A nanotubular metal-organic framework with permanent porosity: structure analysis and gas sorption studies.
A nanotubular metal-organic framework, PCN-19, was constructed based on a micro3-oxo-trinickel basic carboxylate secondary building unit (SBU) and the 9,10-anthracenedicarboxylate ligand; its permanent porosity was confirmed by N2 adsorption isotherms, and its H2 storage performances were evaluated under both low and high pressures at 77 K.
Ma
Shengqian
S
Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL 60439, USA. sma@anl.gov
Simmons
Jason M
JM
Yuan
Daqiang
D
Li
Jian-Rong
JR
Weng
Wei
W
Liu
Di-Jia
DJ
Zhou
Hong-Cai
HC