Experimentally based DFT calculations on the hindered disproportionation of [Al(4)Cp*(4)]: formation of metalloid clusters as intermediates on the way to solid Al prevents the decomposition of a textbook molecule.
Huber
Michael
M
Karlsruhe Institue of Technology (KIT), Center for Functional Nanostructures (CFN) and Institute for Inorganic Chemistry, University of Karlsruhe (TH), 76128 Karlsruhe, Germany.
Henke
Patrick
P
Schnöckel
Hansgeorg
H