The key intermediate in the amination of saturated C-H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)(2) (Ar = 3,5-(CF(3))(2)C(6)H(3)).
The complex Ru(TPP)(NAr)(2) inserts a nitrene group into allylic and benzylic C-H bonds and is the key intermediate in the ruthenium porphyrin-catalyzed amination of hydrocarbons by aryl azides.
Fantauzzi
Simone
S
Dipartimento di Chimica Inorganica, Metallorganica e Analitica L Malatesta, Università di Milano and ISTM-CNR, Milano, Italy.
Gallo
Emma
E
Caselli
Alessandro
A
Ragaini
Fabio
F
Casati
Nicola
N
Macchi
Piero
P
Cenini
Sergio
S