An efficient catalyst system for Pd-catalyzed amination of [2.2]paracyclophanyl bromides.
A practical Buchwald-Hartwig amination of [2.2]paracyclophanyl bromides with benzhydrylideneamine is developed. The method provides a facile route to a variety of imino and amino [2.2]paracyclophanes that are otherwise not readily synthesized.
Qu
Bo
B
Department of Chemistry, Shandong University, Shanda South Road No. 27, Jinan 250100, People's Republic of China.
Ma
Yudao
Y
Ma
Qingshuang
Q
Liu
Xiao
X
He
Fuyan
F
Song
Chun
C