The temperature-controlled growth of In2O3 nanowires, nanotowers and ultra-long layered nanorods.
Indium oxide (In(2)O(3)) nanowires (with diameters of 25-90 nm and lengths of 10-50 microm), nanotowers (with diameters 100-150 nm and lengths below 10 microm) and long layered nanorods (with diameters of 200-400 nm and lengths of 20-50 microm) are grown through carbothermal reduction of In(2)O(3) powder by varying the source temperature in a CVD horizontal furnace. At 875 degrees C source temperature, In(2)O(3) nanowires were formed by a VLS (vapor-liquid-solid) mechanism. The growth is changed to VS (vapor-solid)-initiated growth on the substrate surface when the source temperature is raised to 950 degrees C due to high saturation vapor pressure. Meanwhile, alternate VLS-VS grown nanotowers can be obtained at the bottom of the substrates. Growth of one-dimensional nanostructures with different structures and variation in growth mechanism from a single precursor with the confinement of vapor pressure enables the diversity of In(2)O(3) nanostructure synthesis. The morphologies and crystalline structures are characterized by x-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) and high-resolution transmission electron microscopy (HRTEM). The growth mechanisms of these structures are discussed.
Singh
Nandan
N
School of Materials Science and Engineering, Nanyang Technological University, Singapore.
Zhang
Tao
T
Lee
Pooi See
PS
D003460:Crystallization / Q000379:methods*; D007204:Indium / Q000737:chemistry*; D046911:Macromolecular Substances / Q000737:chemistry; D008422:Materials Testing; D008968:Molecular Conformation; D036103:Nanotechnology / Q000379:methods*; D043942:Nanotubes / Q000737:chemistry* / Q000648:ultrastructure*; D010316:Particle Size; D013499:Surface Properties; D013696:Temperature
D046911:Macromolecular Substances; D007204:Indium; C047711:indium oxide