Palladium nanoclusters in microcapsule membranes: from synthetic shells to synthetic cells.
We show that polyelectrolyte shells may be perfect hosts and microreactors for catalysis. Using a layer-by-layer self-assembly process to form hollow polyelectrolyte capsules, we show that individual layers can be replaced by palladium and gold nanoclusters forming robust cell-type microcapsules. Testing the catalytic activity of those embedded nanoclusters using the Sonogashira cross-coupling reaction, we show that simple self-assembled polyelectrolyte shells are ideal as carrier of at least one expensive catalyst, and possibly several, opening the road to new cascade reactions.
Turkenburg
Daan H
DH
van t Hoff Institute for Molecular Sciences, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands.
Antipov
Alexei A
AA
Thathagar
Mehul B
MB
Rothenberg
Gadi
G
Sukhorukov
Gleb B
GB
Eiser
Erika
E
D002384:Catalysis; D008567:Membranes, Artificial; D053769:Nanocapsules / Q000737:chemistry* / Q000648:ultrastructure; D010165:Palladium / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry
D008567:Membranes, Artificial; D053769:Nanocapsules; D011108:Polymers; D010165:Palladium