Intermediates in reactions of copper(I) complexes with N-oxides: from the formation of stable adducts to oxo transfer.
Reactions of copper(I) complexes of bidentate N-donor supporting ligands with pyridine- and trimethylamine-N-oxides or PhIO were explored. Key results include the identification of novel copper(I) N-oxide adducts, aryl substituent hydroxylation, and bis(mu-oxo)dicopper complex formation via a route involving oxo transfer.
Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota 55455, USA.
Sungjun
S
Hong
Aalo K
AK
Gupta
William B
WB
Tolman
D056831:Coordination Complexes / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D006900:Hydroxylation; D008024:Ligands; D008744:Methylamines / Q000737:chemistry*; D008958:Models, Molecular; D009589:Nitrogen Oxides / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*
D056831:Coordination Complexes; D008024:Ligands; D008744:Methylamines; D009589:Nitrogen Oxides; D011725:Pyridines; D003300:Copper; C023336:trimethylamine; C023666:pyridine