A functional hybrid polyoxometalate framework based on a 'trilacunary' heteropolyanion [(P4W6O34)2Co2Na2(H2O)2]18-.
Using multifunctional organocations a novel heteropolyanion, [(P4W6O34)2Co2Na2(H2O)2]18-, with unprecedented structural features, has been observed, and extension of these clusters from molecules into 1D chains occurs through a dimeric cobalt species, with this material exhibiting reversible colour/magnetic susceptibility changes upon dehydration.
Ritchie
Chris
C
WestCHEM, Department of Chemistry, University of Glasgow, Joseph Black Building, University Avenue, Glasgow, UK G12 8QQ.
Li
Fengyan
F
Pradeep
Chullikkattil P
CP
Long
De-Liang
DL
Xu
Lin
L
Cronin
Leroy
L