Isolation and structural X-ray investigation of perfluoroalkyl derivatives of six cage isomers of C84.
Perfluoroalkylation of a higher fullerene mixture with CF(3)I or C(2)F(5)I, followed by HPLC separation of CF(3) and C(2)F(5) derivatives, resulted in the isolation of several C(84)(R(F))(n) (n=12, 16) compounds. Single-crystal X-ray crystallography with the use of synchrotron radiation allowed structure elucidation of eight C(84)(R(F))(n) compounds containing six different C(84) cages (the number of the C(84) isomer is given in parentheses): C(84) (23)(C(2)F(5))(12) (I), C(84) (22)(CF(3))(16) (II), C(84) (22)(C(2)F(5))(12) (III), C(84) (11)(C(2)F(5))(12) (IV), C(84) (16)(C(2)F(5))(12) (V), C(84) (4)(CF(3))(12) (VI with toluene and VII with hexane as solvate molecules), and C(84) (18)(C(2)F(5))(12) (VIII). Whereas some connectivity patterns of C(84) isomers (22, 23, 11) had previously been unambiguously confirmed by different methods, derivatives of C(84) isomers numbers 4, 16, and 18 have been investigated crystallographically for the first time, thus providing direct proof of the connectivity patterns of rare C(84) isomers. General aspects of the addition of R(F) groups to C(84) cages are discussed in terms of the preferred positions in the pentagons under the formation of chains, pairs, and isolated R(F) groups.
Tamm
Nadezhda B
NB
Department of Chemistry, Moscow State University, 119991 Moscow, Leninskie gory, Russia.
Sidorov
Lev N
LN
Kemnitz
Erhard
E
Troyanov
Sergey I
SI