Decamethylytterbocene complexes of bipyridines and diazabutadienes: multiconfigurational ground states and open-shell singlet formation.
Partial ytterbium f-orbital occupancy (i.e., intermediate valence) and open-shell singlet formation are established for a variety of bipyridine and diazabutadiene adducts with decamethylytterbocene, (C(5)Me(5))(2)Yb, abbreviated as Cp*(2)Yb. Data used to support this claim include ytterbium valence measurements using Yb L(III)-edge X-ray absorption near-edge structure spectroscopy, magnetic susceptibility, and complete active space self-consistent field (CASSCF) multiconfigurational calculations, as well as structural measurements compared to density functional theory calculations. The CASSCF calculations indicate that the intermediate valence is the result of a multiconfigurational ground-state wave function that has both an open-shell singlet f(13)(pi*)(1), where pi* is the lowest unoccupied molecular orbital of the bipyridine or diazabutadiene ligands, and a closed-shell singlet f(14) component. A number of other competing theories for the unusual magnetism in these materials are ruled out by the lack of temperature dependence of the measured intermediate valence. These results have implications for understanding chemical bonding not only in organolanthanide complexes but also for f-element chemistry in general, as well as understanding magnetic interactions in nanoparticles and devices.
Booth
Corwin H
CH
Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA. chbooth@lbl.gov
Walter
Marc D
MD
Kazhdan
Daniel
D
Hu
Yung-Jin
YJ
Lukens
Wayne W
WW
Bauer
Eric D
ED
Maron
Laurent
L
Eisenstein
Odile
O
Andersen
Richard A
RA