[Deactivation by SO2 of transition metal oxides modified low-temperature SCR catalyst for NOx reduction with NH3].
MnOx-CeOx/ACF catalyst was prepared by impregnation method, which exhibited high activity for low-temperature selective catalytic reduction of NOx over the temperature range 110-230 degrees C. Experiments results indicated that the catalyst yielded 80% NO conversion at 150 degrees C and 90% at 230 degrees C. The Oxides of Fe,Cu and V were added to the catalysts based on MnOx-CeOx/ACF. The additions of these transition metal oxides had a negative effect on the activity of the catalysts. Compared with MnOx-CeOx/ACF and Cu and V modified catalysts, NO conversion for Fe-MnOx-CeOx/ACF catalyst leveled off at nearly 75% in the first 6 h in the presence of SO2. Two mechanisms of catalyst deactivation by SO2 were discovered by the methods of X-ray photoelectron spectrum (XPS) and Fourier transform infrared spectra (FTIR), indicating that the catalysts were covered by ammonium sulfates and the metal oxides, acting as active components, were also sulfated by SO2 to form metal sulfates.
Shen
Bo-xiong
BX
College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China. shenbx@nankai.edu.cn
Liu
Ting
T
Yang
Ting-ting
TT
Xiong
Li-xian
LX
Wang
Jing
J
D000641:Ammonia / Q000737:chemistry*; D002384:Catalysis; D002563:Cerium / Q000737:chemistry; D003080:Cold Temperature; D017895:Manganese Compounds / Q000737:chemistry*; D009569:Nitric Oxide / Q000737:chemistry*; D010084:Oxidation-Reduction; D010087:Oxides / Q000737:chemistry*; D013458:Sulfur Dioxide / Q000737:chemistry*
D017895:Manganese Compounds; D010087:Oxides; D013458:Sulfur Dioxide; D002563:Cerium; D009569:Nitric Oxide; C030583:ceric oxide; C027424:manganese oxide; D000641:Ammonia