Pulse radiolysis studies on the temperature-dependent spectrum and the time-dependent yield of solvated electron in propane-1,2,3-triol.
With a revisit of the absorption coefficient of the solvated electron in propane-1,2,3-triol, the temperature-dependent behavior of the absorption spectrum of solvated electron was studied from room temperature to 573 K by pulse radiolysis techniques. The change in the absorption spectrum of solvated electron in propane-1,2,3-triol observed by cooling down from a high temperature to 333 K is compared with that occurring during the electron solvation process at 333 K. The effect of the specific molecular structure of propane-1,2,3-triol compared to other alcohols is discussed.
Lin
Mingzhang
M
Advanced Science Research Center, Japan Atomic Energy Agency, 2-4 Shirakata shirane, Tokaimura, Nakagun, Ibaraki 319-1195, Japan.
Fu
Haiying
H
Lampre
Isabelle
I
de Waele
Vincent
V
Muroya
Yusa
Y
Yan
Yu
Y
Yamashita
Shinichi
S
Katsumura
Yosuke
Y
Mostafavi
Mehran
M