Luminescence vapochromic properties of a platinum(II) complex with 5,5'-bis(trimethylsilylethynyl)-2,2'-bipyridine.
A platinum(II) complex of 5,5'-bis(trimethylsilylethynyl)-2,2'-bipyridine displays unusually reversible colour and luminescence changes when exposed to specific organic vapours, correlated well with Pt...Pt distances as well as pi-pi and C-H...(C[triple bond]C) interactions in the stacking of square-planar platinum(II) moieties.
Ni
Jun
J
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
Zhang
Li-Yi
LY
Wen
Hui-Min
HM
Chen
Zhong-Ning
ZN