title: A facile route to semiconductor nanocrystal-semiconducting polymer complex using amine-functionalized rod-coil triblock copolymer as multidentate ligand.
abstract: A facile strategy affording an intimate nanocomplex of an amine-containing rod-coil triblock copolymer poly(2-(dimethylamino)ethylmethacrylate)-poly(fluorene)-poly(2-(dimethyl amino) ethylmethacrylate) and CdSe nanocrystals is presented. Ligand exchange is observed by (31)P NMR. TEM and UV-vis absorption results indicate the CdSe NCs have a good dispersion in the conjugated polymer. Also, the PL spectra show photoinduced charge transfer has been facilitated by the complex formation.
authors.affiliation: Institute of Advanced Materials (IAM), Fudan University, Shanghai 200433, People's Republic of China.
authors.forename: Chun
authors.initials: C
authors.lastname: Fang
authors.forename: Xiao-Ying
authors.initials: XY
authors.lastname: Qi
authors.forename: Qu-Li
authors.initials: QL
authors.lastname: Fan
authors.forename: Lian-Hui
authors.initials: LH
authors.lastname: Wang
authors.forename: Wei
authors.initials: W
authors.lastname: Huang