title: Gas-phase energetics of actinide oxides: an assessment of neutral and cationic monoxides and dioxides from thorium to curium.
abstract: An assessment of the gas-phase energetics of neutral and singly and doubly charged cationic actinide monoxides and dioxides of thorium, protactinium, uranium, neptunium, plutonium, americium, and curium is presented. A consistent set of metal-oxygen bond dissociation enthalpies, ionization energies, and enthalpies of formation, including new or revised values, is proposed, mainly based on recent experimental data and on correlations with the electronic energetics of the atoms or cations and with condensed-phase thermochemistry.
authors.affiliation: Unidade de Ciências Químicas e Radiofarmaceuticas, Instituto Tecnológico e Nuclear, 2686-953 Sacavém, Portugal. jmarcalo@itn.pt
authors.forename: Joaquim
authors.initials: J
authors.lastname: Marçalo
authors.forename: John K
authors.initials: JK
authors.lastname: Gibson
mesh_terms: D008671:Actinoid Series Elements / Q000737:chemistry*; D002412:Cations / Q000737:chemistry; D003476:Curium / Q000737:chemistry*; D005740:Gases / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry*; D013816:Thermodynamics; D013910:Thorium / Q000737:chemistry*
chemical_list: D008671:Actinoid Series Elements; D002412:Cations; D005740:Gases; D010087:Oxides; D013910:Thorium; D003476:Curium