title: Pesticide transport via sub-surface drains in Europe.
abstract: Transport of pesticides from point of application via sub-surface drains can contribute significantly to contamination of surface waters. Results of 23 field drainage experiments undertaken at sites across Europe were collated and analysed by residual maximum likelihood. Both maximum concentration of pesticide in drainflow (n = 167) and seasonal loss of pesticide to drains (n = 97) were significantly related to strength of pesticide sorption to soil, half-life of the pesticide in soil, the interval between application and first drainflow and the clay content of the soil. The statistical models accounted for 71% of the variability in both maximum concentration and seasonal load. Next, the dataset was used to evaluate the current methodology for assessment of aquatic exposure used in pesticide registration in Europe. Simulations for seven compounds with contrasting properties showed a good correspondence with field measurements. Finally, the review examines management approaches to reduce pesticide transport via sub-surface drains. Despite a large amount of work in this area, there are few dependable mitigation options other than to change application rate or timing or to restrict use of a compound in the most vulnerable situations.
authors.affiliation: Environment Department, University of York, Heslington, York YO10 5DD, UK. cdb501@york.ac.uk
authors.forename: Colin D
authors.initials: CD
authors.lastname: Brown
authors.forename: Wendy
authors.initials: W
authors.lastname: van Beinum
mesh_terms: D005060:Europe; D007700:Kinetics; D008962:Models, Theoretical; D010575:Pesticides / Q000737:chemistry*; D014872:Water Movements; D014874:Water Pollutants, Chemical / Q000737:chemistry*
chemical_list: D010575:Pesticides; D014874:Water Pollutants, Chemical