Copper(I) scorpionate complexes and their application in palladium-mediated [(11)C]carbonylation reactions.
Solutions of copper(I) tris(pyrazolyl)borate complexes have been used to greatly improve the solubility of [(11)C]carbon monoxide, enabling it to be used in low-pressure, 'one-pot' palladium-mediated carbonylation reactions to form (11)C-radiolabelled amides and ureas for use in positron emission tomography.
Kealey
Steven
S
Department of Chemistry, Imperial College, London, UK SW7 2AZ.
Miller
Philip W
PW
Long
Nicholas J
NJ
Plisson
Christophe
C
Martarello
Laurent
L
Gee
Antony D
AD
D000447:Aldehydes / Q000737:chemistry; D000577:Amides / Q000737:chemistry; D002250:Carbon Radioisotopes / Q000737:chemistry; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D011720:Pyrazoles / Q000737:chemistry*; D014510:Urease / Q000737:chemistry
D000447:Aldehydes; D000577:Amides; D002250:Carbon Radioisotopes; D007659:Ketones; D009942:Organometallic Compounds; D011720:Pyrazoles; D010165:Palladium; D003300:Copper; D014510:Urease