A three-dimensional supramolecular vanadium hydroxylamide complex: poly[di-mu2-aqua-bis(hydroxylamido)-mu3-malonato-oxidosodiumvanadium(V)].
The crystal structure of the title compound, [NaV(C3H2O4)(NH2O)2O(H2O)2], is built up of NaO6 and VO5N2 polyhedra connected through malonate bridges. The NaO6 octahedra are linked by edge sharing in the equatorial plane to form one-dimensional infinite chains. These chains are linked together by the malonate bridges to form two-dimensional layers. The distorted VO5N2 pentagonal bipyramid is grafted on to the layer by a malonate carboxylate O atom. Adjacent layers are connected through O-H...O and N-H...O hydrogen bonds to build up a three-dimensional supramolecular structure.
Zhang
Qi-Ying
QY
Department of Chemistry, East China Normal University, Shanghai 200062, People's Republic of China.
Zhang
Heng-Qiang
HQ
Kong
Ai-Guo
AG
Yang
Qian
Q
Shan
Yong-Kui
YK
D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D046911:Macromolecular Substances / Q000737:chemistry*; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D014639:Vanadium / Q000737:chemistry*
D046911:Macromolecular Substances; D009942:Organometallic Compounds; C544643:poly(di-mu2-aqua-bis(hydroxylamido)-mu3-malonato-oxidosodiumvanadium(V)); D014639:Vanadium