title: Regio- and stereoselective synthesis of multisubstituted vinylsilanes via zirconacycles.
abstract: A series of novel multisubstituted vinylsilanes are prepared regio- and stereoselectively by carbozirconation of various alkynylsilanes through zirconacycles such as zirconacyclopropenes and zirconacyclopentenes and the subsequent transformation of the formed alkenylzirconocene complexes.
authors.affiliation: Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530, Japan. ynishiha@cc.okayama-u.ac.jp
authors.forename: Yasushi
authors.initials: Y
authors.lastname: Nishihara
authors.forename: Daisuke
authors.initials: D
authors.lastname: Saito
authors.forename: Kenki
authors.initials: K
authors.lastname: Tanemura
authors.forename: Shintaro
authors.initials: S
authors.lastname: Noyori
authors.forename: Kentaro
authors.initials: K
authors.lastname: Takagi