Synthesis of meso-polyphosphorylporphyrins and example of self-assembling.
Pd-catalyzed coupling reactions have been used to prepare meso-phosphorylporphyrins. A 2D metal-organic network formed via P horizontal lineO...Zn axial supramolecular coordination of 5,15-bis(diethoxyphosphoryl)-10,20-diphenylporphyrin is the first example of a 2D framework based on phosphorylporphyrin derivatives.
Enakieva
Yulia Y
YY
Russian Academy of Science, Frumkin Institute of Physical Chemistry and Electrochemistry, Leninsky pr., 31, GSP-1, 119991, Moscow, Russia. yulia@igic.ras.ru
Bessmertnykh
Alla G
AG
Gorbunova
Yulia G
YG
Stern
Christine
C
Rousselin
Yoann
Y
Tsivadze
Aslan Y
AY
Guilard
Roger
R
D002384:Catalysis; D008665:Metalloporphyrins / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry; D015032:Zinc / Q000737:chemistry*
D008665:Metalloporphyrins; D010165:Palladium; D015032:Zinc