title: Synthesis of chiral fluorine-tagged reference standards for the (19)F NMR-based stereochemical analysis of sulfoxides at trace analytical levels.
abstract: Chiral fluorine-tagged sulfoxides of known absolute configuration have been synthesized. These compounds are required as reference standards to validate a (19)F NMR-based micromethod for the stereochemical analysis of biosynthetic fatty acyl sulfoxides.
authors.affiliation: Ottawa-Carleton Chemistry Institute, Department of Chemistry, Carleton University, 1125 Colonel By Drive, Ottawa, Ontario, Canada.
authors.forename: Amy E
authors.initials: AE
authors.lastname: Tremblay
authors.forename: Kim Y Y
authors.initials: KY
authors.lastname: Lao
authors.forename: Derek J
authors.initials: DJ
authors.lastname: Hodgson
authors.forename: Brian
authors.initials: B
authors.lastname: Dawson
authors.forename: Peter H
authors.initials: PH
authors.lastname: Buist
mesh_terms: D005461:Fluorine / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods* / Q000592:standards; D012015:Reference Standards; D013237:Stereoisomerism; D013454:Sulfoxides / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: D013454:Sulfoxides; D005461:Fluorine