Radical pairs with rotational fluidity in the photochemical reaction of acetophenone and cyclohexane in the zeolite NAY: a (13)C CPMAS NMR and product analysis study.
The photochemical reaction of acetophenone and cyclohexane in the zeolite NaY occurs by combination of the geminate radical pairs to give products that reveal a significant amount of rotational fluidity, which was also documented by intermolecular nuclear dipolar interaction measurements using cross polarization (13)C NMR (CPMAS) experiments.
Amboya
Ammee
A
Mount St. Mary's College, Los Angeles, CA 90049, USA.
Nguyen
Tina
T
Huynh
T Hien
TH
Brown
Ashley
A
Ratliff
Gretchen
G
Yonutas
Heather
H
Cizmeciyan
Deniz
D
Natarajan
Arunkumar
A
Garcia Garibay
Miguel A
MA
D000098:Acetophenones / Q000737:chemistry*; D002247:Carbon Isotopes; D003510:Cyclohexanes / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D055668:Photochemical Processes; D017641:Zeolites / Q000737:chemistry*
D000098:Acetophenones; D002247:Carbon Isotopes; D003510:Cyclohexanes; D017641:Zeolites; C506365:Cyclohexane; C038699:acetophenone