title: One-dimensional cyanide-bridged Mn(III)W(V) bimetallic complexes: metamagnetism, spontaneous resolution, and slow magnetic relaxation.
abstract: The reaction of [W(CN)(6)(bpy)](-) with the corresponding Mn Schiff bases led to the formation of two antiferromagnetic (1) and ferromagnetic (2) chains. The formation of the conglomerate (2) is associated with chiral induction by the enantiomeric chelate-ring conformation of the Mn Schiff base. Modulation of the linking groups in the Mn Schiff bases affects the interchain contacts, causing alteration of the magnetic behaviors from metamagnetism (1) to slow magnetic relaxation (2).
authors.affiliation: Department of Chemistry (BK21), Korea University, Seoul 136-713, Korea.
authors.forename: Seok Woo
authors.initials: SW
authors.lastname: Choi
authors.forename: Dae Won
authors.initials: DW
authors.lastname: Ryu
authors.forename: Jin Wuk
authors.initials: JW
authors.lastname: Lee
authors.forename: Jung Hee
authors.initials: JH
authors.lastname: Yoon
authors.forename: Hyoung Chan
authors.initials: HC
authors.lastname: Kim
authors.forename: Hyosug
authors.initials: H
authors.lastname: Lee
authors.forename: Beong Ki
authors.initials: BK
authors.lastname: Cho
authors.forename: Chang Seop
authors.initials: CS
authors.lastname: Hong