Bulk shear-mode contribution to thermally generated capillary waves on a room-temperature ionic-liquid surface.
In the present work, we show that the autocorrelation function of the capillary-wave displacement is expressed by the sum of the ordinary oscillator and the bulk shear-mode terms. The former is expressed by a simple damped oscillator form or a sum of exponentially damping functions depending on the extent of damping. The latter is also written by superposition of exponentially damping modes, and an analytically exact formulation is obtained. We performed surface dynamic light-scattering experiment for the surface of an ionic liquid, 1-butyl- 3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide, and compared the experimental autocorrelation function with the theoretical one. We observed for the first time the bulk shear-mode contribution, and confirmed that the experimental data is well explained by the theoretical autocorrelation function.
Ohmasa
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Y
Department of Intelligent Mechanical Engineering, Faculty of Engineering, Hiroshima Institute of Technology, Hiroshima 731-5193, Japan. ohmasa@cc.it-hiroshima.ac.jp
Hoshino
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T
Osada
R
R
Yao
M
M