Dynamic interactions between fast microscale rotors.
Trimetallic catalytic microrotors were fabricated by electrodeposition of cylindrical Au-Ru rods in the pores of anodic alumina membranes, dissolution of the template membrane, and then sequential vapor deposition of Cr, SiO(2), Cr, Au, and Pt on one side of each rod. This design provides two force vectors for the catalytic motor, including one perpendicular to the rod axis. The rods rotated rapidly (approximately 180 rpm) in 15% aqueous H(2)O(2) solution with minimal orbital or translational movement. The rotation was rapid enough to observe qualitatively different interactions between pairs of co- and counter-rotating rods. Counter-rotating rods were able to approach each other closely and underwent frequent tip-to-tip collisions. Co-rotating rods could approach each other only to a distance of approximately 0.9 microm. This difference is rationalized on the basis of shear forces generated by the catalytically driven rotation of the rods.
Wang
Yang
Y
Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, USA.
Fei
Shih-to
ST
Byun
Young-Moo
YM
Lammert
Paul E
PE
Crespi
Vincent H
VH
Sen
Ayusman
A
Mallouk
Thomas E
TE