title: Advanced supramolecular initiator for nitroxide-mediated polymerizations containing both metal-ion coordination and hydrogen-bonding sites.
abstract: The synthesis of a new difunctional nitroxide initiator combining two orthogonal supramolecular entities is reported; controlled radical polymerization of styrene using this initiator is demonstrated to generate well-defined heterotelechelic polymers in a one-step procedure.
authors.affiliation: Laboratory of Organic and Macromolecular Chemistry, Friedrich-Schiller-Universität Jena, Humboldtstrasse 10, 07743 Jena, Germany.
authors.forename: Ulrich
authors.initials: U
authors.lastname: Mansfeld
authors.forename: Martin D
authors.initials: MD
authors.lastname: Hager
authors.forename: Richard
authors.initials: R
authors.lastname: Hoogenboom
authors.forename: Christina
authors.initials: C
authors.lastname: Ott
authors.forename: Andreas
authors.initials: A
authors.lastname: Winter
authors.forename: Ulrich S
authors.initials: US
authors.lastname: Schubert