Boron-enriched star-shaped molecule via cycloaddition reaction.
The facile synthesis of a thermally stable carborane appended symmetrical star-shaped molecule having six bulky o-carborane clusters on the periphery, thereby containing sixty boron atoms was accomplished via a cobalt-catalyzed [2+2+2] cycloaddition reaction.
Prasanna Dash
Barada
B
Department of Chemistry and Biochemistry, Northern Illinois University, DeKalb, Illinois 60115-2862, USA.
Satapathy
Rashmirekha
R
Maguire
John A
JA
Hosmane
Narayan S
NS
D001554:Benzene / Q000737:chemistry; D001880:Boranes / Q000138:chemical synthesis* / Q000737:chemistry; D001895:Boron / Q000737:chemistry*; D002384:Catalysis; D003035:Cobalt / Q000737:chemistry; D050091:Dendrimers / Q000138:chemical synthesis / Q000737:chemistry
D001880:Boranes; D050091:Dendrimers; D003035:Cobalt; D001554:Benzene; D001895:Boron