Superoxide dismutase activity of corrole metal complexes.
The first report regarding SOD activity of metallocorroles, investigated via the combination of the cytochrome C assay, pulse radiolysis, and electrochemistry, is used for identifying the main criteria needed for achieving good performance, as well as for elucidating mechanistic aspects of their action.
Eckshtain
Meital
M
Schulich Faculty of Chemistry, Technion-Israel Institute of Technology, Haifa, 32000, Israel.
Zilbermann
Israel
I
Mahammed
Atif
A
Saltsman
Irena
I
Okun
Zoya
Z
Maimon
Eric
E
Cohen
Haim
H
Meyerstein
Dan
D
Gross
Zeev
Z
D045304:Cytochromes c / Q000378:metabolism; D008670:Metals / Q000737:chemistry*; D010084:Oxidation-Reduction; D011166:Porphyrins / Q000737:chemistry*; D013451:Sulfonic Acids / Q000737:chemistry; D013482:Superoxide Dismutase / Q000737:chemistry / Q000378:metabolism*
D008670:Metals; D011166:Porphyrins; D013451:Sulfonic Acids; C431863:corrole; D045304:Cytochromes c; D013482:Superoxide Dismutase