Addition of ArSSAr to dienes via intramolecular C-C bond formation initiated by a catalytic amount of ArS+.
A catalytic amount of electrochemically generated "ArS+" ("ArS+" = ArS(ArSSAr)+) initiates a cation chain reaction of dienes that involves the addition of ArSSAr associated with stereoselective intramolecular carbon-carbon bond formation, and the direct (in-cell) electrolysis of a mixture of a diene and ArSSAr with a catalytic amount of electricity also effectively initiates the reaction.
Matsumoto
Kouichi
K
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan.
Fujie
Shunsuke
S
Suga
Seiji
S
Nokami
Toshiki
T
Yoshida
Jun-ichi
J
D000466:Alkadienes / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D004220:Disulfides / Q000737:chemistry*; D004563:Electrochemistry; D006841:Hydrocarbons, Aromatic / Q000737:chemistry*; D008956:Models, Chemical; D013237:Stereoisomerism
D000466:Alkadienes; D004220:Disulfides; D006841:Hydrocarbons, Aromatic