title: A convenient ligand exchange pathway to [2Fe-2S] ferredoxin analogues.
abstract: The benzanellated analogues (NEt(4))(2)[Fe(2)S(2)(indolate)(4)] (2) and (NEt(4))(2)[Fe(2)S(2)(carbazolate)(4)] (3) of the previously reported parent (NEt(4))(2)[Fe(2)S(2)(pyrrolate)(4)] cluster (1) were synthesized and characterized spectroscopically. In contrast to 1 and 3, compound 2 can be applied as a versatile precursor in ligand exchange reactions with various thiophenols affording the thiophenolate-coordinate [2Fe-2S] clusters. Heteroaromatic thiols and chelating biphenols are suitable substrates in this conversion as well, providing a convenient access to a variety of new [2Fe-2S] ferredoxin analogues and related complexes. Several new S- and O-coordinate [2Fe-2S] clusters have been prepared and fully characterized, including five X-ray crystal structures.
authors: Institut für Anorganische Chemie, Georg-August-Universität, Göttingen, Germany.
authors: Joachim
authors: J
authors: Ballmann
authors: Xianru
authors: X
authors: Sun
authors: Sebastian
authors: S
authors: Dechert
authors: Benjamin
authors: B
authors: Schneider
authors: Franc
authors: F
authors: Meyer