A Stable (Amino)(Phosphino)Carbene as bidentate ligand for Palladium and Nickel Complexes: Synthesis, Structure, and Catalytic Activity.
Two original complexes featuring an (amino)(phosphino)carbene η(2)-bonded to the metal have been obtained in 60 and 80 % yields, by addition of the corresponding stable carbene to PdCl(2)(cod) and NiCl(2)(PPh(3))(2), respectively. Both complexes have been fully characterized including X-ray diffraction studies. The catalytic activity of the palladium complex has been evaluated for aryl amination reactions.
Teuma
Emmanuelle
E
Laboratoire Hétérochimie Fondamentale et Appliquée, UMR 5069, Université Paul Sabatier, 118 route de Narbonne, F-31062 Toulouse cedex 04, France.
Lyon-Saunier
Céline
C
Gornitzka
Heinz
H
Mignani
Gérard
G
Baceiredo
Antoine
A
Bertrand
Guy
G