Adsorption and thermodynamic properties of the alumina-polyacrylic acid solution system.
Free energies of polyacrylic acid (PAA) adsorption (DeltaG( composite function)) on an alumina (Al(2)O(3)) surface in the temperature range 15-35 degrees C were estimated on the basis of adsorption-desorption measurements of the inorganic radioactive ions (36)Cl, (45)Ca, and (55)Fe. Adsorbing polymer macromolecules caused the desorption process of previously adsorbed radioactive ions. The free energy of Ca-PAA surface complex formation (DeltaG(o)) was estimated to be close to the free energy of Ca(2+) ions adsorption (polymer causes about 50% desorption of these ions). Moreover, a free energy of polymer molecule adsorption increase with the increasing temperature was observed. The obtained values of DeltaG(o) were compared with those calculated from the adsorption data. Additionally, the amount of polymer adsorbed and the thicknesses of polymer adsorption layers were determined in the temperature range 15-35 degrees C. The changes of polymer chain conformation with the temperature increase are responsible for the increase of PAA adsorption as well as thickness of polymer adsorption layers in the studied temperature range.
Wiśniewska
M
M
Department of Radiochemistry and Colloids Chemistry, Faculty of Chemistry, Maria Curie Sklodowska University, M. Curie Sklodowska Sq. 3, 20-031 Lublin, Poland. wisniewska@hektor.umcs.lublin.pl
Chibowski
S
S
Urban
T
T