Intermediate spin ground state of an isosceles triangular [Mn(II)(3)] complex.
[{Mn(tmeda)}(3){GeSe(3)(OMe)}(2)] (), synthesized by the reaction of [K(4)(H(2)O)(3)][Ge(2)Se(6)] with MnCl(2).4H(2)O in MeOH-tmeda (tmeda = N,N,N',N'-tetramethyl-1,2-diaminoethane), exhibits an isosceles triangular arrangement of Mn(2+) ions that are antiferromagnetically coupled with an S = 3/2 ground state.
Fachbereich Chemie der Philipps-Universität Marburg, Wissenschaftliches Zentrum für Materialwissenschaften (WZMW), Hans-Meerwein-Strasse, D-35043 Marburg, Germany.
Sima
S
Haddadpour
Heiko
H
Niedermeyer
Rodolphe
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Clérac
Stefanie
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Dehnen