title: Salan ligands assembled around chiral bipyrrolidine: predetermination of chirality around octahedral Ti and Zr centres.
abstract: The first synthesis of Salan ligands assembled around the chiral 2,2'-bipyrrolidine backbone is described; as chelation to a metal can only occur via specific faces of the two pyrrolidine nitrogens, these ligands lead to predetermined chirality at metal centres of octahedral titanium and zirconium complexes.
authors.affiliation: The School of Chemistry, Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, Ramat Aviv, Tel Aviv, 69978, Israel.
authors.forename: Ekaterina
authors.initials: E
authors.lastname: Sergeeva
authors.forename: Jacob
authors.initials: J
authors.lastname: Kopilov
authors.forename: Israel
authors.initials: I
authors.lastname: Goldberg
authors.forename: Moshe
authors.initials: M
authors.lastname: Kol