title: Diffusion in two-dimensional colloidal systems on periodic substrates.
abstract: We study the diffusive behavior of two-dimensional charged colloidal suspensions subjected to a sinusoidal substrate by means of Brownian dynamics simulations. We mainly focus on the dependence of the mean-square displacement on the substrate strength. Our findings show a variation in the particle diffusion due to a substrate-induced distortion of the dynamic cage of nearest-neighbor colloids. This mechanism leads to a transition from normal diffusion at short times to subdiffusion on intermediate time scales. However, at long times normal diffusion is recovered. We also show that the variation in the long-time self-diffusion coefficient may be associated with the freezing and re-entrant melting transitions.
authors.affiliation: Instituto de Física, Universidad de Guanajuato, Loma del Bosque 103, Col. Lomas del Campestre, 37150 León, Guanajuato, Mexico.
authors.forename: Salvador
authors.initials: S
authors.lastname: Herrera-Velarde
authors.forename: Ramón
authors.initials: R
authors.lastname: Castañeda-Priego