Unusual selectivity of a (pincer)Ni-hydride reacting with CO2.
The reaction of (PNP)NiH, where PNP is ((t)Bu2PCH2SiMe2)2-N(-1), with CO2 occurs over a period of hours at 25 degrees C to form (POP)NiH(NCO), which involves transposition of the initial amide nitrogen and one oxygen of CO2.
Laird
Matthew F
MF
Department of Chemistry, Indiana University, Bloomington, IN, USA.
Pink
Maren
M
Tsvetkov
Nikolay P
NP
Fan
Hongjun
H
Caulton
Kenneth G
KG