Daphnezomines T--V, alkaloids from Daphniphyllum humile.
Three new Daphniphyllum alkaloids, daphnezomines T-V (1-3), were isolated from the leaves and branches of Daphniphyllum humile (Daphniphyllaceae). The structures and relative stereochemistry of 1-3 were elucidated on the basis of spectroscopic data. Daphnezomine T (1) is the first alkaloid without a branched C(1) unit at C-5 among all Daphiniphyllum alkaloids reported so far.
Kubota
Takaaki
T
Graduate School of Pharmaceutical Sciences, Hokkaido University, Sapporo, Japan.
Suzuki
Teppei
T
Ishiuchi
Kan'ichiro
K
Kuhara
Taiga
T
Kobayashi
Jun'ichi
J
D000470:Alkaloids / Q000737:chemistry / Q000302:isolation & purification*; D006576:Heterocyclic Compounds, 4 or More Rings / Q000737:chemistry / Q000302:isolation & purification*; D009682:Magnetic Resonance Spectroscopy; D019684:Magnoliopsida / Q000737:chemistry* / Q000145:classification; D015394:Molecular Structure; D010936:Plant Extracts / Q000737:chemistry*; D018515:Plant Leaves / Q000737:chemistry*; D013237:Stereoisomerism
D000470:Alkaloids; D006576:Heterocyclic Compounds, 4 or More Rings; D010936:Plant Extracts; C540608:daphnezomine T; C540610:daphnezomine U; C540609:daphnezomine V