Sterically controlled naphthalene homo-oligoamides with novel structural architectures.
Herein we report novel naphthalene homo-oligoamides, derived from 4-amino-3-methoxy-naphthalene-2-carboxylic acid and 4-amino-1-methoxy-naphthalene-2-carboxylic acid as monomer building blocks, that display an anti-periplanar arrangement of the naphthyl rings, primarily induced by steric interactions between adjacent groups and functionalities.
Prabhakaran
Panchami
P
Division of Organic Chemistry, National Chemical Laboratory, Dr. Homi Bhabha Road, Pune, 411 008, India.
Puranik
Vedavati G
VG
Chandran
Jima N
JN
Rajamohanan
P R
PR
Hofmann
Hans-Jörg
HJ
Sanjayan
Gangadhar J
GJ
D015057:1-Naphthylamine / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry; D000577:Amides / Q000138:chemical synthesis* / Q000737:chemistry; D018360:Crystallography, X-Ray; D019281:Dimerization; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D009281:Naphthalenes / Q000138:chemical synthesis* / Q000737:chemistry; D011789:Quantum Theory; D013237:Stereoisomerism
D000577:Amides; D009281:Naphthalenes; C031721:naphthalene; D015057:1-Naphthylamine