Application of the BaTiO(3) beam-fanning optical limiter as an adaptive spatial filter for signal enhancement in pulsed infrared laser-excited photothermal spectroscopy.
A method for obtaining a high-contrast visible-light signal from infrared absorption in low-absorbance samples is described. This method is based on a beam-fanning optical limiter in photorefractive BaTiO(3). The resulting signal is not linear but does exhibit an enhanced signal-to-background ratio that is 4 to 6 orders of magnitude better than that of conventional infrared absorption spectrophotometry in the shot-noise limit. A simple model for the beam-fanning, optical-limiter-based, pulsed-laser-excited photothermal spectroscopy detector is found to describe the experimental data adequately. This technique using photothermal spectroscopy detection may have advantages for rapid signal analysis and for two-dimensional visible imaging of infrared absorption.
Bialkowski
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