Self-assembled hexadecanitroxide.
A radical-armed guanosine derivative shows drastic magnetic changes by addition (removal) of alkali metal cations corresponding to the reversible assembly (disassembly). In the presence of templating metal ions, the assembly is formed by 8 molecules and 16 open-shell moieties confined in a sphere with a diameter of ca. 30 A.
Neviani
Paolo
P
Alma Mater Studiorum-Università di Bologna, Dipartimento di Chimica Organica A. Mangini, Via San Giacomo 11, 40126 Bologna, Italy.
Mileo
Elisabetta
E
Masiero
Stefano
S
Pieraccini
Silvia
S
Lucarini
Marco
M
Spada
Gian Piero
GP