Kinetics and equilibrium of desorption removal of copper from magnetic polymer adsorbent.
This study examined the desorption of copper ions, which were adsorbed on the magnetic polymer adsorbent (MPA) of polyvinyl acetate-iminodiacetic acid (M-PVAC-IDA), by ethylenediaminetetraacetic acid (EDTA). Stage-wise desorptions were applied to remove the Cu(II) ions from the Cu(II) adsorbed M-PVAC-IDA (A-M-PVAC-IDA). About seven desorption runs were needed to regenerate the A-M-PVAC-IDA. The Cu(II) desorbed M-PVAC-IDA (D-M-PVAC-IDA) was then reused to adsorb the Cu(II) ions from the Cu(II) ions-containing solution. The cyclic adsorption and desorption operations (CADOs) were performed to further elucidate the kinetics and equilibria of the desorption system of EDTA/A-M-PVAC-IDA and the adsorption system of Cu(II)-containing solution/D-M-PVAC-IDA. Two simple kinetic models, the pseudo-first-order equation and pseudo-second-order equation, were employed to simulate the kinetic behaviors of adsorption and desorption. With respect to the kinetics of adsorption behavior, the simulated results by both kinetic models exhibit good agreement with the experimental data. However, the adsorption capacities (q(e)) estimated by the pseudo-first-order equation are more accurate in comparison with those simulated by the pseudo-second-order equation. As for the desorption kinetics, the examination of correlation coefficients of model fittings of data shows that the pseudo-first-order kinetic model gives the better agreement for the cases with different initial solid-phase concentrations and can accurately compute the equilibrium concentrations of solid-phase. The values of q(e) after CADOs are consistent with the predicted results via the previous work, evidencing that the adsorption behavior and the characteristics of the regenerated adsorbent of D-M-PVAC-IDA were not altered. In the experiments of desorbing copper ions and CADOs, the desorption isotherm was set up. The Freundlich and Langmuir adsorption (or desorption) isotherms were used to simulate the equilibrium of desorption. The results indicate that the Freundlich equation shows better agreement with the experimental data than the Langmuir equation. The information thus obtained is useful for the better use of M-PVAC-IDA on the removal of heavy mental ions of Cu(II) from the Cu(II) ion-containing water solution with the consideration of its regeneration.
Tseng
Jyi-Yeong
JY
Graduate Institute of Environmental Engineering, National Taiwan University, Taipei 106, Taiwan.
Chang
Ching-Yuan
CY
Chang
Chiung-Fen
CF
Chen
Yi-Hung
YH
Chang
Chia-Chi
CC
Ji
Dar-Ren
DR
Chiu
Chun-Yu
CY
Chiang
Pen-Chi
PC
D000327:Adsorption; D002614:Chelating Agents / Q000737:chemistry; D003300:Copper / Q000032:analysis* / Q000737:chemistry; D004492:Edetic Acid / Q000737:chemistry; D007098:Imino Acids / Q000737:chemistry; D007477:Ions; D007700:Kinetics; D008280:Magnetics; D008956:Models, Chemical; D011108:Polymers / Q000737:chemistry*; D011145:Polyvinyls / Q000737:chemistry; D013997:Time Factors; D014865:Waste Disposal, Fluid / Q000379:methods*; D014874:Water Pollutants, Chemical / Q000032:analysis; D018508:Water Purification / Q000379:methods*
D002614:Chelating Agents; D007098:Imino Acids; D007477:Ions; D011108:Polymers; D011145:Polyvinyls; D014874:Water Pollutants, Chemical; C013215:polyvinyl acetate; D003300:Copper; D004492:Edetic Acid; C008109:iminodiacetic acid