Temperature dependence of the primary relaxation in 1-hexyl-3-methylimidazolium bis{(trifluoromethyl)sulfonyl}imide.
We present results from complementary characterizations of the primary relaxation rate of a room temperature ionic liquid (RTIL), 1-hexyl-3-methylimidazolium bis{(trifluoromethyl)sulfonyl} imide, [C6mim][Tf2N], over a wide temperature range. This extensive data set is successfully merged with existing literature data for conductivity, viscosity, and NMR diffusion coefficients thus providing, for the case of RTILs, a unique description of the primary process relaxation map over more than 12 decades in relaxation rate and between 185 and 430 K. This unique data set allows a detailed characterization of the VTF parameters for the primary process, that are: B=890 K, T0=155.2 K, leading to a fragility index m=71, corresponding to an intermediate fragility. For the first time neutron spin echo data from a fully deuteriated sample of RTIL at the two main interference peaks, Q=0.76 and 1.4 A(-1) are presented. At high temperature (T>250 K), the collective structural relaxation rate follows the viscosity behavior; however at lower temperatures it deviates from the viscosity behavior, indicating the existence of a faster process.
Russina
Olga
O
Istituto per i Processi Chimico-Fisici, Consiglio Nazionale delle Ricerche, Salita Sperone, C. da Papardo, 98158 Faro Superiore, Messina, Italy.
Beiner
Mario
M
Pappas
Catherine
C
Russina
Margarita
M
Arrighi
Valeria
V
Unruh
Tobias
T
Mullan
Claire L
CL
Hardacre
Christopher
C
Triolo
Alessandro
A