title: Photophysics of manisyl-substituted 2-pyridin-2-yl-1,10-phenanthrolines. Dual emission dependent on structure and solvent.
abstract: Systematic variation of the substitution pattern of 2-pyridin-2-yl-1,10-phenanthrolines with 4-methoxy-2,6-dimethylphenyl (manisyl) groups alpha, beta, and gamma to the nitrogen atoms results in a 3 x 3 array of pyridyl-phenanthrolines displaying low to high quantum yields (Phi(f) = 0.03-0.60). Photophysical studies elucidated a duality of emissive states: a weakly emissive, locally excited state, similar to the (1)pi,pi state of phenanthroline; and a strongly emissive, charge-transfer state, dependent on manisyl regiochemistry and solvent polarity. Ab initio calculations underscore the similarities in the electronic structures of phenanthroline and pyridyl-phenanthrolines rather than between terpyridine and pyridyl-phenanthroline.
authors: Organisch-chemisches Institut, Universität Zürich Winterthurerstrasse 190 Zürich, Switzerland CH-8057.
authors: Jeremy K
authors: JK
authors: Klosterman
authors: Kim K
authors: KK
authors: Baldridge
authors: Jay S
authors: JS
authors: Siegel
mesh_terms: D003198:Computer Simulation; D008958:Models, Molecular; D015394:Molecular Structure; D010618:Phenanthrolines / Q000737:chemistry*; D010777:Photochemistry; D010825:Physics; D011725:Pyridines / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry*; D013050:Spectrometry, Fluorescence
chemical_list: D010618:Phenanthrolines; D011725:Pyridines; D012997:Solvents