Ten-vertex {closo-2,1,10-FeC2B7} clusters with intramolecular imidate linkages: anchors for supramolecular construction.
Intramolecular hydroxyl attack upon iron-coordinated nitriles in a {closo-2,1,10-FeC2B7} system forms imidates that allow construction of a tetra-cluster {FeC2B7}-{C2Co2}-{C2Co2}-{FeC2B7} molecule.
Franken
Andreas
A
Department of Chemistry & Biochemistry, Baylor University, Waco, TX 76798-7348, USA.
McGrath
Thomas D
TD
Stone
F Gordon A
FG
D018360:Crystallography, X-Ray; D007096:Imidoesters / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D008968:Molecular Conformation; D009570:Nitriles / Q000737:chemistry
D007096:Imidoesters; D009570:Nitriles; D007501:Iron