Strong hydrogen binding within a 3D microporous metal-organic framework.
A 3D microporous cadmium(II) metal-organic framework based on 1H-tetrazole exhibits strong hydrogen binding with an initial enthalpy of adsorption of 13.3 kJ/mol, due to the smaller pore sizes and the high hydrogen binding affinity of the tetrazolyl-ring-decorated inner surface of the pores.
Zhong
Di-Chang
DC
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, and School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.
Lin
Jian-Bin
JB
Lu
Wen-Guan
WG
Jiang
Long
L
Lu
Tong-Bu
TB
D002104:Cadmium / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006859:Hydrogen / Q000737:chemistry*; D008832:Microchemistry; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D016062:Porosity; D013777:Tetrazoles / Q000737:chemistry; D013816:Thermodynamics
D009942:Organometallic Compounds; D013777:Tetrazoles; D002104:Cadmium; C045574:1H-tetrazole; D006859:Hydrogen