Ruthenium-catalyzed selective N ,N-diallylation- and N ,N ,O-triallylation of free amino acids.
Selective N ,N-diallylation and N ,N, O-triallylation of free amino acids in the presence of catalytic amounts of RuCp*(MeCN)(3)PF(6) is reported. The crucial influence of the solvent makes these allylation reactions selectively possible.
Sundararaju
Basker
B
UMR6226 CNRS-Université de Rennes, Sciences chimiques de Rennes, Catalyse et Organométalliques, Campus de Beaulieu, 35042, Rennes Cedex, France.
Achard
Mathieu
M
Sharma
Gangavaram V M
GV
Bruneau
Christian
C
D000498:Allyl Compounds / Q000737:chemistry*; D000596:Amino Acids / Q000737:chemistry*; D002384:Catalysis; D009584:Nitrogen / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D013379:Substrate Specificity; D013696:Temperature
D000498:Allyl Compounds; D000596:Amino Acids; D012428:Ruthenium; D009584:Nitrogen; D010100:Oxygen