title: Characterisation and mechanical testing of hydrothermally treated HA/ZrO₂ composites.
abstract: Hydrothermal treatment is traditionally employed to improve the sinterability of powder compacts by reducing porosity and increasing apparent density. The effect of hydrothermal treatment on green powder compacts has been assessed in order to better understand how treatment may affect the sinterability of the bodies. Laboratory synthesised nano sized hydroxyapatite (HA) and a commercial zirconia (ZrO(2)) powder have been ball milled together to create composite mixtures containing 0-5 wt% ZrO(2) loadings. Disc shaped bodies have been formed using uniaxial and subsequent isostatic pressure. The resultant coherent samples were subjected to hydrothermal treatment at either 120 or 250 degrees C for 10 h in order to assess the effect of this processing technique on the physical, mechanical and microstructural properties of the green composites. ZrO(2) loadings up to 3 wt% increased apparent density from 90 to 92%, whereas increased loading to 5 wt% increased flexural strength, from 6 to 9 MPa. Increasing the hydrothermal treatment temperature increased open porosity, from ~44 to ~48% and reduced biaxial flexural strengths of the treated bodies compared to those of their room temperature isostatically pressed counterparts (~10 to ~6 MPa).
authors.affiliation: Clinical Materials Unit, Materials and Surface Science Institute, University of Limerick, National Technological Park, Limerick, Ireland.
authors.forename: D J
authors.initials: DJ
authors.lastname: Curran
authors.forename: T J
authors.initials: TJ
authors.lastname: Fleming
authors.forename: G
authors.initials: G
authors.lastname: Kawachi
authors.forename: C
authors.initials: C
authors.lastname: Ohtsuki
authors.forename: M R
authors.initials: MR
authors.lastname: Towler
mesh_terms: D001672:Biocompatible Materials / Q000737:chemistry*; D002118:Calcium / Q000737:chemistry; D017886:Durapatite / Q000737:chemistry*; D004867:Equipment Design; D008422:Materials Testing; D008855:Microscopy, Electron, Scanning / Q000379:methods; D036103:Nanotechnology / Q000379:methods; D010316:Particle Size; D010758:Phosphorus / Q000737:chemistry; D016062:Porosity; D011208:Powders; D011312:Pressure; D013314:Stress, Mechanical; D013499:Surface Properties; D013696:Temperature; D014961:X-Ray Diffraction; D015040:Zirconium / Q000737:chemistry*
chemical_list: D001672:Biocompatible Materials; D011208:Powders; D010758:Phosphorus; D017886:Durapatite; D015040:Zirconium; C028541:zirconium oxide; D002118:Calcium