title: A synthesis of an ionomycin calcium complex.
abstract: Caught in the middle: The ionomycin calcium complex (see structure; O red, Ca green) was the target of an approach featuring the efficient asymmetric synthesis of an allene by a copper(I)-mediated anti-selective S(N)2' reaction, a highly stereoselective gold(III)-catalyzed cycloisomerization of an alpha-hydroxyallene, and a Rh-catalyzed rearrangement of an alpha-diazo-beta-hydroxyketone.
authors.affiliation: The School of Chemistry and The Institute of Process Research and Development, Leeds University, Leeds LS2 9 JT, UK.
authors.forename: Zhanghua
authors.initials: Z
authors.lastname: Gao
authors.forename: Yingfa
authors.initials: Y
authors.lastname: Li
authors.forename: John P
authors.initials: JP
authors.lastname: Cooksey
authors.forename: Thomas N
authors.initials: TN
authors.lastname: Snaddon
authors.forename: Stefan
authors.initials: S
authors.lastname: Schunk
authors.forename: Eddy M E
authors.initials: EM
authors.lastname: Viseux
authors.forename: Stephen M
authors.initials: SM
authors.lastname: McAteer
authors.forename: Philip J
authors.initials: PJ
authors.lastname: Kocienski
mesh_terms: D000900:Anti-Bacterial Agents / Q000737:chemistry; D002118:Calcium / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D006046:Gold / Q000737:chemistry; D015759:Ionomycin / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000900:Anti-Bacterial Agents; D015759:Ionomycin; D006046:Gold; D002118:Calcium