Formation and [3,3]-sigmatropic rearrangement of O-allyl nitronic esters: a new route to gamma,delta-unsaturated nitro compounds.
O-Allyl nitronic esters that are obtained from tin(IV) catalyzed Diels-Alder reactions undergo thermal rearrangement to gamma,delta-unsaturated nitro compounds.
Wade
Peter A
PA
Department of Chemistry, Drexel University, Philadelphia, PA 19104, USA. wadepa@drexel.edu
Pipic
Alma
A
Santhanaraman
Manikandan
M
Le
Hung T
HT