Two novel domino reactions triggered by thiyl-radical addition to vinylcyclopropyl oxime ether.
Two domino reactions of vinylcyclopropyl oxime ethers involving (i) thiyl radical addition, ring-opening, and hydroxylation reactions and (ii) thiyl radical addition, ring-opening, and aldol-type reactions were developed.
Rahaman
Habibur
H
Kobe Pharmaceutical University, 4-19-1, Motoyamakita, Higashinada, Kobe 658-8558, Japan.
Ueda
Masafumi
M
Miyata
Okiko
O
Naito
Takeaki
T
D000447:Aldehydes / Q000737:chemistry; D000605:Amino Alcohols / Q000138:chemical synthesis* / Q000737:chemistry; D005609:Free Radicals / Q000737:chemistry; D015394:Molecular Structure; D010091:Oximes / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D014753:Vinyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry
D000447:Aldehydes; D000605:Amino Alcohols; D005609:Free Radicals; D010091:Oximes; D013438:Sulfhydryl Compounds; D014753:Vinyl Compounds; C116609:3-hydroxybutanal