Simultaneous oxidation of NO, SO2 and Hg0 from flue gas by pulsed corona discharge.
A process capable of simultaneously oxidizing NO, SO2, and Hg0 was proposed, using a high-voltage and short-duration positive pulsed corona discharge. By focusing on NO, SO2, and Hg0 oxidation efficiencies, the influences of pulse peak voltage, pulse frequency, initial concentration, electrode number, residence time and water vapor addition were investigated. The results indicate that NO, SO2 and Hg0 oxidation efficiencies depend primarily on the radicals (OH, HO2, O) and the active species (O3, H2O2, etc.) produced by the pulsed corona discharge. The NO, SO2 and Hg0 oxidation efficiencies could be improved as pulse peak voltage, pulse frequency, electrode number and residence time increased, but they were reduced with increasing initial concentrations. By adding water vapor, the SO2 oxidation efficiency was improved remarkably, while the NO oxidation efficiency decreased slightly. In our experiments, the simultaneous NO, SO2, and Hg0 oxidation efficiencies reached to 40%, 98%, and 55% with the initial concentrations 479 mg/m3, 1040 mg/m3, and 15.0 microg/m3, respectively.
Xu
Fei
F
State key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China. feix@zju.edu.cn
Luo
Zhongyang
Z
Cao
Wei
W
Wang
Peng
P
Wei
Bo
B
Gao
Xiang
X
Fang
Mengxiang
M
Cen
Kefa
K
D000393:Air Pollutants / Q000737:chemistry*; D055664:Electrochemical Techniques / Q000295:instrumentation / Q000379:methods; D004566:Electrodes; D007220:Industrial Waste; D008628:Mercury / Q000737:chemistry*; D009569:Nitric Oxide / Q000737:chemistry*; D010084:Oxidation-Reduction; D012037:Refuse Disposal / Q000379:methods; D013458:Sulfur Dioxide / Q000737:chemistry*; D014867:Water / Q000737:chemistry
D000393:Air Pollutants; D007220:Industrial Waste; D014867:Water; D013458:Sulfur Dioxide; D009569:Nitric Oxide; D008628:Mercury