Phenomenological local field enhancement factor distributions around electromagnetic hot spots.
We propose a general phenomenological description of the enhancement factor distribution for surface-enhanced Raman scattering (SERS) and other related phenomena exploiting large local field enhancements at hot spots. This description extends naturally the particular case of a single (fixed) hot spot, and it is expected to be "universal" for many classes of common SERS substrates containing a collection of electromagnetic hot spots with varying geometrical parameters. We further justify it from calculations with generalized Mie theory. The description studied here provides a useful starting point for a qualitative (and semiquantitative) understanding of experimental data and, in particular, the analysis of the statistics of single-molecule SERS events.
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The MacDiarmid Institute for Advanced Materials and Nanotechnology, School of Chemical and Physical Sciences, Victoria University of Wellington, P.O. Box 600, Wellington 6140, New Zealand. eric.leru@vuw.ac.nz
Etchegoin
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