Modular synthesis of heterobimetallic salen structures using metal templation.
A modular and general synthetic method is disclosed for nonsymmetrical heterobimetallic bis-salphen structures starting from a series of synthetically convenient monometalated triimine precursors. This methodology permits the introduction of various combinations of metal ions within the bis-salphen framework potentially useful in multifunctional materials.
Castilla
Ana M
AM
Institute of Chemical Research of Catalonia (ICIQ), Av. Paisos Catalans 16, 43007 Tarragona, Spain.
Curreli
Simona
S
Escudero-Adán
Eduardo C
EC
Belmonte
Marta Martínez
MM
Benet-Buchholz
Jordi
J
Kleij
Arjan W
AW
D018360:Crystallography, X-Ray; D005029:Ethylenediamines / Q000138:chemical synthesis* / Q000737:chemistry*; D019216:Metals, Heavy / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D005029:Ethylenediamines; D019216:Metals, Heavy; D009942:Organometallic Compounds; C011452:disalicylaldehyde ethylenediamine