Effects of particulates, heavy metals and acid gas on the removals of NO and PAHs by V2O5-WO3 catalysts in waste incineration system.
This study investigated the activities of prepared and commercial V(2)O(5)-WO(3) catalysts for simultaneous removals of NO and polycyclic aromatic hydrocarbons (PAHs) and the influences of particulates, heavy metals, SO(2), and HCl on the performances of catalysts. The experiments were carried out in a laboratory-scale waste incineration system equipped with a catalyst reactor. The DREs of PAHs by prepared and commercial V(2)O(5)-WO(3) catalysts were 64% and 72%, respectively. Increasing the particulate concentrations in flue gas suppressed the DRE of PAHs, but increasing the carbon content on surface of catalysts promotes the NO conversions. The DRE of PAHs by the catalysts was significantly decreased by the increased concentrations of heavy metal Cd, but was promoted by high concentration of Pb. The influence level of SO(2) was higher than HCl on the performances of V(2)O(5)-WO(3) catalysts for PAHs removal, but was lower than HCl for NO removal. Prepared and commercial V(2)O(5)-WO(3) catalysts have similar trends on the effects of particulates, heavy metals, SO(2), and HCl. The results of ESCA analysis reveal that the presence of these pollutants on the surface of catalysts did not change the chemical state of V and W.
Chang
Feng-Yim
FY
Department of Environmental Engineering, National Chung Hsing University, Taichung 402, Taiwan, ROC.
Chen
Jyh-Cherng
JC
Wey
Ming-Yen
MY
Tsai
Shih-An
SA
D000143:Acids; D002384:Catalysis; D004785:Environmental Pollutants / Q000737:chemistry; D005740:Gases; D006256:Hazardous Waste / Q000517:prevention & control; D017745:Incineration / Q000379:methods*; D007220:Industrial Waste / Q000517:prevention & control*; D019216:Metals, Heavy; D009569:Nitric Oxide / Q000737:chemistry*; D010087:Oxides; D052638:Particulate Matter; D010865:Pilot Projects; D011084:Polycyclic Aromatic Hydrocarbons / Q000737:chemistry*; D014414:Tungsten; D017968:Vanadium Compounds
D000143:Acids; D004785:Environmental Pollutants; D005740:Gases; D006256:Hazardous Waste; D007220:Industrial Waste; D019216:Metals, Heavy; D010087:Oxides; D052638:Particulate Matter; D011084:Polycyclic Aromatic Hydrocarbons; D017968:Vanadium Compounds; D009569:Nitric Oxide; C511604:tungsten oxide; D014414:Tungsten