Skeletal rearrangement of all-carbon spiro skeletons mediated by a Lewis acid.
Mediated by AlCl(3), substituted spiro[4.5]deca-tetraenes underwent novel and selective skeletal rearrangement to generate indene derivatives in high to excellent yields.
Zhao
Fei
F
Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.
Wang
Chao
C
Liu
Lantao
L
Zhang
Wen-Xiong
WX
Xi
Zhenfeng
Z
D000143:Acids / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*
D000143:Acids; D002244:Carbon