The anomalous solid state decomposition of ammonium dinitramide: a matter of surface polarization.
Polarized dinitramide anions on the surface of solid ammonium dinitramide (ADN) have a decomposition barrier that is reduced by 16 kcal mol(-1) and explain the anomalous solid state decomposition of ADN.
Rahm
Martin
M
Physical Chemistry, School of Chemical Science and Engineering, Royal Institute of Technology (KTH), Stockholm, Sweden.
Brinck
Tore
T