Facile synthesis of polyaniline "sunflowers" with arrays of oriented nanorods.
Polyaniline (PANI) "sunflowers" made of arrays of oriented nanorods were synthesized by chemical oxidative polymerization of aniline in the presence of cetyltrimethylammonium bromide (CTAB) and suitable concentration of HNO3 at about 0 degrees C (ice bath). The reaction conditions, such as the concentration of reagents and reaction temperature were systematically investigated and controlled on the preparation of PANI "sunflowers". The results also suggest that HNO3 probably plays a key role in forming PANI "sunflowers". A possible forming mechanism of the PANI nanostructures is offered.
Wang
Taoqing
T
College of Materials Science and Engineering, Hunan University, Changsha 410082, PR China.
Zhong
Wenbin
W
Ning
Xutao
X
Wang
Yongxin
Y
Yang
Wantai
W
D000814:Aniline Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D000077286:Cetrimonium; D002593:Cetrimonium Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D036103:Nanotechnology / Q000191:economics / Q000379:methods*; D043942:Nanotubes / Q000737:chemistry / Q000648:ultrastructure; D017942:Nitric Acid / Q000138:chemical synthesis / Q000737:chemistry*; D010084:Oxidation-Reduction; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature; D014961:X-Ray Diffraction
D000814:Aniline Compounds; D002593:Cetrimonium Compounds; C416807:polyaniline; D017942:Nitric Acid; D000077286:Cetrimonium