title: Comparison of two experimental speciation methods with a theoretical approach to monitor free and labile Cd fractions in soil solutions.
abstract: This work focused on the suitability of two techniques to monitor cadmium speciation in soil solutions collected during a 7-day incubation of a contaminated soil. Anodic stripping voltammetry (ASV) and ion exchange were performed on soil solutions collected daily and results were compared with calculations obtained with the speciation software Visual MINTEQ. The electrochemically labile Cd fraction was greater than the exchange-estimated free Cd fraction during the first 6 days, after which it decreased sharply during the last 2 days to reach values close to the exchange-estimated free Cd fraction. Further investigations showed that the increase in pH was mainly responsible for the reduction. However, calculations performed with Visual MINTEQ software clearly demonstrated that a change in the nature of organic matter and/or its complexing capacity also needed to be taken into consideration.
authors: IPREM, UMR 5254, ECABIE, 64053 Pau Cedex 9, France. corinne.parat@univ-pau.fr
authors: C
authors: C
authors: Parat
authors: J-Y
authors: JY
authors: Cornu
authors: A
authors: A
authors: Schneider
authors: L
authors: L
authors: Authier
authors: V
authors: V
authors: Sapin-Didier
authors: L
authors: L
authors: Denaix
authors: M
authors: M
authors: Potin-Gautier
mesh_terms: D001578:Benzopyrans / Q000032:analysis; D002104:Cadmium / Q000032:analysis*; D004784:Environmental Monitoring; D006812:Humic Substances / Q000032:analysis; D006863:Hydrogen-Ion Concentration; D007474:Ion Exchange; D012984:Software; D012987:Soil; D012989:Soil Pollutants / Q000032:analysis*; D013997:Time Factors
chemical_list: D001578:Benzopyrans; D006812:Humic Substances; D012987:Soil; D012989:Soil Pollutants; D002104:Cadmium; C005023:fulvic acid