Synthesis of a diamino substituted terphenyldivinyl chromophore.
(E,E)-1,4-bis(4'-aminostyryl)-2,5-bis(octyloxy)-benzene (6) and its derivative (E,E)-1,4-bis(4'-acetamidostyryl)-2,5-bis(octyloxy)-benzene (7) were synthesized and characterized after alkylation, bromomethylation, Horner-Emmons reaction and reduction from hydroquinone. In order to gain more molecular electronic data, HOMO and LUMO of compound 6 have been calculated by Gaussian 03 W.
Du
Zhen-Ting
ZT
College of Sciences, Northwest A&F University, Yangling, Shaanxi 712100, China. duzt@nwsuaf.edu.cn
Liu
Ru
R
Wang
Jun-Ru
JR
Li
An-Pai
AP
D015394:Molecular Structure; D010569:Perylene / Q000737:chemistry; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry; D014753:Vinyl Compounds / Q000737:chemistry*
D011108:Polymers; D014753:Vinyl Compounds; D010569:Perylene