Kinetics of chromium(III) transport through a liquid membrane containing DNNSA as a carrier.
Kinetics of Cr(III) ions transport through a bulk liquid membrane containing dinonylnaphthalenesulfonic acid (DNNSA) as a carrier, flowing over aqueous phases, has been examined. Special attention has been paid to the effect of the membrane's velocity flow on the chromium concentration decrease in a feed phase. For the description of relationships of chromium(III) concentration in particular phases with the time, a model based on the assumption of consecutive first-order reactions was proposed. Satisfactory compatibility of experiments and model results have been obtained both for the membrane flow velocities below 0.0034 m.s(-1) when the interfaces begin to fluctuate slightly and for low initial Cr(III) concentration in the feed phase.
Religa
Paweł
P
Technical University of Radom, Radom, Poland. p.religa@pr.radom.pl
Gawroński
Roman
R
Gierycz
Paweł
P
D002857:Chromium / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D008051:Lipid Bilayers / Q000737:chemistry* / Q000378:metabolism; D008962:Models, Theoretical; D009282:Naphthalenesulfonates / Q000737:chemistry*; D013997:Time Factors
D008051:Lipid Bilayers; D009282:Naphthalenesulfonates; D002857:Chromium