Pursuit of oxidation behavior for conjugated polyenoyl glycerols and establishment of their novel oxidation prevention method.
Although conjugated oils are paid much attentions to their interesting physiological properties such as anticancer, anti-arteriosclerosis, anti-hypertension activities, loss in body fat etc, there is few information on their oxidation behavior. In the present work, their oxidation behavior and oxidation prevention method were evaluated to utilize as functional foods or drugs. As results, an oxidation behavior of conjugated oils was different from that of corresponding non-conjugated oils, and conjugated oils were supposed to form not only hydroperoxides but also kinds of cyclic peroxides as primary oxidation products in the autoxidation. In a thermal oxidation, polymerization reaction might be prior to decomposition reaction owing to form a large quantity of more polymerized products in conjugated oils. Solidification of conjugated oils by thermal oxidation was prevented for long time by addition of tocopherol, and optimal addition amounts of tocopherol into conjugated oils were 1,000 ppm either in autoxidation or thermal oxidation. Equi-molar of phosphatidyl ethanolamine showed synergistic effect slightly on 1,000 ppm tocopherol for preventing thermal oxidation of conjugated oil.
Department of Materials and Life Science, Faculty of Science and Technology, Seikei University, Musashino-shi, Tokyo, Japan.
Yohko
Y
Kuge
Ayato
A
Kanda
Setsuko
S
Hara
D000975:Antioxidants / Q000737:chemistry; D001205:Ascorbic Acid / Q000031:analogs & derivatives / Q000737:chemistry; D002625:Chemistry, Organic / Q000379:methods*; D019343:Citric Acid / Q000737:chemistry; D004655:Emulsions; D005990:Glycerol / Q000737:chemistry*; D044243:Linoleic Acids, Conjugated; D009821:Oils / Q000737:chemistry*; D010084:Oxidation-Reduction; D010714:Phosphatidylethanolamines / Q000737:chemistry; D010938:Plant Oils / Q000737:chemistry; D013696:Temperature; D024505:Tocopherols / Q000737:chemistry
D000975:Antioxidants; D004655:Emulsions; D044243:Linoleic Acids, Conjugated; D009821:Oils; D010714:Phosphatidylethanolamines; D010938:Plant Oils; D019343:Citric Acid; C483858:phosphatidylethanolamine; D005990:Glycerol; D001205:Ascorbic Acid; C031226:6-O-palmitoylascorbic acid; D024505:Tocopherols