Use of potassium beta-trifluoroborato amides in Suzuki-Miyaura cross-coupling reactions.
Potassium beta-trifluoroborato amides were prepared and used as successful partners in Suzuki-Miyaura reactions with various aryl chlorides, including electron-rich and electron-poor derivatives, as well as several heteroaryl chloride partners.
Molander
Gary A
GA
Roy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323, USA. gmolandr@sas.upenn.edu
Jean-Gérard
Ludivine
L
D000577:Amides / Q000138:chemical synthesis* / Q000737:chemistry; D001881:Borates / Q000138:chemical synthesis* / Q000737:chemistry; D002722:Chlorobenzenes / Q000737:chemistry; D015394:Molecular Structure; D011188:Potassium / Q000737:chemistry*; D013237:Stereoisomerism
D000577:Amides; D001881:Borates; D002722:Chlorobenzenes; D011188:Potassium