Azide groups in high oxidation state Mn carboxylate chemistry: a new Mn(11) complex and its conversion to a Mn(25) azide complex with Me(3)SiN(3).
A new high oxidation state Mn(III/IV)(11) carboxylate complex has been prepared and then converted to a Mn(II/III)(25) azide/carboxylate cluster with Me(3)SiN(3); the Mn(25) product is the initial example of a higher oxidation state Mn azide complex not stabilized by any chelate ligands.
Department of Chemistry, University of Florida, Gainesville, FL 32611-7200, USA.
Theocharis C
TC
Stamatatos
Alina
A
Vinslava
Khalil A
KA
Abboud
George
G
Christou
D001386:Azides / Q000138:chemical synthesis / Q000737:chemistry*; D002264:Carboxylic Acids / Q000138:chemical synthesis / Q000737:chemistry*; D008024:Ligands; D008345:Manganese / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D012821:Silanes / Q000138:chemical synthesis / Q000737:chemistry
D001386:Azides; D002264:Carboxylic Acids; D008024:Ligands; D012821:Silanes; C438544:azidotrimethylsilane; D008345:Manganese