title: Bulk homochirality of a 3-D inorganic framework: ligand control of inorganic network chirality.
abstract: Enantioselective synthesis of a 3-D inorganic net has been achieved leading to metal-organic frameworks built from cobalt-oxide helices in which handedness is controlled by the chirality of the linked ligand.
authors.affiliation: Institut Lavoisier, UMR CNRS 8180, Université de Versailles Saint-Quentin-en-Yvelines, 78035 Versailles, France. carine.livage@uvsq.fr
authors.forename: Carine
authors.initials: C
authors.lastname: Livage
authors.forename: Nathalie
authors.initials: N
authors.lastname: Guillou
authors.forename: Pierre
authors.initials: P
authors.lastname: Rabu
authors.forename: Philip
authors.initials: P
authors.lastname: Pattison
authors.forename: Jérôme
authors.initials: J
authors.lastname: Marrot
authors.forename: Gérard
authors.initials: G
authors.lastname: Férey
mesh_terms: D002384:Catalysis; D003035:Cobalt / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D009532:Nickel / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D008024:Ligands; D009942:Organometallic Compounds; D010087:Oxides; D003035:Cobalt; D009532:Nickel; C060728:cobalt oxide