One-step conversion of unprotected sugars to beta-glycosyl azides using 2-chloroimidazolinium salt in aqueous solution.
Various beta-glycosyl azides have been synthesized directly in water by the reaction of unprotected sugars and sodium azide mediated by 2-chloro-1,3-dimethylimidazolinium chloride (DMC).
Tanaka
Tomonari
T
Department of Biomolecular Engineering, Graduate School of Engineering, Tohoku University, Aoba, Sendai, Miyagi 980-8579, Japan.
Nagai
Hikaru
H
Noguchi
Masato
M
Kobayashi
Atsushi
A
Shoda
Shin-Ichiro
S
D001386:Azides / Q000737:chemistry*; D002241:Carbohydrates / Q000737:chemistry*; D006031:Glycosylation; D048288:Imidazolines / Q000737:chemistry*; D009844:Oligosaccharides / Q000737:chemistry; D012996:Solutions; D014867:Water / Q000737:chemistry*
C542549:2-chloroimidazolinium; D001386:Azides; D002241:Carbohydrates; D048288:Imidazolines; D009844:Oligosaccharides; D012996:Solutions; D014867:Water