title: Enhanced water purification: a single atom makes a difference.
abstract: The aluminum Keggin polycation (Al13) has been identified as an effective specie for neutralization and coagulation of anionic contaminants in water. In this study, we compare efficacy of the aluminum Keggin-ion to the analogues containing a single Ga-atom or single Ge-atom (GaAl12 and GeAl12, respectively) substituted into the center of the polycation in water-treatment studies. We investigated removal of bacteriophage (model viruses), Cryptosporidium, dissolved organic carbon (DOC), and turbidity. In every study, the order of contaminant removal efficacy trends GaAl12 > Al13 > GeAl12. By ESI MS (electrospray ionization mass spectrometry), we noted the GaAl12 deprotonates least of the three aluminum polycations, and thus probably carries the highest charge, and also optimal contaminant-neutralization ability. The ESI MS studies of the aluminum polycation solutions, as well as solid-state characterization of their resulting precipitates both reveal some conversion of Al13 to larger polycations, Al30 for instance. The GaAl12 does not show any evidence for this alteration that is responsible for poor shelf life of commercial prehydrolyzed aluminum coagulants such as polyaluminum chloride. Based on these studies, we conclude that substitution of a single Ga-atom in the center of the aluminum Keggin polycation produces an optimal water-treatment product due to enhanced shelf life and efficacy in neutralization of anionic contaminants.
authors.affiliation: Sandia National Laboratories, P.O. Box 5800 MS-0750, Albuquerque, New Mexico 87185, USA.
authors.forename: Tom A
authors.initials: TA
authors.lastname: Stewart
authors.forename: Daniel E
authors.initials: DE
authors.lastname: Trudell
authors.forename: Todd M
authors.initials: TM
authors.lastname: Alam
authors.forename: C André
authors.initials: CA
authors.lastname: Ohlin
authors.forename: Christian
authors.initials: C
authors.lastname: Lawler
authors.forename: William H
authors.initials: WH
authors.lastname: Casey
authors.forename: Stephen
authors.initials: S
authors.lastname: Jett
authors.forename: May
authors.initials: M
authors.lastname: Nyman
mesh_terms: D000535:Aluminum / Q000737:chemistry*; D000818:Animals; D002412:Cations / Q000737:chemistry*; D003458:Cryptosporidium; D005618:Fresh Water / Q000737:chemistry; D005708:Gallium / Q000737:chemistry; D005857:Germanium / Q000737:chemistry; D006801:Humans; D017909:Levivirus / Q000648:ultrastructure; D015394:Molecular Structure; D012996:Solutions / Q000737:chemistry; D014871:Water Microbiology; D014874:Water Pollutants, Chemical / Q000737:chemistry*; D018508:Water Purification / Q000379:methods*; D014881:Water Supply
chemical_list: D002412:Cations; D012996:Solutions; D014874:Water Pollutants, Chemical; D005857:Germanium; D005708:Gallium; D000535:Aluminum