title: Large H2 storage capacity of a new polyhedron-based metal-organic framework with high thermal and hygroscopic stability.
abstract: Two metal-organic frameworks (MOFs) based on metal-organic cuboctahedra were prepared using a rigid C3 symmetric ligand, where Zn polyhedron-based MOF (PMOF-2(Zn)) did not show any significant gas sorption behavior, whereas the isostructural Cu polyhedron-based MOF (PMOF-2(Cu)) showed a large surface area of approximately 4180 m2 g(-1), high hydrothermal stability, and very promising H2 sorption properties.
authors.affiliation: Department of Chemistry and Applied Chemistry, Hanyang University, Ansan, Kyunggi-do, 426-791, Korea.
authors.forename: Seunghee
authors.initials: S
authors.lastname: Hong
authors.forename: Minhak
authors.initials: M
authors.lastname: Oh
authors.forename: Mira
authors.initials: M
authors.lastname: Park
authors.forename: Ji Woong
authors.initials: JW
authors.lastname: Yoon
authors.forename: Jong-San
authors.initials: JS
authors.lastname: Chang
authors.forename: Myoung Soo
authors.initials: MS
authors.lastname: Lah