title: Direct passivation of hydride-terminated silicon (100) surfaces by free-radically tethered polymer brushes.
abstract: A simple and effective means for passivating crystalline silicon is reported by the use of free-radical polymerization (FRP) to directly graft polymer chains to a hydride-terminated surface (Si-H). Complete surface coverage and passivation was achieved in approximately 24 h at 60 degrees C or 30 min at 90 degrees C. Mechanistic studies determined that chain attachment followed a hydride-transfer-based grafting-to mechanism. The grafting process is compatible with a variety of monomers and was used to assemble polymer brush layers (2-12 nm thick), with grafting densities ranging from 0.02 to 0.65 chains/nm2 rivaling densities typically obtained by grafting-from scenarios. This new passivation route provides a uniquely accessible means to covalently anchor dense polymer brushes to silicon surfaces without the need for functionalization of the polymer chain ends or the substrate.
authors.affiliation: Polymer Science and Engineering Department, University of Massachusetts Amherst, Conte Center for Polymer Research, 120 Governors Drive, Amherst, Massachusetts 01003, USA.
authors.forename: Isaac W
authors.initials: IW
authors.lastname: Moran
authors.forename: Kenneth R
authors.initials: KR
authors.lastname: Carter