Oxidative amination of heteroaromatic zinc reagents mediated by PhI(OAc)(2).
The oxidative amination of functionalized heterocycles has been achieved by using readily available heterocyclic zinc reagents and lithium amides. PhI(OAc)(2) proved to be a suitable reagent for this oxidative amination.
Department Chemie & Biochemie, Ludwig-Maximilians-Universität, Butenandtstrasse 5-13, 81377, München, Germany.
Marcel
M
Kienle
Cora
C
Dunst
Paul
P
Knochel
D000586:Amination; D006847:Hydrocarbons, Iodinated / Q000737:chemistry*; D007202:Indicators and Reagents / Q000138:chemical synthesis / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010084:Oxidation-Reduction; D013237:Stereoisomerism; D013844:Thiazoles / Q000138:chemical synthesis / Q000737:chemistry; D015032:Zinc / Q000737:chemistry*
D006847:Hydrocarbons, Iodinated; D007202:Indicators and Reagents; D009942:Organometallic Compounds; D013844:Thiazoles; D015032:Zinc