Asymmetric total synthesis and revised structure of cephalezomine H.
A revised structure of cephalezomine H, Cephalotaxus alkaloids, is presented. The originally assigned and revised structures of cephalezomine H were synthesized from the key intermediate for the synthesis of (-)-cephalotaxine.
Taniguchi
Tsuyoshi
T
School of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan.
Yokoyama
Shin'ichi
S
Ishibashi
Hiroyuki
H
D032483:Cephalotaxus / Q000737:chemistry*; D006248:Harringtonines / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism
D006248:Harringtonines; C545414:cephalezomine H