title: Trapping and decomposing of color compounds from recycled water by TiO(2) coated activated carbon.
abstract: Five types of commercially available activated carbons (ACs) were coated with TiO(2) nanoparticles prepared using a sol-gel method. Color and trace organics remaining in the actual treated effluent were adsorbed by TiO(2) coated ACs. The absorbed organic compounds were then decomposed using a photocatalytic process, and the ACs were regenerated for reuse. The efficiency of the process was assessed by the characterization of true color and A(254) (the organics absorption at the wavelength of 254nm) at the beginning and the end of the experiment. The effects of UV light source, UV irradiation time, hydrogen peroxide and ultrasound on the efficiency of photocatalytic regeneration were also investigated. Significant differences in the efficiency were observed between uncoated ACs and TiO(2) coated samples. Among the 5 types of ACs tested, AC-3, AC-4 and their coated ones achieved better efficiency in color and A(254) removal, with around 90% or more color and A(254) being removed within 1h of treatment. The data obtained in this study also demonstrated that the photocatalytic process was effective for decomposing the adsorbed compounds and regenerating the spent TiO(2)/AC-3. Finally, it was found that this regeneration process could be greatly enhanced with the assistance of H(2)O(2) and ultrasound by reducing the required regeneration time.
authors.affiliation: Institute for Sustainability and Innovation, Victoria University, P.O. Box 14428, Melbourne, Vic 8001, Australia.
authors.forename: Bo
authors.initials: B
authors.lastname: Zhu
authors.forename: Linda
authors.initials: L
authors.lastname: Zou
mesh_terms: D000042:Absorption; D002606:Charcoal / Q000737:chemistry*; D003116:Color; D010777:Photochemistry / Q000379:methods; D014025:Titanium / Q000737:chemistry*; D018508:Water Purification / Q000379:methods*
chemical_list: C009495:titanium dioxide; D002606:Charcoal; D014025:Titanium