title: Highly oxidized diiron complexes: generation, spectroscopy, and stabilities.
abstract: Oxidation of the diferric complex [LFe(III)OFe(III)L] to the monoradical complex [LFe(III)OFe(III)L ](+) and the diradical complex [L Fe(III)OFe(III)L ](2+) is followed by a decay into monomeric complexes including a highly reactive putative [LFe(IV)[double bond, length as m-dash]O] complex.
authors.affiliation: Fakultät für Chemie, Universität Bielefeld, 33615, Bielefeld, Germany.
authors.forename: Julia Bernhardette Hildegard
authors.initials: JB
authors.lastname: Strautmann
authors.forename: Carl-Georg
authors.initials: CG
authors.lastname: Freiherr von Richthofen
authors.forename: Serena
authors.initials: S
authors.lastname: DeBeer George
authors.forename: Eberhard
authors.initials: E
authors.lastname: Bothe
authors.forename: Eckhard
authors.initials: E
authors.lastname: Bill
authors.forename: Thorsten
authors.initials: T
authors.lastname: Glaser
mesh_terms: D004563:Electrochemistry; D005290:Ferric Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D013057:Spectrum Analysis
chemical_list: D005290:Ferric Compounds; D010100:Oxygen