Reduction of oxyiron(V) by sulfite and thiosulfate in aqueous solution.
The reduction of oxyiron(V), Fe(V)O(4)(3-) by inorganic oxysulfur species (SO(3)(2-) and S2O(3)(2-)) has been studied anaerobically in alkaline medium by using a premix pulse radiolysis technique. Studies on the reactions of Fe(VI)O(4)(2-) with the two sulfur radicals were also carried out. The spectroscopic results demonstrated that sulfur radicals reduced Fe(VI)O(4)(2-) to Fe(V)O(4)(3-) which is subsequently reduced by oxysulfur species by a two-electron reduction step to Fe(III). The rate constants for reduction of Fe(VI)O(4)(2-) to Fe(V)O(4)(3-) by sulfite and thiosulfate radicals (*SO3- and S4O(6)(*3-)) were found to be (1.9 +/- 0.3) x 10(8) and (7.5 +/- 0.8) x 10(7) M(-1) s(-1), respectively. However, the reactions of Fe(V)O(4)(3-) with the SO(3)(2-) and S2O(3)(2-) ions were separated by an order of magnitude, with SO(3)(2-) reacting at (3.9 +/- 0.3) x 10(4) M(-1) s(-1) while S2O(3)(2-) reacted with Fe(V) at (2.1 +/- 0.1) x 10(3) M(-1) s(-1) at pH 11.4.
Sharma
Virender K
VK
Department of Chemistry, Florida Institute of Technology, 150 West University Boulevard, Melbourne, Florida 32901, USA. vsharma@fit.edu
Cabelli
Diane
D
D005290:Ferric Compounds / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D010084:Oxidation-Reduction; D012996:Solutions; D013447:Sulfites / Q000737:chemistry*; D013455:Sulfur / Q000737:chemistry; D013885:Thiosulfates / Q000737:chemistry*; D014867:Water / Q000737:chemistry*
D005290:Ferric Compounds; D012996:Solutions; D013447:Sulfites; D013885:Thiosulfates; D014867:Water; C000499:ferric oxide; D013455:Sulfur