title: Asymmetric beta-boration of alpha,beta-unsaturated carbonyl compounds promoted by chiral rhodium-bisoxazolinylphenyl catalysts.
abstract: Chiral rhodium-bisoxazolinylphenyl acetate complexes exhibited high catalytic activity for the beta-boration of alpha,beta-unsaturated carbonyl compounds with bis(pinacolato)diboron in the presence of sodium t-butoxide with enantioselectivity up to 97%.
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Chikusa, Nagoya, 464-8603, Japan.
authors.forename: Takushi
authors.initials: T
authors.lastname: Shiomi
authors.forename: Takahiro
authors.initials: T
authors.lastname: Adachi
authors.forename: Kenji
authors.initials: K
authors.lastname: Toribatake
authors.forename: Li
authors.initials: L
authors.lastname: Zhou
authors.forename: Hisao
authors.initials: H
authors.lastname: Nishiyama