Mini-review: green sustainable processes using supercritical fluid carbon dioxide.
Environmentally benign carbon dioxide offers significant potential in its supercritical fluid phase to replace current reliance on a range of hazardous, relatively expensive and environmentally damaging organic solvents that are used on an extensive global basis. The unique combination of the physical properties of supercritical fluids are being exploited and further researched to continue the development and establishment of high efficiency, compact plant to provide energy and water efficient manufacturing processes. This mini-review is focused on the use and potential applications of supercritical fluid carbon dioxide for a selected range of key and emerging industrial processes as a sustainable alternative to totally eliminate or greatly reduce the requirement of numerous conventional organic solvents. Examples of the industries include: chemical extraction and purification, synthetic chemical reactions including polymerization and inorganic catalytic processes. Biochemical reactions involving enzymes, particle size engineering, textile dyeing and advanced material manufacture provide further illustrations of vital industrial activities where supercritical fluid technology processes are being implemented or developed. Some aspects relating to the economics of sustainable supercritical fluid carbon dioxide processes are also considered.
Ramsey
Edward
E
University of Science and Technology Liaoning, Anshan 114051, China. syphir2008@gmail.com
Sun
Qiubai
Q
Zhang
Zhiqiang
Z
Zhang
Chongmin
C
Gou
Wei
W
D002245:Carbon Dioxide / Q000737:chemistry*; D002384:Catalysis; D025924:Chromatography, Supercritical Fluid / Q000295:instrumentation / Q000379:methods*; D004396:Coloring Agents / Q000737:chemistry; D055772:Green Chemistry Technology / Q000295:instrumentation / Q000379:methods; D006801:Humans; D007220:Industrial Waste; D012997:Solvents / Q000737:chemistry / Q000633:toxicity; D013783:Textile Industry / Q000379:methods
D004396:Coloring Agents; D007220:Industrial Waste; D012997:Solvents; D002245:Carbon Dioxide