Octacyanometalate-based ferrimagnetic M(V)Mn(III) (M = Mo, W) bimetallic chain racemates with slow magnetic relaxations.
Cyanide-bridged M(V)-Mn(III) (M = Mo, W) bimetallic chain complexes with racemic spatial dispositions were constructed by self-assembling [M(CN)(8)](3-) precursors and Mn(III) Schiff bases. Antiferromagnetic couplings between spin centers within a chain result in a ferrimagnetic nature, and slow magnetic relaxations are observed as well.
Yoo
Houng Sik
HS
Department of Chemistry (BK21), Korea University, Seoul 136-713, Korea.
Ko
Hyun Hee
HH
Ryu
Dae Won
DW
Lee
Jin Wuk
JW
Yoon
Jung Hee
JH
Lee
Woo Ram
WR
Kim
Hyoung Chan
HC
Koh
Eui Kwan
EK
Hong
Chang Seop
CS
D006860:Hydrogen Bonding; D008280:Magnetics; D008670:Metals / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D013237:Stereoisomerism
D008670:Metals