Stereoselective synthesis of 2,6-cis-tetrahydropyrans through a tandem allylic oxidation/oxa-Michael reaction promoted by the gem-disubstituent effect: synthesis of (+)-neopeltolide macrolactone.
Kim
Hyoungsu
H
Department of Chemistry, Duke University, Durham, NC 27708, USA.
Park
Yongho
Y
Hong
Jiyong
J
D007783:Lactones / Q000138:chemical synthesis / Q000737:chemistry; D018942:Macrolides / Q000138:chemical synthesis / Q000737:chemistry; D015394:Molecular Structure; D010084:Oxidation-Reduction; D011714:Pyrans / Q000138:chemical synthesis / Q000737:chemistry; D013237:Stereoisomerism
D007783:Lactones; D018942:Macrolides; D011714:Pyrans; C519136:neopeltolide