Functional group compatibility. Propargyl alcohol reduction in the presence of a vinyl iodide.
Vinyl iodides are stable to the reduction of propargyl alcohols to cis allylic alcohols by hydrogen over Pd/CaCO(3) in hexane. They are also stable to the reduction of propargyl alcohols to saturated alcohols by hydrogen over Crabtree's iridium catalyst in CH(2)Cl(2).
Denton
Richard W
RW
Department of Chemistry, SUNY Stony Brook, Stony Brook, New York 11794-3400, USA.
Parker
Kathlyn A
KA
D000480:Alkynes / Q000737:chemistry*; D002119:Calcium Carbonate / Q000737:chemistry; D002384:Catalysis; D006847:Hydrocarbons, Iodinated / Q000737:chemistry*; D007495:Iridium / Q000737:chemistry; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010165:Palladium / Q000737:chemistry; D020005:Propanols / Q000737:chemistry*; D013237:Stereoisomerism; D014753:Vinyl Compounds / Q000737:chemistry*
D000480:Alkynes; D006847:Hydrocarbons, Iodinated; D020005:Propanols; D014753:Vinyl Compounds; C006463:allyl alcohol; D007495:Iridium; D010165:Palladium; C028255:propargyl alcohol; D002119:Calcium Carbonate