New one-pot synthesis of (E)-beta-aryl vinyl halides from styrenes.
A new, efficient protocol for the highly stereoselective one-pot synthesis of (E)-beta-aryl vinyl iodides and (E)-beta-aryl vinyl bromides from styrenes based on sequential ruthenium-catalyzed silylative coupling-N-halosuccinimide-mediated halodesilylation reactions is reported.
Pawluć
Piotr
P
Department of Organometallic Chemistry, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznan, Poland.
Hreczycho
Grzegorz
G
Szudkowska
Justyna
J
Kubicki
Maciej
M
Marciniec
Bogdan
B
D007454:Iodides / Q000138:chemical synthesis* / Q000737:chemistry; D012428:Ruthenium / Q000737:chemistry*; D013237:Stereoisomerism; D013343:Styrenes / Q000737:chemistry*; D014753:Vinyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry
D007454:Iodides; D013343:Styrenes; D014753:Vinyl Compounds; D012428:Ruthenium; C003763:vinyl bromide