Hydrogen evolution at liquid-liquid interfaces.
Blowing bubbles: Hydrogen evolution by proton reduction with [(C(5)Me(5))(2)Fe] occurs at a soft interface between water and 1,2-dichloroethane (DCE). The reaction proceeds by proton transfer assisted by [(C(5)Me(5))(2)Fe] across the water-DCE interface with subsequent proton reduction in DCE. The interface essentially acts as a proton pump, allowing hydrogen evolution by directly using the aqueous proton.
Hatay
Imren
I
Laboratoire d'Electrochimie Physique et Analytique, Ecole Polytechnique Fédérale de Lausanne, Station 6, 1015 Lausanne, Switzerland.
Su
Bin
B
Li
Fei
F
Partovi-Nia
Raheleh
R
Vrubel
Heron
H
Hu
Xile
X
Ersoz
Mustafa
M
Girault
Hubert H
HH