Periodic mesoporous organosilica materials: self-assembly of carbamothioic acid-bridged organosilane precursors.
A new series of carbamothioic acid-containing periodic mesoporous organosilica (PMO) materials has been synthesized by a direct cocondensation method, in which an organosilica precursor N,S-bis[3-(triethoxysilyl)propyl]carbamothioic acid (MI) is treated with tetraethyl orthosilicate (TEOS), and the nonionic surfactant Pluronic 123 (P123) is used as a template under acidic conditions in the presence of inorganic additives. Moreover, the synthesis of the PMO material consisting of the MI precursor without TEOS has been realized. These novel PMO materials have large surface areas, well-ordered mesoporous structures, hollow fiberlike morphologies, and thick walls. They are also structurally well-ordered with a high organosilica precursor content, and the carbamothioic acid groups are thermally stable up to 250 degrees C. Furthermore, the organosilica materials exhibit hydrothermal stability in basic solution.
Gao
Ling
L
Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.
Wei
Feng
F
Zhou
Yu
Y
Fan
Xiao Xing
XX
Wang
Ying
Y
Zhu
Jian Hua
JH