Jahn-Teller distortions of six-coordinate CuII compounds: cis or trans?
Unlike their octahedral analogues, copper(II) compounds with trigonal prismatic stereochemistry undergo an elongation of two bonds in cis positions due to a Jahn-Teller effect, a behavior that can also occur in slightly twisted octahedra.
Echeverría
Jorge
J
Departament de Química Inorgànica and Institut de Química Teòrica i Computacional, Universitat de Barcelona, Martí i Franquès 1-11, 08028 Barcelona, Spain.
Cremades
Eduard
E
Amoroso
Angelo J
AJ
Alvarez
Santiago
S