Manganese-catalyzed cross-coupling reactions of nitrogen nucleophiles with aryl halides in water.
A facile and convenient strategy for the assembly of N-arylated heterocycles has been demonstrated using a MnCl2.4H2O/trans-1,2-diaminocyclohexane catalyst and K3PO4 as the base in water.
Teo
Yong-Chua
YC
Natural Sciences and Science Education, National Institute of Education, Nanyang Technological University, 1 Nanyang Walk, Singapore 637616. yongchua.teo@nie.edu.sg
Yong
Fui-Fong
FF
Poh
Chai-Yun
CY
Yan
Yaw-Kai
YK
Chua
Guan-Leong
GL
D001554:Benzene / Q000138:chemical synthesis / Q000737:chemistry*; D002384:Catalysis; D006219:Halogens / Q000138:chemical synthesis / Q000737:chemistry*; D008345:Manganese / Q000737:chemistry*; D009584:Nitrogen / Q000737:chemistry*
D006219:Halogens; D008345:Manganese; D001554:Benzene; D009584:Nitrogen