title: Radical pairs with rotational fluidity in the photochemical reaction of acetophenone and cyclohexane in the zeolite NAY: a (13)C CPMAS NMR and product analysis study.
abstract: The photochemical reaction of acetophenone and cyclohexane in the zeolite NaY occurs by combination of the geminate radical pairs to give products that reveal a significant amount of rotational fluidity, which was also documented by intermolecular nuclear dipolar interaction measurements using cross polarization (13)C NMR (CPMAS) experiments.
authors.affiliation: Mount St. Mary's College, Los Angeles, CA 90049, USA.
authors.forename: Ammee
authors.initials: A
authors.lastname: Amboya
authors.forename: Tina
authors.initials: T
authors.lastname: Nguyen
authors.forename: T Hien
authors.initials: TH
authors.lastname: Huynh
authors.forename: Ashley
authors.initials: A
authors.lastname: Brown
authors.forename: Gretchen
authors.initials: G
authors.lastname: Ratliff
authors.forename: Heather
authors.initials: H
authors.lastname: Yonutas
authors.forename: Deniz
authors.initials: D
authors.lastname: Cizmeciyan
authors.forename: Arunkumar
authors.initials: A
authors.lastname: Natarajan
authors.forename: Miguel A
authors.initials: MA
authors.lastname: Garcia Garibay
mesh_terms: D000098:Acetophenones / Q000737:chemistry*; D002247:Carbon Isotopes; D003510:Cyclohexanes / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D055668:Photochemical Processes; D017641:Zeolites / Q000737:chemistry*
chemical_list: D000098:Acetophenones; D002247:Carbon Isotopes; D003510:Cyclohexanes; D017641:Zeolites; C506365:Cyclohexane; C038699:acetophenone