Metal-organic framework assembled from T-shaped and octahedral nodes: a mixed-linker strategy to create a rare anatase TiO2 topology.
A novel porphyrin paddlewheel framework (PPF-25), assembled from a zinc paddlewheel cluster and mixed linkers (4,4'-bipyridyl; zinc 5,15-di(4-carboxyphenyl)-10,20-diphenylporphyrin), has been synthesized and structurally characterized. T-shaped organometallic nodes are generated, and the resulting structure is closely related to anatase, a polymorph of TiO(2).
Department of Chemistry, University of Nebraska-Lincoln, Lincoln, Nebraska 68588-0304, USA.
Jennifer M
JM
Verduzco
Haemi
H
Chung
Chunhua
C
Hu
Wonyoung
W
Choe