title: A novel nonenzymatic hydrogen peroxide sensor based on multi-wall carbon nanotube/silver nanoparticle nanohybrids modified gold electrode.
abstract: A novel strategy to fabricate hydrogen peroxide (H(2)O(2)) sensor was developed based on multi-wall carbon nanotube/silver nanoparticle nanohybrids (MWCNT/Ag nanohybrids) modified gold electrode. The process to synthesize MWCNT/Ag nanohybrids was facile and efficient. In the presence of carboxyl groups functionalized multi-wall carbon nanotubes (MWCNTs), silver nanoparticles (Ag NPs) were in situ generated from AgNO(3) aqueous solution and readily attached to the MWCNTs convex surfaces at room temperature, without any additional reducing reagent or irradiation treatment. The formation of MWCNT/Ag nanohybrids product was observed by transmission electron microscope (TEM), and the electrochemical properties of MWCNT/Ag nanohybrids modified gold electrode were characterized by electrochemical measurements. The results showed that this sensor had a favorable catalytic ability for the reduction of H(2)O(2). The resulted sensor could detect H(2)O(2) in a linear range of 0.05-17 mM with a detection limit of 5x10(-7)M at a signal-to-noise ratio of 3. The sensitivity was calculated as 1.42 microA/mM at a potential of -0.2 V. Additionally, it exhibited good reproducibility, long-term stability and negligible interference of ascorbic acid (AA), uric acid (UA), and acetaminophen (AP).
authors.affiliation: The Key Laboratory of Bioactive Materials, Ministry of Education, College of Life Science, Nankai University, Tianjin, China.
authors.forename: Wei
authors.initials: W
authors.lastname: Zhao
authors.forename: Huicai
authors.initials: H
authors.lastname: Wang
authors.forename: Xia
authors.initials: X
authors.lastname: Qin
authors.forename: Xinsheng
authors.initials: X
authors.lastname: Wang
authors.forename: Zixia
authors.initials: Z
authors.lastname: Zhao
authors.forename: Zhiying
authors.initials: Z
authors.lastname: Miao
authors.forename: Lili
authors.initials: L
authors.lastname: Chen
authors.forename: Miaomiao
authors.initials: M
authors.lastname: Shan
authors.forename: Yuxin
authors.initials: Y
authors.lastname: Fang
authors.forename: Qiang
authors.initials: Q
authors.lastname: Chen
mesh_terms: D000082:Acetaminophen / Q000737:chemistry; D001205:Ascorbic Acid / Q000737:chemistry; D015374:Biosensing Techniques / Q000295:instrumentation / Q000379:methods*; D055664:Electrochemical Techniques / Q000295:instrumentation / Q000379:methods; D004566:Electrodes; D006046:Gold / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000032:analysis* / Q000737:chemistry; D046529:Microscopy, Electron, Transmission; D008956:Models, Chemical; D053758:Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D037742:Nanotubes, Carbon / Q000737:chemistry*; D010084:Oxidation-Reduction; D015203:Reproducibility of Results; D012834:Silver / Q000737:chemistry*; D014527:Uric Acid / Q000737:chemistry
chemical_list: D037742:Nanotubes, Carbon; D014527:Uric Acid; D000082:Acetaminophen; D012834:Silver; D006046:Gold; D006861:Hydrogen Peroxide; D001205:Ascorbic Acid