In situ generation of novel acyclic diaminocarbene-copper complex.
A novel acyclic diaminocarbene-copper complex appears to be generated from a chloroamidinium salt and Cu(I)-thiophenecarboxylate in the presence of Grignard reagent based on (13)C NMR studies and is a highly efficient catalyst for S(N)2'-allylic alkylation.
Hirsch-Weil
Dimitri
D
Department of Chemistry, University of Florida, Gainesville, 32611-7200, USA.
Snead
David R
DR
Inagaki
Sebastien
S
Seo
Hwimin
H
Abboud
Khalil A
KA
Hong
Sukwon
S