Formation of polymer brushes inside cylindrical pores: a computer simulation study.
The formation process of polymer brushes, formed by the adsorption of flexible end-functionalized chains from dilute solutions on the inner surface of cylindrical pores is studied by bond fluctuation Monte Carlo simulations. Various properties as the grafting density, monomer, and free-end distribution are monitored as a function of pore diameter D and chain length N. Two different modes of end-segment attachment on the inner pore surface are considered: (a) pure-irreversible "hard" grafting and (b) irreversible "soft" grafting where grafted-ends can move freely on the pore surface but cannot detach from it. Different regimes of pore coating are identified, depending on the mode of end-segment attachment and on the ratio of D to the radius of gyration of the free polymer chains in solution R(g). These initial findings can be used as a guide for the preparation of actual polymer brushes inside ordered porous membranes by the "grafting to" approach.
Koutsioubas
Alexandros G
AG
Department of Physics, University of Patras, Patras 26500, Greece.
Spiliopoulos
Nikolaos
N
Anastassopoulos
Dimitris L
DL
Vradis
Alexandros A
AA
Toprakcioglu
Chris
C