One-pot synthesis and biofunctionalization of glycopolymers via RAFT polymerization and thiol-ene reactions.
A modification of a polymeric activated ester with sugar-amines and a simultaneous aminolysis-thiol-ene reaction involving the RAFT end-groups yield biotin functionalized glycopolymer in one-pot.
Boyer
Cyrille
C
Centre for Advanced Macromolecular Design (CAMD), School of Chemical Sciences and Engineering, The University of New South Wales, Sydney, NSW 2052, Australia.
Davis
Thomas P
TP
D000606:Amino Sugars / Q000138:chemical synthesis* / Q000737:chemistry; D040761:Biomimetic Materials / Q000138:chemical synthesis* / Q000737:chemistry; D004952:Esters / Q000138:chemical synthesis / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry; D012995:Solubility; D013438:Sulfhydryl Compounds / Q000138:chemical synthesis* / Q000737:chemistry
D000606:Amino Sugars; D004952:Esters; D011108:Polymers; D013438:Sulfhydryl Compounds