title: X-ray emission spectroscopy.
abstract: We describe the chemical information that can be obtained by means of hard X-ray emission spectroscopy (XES). XES is presented as a technique that is complementary to X-ray absorption spectroscopy (XAS) and that provides valuable information with respect to the electronic structure (local charge- and spin-density) as well as the ligand environment of a 3d transition metal. We address non-resonant and resonant XES and present results that were recorded on Mn model systems and the Mn(4)Ca-cluster in the oxygen evolving complex of photosystem II. A brief description of the instrumentation is given with an outlook toward future developments.
authors.affiliation: Stanford Synchrotron Radiation Lightsource, P.O. Box 20450, Stanford, CA 94305, USA. bergmann@slac.stanford.edu
authors.forename: Uwe
authors.initials: U
authors.lastname: Bergmann
authors.forename: Pieter
authors.initials: P
authors.lastname: Glatzel
mesh_terms: D004583:Electrons; D013052:Spectrometry, X-Ray Emission / Q000295:instrumentation / Q000379:methods*; D013816:Thermodynamics; D014965:X-Rays
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