A porous 3D heterometal-organic framework containing both lanthanide and high-spin Fe(ii) ions.
The first porous 3D [Ln-Fe] heterometal-organic frameworks incorporating high-spin Fe(ii) ions were structurally characterized with fascinating 1D channels and higher thermal stability: the robust frameworks still keep intact on removing free H(2)O or adsorbing C(2)H(5)OH, and the luminescence of [Eu-Fe] complex displays selective detection of Mg(2+).
Zhao
Bin
B
Department of Chemistry, Nankai University, Tianjin, 300071, P.R. China.
Chen
Xiao-Yan
XY
Chen
Zhi
Z
Shi
Wei
W
Cheng
Peng
P
Yan
Shi-Ping
SP
Liao
Dai-Zheng
DZ