Reactions of Ar'CrCrAr' with N2O or N3(1-Ad): complete cleavage of the Cr-Cr quintuple interaction.
Reaction of Ar'CrCrAr' (Ar' = C(6)H(3)-2,6-(C(6)H(3)-2,6-Pr(i)(2))(2)) with heterocumulene reagents N(2)O or N(3)(1-Ad) resulted in Ar'Cr(micro-O)(2)Cr(O)Ar' or Ar'Cr(micro(2):eta(1),eta(3)-N(3)(1-Ad))CrAr' which have no metal-metal bonding.
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Chengbao
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Department of Chemistry, University of California, Davis, California 95616, USA.
Ellis
Bobby D
BD
Long
Gary J
GJ
Power
Philip P
PP