Host-guest transformational correlations for a gas inclusion co-crystal on changing gas pressure and temperature.
The CO(2) adsorption behavior and inclusion structure of a flexible single-crystal host [Cu(2)(bza)(4)(pyz)](n) were studied under various conditions (203-373 K, <15.4 MPa) and the correlation between changes in gas adsorption behavior and the structures of guest arrangement and host component packing were investigated.
Department of Nanosystem Science, Graduate School of Nanobioscience, Yokohama City University, Kanazawa-ku, Yokohama, Kanagawa 236-0027, Japan. staka@yokohama-cu.ac.jp
Satoshi
S
Takamizawa
Yuichi
Y
Takasaki
Ryosuke
R
Miyake
D003460:Crystallization; D005740:Gases / Q000737:chemistry*; D011312:Pressure; D013696:Temperature
D005740:Gases