A variational framework for nonlinear chemical thermodynamics employing the maximum energy dissipation principle.
The maximum energy dissipation principle is employed to nonlinear chemical thermodynamics in terms of distance variable (generalized displacement) from the global equilibrium, applying the optimal control interpretation to develop a variational formulation. The cost-like functional was chosen to support the suggestion that such a formulation corresponds to the maximum energy dissipation principle. Using this approach, the variational framework was proposed for a nonlinear chemical thermodynamics, including a general cooperative kinetics model. The formulation is in good agreement with standard linear nonequilibrium chemical thermodynamics.
Moroz
Adam
A
Engineering Department, Faculty of Technology, De Montfort University, Leicester, U.K.
D008962:Models, Theoretical; D013816:Thermodynamics