Pulling an adsorbed polymer chain off a solid surface.
The thermally assisted detachment of a self-avoiding polymer chain from an adhesive surface by an external force applied to one of the chain-ends is investigated. We perform our study in the "fixed height" statistical ensemble where one measures the fluctuating force, exerted by the chain on the last monomer when a chain-end is kept fixed at height h over the solid plane at different adsorption strength [Formula: see text]. The phase diagram in the h-[Formula: see text] plane is calculated both analytically and by Monte Carlo simulations. We demonstrate that in the vicinity of the polymer desorption transition a number of properties like fluctuations and probability distribution of various quantities behave differently, if h rather than f is used as an independent control parameter.
Bhattacharya
S
S
Max Planck Institute for Polymer Research, 55128 Mainz, Germany. bhattach@mpip-mainz.mpq.de
Milchev
A
A
Rostiashvili
V G
VG
Vilgis
T A
TA