title: Role of distributions of intramolecular concentrations on the dynamics of miscible polymer blends probed by molecular dynamics simulation.
abstract: Using molecular dynamics simulations we show that a given monomer in a miscible polymer blend experiences broad distributions of both connectivity driven self-concentrations and thermodynamically controlled intermolecular concentration fluctuations. While these distributions should play a significant role in determining the constituent's dynamics across the whole concentration range, the distribution of self-concentrations is particularly important in the dilute limit, where intermolecular concentration fluctuations should be absent. These conclusions allow us to rationalize the recent literature results that report the apparent self-concentration determined in the dilute limit surprisingly depended on the blend partner.
authors: Department of Materials Science and Engineering, Pennsylvania State University, University Park, Pennsylvania 16802, USA.
authors: Wenjuan
authors: W
authors: Liu
authors: Dmitry
authors: D
authors: Bedrov
authors: Sanat K
authors: SK
authors: Kumar
authors: Boris
authors: B
authors: Veytsman
authors: Ralph H
authors: RH
authors: Colby