Metal-induced tautomerization of oxazole and thiazole molecules to heterocyclic carbenes.
Oxazole and thiazole molecules N-coordinated to manganese(i) are transformed into their corresponding 2,3-dihydrooxazol-2-ylidene and 2,3-dihydrothiazol-2-ylidene carbene tautomers by acid-base reactions, and subsequently transmetalated to gold(i), via isolable heterometallic intermediates.
Ruiz
Javier
J
Departamento de Química Orgánica e Inorgánica, Facultad de Química, Universidad de Oviedo, 33006, Oviedo, Spain. jruiz@uniovi.es
Perandones
Bernabé F
BF
D007536:Isomerism; D009682:Magnetic Resonance Spectroscopy; D008345:Manganese / Q000737:chemistry; D008670:Metals / Q000494:pharmacology*; D008697:Methane / Q000031:analogs & derivatives* / Q000138:chemical synthesis; D050607:Organogold Compounds / Q000138:chemical synthesis; D010080:Oxazoles / Q000737:chemistry*; D013844:Thiazoles / Q000737:chemistry*
D008670:Metals; D050607:Organogold Compounds; D010080:Oxazoles; D013844:Thiazoles; C030011:carbene; D008345:Manganese; D008697:Methane