title: Distribution of REEs in box-core sediments offshore an industrial area in SE Sicily, Ionian Sea: evidence of anomalous sedimentary inputs.
abstract: The distribution of rare earth elements and yttrium (REEs+Y) has been investigated in box-core sediments recovered from four stations in the Sicilian coastal zone seawards of Augusta, one of the most industrialized and contaminated areas in the Mediterranean region. Shale-like REE patterns and low Y/Ho ratios (close to the chondritic ratio) suggest a dominant terrigenous (geogenic) source for REE. Slight enrichment of LREE over the HREE is interpreted as due to preferential adsorptive transfer of LREE from seawater to sediment particles. Samples from offshore cores exhibit slightly positive Gd and negative Ce anomalies. It is here hypothesized that main drivers of anthropogenic Gd flux towards the offshore are dredged contaminated materials that, recovered from the Augusta Bay, have been repeatedly discharged offshore. Consistent with the redox-chemistry of Ce, these anomalous sedimentary inputs induce a decrease of O(2) concentration in the sediment, which in turn triggers Ce regeneration.
authors.affiliation: Dipartimento di Chimica e Fisica della Terra ed Applicazioni alle Georisorse e ai Rischi Naturali (CFTA), Università degli Studi di Palermo, via Archirafi 36, 90123 Palermo, Italy.
authors.forename: Rossella
authors.initials: R
authors.lastname: Di Leonardo
authors.forename: Adriana
authors.initials: A
authors.lastname: Bellanca
authors.forename: Rodolfo
authors.initials: R
authors.lastname: Neri
authors.forename: Giorgio
authors.initials: G
authors.lastname: Tranchida
authors.forename: Salvo
authors.initials: S
authors.lastname: Mazzola
mesh_terms: D002563:Cerium / Q000032:analysis; D004784:Environmental Monitoring; D005682:Gadolinium / Q000032:analysis; D019015:Geologic Sediments / Q000737:chemistry*; D007220:Industrial Waste; D008674:Metals, Rare Earth / Q000032:analysis / Q000737:chemistry*; D009792:Oceans and Seas; D012802:Sicily; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000737:chemistry*
chemical_list: D007220:Industrial Waste; D008674:Metals, Rare Earth; D014874:Water Pollutants, Chemical; D002563:Cerium; D005682:Gadolinium