Hydrodynamic sono-voltammetry of ferrocene in [Tf2N]- based ionic liquid media.
The present work deals with the hydrodynamic behavior of several room-temperature ionic liquids presenting the same bis(trifluoromethanesulfonyles)imide anion, associated with four different cations: 1-butyl-3-methylimidazolium, 1-octyl-3-methylimidazolium, N-trimethyl-N-propylammonium and 1-butyl-1-methylpyrrolidinium cations. Steady state voltammetry was used as an electrochemical technique to characterize mass transfer in both silent and sonicated conditions, using a rotating disk electrode. Results obtained in RTILs media are compared to those acquired in synthetic solutions of controlled viscosity, in order to develop a better understanding of the phenomena involved in such media.
Costa
Cédric
C
Equipe Sonochimie et Réactivité des Surfaces, Institut UTINAM UMR CNRS 6213, Université de Franche-Comté, 25009 Besançon, France.
Doche
Marie-Laure
ML
Hihn
Jean-Yves
JY
Bisel
Isabelle
I
Moisy
Philippe
P
Lévêque
Jean-Marc
JM