Rhodium-catalyzed asymmetric enyne cycloisomerization of terminal alkynes and formal total synthesis of (-)-platensimycin.
Nicolaou
K C
KC
Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, CA 92037, USA. kcn@scripps.edu
Li
Ang
A
Ellery
Shelby P
SP
Edmonds
David J
DJ
D000218:Adamantane / Q000138:chemical synthesis* / Q000737:chemistry; D000480:Alkynes / Q000737:chemistry*; D062365:Aminobenzoates / Q000138:chemical synthesis* / Q000737:chemistry; D000813:Anilides / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D018360:Crystallography, X-Ray; D007536:Isomerism; D008968:Molecular Conformation; D012238:Rhodium / Q000737:chemistry*
D000480:Alkynes; D062365:Aminobenzoates; D000813:Anilides; D012238:Rhodium; D000218:Adamantane; C510909:platensimycin