Synthesis of novel asymmetric zinc (II) phthalocyanines bearing octadecyloxyl and glucosyl groups.
A novel asymmetric zinc (II) phthalocyanine substituted by one lipophilic octadecyloxyl group and three hydrophilic glucosyl groups was synthesized. Using Q-TOF MS, the major byproducts formed during the deprotection processes were identified. An improved procedure was worked out to convert these byproducts to the desired product in quantitative yield.
Zhang
Pei
P
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China. spaceswimer@hotmail.com
Zhang
Shufen
S
Han
Gang
G
D005947:Glucose / Q000737:chemistry*; D007211:Indoles / Q000737:chemistry*; D054833:Isoindoles; D013058:Mass Spectrometry; D015032:Zinc / Q000737:chemistry*
D007211:Indoles; D054833:Isoindoles; D005947:Glucose; D015032:Zinc; C013647:phthalocyanine