Topochemical limits for solid-state photoreactivity by fine tuning of the pi-pi interactions.
The limiting topochemical criteria for photodimerization were studied by modulation of the pi-pi stacking interactions between self-templating planar molecules with hydrogen bonding. The product yield and composition can be controlled predominantly by the distance between the reactive bonds.
Yang
Shi-Yao
SY
Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka, Japan.
Naumov
Pance
P
Fukuzumi
Shunichi
S