The hydrated platinum(ii) ion in aqueous solution--a combined theoretical and EXAFS spectroscopic study.
The hydrated platinum(ii) ion, previously characterized as square-planar in aqueous solution, has been shown by quantum mechanical charge field molecular dynamic (QMCF MD) simulations and EXAFS experiments to be hexa-coordinated with two additional ligands in elongated axial positions.
Hofer
Thomas S
TS
Theoretical Chemistry Division, Institute of General, Inorganic and Theoretical Chemistry, University of Innsbruck, Innrain 52a, A-6020, Innsbruck, Austria.
Randolf
Bernhard R
BR
Rode
Bernd M
BM
Persson
Ingmar
I
D007477:Ions; D008956:Models, Chemical; D010984:Platinum / Q000737:chemistry*; D013052:Spectrometry, X-Ray Emission; D014867:Water / Q000737:chemistry*
D007477:Ions; D014867:Water; D010984:Platinum