Synthesis, structure and reactivity of disila- and distanna ansa half-sandwich complexes of molybdenum and tungsten.
We present the synthesis and characterization of disila- and distanna ansa half-sandwich complexes of Group 6 transition metals. These compounds exhibit high ring strain within the ansa bridge, which is the key factor for the insertion of elemental chalcogens.
Bera
Holger
H
Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany.
Braunschweig
Holger
H
Dörfler
Rainer
R
Hammond
Kai
K
Oechsner
Andreas
A
Radacki
Krzysztof
K
Uttinger
Katharina
K