Mechanistic insights into a copper-disulfide interaction in oxidation of imines by disulfides.
The concept of using disulfides as an oxidant for Cu(i) is introduced as part of a Cu-catalyzed process leading to the formation of benzothiazole from an iminodisulfide under an inert atmosphere.
Srogl
Jiri
J
Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo nám. 2, 166 10 Praha 6. jsrogl@uochb.cas.cz
Hývl
Jakub
J
Révész
Agnes
A
Schröder
Detlef
D