title: Stereoselective cross-coupling between allylic alcohols and aldimines.
abstract: A cross-coupling reaction between an allylic alcohol and an imine is described for stereoselective allylation of aromatic and aliphatic imines. This method provides operationally simple, enantioselective access to functionalized homoallylic amines. Particularly noteworthy is direct use of a functionalized allylic alcohol as an allylating reagent without prederivatization, which obviates the use of preformed organometallic reagents or activated imine derivatives.
authors: Department of Chemistry, Wayne State University, 5101 Cass Avenue, Detroit, Michigan 48202, USA.
authors: Ivan L
authors: IL
authors: Lysenko
authors: Hyung Goo
authors: HG
authors: Lee
authors: Jin Kun
authors: JK
authors: Cha