Unexpected formation of a cyclopentadienylruthenium alkoxycarbonyl complex with a coordinated C=C bond.
Reaction of (eta(5)-Ph(5)C(5))Ru(CO)(2)(Ot-Bu) with 5-hexen-2-ol produces two diastereomers of an alkoxycarbonyl complex having the double bond coordinated to ruthenium. The complexes were characterized by (1)H and (13)C NMR spectroscopy and in situ FT-IR measurements. The (13)C NMR carbonyl peaks of the complexes appear at 203.48, 203.55, and 204.0 ppm in a ratio of 1:1:2. IR peaks for CO and acyl were detected at 1982 (CO) and 1644 (acyl) cm(-1).
Aberg
Jenny B
JB
Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden.
Warner
Madeleine C
MC
Bäckvall
Jan-E
JE
D002244:Carbon / Q000737:chemistry; D002384:Catalysis; D005656:Fungal Proteins; D008049:Lipase / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D009942:Organometallic Compounds / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared; D013237:Stereoisomerism
D005656:Fungal Proteins; D009942:Organometallic Compounds; D002244:Carbon; D012428:Ruthenium; D008049:Lipase; C431349:lipase B, Candida antarctica