Mass transfer in the absorption of SO2 and NO(x) using aqueous euchlorine scrubbing solution.
Attempts have been made to generate euchlorine gas by chlorate-chloride process and to utilize it further to clean up SO2 and NO(x) from the flue gas in a lab scale bubbling reactor. Preliminary experiments were carried out to determine the gas and liquid phase mass transfer coefficients and their correlation equations have been established. Simultaneous removal of SO2 and NO(x) from the simulated flue gas using aqueous euchlorine scrubbing solution has been investigated. Euchlorine oxidized NO into NO2 completely and the later subsequently absorbed into the scrubbing solution in the form of nitrate. SO2 removal efficiency around 100% and NO(x) removal efficiency around 72% were achieved under optimal conditions. Mass balance has been confirmed by analyzing the sulfate, nitrate, euchlorine and chloride ion using ion chromatograph/auto-titrator and comparing it with their corresponding calculated values.
Deshwal
Bal-Raj
BR
Department of Chemistry, A.I.J.H.M. College, Rohtak 124001, Haryana, India. deshwalbr@yahoo.com
Lee
Hyung-Keun
HK
D000042:Absorption; D002713:Chlorine / Q000737:chemistry*; D005740:Gases / Q000737:chemistry; D008970:Molecular Weight; D009566:Nitrates / Q000737:chemistry* / Q000302:isolation & purification; D009573:Nitrites / Q000737:chemistry* / Q000302:isolation & purification; D012996:Solutions; D013458:Sulfur Dioxide / Q000737:chemistry* / Q000302:isolation & purification; D014867:Water / Q000737:chemistry*
D005740:Gases; D009566:Nitrates; D009573:Nitrites; D012996:Solutions; D014867:Water; D013458:Sulfur Dioxide; D002713:Chlorine