First hexanuclear copper(II) pyrophosphate through hydrolysis of phosphodiester with a dicopper complex.
Facile hydrolysis of a phosphodiester promoted by a dicopper bis(mu-hydroxo) complex containing a new biphenyl appended N-bidentate ligand led to the isolation of the first example of hexameric copper pyrophosphate through 'in situ self assembly'.
Sabiah
Shahulhameed
S
Department of Chemistry, Indian Institute of Technology, Madras, India. sabiahs@gmail.com
Varghese
Babu
B
Murthy
Narasimha N
NN
D003300:Copper / Q000737:chemistry*; D011756:Diphosphates / Q000737:chemistry*; D006868:Hydrolysis; D008024:Ligands; D008968:Molecular Conformation
D011756:Diphosphates; D008024:Ligands; D003300:Copper