Changing the local coordination environment in mono- and bi- nuclear lanthanide complexes through "click" chemistry.
Alkyne appended lanthanide complexes derived from DO3A undergo copper catalysed cycloaddition reactions with azides to form triazole appended complexes: coordination of one of the triazole nitrogen atoms to the metal centre changes the local coordination environment and the spectroscopic properties of the complex.
Jauregui
Maite
M
School of Chemistry, University of Manchester, Oxford Road, Manchester, UK M13 9PL.
Perry
William S
WS
Allain
Clémence
C
Vidler
Lewis R
LR
Willis
Michael C
MC
Kenwright
Alan M
AM
Snaith
John S
JS
Stasiuk
Graeme J
GJ
Lowe
Mark P
MP
Faulkner
Stephen
S