Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2,2':6',2''-terpyridine.
Thermal activation of terpyridine in the presence of an unsaturated Ir(III) fragment stabilized by a hydrotris(pyrazolyl) borate ligand gives rise to mononuclear complex and binuclear , in which the polypyridine behaves, respectively, as a mono- or a bi-dentate N-heterocyclic carbene.
Paneque
Margarita
M
Instituto de Investigaciones Químicas, Departamento de Química Inorgánica, Consejo Superior de Investigaciones Científicas, Universidad de Sevilla, Avda. Américo Vespucio 49Isla de la Cartuja, Sevilla, 41092, Spain.
Poveda
Manuel L
ML
Vattier
Florencia
F
Alvarez
Eleuterio
E
Carmona
Ernesto
E