title: Nucleation mechanism of GaN nanowires grown on (111) Si by molecular beam epitaxy.
abstract: We have performed a real-time in situ x-ray scattering study of the nucleation of GaN nanowires grown by plasma-assisted molecular beam epitaxy on AlN(0001)/Si(111). The intensity variation of the GaN diffraction peak as a function of time was found to exhibit three different regimes: (i) the deposition of a wetting layer, which is followed by (ii) a supralinear regime assigned to nucleation of almost fully relaxed GaN nanowires, eventually leading to (iii) a steady-state growth regime. Based on scanning electron microscopy and electron microscopy analysis, it is proposed that the granular character of the thin AlN buffer layer may account for the easy plastic relaxation of GaN, establishing that three-dimensional islanding and plastic strain relaxation of GaN are two necessary conditions for nanowire growth.
authors.affiliation: CEA-CNRS Group, Nanophysique et Semiconducteurs, Institut Néel/CNRS-University J Fourier and CEA Grenoble, INAC, SP2M, 17 rue des Martyrs, F-38054 Grenoble, France.
authors.forename: O
authors.initials: O
authors.lastname: Landré
authors.forename: C
authors.initials: C
authors.lastname: Bougerol
authors.forename: H
authors.initials: H
authors.lastname: Renevier
authors.forename: B
authors.initials: B
authors.lastname: Daudin
mesh_terms: D005708:Gallium / Q000737:chemistry*; D017348:Microscopy, Electron, Scanning Transmission; D036103:Nanotechnology / Q000379:methods*; D053770:Nanowires / Q000737:chemistry* / Q000648:ultrastructure*
chemical_list: D005708:Gallium; C027235:gallium nitrate