N-H...Cl hydrogen bonded networks constructed of a secondary thioamide-based SCS pincer palladium complex.
A secondary thioamide-based SCS pincer Pd complex, [2,6-bis(anilinothiocarbonyl)-kappa2S,S'-phenyl-kappaC1]chloropalladium(II) (1), forms the intermolecular N-H...Cl hydrogen bonds in the crystals. The intermolecular hydrogen bonds induce spontaneous formation of layered and cage-shaped network structures of 1 in the solid state. Formation of the different two types of networks is assisted by the kind of solvated molecules.
Okamoto
Ken
K
Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama, 226-8503, Japan.
Yamamoto
Takakazu
T
Kanbara
Takaki
T