Structural link between giant molybdenum oxide based ions and derived Keggin structure: modular assemblies based on the [BW11O39]9- ion and pentagonal {M'M5} units (M' = W; M = Mo,W).
Linked to the Pentagon: The addition of molybdate to [HBW(11)O(39)](8-) ions leads to the formation of mixed pentagonal units {W(Mo(5))} and {W(WMo(4))} trapped as linkers in the resulting modular assemblies, thus establishing the first link between the conventional Keggin ion derivatives and the giant molybdenum oxide and keplerate ions.
Leclerc-Laronze
Nathalie
N
Université de Versailles Saint Quentin, Institut Lavoisier de Versailles, ILV, UMR CNRS 8180, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France.
Marrot
Jérôme
J
Thouvenot
René
R
Cadot
Emmanuel
E
D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D007477:Ions / Q000737:chemistry*; D008968:Molecular Conformation; D008982:Molybdenum / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry*; D017973:Tungsten Compounds / Q000737:chemistry
D007477:Ions; D009942:Organometallic Compounds; D010087:Oxides; D017973:Tungsten Compounds; C539565:molybdenum dioxide; D008982:Molybdenum