A Diastereoselective Intramolecular Pauson-Khand Approach to the Construction of the BC Ring System in Tuberostemoninol.
Herein we describe an asymmetric approach to the synthesis of a BC-ring synthon in tuberostemoninol via an intramolecular Pauson-Khand reaction stereocontrolled by a commercially available chiral glycinate.
Departement of Chemsitry, Colorado State University, Fort Collins, CO 80523-1872.
Xiangna
X
Jia
Robert M
RM
Williams