Pectenotoxins and yessotoxin from Arica Bay, North Chile as determined by tandem mass spectrometry.
Lipophilic phycotoxins were measured by tandem mass spectrometry coupled to liquid chromatography (LC-MS/MS) in size-fractionated plankton samples taken at five stations in Arica Bay, northern Chile in the southern summer 2007/2008. Pectenotoxins-2 (PTX-2), -11 (PTX-11), -2 seco acid (PTX-2sa) and yessotoxin (YTX) were identified by comparison of retention times and collision-induced mass spectra of certified standards and field sample extracts. This is the first report of PTXs and YTX from planktonic samples in Chilean coastal waters.
Krock
Bernd
B
Alfred-Wegener Institut für Polar- und Meeresforschung, 27570 Bremerhaven, Germany. bernd.krock@awi.de
Seguel
Carmen Gloria
CG
Valderrama
Katherinne
K
Tillmann
Urban
U
D002677:Chile; D005663:Furans / Q000032:analysis*; D018942:Macrolides; D008387:Marine Toxins / Q000032:analysis*; D008978:Mollusk Venoms; D035964:Oxocins / Q000032:analysis*; D011714:Pyrans / Q000032:analysis*; D053719:Tandem Mass Spectrometry / Q000379:methods*; D000095702:Polyether Toxins
D005663:Furans; D018942:Macrolides; D008387:Marine Toxins; D008978:Mollusk Venoms; D035964:Oxocins; D011714:Pyrans; C538993:pectenotoxin-11, Dinophysis acuta; D000095702:Polyether Toxins; C098380:pectenotoxin 2; C066632:yessotoxin