title: Selective functionalisation of Re6 cluster anionic units: from hexa-hydroxo [Re6Q8(OH)6]4- (Q = S, Se) to neutral trans-[Re6Q8L4L'2] hybrid building blocks.
abstract: The reaction of [Re6Q(i)8(OH)(a)6]4- (Q = S, Se) with p-tert-butylpyridine (TBP) in water leads to neutral trans-[Re6Q8(TBP)4(OH)2] whose hydroxyl reactivity with carboxylic acid and TBP exchange reaction with functional pyridine have been investigated.
authors.affiliation: Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, Avenue du Geńérale Leclerc, 35042, Rennes Cedex, France.
authors.forename: Frédérick
authors.initials: F
authors.lastname: Dorson
authors.forename: Yann
authors.initials: Y
authors.lastname: Molard
authors.forename: Stéphane
authors.initials: S
authors.lastname: Cordier
authors.forename: Bruno
authors.initials: B
authors.lastname: Fabre
authors.forename: Olga
authors.initials: O
authors.lastname: Efremova
authors.forename: David
authors.initials: D
authors.lastname: Rondeau
authors.forename: Yuri
authors.initials: Y
authors.lastname: Mironov
authors.forename: Viorel
authors.initials: V
authors.lastname: Cîrcu
authors.forename: Nikolay
authors.initials: N
authors.lastname: Naumov
authors.forename: Christiane
authors.initials: C
authors.lastname: Perrin