title: Experimental aspects of combined NOx and SO2 removal from flue-gas mixture in an integrated wet scrubber-electrochemical cell system.
abstract: The objective of this work was to study the effect of some operating conditions on the simultaneous removal of NO(x) and SO2 from simulated NO-SO2-air flue-gas mixtures in a scrubber column. The gaseous components were absorbed into 6M HNO3 electrolyte in the scrubber in a counter-current mode, and were oxidatively removed by the Ag(II) mediator oxidant electrochemically generated in an electrochemical cell set-up. The integration of the electrochemical cell with the scrubber set-up ensured continuous regeneration of the Ag(II) mediator and its repeated reuse for NO(x) and SO2 removal purpose, thereby avoiding: (1) the usage of chemicals continuously for oxidation and (2) the production of secondary waste. The influences of packing material (raschig glass rings, raschig poly(vinylidene) fluoride rings, Jaeger tri-pack perfluoroalkoxy spheres), feed concentrations of NO and SO2 (100-400 ppm NO and 100-400 ppm SO2), superficial gas velocity (0.061-0.61ms(-1)) and liquid velocity (0.012-0.048 ms(-1)) were investigated. The raschig glass rings with high surface area provided highest NO removal efficiency. NO and NO(x) showed decreasing abatement at higher feed concentrations. The removal of nitrogen components was faster and also greater, when SO2 co-existed in the feed. Whereas the gas flow rate decreased the removal efficiency, the liquid flow rate increased it for NO and NOx. The flow rate effects were analyzed in terms of gas/liquid residence time and superficial liquid velocity/superficial gas velocity ratio. SO2 removal was total under all conditions.
authors.affiliation: Department of Chemical Engineering, Sunchon National University, # 315 Maegok Dong, Suncheon 540-742, Chonnam, Republic of Korea. kc_pillai@yahoo.com
authors.forename: K
authors.initials: K
authors.lastname: Chandrasekara Pillai
authors.forename: Sang Joon
authors.initials: SJ
authors.lastname: Chung
authors.forename: T
authors.initials: T
authors.lastname: Raju
authors.forename: Il-Shik
authors.initials: IS
authors.lastname: Moon
mesh_terms: D000042:Absorption; D000388:Air; D004563:Electrochemistry / Q000295:instrumentation*; D017942:Nitric Acid / Q000737:chemistry; D009589:Nitrogen Oxides / Q000737:chemistry / Q000302:isolation & purification*; D010084:Oxidation-Reduction; D012835:Silver Nitrate / Q000737:chemistry; D013458:Sulfur Dioxide / Q000737:chemistry / Q000302:isolation & purification*; D013997:Time Factors; D014867:Water / Q000737:chemistry
chemical_list: D009589:Nitrogen Oxides; D014867:Water; D013458:Sulfur Dioxide; D017942:Nitric Acid; D012835:Silver Nitrate