Annual metallic flows in roof runoff from different materials: test-bed scale in Paris conurbation.
A substantial database of annual metal runoff loads, obtained from a 14-month field exposure campaign on 12 different metal roofing materials at two sites within Paris conurbation, is presented herein. Thirteen metallic species have been considered. A comparison among the various roofing materials yields a ranking of their runoff pollution potential, which highlights that aluminum, coated products, and stainless steel display the lower emission levels, before zinc and copper materials. Lead materials appear to release more metallic species, and tend to do so in quite large quantities. Whatever the material family considered, older materials apparently release more metallic species with higher levels of emission. In considering zinc emissions from zinc-based materials, it is clear that surface coatings significantly reduce zinc emissions (40% less for the Zn3(PO4)2 surface-treated Anthra zinc, compared to natural zinc; and 99% less for prepainted galvanized steel compared to standard galvanized steel). In the case of Anthra zinc however, surface treatment induces the release of Ni into the runoff, and Ni constitutes a priority pollutant in the European Water Framework Directive (2000/60 CE). A high level of consistency with literature data has been found for Zn runoff when considering runoff rates reported at the same inclination.
Robert-Sainte
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Université Paris-Est, Laboratoire Eau, Environnement, Systèmes Urbains, UMR-MA102 - AgroParisTech: 6-8 avenue Blaise Pascal, Cité Descartes, Champs-sur-Marne, 77455 Marne La Vallée Cedex 2, France. Robert@cereve.enpc.fr
Gromaire
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De Gouvello
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Saad
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Chebbo
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D000535:Aluminum / Q000737:chemistry; D003252:Construction Materials; D004784:Environmental Monitoring / Q000379:methods; D005602:France; D006798:Housing; D008420:Manufactured Materials; D008670:Metals / Q000737:chemistry*; D015233:Models, Statistical; D009532:Nickel / Q000737:chemistry; D010710:Phosphates / Q000737:chemistry; D011891:Rain; D013232:Steel / Q000737:chemistry; D014872:Water Movements; D014873:Water Pollutants / Q000032:analysis*; D015032:Zinc / Q000737:chemistry; D017967:Zinc Compounds / Q000737:chemistry
D008670:Metals; D010710:Phosphates; D014873:Water Pollutants; D017967:Zinc Compounds; D013232:Steel; C043952:zinc phosphate; D009532:Nickel; D000535:Aluminum; D015032:Zinc