Colloidal properties of aqueous fullerenes: isoelectric points and aggregation kinetics of C60 and C60 derivatives.
Aqueous colloidal suspensions of C60 (aqu/C60) and the C60 derivatives PCBM ([6,6]-phenyl C61-butyric acid methyl ester) and the corresponding butyl and octyl esters, PCBB and PCBO (aqu/PCB-R, where R is an alkyl group), were produced by stirring in double deionized water for 5 months. Kinetically stable fullerene aggregates were formed using this procedure that ranged in intensity-averaged hydrodynamic diameter (Dh) from 193 +/- 2 nm (95% C.L.) for aqu/C60 to 259 +/- 6 nm for aqu/PCBO. Measured zeta potentials (zeta) were < -50 mV, and the isoelectric points (p) were < 1.0 for all of the aqu/fullerenes. Time-resolved dynamic light scattering (TRDLS) was used to measure aqu/fullerene Dh change with time and as a function of background solution ionic strength. The critical coagulation concentration (CCC) values for the aqu/PCB-R fullerenes were significantly higher than that of aqu/C60, indicating that the phenyl alkyl ester moieties of the equ/PCB-R fullerenes were impeding the aggregation process.
Bouchard
Dermont
D
U.S. Environmental Protection Agency, National Exposure Research Laboratory, and National Research Council Research Associate, Athens, Georgia 30605, USA. bouchard.dermont@epa.gov
Ma
Xin
X
Isaacson
Carl
C
D004782:Environmental Health; D004785:Environmental Pollutants / Q000737:chemistry*; D037741:Fullerenes / Q000737:chemistry*; D007526:Isoelectric Point; D007700:Kinetics; D015394:Molecular Structure; D049329:Nanostructures / Q000737:chemistry*; D010316:Particle Size; D013535:Suspensions; D014867:Water / Q000737:chemistry
D004785:Environmental Pollutants; D037741:Fullerenes; D013535:Suspensions; D014867:Water; C069837:fullerene C60