The reaction of diethyl bromomalonate with p-tert-butylthia-calix[4]arene: an approach to asymmetrical derivatives.
New dissymmetric and asymmetric p-tert-butylthiacalix[4]arene derivatives were prepared as a result of the reaction of p-tert-butylthiacalix[4]arene with diethyl bromomalonate in the presence of different alkali metals (Cs, K and Na) in refluxing acetone for 7 days. The structures of the prepared compounds were investigated by IR, (1)H-NMR and MALDI-TOF mass spectroscopy.
Omran
Omran Abdellah
OA
Chemistry Department, Sohag University, Sohag, Egypt. omran2002@mailcity.com
D017605:Bromine Compounds / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008314:Malonates / Q000737:chemistry*; D008672:Metals, Alkali / Q000737:chemistry; D015394:Molecular Structure; D010636:Phenols / Q000737:chemistry*
D017605:Bromine Compounds; D008314:Malonates; D008672:Metals, Alkali; D010636:Phenols; C442852:p-tert-butylthiacalix(4)arene