Innovative methodology for comprehensive utilization of iron ore tailings: part 2: The residues after iron recovery from iron ore tailings to prepare cementitious material.
In order to comprehensive utilization of iron ore tailings, this experimental research was to investigate the possibility of using the residues after iron recovery from iron ore tailings as raw materials for the preparation of cementitious material, abbreviated as TSC, including analyses of its mechanical properties, physical properties and hydration products. The TSC1 was prepared by blending 30% the residues, 34% blast-furnace slag, 30% clinker and 6% gypsum. Meanwhile, the raw iron ore tailings (before iron recovery) with the same proportion of TSC1 were selected to compare the cementitious activity of raw tailings and the residues after magnetizing roasting, denoted by TSC0. The hydration products of them were mostly ettringite, calcium hydroxide and C-S-H gel, characterized by XRD, IR and SEM. It was found that ettringite and C-S-H gel were principally responsible for the strength development of TSC mortars with curing time. The results showed that the kaolinite of the tailings was decomposed completely after magnetizing roasting, which promoted the cementitious property of TSC1. Moreover, the mechanical properties of TSC1 are well comparable with those of 42.5 ordinary Portland cement according to Chinese GB175-2007 standard.
Department of Materials Science and Engineering, State Key Lab of New Ceramics and Fine Processing, Tsinghua University, Beijing 100084, China. chao-li07@mails.tsinghua.edu.cn
Chao
C
Li
Henghu
H
Sun
Zhonglai
Z
Yi
Longtu
L
Li
D007501:Iron / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D013056:Spectrophotometry, Ultraviolet; D014961:X-Ray Diffraction
D007501:Iron