Iron-catalyzed 1,4-hydroboration of 1,3-dienes.
A chemo-, regio-, and stereoselective iron-catalyzed 1,4-hydroboration of dienes that affords gamma-disubstituted allylboranes has been developed. 1,4-Hydroboration of 2-substituted dienes forms allylborane products with (E)-trisubstituted double bonds exclusively.
Wu
Jessica Y
JY
Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA 02138, USA.
Moreau
Benoît
B
Ritter
Tobias
T
D000466:Alkadienes / Q000737:chemistry*; D001896:Boron Compounds / Q000737:chemistry*; D002384:Catalysis; D007501:Iron / Q000737:chemistry*; D015394:Molecular Structure
D000466:Alkadienes; D001896:Boron Compounds; D007501:Iron