Topochemical limits for solid-state photoreactivity by fine tuning of the pi-pi interactions.
The limiting topochemical criteria for photodimerization were studied by modulation of the pi-pi stacking interactions between self-templating planar molecules with hydrogen bonding. The product yield and composition can be controlled predominantly by the distance between the reactive bonds.
Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka, Japan.
Shi-Yao
SY
Yang
Pance
P
Naumov
Shunichi
S
Fukuzumi