The first thiosilicate from solution: synthesis and crystal structure of (NH4)2[SiS3(NH3)].2NH3.
The ammonolysis of SiS(2) in liquid ammonia yields crystalline (NH(4))(2)[SiS(3)(NH(3))].2NH(3), which contains [SiS(3)(NH(3))](2-) as a derivative of the ortho-thiosilicate anion SiS(4)(4-).
Institut für Anorganische Chemie, Universität Regensburg, 93040 Regensburg, Germany.
Martin
M
Meier
Nikolaus
N
Korber