Contamination and restoration of an estuary affected by phosphogypsum releases.
The Huelva Estuary in Huelva, Spain, has been one of the most studied environmental compartments in the past years from the point of view of naturally occurring radioactive material (NORM) releases. It has been historically affected by waste releases, enriched in radionuclides from the U-decay series, from factories located in the area devoted to the production of phosphoric acid and phosphate fertilizers. Nevertheless, changes in national regulations forced a new waste management practice in 1998, prohibiting releases of phosphogypsum into the rivers. The input of natural radionuclides from phosphate factories to rivers was drastically reduced. Because of this there was a unique opportunity for the study of the response of a contaminated environmental compartment, specifically an estuary affected by tidal influences, after the cessation of the contaminant releases to, in this case, the Huelva Estuary (henceforth referred to as the Estuary). To investigate the environmental response to this new discharge regime, the specific activities of radionuclides 226Ra and 210Pb in water and sediment samples collected in four campaigns (from 1999 to 2005) were determined and compared with pre-1998 values. From this study it is possible to infer the most effective mechanisms of decontamination for the Estuary. Decontamination rates of 210Pb and 226Ra in the sediments and water have been calculated using exponential fittings and corresponding half-lives have been deduced from them. The cleaning half-life in the whole area of the Estuary is about 6 and 3.5 years for 226Ra and 210Pb respectively. The observed trend clearly shows that contamination of the Estuary by natural radionuclides is now decreasing and radioactive levels in waters and sediments are approaching the natural background references. This work attempts to evaluate whether it can be expected that the decontamination of the enhanced levels of natural radioactivity in the Estuary can be performed via natural processes.
Villa
M
M
Centro de Investigación, Tecnología e Innovación, Universidad de Sevilla CITIUS, Av. Reina Mercedes 4B, E41012-Sevilla, Spain. mvilla@us.es
Mosqueda
F
F
Hurtado
S
S
Mantero
J
J
Manjón
G
G
Periañez
R
R
Vaca
F
F
García-Tenorio
R
R
D002133:Calcium Sulfate / Q000032:analysis*; D004784:Environmental Monitoring; D005308:Fertilizers; D019015:Geologic Sediments / Q000737:chemistry*; D006207:Half-Life; D007220:Industrial Waste / Q000032:analysis* / Q000517:prevention & control*; D010758:Phosphorus / Q000032:analysis*; D011868:Radioisotopes / Q000032:analysis*; D045483:Rivers; D013030:Spain; D013997:Time Factors; D014875:Water Pollutants, Radioactive / Q000032:analysis*
D005308:Fertilizers; D007220:Industrial Waste; D011868:Radioisotopes; D014875:Water Pollutants, Radioactive; C077769:phosphogypsum; D010758:Phosphorus; D002133:Calcium Sulfate