Ionization studies in laser-excited alkaline-earth vapors.
We report on the time behavior of ionization signals produced by laser excitation of Ca and Ba atomic vapor to high-Rydberg states. A space-charge-limited thermionic diode detector shows a long-lived (>I-msec) ionization signal. However, optical detection of atomic ions (Ca+, Ba+) shows that these species live for much shorter times (<100 microsec). These results, in conjunction with published results on mass-spectrometric studies of high-density atomic beams, suggest that our ionization signal is primarily due to molecular species (Ca2+, Ba2+). We also observed optically pumped amplified spontaneous emission and stimulated electronic Raman scattering in Ca+ and Ba+.
Hermann
J P
JP
IBD Thomas J. Watson Research Center, PO Box 218, Yorktown Heights, New York 10598, USA.
Wynne
J J
JJ