title: Two regioisomers of endohedral pyrrolidinodimetallofullerenes M2@I(h)-C80(CH2)2NTrt (M = La, Ce; Trt = trityl): control of metal atom positions by addition positions.
abstract: The two regioisomers of endohedral pyrrolidinodimetallofullerenes M(2)@I(h)-C(80)(CH(2))(2)NTrt (M = La, Ce; Trt = trityl) were synthesized, isolated, and characterized. X-ray crystallographic analyses of [6,6]-La(2)@I(h)-C(80)(CH(2))(2)NTrt and [6,6]-Ce(2)@I(h)-C(80)(CH(2))(2)NTrt revealed that the encapsulated metal atoms are located at the slantwise positions on the mirror plane that parallels the pyrrolidine ring. Paramagnetic NMR analyses of [6,6]- and [5,6]-Ce(2)@I(h)-C(80)(CH(2))(2)NTrt were also carried out to clarify the metal positions. As for the [6,6]-adduct, the metal positions obtained by paramagnetic NMR analysis agree well with the X-ray structure. In contrast, paramagnetic NMR analysis of the [5,6]-adduct showed that the two Ce atoms are collinear with the pyrrolidine ring. We also compared the observed paramagnetic effects of the pyrrolidinodimetallofullerenes with those of other cerium-encapsulating fullerene derivatives such as bis-silylated Ce(2)@I(h)-C(80) and a carbene adduct of Ce(2)@I(h)-C(80). We found that the metal positions can be explained by the electrostatic potential maps of the corresponding [6,6]- and [5,6]-adducts of [I(h)-C(80)(CH(2))(2)NTrt](6-). These findings clearly show that metal positions inside fullerene cages can be controlled by means of the addition positions of the addends. In addition, the radical anions of the pyrrolidinodimetallofullerenes were prepared by bulk controlled-potential electrolysis and characterized by X-band EPR spectral study.
authors.affiliation: Center for Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan.
authors.forename: Michio
authors.initials: M
authors.lastname: Yamada
authors.forename: Mayuko
authors.initials: M
authors.lastname: Okamura
authors.forename: Satoru
authors.initials: S
authors.lastname: Sato
authors.forename: Chika I
authors.initials: CI
authors.lastname: Someya
authors.forename: Naomi
authors.initials: N
authors.lastname: Mizorogi
authors.forename: Takahiro
authors.initials: T
authors.lastname: Tsuchiya
authors.forename: Takeshi
authors.initials: T
authors.lastname: Akasaka
authors.forename: Tatsuhisa
authors.initials: T
authors.lastname: Kato
authors.forename: Shigeru
authors.initials: S
authors.lastname: Nagase