Catalytic direct acetoxylation of indoles.
3-Acetoxyindole-2-carboxylates could be readily synthesized in a Pd(OAc)(2)- or PtCl(2)-catalyzed direct C-3 acetoxylation of indole-2-carboxylates using PhI(OAc)(2) as a terminal oxidant.
Mutule
Ilga
I
Latvian Institute of Organic Synthesis, Aizkraukles 21, LV-1006, Riga, Latvia.
Suna
Edgars
E
Olofsson
Kristofer
K
Pelcman
Benjamin
B
D000107:Acetylation; D002264:Carboxylic Acids / Q000737:chemistry; D002384:Catalysis; D007211:Indoles / Q000138:chemical synthesis* / Q000737:chemistry; D008956:Models, Chemical; D016877:Oxidants / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*
D002264:Carboxylic Acids; D007211:Indoles; D016877:Oxidants; C503382:indole-2-carboxylate; D010165:Palladium