The solid-state 2:1 molecular complex of 1,5:3,7-dimethano-1,3,5,7-benzotetrazonine with hydroquinone.
The title compound, 1,5:3,7-dimethano-1,3,5,7-benzotetrazonine-hydroquinone (2/1), 2C(11)H(14)N(4).C(6)H(6)O(2), crystallizes with the hydroquinone molecule located on a center of inversion. In contrast to other hydroquinone-adamanzane adducts, which form extended hydrogen-bonded networks, in the present case, one hydroquinone molecule is linked to two 1,5:3,7-dimethano-1,3,5,7-benzotetrazonine molecules, forming a 2:1 cluster through O-H...N hydrogen bonds.
Rivera
Augusto
A
Departamento de Química, Universidad Nacional de Colombia, Colombia. ariverau@unal.edu.co
Guevara-Pulido
James
J
Sadat-Bernal
John
J
Ríos-Motta
Jaime
J
Zaragoza
Guillermo
G