title: Altitudinal and chiral signature of persistent organochlorine pesticides in air, soil, and spruce needles (Picea abies) of the Alps.
abstract: The present study investigated the distribution, transportation, and biodegradation of the selected chiral persistent organochlorine pesticides (OCP) in the Alps. In the complex environment, we found the movement and fate of OCP could be defined by many factors. Taking HCE as an example, below the timberline its accumulation from air into SPMD increased with altitude and seasonally changed, but the trends reversed above the timberline. In soil, the tendency of HCE concentrations vs organic materials followed a sigmoid curve, and HCE concentration-altitude correlations are positive in central Alps but negative in southern Alps. The HCE enantiomeric ratios (ERs) in soil correlated to HCE isomers concentrations, the humus pH values, and the sampling site altitudes. HCE shift from humus to mineral soil can also be traced by ERs. The altitudinal and longitudinal trends in needles suggested that alpha-HCH has a more complex movementthan HCE in Alps. In conclusion, altitude conducted condensation, plant canopies, organic material in soil, and geographic specific precipitations may affect OCP distributions and transportation, whereas altitude conducted temperature and soil pH could dictate their fate in the environment.
authors.affiliation: Helmholtz Zentrum München-German Research Center for Environmental Health, Ingolstädter Landstrasse 1, D-85764 Neuherberg, Germany.
authors.forename: Heqing
authors.initials: H
authors.lastname: Shen
authors.forename: Bernhard
authors.initials: B
authors.lastname: Henkelmann
authors.forename: Walkiria
authors.initials: W
authors.lastname: Levy
authors.forename: Adam
authors.initials: A
authors.lastname: Zsolnay
authors.forename: Peter
authors.initials: P
authors.lastname: Weiss
authors.forename: Gert
authors.initials: G
authors.lastname: Jakobi
authors.forename: Manfred
authors.initials: M
authors.lastname: Kirchner
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Moche
authors.forename: Katharina
authors.initials: K
authors.lastname: Braun
authors.forename: Karl-Werner
authors.initials: KW
authors.lastname: Schramm
mesh_terms: D000393:Air Pollutants / Q000032:analysis*; D000531:Altitude; D006843:Hydrocarbons, Chlorinated / Q000032:analysis*; D010575:Pesticides / Q000032:analysis*; D028222:Picea / Q000737:chemistry*; D018515:Plant Leaves / Q000737:chemistry*; D012621:Seasons; D012989:Soil Pollutants / Q000032:analysis*
chemical_list: D000393:Air Pollutants; D006843:Hydrocarbons, Chlorinated; D010575:Pesticides; D012989:Soil Pollutants