title: Au(PPh(3))Cl-AgSbF(6)-catalyzed rearrangement of propargylic 1,3-dithianes: formation of 8-membered 1,3-bisthio-substituted cyclic allenes.
abstract: Au(PPh(3))Cl-AgSbF(6)-catalyzed rearrangement of propargylic 1,3-dithiane leads to the formation of 8-membered dithio-substituted cyclic allenes, which are remarkably stable.
authors.affiliation: Peking University, Beijing, China.
authors.forename: Xia
authors.initials: X
authors.lastname: Zhao
authors.forename: Zhenzhen
authors.initials: Z
authors.lastname: Zhong
authors.forename: Lingling
authors.initials: L
authors.lastname: Peng
authors.forename: Wenxiong
authors.initials: W
authors.lastname: Zhang
authors.forename: Jianbo
authors.initials: J
authors.lastname: Wang
mesh_terms: D000466:Alkadienes / Q000737:chemistry*; D002384:Catalysis; D006571:Heterocyclic Compounds / Q000737:chemistry*; D050607:Organogold Compounds / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D013455:Sulfur / Q000737:chemistry*
chemical_list: D000466:Alkadienes; D006571:Heterocyclic Compounds; D050607:Organogold Compounds; C016798:triphenylphosphine gold chloride; D012834:Silver; C025947:propadiene; C012947:1,3-dithiane; D013455:Sulfur