Phosphole-N-phenylmaleimide [4+2] cycloadducts as synthetic equivalents of nucleophilic phosphinidenes.
Using 1-R-3,4-dimethylphosphole-N-phenylmaleimide cycloadducts as synthetic equivalents of phosphinidenes [R-P], the following sequence has been developed: [R-P] + R(1)X --> RR(1)PX --> RR(1)P-OR(2).
Tian
Rongqiang
R
Chemistry Department, Zhengzhou University, P.R. China.
Duan
Zheng
Z
Zhou
Xiaoxu
X
Geng
Dingjin
D
Wu
Yangjie
Y
Mathey
François
F