title: Rearrangement of 2,5-bis(silylated)-N-Boc pyrroles into the corresponding 2,4-species.
abstract: The rearrangement of 2,5-bis(silylated)-N-Boc pyrroles in their 2,4-isomers is shown to proceed under mild acidic conditions. A reasonable mechanism, based on literature as well as experiments, is proposed to rationalize this transformation.
authors.affiliation: Laboratoire Charles Friedel, UMR 7223, Ecole Nationale Supérieure de Chimie de Paris, 11 rue Pierre et Marie Curie, 75231 Paris Cedex 05, France.
authors.forename: Jean-Hugues
authors.initials: JH
authors.lastname: Mirebeau
authors.forename: Mansour
authors.initials: M
authors.lastname: Haddad
authors.forename: Martin
authors.initials: M
authors.lastname: Henry-Ellinger
authors.forename: Gérard
authors.initials: G
authors.lastname: Jaouen
authors.forename: Julien
authors.initials: J
authors.lastname: Louvel
authors.forename: Franck
authors.initials: F
authors.lastname: Le Bideau