title: Crossed intramolecular Rauhut-Currier-type reactions via dienamine activation.
abstract: The intramolecular Rauhut-Currier reaction creates a carbon-carbon bond between two tethered Michael acceptors. Previous asymmetric versions have relied on 1,4-additions of chiral nucleophilic catalysts. Herein, we investigate a novel strategy that involves the formation of electron rich dienamines as key intermediates. Our methodology provides an efficient entry to the iridoid framework.
authors: TU Dortmund University, Otto-Hahn-Str. 6, D-44227 Dortmund, Germany.
authors: Eugenia
authors: E
authors: Marqués-López
authors: Raquel P
authors: RP
authors: Herrera
authors: Timo
authors: T
authors: Marks
authors: Wiebke C
authors: WC
authors: Jacobs
authors: Daniel
authors: D
authors: Könning
authors: Renata M
authors: RM
authors: de Figueiredo
authors: Mathias
authors: M
authors: Christmann
mesh_terms: D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D003429:Cross Reactions; D018360:Crystallography, X-Ray / Q000379:methods; D003500:Cyclization; D006861:Hydrogen Peroxide / Q000737:chemistry; D015394:Molecular Structure; D010100:Oxygen / Q000737:chemistry* / Q000145:classification; D013237:Stereoisomerism
chemical_list: D002244:Carbon; D006861:Hydrogen Peroxide; D010100:Oxygen