Poly[diaqua[mu-1,4-bis(imidazol-1-ylmethyl)benzene-kappa2N3:N3'](mu-trans-cyclohexane-1,4-carboxylato-kappa2O1:O4)manganese(II)]: a three-dimensional hydrogen-bonding alpha-polonium net.
In the title coordination compound, [Mn(C8H10O4)(C14H14N4)(H2O)2]n, each Mn(II) centre occupies an inversion centre. The 1,4-bis(imidazol-1-ylmethyl)benzene (1,4-bix) ligand and the trans-cyclohexane-1,4-dicarboxylate dianion (chdc) both function in bridging modes, linking adjacent Mn(II) centres into a two-dimensional four-connected (4,4) network. These two-dimensional layers are stacked in a parallel mode. Hydrogen bonds between water molecules and carboxylate O atoms link neighbouring (4,4) networks, yielding a three-dimensional alpha-polonium net.
Wang
Qing-Wei
QW
College of Chemistry, Jilin Normal University, Siping 136000, People's Republic of China.
Wang
Xiu-Yan
XY
Wang
Ming
M
Li
Bing-Yang
BY
Ma
Xiao-Yuan
XY
D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008024:Ligands; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D014867:Water
D008024:Ligands; D009942:Organometallic Compounds; C543251:poly(diaqua(mu-1,4-bis(imidazol-1-ylmethyl)benzene-kappa2N3-N3')(mu-trans-cyclohexane-1,4-carboxylato-kappa)2O1-O4)manganese(II); D014867:Water; D008345:Manganese