Synthesis and characterization of Fe2O3/SiO2 nanocomposites.
Fe2O3/SiO2 nanocomposites based on fumed silica A-300 (S(BET)=337 m2/g) with iron oxide deposits at different content were synthesized using Fe(III) acetylacetonate (Fe(acac)3) dissolved in isopropyl alcohol or carbon tetrachloride for impregnation of the nanosilica powder at different amounts of Fe(acac)3 then oxidized in air at 400-900 degrees C. Samples with Fe(acac)3 adsorbed onto nanosilica and samples with Fe2O3/SiO2 including 6-17 wt% of Fe2O3 were investigated using XRD, XPS, TG/DTA, TPD MS, FTIR, AFM, nitrogen adsorption, Mössbauer spectroscopy, and quantum chemistry methods. The structural characteristics and phase composition of Fe2O3 deposits depend on reaction conditions, solvent type, content of grafted iron oxide, and post-reaction treatments. The iron oxide deposits on A-300 (impregnated by the Fe(acac)3 solution in isopropanol) treated at 500-600 degrees C include several phases characterized by different nanoparticle size distributions; however, in the case of impregnation of A-300 by the Fe(acac)3 solution in carbon tetrachloride only alpha-Fe2O3 phase is formed in addition to amorphous Fe2O3. The Fe2O3/SiO2 materials remain loose (similar to the A-300 matrix) at the bulk density of 0.12-0.15 g/cm3 and S(BET)=265-310 m2/g.
Bogatyrev
V M
VM
National Academy of Sciences of Ukraine, Chuiko Institute of Surface Chemistry, General Naumov Street 17, 03164 Kiev, Ukraine.
Gun'ko
V M
VM
Galaburda
M V
MV
Borysenko
M V
MV
Pokrovskiy
V A
VA
Oranska
O I
OI
Polshin
E V
EV
Korduban
O M
OM
Leboda
R
R
Skubiszewska-Zieba
J
J
D019840:2-Propanol / Q000737:chemistry; D000327:Adsorption; D002251:Carbon Tetrachloride / Q000737:chemistry; D005290:Ferric Compounds / Q000737:chemistry*; D053761:Nanocomposites / Q000737:chemistry*; D010084:Oxidation-Reduction; D012822:Silicon Dioxide / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry; D013499:Surface Properties; D013696:Temperature; D014050:Toluene / Q000737:chemistry
D005290:Ferric Compounds; D012997:Solvents; C000499:ferric oxide; D014050:Toluene; D012822:Silicon Dioxide; D002251:Carbon Tetrachloride; D019840:2-Propanol