title: Highly asymmetric cobalt-catalyzed aziridination of alkenes with trichloroethoxysulfonyl azide (TcesN3).
abstract: A Co(II)-based catalytic system has been developed for asymmetric aziridination of alkenes with trichloroethoxysulfonyl azide (TcesN3) under mild conditions, forming the corresponding N-Tces-aziridines in high yields and excellent enantioselectivities.
authors: Department of Chemistry, University of South Florida, Tampa, FL 33620-5250, USA.
authors: Velusamy
authors: V
authors: Subbarayan
authors: Joshua V
authors: JV
authors: Ruppel
authors: Shifa
authors: S
authors: Zhu
authors: Jason A
authors: JA
authors: Perman
authors: X Peter
authors: XP
authors: Zhang
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D001386:Azides / Q000737:chemistry*; D001388:Aziridines / Q000737:chemistry*; D002384:Catalysis; D003035:Cobalt / Q000737:chemistry*
chemical_list: D000475:Alkenes; D001386:Azides; D001388:Aziridines; C543266:trichloroethoxysulfonyl azide; D003035:Cobalt