cis-Tach based pentadecadentate ligands as building blocks in the synthesis of Fe III and Pd II coordination clusters.
A dodecanuclear Fe(III) complex, consisting of two {Fe(6)} units coupled across a single hydroxy-bridge and a cage-like Pd(II) trimer were synthesised using the highly branched, pentadecadentate chelating ligand cis,cis-1,3,5-cyclohexanetriamine-N,N,N',N',N'',N''-hexaacetic acid (H(6)hact).
WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow, UK.
Graham N
GN
Newton
Geoffrey J T
GJ
Cooper
Dominik
D
Schuch
Takuya
T
Shiga
Sumit
S
Khanra
De-Liang
DL
Long
Hiroki
H
Oshio
Leroy
L
Cronin
D018360:Crystallography, X-Ray; D005290:Ferric Compounds / Q000737:chemistry*; D008024:Ligands; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*
D005290:Ferric Compounds; D008024:Ligands; D009942:Organometallic Compounds; D010165:Palladium