A facile template approach to high-nuclearity silver(I) alkynyl clusters.
Peanut clusters: Anion templates are used in a facile approach for the synthesis of high-nuclearity silver clusters. The cluster nuclearity can be controlled by adjusting the size of the templating anions and by using different alkynyl ligands. The largest silver alkynyl cluster, which consists of 35 silver(I) centers in the shape of a peanut, has been prepared by using chromate anions as templates (see picture).
Bian
Shu-Dan
SD
State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen, 361005 PR China.
Wu
Hua-Bin
HB
Wang
Quan-Ming
QM