IM-19: a new flexible microporous gallium based-MOF framework with pressure- and temperature-dependent openings.
Five metal-organic frameworks (MOFs) based on the same three-dimensional gallium terephthalate network (IM-19) are described, and an incommensurate structure (for the as-synthesized form) as well as two remarkable guest-free polymorphs (open and closed) are highlighted.
Chaplais
Gérald
G
Equipe Matériaux à Porosité Contrôlée (MPC), Institut de Science des Matériaux de Mulhouse (IS2M), LRC CNRS 7228, Université Haute Alsace, ENSCMu, 3 rue Alfred Werner, 68093, Mulhouse Cedex, France. gerald.chaplais@uha.fr
Simon-Masseron
Angélique
A
Porcher
Florence
F
Lecomte
Claude
C
Bazer-Bachi
Delphine
D
Bats
Nicolas
N
Patarin
Joël
J
D005708:Gallium / Q000737:chemistry*; D008832:Microchemistry; D010795:Phthalic Acids / Q000737:chemistry*; D016062:Porosity; D011312:Pressure; D013696:Temperature
D010795:Phthalic Acids; C011363:terephthalic acid; D005708:Gallium