Direct functionalization of benzylic C-Hs with vinyl acetates via Fe-catalysis.
Direct cross-coupling to construct sp3 C-sp3 C bonds via Fe-catalyzed benzylic C-H activation with 1-aryl vinyl acetate was developed.
Song
Chun-Xiao
CX
Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, Peking University, Beijing, China.
Cai
Gui-Xin
GX
Farrell
Thomas R
TR
Jiang
Zhong-Ping
ZP
Li
Hu
H
Gan
Liang-Bing
LB
Shi
Zhang-Jie
ZJ
D001593:Benzyl Compounds / Q000737:chemistry*; D002384:Catalysis; D003432:Cross-Linking Reagents / Q000737:chemistry; D007501:Iron / Q000737:chemistry*; D008958:Models, Molecular; D014753:Vinyl Compounds / Q000737:chemistry*
D001593:Benzyl Compounds; D003432:Cross-Linking Reagents; D014753:Vinyl Compounds; D007501:Iron; C011566:vinyl acetate