New diarylmethanofullerene derivatives and their properties for organic thin-film solar cells.
A number of diarylmethanofullerene derivatives were synthesized. The cyclopropane ring of the derivatives has two aryl groups substituted with electron-withdrawing and -donating groups, the latter with long alkyl chains to improve solubility in organic solvents, an important property in processing cells. First reduction potentials of most derivatives were less negative than that of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM), which is possibly ascribed to their electron-withdrawing nature. Organic thin-film photovoltaic cells fabricated with poly(3-hexylthiophene) (P3HT) as the electron-donor and diarylmethanofullerene derivatives as the electron-acceptor material were examined. The {(methoxycarbonyl)phenyl[bis(octyloxy)phenyl]methano}fullerene showed power conversion efficiency as high as PCBM, but had higher solubility in a variety of organic solvents than PCBM. The V(oc) value was higher than that of PCBM, which is derived from the electron-donating (octyloxy)phenyl group, possibly raising the LUMO level. Photovoltaic effects of the devices fabricated with the derivatives having some electron-withdrawing groups were also examined.
Sukeguchi
Daisuke
D
Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466 8555, Japan.
Singh
Surya Prakash
SP
Reddy
Mamidi Ramesh
MR
Yoshiyama
Hideyuki
H
Afre
Rakesh A
RA
Hayashi
Yasuhiko
Y
Inukai
Hiroki
H
Soga
Tetsuo
T
Nakamura
Shuichi
S
Shibata
Norio
N
Toru
Takeshi
T