title: Dechlorination reaction of hexachlorobenzene with calcium oxide at 300-400 degrees C.
abstract: Hexachlorobenzene (HCB) was thermally treated with calcium oxide (CaO) at 300-400 degrees C. Analyses of chloride ions and residual HCB confirmed that a dechlorination reaction had occurred. The dechlorination mechanism was investigated with a series of analytical methods including X-ray fluorescence (XRF), X-ray diffraction (XRD), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS). The final products detected were CaCO(3) by XRD and Raman spectroscopy, amorphous carbon by Raman spectroscopy, and CaCl(2) by XPS. The newly produced species of CaCO(3) and amorphous carbon were thought to be the ultimate fate of the C element of HCB. After identification of the final dechlorination products, we can conclude that the reaction of HCB with CaO at 300-400 degrees C is through a dechlorination/polymerization pathway, which is induced by electron transfer. An overall reaction formula for HCB reaction with CaO was proposed and was energetically quite favorable. The results are helpful for the further comprehension of the reaction mechanism for thermal dechlorination of PCDD/Fs in CaO rich matrices.
authors.affiliation: Department of Environmental Science and Engineering, Tsinghua University, Beijing 100084, China. gaoxingbao00@mails.tsinghua.edu.cn
authors.forename: Xingbao
authors.initials: X
authors.lastname: Gao
authors.forename: Wei
authors.initials: W
authors.lastname: Wang
authors.forename: Xiao
authors.initials: X
authors.lastname: Liu
mesh_terms: D002119:Calcium Carbonate; D002122:Calcium Chloride; D017610:Calcium Compounds / Q000737:chemistry*; D004785:Environmental Pollutants / Q000737:chemistry; D052918:Environmental Restoration and Remediation / Q000379:methods; D054879:Halogenation; D006581:Hexachlorobenzene / Q000737:chemistry*; D006358:Hot Temperature; D010087:Oxides / Q000737:chemistry*; D000072317:Polychlorinated Dibenzodioxins / Q000031:analogs & derivatives / Q000737:chemistry; D012989:Soil Pollutants / Q000737:chemistry
chemical_list: D017610:Calcium Compounds; D004785:Environmental Pollutants; D010087:Oxides; D000072317:Polychlorinated Dibenzodioxins; D012989:Soil Pollutants; D006581:Hexachlorobenzene; C016538:lime; D002119:Calcium Carbonate; D002122:Calcium Chloride