Field gradient imaging of nanoparticle systems: analysis of geometry and surface coating effects.
In this work we compare the standard imaging of various types of nanoparticles deposited on surfaces by atomic force microscopy (AFM) with a complementary analysis of the same samples by either electrostatic force microscopy (EFM) or magnetic force microscopy (MFM). Experiments were carried out on gold nanoparticles (decahedrons and stars) and two different iron oxide systems: goethite (alpha-FeOOH) and hematite (alpha-Fe(2)O(3)). Regardless of the particular geometry, the EFM signal appears to be stronger on edges or tips of pure gold nanoparticles. Both EFM and MFM experiments were also carried out on iron oxide particles. Apart from the structural analysis, we analyzed the influence of a shell layer deposited on the gold and iron oxide particles, the shell being amorphous SiO(2). Although the silica layer was found to have an insulating effect around the particles, in all cases EFM/MFM measurements could still be performed by the proper choice of the scan lift height (with an eventual slight increase of the sample bias, where applicable).
Departamento de Química Física, and Unidad Asociada CSIC, Universidade de Vigo, Vigo, Spain. jessicap@uvigo.es
J
J
Pacifico
Y M
YM
van Leeuwen
M
M
Spuch-Calvar
A
A
Sánchez-Iglesias
L
L
Rodríguez-Lorenzo
J
J
Pérez-Juste
I
I
Pastoriza-Santos
L M
LM
Liz-Marzán
D003460:Crystallization / Q000379:methods*; D046911:Macromolecular Substances / Q000737:chemistry; D008422:Materials Testing; D018625:Microscopy, Atomic Force / Q000379:methods*; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D036103:Nanotechnology / Q000379:methods*; D010316:Particle Size; D013499:Surface Properties
D046911:Macromolecular Substances