Cation-induced molecular orbital modulations and supramolecular formation of a 15-crown-5-substituted tribenzotetraazachlorin-C60 conjugate.
A tribenzotetraazachlorin (TBTAC)-C(60) conjugate having three 15-crown-5 units as substituents, , has been synthesized, and the electronic and supramolecular structure modulations in the presence of Na(+) or K(+) have been elucidated by means of massmetric and spectroscopic techniques.
Fukuda
Takamitsu
T
Department of Chemistry, Graduate School of Science, Tohoku University, 980-8578 Sendai, Japan.
Sugita
Ippei
I
Kobayashi
Nagao
N