title: In situ generation of novel acyclic diaminocarbene-copper complex.
abstract: A novel acyclic diaminocarbene-copper complex appears to be generated from a chloroamidinium salt and Cu(I)-thiophenecarboxylate in the presence of Grignard reagent based on (13)C NMR studies and is a highly efficient catalyst for S(N)2'-allylic alkylation.
authors.affiliation: Department of Chemistry, University of Florida, Gainesville, 32611-7200, USA.
authors.forename: Dimitri
authors.initials: D
authors.lastname: Hirsch-Weil
authors.forename: David R
authors.initials: DR
authors.lastname: Snead
authors.forename: Sebastien
authors.initials: S
authors.lastname: Inagaki
authors.forename: Hwimin
authors.initials: H
authors.lastname: Seo
authors.forename: Khalil A
authors.initials: KA
authors.lastname: Abboud
authors.forename: Sukwon
authors.initials: S
authors.lastname: Hong