Palladium-catalyzed dehydrogenative coupling of furans with styrenes.
Under palladium(II)-catalyzed and oxidative conditions, the coupling of furans with styrenes leads to the formation of Heck-type products in medium to good yields. The reaction is highly regio- and stereoselective, giving trans-olefins predominantly.
Aouf
Chahinez
C
Institut de Chimie Moléculaire de Reims, UMR 6229, CNRS-Université de Reims Champagne-Ardenne, UFR des Sciences exactes et naturelles, BP 1039, 51687 Reims Cedex 2, France.
Thiery
Emilie
E
Le Bras
Jean
J
Muzart
Jacques
J
D000475:Alkenes / Q000138:chemical synthesis*; D002384:Catalysis; D005663:Furans / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism; D013343:Styrenes / Q000737:chemistry*
D000475:Alkenes; D005663:Furans; D013343:Styrenes; D010165:Palladium; D010100:Oxygen