Gold-catalyzed intermolecular Markovnikov hydroamination of allenes with secondary amines.
A cationic (CAAC)gold(I) complex promotes the addition of all types of nontertiary amines to a variety of allenes, affording allylic amines in good to excellent yields; the amino fragment always adds to the less substituted terminus of the CCC skeleton.
Zeng
Xiaoming
X
UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, California 92521-0403, USA.
Soleilhavoup
Michele
M
Bertrand
Guy
G
D000466:Alkadienes / Q000737:chemistry*; D000588:Amines / Q000737:chemistry*; D002384:Catalysis; D050607:Organogold Compounds / Q000737:chemistry*
D000466:Alkadienes; D000588:Amines; D050607:Organogold Compounds; C025947:propadiene