Design of bicyclic and cage boron compounds based on allylboration of acetylenes with allyldichloroboranes.
Allylboration of acetylenes with allyldichloroboranes has been proposed as a first step of allylboron-acetylene condensation and a way to design condensation products from stage to stage. The chemistry has been applied to the synthesis of isomeric 3-borabicyclo[3.3.1]non-6-enes transformed into 3-methyl-1-boraadamantane and [5-D]-3-methyl-1-boraadamantane derivatives.
Erdyakov
Sergey Yu
SY
N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia 119991.
Ignatenko
Anatolii V
AV
Potapova
Tamara V
TV
Lyssenko
Konstantin A
KA
Gurskii
Mikhail E
ME
Bubnov
Yuri N
YN