Engineering a lignocellulosic biosorbent--coir pith for removal of cesium from aqueous solutions: equilibrium and kinetic studies.
A novel method of engineering lignocellulosic biosorbent- coir pith (CP) by incorporation of nickel hexacyanoferrate (NiHCF), also referred to as Prussian blue analogue (PBA) inside its porous matrix is reported. Structural characterization confirmed the successful synthesis of NiHCF in the coir pith matrix. Sorption capacity of coir pith (CP) before and after loading of NiHCF was investigated for cesium (Cs) in batch equilibrium studies. Kinetic studies showed that the sorption process was rapid and saturation was attained within 30 min. The applicability of non linear Langmuir, Freundlich and Redlich Peterson isotherms was examined for the experimental data. The present studies revealed that there was nearly 100% increase in the sorption capacity of CP after its surface modification with NiHCF. Owing to its low cost, fast sorption kinetics and high uptake capacity, coir pith loaded with NiHCF (CP-NiHCF) seems to be one of the most promising biosorbents for recovery of cesium from liquid nuclear wastes.
Parab
Harshala
H
Analytical Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai, 400085, India. harshprb@gmail.com
Sudersanan
M
M
D000327:Adsorption; D001673:Biodegradation, Environmental; D002586:Cesium / Q000302:isolation & purification*; D052918:Environmental Restoration and Remediation / Q000379:methods*; D005295:Ferrocyanides / Q000737:chemistry; D007700:Kinetics; D008031:Lignin / Q000031:analogs & derivatives* / Q000737:chemistry; D009532:Nickel / Q000737:chemistry; D012996:Solutions; D013696:Temperature; D013818:Thermogravimetry; D013997:Time Factors; D014875:Water Pollutants, Radioactive / Q000302:isolation & purification*; D014961:X-Ray Diffraction
D005295:Ferrocyanides; D012996:Solutions; D014875:Water Pollutants, Radioactive; C507903:coir; C036909:lignocellulose; C027325:nickel ferrocyanide; D002586:Cesium; D009532:Nickel; D008031:Lignin