Bulk homochirality of a 3-D inorganic framework: ligand control of inorganic network chirality.
Enantioselective synthesis of a 3-D inorganic net has been achieved leading to metal-organic frameworks built from cobalt-oxide helices in which handedness is controlled by the chirality of the linked ligand.
Livage
Carine
C
Institut Lavoisier, UMR CNRS 8180, Université de Versailles Saint-Quentin-en-Yvelines, 78035 Versailles, France. carine.livage@uvsq.fr
Guillou
Nathalie
N
Rabu
Pierre
P
Pattison
Philip
P
Marrot
Jérôme
J
Férey
Gérard
G
D002384:Catalysis; D003035:Cobalt / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D009532:Nickel / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry*; D013237:Stereoisomerism
D008024:Ligands; D009942:Organometallic Compounds; D010087:Oxides; D003035:Cobalt; D009532:Nickel; C060728:cobalt oxide