Characterization of wet precipitation by X-ray diffraction (XRD) and scanning electron microscopy (SEM) in the metropolitan area of Porto Alegre, Brazil.
The purpose of this study is to assess the composition of wet precipitation in three sites of the metropolitan area of Porto Alegre. Besides the variables usually considered, such as pH, conductivity, major ions (Cl(-), NO(3)(-), F(-), SO(4)(2-), Na(+), K(+), Mg(2+), NH(4)(+) and Ca(2+)) and metallic elements (Cd, Co, Cr, Cu, Fe, Mn and Ni), the suspended matter was examined by X-ray diffraction (XRD) and scanning electron microscopy (SEM), with energy dispersive system (EDS), for better identification of possible anthropogenic material in this wet precipitation. Results showed an alkaline pH in the samples analyzed and higher concentrations for Na(+), Cl(-) and SO(4)(2-). The acidification and neutralization potential between anions (SO(4)(2-)+NO(3)(-)) and cations (Ca(2+)+Mg(2+)+K(+)+NH(4)(+)) showed a good correlation (0.922). The metallic elements with highest values were Zn, Fe and Mn. Results of XRD identified the presence of some minerals such as quartz, feldspar, mica, clay, carbonates and sulfates. In samples analyzed with SEM, we detected pyroxene, biotite, amphibole and oxides. Cluster analysis (CA) was applied to the data matrix to identify potential pollution sources of metals (natural or anthropogenic) and the association with minerals found in the analysis of SEM.
Migliavacca
Daniela Montanari
DM
Instituto de Biociências, Programa de Pós-Graduação em Ecologia, Universidade Federal do Rio Grande do Sul, 91509-900 Porto Alegre, RS, Brazil.
Teixeira
Elba Calesso
EC
Gervasoni
Fernanda
F
Conceição
Rommulo Vieira
RV
Rodriguez
Maria Teresa Raya
MT
D015258:Acid Rain / Q000032:analysis*; D000838:Anions; D001938:Brazil; D016000:Cluster Analysis; D004784:Environmental Monitoring / Q000379:methods*; D005843:Geography; D006863:Hydrogen-Ion Concentration; D008855:Microscopy, Electron, Scanning / Q000379:methods*; D011891:Rain; D014867:Water / Q000737:chemistry; D014961:X-Ray Diffraction / Q000379:methods*
D015258:Acid Rain; D000838:Anions; D014867:Water