Activation of the C-N bond in nitromethane by palladium alpha-diimine complexes.
The reaction of glyoxal-derived alpha-diimines with palladium acetates in nitromethane leads to cleavage of the C-N bond in nitromethane, to give palladium nitro complexes in which the alpha-diimine ligand has been methylated.
Golisz
Suzanne R
SR
Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, USA.
Hazari
Nilay
N
Labinger
Jay A
JA
Bercaw
John E
JE