Defect structures in nematic liquid crystals around charged particles.
We numerically study the orientation deformations in nematic liquid crystals around charged particles. We set up a Ginzburg-Landau theory with inhomogeneous electric field. If the dielectric anisotropy epsilon 1 is positive, Saturn-ring defects are formed around the particles. For epsilon 1< 0 , novel "ansa" defects appear, which are disclination lines with their ends on the particle surface. We find unique defect structures around two charged particles. To lower the free energy, oppositely charged particle pairs tend to be aligned in the parallel direction for epsilon 1> 0 and in the perpendicular plane for epsilon 1< 0 with respect to the background director. For identically charged pairs the preferred directions for epsilon 1> 0 and epsilon 1< 0 are exchanged. We also examine competition between the charge-induced anchoring and the short-range anchoring. If the short-range anchoring is sufficiently strong, it can be effective in the vicinity of the surface, while the director orientation is governed by the long-range electrostatic interaction far from the surface.
Tojo
K
K
Department of Physics, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan.
Furukawa
A
A
Araki
T
T
Onuki
A
A
D016880:Anisotropy; D004574:Electromagnetic Fields; D050866:Liquid Crystals / Q000737:chemistry*; D008956:Models, Chemical; D010316:Particle Size; D055672:Static Electricity; D013499:Surface Properties; D013816:Thermodynamics