Preparation and synthetic application of partially protected brassinosteroids.
Preparation of partially protected brassinosteroids is achieved through the reaction of the source material (24-epicastasterone and 24-epibrassinolide) with diol-specific reagents (2,2-dimethoxypropane and methylboronic acid). The obtained products were shown to be useful synthetic intermediates for further preparation of minor representatives of this class of natural phytohormones (such as 3,24-diepicastasterone and 3-dehydro-24-epibrassinolide).
Khripach
Vladimir A
VA
Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus, Kuprevich str., 5/2, 220141 Minsk, Belarus. khripach@iboch.bas-net.by
Zhabinskii
Vladimir N
VN
Zhiburtovich
Yuliya Y
YY
Ivanova
Galina V
GV
Konstantinova
Olga V
OV
Tsavlovskii
Dmitrii V
DV
Lorenz
Sybille
S
Schneider
Bernd
B
D060406:Brassinosteroids; D002777:Cholestanols / Q000138:chemical synthesis* / Q000737:chemistry; D008956:Models, Chemical; D015394:Molecular Structure; D010937:Plant Growth Regulators / Q000138:chemical synthesis* / Q000737:chemistry; D020005:Propanols / Q000737:chemistry; D021241:Spectrometry, Mass, Electrospray Ionization; D013260:Steroids, Heterocyclic / Q000138:chemical synthesis* / Q000737:chemistry
D060406:Brassinosteroids; D002777:Cholestanols; D010937:Plant Growth Regulators; D020005:Propanols; D013260:Steroids, Heterocyclic; C017240:2,2-dimethoxypropane; C023623:brassinolide