A 12-connected dodecanuclear copper cluster with yellow luminescence.
The 3-D 12-connected metal-organic framework [Cu(12)Br(2)(CN)(6/2)(SCH(3))(6)][Cu(SCH(3))(2)], containing dodecanuclear copper clusters, has been solvothermally synthesized and exhibits efficient yellow luminescence. The emission mechanism was studied in detail to elucidate the relationship of the luminescent properties and crystal structures, which is helpful for the design and synthesis of more efficient luminescent materials.
Liu
Xi
X
Key Laboratory of Functional Materials, College of Chemistry, Chongqing Normal University, Chongqing 400047, People's Republic of China. xliu@cqnu.edu.cn
Huang
Kun-Lin
KL