Interpretation of the magnetic properties of a compound consisting of cocrystallized Cu(II)(3) and Cu(II)(4) clusters through the targeted synthesis and study of its discrete Cu(II)(4) component.
The use of the binary "blend" of MeCO(2)(-)/pdmH(2) ligands (pdmH(2) = pyridine-2,6-dimethanol) in copper(II) chemistry has provided access to a compound consisting of discrete linear Cu(II)(3) and cubane Cu(II)(4) clusters. The complicated magnetic behavior of the Cu(II)(3) + Cu(II)(4) complex was clarified and interpreted through the designed synthesis of the individual Cu(II)(4) component; a unique 1D (Cu(II)(5))(n) compound containing a Cu(II)(3) subunit, which is structurally similar to the trinuclear cluster in the Cu(II)(3) + Cu(II)(4) compound, was also isolated and structurally characterized.
Stamatatos
Theocharis C
TC
Department of Chemistry, University of Patras, Patras 26504, Greece.
Vlahopoulou
Gina C
GC
Raptopoulou
Catherine P
CP
Terzis
Aris
A
Escuer
Albert
A
Perlepes
Spyros P
SP
D003300:Copper / Q000737:chemistry*; D003460:Crystallization; D008024:Ligands; D008280:Magnetics; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D013696:Temperature
D008024:Ligands; D009942:Organometallic Compounds; D003300:Copper