X-ray emission spectroscopy.
We describe the chemical information that can be obtained by means of hard X-ray emission spectroscopy (XES). XES is presented as a technique that is complementary to X-ray absorption spectroscopy (XAS) and that provides valuable information with respect to the electronic structure (local charge- and spin-density) as well as the ligand environment of a 3d transition metal. We address non-resonant and resonant XES and present results that were recorded on Mn model systems and the Mn(4)Ca-cluster in the oxygen evolving complex of photosystem II. A brief description of the instrumentation is given with an outlook toward future developments.
Bergmann
Uwe
U
Stanford Synchrotron Radiation Lightsource, P.O. Box 20450, Stanford, CA 94305, USA. bergmann@slac.stanford.edu
Glatzel
Pieter
P
D004583:Electrons; D013052:Spectrometry, X-Ray Emission / Q000295:instrumentation / Q000379:methods*; D013816:Thermodynamics; D014965:X-Rays
J Synchrotron Radiat. 2007 Jul;14(Pt 4):361-5
17587662
Rev Sci Instrum. 2007 May;78(5):053101
17552806
J Am Chem Soc. 2001 Jul 25;123(29):7031-9
11459481
J Synchrotron Radiat. 2005 Jul;12(Pt 4):467-72
15968123
Proc Natl Acad Sci U S A. 2005 Aug 23;102(34):12047-52
16103362
Science. 2006 Nov 3;314(5800):821-5
17082458
J Phys Chem Solids. 2005 Dec 1;66(12):2163-2167
25308999
J Phys Chem B. 2006 Nov 23;110(46):23192-6
17107164
J Am Chem Soc. 2004 Aug 18;126(32):9946-59
15303869
J Am Chem Soc. 2001 Aug 15;123(32):7804-20
11493054
J Phys Chem B. 2006 Jun 22;110(24):11647-53
16800459
J Synchrotron Radiat. 2003 Jan 1;10(Pt 1):16-22
12511786
Phys Rev B Condens Matter. 1988 Aug 15;38(5):3158-3171
9946656
J Phys Chem B. 2005 Nov 10;109(44):20751-62
16853690
J Phys Chem A. 2006 May 18;110(19):6365-71
16686473
Phys Rev B Condens Matter. 1989 Sep 15;40(8):5715-5723
9992609
Phys Rev Lett. 1995 May 1;74(18):3700-3703
10058271
Phys Rev Lett. 1992 Mar 23;68(12):1943-1946
10045260
J Synchrotron Radiat. 2001 Mar 1;8(Pt 2):199-203
11512725
Phys Chem Chem Phys. 2004;6(20):4864-4870
25383041
Anal Chem. 2007 Sep 15;79(18):6933-40
17711350
Science. 2005 Nov 11;310(5750):1019-21
16284178
Phys Rev B Condens Matter. 1992 Dec 1;46(21):14274-14277
10003517
J Synchrotron Radiat. 2005 Jul;12(Pt 4):448-54
15968121
J Phys Condens Matter. 2009 Mar 11;21(10):104207
21817427
J Synchrotron Radiat. 2005 Jan;12(Pt 1):19-22
15616360