title: Surprising isomer preference on Ir(III), favoring facile H-C(sp(3)) bond cleavage.
abstract: Species (PNP)Ir(X)(Y), where PNP = N(SiMe(2)CH(2)P(t)Bu(2))(2)(-1) with X and Y halide, have a (t)Bu group C-H bond heterolytically split by addition across the Ir-N bond.
authors.affiliation: Department of Chemistry, Indiana University, 800 E. Kirkwood Avenue, Bloomington, Indiana, USA.
authors.forename: Nikolai P
authors.initials: NP
authors.lastname: Tsvetkov
authors.forename: Matthew F
authors.initials: MF
authors.lastname: Laird
authors.forename: Hongjun
authors.initials: H
authors.lastname: Fan
authors.forename: Maren
authors.initials: M
authors.lastname: Pink
authors.forename: Kenneth G
authors.initials: KG
authors.lastname: Caulton