On the mechanism of isospecific epoxide polymerization by salen cobalt(III) complexes: evidence for solid-state catalysis.
Mechanistic studies have revealed that the isospecific polymerization of epoxides by a discrete salen cobalt(III) catalyst occurs at the surface of the undissolved, crystalline complex.
Ajiro
Hiroharu
H
Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, USA.
Peretti
Kathryn L
KL
Lobkovsky
Emil B
EB
Coates
Geoffrey W
GW