Methods for preparing metal ion photocages: application to the synthesis of crowncast.
Three different synthetic strategies were utilized in the construction of a novel class of macrocyclic containing o-nitrobenzhydrol group II cation cages. The synthetic methodology presented herein is unparalleled in scope toward the preparation of caged complexes for various main group and transition block cations.
Kennedy
Daniel P
DP
Department of Chemisty, University of Connecticut, 55 North Eagleville Road U-3060, Storrs, Connecticut 06269, USA.
Gwizdala
Celina
C
Burdette
Shawn C
SC
D001559:Benzhydryl Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D002412:Cations / Q000138:chemical synthesis* / Q000737:chemistry; D047028:Macrocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D055668:Photochemical Processes
D001559:Benzhydryl Compounds; D002412:Cations; D047028:Macrocyclic Compounds; D009942:Organometallic Compounds; C544044:o-nitrobenzhydrol