Structure of the sodium dodecyl sulfate surfactant on a solid surface in different NaCl solutions.
Studies of molecular dynamics simulations of sodium dodecyl sulfate (SDS) molecules adsorbed on a graphite surface in different salt (NaCl)/water solutions were conducted. The results showed the formation of hemicylindrical aggregates, at different salt concentrations, in agreement with atomic force microscopy (AFM) results. However, the hemicylinders exhibited different structures as the salt concentration was increased. At low concentrations, the internal structure of the hemicylinder formed well-defined SDS layers, parallel to the surface. However, when the amount of salt was increased, the top layer became less pronounced until it disappeared at the highest concentration. Density profiles of the SDS headgroups were also analyzed, and those profiles were found to become sharper as the NaCl concentration increased. The phenomenon was investigated in terms of how the aggregates wet the solid surface.
Domínguez
Hector
H
Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, UNAM, México DF 04510, Mexico. hectordc@servidor.unam.mx