title: Bonding mode of a new bis-phosphine-borane alkyl ligand to a Rh(I) species.
abstract: The stoichiometric reaction of [Rh(COD)Cl](2) with the anion resulting from the deprotonation of dppm(BH(3))(2) yielded a new alkyl Rh(I) complex; the coordination modes of the BH(3) groups are discussed on the basis of X-ray data, variable temperature multinuclear NMR experiments and DFT studies.
authors: Laboratoire Hétéroéléments et Coordination, UMR CNRS 7653 (DCPH), Ecole Polytechnique, 91128 Palaiseau Cedex, France.
authors: Matthias
authors: M
authors: Blug
authors: Dan
authors: D
authors: Grünstein
authors: Gilles
authors: G
authors: Alcaraz
authors: Sylviane
authors: S
authors: Sabo-Etienne
authors: Xavier-Frederic
authors: XF
authors: Le Goff
authors: Pascal
authors: P
authors: Le Floch
authors: Nicolas
authors: N
authors: Mézailles