Intramolecular Ir(I)-catalyzed benzylic C-H bond amination of ortho-substituted aryl azides.
Iridium(I) catalyzes the intramolecular benzylic C-H bond amination of ortho-homobenzyl-substituted aryl azides to produce indolines at 25 degrees C.
Sun
Ke
K
Department of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, Chicago, Illinois 60607-7061, USA.
Sachwani
Rachna
R
Richert
Kathleen J
KJ
Driver
Tom G
TG
D000586:Amination; D001386:Azides / Q000737:chemistry*; D002384:Catalysis; D007211:Indoles / Q000138:chemical synthesis* / Q000737:chemistry; D007495:Iridium / Q000737:chemistry*; D015394:Molecular Structure
D001386:Azides; D007211:Indoles; D007495:Iridium; C057812:indoline