CuI nanoparticles for C-N and C-O cross coupling of heterocyclic amines and phenols with chlorobenzenes.
Employing CuI nanoparticles as an efficient catalyst for the cross-coupling reactions of various N/O nucleophilic reagents with aryl chlorides could be successfully carried out under mild conditions in the absence of both the ligands and strong bases. A variety of products including N-arylimidazoles and aryl ethers were synthesized in good to excellent yields.
Sreedhar
B
B
Indian Institute of Chemical Technology, Hyderabad 500007, India. sreedharb@iict.res.in
Arundhathi
R
R
Reddy
P Linga
PL
Kantam
M Lakshmi
ML
D000588:Amines / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D002722:Chlorobenzenes / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D006571:Heterocyclic Compounds / Q000737:chemistry*; D007454:Iodides / Q000737:chemistry*; D053768:Metal Nanoparticles; D046529:Microscopy, Electron, Transmission; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D010636:Phenols / Q000737:chemistry*
D000588:Amines; D002722:Chlorobenzenes; D006571:Heterocyclic Compounds; D007454:Iodides; D010636:Phenols; D002244:Carbon; D003300:Copper; C073870:cuprous iodide; D009584:Nitrogen; D010100:Oxygen