Supercritical fluid extraction of the volatile oil from Santolina chamaecyparissus.
Supercritical fluid extraction (SFE) of the volatile oil from Santolina chamaecyparissus L. flower heads was performed under different conditions of pressure, temperature, mean particle size and CO(2) flow rate. This oil was compared with the essential oil isolated by hydrodistillation (HD). The SFE volatile and essential oils were analysed by GC and GC-MS. The range of the main volatile components obtained with HD and SFE were, respectively: 1,8-cineole (25-30% and 7-48%), camphor (7-9% and 8-14%), borneol (7-8% and 2-11%), terpinen-4-ol (6-7% and 1-4%), terpinolene (1-4% and 1-7%) and isobornyl acetate (1-2% and 1-11%). The chemical composition of the extracts was greatly influenced by the conditions of pressure and temperature used. In fact, it was possible to enrich the sesquiterpene fraction by increasing the pressure from 8 to 9 MPa, while changing the temperature from 50 to 40 degrees C at 9 MPa enriched the volatiles in n-alkanes [corrected].
Grosso
Clara
C
Departamento de Engenharia Química e Biológica, IST, Lisboa, Portugal.
Figueiredo
Ana Cristina
AC
Burillo
Jesus
J
Mainar
Ana M
AM
Urieta
José S
JS
Barroso
José G
JG
Coelho
José A
JA
Palavra
António M F
AM
D019659:Asteraceae / Q000737:chemistry*; D002245:Carbon Dioxide / Q000737:chemistry; D025924:Chromatography, Supercritical Fluid / Q000379:methods*; D035264:Flowers / Q000737:chemistry*; D009822:Oils, Volatile / Q000302:isolation & purification*; D010316:Particle Size; D011312:Pressure; D013696:Temperature
D009822:Oils, Volatile; D002245:Carbon Dioxide