N-formylation of amines via the aerobic oxidation of methanol over supported gold nanoparticles.
Dress code: formyl. Gold nanoparticles supported on NiO catalyze the one-pot N-formylation of amines with methanol and molecular oxygen to produce formamide at a selectivity of 90 %. This process generates methyl formate in situ, followed by reaction with amines.
Ishida
Tamao
T
Tokyo Metropolitan University, Minami-osawa, Hachioji, Japan. ishida-tamao@center.tmu.ac.jp
Haruta
Masatake
M
D000588:Amines / Q000737:chemistry*; D005559:Formamides / Q000138:chemical synthesis*; D005561:Formates / Q000737:chemistry*; D006046:Gold; D055772:Green Chemistry Technology / Q000379:methods; D053768:Metal Nanoparticles; D000432:Methanol / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry
D000588:Amines; D005559:Formamides; D005561:Formates; C030544:formic acid; C031066:formamide; D006046:Gold; D010100:Oxygen; D000432:Methanol