Direct lateral metallation using alkali-metal mediated zincation (AMMZn): SiC-H vs.Si-O bond cleavage.
A new application of zincate [(THF)Li(TMP)(tBu)Zn(tBu)] (1) in alkali-metal mediated zincation (AMMZn) is reported by isolating and structurally defining the first intermediates of direct lateral zincation (DlZn) of trimethyl(phenoxy)silane (2) both of which adopt novel six-element {ZnCSiOLiN} ring structures.
Hevia
Eva
E
WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, UK G1 1XL. eva.hevia@strath.ac.uk
Kennedy
Alan R
AR
Klett
Jan
J
McCall
Matthew D
MD