title: Effect of the adsorbate (Bromacil) equilibrium concentration in water on its adsorption on powdered activated carbon. Part 1. Equilibrium parameters.
abstract: This study was carried out to investigate the adsorption equilibrium and kinetics of a pesticide of the uracil group on powdered activated carbon (PAC). The experiments were conducted at a wide range of initial pesticide concentrations (approximately 5 microg L(-1) to approximately 500 microg L(-1) at pH 7.8), corresponding to equilibrium concentrations of less than 0.1 microg L(-1) for the weakest, which is compatible with the tolerance limits of drinking water. Such a very broad range of initial solute concentrations resulting powdered activated carbon (PAC) concentrations (0.1-5 mg L(-1)) is the main particularity of our study. The application of several monosolute equilibrium models (two, three or more parameters) has generally shown that Bromacil adsorption is probably effective on two types of sites. High reactivity sites (K(L) approximately 10(3) Lmg(-1)) which are 10-20 less present in a carbon surface than lower reactivity sites (K(L) approximately 10 Lmg(-1)), according to the q(m) values calculated by two- or three-parameter models. The maximum capacity of the studied powdered activated carbon (PAC), corresponding to monolayer adsorption, compared to the Bromacil molecule surface, would be between 170 mg g(-1) and 190 mg g(-1). This theoretical value is very close to the experimental q(m) values obtained when using linearized forms of Langmuir, Tóth and Fritz-Schluender models.
authors.affiliation: Université de Poitiers, CNRS, Laboratoire de Chimie et Microbiologie de l'Eau (UMR 6008), Ecole Supérieure d'Ingénieurs de Poitiers, 40 avenue du Recteur Pineau, 86022 Poitiers Cedex, France.
authors.forename: Fadi
authors.initials: F
authors.lastname: Al Mardini
authors.forename: Bernard
authors.initials: B
authors.lastname: Legube
mesh_terms: D000327:Adsorption; D000465:Algorithms; D001976:Bromouracil / Q000031:analogs & derivatives* / Q000737:chemistry; D002606:Charcoal / Q000737:chemistry*; D002851:Chromatography, High Pressure Liquid; D006540:Herbicides / Q000737:chemistry*; D007700:Kinetics; D016014:Linear Models; D011208:Powders; D013056:Spectrophotometry, Ultraviolet; D013816:Thermodynamics; D014867:Water / Q000032:analysis; D014881:Water Supply / Q000032:analysis
chemical_list: D006540:Herbicides; D011208:Powders; D014867:Water; D002606:Charcoal; D001976:Bromouracil; C004590:bromacil