Efficient ruthenium-catalyzed synthesis of [3]dendralenes from 1,3-dienic allylic carbonates.
Selective elimination from 1,3-dienic allylic carbonates occurs in the presence of a catalytic amount of [Ru(C(5)Me(5))(4,4'-di-Bu(t)-2,2'-bipyridine)(CH(3)CN)]PF(6) and provides efficient access to a variety of [3]dendralenes.
UMR 6226 CNRS - Université de Rennes 1, Sciences chimiques de Rennes, Catalyse et Organométalliques, Campus de Beaulieu, 35042 Rennes Cedex, France.
Kassem
K
Beydoun
Hui-Jun
HJ
Zhang
Basker
B
Sundararaju
Bernard
B
Demerseman
Mathieu
M
Achard
Zhenfeng
Z
Xi
Christian
C
Bruneau
D000475:Alkenes / Q000737:chemistry*; D002254:Carbonates / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*
C527474:3,4,5-trimethylenehepta-1,6-diene; D000475:Alkenes; D002254:Carbonates; D012428:Ruthenium