title: Strong hydrogen binding within a 3D microporous metal-organic framework.
abstract: A 3D microporous cadmium(II) metal-organic framework based on 1H-tetrazole exhibits strong hydrogen binding with an initial enthalpy of adsorption of 13.3 kJ/mol, due to the smaller pore sizes and the high hydrogen binding affinity of the tetrazolyl-ring-decorated inner surface of the pores.
authors.affiliation: MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, and School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.
authors.forename: Di-Chang
authors.initials: DC
authors.lastname: Zhong
authors.forename: Jian-Bin
authors.initials: JB
authors.lastname: Lin
authors.forename: Wen-Guan
authors.initials: WG
authors.lastname: Lu
authors.forename: Long
authors.initials: L
authors.lastname: Jiang
authors.forename: Tong-Bu
authors.initials: TB
authors.lastname: Lu
mesh_terms: D002104:Cadmium / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006859:Hydrogen / Q000737:chemistry*; D008832:Microchemistry; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D016062:Porosity; D013777:Tetrazoles / Q000737:chemistry; D013816:Thermodynamics
chemical_list: D009942:Organometallic Compounds; D013777:Tetrazoles; D002104:Cadmium; C045574:1H-tetrazole; D006859:Hydrogen