Plasmon resonance changes of gold nanoparticle arrays upon modification.
Periodic Au nanoparticle arrays, fabricated using electron beam lithography, have been modified by chemical reaction in solutions having various concentrations of a reducing agent. As the nanoparticles enlarge due to the formation of additional Au nanolumps on the surface, both the position and intensity of plasmon absorbance of Au nanoparticle arrays change in proportion to the concentration of the reducing agent. Moreover, the plasmon absorbance is split into dipole and quadrupole modes as conductive connections form between the particles. Our results demonstrate that the changes in both the position and intensity of plasmon absorbance can be employed together as complementary readout values of nanosensors.
Ha
Dong Han
DH
Division of Advanced Technology, Korea Research Institute of Standards and Science, Daejeon 305-600, Korea.
Kim
Sanghun
S
Yun
Yong Ju
YJ
Park
Hyung Ju
HJ
Yun
Wan Soo
WS
Song
Jung-Hoon
JH
D003460:Crystallization / Q000379:methods*; D006046:Gold / Q000737:chemistry*; D046911:Macromolecular Substances / Q000737:chemistry; D008422:Materials Testing; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D036103:Nanotechnology / Q000379:methods*; D010316:Particle Size; D020349:Surface Plasmon Resonance / Q000379:methods*; D013499:Surface Properties
D046911:Macromolecular Substances; D006046:Gold