Fabrication of silver decorated anodic aluminum oxide substrate and its optical properties on surface-enhanced Raman scattering and thin film interference.
In this paper, a simple method to fabricate a three-dimensional (3D) nanostructure decorated with Ag nanoparticles for surface-enhanced Raman scattering (SERS) is demonstrated. Highly ordered porous anodic aluminum oxide (AAO) templates were employed to construct these compound nanostructures. First, the AAO templates were fabricated using a two-step anodization approach. Second, an alternating current (AC) electrochemical deposition was used to fill AAO templates with Ag nanoparticles. Taking 4-mercaptopyridine (4-MPy) as the probing molecule, high-quality SERS spectra were observed. The UV-vis mirror reflection spectra were measured to investigate the surface plasma resonance (SPR) absorbance. An interesting phenomenon of SPR-affected thin film interference was observed. SERS mapping was performed to characterize the homogeneity of as-prepared substrates. Good homogeneity and stability make these substrates good candidates for SERS spectroscopy.
Ji
Nan
N
State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012, People's Republic of China.
Ruan
Weidong
W
Wang
Chunxu
C
Lu
Zhicheng
Z
Zhao
Bing
B
D000537:Aluminum Oxide / Q000737:chemistry*; D004553:Electric Conductivity; D004563:Electrochemistry; D004566:Electrodes; D053768:Metal Nanoparticles / Q000737:chemistry; D008855:Microscopy, Electron, Scanning; D055620:Optical Phenomena; D016062:Porosity; D012834:Silver / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D013059:Spectrum Analysis, Raman; D013499:Surface Properties
D012834:Silver; D000537:Aluminum Oxide