title: Adsorptive desulfurization by activated alumina.
abstract: This study reports usage of commercial grade activated alumina (aluminum oxide) as adsorbent for the removal of sulfur from model oil (dibenthiophene (DBT) dissolved in n-hexane). Bulk density of alumina was found to be 1177.77 kg/m(3). The BET surface area of alumina was found to decrease from 143.6 to 66.4 m(2)/g after the loading of DBT at optimum conditions. The carbon-oxygen functional groups present on the surface of alumina were found to be effective in the adsorption of DBT onto alumina. Optimum adsorbent dose was found to be 20 g/l. The adsorption of DBT on alumina was found to be gradual process, and quasi-equilibrium reached in 24 h. Langmuir isotherm best represented the equilibrium adsorption data. The heat of adsorption and change in entropy for DBT adsorption onto alumina was found to be 19.5 kJ/mol and 139.2 kJ/mol K, respectively.
authors.affiliation: Department of Chemical Engineering, Indian Institute of Technology Roorkee, Roorkee 247667, India.
authors.forename: Ankur
authors.initials: A
authors.lastname: Srivastav
authors.forename: Vimal Chandra
authors.initials: VC
authors.lastname: Srivastava
mesh_terms: D000327:Adsorption; D000537:Aluminum Oxide / Q000737:chemistry*; D004058:Diffusion; D006586:Hexanes / Q000737:chemistry; D007700:Kinetics; D008855:Microscopy, Electron, Scanning; D015233:Models, Statistical; D009821:Oils / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared; D013455:Sulfur / Q000737:chemistry*; D013816:Thermodynamics; D013876:Thiophenes / Q000737:chemistry; D014961:X-Ray Diffraction
chemical_list: D006586:Hexanes; D009821:Oils; D013876:Thiophenes; C026385:n-hexane; D013455:Sulfur; D000537:Aluminum Oxide; C016366:dibenzothiophene