Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa2P,N1,O]nickel(II).
The title compound, [Ni(C(20)H(17)N(3)OP)(N(3))], is the first complex with a semicarbazide-based ligand having a P atom as one of the donors. The influence of the P atom on the deformation of the coordination geometry of the Ni(II) ion is evident but less expressed than in the cases of complexes with analogous seleno- and thiosemicarbazide ligands. The torsion angles involving the two bonds formed by the P atom within the six-membered chelate ring have the largest values [C-P-Ni-N = 24.3 (2) degrees and C-C-P-Ni = -24.2 (4) degrees ], suggesting that the P atom considerably influences the conformation of the ring. Two types of N-H...N hydrogen bond connect the complex units into chains.
Novaković
Sladjana B
SB
Vinca Institute of Nuclear Sciences, Laboratory of Theoretical Physics and Condensed Matter Physics, PO Box 522, 11001 Belgrade, Serbia. snovak@vinca.rs
Bogdanović
Goran A
GA
Brceski
Ilija D
ID
Leovac
Vukadin M
VM
D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008024:Ligands; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*
D008024:Ligands; D009942:Organometallic Compounds; C542968:azido(2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa2P,N1,O)nickel(II); D009532:Nickel