Total synthesis of (+)-19-deoxyicetexone, (-)-icetexone, and (+)-5-epi-icetexone.
The first asymmetric total syntheses of 19-deoxyicetexone, icetexone, and 5-epi-icetexone was achieved from epimeric tricyclic dienes.
Majetich
George
G
Department of Chemistry, University of Georgia, Athens, Georgia 30602, USA. majetich@chem.uga.edu
Grove
Jeremy L
JL
D001688:Biological Products / Q000138:chemical synthesis* / Q000737:chemistry; D004224:Diterpenes / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D019906:Nuclear Magnetic Resonance, Biomolecular; D013237:Stereoisomerism
C542301:19-deoxyicetexone; D001688:Biological Products; D004224:Diterpenes; C512853:icetexone