Bimodal three-membered valence tautomerism of an alkyl chain-functionalized manganese dioxolene complex.
A novel alkyl chain-functionalized manganese complex with dioxolene ligands shows a bimodal three-membered valence tautomerism, one of which synchronizes with a cooperative solid-melt phase transition and the other occurs in the melt noncooperatively.
Kiriya
Daisuke
D
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
Nakamura
Kohei
K
Chang
Ho-Chol
HC
Kitagawa
Susumu
S