Trapping reactive metal-carbene complexes by a bis-pocket porphyrin: X-ray crystal structures of Ru=CHCO(2)Et and trans-[Ru(CHR)(CO)] species and highly selective carbenoid transfer reactions.
Deng
Qing-Hai
QH
Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, The Chinese Academy of Sciences, 354 Feng Lin Road, Shanghai 200032, China.
Chen
Jian
J
Huang
Jie-Sheng
JS
Chui
Stephen Sin-Yin
SS
Zhu
Nianyong
N
Li
Guang-Yu
GY
Che
Chi-Ming
CM
D018360:Crystallography, X-Ray; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008968:Molecular Conformation; D015394:Molecular Structure; D011166:Porphyrins / Q000138:chemical synthesis* / Q000737:chemistry; D012428:Ruthenium / Q000737:chemistry*; D013237:Stereoisomerism
D011166:Porphyrins; C030011:carbene; D012428:Ruthenium; D008697:Methane