title: Pd(II)-catalyzed amination of C-H bonds using single-electron or two-electron oxidants.
abstract: Pd(II)-catalyzed intramolecular amination of arenes is developed using either a one- or two-electron oxidant. The reaction protocol tolerates a wide range of deactivating groups including acetyl, cyano, and nitro groups. This catalytic reaction allows expedient syntheses of broadly useful substituted indolines or indoles.
authors.affiliation: Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA.
authors.forename: Tian-Sheng
authors.initials: TS
authors.lastname: Mei
authors.forename: Xisheng
authors.initials: X
authors.lastname: Wang
authors.forename: Jin-Quan
authors.initials: JQ
authors.lastname: Yu
mesh_terms: D000586:Amination; D002384:Catalysis; D004583:Electrons; D007211:Indoles / Q000138:chemical synthesis*; D016877:Oxidants / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*
chemical_list: D007211:Indoles; D016877:Oxidants; D010165:Palladium; C057812:indoline