Surface-mediated visible-light photo-oxidation on pure TiO(2)(001).
We used STM to observe visible light photo-oxidation reactions of formic acid on the ordered lattice-work structure of a TiO(2)(001) surface for the first time. The nanostructured surface makes the band gap significantly smaller than 3.0 eV only at the surface layer, and the surface state of the crystal enables a visible light response.
Ariga
Hiroko
H
Department of Chemistry, Graduate School of Science, The University of Tokyo, Hongo, Tokyo 113-0033, Japan.
Taniike
Toshiaki
T
Morikawa
Harumo
H
Tada
Mizuki
M
Min
Byoung Koun
BK
Watanabe
Kazuya
K
Matsumoto
Yoshiyasu
Y
Ikeda
Susumu
S
Saiki
Koichiro
K
Iwasawa
Yasuhiro
Y