Enhanced sensitivity for the detection of trace gases using multiple line integrated absorption spectroscopy.
We describe a technique that enhances the sensitivity of a spectrometer for trace gas detection employing an external cavity continuously tunable CW quantum cascade laser and integrating the absorption spectra across multiple lines of the species. We demonstrate the power of this method by continuously recording the absorption spectra of NO2 across the R branch from 1628.8 to 1634.5 cm(-1). By integrating the resulting spectra, the detection sensitivity of NO2 is improved by a factor of 15 compared to the sensitivity achieved using single line laser absorption spectroscopy with the same apparatus. This procedure offers much shorter data acquisition times for the real-time monitoring of trace gas species compared to adding repeated scans of the spectra to improve the signal-to-noise ratio.
Karpf
Andreas
A
Department of Physics, Adelphi University, Garden City, New York 11530, USA.
Rao
Gottipaty N
GN
D000465:Algorithms; D008832:Microchemistry / Q000379:methods*; D009569:Nitric Oxide / Q000032:analysis*; D012031:Refractometry / Q000379:methods*; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity; D013057:Spectrum Analysis / Q000379:methods*
D009569:Nitric Oxide