Ultrasound-assisted production of biodiesel fuel from vegetable oils in a small scale circulation process.
Biodiesel production from canola oil with methanol was performed in the presence of a base-catalyst by a circulation process at room temperature. In this process, the transesterification was accelerated by ultrasonic irradiation of low frequency (20 kHz) with an input capacity of 1 kW. The influences of various parameters on the transesterification reaction, including the amount of catalyst, the molar ratio of methanol to oil and the reaction time, were investigated. The objective of this work was to produce biodiesel satisfying the biodiesel-fuel standards of low energy consumption and material savings. The optimal conditions were: methanol/oil molar ratio of 5:1 and 0.7 wt.% catalyst in oil. Under these conditions, the conversion of triglycerides to fatty acid methyl esters was greater than 99% within the reaction time of 50 min. Crude biodiesel was purified by washing with tap water and drying at 70 degrees C under reduced pressure.
Thanh
Le Tu
le T
Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan.
Okitsu
Kenji
K
Sadanaga
Yasuhiro
Y
Takenaka
Norimichi
N
Maeda
Yasuaki
Y
Bandow
Hiroshi
H
D056804:Biofuels; D002384:Catalysis; D004951:Esterification; D007700:Kinetics; D010938:Plant Oils / Q000737:chemistry*; D014465:Ultrasonics
D056804:Biofuels; D010938:Plant Oils