Palladium-catalyzed preparation of silyl enolates from alpha,beta-unsaturated ketones or cyclopropyl ketones with hydrosilanes.
Alpha,beta-unsaturated ketones and cyclopropyl ketones undergo palladium-catalyzed hydrosilylation with hydrosilanes to yield (Z)-silyl enolates.
Sumida
Yuto
Y
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
Yorimitsu
Hideki
H
Oshima
Koichiro
K