title: Effect of ring size on the exo/endo selectivity of a thermal double cycloaddition of fused pyran-2-ones.
abstract: A study of an unusual effect of the size of the ring fused to 2H-pyran-2-ones on the exo/endo selectivity of a thermal double cycloaddition of N-substituted maleimides or maleic anhydride yielding bicyclo[2.2.2]octene derivatives is presented. With subtle variations of starting compounds and reaction conditions exclusively exo,exo or exo,endo products can be prepared.
authors: Faculty of Chemistry and Chemical Technology, University of Ljubljana, Askerceva 5, SI-1000 Ljubljana, Slovenia. kristof.kranjc@fkkt.uni-lj.si
authors: Kristof
authors: K
authors: Kranjc
authors: Franc
authors: F
authors: Perdih
authors: Marijan
authors: M
authors: Kocevar