Electroanalytical method for determination of lead(II) in orange and apple using kaolin modified platinum electrode.
This paper reports on the use of platinum electrode modified with kaolin (K/Pt) and square wave voltammetry for analytical detection of trace lead(II) in pure water, orange and apple samples. The electroanalytical procedure for determination of the Pb(II) comprises two steps: the chemical accumulation of the analyte under open-circuit conditions followed by the electrochemical detection of the preconcentrated species using square wave voltammetry. The analytical performances of the extraction method has been explored by studying the incubating time, and effect of interferences due to other ions. During the preconcentration step, Pb(II) was accumulated on the surface of the kaolin. The observed detection and quantification limits in pure water were 3.6x10(-9)molL(-1) and 1.2x10(-8)molL(-1), respectively. The precision of the method was also determined; the results was 2.35% (n=5).
El Mhammedi
M A
MA
Université Hassan, Kouribga, Morocco. elmhammedi@yahoo.fr
Achak
M
M
Bakasse
M
M
Chtaini
A
A
D002957:Citrus / Q000737:chemistry*; D055664:Electrochemical Techniques / Q000379:methods*; D004566:Electrodes; D005506:Food Contamination / Q000032:analysis*; D007616:Kaolin / Q000737:chemistry*; D007854:Lead / Q000032:analysis*; D027845:Malus / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry*; D011199:Potentiometry
D007616:Kaolin; D007854:Lead; D010984:Platinum