Borane Complexes of the H(3)PO(2) P(III) Tautomer: Useful Phosphinate Equivalents.
The preparation and reactivity of novel (R(1)O)(R(2)O)P(BH(3))H [R(1), R(2) = Et, TIPS] synthons is investigated. The direct alkylation of these compounds with lithium hexamethyldisilazide (LiHMDS) and various electrophiles, provided new series of phosphonite-borane complexes, which can be converted into H-phosphinates and boranophosphonates.
Belabassi
Yamina
Y
Department of Chemistry, Box 298860, Texas Christian University, Fort Worth, Texas 76129, U.S.A.
Antczak
Monika I
MI
Tellez
Jennifer
J
Montchamp
Jean-Luc
JL