Influence of steaming explosion time on the physic-chemical properties of cellulose from Lespedeza stalks (Lespedeza crytobotrya).
The synergistic effect of steam explosion pretreatment and sodium hydroxide post-treatment of Lespedeza stalks (Lespedeza crytobotrya) has been investigated in this study. In this case, Lespedeza stalks were firstly exploded at a fixed steam pressure (22.5 kg/m(2)) for 2-10 min. Then the steam-exploded Lespedeza stalks was extracted with 1 M NaOH at 50 degrees C for 3 h with a shrub to water ratio of 1:20 (g/ml), which yielded 57.3%, 53.1%, 55.4%, 52.8%, 53.2%, and 56.4% (% dry weight) cellulose rich fractions, comparing to 68.0% from non-steam-exploded material. The content of glucose in cellulose rich residues increased with increment of the steaming time and reached to 94.10% at the most severity. The similar increasing trend occurred during the dissolution of hemicelluloses. It is evident that at shorter steam explosion time, autohydrolysis mainly occurred on the hemicelluloses and the amorphous area of cellulose. The crystalline region of cellulose was depolymerized under a prolonged incubation time. The characteristics of the cellulose rich fractions in terms of FT-IR and CP/MAS (13)C NMR spectroscopy and thermal analysis were discussed, and the surface structure was also investigated by SEM.
Wang
Kun
K
Institute of Biomass Chemistry and Technology, Beijing Forestry University, Beijing 100083, China.
Jiang
Jian-Xin
JX
Xu
Feng
F
Sun
Run-Cang
RC
D018533:Biomass; D002482:Cellulose / Q000737:chemistry*; D003460:Crystallization; D004055:Differential Thermal Analysis; D029884:Lespedeza / Q000737:chemistry*; D008031:Lignin / Q000032:analysis; D009682:Magnetic Resonance Spectroscopy; D010636:Phenols / Q000032:analysis; D017550:Spectroscopy, Fourier Transform Infrared; D013227:Steam; D013696:Temperature; D013818:Thermogravimetry; D013997:Time Factors; D014574:Uronic Acids / Q000032:analysis
D010636:Phenols; D013227:Steam; D014574:Uronic Acids; D002482:Cellulose; D008031:Lignin