A new, general method for the synthesis of carbasugar-sugar pseudodisaccharides.
A general synthetic methodology for the synthesis of sugar-carbasugar pseudodisaccharides is described. The methodology is based on the cycloaddition of pyran-2-ones to vinylated sugars and the subsequent manipulation of the cycloadducts to construct the carbasugar component of the pseudodisaccharide.
Afarinkia
Kamyar
K
Institute of Cancer Therapeutics, University of Bradford, Richmond Road, Bradford, BD7 1DP, United Kingdom. k.afarinkia@bradford.ac.uk
Abdullahi
Mohamed Haji
MH
Scowen
Ian J
IJ
D002236:Carbohydrate Conformation; D004187:Disaccharides / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D004187:Disaccharides