title: An efficient PIFA-mediated synthesis of fused diporphyrin and triply-singly interlacedly linked porphyrin array.
abstract: An efficient and metal-free oxidative method was reported for synthesis of triply linked diporphyrins with 2.5 equiv of phenyliodine bis(trifluoroacetate) (PIFA). This reaction showed high selectivity for Zn(II) porphyrins and had been successfully applied in the synthesis of a novel triply-singly interlacedly linked porphyrin array with lower energy gap.
authors.affiliation: State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China.
authors.forename: Qin
authors.initials: Q
authors.lastname: Ouyang
authors.forename: Yi-Zhou
authors.initials: YZ
authors.lastname: Zhu
authors.forename: Cai-Hui
authors.initials: CH
authors.lastname: Zhang
authors.forename: Kai-Qi
authors.initials: KQ
authors.lastname: Yan
authors.forename: Yun-Chao
authors.initials: YC
authors.lastname: Li
authors.forename: Jian-Yu
authors.initials: JY
authors.lastname: Zheng
mesh_terms: D005463:Fluoroacetates; D007462:Iodobenzenes; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010084:Oxidation-Reduction; D011166:Porphyrins / Q000737:chemistry*; D013237:Stereoisomerism; D014269:Trifluoroacetic Acid / Q000737:chemistry; D015032:Zinc / Q000737:chemistry
chemical_list: D005463:Fluoroacetates; D007462:Iodobenzenes; D009942:Organometallic Compounds; D011166:Porphyrins; C517666:phenyliodine(III) bis(trifluoroacetate); D014269:Trifluoroacetic Acid; D015032:Zinc