A direct white-light-emitting metal-organic framework with tunable yellow-to-white photoluminescence by variation of excitation light.
A direct white-light metal-organic framework (MOF), [AgL](n) x nH(2)O (1, L = 4-cyanobenzoate), obtained by the reaction of deprotonated 4-cyanobenzoic acid and AgNO(3) in water, was found to exhibit tunable yellow-to-white photoluminescence by variation of excitation light. Interestingly, the close pure white emission of 1 has CIE-1931 chromaticity coordinates of (0.33, 0.34) when excited by 349-nm UV light, which is compatible to the light output of the deep UV LED.
Wang
Ming-Sheng
MS
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, PR China.
Guo
Sheng-Ping
SP
Li
Yan
Y
Cai
Li-Zhen
LZ
Zou
Jian-Ping
JP
Xu
Gang
G
Zhou
Wei-Wei
WW
Zheng
Fa-Kun
FK
Guo
Guo-Cong
GC