Addition of dimethylaminobismuth to aldehydes, ketones, alkenes, and alkynes.
Bi-O chemistry: A direct regioselective route to bismuth bis(amino)naphthalene compounds, incorporating Bi-O and Bi-C bonds is described, in which an amide precursor is treated with aldehydes, ketones, alkenes, and alkynes, leading to insertion into the Bi-NMe(2) bond.
Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen, Germany.
Bijan
B
Nekoueishahraki
Sankaranarayana Pillai
SP
Sarish
Herbert W
HW
Roesky
Daniel
D
Stern
Carola
C
Schulzke
Dietmar
D
Stalke
D000447:Aldehydes / Q000737:chemistry*; D000475:Alkenes / Q000737:chemistry*; D000480:Alkynes / Q000737:chemistry*; D001729:Bismuth / Q000737:chemistry*; D018360:Crystallography, X-Ray; D004123:Dimethylamines / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D013237:Stereoisomerism
D000447:Aldehydes; D000475:Alkenes; D000480:Alkynes; D004123:Dimethylamines; D007659:Ketones; D001729:Bismuth