Solvent-modulated metamagnetism in a nickel(ii) coordination polymer with mixed azide and carboxylate bridges.
A novel 2D coordination polymer consisting of ferromagnetic Ni(ii) chains with alternating double EO-azide bridges and (EO-azide)bis(carboxylate) triple bridges exhibits solvent-modulated metamagnetism, and the reversible dehydration/hydration processes are accompanied by significant changes in critical temperature, critical field and hysteresis.
Sun
Wei-Wei
WW
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China.
Tian
Chun-Yan
CY
Jing
Xue-Hui
XH
Wang
Yan-Qin
YQ
Gao
En-Qing
EQ