title: Performance of SCS palladium pincer complexes in borylation of allylic alcohols. Control of the regioselectivity in the one-pot borylation-allylation process.
abstract: One-pot borylation-allylation reactions of aldehydes and allylic alcohols were performed under various reaction conditions. The borylation of allylic alcohols was performed using a very efficient SCS palladium pincer-complex catalyst. The regioselectivity of the allylation depends on the applied solvent. The reaction in CHCl3 gave the linear allylic product; however, when MeOH was added to the reaction mixture, the branched allylic product was formed.
authors: Department of Organic Chemistry Arrhenius Laboratory, Stockholm University, Sweden.
authors: Nicklas
authors: N
authors: Selander
authors: Kálmán J
authors: KJ
authors: Szabó