Control of reversible ligand insertion via supramolecular interactions in the solid state.
Reversible insertion of a ligand molecule into the coordination sphere of a metal complex in the solid state by variation of associated supramolecular hydrogen-bonding interactions in the solid is demonstrated in studies of complexes of copper(I) nitrate with thiourea.
Bowmaker
Graham A
GA
Department of Chemistry, University of Auckland, Private Bag 92019, Auckland, New Zealand. ga.bowmaker@auckland.ac.nz
Hanna
John V
JV
Skelton
Brian W
BW
White
Allan H
AH
D006860:Hydrogen Bonding; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D013055:Spectrophotometry, Infrared
D008024:Ligands