A four-shell, 136-metal 3d-4f heterometallic cluster approximating a rectangular parallelepiped.
A nanosized heterometallic cluster containing 60 La(III) and 76 Ni(II) ions, which are arranged into a four-shell, nest-like framework structure, was obtained by the hydrolytic reaction of the mixed La(NO(3))(3)-Ni(NO(3))(2) system using iminodiacetate as an ancillary ligand to control the hydrolysis.
Kong
Xiang-Jian
XJ
State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China.
Long
La-Sheng
LS
Huang
Rong-Bin
RB
Zheng
Lan-Sun
LS
Harris
T David
TD
Zheng
Zhiping
Z
D006868:Hydrolysis; D007098:Imino Acids / Q000737:chemistry; D007811:Lanthanum / Q000737:chemistry*; D008024:Ligands; D008280:Magnetics; D008956:Models, Chemical; D036103:Nanotechnology; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D013696:Temperature
D007098:Imino Acids; D008024:Ligands; D009942:Organometallic Compounds; D007811:Lanthanum; D009532:Nickel; C008109:iminodiacetic acid