title: Delamination and adhesive wear behavior of alpha-tocopherol-stabilized irradiated ultrahigh-molecular-weight polyethylene.
abstract: Wear and delamination of conventional ultrahigh-molecular-weight polyethylene (UHMWPE) components used in total knee arthroplasty can compromise long-term performance. Radiation cross-linking and melt-annealing reduced wear and increased delamination resistance of UHMWPE. An alternative material is the alpha-tocopherol-stabilized irradiated UHMWPE (alphaTPE), with improved mechanical and fatigue properties vs irradiated and melted UHMWPE. We studied the wear and delamination resistance of alphaTPE and conventional UHMWPE (direct compression molded GUR 1050 and Himont 1900) under reciprocating unidirectional motion. Wear resistance was improved, and no delamination was observed in alphaTPE. Accelerated aging did not alter the wear and delamination behavior of alphaTPE. The GUR 1050 UHMWPE showed delamination and pitting when subjected to unidirectional reciprocating motion after accelerated aging. Himont 1900 UHMWPE showed no delamination when subjected to unidirectional reciprocating motion after accelerated aging. alpha-Tocopherol-stabilized irradiated UHMWPE is advanced for use in total knee arthroplasty due to its high resistance to wear, delamination, and oxidation.
authors.affiliation: Harris Orthopedic Biomaterials and Biomechanics Laboratory, Massachusetts General Hospital, Boston, Massachusetts 02114, USA.
authors.forename: Keith K
authors.initials: KK
authors.lastname: Wannomae
authors.forename: Steven D
authors.initials: SD
authors.lastname: Christensen
authors.forename: Brad R
authors.initials: BR
authors.lastname: Micheli
authors.forename: Shannon L
authors.initials: SL
authors.lastname: Rowell
authors.forename: Dave W
authors.initials: DW
authors.lastname: Schroeder
authors.forename: Orhun K
authors.initials: OK
authors.lastname: Muratoglu
mesh_terms: D019645:Arthroplasty, Replacement, Knee / Q000295:instrumentation*; D001672:Biocompatible Materials; D019544:Equipment Failure Analysis; D007720:Knee Prosthesis; D008422:Materials Testing; D010084:Oxidation-Reduction; D011095:Polyethylenes; D011474:Prosthesis Design; D011475:Prosthesis Failure; D024502:alpha-Tocopherol
chemical_list: D001672:Biocompatible Materials; D011095:Polyethylenes; D024502:alpha-Tocopherol