Combination of a binaphthol-derived phosphite and a C1-symmetric phosphinamine generates heteroleptic catalysts in Rh- and Pd-mediated reactions.
Heteroleptic complexes, formed selectively by using a 1 : 1 combination of a sigma-donor and a pi-acceptor ligand, are involved in Rh- and Pd-catalysed reactions.
Pignataro
Luca
L
Dipartimento di Chimica Organica e Industriale, Centro Interdipartimentale C.I.S.I., Università degli Studi di Milano, Via G. Venezian 21, 20133 Milano, Italy.
Lynikaite
Benita
B
Colombo
Raffaele
R
Carboni
Stefano
S
Krupicka
Martin
M
Piarulli
Umberto
U
Gennari
Cesare
C