title: Adsorption of copper (II), chromium (III), nickel (II) and lead (II) ions from aqueous solutions by meranti sawdust.
abstract: The present study proposed the use of meranti sawdust in the removal of Cu(II), Cr(III), Ni(II) and Pb(II) ions from synthetic aqueous solutions. Batch adsorption studies showed that meranti sawdust was able to adsorb Cu(II), Cr(III), Ni(II) and Pb(II) ions from aqueous solutions in the concentration range 1-200mg/L. The adsorption was favoured with maximum adsorption at pH 6, whereas the adsorption starts at pH 1 for all metal ions. The effects of contact time, initial concentration of metal ions, adsorbent dosage and temperature have been reported. The applicability of Langmuir, Freundlich, and Dubinin-Radushkevich (D-R) isotherm was tried for the system to completely understand the adsorption isotherm processes. The adsorption kinetics tested with pseudo-first-order and pseudo-second-order models yielded high R(2) values from 0.850 to 0.932 and from 0.991 to 0.999, respectively. The meranti sawdust was found to be cost effective and has good efficiency to remove these toxic metal ions from aqueous solution.
authors.affiliation: Division of Bio-resource, Paper and Coatings Technology, School of Industrial Technology, Universiti Sains Malaysia, 11800 Penang, Malaysia. mohd_rafatullah@yahoo.co.in
authors.forename: M
authors.initials: M
authors.lastname: Rafatullah
authors.forename: O
authors.initials: O
authors.lastname: Sulaiman
authors.forename: R
authors.initials: R
authors.lastname: Hashim
authors.forename: A
authors.initials: A
authors.lastname: Ahmad
mesh_terms: D000327:Adsorption; D000465:Algorithms; D002857:Chromium / Q000302:isolation & purification; D003300:Copper / Q000302:isolation & purification; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D007854:Lead / Q000302:isolation & purification; D019216:Metals, Heavy / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D015233:Models, Statistical; D009532:Nickel / Q000302:isolation & purification; D012996:Solutions; D017550:Spectroscopy, Fourier Transform Infrared; D013499:Surface Properties; D013696:Temperature; D013816:Thermodynamics; D014867:Water; D014934:Wood
chemical_list: D019216:Metals, Heavy; D012996:Solutions; D014867:Water; D002857:Chromium; D007854:Lead; D003300:Copper; D009532:Nickel