Highly oxidized diiron complexes: generation, spectroscopy, and stabilities.
Oxidation of the diferric complex [LFe(III)OFe(III)L] to the monoradical complex [LFe(III)OFe(III)L ](+) and the diradical complex [L Fe(III)OFe(III)L ](2+) is followed by a decay into monomeric complexes including a highly reactive putative [LFe(IV)[double bond, length as m-dash]O] complex.
Strautmann
Julia Bernhardette Hildegard
JB
Fakultät für Chemie, Universität Bielefeld, 33615, Bielefeld, Germany.
Freiherr von Richthofen
Carl-Georg
CG
DeBeer George
Serena
S
Bothe
Eberhard
E
Bill
Eckhard
E
Glaser
Thorsten
T
D004563:Electrochemistry; D005290:Ferric Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D013057:Spectrum Analysis
D005290:Ferric Compounds; D010100:Oxygen