title: Inter- and intramolecular addition reactions of electron-deficient alkenes with alkyl radicals, generated by SET-photochemical decarboxylation of carboxylic acids, serve as a mild and efficient method for the preparation of gamma-amino acids and macrocyclic lactones.
abstract: Inter- and intramolecular additions of alkyl radicals, generated by SET photochemical decarboxylation reactions of free carboxylic acids, to electron-deficient alkenes take place under mild conditions as part of efficient routes for the formation of N-Boc gamma-amino acids and macrocyclic lactones.
authors.affiliation: Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, University of Fukui, 3-9-1 Bunkyo, Fukui 910-8507, Japan. yyoshimi@u-fukui.ac.jp
authors.forename: Yasuharu
authors.initials: Y
authors.lastname: Yoshimi
authors.forename: Miho
authors.initials: M
authors.lastname: Masuda
authors.forename: Tomoyuki
authors.initials: T
authors.lastname: Mizunashi
authors.forename: Keisuke
authors.initials: K
authors.lastname: Nishikawa
authors.forename: Kousuke
authors.initials: K
authors.lastname: Maeda
authors.forename: Nobumasa
authors.initials: N
authors.lastname: Koshida
authors.forename: Tatsuya
authors.initials: T
authors.lastname: Itou
authors.forename: Toshio
authors.initials: T
authors.lastname: Morita
authors.forename: Minoru
authors.initials: M
authors.lastname: Hatanaka
mesh_terms: D000473:Alkanes / Q000737:chemistry*; D000475:Alkenes / Q000737:chemistry*; D000596:Amino Acids / Q000737:chemistry*; D002264:Carboxylic Acids / Q000737:chemistry*; D004579:Electron Transport; D004583:Electrons; D007783:Lactones / Q000737:chemistry*; D047028:Macrocyclic Compounds / Q000737:chemistry; D055668:Photochemical Processes
chemical_list: D000473:Alkanes; D000475:Alkenes; D000596:Amino Acids; D002264:Carboxylic Acids; D007783:Lactones; D047028:Macrocyclic Compounds