Energetic ion, atom, and molecule reactions and excitation in low-current H2 discharges: spatial distributions of emissions.
Spatial distributions of H alpha , H beta , and the near-uv continuum emission from the H2 a ;{3}Sigma g;+ state are measured and compared with a model for low-current electrical discharges in H2 at high E/N and low Nd , where E is the spatially uniform electric field, N is the gas density, and d is the electrode separation. Data are analyzed for 300 Td<E/N<45 kTd , d=0.04 m , and 2 x 10;{21}<N<2.6 x 10;{22} m;{-3} . (1 Td=10;{-21} V m;{2}) The excitation is produced by electrons and by hydrogen atoms and molecules with mean energies from 5 to 1500 eV. Electron-induced emission, dominant at low E/N and low pressures, is distinguished by its buildup toward the anode. Excitation of H alpha by fast H atoms dominates at high E/N and increases toward the cathode. The observed H alpha emission at low E/N is normalized to previous experiments to yield absolute experimental excitation coefficients for all E/N and Nd . Small adjustments of model parameters yield good agreement with H alpha data. Cross sections are derived for excitation of the H2 near-uv continuum by H atoms. Spatial and pressure dependencies of H alpha and H2 near-uv emissions agree well with a model in which reactions of H2+ , H3+ , and H+ ions with H2 lead to fast H atoms and H2 molecules, which then excite H atoms or H2 molecules.
Petrović
Z Lj
ZLj
JILA, National Institute of Standards and Technology, USA. zoran.petrovic@phy.bg.ac.rs
Phelps
A V
AV