title: One metal-two pathways to the carboxylate-enhanced, iron-containing quercetinase mimics.
abstract: Mononuclear iron(iii) flavonolate was synthesized as synthetic enzyme-substrate complex, and its direct and carboxylate-enhanced dioxygenation as biomimetic functional models with relevance to flavonol 2,4-dioxygenase are briefly described.
authors.affiliation: Department of Chemistry, University of Pannonia, 8201 Veszprém, Hungary.
authors.forename: Gábor
authors.initials: G
authors.lastname: Baráth
authors.forename: József
authors.initials: J
authors.lastname: Kaizer
authors.forename: Gábor
authors.initials: G
authors.lastname: Speier
authors.forename: László
authors.initials: L
authors.lastname: Párkányi
authors.forename: Erno
authors.initials: E
authors.lastname: Kuzmann
authors.forename: Attila
authors.initials: A
authors.lastname: Vértes
mesh_terms: D040761:Biomimetic Materials / Q000138:chemical synthesis* / Q000737:chemistry; D002264:Carboxylic Acids / Q000737:chemistry*; D049308:Dioxygenases / Q000737:chemistry* / Q000378:metabolism; D007501:Iron / Q000737:chemistry*; D007700:Kinetics; D008958:Models, Molecular; D015394:Molecular Structure; D013053:Spectrophotometry
chemical_list: D002264:Carboxylic Acids; D007501:Iron; D049308:Dioxygenases; C003281:quercetin 2,3-dioxygenase