title: Hydrogen-bonding interactions of (CF3)3CH and (CF3)3C- in the gas phase. An experimental (FT-ICR) and computational study.
abstract: Hydrogen-bonding interactions involving 2-(trifluoromethyl)-1,1,1,3,3,3-hexafluoropropane (1H) and 1(-) have been quantitatively studied by means of Fourier transform ion cyclotron resonance spectrometry. The existence of the species (1HCl)(-) and (1H1)(-) was demonstrated, and their thermodynamic stabilities were determined experimentally and computationally. In addition, some of their structural features were analyzed.
authors.affiliation: Instituto de Química Física Rocasolano, CSIC, C/Serrano 119, E-28006 Madrid, Spain.
authors.forename: Andrés
authors.initials: A
authors.lastname: Guerrero
authors.forename: Rebeca
authors.initials: R
authors.lastname: Herrero
authors.forename: Juan Z
authors.initials: JZ
authors.lastname: Dávalos
authors.forename: Ivar
authors.initials: I
authors.lastname: Koppel
authors.forename: José-Luis M
authors.initials: JL
authors.lastname: Abboud
authors.forename: Antonio
authors.initials: A
authors.lastname: Chana
authors.forename: Ilmar A
authors.initials: IA
authors.lastname: Koppel