title: Preparation and properties of lithium and sodium peroxynitrite.
abstract: We describe the preparation of aqueous solutions of LiONOO and NaONOO from (Me4N)ONOO. An aqueous solution of analytically pure, commercially available (Me4N)ONOO is applied to an Amberlyst 15 column at 4 degrees C, and the Me4N+ is rapidly (in 20 min) exchanged against Li+ or Na+. The exchanged peroxynitrite is produced in yields of ca. 90% with a nitrite content of 5-6%.
authors: Institute of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zurich, 8093 Zürich, Switzerland.
authors: Manuel
authors: M
authors: Sturzbecher-Höhne
authors: Reinhard
authors: R
authors: Kissner
authors: Thomas
authors: T
authors: Nauser
authors: Willem H
authors: WH
authors: Koppenol
mesh_terms: D002852:Chromatography, Ion Exchange / Q000379:methods; D007474:Ion Exchange; D018020:Lithium Compounds / Q000737:chemistry*; D016877:Oxidants / Q000138:chemical synthesis*; D030421:Peroxynitrous Acid / Q000138:chemical synthesis* / Q000737:chemistry; D000644:Quaternary Ammonium Compounds / Q000737:chemistry*; D021241:Spectrometry, Mass, Electrospray Ionization
chemical_list: D018020:Lithium Compounds; D016877:Oxidants; D000644:Quaternary Ammonium Compounds; C113914:tetramethylammonium peroxynitrite; D030421:Peroxynitrous Acid; C028467:lithium hydroxide