title: Synthesis and structure of an air-stable cationic organobismuth complex and its use as a highly efficient catalyst for the direct diastereoselective Mannich reaction in water.
abstract: An air-stable cationic organobismuth complex was successfully synthesized and found to show high catalytic efficiency in the direct diastereoselective Mannich reaction in water.
authors.affiliation: College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, China.
authors.forename: Renhua
authors.initials: R
authors.lastname: Qiu
authors.forename: Shuangfeng
authors.initials: S
authors.lastname: Yin
authors.forename: Xiaowen
authors.initials: X
authors.lastname: Zhang
authors.forename: Jun
authors.initials: J
authors.lastname: Xia
authors.forename: Xinhua
authors.initials: X
authors.lastname: Xu
authors.forename: Shenglian
authors.initials: S
authors.lastname: Luo
mesh_terms: D000388:Air; D001729:Bismuth / Q000737:chemistry*; D002384:Catalysis; D002412:Cations / Q000737:chemistry; D008352:Mannich Bases / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism; D014867:Water / Q000737:chemistry*
chemical_list: D002412:Cations; D008352:Mannich Bases; D009942:Organometallic Compounds; D014867:Water; D001729:Bismuth