Fabrication of sphere-like Au nanoparticles on substrate with laser irradiation and their polarized localized surface plasmon behaviors.
The fabrications of sphere-like Au nanoparticles (NPs) on sapphire, GaN, and SiO(2) substrates through the irradiation of a few pulses of 266-nm laser onto Au thin films deposited on the substrates are demonstrated. The top-view diameter, contact angle on substrate, surface population density, and surface coverage percentage of the NPs can be controlled by the Au thin film thickness, laser energy density, substrate choice, and the gas or liquid, in which the Au thin film is immersed during laser irradiation. Optical transmission measurements show clear in-plane and out-of-plane localized surface plasmon resonance (LSPR) features, including the air resonance feature dictated by the gas or liquid immersing the NPs during transmission measurement, the in-plane substrate resonance feature controlled by the substrate material and the contact angle, and the out-of-plane resonance feature, which is strongly influenced also by the substrate material and the contact angle. Numerical simulations based on the finite-element method using the experimental parameters show highly consistent LSPR spectral positions and their variation trends. From the simulation results, one can also observe the relative importance between NP absorption and scattering in contributing to the extinction. This simple laser-irradiation method for fabricating sphere-like Au NPs of no aggregation and of strong adhesion to the substrate is useful for developing polarization-sensitive LSPR bio-sensing.
Chen
Cheng-Yen
CY
Department of Electrical Engineering, Institute of Photonics and Optoelectronics, National Taiwan University,Taipei, 10617 Taiwan.
Wang
Jyh-Yang
JY
Tsai
Fu-Ji
FJ
Lu
Yen-Cheng
YC
Kiang
Yean-Woei
YW
Yang
C C
CC
D003460:Crystallization / Q000379:methods*; D006046:Gold / Q000737:chemistry*; D007834:Lasers; D008422:Materials Testing; D054118:Nanospheres / Q000737:chemistry* / Q000528:radiation effects*; D036103:Nanotechnology / Q000379:methods*; D020349:Surface Plasmon Resonance / Q000379:methods*
D006046:Gold