Pseudo-allosteric regulation of the anion binding affinity of a macrocyclic coordination complex.
The anion binding affinity of a macrocyclic Rh complex can be allosterically regulated by reaction with a small molecule (an isocyanide), which effects a change in macrocycle size and shape.
Kuwabara
Junpei
J
Department of Chemistry and the International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208-3113, USA.
Yoon
Hyo Jae
HJ
Mirkin
Chad A
CA
DiPasquale
Antonio G
AG
Rheingold
Arnold L
AL