title: Octacyanometalate-based ferrimagnetic M(V)Mn(III) (M = Mo, W) bimetallic chain racemates with slow magnetic relaxations.
abstract: Cyanide-bridged M(V)-Mn(III) (M = Mo, W) bimetallic chain complexes with racemic spatial dispositions were constructed by self-assembling [M(CN)(8)](3-) precursors and Mn(III) Schiff bases. Antiferromagnetic couplings between spin centers within a chain result in a ferrimagnetic nature, and slow magnetic relaxations are observed as well.
authors.affiliation: Department of Chemistry (BK21), Korea University, Seoul 136-713, Korea.
authors.forename: Houng Sik
authors.initials: HS
authors.lastname: Yoo
authors.forename: Hyun Hee
authors.initials: HH
authors.lastname: Ko
authors.forename: Dae Won
authors.initials: DW
authors.lastname: Ryu
authors.forename: Jin Wuk
authors.initials: JW
authors.lastname: Lee
authors.forename: Jung Hee
authors.initials: JH
authors.lastname: Yoon
authors.forename: Woo Ram
authors.initials: WR
authors.lastname: Lee
authors.forename: Hyoung Chan
authors.initials: HC
authors.lastname: Kim
authors.forename: Eui Kwan
authors.initials: EK
authors.lastname: Koh
authors.forename: Chang Seop
authors.initials: CS
authors.lastname: Hong
mesh_terms: D006860:Hydrogen Bonding; D008280:Magnetics; D008670:Metals / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D008670:Metals