Heteropoly-13-palladates(II) [Pd(II)(13)(As(V)Ph)(8)O(32)](6-) and [Pd(II)(13)Se(IV)(8)O(32)](6-).
Two discrete anionic palladium(II)-oxo clusters have been prepared: [Pd(13)(As(V)Ph)(8)O(32)](6-) (1) and [Pd(13)Se(IV)(8)O(32)](6-) (2) were synthesized in one-pot self-assembly reactions of Pd(OAc)(2) with PhAsO(3)H(2) and SeO(2) and characterized by single-crystal X-ray analysis, IR, thermogravimetric analysis, elemental analysis, magnetic and electron paramagnetic resonance measurements, and electrochemistry.
Izarova
Natalya V
NV
Jacobs University, School of Engineering and Science, P.O. Box 750 561, 28725 Bremen, Germany.
Dickman
Michael H
MH
Biboum
Rosa Ngo
RN
Keita
Bineta
B
Nadjo
Louis
L
Ramachandran
Vasanth
V
Dalal
Naresh S
NS
Kortz
Ulrich
U