nu(3) vibrational ladder of SF(6).
From an analysis of the high-resolution spectrum of the 3nu(3) manifold of SF(6) , we have determined the anharmonicity constants to be (in reciprocal centimeters) X(33) =-1.7426, G(33)=0.9188, and T(33) = -0.24635. By using these constants, one can for the first time to our knowledge accurately predict the energies of the lower-vibrational sublevels of the nu(3) ladder and determine the pathways for multiple-photon absorption.
Patterson
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CW
Krohn
B J
BJ
Pine
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AS