Direct measurement of sub-Debye-length attraction between oppositely charged surfaces.
Using a surface force balance with fast video analysis, we have measured directly the attractive forces between oppositely charged solid surfaces (charge densities sigma(+), sigma(-)) across water over the entire range of interaction, in particular, at surface separations D below the Debye screening length lambda(S). At very low salt concentration we find a long-ranged attraction between the surfaces (onset ca. 100 nm), whose variation at D<lambda(S) agrees well with predictions based on solving the Poisson-Boltzmann theory, when due account is taken of the independently-determined surface charge asymmetry (sigma(+) not equal to |sigma(-)|).
Kampf
Nir
N
Department of Materials and Interfaces, Weizmann Institute of Science, Rehovot 76100, Israel.
Ben-Yaakov
Dan
D
Andelman
David
D
Safran
S A
SA
Klein
Jacob
J