Versatile chemoselectivity in Ni-catalyzed multiple bond carbonylations and cyclocarbonylations in CO(2)-expanded liquids.
Selective mono or double carbonylations could be achieved by using CO(2)-expanded liquids in [2 + 2 + 1] carbonylative reactions of alkenes or acetylenes with allyl bromides catalyzed by Ni(i).
del Moral
Daniel
D
Homogeneous Catalysis Group, Institut de Ciència de Materials de Barcelona (CSIC), UAB Campus, 08193-Bellaterra, Spain.
Banet Osuna
Anna M
AM
Córdoba
Alba
A
Moretó
Josep M
JM
Veciana
Jaume
J
Ricart
Susagna
S
Ventosa
Nora
N
D000096:Acetone / Q000737:chemistry*; D000480:Alkynes / Q000737:chemistry; D000498:Allyl Compounds / Q000737:chemistry; D002245:Carbon Dioxide / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*
D000480:Alkynes; D000498:Allyl Compounds; D000096:Acetone; D002245:Carbon Dioxide; D009532:Nickel