title: Spin-canting and metamagnetic behavior in a new species from the hydrothermal Co(II)-trans-3-pyridylacrylate system.
abstract: Hydrothermal reaction of CoCl(2) with trans-3-pyridylacrylic acid (3-pycaH) and Et(3)N results in the formation of a new three-dimensional network formulated as [{Co(4)(mu-H(2)O)(2)(3-pyca)(8)}(0.94){Co(5)(mu(3)-OH)(2)(3-pyca)(8)}(0.06)]. Magnetic measurements reveal that spin-canting and metamagnetic behavior coexist in this compound with a critical temperature at 9.5 K.
authors.affiliation: Institut für Anorganische Chemie der Universität Karlsruhe, Karlsruhe Institute of Technology, Engesserstrasse 15, D-76131 Karlsruhe, Germany.
authors.forename: Kartik Chandra
authors.initials: KC
authors.lastname: Mondal
authors.forename: George E
authors.initials: GE
authors.lastname: Kostakis
authors.forename: Yanhua
authors.initials: Y
authors.lastname: Lan
authors.forename: Christopher E
authors.initials: CE
authors.lastname: Anson
authors.forename: Annie K
authors.initials: AK
authors.lastname: Powell