Synthesis of novel vanillin derivatives containing isothiazole moieties and its synergistic effect in mixtures with insecticides.
Reaction between 4-formyl-2-methoxyphenyl 4,5-dichloroisothiazole-3-carboxylate with various aromatic amines led to azomethins 2-7 formation. By treatment of azomethins 2-7 with sodium triacetoxyborohydride corresponding amines 8-11 were obtained. During the bioassays of new vanillin derivatives in mixtures with insecticides remarkable synergetic effect was discovered.
Potkin
Vladimir
V
Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, 13 Surganova Str., 220072 Minsk, Belarus. potkin@ifoch.bas-net.by
Zubenko
Yuri
Y
Bykhovetz
Anatoly
A
Zolotar
Romualda
R
Goncharuk
Violetta
V
D000818:Animals; D001547:Benzaldehydes / Q000138:chemical synthesis* / Q000737:chemistry; D001681:Biological Assay; D001517:Coleoptera / Q000254:growth & development*; D007306:Insecticides / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D010574:Pesticide Synergists / Q000138:chemical synthesis* / Q000737:chemistry; D013055:Spectrophotometry, Infrared; D013844:Thiazoles / Q000138:chemical synthesis* / Q000737:chemistry
D001547:Benzaldehydes; D007306:Insecticides; D010574:Pesticide Synergists; D013844:Thiazoles; C100058:vanillin