Infrared multiphoton electron detachment spectroscopy of C76(2-).
In this letter, we report the first infrared spectrum of C(76)(2-). This multiply charged anion has been studied in an electrodynamic ion trap held at room temperature using tunable infrared radiation from a free-electron laser. Resonant vibrational excitation is found to cause electron detachment and the resulting singly negatively charged as well as the remaining doubly charged parent ion are monitored as a function of IR wavelength in an experimental scheme that we term infrared multiphoton electron detachment spectroscopy. The obtained IR spectra are contrasted to computed vibrational spectra using density functional theory. The dianionic molecule retains its overall symmetry (i.e., D(2) point group) with a (1)A(1) ground state with respect to the neutral fullerene. Spectral shifts of characteristic tangential modes relative to the neutral cage are shown to originate from the excess charge density.
Institut für Nanotechnologie, Karlsruhe Institute of Technology (KIT), 76021 Karlsruhe, Germany. oliver.hampe@int.fzk.de
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Hampe
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Neumaier
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Boese
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Lemaire
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Niedner-Schatteburg
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Kappes