A Zn-based, pillared paddlewheel MOF containing free carboxylic acids via covalent post-synthesis elaboration.
A Zn-based, mixed-ligand (pillared paddlewheel), metal-organic framework (MOF) has been covalently and quantitatively decorated with free carboxylic acids to demonstrate the utility of covalent post-synthesis modification in the construction of otherwise inaccessible carboxy-functionalized MOFs.
Gadzikwa
Tendai
T
Department of Chemistry and the Institute for Catalysis in Energy Processes, Northwestern University, Evanston, IL 60208-3113, USA.
Farha
Omar K
OK
Mulfort
Karen L
KL
Hupp
Joseph T
JT
Nguyen
SonBinh T
ST