Facile chemical conversion synthesis and luminescence properties of uniform Ln3+ (Ln = Eu, Tb)-doped NaLuF4 nanowires and LuBO3 microdisks.
Uniform NaLuF(4) nanowires and LuBO(3) microdisks have been successfully prepared by a designed chemical conversion method. The lutetium precursor nanowires were first prepared through a simple hydrothermal process. Subsequently, uniform NaLuF(4) nanowires and LuBO(3) microdisks were synthesized at the expense of the precursor by a hydrothermal conversion process. The whole process was carried out in aqueous condition without any organic solvents, surfactant, or catalyst. The conversion processes from precursor to the final products have been investigated in detail. The as-obtained Eu(3+) and Tb(3+)-doped LuBO(3) microdisks and NaLuF(4) nanowires show strong characteristic red and green emissions under ultraviolet excitation or low-voltage electron beam excitation. Moreover, the luminescence colors of the Eu(3+) and Tb(3+) codoped LuBO(3) samples can be tuned from red, orange, yellow, and green-yellow to green by simply adjusting the relative doping concentrations of the activator ions under a single wavelength excitation, which might find potential applications in the fields such as light display systems and optoelectronic devices.
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR China.
Guang
G
Jia
Hongpeng
H
You
Yanhua
Y
Song
Junjiao
J
Jia
Yuhua
Y
Zheng
Lihui
L
Zhang
Kai
K
Liu
Hongjie
H
Zhang
D001895:Boron / Q000737:chemistry; D005063:Europium / Q000737:chemistry*; D005461:Fluorine / Q000737:chemistry; D008163:Luminescent Measurements; D008187:Lutetium / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D053770:Nanowires / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry; D013725:Terbium / Q000737:chemistry*
D013725:Terbium; D005461:Fluorine; D005063:Europium; D008187:Lutetium; D001895:Boron; D010100:Oxygen