title: A ligand free and room temperature protocol for Pd-catalyzed Kumada-Corriu couplings of unactivated alkenyl phosphates.
abstract: Kumada-Corriu cross-couplings of nonactivated cyclic and acyclic vinyl phosphates with aryl magnesium reagents afforded a series of 1,1-disubtituted alkenes in good yields for most cases when the reactions were performed at room temperature with the simple palladium salt, PdCl(2), without the presence of phosphine ligands.
authors.affiliation: The Center for Insoluble Protein Structures (inSPIN), Department of Chemistry and the Interdisciplinary Nanoscience Center, Aarhus University, Langelandsgade 140, 8000 Aarhus C, Denmark.
authors.forename: Delphine
authors.initials: D
authors.lastname: Gauthier
authors.forename: Stephan
authors.initials: S
authors.lastname: Beckendorf
authors.forename: Thomas M
authors.initials: TM
authors.lastname: Gøgsig
authors.forename: Anders T
authors.initials: AT
authors.lastname: Lindhardt
authors.forename: Troels
authors.initials: T
authors.lastname: Skrydstrup
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D008024:Ligands; D010165:Palladium / Q000737:chemistry*; D010710:Phosphates / Q000737:chemistry*; D013696:Temperature
chemical_list: D000475:Alkenes; D008024:Ligands; D010710:Phosphates; D010165:Palladium