Ketoximes to N-substituted thioamides via PSCl3 mediated Beckmann rearrangement.
N-Substituted thioamides were accessed from ketoximes by utilising PSCl3 as a uniquely capable reagent to induce Beckmann rearrangement as well as to capture the intermediate nitrilium ion.
Pathak
Uma
U
Synthetic Chemistry Division, Defence R & D Establishment, Jhansi Road, Gwalior-474002, M. P. India. sc_drde@rediffmail.com
Pandey
Lokesh Kumar
LK
Mathur
Sweta
S
Suryanarayana
M V S
MV