Unusual allylpalladium carboxylate complexes: identification of the resting state of catalytic enantioselective decarboxylative allylic alkylation reactions of ketones.
Sherden
Nathaniel H
NH
The Arnold and Mabel Beckman Laboratories of Chemical Synthesis and the Caltech Center for Catalysis and Chemical Synthesis, Division of Chemistry and Chemical Engineering, California Institute of Technology, 1200 E. California Boulevard MC 164-30, Pasadena, CA 91125, USA.
Behenna
Douglas C
DC
Virgil
Scott C
SC
Stoltz
Brian M
BM
D000478:Alkylation; D002264:Carboxylic Acids / Q000737:chemistry*; D002384:Catalysis; D018360:Crystallography, X-Ray; D007659:Ketones / Q000737:chemistry*; D008968:Molecular Conformation; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
D002264:Carboxylic Acids; D007659:Ketones; D010165:Palladium