Photodissociation of H2(+) upon exposure to an intense pulsed photonic Fock state.
Producing and controlling nonclassical light states are now the subject of intense experimental efforts. In this paper we consider the interaction of such a light state with a small molecule. Specifically, we develop the theory and apply it numerically to calculate in detail how a short pulse of nonclassical light, such as the high intensity Fock state, induces photodissociation in H(2)(+). We compare the kinetic energy distributions and photodissociation yields with the analogous results of quasi-classical light, namely a coherent state. We find that Fock-state light decreases the overall probability of dissociation for low vibrational states of H(2)(+) as well as the location of peaks and line shapes in the kinetic energy distribution of the nuclei.
Paul
Amit K
AK
Department of Physical Chemistry, Indian Association for Cultivation of Science, Jadavpur, Kolkata 700 032, India.
Adhikari
Satrajit
S
Mukhopadhyay
Debasis
D
Halász
Gabor J
GJ
Vibók
Agnes
A
Baer
Roi
R
Baer
Michael
M