Synthesis, structure and reactivity of disila- and distanna ansa half-sandwich complexes of molybdenum and tungsten.
We present the synthesis and characterization of disila- and distanna ansa half-sandwich complexes of Group 6 transition metals. These compounds exhibit high ring strain within the ansa bridge, which is the key factor for the insertion of elemental chalcogens.
Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany.
Holger
H
Bera
Holger
H
Braunschweig
Rainer
R
Dörfler
Kai
K
Hammond
Andreas
A
Oechsner
Krzysztof
K
Radacki
Katharina
K
Uttinger