Polyoxometalate-based {Mn(III)2}-Schiff base composite materials exhibiting single-molecule magnet behaviour.
The introduction of [Mn(salen)(H2O)]2(ClO4)2.H2O ({Mn(III)2}) into the polyoxometalate (POM) systems Na3[XMo6(OH)6O18] (X = Al and Cr) led to the isolation of new {Mn(III)2}-POM composite materials with single-molecule magnetic behaviour.
Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Renmin Street No.5268, Changchun, Jilin, 130024, P. R. China.
Qiong
Q
Wu
Yang-Guang
YG
Li
Yong-Hui
YH
Wang
Rodolphe
R
Clérac
Ying
Y
Lu
En-Bo
EB
Wang