Synthesis and characterization of a novel cationic chitosan-based flocculant with a high water-solubility for pulp mill wastewater treatment.
In this work, pulp mill wastewater was treated using a novel copolymer flocculant with a high water-solubility, which was synthesized through grafting (2-methacryloyloxyethyl) trimethyl ammonium chloride (DMC) onto chitosan initiated by potassium persulphate. The experimental results demonstrate that the two main problems associated with the utilization of chitosan as a flocculant, i.e., low molecular weight and low water-solubility, were concurrently sorted out. The physicochemical properties of this flocculant were characterized with Fourier-transform infrared spectroscopy, (1)H nuclear magnetic resonance spectroscopy, X-ray powder diffraction and field emission scanning electron microscopy. Reaction parameters influencing the grafting percentage, such as temperature, reaction time, initiator concentration and monomer concentration, were optimized using an orthogonal array design matrix. With an increase in grafting percentage, the water-solubility of the flocculant was improved, and it became thoroughly soluble in water when the grafting percentage reached 236.4% or higher. Its application for the treatment of pulp mill wastewater indicates that it had an excellent flocculation capacity and that its flocculation efficiency was much better than that of polyacrylamide. The optimal conditions for the flocculation treatment of pulp mill wastewater were also obtained.
Wang
Jian-Ping
JP
Department of Chemistry, University of Science & Technology of China, Hefei 230026, China.
Chen
Yong-Zhen
YZ
Yuan
Shi-Jie
SJ
Sheng
Guo-Ping
GP
Yu
Han-Qing
HQ
D048271:Chitosan / Q000031:analogs & derivatives* / Q000737:chemistry*; D002794:Choline / Q000031:analogs & derivatives / Q000737:chemistry; D005427:Flocculation / Q000187:drug effects; D007220:Industrial Waste / Q000032:analysis*; D007616:Kaolin / Q000737:chemistry; D007700:Kinetics; D009682:Magnetic Resonance Spectroscopy; D008689:Methacrylates / Q000737:chemistry; D010209:Paper; D017680:Potassium Compounds / Q000737:chemistry; D012995:Solubility; D013431:Sulfates / Q000737:chemistry; D014865:Waste Disposal, Fluid / Q000379:methods*; D014867:Water / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000737:chemistry
C545433:2-methacryloyloxyethyltriethylammonium; D007220:Industrial Waste; D008689:Methacrylates; D017680:Potassium Compounds; D013431:Sulfates; D014874:Water Pollutants, Chemical; D014867:Water; D007616:Kaolin; C009007:potassium persulfate; D048271:Chitosan; D002794:Choline