title: Three-dimensional modeling of HCFC-123 in the atmosphere: assessing its potential environmental impacts and rationale for continued use.
abstract: HCFC-123 (C2HCl2F3) is used in large refrigeration systems and as a fire suppression agent blend. Like other hydrochlorofluorocarbons, production and consumption of HCFC-123 is limited under the Montreal Protocol on Substances that Deplete the Ozone Layer. The purpose of this study is to update the understanding of the current and projected impacts of HCFC-123 on stratospheric ozone and on climate and to discuss the potential environmental effects from continued use of this chemical for specific applications. For the first time, the Ozone Depletion Potential (ODP) of a HCFC is determined using a three-dimensional model (MOZART-3) of atmospheric physics and chemistry. All previous studies have relied on results from two-dimensional models. The derived HCFC-123 ODP of 0.0098 is smaller than previous values. Analysis of the projected uses and emissions of HCFC-123, assuming reasonable levels of projected growth and use in centrifugal chiller and fire suppressant applications, suggests an extremely small impact on the environment due to its short atmospheric lifetime, low ODP, low Global Warming Potential (GWP), and the small production and emission of its limited applications. The current contribution of HCFC-123 to stratospheric reactive chlorine is too small to be measurable.
authors.affiliation: Department of Atmospheric Sciences, University of Illinois, Urbana, Illinois 61801, USA wuebbles@illinois.edu
authors.forename: Donald J
authors.initials: DJ
authors.lastname: Wuebbles
authors.forename: Kenneth O
authors.initials: KO
authors.lastname: Patten
mesh_terms: D000393:Air Pollutants / Q000032:analysis*; D001272:Atmosphere / Q000737:chemistry*; D002713:Chlorine / Q000032:analysis; D017402:Chlorofluorocarbons / Q000032:analysis*; D064227:Chlorofluorocarbons, Ethane; D004777:Environment; D017752:Greenhouse Effect; D008956:Models, Chemical; D010126:Ozone / Q000032:analysis; D012621:Seasons
chemical_list: D000393:Air Pollutants; D017402:Chlorofluorocarbons; D064227:Chlorofluorocarbons, Ethane; C067411:2,2-dichloro-1,1,1-trifluoroethane; D002713:Chlorine; D010126:Ozone