title: Aerosol assisted chemical vapour deposition of Cu-ZnO composite from single source precursors.
abstract: Two heterobimetallic precursors [Zn(TFA)3(micro-OH)Cu3(dmae)3Cl].THF (1) and [Zn(TFA)4Cu3(dmae)4] (2) [dmae=N,N-dimethylaminoethanolate and TFA=trifluoroacetate], have been synthesized and characterized by their melting points, elemental analysis, FT-IR spectroscopy, mass spectrometry, TGA and single crystal X-ray diffraction methods. Both complexes were used to deposit thin films of Cu-ZnO composite on glass substrates by aerosol assisted chemical vapor deposition (AACVD) method. The films were characterized by "scotch tape" test for adhesion, thickness measurement as a function of temperature, EDX for composition, SEM for surface morphology and XRD for crystalline phases. Thin film deposition studies at 250, 325, 400, 475 degrees C indicated the increase in thickness with temperature reaching a maximum at 400 degrees C and then decreasing. EDX and PXRD results showed the uniform distribution of cubic metallic copper and hexagonal zinc oxide phases which make them useful for nanocatalysis on structured surfaces.
authors: Department of Chemistry, Quaid-I-Azam University, Islamabad, 45320, Pakistan.
authors: Muhammad
authors: M
authors: Shahid
authors: Muhammad
authors: M
authors: Mazhar
authors: Mazhar
authors: M
authors: Hamid
authors: Paul
authors: P
authors: O'Brien
authors: Mohammad A
authors: MA
authors: Malik
authors: Madeleine
authors: M
authors: Helliwell
authors: James
authors: J
authors: Raftery