Palladium-catalyzed heteroannulation of [60]fullerene with anilides via C-H bond activation.
The palladium-catalyzed reaction of [60]fullerene with a variety of readily available anilides, initiated by C-H bond activation and followed by cyclization, afforded [60]fulleroindolines in a highly regioselective manner. A plausible reaction mechanism was proposed.
Zhu
Bo
B
Hefei National Laboratory for Physical Sciences at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, PR China.
Wang
Guan-Wu
GW