Assembly of a 1D coordination polymer through in situ formation of a new ligand by double C-C coupling on CHCl3 under solvothermal conditions.
A rare in situ metal/ligand reaction has been observed during the assembly of a manganese-coordination polymer under solvothermal conditions, which leads to double C-C coupling on CHCl(3) involving cleavage of three C-Cl bonds and the formation of two new C-C bonds at the same carbon center.
Li
Guo-Bi
GB
MOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.
Liu
Jun-Min
JM
Yu
Zhi-Quan
ZQ
Wang
Wei
W
Su
Cheng-Yong
CY
D002244:Carbon / Q000737:chemistry*; D002725:Chloroform / Q000737:chemistry*; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D008345:Manganese / Q000737:chemistry*; D008745:Methylation; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry; D012997:Solvents / Q000737:chemistry; D021241:Spectrometry, Mass, Electrospray Ionization; D013696:Temperature
D008024:Ligands; D009942:Organometallic Compounds; D011108:Polymers; D011725:Pyridines; D012997:Solvents; D008345:Manganese; D002244:Carbon; D002725:Chloroform; C023666:pyridine