An isolable o-quinodimethane and its fixation of molecular oxygen to give an endoperoxide.
Addition of the germene Mes2Ge=CR2 to 1,4-naphthoquinone yields a singular o-quinodimethane which gives Diels-Alder reactions at room temperature and reacts cleanly with oxygen to form an endoperoxide.
Ghereg
Dumitru
D
Université de Toulouse, UPS, LHFA, 118 route de Narbonne, F-31062, Toulouse, France.
Ech-Cherif El Kettani
Sakina
S
Lazraq
Mohamed
M
Ranaivonjatovo
Henri
H
Schoeller
Wolfgang W
WW
Escudié
Jean
J
Gornitzka
Heinz
H