title: 1,10-phenanthrolines: versatile building blocks for luminescent molecules, materials and metal complexes.
abstract: 1,10-phenanthroline entails several appealing structural and chemical properties: rigidity, planarity, aromaticity, basicity, chelating capability. This makes it a versatile starting material for synthetic organic, inorganic and supramolecular chemistry. In this tutorial review we examine how the chemical versatility of pristine 1,10-phenanthroline, a weakly fluorescent molecule, has been exploited to design many UV-Vis-NIR luminescent organic derivatives and coordination compounds with transition-metal (Ru(ii), Os(ii), Rh(iii), Cr(iii), Pt(ii), Zn(ii), Cu(i), Ag(i)) and rare-earth (Eu(iii),Tb(iii), Yb(iii), Nd(iii), Er(iii)) cations. They are utilized for many analytical and technological applications.
authors: Molecular Photoscience Group-Istituto per la Sintesi Organica e la Fotoreattivitá (ISOF), Consiglio Nazionale delle Ricerche (CNR), Via Gobetti 101, 40129 Bologna, Italy.
authors: Gianluca
authors: G
authors: Accorsi
authors: Andrea
authors: A
authors: Listorti
authors: K
authors: K
authors: Yoosaf
authors: Nicola
authors: N
authors: Armaroli