TG-FTIR study on urea-formaldehyde resin residue during pyrolysis and combustion.
The pyrolysis and combustion characteristics of urea-formaldehyde resin (UFR) residue were investigated by using thermogravimetric analysis, coupled with Fourier transform infrared spectroscopy (TG-FTIR). It is indicated that the pyrolysis process can be subdivided into three stages: drying the sample, fast thermal decomposition and further cracking process. The total weight loss of 90 wt.% at 950 degrees C is found in pyrolysis, while 74 wt.% of the original mass lost in the second stage is between 195 degrees C and 430 degrees C. The emissions of carbon dioxide, isocyanic acid, ammonia, hydrocyanic acid and carbon monoxide are identified in UFR residue pyrolysis, moreover, isocyanic acid emitted at low temperature is found as the most important nitrogen-containing gaseous product in UFR residue pyrolysis, and there is a large amount of hydrocyanic acid emitted at high temperature. The similar TG and emission characteristics as the first two stages during pyrolysis are found in UFR residue combustion at low temperature. The combustion process almost finishes at 600 degrees C; moreover, carbon dioxide and water are identified as the main gaseous products at high temperature. It is indicated that the UFR residue should be pyrolyzed at low temperature to remove the initial nitrogen, and the gaseous products during pyrolysis should be burnt in high temperature furnace under oxygen-rich conditions for pollutant controlling.
Jiang
Xuguang
X
State Key Laboratory of Clean Energy Utilization, Zhejiang University, Zheda Road 38#, Hangzhou, Zhejiang Province, 310027, China. jiangxg@zju.edu.cn
Li
Chunyu
C
Chi
Yong
Y
Yan
Jianhua
J
D000395:Air Pollutants, Occupational / Q000032:analysis; D005557:Formaldehyde / Q000737:chemistry*; D015386:Hazardous Substances / Q000032:analysis; D006256:Hazardous Waste / Q000032:analysis; D017745:Incineration; D007220:Industrial Waste; D007700:Kinetics; D012037:Refuse Disposal; D013055:Spectrophotometry, Infrared; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature; D013818:Thermogravimetry; D014508:Urea / Q000737:chemistry*
D000395:Air Pollutants, Occupational; D015386:Hazardous Substances; D006256:Hazardous Waste; D007220:Industrial Waste; D005557:Formaldehyde; C028278:urea formaldehyde foam; D014508:Urea