Viscoelastic properties of crystals.
We examine the question of whether fluids and crystals are differentiated on the basis of their zero frequency shear moduli or their limiting zero frequency shear viscosity. We show that while fluids, in contrast with crystals, do have a zero value for their shear modulus, in contradiction to a widespread presumption, a crystal does not have an infinite or exceedingly large value for its limiting zero frequency shear viscosity. In fact, while the limiting shear viscosity of a crystal is much larger than that of the liquid from which it is formed, its viscosity is much less than that of the corresponding glass that may form assuming the liquid is a good enough glass former.
Williams
Stephen R
SR
Research School of Chemistry, The Australian National University, Canberra, Australian Capital Territory 0200, Australia. swilliams@rsc.anu.edu.au
Evans
Denis J
DJ