Preparation and characterization of Mn and (Mn, Cu) co-doped ZnO nanostructures.
We report on the ferromagnetic characteristics of Zn(1-x)Mn(x)O nanorods synthesized by a seed-mediated solution method. The as-doped ZnO nanorods had a length about 200 nm and a diameter ranging from 20 to 30 nm. Magnetic property measurements revealed that the Zn(1-x)Mn(x)O nanorods exhibited weak ferromagnetism at 305 K. Similar solution method were also employed to fabricate the (Mn, Cu) co-doped nanostructures. The presence of Cu2+ was found to change the nanorod morphology (in the case of pure ZnO) to nanoparticle. On the other hand, not only the hysteresis curve saturated at lower magnetic field, but also the saturation magnetization was increased with the Cu doping. Transmission electron microscopy, X-ray photoelectron spectroscopy and Photoluminescence analysis suggested that the room temperature (RT) ferromagnetism could be originated from the Mn2+ doped into the ZnO lattice, and additional carriers due to the Cu co-doping may enhance the room temperature ferromagnetism in the Mn:ZnO system.
Wang
H B
HB
Faculty of Physics and Electronic Technology and Key Laboratory of Ferro- and Piezo-Electric Materials and Devices, Hubei University, Wuhan 430062, People's Republic China.
Wang
H
H
Zhang
C
C
Yang
F J
FJ
Duan
J X
JX
Yang
C P
CP
Gu
H S
HS
Zhou
M J
MJ
Li
Q
Q
Jiang
Y
Y