Red- and green-emitting iridium(III) complexes for a dual barometric and temperature-sensitive paint.
A new dual luminescent sensitive paint for barometric pressure and temperature (T) is presented. The green-emitting iridium(III) complex [Ir(ppy)(2)(carbac)] (ppy=2-phenylpyridine; carbac=1-(9H-carbazol-9-yl)-5,5-dimethylhexane-2,4-dione) was applied as a novel probe for T along with the red-emitting complex [Ir(btpy)(3)], (btpy=2-(benzo[b]thiophene-2-yl)pyridine) which functions as a barometric (in fact oxygen-sensitive) probe. Both iridium complexes were dissolved in different polymer materials to achieve optimal responses. The probe [Ir(ppy)(2)(carbac)] was dispersed in gas-blocking poly(acrylonitrile) microparticles in order to suppress any quenching of its luminescence by oxygen. The barometric probe [Ir(btpy)(3)], in turn, was incorporated in a cellulose acetate butyrate film which exhibits good permeability for oxygen. The effects of temperature on the response of the oxygen probe can be corrected by simultaneous optical determination of T, as the poly(acrylonitrile) microparticles containing the temperature indicator are incorporated into the film. The phosphorescent signals of the probes for T and barometric pressure, respectively, can be separated by optical filters due to the approximately 75 nm difference in their emission maxima. The dual sensor is applicable to luminescence lifetime imaging of T and barometric pressure. It is the first luminescent dual sensor material for barometric pressure/T based exclusively on the use of Ir(III) complexes in combination with luminescence lifetime imaging.
Fischer
Lorenz H
LH
Institute of Analytical Chemistry, Chemo- and Biosensors, University Regensburg, Universitätsstr. 93051 Regensburg, Germany.
Stich
Matthias I J
MI
Wolfbeis
Otto S
OS
Tian
Nan
N
Holder
Elisabeth
E
Schäferling
Michael
M
D004396:Coloring Agents / Q000737:chemistry*; D007495:Iridium / Q000737:chemistry*; D049449:Luminescence; D008958:Models, Molecular; D015394:Molecular Structure; D010150:Paint; D013696:Temperature
D004396:Coloring Agents; D007495:Iridium