Hydrogen storage in double clathrates with tert-butylamine.
The first proof-of-concept of the formation of a double tert-butylamine (t-BuNH(2)) + hydrogen (H(2)) clathrate hydrate has been demonstrated. Binary clathrate hydrates with different molar concentrations of the large guest t-BuNH(2) (0.98-9.31 mol %) were synthesized at 13.8 MPa and 250 K, and characterized by powder X-ray diffraction and Raman microscopy. A structural transformation from sVI to sII of t-BuNH(2) hydrate was clearly observed under hydrogen pressures. Raman spectroscopic data suggested that the hydrogen molecules occupied the small cages and had similar occupancy to hydrogen in the double tetrahydrofuran (THF) + H(2) clathrate hydrate. The hydrogen storage capacity in this system was approximately 0.7 H(2) wt % at the molar concentration of t-BuNH(2) close to the sII stoichiometry.
Prasad
Pinnelli S R
PS
Sugahara
Takeshi
T
Sum
Amadeu K
AK
Sloan
E Dendy
ED
Koh
Carolyn A
CA
D002082:Butylamines / Q000138:chemical synthesis / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D033362:Powder Diffraction; D013059:Spectrum Analysis, Raman; D014867:Water / Q000737:chemistry
D002082:Butylamines; D014867:Water; C025397:tert-butylamine; D006859:Hydrogen