Oxidative addition reactions of element-hydrogen bonds with different polarities to a gallium(I) compound.
The gallium(I) derivative [Ga({N(dipp)CMe}(2)CH)] (1; dipp = 2,6-diisopropylphenyl) undergoes facile oxidative addition reactions with various element-hydrogen bonds including N-H, P-H, O-H, Sn-H, and H-H bonds. This was demonstrated by its reaction with triphenyltin hydride, ethanol, water, diethylamine, diphenylphosphane, and dihydrogen. All products were characterized by means of single-crystal X-ray structure determination, NMR spectroscopy, IR spectroscopy, and mass spectrometry.
Universität Heidelberg, Anorganisch-Chemisches Institut, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany.
Annekathrin
A
Seifert
Dominik
D
Scheid
Gerald
G
Linti
Thomas
T
Zessin