Microflow radical carboaminoxylations with a novel alkoxyamine.
Highly efficient thermal radical carboaminoxylations of various olefins by using the novel alkoxyamine A to give adducts of type B are described. It is reported that these radical addition reactions can be performed in a microflow reaction system. As compared to conventional batch reaction setup, significantly higher yields are obtained by running carboaminoxylations using the microflow system under analogous conditions.
Organisch-Chemisches Institut, Westfälische Wilhelms-Universität, Corrensstrasse 40, 48149 Münster, Germany.
Inga C
IC
Wienhöfer
Armido
A
Studer
Md Taifur
MT
Rahman
Takahide
T
Fukuyama
Ilhyong
I
Ryu
D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry; D000588:Amines / Q000737:chemistry*; D002625:Chemistry, Organic / Q000379:methods; D015394:Molecular Structure
D000475:Alkenes; D000588:Amines