title: Heteropoly-13-palladates(II) [Pd(II)(13)(As(V)Ph)(8)O(32)](6-) and [Pd(II)(13)Se(IV)(8)O(32)](6-).
abstract: Two discrete anionic palladium(II)-oxo clusters have been prepared: [Pd(13)(As(V)Ph)(8)O(32)](6-) (1) and [Pd(13)Se(IV)(8)O(32)](6-) (2) were synthesized in one-pot self-assembly reactions of Pd(OAc)(2) with PhAsO(3)H(2) and SeO(2) and characterized by single-crystal X-ray analysis, IR, thermogravimetric analysis, elemental analysis, magnetic and electron paramagnetic resonance measurements, and electrochemistry.
authors.affiliation: Jacobs University, School of Engineering and Science, P.O. Box 750 561, 28725 Bremen, Germany.
authors.forename: Natalya V
authors.initials: NV
authors.lastname: Izarova
authors.forename: Michael H
authors.initials: MH
authors.lastname: Dickman
authors.forename: Rosa Ngo
authors.initials: RN
authors.lastname: Biboum
authors.forename: Bineta
authors.initials: B
authors.lastname: Keita
authors.forename: Louis
authors.initials: L
authors.lastname: Nadjo
authors.forename: Vasanth
authors.initials: V
authors.lastname: Ramachandran
authors.forename: Naresh S
authors.initials: NS
authors.lastname: Dalal
authors.forename: Ulrich
authors.initials: U
authors.lastname: Kortz