Removal of phenol from aqueous solutions by adsorption onto organomodified Tirebolu bentonite: equilibrium, kinetic and thermodynamic study.
A natural bentonite modified with a cationic surfactant, cetyl trimethylammonium bromide (CTAB), was used as an adsorbent for removal of phenol from aqueous solutions. The natural and modified bentonites (organobentonite) were characterized with some instrumental techniques (FTIR, XRD and SEM). Adsorption studies were performed in a batch system, and the effects of various experimental parameters such as solution pH, contact time, initial phenol concentration, organobentonite concentration, and temperature, etc. were evaluated upon the phenol adsorption onto organobentonite. Maximum phenol removal was observed at pH 9.0. Equilibrium was attained after contact of 1h only. The adsorption isotherms were described by Langmuir and Freundlich isotherm models, and both model fitted well. The monolayer adsorption capacity of organobentonite was found to be 333 mg g(-1). Desorption of phenol from the loaded adsorbent was achieved by using 20% acetone solution. The kinetic studies indicated that the adsorption process was best described by the pseudo-second-order kinetics (R(2) > 0.99). Thermodynamic parameters including the Gibbs free energy (DeltaG degrees), enthalpy (DeltaH degrees), and entropy (DeltaS degrees) were also calculated. These parameters indicated that adsorption of phenol onto organobentonite was feasible, spontaneous and exothermic in the temperature range of 0-40 degrees C.
Senturk
Hasan Basri
HB
Department of Chemistry, Karadeniz Technical University, Faculty of Arts & Sciences, 61080 Trabzon, Turkey.
Ozdes
Duygu
D
Gundogdu
Ali
A
Duran
Celal
C
Soylak
Mustafa
M
D000327:Adsorption; D001546:Bentonite / Q000737:chemistry; D000077286:Cetrimonium; D002593:Cetrimonium Compounds / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D008855:Microscopy, Electron, Scanning / Q000379:methods; D019800:Phenol / Q000737:chemistry / Q000302:isolation & purification*; D013053:Spectrophotometry / Q000379:methods; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature; D013816:Thermodynamics; D013997:Time Factors; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods*; D014961:X-Ray Diffraction
D002593:Cetrimonium Compounds; D014874:Water Pollutants, Chemical; D001546:Bentonite; D019800:Phenol; D000077286:Cetrimonium