Reversible uptake of HgCl2 in a porous coordination polymer based on the dual functions of carboxylate and thioether.
Bifunctional tetrakis(methylthio)-1,4-benzenedicarboxylic acid and Pb2+ ions form a robust porous net featuring free-standing thioether groups that allow reversible uptake of HgCl2.
Zhou
Xiao-Ping
XP
Department of Biology and Chemistry, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong, P. R. China.
Xu
Zhengtao
Z
Zeller
Matthias
M
Hunter
Allen D
AD
D000081:Acetamides / Q000737:chemistry; D000097:Acetonitriles / Q000737:chemistry; D000327:Adsorption; D001554:Benzene / Q000737:chemistry; D001555:Benzene Derivatives / Q000737:chemistry; D002264:Carboxylic Acids / Q000737:chemistry*; D018360:Crystallography, X-Ray; D007854:Lead / Q000737:chemistry; D008627:Mercuric Chloride / Q000737:chemistry*; D008958:Models, Molecular; D009566:Nitrates / Q000737:chemistry; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D013440:Sulfides / Q000737:chemistry*; D013818:Thermogravimetry; D014961:X-Ray Diffraction
D000081:Acetamides; D000097:Acetonitriles; D001555:Benzene Derivatives; D002264:Carboxylic Acids; D009566:Nitrates; D009942:Organometallic Compounds; D011108:Polymers; D013440:Sulfides; C533406:tetrakis(methylthio)-1,4-benzenedicarboxylic acid; D007854:Lead; D008627:Mercuric Chloride; C017461:lead nitrate; D001554:Benzene; C013959:dimethylacetamide; C032159:acetonitrile