Rh-catalyzed reductive coupling reaction of aldehydes with conjugated dienes promoted by triethylborane.
Rh(I) catalyzes the reductive coupling reaction of a wide variety of aldehydes with conjugated dienes in the presence of a stoichiometric amount of triethylborane to provide homoallyl alcohols in a single operation.
Kimura
Masanari
M
Department of Applied Chemistry, Faculty of Engineering, Nagasaki University, 1-14 Bunkyo-machi, Nagasaki 852-8521, Japan. masanari@nagasaki-u.ac.jp
Nojiri
Daisuke
D
Fukushima
Masahiro
M
Oi
Shuichi
S
Sonoda
Yusuke
Y
Inoue
Yoshio
Y
D000438:Alcohols / Q000138:chemical synthesis* / Q000737:chemistry; D000447:Aldehydes / Q000737:chemistry*; D001880:Boranes / Q000737:chemistry*; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D015394:Molecular Structure; D010084:Oxidation-Reduction; D012238:Rhodium / Q000737:chemistry*
D000438:Alcohols; D000447:Aldehydes; D001880:Boranes; D012238:Rhodium; C079756:triethylborane