title: Unusual selectivity of a (pincer)Ni-hydride reacting with CO2.
abstract: The reaction of (PNP)NiH, where PNP is ((t)Bu2PCH2SiMe2)2-N(-1), with CO2 occurs over a period of hours at 25 degrees C to form (POP)NiH(NCO), which involves transposition of the initial amide nitrogen and one oxygen of CO2.
authors.affiliation: Department of Chemistry, Indiana University, Bloomington, IN, USA.
authors.forename: Matthew F
authors.initials: MF
authors.lastname: Laird
authors.forename: Maren
authors.initials: M
authors.lastname: Pink
authors.forename: Nikolay P
authors.initials: NP
authors.lastname: Tsvetkov
authors.forename: Hongjun
authors.initials: H
authors.lastname: Fan
authors.forename: Kenneth G
authors.initials: KG
authors.lastname: Caulton