The synthesis and hydrogen storage properties of a MgH(2) incorporated carbon aerogel scaffold.
A new approach to the incorporation of MgH2 in the nanometer-sized pores of a carbon aerogel scaffold was developed, by infiltrating the aerogel with a solution of dibutylmagnesium (MgBu2) precursor, and then hydrogenating the incorporated MgBu2 to MgH2. The resulting impregnated material showed broad x-ray diffraction peaks of MgH2. The incorporated MgH2 was not visible using a transmission electron microscope, which indicated that the incorporated hydride was nanosized and confined in the nanoporous structure of the aerogel. The loading of MgH2 was determined as 15-17 wt%, of which 75% is reversible over ten cycles. Incorporated MgH2 had >5 times faster dehydrogenation kinetics than ball-milled activated MgH2, which may be attributed to the particle size of the former being smaller than that of the latter. Cycling tests of the incorporated MgH(2) showed that the dehydrogenation kinetics are unchanged over four cycles. Our results demonstrate that confinement of metal hydride materials in a nanoporous scaffold is an efficient way to avoid aggregation and improve cycling kinetics for hydrogen storage materials.
Department of Chemistry, University of Hawaii at Manoa, 2545 McCathy Mall, Honolulu, HI 96822, USA.
Shu
S
Zhang
Adam F
AF
Gross
Sky L
SL
Van Atta
Maribel
M
Lopez
Ping
P
Liu
Channing C
CC
Ahn
John J
JJ
Vajo
Craig M
CM
Jensen
D000388:Air; D002244:Carbon / Q000737:chemistry*; D003460:Crystallization / Q000379:methods*; D005740:Gases / Q000737:chemistry; D005782:Gels / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry* / Q000302:isolation & purification*; D046911:Macromolecular Substances / Q000737:chemistry; D008274:Magnesium / Q000737:chemistry*; D008422:Materials Testing; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D036103:Nanotechnology / Q000379:methods; D010316:Particle Size; D013499:Surface Properties
D005740:Gases; D005782:Gels; D046911:Macromolecular Substances; D002244:Carbon; D006859:Hydrogen; D008274:Magnesium