Quaternary tin(IV) antimony(III) sulfide decorated with lanthanum(III) ethylenediamine complexes: [La(en)4SbSnS5]2 x 0.5 H2O.
A quaternary tin(IV) antimony(III) sulfide decorated by lanthanum(III) ethylenediamine complexes, namely, [La(en)(4)SbSnS(5)](2) x 0.5 H(2)O (1; en = ethylenediamine), has been solvothermally synthesized and structurally, thermally, and optically characterized. Its structure features an isolated hexanuclear molecule of [La(en)(4)SbSnS(5)](2). The intermolecule hydrogen-bond interactions result in a three-dimensional supramolecular network, which remains intact upon dehydration.
Feng
Mei-Ling
ML
State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou 350002, People's Republic of China.
Ye
Dong
D
Huang
Xiao-Ying
XY
D000965:Antimony / Q000737:chemistry*; D018360:Crystallography, X-Ray; D005029:Ethylenediamines / Q000737:chemistry*; D006860:Hydrogen Bonding; D007811:Lanthanum / Q000737:chemistry*; D046911:Macromolecular Substances / Q000138:chemical synthesis / Q000737:chemistry; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013440:Sulfides / Q000737:chemistry*; D017971:Tin Compounds / Q000737:chemistry*
D005029:Ethylenediamines; D046911:Macromolecular Substances; D009942:Organometallic Compounds; D013440:Sulfides; D017971:Tin Compounds; C078041:tin sulfide; C031234:ethylenediamine; D007811:Lanthanum; D000965:Antimony; C064234:antimony trisulfide