Structural tracking of a bimolecular reaction in solution by time-resolved X-ray scattering.
Molecular movies: Time-resolved X-ray scattering provides direct structural information on an electronically excited complex while it is formed in the bimolecular reaction between excited octahydrogen[tetrakis-mu-diphosphito-1kappaP:2kappaP'-diplatinate](4-) (PtPOP*) and thallium ions. In the exciplex one thallium(I) and two platinum(II) ions are found to be collinear.
Haldrup
Kristoffer
K
Centre for Molecular Movies, Department of Chemistry and Niels Bohr Institute, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen, Denmark.
Christensen
Morten
M
Cammarata
Marco
M
Kong
Qingyu
Q
Wulff
Michael
M
Mariager
Simon O
SO
Bechgaard
Klaus
K
Feidenhans'l
Robert
R
Harrit
Niels
N
Nielsen
Martin M
MM