title: Hydrogen evolution at liquid-liquid interfaces.
abstract: Blowing bubbles: Hydrogen evolution by proton reduction with [(C(5)Me(5))(2)Fe] occurs at a soft interface between water and 1,2-dichloroethane (DCE). The reaction proceeds by proton transfer assisted by [(C(5)Me(5))(2)Fe] across the water-DCE interface with subsequent proton reduction in DCE. The interface essentially acts as a proton pump, allowing hydrogen evolution by directly using the aqueous proton.
authors.affiliation: Laboratoire d'Electrochimie Physique et Analytique, Ecole Polytechnique Fédérale de Lausanne, Station 6, 1015 Lausanne, Switzerland.
authors.forename: Imren
authors.initials: I
authors.lastname: Hatay
authors.forename: Bin
authors.initials: B
authors.lastname: Su
authors.forename: Fei
authors.initials: F
authors.lastname: Li
authors.forename: Raheleh
authors.initials: R
authors.lastname: Partovi-Nia
authors.forename: Heron
authors.initials: H
authors.lastname: Vrubel
authors.forename: Xile
authors.initials: X
authors.lastname: Hu
authors.forename: Mustafa
authors.initials: M
authors.lastname: Ersoz
authors.forename: Hubert H
authors.initials: HH
authors.lastname: Girault