Electrochemically controlled ligand shuttling between zinc porphyrin and meso-phenylenediamine substituent.
ZnTMP-PD was synthesized and fully characterized; by using electrochemical and spectroelectrochemical methods, ligand shuttling between the zinc porphyrin and the meso-phenylenediamine substituent could be monitored; EPR results indicated that the charge was delocalized on ZnTMP-PD.
Department of Applied Chemistry, National Chi Nan University 1, Puli, Nantou Hsien, Taiwan.
Kuo Yuan
KY
Chiu
Yuhlong Oliver
YO
Su
D004563:Electrochemistry / Q000379:methods*; D006860:Hydrogen Bonding; D007093:Imidazoles / Q000737:chemistry; D008024:Ligands; D008665:Metalloporphyrins / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010655:Phenylenediamines / Q000138:chemical synthesis* / Q000737:chemistry; D013053:Spectrophotometry
D007093:Imidazoles; D008024:Ligands; D008665:Metalloporphyrins; D010655:Phenylenediamines; C017802:zinc hematoporphyrin; C018100:1-methylimidazole