Catalytic membrane-installed microchannel reactors for one-second allylic arylation.
A variety of catalytic membranes of palladium-complexes with linear polymer ligands were prepared inside a microchannel reactor via coordinative and ionic molecular convolution to provide catalytic membrane-installed microdevices, which were applied to the instantaneous allylic arylation reaction of allylic esters and aryl boron reagents under microflow conditions to afford the corresponding coupling products within 1 second of residence time.
Yamada
Yoichi M A
YM
RIKEN, Hirosawa, Wako, Saitama 351-0198, Japan.
Watanabe
Toshihiro
T
Torii
Kaoru
K
Uozumi
Yasuhiro
Y