Controlled assembly of highly Raman-enhancing silver nanocap arrays templated by porous anodic alumina membranes.
A convenient nanoscale technique is reported for the fabrication of highly ordered hemispherical silver nanocap arrays templated by porous anodic alumina (PAA) membranes as robust and cost-efficient surface-enhanced Raman scattering (SERS) substrates. This geometry produces a high Raman signal due to its periodic hexagonal arrangements and control of the gap between the nanostructures in the sub-10-nm regime. The surface structure can be tuned further to optimize the enhancement factor according to optional PAA fabrication and silver deposition parameters. Finite-difference time-domain calculations indicate that the structure may possess excellent SERS characteristics due to the high density and abundance of hot spots.
Qiu
Teng
T
Department of Physics, Southeast University, Nanjing 211189, PR China. tqiu@seu.edu.cn
Zhang
Wenjun
W
Lang
Xianzhong
X
Zhou
Yongjin
Y
Cui
Tiejun
T
Chu
Paul K
PK
D049329:Nanostructures / Q000737:chemistry*; D036103:Nanotechnology; D012834:Silver / Q000737:chemistry*; D013059:Spectrum Analysis, Raman / Q000379:methods*
D012834:Silver