A direct route to bifunctional aldehyde derivatives via self- and cross-metathesis of unsaturated aldehydes.
Ruthenium-catalyzed self- and cross-metathesis, with acrolein, acrylonitrile, acrylic acid and methylacrylate, of the bioresource undecylenic aldehyde leads to a variety of unsaturated omega-functional aldehydes. Tandem olefin metathesis/hydrogenation catalytic reactions afford saturated C(20) and C(12) diols in good yields.
Miao
Xiaowei
X
Institut Sciences Chimiques de Rennes, UMR CNRS-Université de Rennes, France.
Fischmeister
Cédric
C
Bruneau
Christian
C
Dixneuf
Pierre H
PH
D000171:Acrolein; D000179:Acrylates; D000181:Acrylonitrile; D000438:Alcohols / Q000138:chemical synthesis; D000447:Aldehydes / Q000138:chemical synthesis* / Q000737:chemistry; D000498:Allyl Compounds / Q000737:chemistry*; D055772:Green Chemistry Technology / Q000379:methods; D006865:Hydrogenation; D012428:Ruthenium
D000179:Acrylates; D000438:Alcohols; D000447:Aldehydes; D000498:Allyl Compounds; D000171:Acrolein; D012428:Ruthenium; D000181:Acrylonitrile