title: Isolation and structures of sulfonium salts derived from thioethers: [{o-C(6)H(4)(CH(2)SMe)(2)}H][NbF(6)] and [{[9]aneS(3)}H][NbF(6)].
abstract: Two very unusual sulfonium salts, [{o-C(6)H(4)(CH(2)SMe)(2)}H][NbF(6)] and [{[9]aneS(3)}H][NbF(6)], obtained from reaction of the thioethers with NbF(5) in CH(2)Cl(2) solution, are reported and their structures described; the eight-coordinate tetrafluoro Nb(v) cation of the dithioether is obtained from the same reaction.
authors.affiliation: School of Chemistry, University of Southampton, Southampton, UKSO17 1BJ.
authors.forename: Marek
authors.initials: M
authors.lastname: Jura
authors.forename: William
authors.initials: W
authors.lastname: Levason
authors.forename: Gillian
authors.initials: G
authors.lastname: Reid
authors.forename: Michael
authors.initials: M
authors.lastname: Webster