title: [Ru(bpy)3]2+ nanocomposites containing heteropolyacids: simple preparation and stable solid-state electrochemiluminescence detection application.
abstract: In order to solidify the electrochemiluminescence (ECL) luminophor tris(2,2'-bipyridyl) ruthenium(II) ([Ru(bpy)(3)](2+)) onto the electrode surfaces robustly, the negative charged heteropolyacids (HPAs) moieties were utilized to attract and bond cations [Ru(bpy)(3)](2+) via an adsorption method. The compositions and microstructures of the hybrid complexes were characterized by elemental analysis (EDS), spectroscopic techniques (UV-vis, FTIR) and field-emission scanning electron microscopy (FE-SEM). The electrochemical and ECL behaviors of the [Ru(bpy)(3)](2+)/[PW(12)O(40)](3-) hybrid complex contained in the solid film of the nanocomposites formed on the electrode surfaces were also studied. It was found that the corresponding solid membranes exhibited a diffusion-controlled voltammetric feature and excellent electrochemiluminescence behaviors. Hence potential prospects as new electrochemiluminescent materials for application in electroanalytical detection are envisioned.
authors.affiliation: State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin, China.
authors.forename: Yali
authors.initials: Y
authors.lastname: Li
authors.forename: Hui
authors.initials: H
authors.lastname: Zhu
authors.forename: Xiurong
authors.initials: X
authors.lastname: Yang
mesh_terms: D055664:Electrochemical Techniques / Q000295:instrumentation / Q000379:methods*; D004566:Electrodes; D008163:Luminescent Measurements / Q000295:instrumentation / Q000379:methods*; D053768:Metal Nanoparticles / Q000737:chemistry / Q000648:ultrastructure; D008855:Microscopy, Electron, Scanning; D053761:Nanocomposites / Q000737:chemistry* / Q000648:ultrastructure; D009942:Organometallic Compounds / Q000032:analysis / Q000737:chemistry*; D012428:Ruthenium / Q000032:analysis / Q000737:chemistry; D013053:Spectrophotometry; D017550:Spectroscopy, Fourier Transform Infrared
chemical_list: D009942:Organometallic Compounds; C415768:tris(2,2'-bipyridyl)ruthenium(II); D012428:Ruthenium