Oxidative amination of heteroaromatic zinc reagents mediated by PhI(OAc)(2).
The oxidative amination of functionalized heterocycles has been achieved by using readily available heterocyclic zinc reagents and lithium amides. PhI(OAc)(2) proved to be a suitable reagent for this oxidative amination.
Kienle
Marcel
M
Department Chemie & Biochemie, Ludwig-Maximilians-Universität, Butenandtstrasse 5-13, 81377, München, Germany.
Dunst
Cora
C
Knochel
Paul
P
D000586:Amination; D006847:Hydrocarbons, Iodinated / Q000737:chemistry*; D007202:Indicators and Reagents / Q000138:chemical synthesis / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010084:Oxidation-Reduction; D013237:Stereoisomerism; D013844:Thiazoles / Q000138:chemical synthesis / Q000737:chemistry; D015032:Zinc / Q000737:chemistry*
D006847:Hydrocarbons, Iodinated; D007202:Indicators and Reagents; D009942:Organometallic Compounds; D013844:Thiazoles; D015032:Zinc