Size- and density-controlled synthesis of TiO2 nanodots on a substrate by phase-separation-induced self-assembly.
This work presents a facile way, i.e. phase-separation-induced self-assembly, to prepare TiO(2) nanodots on a substrate. This method induces convective flow in a spin-coated titanium tetrabutoxide (TBOT)/polyvinyl pyrrolidone (PVP)/ethanol liquid film through the Marangoni effect and turns TBOT into crystalline TiO(2) nanodots on a substrate after calcination. The size and density of the TiO(2) nanodots can be finely tailored by controlling the concentrations of TBOT and PVP in the precursor sol. The TiO(2) nanodot-deposited surface showed a hydrophilic characteristic and the wettability was obviously improved by increasing nanodot size.
Luo
Ming
M
Department of Material Science and Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou, People's Republic of China.
Cheng
Kui
K
Weng
Wenjian
W
Song
Chenlu
C
Du
Piyi
P
Shen
Ge
G
Xu
Gang
G
Han
Gaorong
G
D003460:Crystallization / Q000379:methods*; D046911:Macromolecular Substances / Q000737:chemistry; D008422:Materials Testing; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D036103:Nanotechnology / Q000379:methods*; D010316:Particle Size; D013499:Surface Properties; D014025:Titanium / Q000737:chemistry*
D046911:Macromolecular Substances; C009495:titanium dioxide; D014025:Titanium