title: Two-dimensional coordination polymer matrix for solid-phase extraction of pesticide residues from plant Cordia salicifolia.
abstract: The 2D coordination polymer (infinity[Gd(DPA)(HDPA)]) was tested for extraction of acephate, chlorpropham, pirimicarb, bifenthrin, tetradifon, and phosalone from the medicinal plant Cordia salicifolia, whose extracts are commercialized in Brazil as diuretic, appetite suppressant, and weight loss products, using GC/MS, SIM. Considering that there are no Brazilian regulations concerning maximum permissible pesticide residue concentrations in medicinal herbs, recovery experiments were carried out (seven replicates), at two arbitrary fortification levels (0.5 and 1.0 mg/kg), resulting in recoveries in range of 20 to 107.7% and SDRSDs were between 5.6 and 29.1% for infinity[Gd(DPA)(HDPA)] sorbent. Detection and quantification limits for herb ranged from 0.10 to 0.15 mg/kg and from 0.15 to 0.25 mg/kg, respectively, for the different pesticides studied. The developed method is linear over the range assayed, 0.5-10.0 microg/mL, with correlation coefficients ranging from 0.9975 to 0.9986 for all pesticides. Comparison between infinity[Gd(DPA)(HDPA)] sorbent and conventional sorbent (neutral alumina) showed similar performance of infinity[Gd(DPA)(HDPA)] polymeric sorbent for three (bifenthrin, tetradifon, and phosalone) out of six pesticides tested.
authors.affiliation: Departamento de Química, Universidade Federal de Sergipe, São Cristóvão, SE, Brazil.
authors.forename: Pedro Henrique Viana
authors.initials: PH
authors.lastname: de Carvalho
authors.forename: Alysson Santos
authors.initials: AS
authors.lastname: Barreto
authors.forename: Marcelo O
authors.initials: MO
authors.lastname: Rodrigues
authors.forename: Vanessa de Menezes
authors.initials: Vde M
authors.lastname: Prata
authors.forename: Péricles Barreto
authors.initials: PB
authors.lastname: Alves
authors.forename: Maria Eliane
authors.initials: ME
authors.lastname: de Mesquita
authors.forename: Severino
authors.initials: S
authors.lastname: Alves
authors.forename: Sandro
authors.initials: S
authors.lastname: Navickiene
mesh_terms: D000327:Adsorption; D001938:Brazil; D031213:Cordia / Q000737:chemistry*; D005682:Gadolinium / Q000737:chemistry; D008401:Gas Chromatography-Mass Spectrometry / Q000295:instrumentation / Q000379:methods; D006801:Humans; D010573:Pesticide Residues / Q000032:analysis*; D010946:Plants, Medicinal / Q000737:chemistry; D011108:Polymers / Q000737:chemistry*; D052616:Solid Phase Extraction / Q000295:instrumentation / Q000379:methods
chemical_list: D010573:Pesticide Residues; D011108:Polymers; D005682:Gadolinium