title: Optimisation of the chemical generation of singlet oxygen (1O2, 1Deltag) from the hydrogen peroxide-lanthanum(III) catalytic system using an improved NIR spectrometer.
abstract: A near-IR chemiluminescence spectrometer designed to study chemical sources of singlet oxygen ((1)O(2), (1)Delta(g)), was built by coupling a reactor compartment to a nitrogen-cooled Ge diode through a bundle of optical fibres. This device was used to optimise the generation of (1)O(2) from the hydrogen peroxide-lanthanum(iii) catalytic system. The reaction kinetics were studied with a 2(3)3(3)//12 screening experimental design comprising twelve experiments. The influence of six factors was examined: the nature of the lanthanum salt (hydroxide, oxide or nitrate) and its concentration (0.05 or 0.1 mol L(-1)), the pH value (5, 7 or 9), the concentration of H(2)O(2) (0.5, 1 or 2 mol L(-1)), the temperature (20 or 30 degrees C) and the concentration of EDTA (0 or 5 mmol L(-1)). Two responses were measured: the rate of H(2)O(2) disproportionation and the intensity of the luminescence of (1)O(2) at 1270 nm. The essential factor is the nature of the lanthanum salt since La(NO(3))(3) induces the disproportionation of H(2)O(2) about 60 x faster than La(2)O(3) or La(OH)(3). Other influencing factors are the pH value, the concentration of H(2)O(2), the temperature and the concentration of the lanthanum salt whereas the concentration of EDTA has no effect on the reaction. The catalytic activity of La(NO(3))(3) was then investigated in further detail by studying the influence of two factors (pH and [H(2)O(2)]) thanks to a Doehlert design.
authors: LCOM, Equipe de Recherche "Oxydation et Physicochimie de la Formulation", UMR CNRS 8009, ENSCL, B.P. 90 108, F-59652, Villeneuve d'Ascq Cedex, France.
authors: Christel
authors: C
authors: Pierlot
authors: Jacques
authors: J
authors: Barbillat
authors: Véronique
authors: V
authors: Nardello-Rataj
authors: Didier
authors: D
authors: Mathieu
authors: Michelle
authors: M
authors: Sergent
authors: Jean
authors: J
authors: Marko
authors: Jean-Marie
authors: JM
authors: Aubry
mesh_terms: D002384:Catalysis; D004867:Equipment Design; D006861:Hydrogen Peroxide / Q000737:chemistry*; D007811:Lanthanum / Q000737:chemistry*; D049449:Luminescence; D026082:Singlet Oxygen / Q000737:chemistry*; D019265:Spectroscopy, Near-Infrared / Q000295:instrumentation* / Q000379:methods
chemical_list: D026082:Singlet Oxygen; C016534:lanthanide nitrate; D007811:Lanthanum; D006861:Hydrogen Peroxide