Iron-catalyzed dehydrogenative phosphonation of N,N-dimethylanilines.
Iron(II) and iron(III) salts catalyze the oxidative alpha-phosphonation of N,N-dimethylanilines with dialkyl H-phosphonates in the presence of tert-butylhydroperoxide.
Han
Wei
W
Department Chemie und Biochemie, Ludwig-Maximilians-Universität München, Butenandtstr. 5-13 (Haus F), 81377 München, Germany.
Ofial
Armin R
AR
D000814:Aniline Compounds / Q000737:chemistry*; D002384:Catalysis; D007501:Iron; D008958:Models, Molecular; D009943:Organophosphorus Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D020122:tert-Butylhydroperoxide / Q000737:chemistry*
D000814:Aniline Compounds; D009943:Organophosphorus Compounds; C007766:2,6-xylidine; D020122:tert-Butylhydroperoxide; D007501:Iron