Microwave-accelerated iridium-catalyzed borylation of aromatic C-H bonds.
Microwave heating accelerates the Ir-catalyzed C-H borylation of aromatic substrates when compared with reactions carried out at the same temperature under standard heating conditions. Application to a one-pot single solvent process for tandem C-H borylation/Suzuki-Miyaura cross-coupling sequences using microwave-accelerated reactions gives fast and efficient access to a wide range of biaryl and heterobiaryl compounds.
Harrisson
Peter
P
Department of Chemistry, Durham University, South Road, Durham DH1 3LE, UK.
Morris
James
J
Marder
Todd B
TB
Steel
Patrick G
PG