Undecanuclear mixed-valence 3d-4f bimetallic clusters.
Two undecanuclear 3d-4f clusters with the general formula {Mn(III)(4)Mn(IV)Ln(III)(6)}, where Ln = Gd or Tb, were synthesized, with both showing large spin ground states, and the Tb species acting as a single molecule magnet.
Shiga
Takuya
T
Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba 305-8571, Japan.
Onuki
Tatsuya
T
Matsumoto
Takuto
T
Nojiri
Hiroyuki
H
Newton
Graham N
GN
Hoshino
Norihisa
N
Oshio
Hiroki
H