Production of natural antioxidants from vegetable oil deodorizer distillates: effect of catalytic hydrogenation.
Natural tocopherols are one of the main types of antioxidants found in living creatures, but they also have other critical biological functions. The biopotency of natural (+)-alpha-tocopherol (RRR) is 36% higher than that of the synthetic racemic mixture and 300% higher than the SRR stereoisomer. Vegetable oil deodorizer distillates (DD) are an excellent source of natural tocopherols. Catalytic hydrogenation of DD preconcentrates has been suggested as a feasible route for recovery of tocopherols in high yield. However, it is important to know whether the hydrogenation operation, as applied to these tocopherol-rich mixtures, is capable of preserving the chiral (RRR) character, which is critical to its biopotency. Fortified (i.e., (+)-alpha-tocopherol enriched) sunflower oil and methyl stearate, as well as sunflower oil DD, were fully hydrogenated using commercial Ni and Pd catalysts (120-180 degrees C; 20-60 psig). Products were analyzed by chiral HPLC. Results show that the desired chiral configuration (RRR) is fully retained. Thus, the hydrogenation route can be safely considered as a valid alternative for increasing the efficiency of tocopherol recovery processes from DDs while preserving their natural characteristics.
Pagani
María Ayelén
MA
INTEC, Instituto de Desarrollo Tecnológico para la Industria Química, Universidad Nacional del Litoral and Consejo Nacional de Investigaciones Científicas y Técnicas, Güemes 3450, S3000GLN Santa Fe, Argentina.
Baltanás
Miguel A
MA
D000327:Adsorption; D000975:Antioxidants / Q000138:chemical synthesis*; D002384:Catalysis; D002851:Chromatography, High Pressure Liquid; D057168:Distillation / Q000379:methods*; D006865:Hydrogenation; D007536:Isomerism; D009812:Odorants / Q000032:analysis*; D010938:Plant Oils / Q000737:chemistry* / Q000378:metabolism; D013228:Stearates; D000074242:Sunflower Oil; D013499:Surface Properties; D013696:Temperature; D024505:Tocopherols / Q000032:analysis / Q000138:chemical synthesis* / Q000737:chemistry
D000975:Antioxidants; D010938:Plant Oils; D013228:Stearates; D000074242:Sunflower Oil; D024505:Tocopherols