Access to new magnetic cores in Fe(III) and Fe(III)/Cu(II) spin clusters.
The synthesis, structure and magnetic properties of [Fe(14)O(4)(OH)(4)(H(2)L)(2)(HL)(4)(piv)(20)] (1) and [Fe(8)Cu(2)O(4)(H(2)L)(4)(HL)(2)(OBz)(12)] (2) are reported (H(3)L = 2-amino-2-(hydroxymethyl)propane-1,3-diol): both complexes have unique core structures and display non-zero spin ground states.
WestCHEM, Department of Chemistry, University of Glasgow, University Avenue, UK G12 8QQ.
Alan
A
Ferguson
Julie
J
McGregor
Euan K
EK
Brechin
Lynne H
LH
Thomas
Mark
M
Murrie