Investigating the photostability of carboxylic acids exposed to Mars surface ultraviolet radiation conditions.
The detection and identification of organic molecules on Mars are of primary importance to establish the existence of a possible ancient prebiotic chemistry or even biological activity. The harsh environmental conditions at the surface of Mars could explain why the Viking probes-the only efforts, to date, to search for organics on Mars-detected no organic matter. To investigate the nature, abundance, and stability of organic molecules that could survive such environmental conditions, we developed a series of experiments that simulate martian surface environmental conditions. Here, we present results with regard to the impact of solar UV radiation on various carboxylic acids, such as mellitic acid, which are of astrobiological interest to the study of Mars. Our results show that at least one carboxylic acid, mellitic acid, could produce a resistant compound-benzenehexacarboxylic acid-trianhydride (C(12)O(9))-when exposed to martian surface radiation conditions. The formation of such products could contribute to the presence of organic matter in the martian regolith, which should be considered a primary target for in situ molecular analyses during future surface missions.
Stalport
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Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA), Universities of Paris 7 and Paris 12, 94000 Créteil, France. stalport@lisa.univ-paris12.fr
Coll
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Szopa
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Cottin
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Raulin
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D001565:Benzoates / Q000737:chemistry; D019817:Benzoic Acid / Q000737:chemistry; D002264:Carboxylic Acids / Q000737:chemistry*; D019418:Evolution, Chemical; D005118:Extraterrestrial Environment / Q000737:chemistry*; D018535:Mars; D019815:Oxalic Acid / Q000737:chemistry; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet; D013499:Surface Properties / Q000528:radiation effects; D013997:Time Factors; D014466:Ultraviolet Rays
D001565:Benzoates; D002264:Carboxylic Acids; D019817:Benzoic Acid; D019815:Oxalic Acid; C015339:mellitic acid