Effect of aryloxo substituents in ethylene polymerisation by tris(pyrazolyl)borate titanium(IV) complexes containing aryloxo ligands of type, TpTiCl2(OAr).
Tris(pyrazolyl)borate titanium(IV) complexes containing aryloxo ligand of type, TpTiCl(2)(OAr) [Tp = HB(pyrazolyl)(3); Ar = 2-(i)PrC(6)H(4), C(6)F(5), 2,6-Ph(2)C(6)H(3)], have been prepared, identified, and the structures of TpTiCl(2)(OC(6)F(5)), TpTiCl(2)(O-2,6-Ph(2)C(6)H(3)) have been determined by X-ray crystallography. The 2-(i)PrC(6)H(4) analogue exhibits especially high catalytic activities for ethylene polymerisation in the presence of methylaluminoxane (MAO), and the activity by TpTiCl(2)(OAr) increased in the order: Ar = 2-(i)PrC(6)H(4) > Ph > C(6)F(5) >> 2,6-Ph(2)C(6)H(3) > 2,6-Me(2)C(6)H(3), 2,6-(i)Pr(2)C(6)H(3).
Nomura
Kotohiro
K
Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara 630-0101, Japan. nomurak@ms.naist.jp
Hasumi
Shinya
S
Fujiki
Michiya
M
Itagaki
Koji
K