[Simultaneous desulfurization and denitrification by TiO2/ACF under different irradiation].
The supported TiO2 photocatalysts were prepared in laboratory, and the experiments of simultaneous desulfurization and denitrification were carried out by self-designed photocatalysis reactor. The optimal experimental conditions were achieved, and the efficiencies of simultaneous desulfurization and denitrification under two different light sources were compared. The results show that the oxygen content of flue gas, reaction temperature, flue gas humidity and irradiation intensity are most essential factors to photocatalysis. For TiO2/ACF, the removal efficiencies of 99.7% for SO2 and 64.3% for NO are obtained respectively at optimal experimental conditions under UV irradiation. For TiO2/ACF, the removal efficiencies of 97.5% for SO2 and 49.6% for NO are achieved respectively at optimal experimental conditions under the visible light irradiation. The results of five times parallel experiments indicate standard deviation S of parallel data is little. The mechanism of removal for SO2 and NO is proposed under two light sources by ion chromatography analysis of the absorption liquid.
Han
Jing
J
School of Environmental Science and Engineering, North China Electric Power University, Baoding 071003, China. hgxhjj@163.com
Zhao
Yi
Y
D000393:Air Pollutants / Q000737:chemistry*; D000397:Air Pollution / Q000032:analysis / Q000517:prevention & control; D002244:Carbon / Q000737:chemistry*; D000077482:Carbon Fiber; D002384:Catalysis / Q000528:radiation effects; D008027:Light; D009569:Nitric Oxide / Q000737:chemistry*; D010084:Oxidation-Reduction; D055668:Photochemical Processes / Q000528:radiation effects; D013458:Sulfur Dioxide / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*; D014466:Ultraviolet Rays
D000393:Air Pollutants; D000077482:Carbon Fiber; D013458:Sulfur Dioxide; C009495:titanium dioxide; D009569:Nitric Oxide; D002244:Carbon; D014025:Titanium