ZnO/Al2O3 core-shell nanorod arrays: growth, structural characterization, and luminescent properties.
We report an aqueous chemical method to fabricate well-aligned ZnO/Al(2)O(3) nanocrystal (NC) core-shell nanorod arrays (NRAs). Structural characterization showed that the shell layers are composed of alpha-Al(2)O(3) nanocrystals. Photoluminescence measurements showed the enhancement of near-band-edge (NBE) emission of ZnO NRAs due to the presence of Al(2)O(3) NC shells. The Al(2)O(3) NC shell layer resulting in the flat-band effect near the ZnO surface leads to a stronger overlap of the wavefunctions of electrons and holes in the ZnO core, further enhancing the NBE emission. This approach should be very useful in designing many other core-shell NRAs for creating varieties of high-efficiency optoelectronic devices.
Chen
C Y
CY
Institute of Photonics and Optoelectronics, National Taiwan University, Taipei 10617, Taiwan.
Lin
C A
CA
Chen
M J
MJ
Lin
G R
GR
He
J H
JH
D000537:Aluminum Oxide / Q000737:chemistry*; D003460:Crystallization / Q000379:methods*; D008163:Luminescent Measurements / Q000379:methods*; D046911:Macromolecular Substances / Q000737:chemistry; D008422:Materials Testing; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D036103:Nanotechnology / Q000379:methods*; D010316:Particle Size; D013499:Surface Properties; D015034:Zinc Oxide / Q000737:chemistry*
D046911:Macromolecular Substances; D000537:Aluminum Oxide; D015034:Zinc Oxide