A {Co32} nanosphere supported by p-tert-butylthiacalix[4]arene.
Calixarene-capped Co(32) clusters are constructed by a sodalite Co(II)(24) cage and an encapsulated Co(III)(8) cube. The spherical units are arranged into three isomeric structures, two of which are stacked by the bcc lattices and the third of which is assembled by the cubic closest packing of the spherical units.
Bi
Yanfeng
Y
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 130022 Changchun, China.
Wang
Xiu-Teng
XT
Liao
Wuping
W
Wang
Xiaofei
X
Wang
Xinwu
X
Zhang
Hongjie
H
Gao
Song
S
D003035:Cobalt / Q000737:chemistry*; D007536:Isomerism; D008280:Magnetics; D054118:Nanospheres / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010636:Phenols / Q000737:chemistry*
D009942:Organometallic Compounds; D010636:Phenols; C442852:p-tert-butylthiacalix(4)arene; D003035:Cobalt