A three-dimensional porous metal-organic framework constructed from two-dimensional sheets via interdigitation exhibiting dynamic features.
A three-dimensional porous metal-organic framework (PCN-18) was constructed through interdigitating two-dimensional grid sheets composed of 4,4'-(anthracene-9,10-diyl)dibenzoate and copper paddlewheel secondary building units, and its dynamic features were evidenced by gas sorption isotherms.
Ma
Shengqian
S
Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, Illinois 60439, USA. sma@anl.gov
Sun
Daofeng
D
Forster
Paul M
PM
Yuan
Daqiang
D
Zhuang
Wenjuan
W
Chen
Yu-Sheng
YS
Parise
John B
JB
Zhou
Hong-Cai
HC