An efficient PIFA-mediated synthesis of fused diporphyrin and triply-singly interlacedly linked porphyrin array.
An efficient and metal-free oxidative method was reported for synthesis of triply linked diporphyrins with 2.5 equiv of phenyliodine bis(trifluoroacetate) (PIFA). This reaction showed high selectivity for Zn(II) porphyrins and had been successfully applied in the synthesis of a novel triply-singly interlacedly linked porphyrin array with lower energy gap.
Ouyang
Qin
Q
State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China.
Zhu
Yi-Zhou
YZ
Zhang
Cai-Hui
CH
Yan
Kai-Qi
KQ
Li
Yun-Chao
YC
Zheng
Jian-Yu
JY
D005463:Fluoroacetates; D007462:Iodobenzenes; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010084:Oxidation-Reduction; D011166:Porphyrins / Q000737:chemistry*; D013237:Stereoisomerism; D014269:Trifluoroacetic Acid / Q000737:chemistry; D015032:Zinc / Q000737:chemistry
D005463:Fluoroacetates; D007462:Iodobenzenes; D009942:Organometallic Compounds; D011166:Porphyrins; C517666:phenyliodine(III) bis(trifluoroacetate); D014269:Trifluoroacetic Acid; D015032:Zinc