Cationic palladium complex catalyzed diastereo- and enantioselective tandem annulation of 2-formylarylboronic acids with allenoates.
Cationic palladium complex [(dppp)Pd(H(2)O)(2)](2+)(BF(4)(-))(2) catalyzed tandem annulation reactions of 2-formylarylboronic acids and allenoates produce the indenol derivatives diastereo- and enantioselectively in a highly efficient way.
Yu
Xufen
X
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China.
Lu
Xiyan
X
D000438:Alcohols / Q000138:chemical synthesis* / Q000737:chemistry; D000466:Alkadienes / Q000737:chemistry*; D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D002412:Cations / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
D000438:Alcohols; D000466:Alkadienes; D001897:Boronic Acids; D002412:Cations; D009942:Organometallic Compounds; D010165:Palladium