Synthesis of heteroaromatic compounds by oxidative aromatization using an activated carbon/molecular oxygen system.
A variety of heteroaromatic compounds, such as substituted pyridines, pyrazoles, indoles, 2-substituted imidazoles, 2-substituted imidazoles, 2-arylbenzazoles and pyrimidin-2(1H)-ones are synthesized by oxidative aromatization using the activated carbon and molecular oxygen system. Mechanistic study focused on the role of activated carbon in the synthesis of 2-arylbenzazoles is also discussed. In the final section, we will disclose the efficient synthesis of substituted 9,10-anthracenes via oxidative aromatization.
Kawashita
Yuka
Y
Department of Chemistry, Graduate School of Science, Kobe University, Kobe 657-8501, Japan.
Hayashi
Masahiko
M
D002606:Charcoal / Q000737:chemistry*; D006841:Hydrocarbons, Aromatic / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*
D006841:Hydrocarbons, Aromatic; D002606:Charcoal; D010100:Oxygen
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