title: Removal of fluoride from aqueous environment by modified Amberlite resin.
abstract: Fluoride in drinking water above permissible level is responsible for human being affected by skeletal fluorosis. In this study, Amberlite XAD-4 has been modified by introducing amino group onto the aromatic ring for its application in fluoride remediation. Characterization of the modified resin was made by, FT-IR and elemental analysis (CHNS) techniques. The pH 9 was optimum value for quantitative sorption of fluoride in both batch and column experiments. The desorption of fluoride was achieved by using 10% HCl. The batch and column sorption studies of fluoride with modified resin were carried out to evaluate sorption isotherms too. Thus equation isotherms such as Langmuir, Freundlich, and Dubinin-Radushkevich (D-R) were successfully used to model the experimental data. The sorption capacity of modified Amberlite XAD-4 resin was found as 5.04 x 10(-3) mol g(-1). From the D-R isotherm parameters, it has been evaluated that the uptake of fluoride by modified resin occurs through ion exchange adsorption mechanism. The study will contribute toward the removal of fluoride from the aqueous environment as well as in the field of analytical and environmental chemistry.
authors.affiliation: National Center of Excellence in Analytical Chemistry, University of Sindh, Jamshoro 76080, Pakistan.
authors.forename: Imam Bakhsh
authors.initials: IB
authors.lastname: Solangi
authors.forename: Shahabuddin
authors.initials: S
authors.lastname: Memon
authors.forename: M I
authors.initials: MI
authors.lastname: Bhanger
mesh_terms: D000327:Adsorption; D002845:Chromatography / Q000379:methods; D005459:Fluorides / Q000032:analysis / Q000737:chemistry / Q000302:isolation & purification*; D006863:Hydrogen-Ion Concentration; D007477:Ions; D008956:Models, Chemical; D011137:Polystyrenes / Q000737:chemistry*; D011145:Polyvinyls / Q000737:chemistry*; D012117:Resins, Synthetic / Q000737:chemistry*; D013997:Time Factors; D014867:Water / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods*
chemical_list: D007477:Ions; D011137:Polystyrenes; D011145:Polyvinyls; D012117:Resins, Synthetic; D014874:Water Pollutants, Chemical; D014867:Water; C012101:XAD-4 resin; C046797:amberlite; D005459:Fluorides