Bonding mode of a new bis-phosphine-borane alkyl ligand to a Rh(I) species.
The stoichiometric reaction of [Rh(COD)Cl](2) with the anion resulting from the deprotonation of dppm(BH(3))(2) yielded a new alkyl Rh(I) complex; the coordination modes of the BH(3) groups are discussed on the basis of X-ray data, variable temperature multinuclear NMR experiments and DFT studies.
Blug
Matthias
M
Laboratoire Hétéroéléments et Coordination, UMR CNRS 7653 (DCPH), Ecole Polytechnique, 91128 Palaiseau Cedex, France.
Grünstein
Dan
D
Alcaraz
Gilles
G
Sabo-Etienne
Sylviane
S
Le Goff
Xavier-Frederic
XF
Le Floch
Pascal
P
Mézailles
Nicolas
N