A bimetallic pillared-layer metal-organic coordination framework with a 3D biporous structure.
A novel bimetallic [Mn(ii)-Fe(iii)] 3D biporous pillared-layer metal-organic coordination framework constructed by a cyanometallate anion ([Fe(CN)(6)](3-)) and an organic linker (4,4'-bipy) is found to exhibit permanent porosity with excellent size selective vapour sorption properties and H(2)-storage capability.
Maji
Tapas Kumar
TK
Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, 560 064, India. tmaji@jncasr.ac.in
Pal
Suchetan
S
Gurunatha
K L
KL
Govindaraj
A
A
Rao
C N R
CN