title: Mediated electrochemical oxidation of a fully encapsulated redox active center.
abstract: While the direct electrochemical oxidation of ferrocene encapsulated inside a dimeric molecular capsule is essentially suppressed, a cationic ferrocene derivative binds to the capsule's external surface and acts as an effective electrochemical mediator.
authors.affiliation: Center for Supramolecular Science and Department of Chemistry, University of Miami, Coral Gables, Florida 33124-0431, USA.
authors.forename: Dagmara
authors.initials: D
authors.lastname: Podkoscielny
authors.forename: Suresh
authors.initials: S
authors.lastname: Gadde
authors.forename: Angel E
authors.initials: AE
authors.lastname: Kaifer
mesh_terms: D019281:Dimerization; D004563:Electrochemistry; D005296:Ferrous Compounds / Q000737:chemistry*; D000075163:Metallocenes; D008958:Models, Molecular; D010084:Oxidation-Reduction
chemical_list: D005296:Ferrous Compounds; D000075163:Metallocenes; C004998:ferrocene