Nitric oxide chemisorption in a postsynthetically modified metal-organic framework.
Postsynthetic metal-organic framework (MOF) derivatization introduces accessible secondary amine functionalities that react with nitric oxide (NO) to form N-diazenium diolates. This is in contrast to the parent MOF that binds NO essentially irreversibly at open metal coordination sites.
Ingleson
Michael J
MJ
Department of Chemistry, University of Liverpool, Liverpool L69 7ZD, UK.
Heck
Romain
R
Gould
Jamie A
JA
Rosseinsky
Matthew J
MJ