Subdiffusion in time-averaged, confined random walks.
Certain techniques characterizing diffusive processes, such as single-particle tracking or molecular dynamics simulation, provide time averages rather than ensemble averages. Whereas the ensemble-averaged mean-squared displacement (MSD) of an unbounded continuous time random walk (CTRW) with a broad distribution of waiting times exhibits subdiffusion, the time-averaged MSD, delta2, does not. We demonstrate that, in contrast to the unbounded CTRW, in which delta2 is linear in the lag time Delta, the time-averaged MSD of the CTRW of a walker confined to a finite volume is sublinear in Delta, i.e., for long lag times delta2 approximately Delta1-alpha. The present results permit the application of CTRW to interpret time-averaged experimental quantities.
Neusius
Thomas
T
Computational Molecular Biophysics, Universität Heidelberg, Im Neuenheimer Feld 368, D-69120 Heidelberg, Germany.
Sokolov
Igor M
IM
Smith
Jeremy C
JC