title: A W-band pulsed EPR/ENDOR study of Co(II)S(4) coordination in the Co[(SPPh(2))(SP(i)Pr(2))N](2) complex.
abstract: Spin-echo detection at 95 GHz enables an electron-paramagnetic-resonance study of a cobalt complex with a bio-mimetic coordination of the transition metal by four sulfur atoms. A magnetically diluted single crystal of the complex has been investigated in great detail. Electron-nuclear double-resonance signals were observed of ligand nuclei and complete hyperfine tensors of the distinct phosphorus nuclei were derived, assigned and discussed.
authors.affiliation: Leiden University Niels Bohrweg 2, 2333 CA Leiden, The Netherlands. sottini@molphys.leidenuniv.nl
authors.forename: Silvia
authors.initials: S
authors.lastname: Sottini
authors.forename: Guinevere
authors.initials: G
authors.lastname: Mathies
authors.forename: Peter
authors.initials: P
authors.lastname: Gast
authors.forename: Dimitrios
authors.initials: D
authors.lastname: Maganas
authors.forename: Panayotis
authors.initials: P
authors.lastname: Kyritsis
authors.forename: Edgar J J
authors.initials: EJ
authors.lastname: Groenen
mesh_terms: D003035:Cobalt / Q000737:chemistry*; D004578:Electron Spin Resonance Spectroscopy; D009942:Organometallic Compounds / Q000737:chemistry*; D010758:Phosphorus / Q000032:analysis / Q000737:chemistry; D013455:Sulfur / Q000737:chemistry*
chemical_list: C544999:Co((SPPh(2))(SP(i)Pr(2))N)(2); D009942:Organometallic Compounds; D010758:Phosphorus; D003035:Cobalt; D013455:Sulfur