Photon-gated photoconductivity of Pr(3+):YAG.
We have observed photon-gated photoconductivity in Pr:YAG, providing clear evidence for photoionization of the trivalent praseodymium ion in the solid state. Photoionization occurs by two-step absorption from (3)H(4)(1) ? (1)D(2)(1) followed by an excited-state absorption from (1)D(2) to the lowest component of the 4f5d configuration. The excitation spectrum of the photocurrent shows sharp (1)D(2) spectral features, providing unambiguous assignment of the photocurrent.
Wittmann
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Macfarlane
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