title: A high temperature piezoelectric ceramic: (1-x)(Bi0.9La0.1)FeO(3-x)PbTiO3 crystalline solutions.
abstract: (1-x)(Bi(0.9)La(0.1))FeO(3-x)PbTiO(3) (BLF-PT) crystalline solutions for x = 0.35, 0.37, 0.4, 0.43 and 0.45 have been prepared by the solid-state reaction method. The X-ray diffraction analysis shows that BLF-PT has a single perovskite phase with mixed tetragonal and rhombohedral phases between x = 0.4 and 0.43. The Curie temperature of BLF-PT for x = 0.4 attains 460 degrees C, which is about 80 degrees C higher than that of hard Pb(Zr,Ti)O(3) ceramics. The remnant polarization and piezoelectric constant of BLF-PT for x = 0.4 reach 38 microC/cm(2) and 112 pC/N, respectively. The planar coupling factor k(p) of BLF-PT for x = 0.4 remains stable at temperature increases of up to 360 degrees C. The impedance spectroscopy study reveals that the high temperature conduction of BLF-PT may be attributed to the motion of oxygen vacancies within the material. Our results indicate that BLF-PT is a promising candidate for high temperature applications.
authors.affiliation: School of Material Science and Engineering, Shanghai University, Shanghai, China.
authors.forename: Jianguo
authors.initials: J
authors.lastname: Chen
authors.forename: Yufa
authors.initials: Y
authors.lastname: Qi
authors.forename: Guiyang
authors.initials: G
authors.lastname: Shi
authors.forename: Shengwen
authors.initials: S
authors.lastname: Yu
authors.forename: Jinrong
authors.initials: J
authors.lastname: Cheng