Determination of the aerosol yield of isoprene in the presence of an organic seed with carbon isotope analysis.
We examined a new method to determine the aerosol yield of precursors of secondary organic aerosols in the presence of organic seed particles. To distinguish between the oxidation products of the compound in question and the organic seed, the compound was labeled with stable isotopes and aerosol samples were analyzed by isotope ratio mass spectrometry (IRMS). 13C labeled isoprene was obtained from isoprene emitting plants that were exposed to (13)CO2. The aerosol yield of isoprene was determined from the 13C/12C ratio measured in the aerosol. Measurements at organic aerosol mass concentrations as low as 10 microg m(-3) were performed. Three different methods of aerosolsampling procedureswere evaluated: impactor, filter, and electrostatic deposition. The excess-% 13C measured by the three sampling methods agreed well. The aerosol yield of isoprene derived from these measurements showed a strong dependence on further oxidation of first-generation products and is within the range of reported yield values (1-5%) obtained so far from pure isoprene experiments.
Dommen
Josef
J
Laboratory of Atmospheric Chemistry, Paul Scherrer Institut, 5232 Villigen PSI, Switzerland. josef.dommen@psi.ch
Hellén
Heidi
H
Saurer
Matthias
M
Jaeggi
Maya
M
Siegwolf
Rolf
R
Metzger
Axel
A
Duplissy
Jonathan
J
Fierz
Martin
M
Baltensperger
Urs
U
D000336:Aerosols; D001272:Atmosphere / Q000032:analysis*; D000081008:Bicyclic Monoterpenes; D002070:Butadienes / Q000032:analysis*; D002247:Carbon Isotopes; D004784:Environmental Monitoring / Q000379:methods*; D045782:Hemiterpenes / Q000032:analysis*; D008962:Models, Theoretical; D039821:Monoterpenes / Q000737:chemistry*; D010084:Oxidation-Reduction; D052638:Particulate Matter / Q000032:analysis*; D010420:Pentanes / Q000032:analysis*
D000336:Aerosols; D000081008:Bicyclic Monoterpenes; D002070:Butadienes; D002247:Carbon Isotopes; D045782:Hemiterpenes; D039821:Monoterpenes; D052638:Particulate Matter; D010420:Pentanes; C005059:isoprene; C005451:alpha-pinene