Nitric oxide chemisorption in a postsynthetically modified metal-organic framework.
Postsynthetic metal-organic framework (MOF) derivatization introduces accessible secondary amine functionalities that react with nitric oxide (NO) to form N-diazenium diolates. This is in contrast to the parent MOF that binds NO essentially irreversibly at open metal coordination sites.
Department of Chemistry, University of Liverpool, Liverpool L69 7ZD, UK.
Michael J
MJ
Ingleson
Romain
R
Heck
Jamie A
JA
Gould
Matthew J
MJ
Rosseinsky