Analysis of hydrocarbon contamination with membrane-assisted solvent extraction: comparison of agitation and sonication methods.
Membrane-assisted solvent extraction (MASE) coupled to large volume injection was applied to the determination of (gasoline-type) hydrocarbon contamination in water samples. Hexane was used as acceptor phase. 50 microL extract was injected in the programmed temperature vaporizer injector using combined split-splitless evaporation. The extraction conditions were optimized both for MASE with agitation and for MASE with sonication. In the course of optimization the effect of extraction time, extraction temperature, agitation speed, solvent volume, pH, ionic strength and the addition of methanol were tested. Over 75% recovery was accomplished in the range of diesel oil hydrocarbons (n-C(9)-n-C(24)). The developed method was validated. Linearity, accuracy and precision were tested. The method showed excellent linearity between 1 and 1000 microgL(-1) for n-alkanes and between 0.05 and 50 mgL(-1) for gasoline. The method was tested with comprehensive GCxGC as well and found to be non-discriminative to all major compounds of diesel oil.
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Eötvös Loránd University, Joint Research and Training Laboratory (EKOL), H-1117 Budapest, Pázmány Péter sétány 1/A, Hungary. zoltan.szekeres@gmail.com
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D000473:Alkanes / Q000032:analysis*; D005591:Chemical Fractionation / Q000379:methods*; D005410:Flame Ionization; D005742:Gasoline / Q000032:analysis*; D006358:Hot Temperature; D006863:Hydrogen-Ion Concentration; D008567:Membranes, Artificial; D009994:Osmolar Concentration; D010578:Petroleum / Q000032:analysis; D015203:Reproducibility of Results; D012997:Solvents; D013010:Sonication; D013997:Time Factors; D014867:Water / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis*
D000473:Alkanes; D005742:Gasoline; D008567:Membranes, Artificial; D010578:Petroleum; D012997:Solvents; D014874:Water Pollutants, Chemical; D014867:Water