Oligosilylated group 4 titanocenes in the oxidation state +3.
Reactions of oligosilylanions with Cp2TiCl2 led to the formation of ate-complexes of silylated titanocenes, which form upon silylation of the intermediate K[Cp2TiCl2].18-crown-6.
Zirngast
Michaela
M
Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 16, 8010 Graz, Austria.
Flörke
Ulrich
U
Baumgartner
Judith
J
Marschner
Christoph
C