Sonochemical synthesis of nanoscale mixed-ligands lead(II) coordination polymers as precursors for preparation of Pb(2)(SO(4))O and PbO nanoparticles; thermal, structural and X-ray powder diffraction studies.
Nano-structures of two new Pb(II) two-dimensional coordination polymers, [Pb(micro-4-pyc)(micro-NCS)(micro-H(2)O)](n) (1) and [Pb(micro-4-pyc)(micro-N(3))(micro-H(2)O)](n) (2), 4-Hpyc=4-pyridinecarboxylic acid were synthesized by a sonochemical method. The new nano-structures were characterized by scanning electron microscopy, X-ray powder diffraction, IR spectroscopy and elemental analyses. Compounds 1 and 2 were structurally characterized by single crystal X-ray diffraction and consist of two-dimensional polymeric units. The thermal stability of compounds 1 and 2 were studied by thermal gravimetric and differential thermal analyses and compared. Pb(2)(SO(4))O and PbO nanoparticles were obtained by calcination of the nano-structures of compounds 1 and 2 at 600 degrees C, respectively.
Fard-Jahromi
Mohammad Jafar Soltanian
MJ
Faculty of Basic Science, Department of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Iran.
Morsali
Ali
A
D002621:Chemistry / Q000379:methods*; D007854:Lead / Q000737:chemistry*; D008024:Ligands; D008855:Microscopy, Electron, Scanning; D053758:Nanoparticles / Q000737:chemistry; D036103:Nanotechnology / Q000379:methods*; D010087:Oxides / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry; D011208:Powders; D012997:Solvents / Q000737:chemistry; D013455:Sulfur / Q000737:chemistry*; D013696:Temperature; D014465:Ultrasonics; D014961:X-Ray Diffraction
D008024:Ligands; D010087:Oxides; D011108:Polymers; D011208:Powders; D012997:Solvents; D007854:Lead; C047365:lead oxide; D013455:Sulfur; D010100:Oxygen