End-point detection in potentiometric titration by continuous wavelet transform.
The aim of this work was construction of the new wavelet function and verification that a continuous wavelet transform with a specially defined dedicated mother wavelet is a useful tool for precise detection of end-point in a potentiometric titration. The proposed algorithm does not require any initial information about the nature or the type of analyte and/or the shape of the titration curve. The signal imperfection, as well as random noise or spikes has no influence on the operation of the procedure. The optimization of the new algorithm was done using simulated curves and next experimental data were considered. In the case of well-shaped and noise-free titration data, the proposed method gives the same accuracy and precision as commonly used algorithms. But, in the case of noisy or badly shaped curves, the presented approach works good (relative error mainly below 2% and coefficients of variability below 5%) while traditional procedures fail. Therefore, the proposed algorithm may be useful in interpretation of the experimental data and also in automation of the typical titration analysis, specially in the case when random noise interfere with analytical signal.
Jakubowska
Małgorzata
M
Faculty of Materials Science and Ceramics, AGH University of Science and Technology, Kraków, Poland. jakubows@agh.edu.pl
Baś
Bogusław
B
Kubiak
Władysław W
WW
D000465:Algorithms; D011199:Potentiometry / Q000379:methods*; D017186:Titrimetry