Electrochemical assessment of the interaction of dihydrogen phosphate with a novel ferrocenyl receptor.
A novel ferrocene-based amide has been synthesized by condensation reaction and characterized by (1)H NMR and UV-vis spectroscopies. The electrochemical properties and anion recognition properties of the ferrocene-based amide were investigated by the CV and UV-vis techniques. An interesting phenomenon was revealed by CV: a second oxidative peak, and the first oxidative peak decreased. Therefore, an effective dihydrogen phosphate recognition sensor is expected from this compound in the future.
State Key Laboratory of Chemical Engineering, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China.
Chao
C
Li
Li
L
Wang
Libo
L
Deng
Haojie
H
Yu
Jia
J
Huo
Liang
L
Ma
Jianjun
J
Wang
D000838:Anions / Q000737:chemistry; D055664:Electrochemical Techniques / Q000379:methods*; D005296:Ferrous Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D000075163:Metallocenes; D008968:Molecular Conformation; D010710:Phosphates / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet
D000838:Anions; C546614:BAE-2Fc; D005296:Ferrous Compounds; D000075163:Metallocenes; D010710:Phosphates; D006859:Hydrogen; C004998:ferrocene