Domino palladium-catalyzed Heck-intermolecular direct arylation reactions.
A domino palladium-catalyzed Heck-intermolecular direct arylation reaction has been developed, giving access to a variety of dihydrobenzofurans, indolines, and oxindoles. A variety of sulfur-containing heterocycles such as thiazoles, thiophenes, and benzothiophene can be employed as the direct arylation coupling partner in yields up to 99%.
René
Olivier
O
Centre for Catalysis Research and Innovation, Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, ON K1N 6N5, Canada.
Lapointe
David
D
Fagnou
Keith
K
D002384:Catalysis; D006571:Heterocyclic Compounds / Q000737:chemistry; D007202:Indicators and Reagents / Q000737:chemistry; D007700:Kinetics; D009942:Organometallic Compounds / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*
D006571:Heterocyclic Compounds; D007202:Indicators and Reagents; D009942:Organometallic Compounds; D010165:Palladium