Enantiospecific synthesis of [2.2]paracyclophane-4-thiol and derivatives.
This paper describes a simple route to enantiomerically enriched [2.2]paracyclophane-4-thiol via the stereospecific introduction of a chiral sulfoxide to the [2.2]paracyclophane skeleton. The first synthesis of an enantiomerically enriched planar chiral benzothiazole is also reported.
Rowlands
Gareth J
GJ
Institute of Fundamental Sciences, Massey University, Private Bag 11 222, Palmerston North, New Zealand. g.j.rowlands@massey.ac.nz
Seacome
Richard J
RJ