title: Enhanced cycling performance of an Fe0/Fe3O4 nanocomposite electrode for lithium-ion batteries.
abstract: We demonstrate the formation of a highly conductive, Fe0/Fe3O4 nanocomposite electrode by the hydrogen reduction process. Fe2O3 nanobundles composed of one-dimensional nanowires were initially prepared through thermal dehydrogenation of hydrothermally synthesized FeOOH. The systematic phase and morphological evolutions from Fe2O3 to Fe2O3/Fe3O4, Fe3O4, and finally to Fe/Fe3O4 by the controlled thermochemical reduction at 300 degrees C in H2 were characterized using x-ray diffraction (XRD) and transmission electron microscopy (TEM). The Fe/Fe3O4 nanocomposite electrode shows excellent capacity retention ( approximately 540 mA h g(-1) after 100 cycles at a rate of 185 mA g(-1)), compared to that of Fe2O3 nanobundles. This enhanced electrochemical performance in Fe/Fe3O4 composites was attributed to the formation of unique, core-shell nanostructures offering an efficient electron transport path to the current collector.
authors: Nano-Materials Research Center, Nano-Science Research Division, Korea Institute of Science and Technology, Seoul 136-791, Korea.
authors: Gwang-Hee
authors: GH
authors: Lee
authors: Jae-Gwan
authors: JG
authors: Park
authors: Yun-Mo
authors: YM
authors: Sung
authors: Kyung Yoon
authors: KY
authors: Chung
authors: Won Il
authors: WI
authors: Cho
authors: Dong-Wan
authors: DW
authors: Kim