*GaGaAr*] with a lowest value of approximately -2 kcal mol(-1) for monomeric 10 and a highest value approximately 9 kcal mol(-1) for the least crowded species [Ar'GaGaAr']. The weak bonding in the complexes supports the view that the GaGa bonding in the previously published doubly reduced Na(2)[Ar*GaGaAr*] and Na(2)[Ar'GaGaAr'] is also weak and is consistent with approximate single bonding.
Zhu
Zhongliang
Z
University of California, Department of Chemistry, One Shields Avenue, Davis, CA 95616, USA.
Fischer
Roland C
RC
Ellis
Bobby D
BD
Rivard
Eric
E
Merrill
W Alexander
WA
Olmstead
Marilyn M
MM
Power
Philip P
PP
Guo
J D
JD
Nagase
Shigeru
S
Pu
Lihung
L