Molecular tectonics: generation and structural studies on 1- and 2D coordination networks based on a meta-cyclophane in 1,3-alternate conformation bearing four pyrazolyl units and cobalt, zinc and copper cations.
The combination of a [1111] metacyclophane blocked in 1,3-alternate conformation and bearing four pyrazolyl coordinating units with MX(2) (M = Co, Zn and X = Cl or Br) leads to the formation of crystals formed by packing of 2D coordination networks. In the case of CuBr(2), the formation of a 1D network was observed. Structural studies by X-ray diffraction methods on single crystals were performed on all cases reported.
Ehrhart
Jérôme
J
Laboratoire de Chimie de Coordination Organique (UMR CNRS 7140), Université de Strasbourg, Institut Le Bel, 4 rue Blaise Pascal, 67000, Strasbourg, France.
Planeix
Jean-Marc
JM
Kyritsakas-Gruber
Nathalie
N
Hosseini
Mir Wais
MW