title: Adsorption of dextrin on hydrophobic minerals.
abstract: The adsorption of dextrin on talc, molybdenite, and graphite (three naturally hydrophobic minerals) has been compared. Adsorption isotherms and in situ tapping mode atomic force microscope (TMAFM) imaging have enabled polymer adsorbed amount and morphology of the adsorbed layer (area coverage and polymer domain size) to be determined and also the amount of hydration water in the structure of the adsorbed layer. The effect of the polymer on the mineral contact angles, measured by the captive bubble method on cleaved mineral surfaces, indicates clear correlations between the hydrophobicity reduction of the minerals, the adsorbed amount, and the surface coverage of the adsorbed polymer. Predictions of the flotation recovery of the treated mineral phases have been confirmed by performing batch flotation experiments. The influence of the polymer surface coverage on flotation recovery has highlighted the importance of this key parameter in the predictions of depressant efficiency. The roles of the initial hydrophobicity and the surface structure of the mineral basal plane in determining adsorption parameters and flotation response of the polymer-treated minerals are also discussed.
authors.affiliation: Ian Wark Research Institute, ARC Special Research Centre for Particles and Material Interfaces, University of South Australia, Mawson Lakes SA 5095, Australia.
authors.forename: Audrey
authors.initials: A
authors.lastname: Beaussart
authors.forename: Agnieszka
authors.initials: A
authors.lastname: Mierczynska-Vasilev
authors.forename: David A
authors.initials: DA
authors.lastname: Beattie
mesh_terms: D000327:Adsorption; D003912:Dextrins / Q000737:chemistry*; D006108:Graphite / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D057927:Hydrophobic and Hydrophilic Interactions; D018625:Microscopy, Atomic Force / Q000379:methods; D008956:Models, Chemical; D008968:Molecular Conformation; D015394:Molecular Structure; D008982:Molybdenum / Q000737:chemistry; D010316:Particle Size; D011108:Polymers / Q000737:chemistry; D013499:Surface Properties; D013627:Talc / Q000737:chemistry; D014867:Water / Q000737:chemistry
chemical_list: D003912:Dextrins; D011108:Polymers; D014867:Water; D013627:Talc; D006108:Graphite; D008982:Molybdenum