Gas sensing properties of single conducting polymer nanowires and the effect of temperature.
We measured the electronic properties and gas sensing responses of template-grown poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) (PEDOT/PSS)-based nanowires. The nanowires had a 'striped' structure (gold-PEDOT/PSS-gold), and were typically 8 microm long (1 microm-6 microm-1 microm for the sections, respectively) and 220 nm in diameter. Single-nanowire devices were contacted with pre-fabricated gold electrodes using dielectrophoretic assembly. A polymer conductivity of 11.5 +/- 0.7 S cm(-1) and a contact resistance of 27.6 +/- 4 kOmega were inferred from measurements on nanowires of varying length and diameter. The nanowire sensors detected a variety of odors, with rapid response and recovery (seconds). The response (DeltaR/R) varied as a power law with analyte concentration. The power law exponent was found to increase with the molecular weight of the analyte and as a function of temperature. The detection limits are set by noise intrinsic to the device and are at the ppm level even for very volatile analytes.
Department of Electrical Engineering, University of Pennsylvania, Philadelphia, PA 19104, USA.
Yaping
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Dan
Yanyan
Y
Cao
Tom E
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Mallouk
Stephane
S
Evoy
A T Charlie
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Johnson