Width of reaction zones in A+B-->C type reaction-diffusion processes: effects of an electric current.
We investigate the effects of an electric current on the width of a stationary reaction zone in an irreversible A(-)+B(+)-->C reaction-diffusion process. The ion dynamics of electrolytes A identical with (A(+),A(-)) and B identical with (B(+),B(-)) is described by reaction-diffusion equations obeying local electroneutrality and the stationary state is obtained by employing reservoirs of fixed electrolyte concentrations at the opposite ends of a finite domain. We find that the width of the reaction zone decreases when the current drives the reacting ions toward the reaction zone while it increases in the opposite case. The linear response of the width to the current is estimated by developing a phenomenological theory based on conservation laws and on electroneutrality. The theory is found to reproduce numerical solutions to a good accuracy.
Martens
K
K
Department of Theoretical Physics, University of Genève, CH-1211 Genève 4, Switzerland. kirsten.martens@unige.ch
Droz
M
M
Rácz
Z
Z
D003198:Computer Simulation; D004058:Diffusion; D004560:Electricity; D004573:Electrolytes / Q000737:chemistry; D008956:Models, Chemical
D004573:Electrolytes