title: Polarization-modulation infrared reflection-absorption spectroscopy affording time-resolved simultaneous detection of surface and liquid phase species at catalytic solid-liquid interfaces.
abstract: Polarization-modulation infrared reflection-absorption spectroscopy (PM-IRRAS) combined with concentration modulation allows simultaneous monitoring of dynamic evolutions of surface and liquid phase species during reactions at catalytic interfaces as demonstrated for the Pt-catalysed oxidation of CO by O2 in cyclohexane.
authors.affiliation: Department of Chemistry and Applied Biosciences, ETH Zurich, Hönggerberg, CH-8093 Zurich, Switzerland.
authors.forename: Daniel M
authors.initials: DM
authors.lastname: Meier
authors.forename: Atsushi
authors.initials: A
authors.lastname: Urakawa
authors.forename: Alfons
authors.initials: A
authors.lastname: Baiker
mesh_terms: D002248:Carbon Monoxide / Q000737:chemistry*; D002384:Catalysis; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry*; D013055:Spectrophotometry, Infrared / Q000379:methods; D013057:Spectrum Analysis / Q000379:methods; D013499:Surface Properties
chemical_list: D010984:Platinum; D002248:Carbon Monoxide; D010100:Oxygen