title: 2D 1H and 13C NMR conformational studies of thienopyridines and carboline biarylic compounds.
abstract: In this paper, we report on conformational studies of biarylic compounds, as prepared through the well-known aza-Wittig methodology. The conformational studies were mainly realized by bidimensional (2D) nuclear magnetic resonance spectroscopy (NMR) and NOESY experiments. The conformational behavior showed that these biarylic compounds display an orthogonal symmetry and adopt a characteristic arrangement around the pivotal bond. Molecular modeling calculations were performed to support structure conformations.
authors.affiliation: Centro de Investigación en Química Sustentable, Facultad de Química, Universidad Autónoma del Estado de México, Toluca Estado de México, 50200, Mexico. barrios@servidor.unam.mx
authors.forename: D
authors.initials: D
authors.lastname: Corona
authors.forename: E
authors.initials: E
authors.lastname: Díaz
authors.forename: H
authors.initials: H
authors.lastname: Barrios
authors.forename: E
authors.initials: E
authors.lastname: Sánchez
authors.forename: C
authors.initials: C
authors.lastname: Alvarado
authors.forename: C K
authors.initials: CK
authors.lastname: Jankowski
authors.forename: A
authors.initials: A
authors.lastname: Guzmán
mesh_terms: D002243:Carbolines / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D008968:Molecular Conformation; D011725:Pyridines / Q000737:chemistry*
chemical_list: D002243:Carbolines; D011725:Pyridines; C446540:thienopyridine