title: Dynamic spectroscopic ellipsometry determination of nanostructural changes in plasmonic silver films.
abstract: Dynamic in situ spectroscopic ellipsometry is used to probe post-deposition nano-structural changes in silver films at room temperature in the pre- and post-coalescence stages of Volmer-Weber growth. In the island growth phase the Maxwell-Garnett theory is used to determine structural changes in the island film. Changes in the plasmon resonance frequency indicate an increased distance between islands which explain pre-coalescence resistivity changes. Post-coalescence changes in the resistivity are determined to be due to grain growth. A reduction in film thickness of 0.2 - 0.3 nm is also observed. The results are used to evaluate recent competing theories based on in situ stress measurements.
authors: T W H
authors: TW
authors: Oates
authors: L
authors: L
authors: Ryves
authors: M M M
authors: MM
authors: Bilek