title: Spatial trends and historical deposition of mercury in eastern and northern Canada inferred from lake sediment cores.
abstract: Recent and historical deposition of mercury (Hg) was examined over a broad geographic area from southwestern Northwest Territories to Labrador and from the U.S. Northeast to northern Ellesmere Island using dated sediment cores from 50 lakes (18 in midlatitudes (41-50 degrees N), 14 subarctic (51-64 degrees N) and 18 in the Arctic (65-83 degrees N)). Distinct increases of Hg overtime were observed in 76% of Arctic, 86% of subarctic and 100% of midlatitude cores. Subsurface maxima in Hg depositional fluxes (microg m(-2) y(-1)) were observed in only 28% of midlatitude lakes and 18% of arctic lakes, indicating little recent reduction of inputs. Anthropogenic Hg fluxes adjusted for sediment focusing and changes in sedimentation rates (deltaF(adj,F)) ranged from -22.9 to 61 microg m(-2) y(-1) and were negatively correlated (r = -0.57, P < 0.001) with latitude. Hg flux ratios (FRs; post-1990)/pre-1850) ranged from 0.5 to 7.7. The latitudinal trend for Hg deltaF(adj,F) values showed excellent agreement with predictions of the global mercury model, GRAHM for the geographic location of each lake (r = 0.933, P < 0.001). The results are consistent with a scenario of slow atmospheric oxidation of mercury, and slow deposition of reactive mercury emissions, declining with increasing latitude away from emission sources in the midlatitudes, and support the view that there are significant anthropogenic Hg inputs in the Arctic.
authors: Environment Canada, Aquatic Ecosystem Protection Research Division, Burlington ON L7R 4A6, Canada. derek.muir@ec.gc.ca
authors: D C G
authors: DC
authors: Muir
authors: X
authors: X
authors: Wang
authors: F
authors: F
authors: Yang
authors: N
authors: N
authors: Nguyen
authors: T A
authors: TA
authors: Jackson
authors: M S
authors: MS
authors: Evans
authors: M
authors: M
authors: Douglas
authors: G
authors: G
authors: Köck
authors: S
authors: S
authors: Lamoureux
authors: R
authors: R
authors: Pienitz
authors: J P
authors: JP
authors: Smol
authors: W F
authors: WF
authors: Vincent
authors: A
authors: A
authors: Dastoor
mesh_terms: D001110:Arctic Regions; D001272:Atmosphere; D002170:Canada; D004784:Environmental Monitoring / Q000379:methods; D005843:Geography; D019015:Geologic Sediments; D008628:Mercury / Q000032:analysis / Q000633:toxicity*; D010100:Oxygen / Q000032:analysis; D013997:Time Factors; D014873:Water Pollutants / Q000032:analysis*; D014876:Water Pollution / Q000032:analysis; D014881:Water Supply
chemical_list: D014873:Water Pollutants; D008628:Mercury; D010100:Oxygen