Synthesis of the deoxyaminosugar (+)-D-forosamine via a novel domino-Knoevenagel-hetero-Diels-Alder reaction.
A synthesis of (+)-D-forosamine was developed. The sugar-scaffold was constructed by a new domino-Knoevenagel-hetero-Diels-Alder reaction from easily available starting materials.
Tietze
L F
LF
Institute of Organic and Biomolecular Chemistry, Georg-August-University Göttingen, Tammannstr. 2, 37077 Göttingen, Germany. ltietze@gwdg.de
Böhnke
N
N
Dietz
S
S
D002384:Catalysis; D006595:Hexosamines / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D013237:Stereoisomerism; D013302:Streptomyces / Q000378:metabolism
D006595:Hexosamines; C012325:forosamine