Palladium(II) complexes of 1,10-phenanthroline: Synthesis and X-ray crystal structure determination.
Two palladium(II) complexes, [Pd(phen)(N identical withCCH(3))(2)][O(3)SCF(3)](2) (1) and [Pd(phen)(mu-OH)](2)[O(3)SCF(3)](2).2H(2)O (2) (where phen= 1,10-phenanthroline), have been crystallized following the reaction of Pd(phen)Cl(2) with silver triflate, Ag(O(3)SCF(3)), in acetonitrile and water, respectively. The structures of both complexes are based on a Pd(phen)(2+) metal core, with two acetonitrile molecules binding in a monodentate fashion in complex 1 and two hydroxo bridges holding together two cores to form a dimer in complex 2. Additionally, both complexes present a hydrogen bonded 3-D network involving the triflate anions in 1, and water and triflate anions in 2. Both complexes have been characterized by infrared and (1)H NMR spectroscopy and their crystal structures determined by X-ray crystallography.
Adrian
Rafael A
RA
Department of Chemistry, The University of Texas at San Antonio, San Antonio, TX 78249-0698 Email: judith.walmsley@utsa.edu.
Broker
Grant A
GA
Tiekink
Edward R T
ER
Walmsley
Judith A
JA
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17348722
Org Lett. 2007 Jun 7;9(12):2373-5
17497870
J Am Chem Soc. 2001 May 2;123(17):3940-52
11457144
J Org Chem. 2007 Mar 16;72(6):2232-5
17295543
J Org Chem. 1997 Oct 17;62(21):7512-7515
11671879
J Inorg Biochem. 2007 Feb;101(2):245-53
17097146
J Inorg Biochem. 2007 Mar;101(3):477-92
17208304
Inorg Chem. 2006 Nov 27;45(24):9688-95
17112264
Inorg Chem. 2007 Apr 16;46(8):3395-406
17358054