Enhancing MQMAS of low-gamma nuclei by using a high B(1) field balanced probe circuit.
A balanced probe circuit is used to generate high B(1) magnetic field for sensitivity enhancement of multiple-quantum magic-angle spinning (MQMAS) experiment applied to low-gamma quadrupolar nuclei. Electrical balancing of the sample coil can cut the peak voltage by a half, therefore improving the power handling when generating a two-fold higher B(1) field. Experimental results, illustrated here with (25)Mg data for two layered double hydroxides, show that the MQMAS efficiency increases more than linearly with the B(1) field strength. The multiplicative enhancements from high B(0) and B(1) fields and an optimized MQMAS pulse sequence provide the critically needed sensitivity for acquiring MQMAS spectra of low-gamma quadrupolar nuclei such as (25)Mg at natural abundance.
Gan
Zhehong
Z
Center for Interdisciplinary Magnetic Resonance, National High Magnetic Field Laboratory, Florida State University, 1800 E. Paul Dirac Drive, Tallahassee, FL 32310, USA. gan@magnet.fsu.edu
Gor'kov
Peter L
PL
Brey
William W
WW
Sideris
Paul J
PJ
Grey
Clare P
CP
D000465:Algorithms; D000535:Aluminum / Q000032:analysis; D004574:Electromagnetic Fields; D005720:Gamma Rays; D008274:Magnesium; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D011868:Radioisotopes
D011868:Radioisotopes; D000535:Aluminum; D008274:Magnesium