Ni(0)-catalyzed formation of azaaluminacyclopentenes via azanickelacyclopentenes: a unique nickel/aluminum double transmetalation reaction.
Azaaluminacyclopentenes, which serve as useful precursors for gamma-substituted allylamines, were catalytically prepared from novel Ni-mediated three-component cyclocondensation of an alkyne, an imine, and AlMe(3).
Ohashi
Masato
M
Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.
Kishizaki
Osamu
O
Ikeda
Haruo
H
Ogoshi
Sensuke
S