Transformation of hydroxylamide into hydrazide units in the coordination spheres of group 4 metals.
Hydroxylamine units, bonded via their oxygen atom to a cyclo-pentadienyldimethylsilyl group are transformed into siloxy ligands and hydrazide units by the reaction with tetrakis(dimethylamido)-titanium and -zirconium by the same reaction principle but resulting in different aggregates of the products.
Willner
Alexander
A
Lehrstuhl für Anorganische Chemie und Strukturchemie, Universitätsstrasse 25, 33615, Bielefeld, Germany.
Neumann
Beate
B
Stammler
Hans-Georg
HG
Mitzel
Norbert W
NW