A novel type of heteropolyoxoanion precursors [[Ca(H2O)]6[P4M6O34]2](12-) (M = WVI, MoVI) constructed by two [P4M6O34](12-) subunits via a rare hexa-calcium cluster.
A novel type of heteropolyoxoanion (HPOA) precursors [[Ca (H(2)O)](6)[P(4)M(6)O(34)](2)](12-) [M = W(VI) (1), Mo(VI) (2)] has been synthesized and structurally characterized, which represents the rare membership of the HPOA family constituted by two early-transition-metal clusters ([P(4)M(6)O(34)](12-)) and a main-group metal cluster of high nuclearity ([Ca(6)](12+)).
Wang
Jingping
J
Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, 475004, Kaifeng, PR China.
Zhao
Junwei
J
Ma
Pengtao
P
Ma
Junchuang
J
Yang
Linping
L
Bai
Yan
Y
Li
Mingxue
M
Niu
Jingyang
J
D000838:Anions / Q000737:chemistry; D002118:Calcium / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D008982:Molybdenum / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry*; D014414:Tungsten / Q000737:chemistry*
D000838:Anions; D010087:Oxides; D008982:Molybdenum; D002118:Calcium; D014414:Tungsten