title: The key intermediate in the amination of saturated C-H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)(2) (Ar = 3,5-(CF(3))(2)C(6)H(3)).
abstract: The complex Ru(TPP)(NAr)(2) inserts a nitrene group into allylic and benzylic C-H bonds and is the key intermediate in the ruthenium porphyrin-catalyzed amination of hydrocarbons by aryl azides.
authors: Dipartimento di Chimica Inorganica, Metallorganica e Analitica L Malatesta, Università di Milano and ISTM-CNR, Milano, Italy.
authors: Simone
authors: S
authors: Fantauzzi
authors: Emma
authors: E
authors: Gallo
authors: Alessandro
authors: A
authors: Caselli
authors: Fabio
authors: F
authors: Ragaini
authors: Nicola
authors: N
authors: Casati
authors: Piero
authors: P
authors: Macchi
authors: Sergio
authors: S
authors: Cenini