Methyl and t-butyl reorientation in an organic molecular solid.
We have determined the molecular and crystal structure of 4,5-dibromo-2,7-di-t-butyl-9,9-dimethylxanthene and measured the (1)H spin-lattice relaxation rate from 87 to 270K at NMR frequencies of omega/2pi=8.50, 22.5, and 53.0MHz. All molecules in the crystal see the same intra and intermolecular environment and the repeating unit is half a molecule. We have extended models developed for (1)H spin-lattice relaxation resulting from the reorientation of a t-butyl group and its constituent methyl groups to include these rotors and the 9-methyl groups. The relaxation rate data is well-fitted assuming that the t-butyl groups and all three of their constituent methyl groups, as well as the 9-methyl groups all reorient with an NMR activation energy of 15.8+/-1.6kJmol(-1) corresponding to a barrier of 17.4+/-3.2kJmol(-1). Only intramethyl and intra-t-butyl intermethyl spin-spin interactions need be considered. A unique random-motion Debye (or BPP) spectral density will not fit the data for any reasonable choice of parameters. A distribution of activation energies is required.
Beckmann
Peter A
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Department of Physics, Bryn Mawr College, 101 North Merion Ave., Bryn Mawr, PA 19010-2899, USA. pbeckman@brynmawr.edu
Dougherty
William G
WG
Scott Kassel
W
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