Photoinduced nitric oxide release from a hindered nitrobenzene derivative by two-photon excitation.
Here, we demonstrated photoinduced NO generation from a 2,6-dimethylnitrobenzene-based compound (Flu-DNB) via a two-photon excitation (TPE) process. After pulse laser irradiation to a solution of Flu-DNB, oxidation products of NO were observed. This is the first account of a non-nitrosyl-chelated metal ion containing NO donor which can be controlled by the TPE technique.
Graduate School of Pharmaceutical Sciences, Nagoya City University, 3-1 Tanabe-dori Mizuho-ku, Nagoya, Aichi 467-8603, Japan.
Kazuhiro
K
Hishikawa
Hidehiko
H
Nakagawa
Toshiaki
T
Furuta
Kiyoshi
K
Fukuhara
Hiroki
H
Tsumoto
Takayoshi
T
Suzuki
Naoki
N
Miyata
D004578:Electron Spin Resonance Spectroscopy; D005452:Fluoresceins / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D009569:Nitric Oxide / Q000737:chemistry*; D009578:Nitrobenzenes / Q000737:chemistry*; D055668:Photochemical Processes; D017785:Photons
D005452:Fluoresceins; D009578:Nitrobenzenes; D009569:Nitric Oxide