Significantly enhanced superbroadband near infrared emission in bismuth/aluminum doped high-silica zeolite derived nanoparticles.
Significantly enhanced superbroadband near infrared emission has been realized in bismuth/aluminum doped high-silica zeolite derived nanoparticles. The emission intensity can be easily tailored by the introduction of aluminum. The luminescence lifetime can reach up to 695 micros. The results reveal that the existence of charge imbalance environment caused by [AlOV(4/2)](-) units in host materials is requisite to the formation of infrared-active Bi(+). The finding presents a feasible route to design high-efficient bismuth activated infrared luminescent nanoparticles. These bismuth doped nanoparticles may find applications as superbroadband near infrared nano optical sources.
Department of Electrical and Electronic Engineering, Graduate School of Engineering, Kobe University, Rokkodai, Nada, Kobe 657-8501, Japan. timothyhsun@gmail.com
Hong-Tao
HT
Sun
Takashi
T
Hasegawa
Minoru
M
Fujii
Fumiaki
F
Shimaoka
Zhenhua
Z
Bai
Minoru
M
Mizuhata
Shinji
S
Hayashi
Shigehito
S
Deki
D000535:Aluminum / Q000737:chemistry*; D001729:Bismuth / Q000737:chemistry*; D017076:Computer-Aided Design; D004867:Equipment Design; D019544:Equipment Failure Analysis; D007259:Infrared Rays; D008029:Lighting / Q000295:instrumentation* / Q000379:methods; D053758:Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity; D012822:Silicon Dioxide / Q000737:chemistry*; D013055:Spectrophotometry, Infrared / Q000295:instrumentation* / Q000379:methods; D017641:Zeolites / Q000737:chemistry*
D017641:Zeolites; D012822:Silicon Dioxide; D000535:Aluminum; D001729:Bismuth