Spectroelectrochemistry at ultrahigh vacuum: in situ monitoring of electrochemically generated species by X-ray photoelectron spectroscopy.
The electrochemical reduction of Fe(III) to Fe(II) in the ionic liquid (IL) mixture of 1-ethyl-3-methylimidazolium ethylsulfate, [C(2)C(1)Im][EtOSO(3)], and 1-butyl-3-methylimidazolium tetrachloroferrate (III), [C(4)C(1)Im][Fe(III)Cl(4)], was monitored in situ by X-ray photoelectron spectroscopy (XPS).
School of Chemistry, The University of Nottingham, University Park, Nottingham, UK.
Alasdair W
AW
Taylor
Fulian
F
Qiu
Ignacio J
IJ
Villar-Garcia
Peter
P
Licence