Synthesis and structure of an air-stable cationic organobismuth complex and its use as a highly efficient catalyst for the direct diastereoselective Mannich reaction in water.
An air-stable cationic organobismuth complex was successfully synthesized and found to show high catalytic efficiency in the direct diastereoselective Mannich reaction in water.
Qiu
Renhua
R
College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, China.
Yin
Shuangfeng
S
Zhang
Xiaowen
X
Xia
Jun
J
Xu
Xinhua
X
Luo
Shenglian
S
D000388:Air; D001729:Bismuth / Q000737:chemistry*; D002384:Catalysis; D002412:Cations / Q000737:chemistry; D008352:Mannich Bases / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism; D014867:Water / Q000737:chemistry*
D002412:Cations; D008352:Mannich Bases; D009942:Organometallic Compounds; D014867:Water; D001729:Bismuth