title: Fullerene/thiol-terminated molecules.
abstract: A series of fullerene-terminated oligo(phenylene ethynylene) (OPEs) have been synthesized for potential use in electronic or optoelectronic device monolayers. Electronic properties such as the energy levels and the distribution of HOMOs and LUMOs of fullerene-terminated OPEs have been calculated using the ab initio method at the B3LYP/6-31G(d) level. The calculations have revealed the concentration of frontier orbitals on the fullerene cage and a narrow distribution of HOMO-LUMO energy gaps. Ultraviolet photoelectron spectroscopy and inverse photoemission spectroscopy studies have been performed to further examine the electronic properties of the fullerene-terminated OPEs on gold surfaces. The obtained broad photoelectron spectra suggest that there are strong intermolecular interactions in the fullerene self-assembled monolayers, and the small bandgap (approximately 1.5 eV), determined by the photoelectron spectroscopy, indicates the unique nature of the fullerene-terminated OPEs in which the C(60) moiety can be connected to the Au surface through the conjugated OPE backbone.
authors.affiliation: Department of Chemistry, Smalley Institute for Nanoscale Science and Technology, Rice University, MS-222, 6100 Main Street, Houston, Texas 77005, USA.
authors.forename: Yasuhiro
authors.initials: Y
authors.lastname: Shirai
authors.forename: Jason M
authors.initials: JM
authors.lastname: Guerrero
authors.forename: Takashi
authors.initials: T
authors.lastname: Sasaki
authors.forename: Tao
authors.initials: T
authors.lastname: He
authors.forename: Huanjun
authors.initials: H
authors.lastname: Ding
authors.forename: Guillaume
authors.initials: G
authors.lastname: Vives
authors.forename: Byung-Chan
authors.initials: BC
authors.lastname: Yu
authors.forename: Long
authors.initials: L
authors.lastname: Cheng
authors.forename: Austen K
authors.initials: AK
authors.lastname: Flatt
authors.forename: Priscilla G
authors.initials: PG
authors.lastname: Taylor
authors.forename: Yongli
authors.initials: Y
authors.lastname: Gao
authors.forename: James M
authors.initials: JM
authors.lastname: Tour