title: Mechanistic insight into TEMPO-inhibited polymerisation: simultaneous determination of oxygen and inhibitor concentrations by EPR.
abstract: Convolution-based fitting of EPR spectra makes it possible to simultaneously determine concentrations of TEMPO and oxygen in TEMPO-inhibited polymerisations and autoxidations; this method is useful for understanding the chemistry of inhibitor mixtures.
authors.affiliation: Department of Chemistry, University of York, Heslington, York YO10 5DD, UK.
authors.forename: Marco
authors.initials: M
authors.lastname: Conte
authors.forename: Yun
authors.initials: Y
authors.lastname: Ma
authors.forename: Colin
authors.initials: C
authors.lastname: Loyns
authors.forename: Peter
authors.initials: P
authors.lastname: Price
authors.forename: David
authors.initials: D
authors.lastname: Rippon
authors.forename: Victor
authors.initials: V
authors.lastname: Chechik
mesh_terms: D003497:Cyclic N-Oxides / Q000032:analysis* / Q000494:pharmacology*; D004578:Electron Spin Resonance Spectroscopy / Q000379:methods*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010100:Oxygen / Q000032:analysis*; D011108:Polymers / Q000737:chemistry*; D013997:Time Factors
chemical_list: D003497:Cyclic N-Oxides; D011108:Polymers; D010100:Oxygen; C003959:TEMPO