title: An unprecedented oxidative Wagner-Meerwein transposition.
abstract: An oxidative Wagner-Meerwein transposition involving different functionalities mediated by a hypervalent iodine reagent has been accomplished. The strategy fits within the concept of "aromatic ring umpolung" and allows rapid access to highly functionalized cores.
authors.affiliation: Laboratoire de Méthodologie et Synthèse de Produits Naturels, Université du Québec à Montréal, C.P. 8888, Succ. Centre-Ville, Montréal, H3C 3P8, Québec, Canada.
authors.forename: Kimiaka C
authors.initials: KC
authors.lastname: Guérard
authors.forename: Clément
authors.initials: C
authors.lastname: Chapelle
authors.forename: Marc-André
authors.initials: MA
authors.lastname: Giroux
authors.forename: Cyrille
authors.initials: C
authors.lastname: Sabot
authors.forename: Marc-André
authors.initials: MA
authors.lastname: Beaulieu
authors.forename: Nabil
authors.initials: N
authors.lastname: Achache
authors.forename: Sylvain
authors.initials: S
authors.lastname: Canesi
mesh_terms: D007202:Indicators and Reagents / Q000737:chemistry; D007455:Iodine / Q000737:chemistry; D010084:Oxidation-Reduction; D010636:Phenols / Q000737:chemistry*
chemical_list: D007202:Indicators and Reagents; D010636:Phenols; D007455:Iodine