Palladium nanoparticle-catalyzed C-N bond formation. A highly regio- and stereoselective allylic amination by allyl acetates.
Palladium nanoparticles, generated in situ from the reaction of palladium(II) chloride, have been demonstrated to be an efficient catalyst for C-N bond formation. A variety of aliphatic and aromatic amines have been allylated by substituted and unsubstituted allyl acetates in high yields by using palladium nanoparticles in the presence of a base without any ligand. The allylations are highly regio- and stereoselective.
Adak
Laksmikanta
L
Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Kolkata-700 032, India.
Chattopadhyay
Kalicharan
K
Ranu
Brindaban C
BC
D000085:Acetates / Q000737:chemistry*; D000498:Allyl Compounds / Q000737:chemistry*; D000586:Amination; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D053768:Metal Nanoparticles / Q000737:chemistry*; D009584:Nitrogen / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism; D013379:Substrate Specificity
D000085:Acetates; D000498:Allyl Compounds; D010165:Palladium; D002244:Carbon; C498551:allyl acetate; D009584:Nitrogen