Green molecular transformation by a B(12)-TiO(2) hybrid catalyst as an alternative to tributyltin hydride.
The B(12)-TiO(2) hybrid catalyst was effectively used for the radical reactions, such as 1,2-migrations of phenyl groups and acyl groups under irradiation by UV light, and the selectivity of the reaction was controlled by the solvent system.
Shimakoshi
Hisashi
H
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Motooka, Fukuoka 819-0395, Japan.
Abiru
Makoto
M
Izumi
Shin-ichiro
S
Hisaeda
Yoshio
Y
D002384:Catalysis; D014025:Titanium / Q000737:chemistry*; D014220:Trialkyltin Compounds / Q000737:chemistry*; D014466:Ultraviolet Rays; D014805:Vitamin B 12 / Q000737:chemistry*
D014220:Trialkyltin Compounds; C009495:titanium dioxide; C011559:tributyltin; D014025:Titanium; D014805:Vitamin B 12