Optically active metallo-supramolecular polymers derived from chiral bis-terpyridines.
The optically active metallo-supramolecular polymers were successfully synthesized via complexation of Fe(II) ions with new bis-terpyridines containing chiral tetra-ethylene glycol units at the ortho-position of the peripheral pyridine rings. In addition, we also revealed solvent and temperature effects toward assembly and dis-assembly behavior of polymers.
Pal
Ravindra R
RR
International Center for Materials Nanoarchitectonics, National Institute for Materials Science, 1-1 Namiki, Tsukuba 305-0044, Japan.
Higuchi
Masayoshi
M
Kurth
Dirk G
DG
D001896:Boron Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D002942:Circular Dichroism; D005296:Ferrous Compounds / Q000737:chemistry; D015394:Molecular Structure; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry; D011725:Pyridines / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D001896:Boron Compounds; D005296:Ferrous Compounds; D011108:Polymers; D011725:Pyridines