title: Mechanisms in the reaction of palladium(II)-pi-allyl complexes with aryl halides: evidence for NHC exchange between two palladium complexes.
abstract: A detailed experimental and DFT study (PBE level) of the reaction of [Pd(eta(3)-C(3)H(5))(tmiy)(PR(3))]BF(4) (tmiy = tetramethylimidazolin-2-ylidene, PR(3) = phosphane), precursors to monoligated Pd(0) species, with aryl electrophiles yielding 2-arylimidazolium salt is reported. Experiments establish that an autocatalytic ligand transfer mechanism is preferred over Pd(IV) and sigma-bond metathesis pathways, and that transmetalation is the rate-determining step. Calculations indicate that the key step involves the concerted exchange of NHC and iodo ligands between two different Pd(II) complexes. This is corroborated by experimental results showing the slower reaction of complexes containing the bulkier dipdmiy (dipdmiy = diisopropyldimethylimidazolin-2-ylidene).
authors: School of Chemistry, Cardiff University, 51 Park Place, Cardiff CF10 3AT, Wales, UK.
authors: Adrien T
authors: AT
authors: Normand
authors: Mikhail S
authors: MS
authors: Nechaev
authors: Kingsley J
authors: KJ
authors: Cavell