title: Coordination of Ce(III) and Nd(III) with pentaethylene glycol in the presence of picrate anion: spectroscopic and X-ray structural studies.
abstract: (1)H NMR evidence for direct coordination between the Ln(III) ion and the oxygen atoms of the pentaethylene glycol (EO5) ligand and the picrate anion (Pic) in [Ln(Pic)(2)(EO5)][Pic] {Ln=Ce and Nd} complexes are confirmed by single X-ray diffraction. No dissociation of Ln-O bonds in dimethyl sulfoxide-d solution was observed in NMR studies conducted at different temperatures ranging 25-100 degrees C. The Ln(III) ion was chelated to nine oxygen atoms from the EO5 ligand in a hexadentate manner and the two Pic anions in each bidentate and monodentate modes. Both compounds are isostructural and crystallized in monoclinic with space group P2(1)/c. Coordination environment around the Ce1 and Nd1 atoms can be described as tricapped trigonal prismatic and monocapped square antiprismatic geometries, respectively. The crystal packing of the complexes have stabilized by one dimensional (1D) chains along the [001] direction to form intermolecular O-Hcdots, three dots, centeredO and C-Hcdots, three dots, centeredO hydrogen bonding. The molar conductance of the complexes in DMSO solution indicated that both compounds are ionic. The complexes had a good thermal stability. Under the UV-excitation, these complexes exhibited the red-shift emission.
authors: Department of Chemical Sciences, Faculty of Science and Technology, Universiti Malaysia Terengganu, 21030 Kuala Terengganu, Terengganu, Malaysia. eny2kus@yahoo.com
authors: Eny
authors: E
authors: Kusrini
authors: Muhammad Idiris
authors: MI
authors: Saleh
authors: Claude
authors: C
authors: Lecomte
mesh_terms: D000838:Anions / Q000737:chemistry / Q000494:pharmacology; D002563:Cerium / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008163:Luminescent Measurements; D008954:Models, Biological; D008958:Models, Molecular; D015394:Molecular Structure; D009354:Neodymium / Q000737:chemistry*; D010851:Picrates / Q000737:chemistry / Q000494:pharmacology*; D011092:Polyethylene Glycols / Q000737:chemistry*; D013057:Spectrum Analysis; D013818:Thermogravimetry
chemical_list: D000838:Anions; D010851:Picrates; D009354:Neodymium; D002563:Cerium; D011092:Polyethylene Glycols; C005858:picric acid