An unprecedentedly huge square-grid copper(II)-organic framework material built from a bulky pyrene-derived elongated cross-shaped scaffold.
A new bulky pyrene-derived elongated cross-shaped organic scaffold was successfully incorporated into a highly porous, noninterpenetrated square-grid copper(II)-organic framework material with the unprecedentedly huge dimensions of 25.5 x 25.5 A(2), while the layer-to-layer NH...N interaction leads to a unique hydrogen-bonded 6(4).8(2)-nbo net.
Tsai
Chen-Chuan
CC
Institute of Chemistry, Academia Sinica, Taipei 115, Taiwan.
Luo
Tzuoo-Tsair
TT
Yin
Jen-Fu
JF
Lin
Hong-Cheu
HC
Lu
Kuang-Lieh
KL
D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D016062:Porosity; D011721:Pyrenes / Q000737:chemistry*; D013818:Thermogravimetry
D008024:Ligands; D009942:Organometallic Compounds; D011721:Pyrenes; D003300:Copper