Highly stereoselective synthesis of (Z,E)-1-halo-1,3-dienol esters via rearrangement of Fischer chromium chloro-carbenes using microwave irradiation.
Functionalized (Z,E)-1-halo-1,3-dienol esters are synthesized in a highly stereoselective manner via CrCl2-mediated rearrangement of allylic trihalomethylcarbinol esters induced by microwave irradiation.
Kashinath
Dhurke
D
Laboratoire de Chimie des Systèmes Fonctionnels, UMR 7199, Faculté de Pharmacie, Université de Strasbourg, 74 Route du Rhin, B. P. 24, 67401 Illkirch, France.
Mioskowski
Charles
C
Falck
J R
JR
Goli
Mohan
M
Meunier
Stéphane
S
Baati
Rachid
R
Wagner
Alain
A
D002712:Chlorides / Q000737:chemistry*; D017608:Chromium Compounds / Q000737:chemistry*; D004952:Esters / Q000138:chemical synthesis* / Q000737:chemistry; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008872:Microwaves; D015394:Molecular Structure; D013237:Stereoisomerism
D002712:Chlorides; D017608:Chromium Compounds; D004952:Esters; C030011:carbene; C017133:chromous chloride; D008697:Methane