Cooperativity in multiply H-bonded complexes.
The free energy of complexation of supramolecular complexes containing phenol-carbamate H-bonds is an additive function of the number of H-bonds, with a constant increment of 6 kJ mol(-1) per interaction in carbon tetrachloride.
Hunter
Christopher A
CA
Department of Chemistry, University of Sheffield, Sheffield, UK. c.hunter@shef.ac.uk
Ihekwaba
Ndidi
N
Misuraca
Maria Cristina
MC
Segarra-Maset
Maria Dolores
MD
Turega
Simon M
SM