[Determination of 2,4,6-trinitromethylbenzene in biological material].
The objective of this study was to search for the optimal conditions necessary to extract 2,4,6-trinitromethylbenzene (2,4,6-TNMB) from biological material with acetonitrile. It is shown that 2,4,6-TNMB can be purified from the coextracted components of the biological material on a silica gel column, L 40/100 mcm. Methods are described for the identification and quantitative measurement of 2,4,6-trinitromethylbenzene in the cadaveric liver tissue by thin layer paper chromatography, IR spectrophotometry, and reverse phase high-performance liquid chromatography (rp-HPLC) with the use of a diode-matrix detector.
Shormanov
V K
VK
Omel'chenko
V A
VA
D000097:Acetonitriles / Q000737:chemistry; D002102:Cadaver; D002851:Chromatography, High Pressure Liquid; D002855:Chromatography, Thin Layer; D053593:Forensic Toxicology / Q000379:methods*; D006801:Humans; D008099:Liver / Q000737:chemistry; D015203:Reproducibility of Results; D013055:Spectrophotometry, Infrared; D014303:Trinitrotoluene / Q000302:isolation & purification*
D000097:Acetonitriles; D014303:Trinitrotoluene; C032159:acetonitrile