Phase-transfer of porphyrins by polypeptide-containing hyperbranched polymers and a novel iron(iii) porphyrin biomimetic catalyst.
Water-soluble porphyrins can be phase transferred by the hyperbranched multiarm copolymer PEI-PZLys; good catalytic activities and recyclabilities were observed for oxidation catalyzed by the encapsulated porphyrins.
Ren
Qi-Zhi
QZ
School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240, PR China. qzren@sjtu.edu.cn
Yao
Yuan
Y
Ding
Xiao-Jian
XJ
Hou
Zong-Sheng
ZS
Yan
De-Yue
DY
D032701:Biomimetics; D002384:Catalysis; D006418:Heme / Q000737:chemistry*; D015394:Molecular Structure; D010455:Peptides / Q000737:chemistry*; D044367:Phase Transition; D011108:Polymers / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry*; D012995:Solubility; D013050:Spectrometry, Fluorescence; D014867:Water / Q000737:chemistry
D010455:Peptides; D011108:Polymers; D011166:Porphyrins; D014867:Water; D006418:Heme