Zirconocene-mediated ligand-switched selective cleavage of active and inert carbon-carbon bonds in allylcyclopropanes.
Selective cleavage of both active and inert C-C bonds in substituted allylcyclopropanes was realized via a novel ligand-controlled approach using zirconocene(II)-1-butene or zirconocene(II)-benzyne complexes.
Wang
Chao
C
Beijing National Laboratory for Molecular Sciences, College of Chemistry, Peking University, 202, Chengfu Rd, Beijing 100871, China.
Deng
Liang
L
Yan
Jun
J
Wang
Hailin
H
Luo
Qian
Q
Zhang
Wen-Xiong
WX
Xi
Zhenfeng
Z