Supramolecular-directed chiral induction in biaryl derivatives.
A thermodynamically controlled resolution has allowed for the generation of diastereomerically enriched complexes, by chirality transfer from an enantiopure building block to a dynamically racemic biaryl derivative. A switchable sense of induction could be achieved depending on the substituents of the chiral block.
Etxebarria
J
J
Institute of Chemical Research of Catalonia (ICIQ), 43007 Tarragona, Spain.
Degenbeck
H
H
Felten
A-S
AS
Serres
S
S
Nieto
N
N
Vidal-Ferran
A
A