Metal-free, retro-cycloaddition of fulleropyrrolidines in ionic liquids under microwave irradiation.
Quantitative cycloreversion of fulleropyrrolidines to [60]fullerene is achieved in ionic liquids within minutes under microwave irradiation without any further additives.
Guryanov
Ivan
I
ITM-CNR and Department of Chemical Sciences, University of Padova, Padova, Italy.
Montellano López
Alejandro
A
Carraro
Mauro
M
Da Ros
Tatiana
T
Scorrano
Gianfranco
G
Maggini
Michele
M
Prato
Maurizio
M
Bonchio
Marcella
M
D002384:Catalysis; D003500:Cyclization / Q000528:radiation effects; D037741:Fullerenes / Q000737:chemistry*; D052578:Ionic Liquids / Q000737:chemistry* / Q000528:radiation effects*; D008872:Microwaves; D011759:Pyrrolidines / Q000737:chemistry*
D037741:Fullerenes; D052578:Ionic Liquids; D011759:Pyrrolidines; C069837:fullerene C60