Heterometallic 3d-4f cubane clusters inserted in polyoxometalate matrices.
Unprecedented molecular and bidimensional compounds based on monovacant polyoxometalates capped by heterometallic 3d-4f {LnCu(3)(OH)(3)O} (Ln = La, Gd, Eu) cubane fragments have been characterized and their magnetic properties investigated.
Nohra
Brigitte
B
Institut Lavoisier de Versailles, UMR 8180, Université de Versailles Saint-Quentin, 78035, Versailles Cedex, France.
Mialane
Pierre
P
Dolbecq
Anne
A
Rivière
Eric
E
Marrot
Jérôme
J
Sécheresse
Francis
F
D028581:Lanthanoid Series Elements / Q000737:chemistry*; D008280:Magnetics; D008956:Models, Chemical; D008958:Models, Molecular; D015394:Molecular Structure; D013696:Temperature
D028581:Lanthanoid Series Elements