Hemiacetals in dynamic covalent chemistry: formation, exchange, selection, and modulation processes.
A reversible formation of hemiacetals represents a useful tool in covalent dynamic chemistry. Heterocyclic hemiacetals can be stabilized effectively via either protonation or metal cation coordination. The resulting hemiacetal systems are highly dynamic, show fast response, and display component selection.
Drahonovský
Dusan
D
ISIS, Université de Strasbourg, 67083 Strasbourg, France.
Lehn
Jean-Marie
JM