Structure, magnetism, and ionic conductivity of the gigantic {Mo176}-wheel assembly: Na15Fe3Co16[Mo176O528H3(H2O)80]Cl27 x 450 H2O.
Single crystals of the nanoscale polyoxomolybdate wheel, Na(15)Fe(3)Co(16)[Mo(176)O(528)(H(2)O)(80)]Cl(27) x 450 H(2)O, was synthesized by the condensation reaction of Na(0.4)Co(0.8)[MoO(4)] x 1.5 H(2)O at low pH and in the presence of an iron-based reducing agent, and these crystals were characterized by the synchrotron-based X-ray single crystal analysis, magnetic susceptibility, and ionic conductivity measurements.
Imai
Hiroyuki
H
Research Institute for Electronic Science, Hokkaido University, N20W10 kita-ku, Sapporo 001-0020, Japan.
Akutagawa
Tomoyuki
T
Kudo
Fumito
F
Ito
Mitsuhiro
M
Toyoda
Kazuhiro
K
Noro
Shin-ichiro
S
Cronin
Leroy
L
Nakamura
Takayoshi
T