title: Solvent-free direct reductive amination by catalytic use of an organotin reagent incorporated on an ionic liquid.
abstract: An organotin reagent supported on an ionic liquid was used as a highly effective catalyst (down to 0.1 mol%) for the direct reductive amination of aldehydes and ketones using PhSiH3; this solvent-free method facilitates purification of the products, thus minimizing the contamination by tin.
authors.affiliation: Laboratoire de Synthèse Organique, UCO2M, UMR CNRS 6011, Université du Maine, Avenue Olivier Messiaen, 72085 Le Mans Cedex 9, France.
authors.forename: Phuoc Dien
authors.initials: PD
authors.lastname: Pham
authors.forename: Philippe
authors.initials: P
authors.lastname: Bertus
authors.forename: Stéphanie
authors.initials: S
authors.lastname: Legoupy
mesh_terms: D000447:Aldehydes / Q000737:chemistry*; D000586:Amination; D002384:Catalysis; D052578:Ionic Liquids / Q000737:chemistry; D007659:Ketones / Q000737:chemistry*; D010084:Oxidation-Reduction; D014001:Tin / Q000737:chemistry*
chemical_list: D000447:Aldehydes; D052578:Ionic Liquids; D007659:Ketones; D014001:Tin