Formation of a 3D porous ferric arsenate containing novel cubane-like Fe4F4 building units.
The purely inorganic microporous compound [H(3)O][Fe(4)F(4)(AsO(4))(3)] x 3 H(2)O (1), which contains novel cubane-like Fe(4)F(4) cages, exhibiting a 3D configuration with channels of dimensions 8 A x 8 A running along the [001], [010], and [100] directions, presents antiferromagnetic interactions.
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China.
Zhihui
Z
Yi
Zhuihui
Z
Yi
Chao
C
Yang
Wujiong
W
Xia
Xianzhu
X
Xu
Xiao
X
Zhang