title: Selective retention of explosives and related compounds on gas-chromatographic capillary columns coated with lanthanide(III) beta-diketonate polymers.
abstract: The purpose of this research was to investigate coating capillary columns with lanthanide(III) beta-diketonate polymers to provide gas-chromatographic columns with selectivity toward explosives and related compounds. Capillary columns were statically coated with a mixture of a lanthanide(III) beta-diketonate polymer, which utilized p-di(4,4,5,5,6,6,6-heptafluoro-1,3-hexanedionyl)benzene (dihed) as a ligand, and SE-30. A novel coating technique was developed that used a methanol-containing azeotrope to provide solubility for both polymers while maintaining a low boiling point compatible with static coating. As based on temperature-programmed retention indices, the experimental columns displayed selective retention of nitroaromatic, nitroalkane, and nitrate ester test probes relative to an appropriate SE-30 control column. Selective retention was more pronounced for strongest Lewis base analyte contained in the test mixture (i.e., cyclohexanone). Relative analyte retention on the La(dihed), Tb(dihed), and Eu(dihed) columns are discussed relative to Lewis acidity and solubility of the polymer in the azeotropic coating solution.
authors: Pacific Northwest National Laboratory, National Security Directorate, MSIN: P7-07, 902 Battelle Boulevard, P.O. Box 999, Richland, WA 99352, USA. scott.harvey@pnl.gov
authors: Scott D
authors: SD
authors: Harvey
authors: Thomas J
authors: TJ
authors: Wenzel
mesh_terms: D004129:Dimethylpolysiloxanes / Q000737:chemistry; D053834:Explosive Agents / Q000032:analysis*; D005410:Flame Ionization / Q000295:instrumentation*; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry; D011108:Polymers / Q000737:chemistry*; D005466:Fluorocarbons
chemical_list: D004129:Dimethylpolysiloxanes; D053834:Explosive Agents; D028581:Lanthanoid Series Elements; D009942:Organometallic Compounds; D011108:Polymers; C535113:(4-bis(4,4,5,5,6,6,6-heptafluoro-1,3-hexanedionyl)benzene)lanthanum(III); D005466:Fluorocarbons