Chemically modified activated carbon with 1-acylthiosemicarbazide for selective solid-phase extraction and preconcentration of trace Cu(II), Hg(II) and Pb(II) from water samples.
A new sorbent 1-acylthiosemicarbazide-modified activated carbon (AC-ATSC) was prepared as a solid-phase extractant and applied for removing of trace Cu(II), Hg(II) and Pb(II) prior to their determination by inductively coupled plasma optical emission spectrometry (ICP-OES). The separation/preconcentration conditions of analytes were investigated, including effects of pH, the shaking time, the sample flow rate and volume, the elution condition and the interfering ions. At pH 3, the maximum static adsorption capacity of Cu(II), Hg(II) and Pb(II) onto the AC-ATSC were 78.20, 67.80 and 48.56 mg g(-1), respectively. The adsorbed metal ions were quantitatively eluted by 3.0 mL of 2% CS(NH2)2 and 2.0 mol L(-1) HCl solution. Common coexisting ions did not interfere with the separation. According to the definition of IUPAC, the detection limits (3sigma) of this method for Cu(II), Hg(II) and Pb(II) were 0.20, 0.12 and 0.45 ng mL(-1), respectively. The relative standard deviation under optimum conditions is less than 4.0% (n=8). The prepared sorbent was applied for the preconcentration of trace Cu(II), Hg(II) and Pb(II) in certified and water samples with satisfactory results.
Gao
Ru
R
Department of Chemistry, Lanzhou University, Lanzhou 730000, PR China.
Hu
Zheng
Z
Chang
Xijun
X
He
Qun
Q
Zhang
Lijun
L
Tu
Zhifeng
Z
Shi
Jianping
J
D000327:Adsorption; D002244:Carbon / Q000737:chemistry*; D002606:Charcoal / Q000737:chemistry; D003300:Copper / Q000302:isolation & purification*; D006863:Hydrogen-Ion Concentration; D007854:Lead / Q000302:isolation & purification*; D008628:Mercury / Q000302:isolation & purification*; D008670:Metals / Q000737:chemistry; D012663:Semicarbazides / Q000737:chemistry*; D052616:Solid Phase Extraction / Q000379:methods; D017550:Spectroscopy, Fourier Transform Infrared; D013997:Time Factors; D014865:Waste Disposal, Fluid / Q000379:methods; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods*
D008670:Metals; D012663:Semicarbazides; D014874:Water Pollutants, Chemical; D002606:Charcoal; D007854:Lead; D002244:Carbon; D003300:Copper; D008628:Mercury