catena-Poly[[[aqua(ethylenediamine-kappa2N,N')(nitrato-kappaO)copper(II)]-mu-4,4'-dithiodipyridine-kappa2N:N'] nitrate monohydrate].
The title compound, {[Cu(NO(3))(C(2)H(4)N(2))(C(10)H(8)N(2)S(2))(H(2)O)]NO(3).H(2)O}(n), is composed of a one-dimensional linear coordination polymer involving cis-protected copper(II) ions and a 4,4'-dithiodipyridine bridging ligand. The polymeric chains run along the c-axis direction. N-H...O and O-H...O hydrogen bonds involving the coordinating amine groups, nitrate ions and water molecules, as well as cocrystallized noncoordinating nitrate ions and water molecules, generate a three-dimensional structure.
Seidel
Rüdiger W
RW
Lehrstuhl für Analytische Chemie, Ruhr-Universität Bochum, Universitätsstrasse 150, 44780 Bochum, Germany. ruediger.seidel@rub.de
Oppel
Iris M
IM