IBS-catalyzed oxidative rearrangement of tertiary allylic alcohols to enones with oxone.
A 2-iodoxybenzenesulfonic acid (IBS)-catalyzed oxidative rearrangement of tertiary allylic alcohols to enones with powdered Oxone in the presence of potassium carbonate and tetrabutylammonium hydrogen sulfate has been developed.
Uyanik
Muhammet
M
Graduate School of Engineering, Nagoya University, Chikusa, Nagoya 464-8603, Japan.
Fukatsu
Ryota
R
Ishihara
Kazuaki
K