title: Highly stereoselective synthesis of (Z,E)-1-halo-1,3-dienol esters via rearrangement of Fischer chromium chloro-carbenes using microwave irradiation.
abstract: Functionalized (Z,E)-1-halo-1,3-dienol esters are synthesized in a highly stereoselective manner via CrCl2-mediated rearrangement of allylic trihalomethylcarbinol esters induced by microwave irradiation.
authors: Laboratoire de Chimie des Systèmes Fonctionnels, UMR 7199, Faculté de Pharmacie, Université de Strasbourg, 74 Route du Rhin, B. P. 24, 67401 Illkirch, France.
authors: Dhurke
authors: D
authors: Kashinath
authors: Charles
authors: C
authors: Mioskowski
authors: J R
authors: JR
authors: Falck
authors: Mohan
authors: M
authors: Goli
authors: Stéphane
authors: S
authors: Meunier
authors: Rachid
authors: R
authors: Baati
authors: Alain
authors: A
authors: Wagner
mesh_terms: D002712:Chlorides / Q000737:chemistry*; D017608:Chromium Compounds / Q000737:chemistry*; D004952:Esters / Q000138:chemical synthesis* / Q000737:chemistry; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008872:Microwaves; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D002712:Chlorides; D017608:Chromium Compounds; D004952:Esters; C030011:carbene; C017133:chromous chloride; D008697:Methane