catena-Poly[[[(iminodiacetato-kappaO)silver(I)]-mu3-2-aminopyrimidine-kappa3N1:N2:N3] monohydrate]: a one-dimensional silver(I) coordination polymer with mixed ligands.
The title compound, {[Ag(C4H6NO4)(C4H5N3)].H2O}n, was synthesized by the reaction of silver(I) nitrate with 2-aminopyrimidine and iminodiacetic acid. X-ray analysis reveals that the crystal structure contains a one-dimensional ladder-like Ag(I) coordination polymer and that N-H...O and O-H...O hydrogen bonding results in a three-dimensional network. The Ag(I) centre is four-coordinated by three N atoms from three different 2-aminopyrimidine ligands and one O atom from one iminodiacetate ligand. Comparison of the structural features with previous findings suggests that the existence of a second ligand plays an important role in the construction of such polymer frameworks.
Sun
Di
D
Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, People's Republic of China.
Luo
Geng-Geng
GG
Huang
Rong-Bin
RB
Zhang
Na
N
Zheng
Lan-Sun
LS
D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*
D008024:Ligands; D009942:Organometallic Compounds; D011108:Polymers; C543256:catena-Poly((((iminodiacetato-kappaO)silver(I))-mu3-2-aminopyrimidine-kappa3N1-N2-N3) monohydrate); D012834:Silver