cis-Tach based pentadecadentate ligands as building blocks in the synthesis of Fe III and Pd II coordination clusters.
A dodecanuclear Fe(III) complex, consisting of two {Fe(6)} units coupled across a single hydroxy-bridge and a cage-like Pd(II) trimer were synthesised using the highly branched, pentadecadentate chelating ligand cis,cis-1,3,5-cyclohexanetriamine-N,N,N',N',N'',N''-hexaacetic acid (H(6)hact).
Newton
Graham N
GN
WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow, UK.
Cooper
Geoffrey J T
GJ
Schuch
Dominik
D
Shiga
Takuya
T
Khanra
Sumit
S
Long
De-Liang
DL
Oshio
Hiroki
H
Cronin
Leroy
L
D018360:Crystallography, X-Ray; D005290:Ferric Compounds / Q000737:chemistry*; D008024:Ligands; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*
D005290:Ferric Compounds; D008024:Ligands; D009942:Organometallic Compounds; D010165:Palladium