Degradation of fifteen emerging contaminants at microg L(-1) initial concentrations by mild solar photo-Fenton in MWTP effluents.
The degradation of 15 emerging contaminants (ECs) at low concentrations in simulated and real effluent of municipal wastewater treatment plant with photo-Fenton at unchanged pH and Fe=5 mg L(-1) in a pilot-scale solar CPC reactor was studied. The degradation of those 15 compounds (Acetaminophen, Antipyrine, Atrazine, Caffeine, Carbamazepine, Diclofenac, Flumequine, Hydroxybiphenyl, Ibuprofen, Isoproturon, Ketorolac, Ofloxacin, Progesterone, Sulfamethoxazole and Triclosan), each with an initial concentration of 100 microg L(-1), was found to depend on the presence of CO(3)(2-) and HCO(3)(-) (hydroxyl radicals scavengers) and on the type of water (simulated water, simulated effluent wastewater and real effluent wastewater), but is relatively independent of pH, the type of acid used for release of hydroxyl radicals scavengers and the initial H(2)O(2) concentration used. Toxicity tests with Vibrio fisheri showed that degradation of the compounds in real effluent wastewater led to toxicity increase.
Plataforma Solar de Almería-CIEMAT, Carretera Senés km 4, 04200 Tabernas (Almería), Spain.
N
N
Klamerth
L
L
Rizzo
S
S
Malato
Manuel I
MI
Maldonado
A
A
Agüera
A R
AR
Fernández-Alba
D048908:Aliivibrio fischeri / Q000187:drug effects; D000890:Anti-Infective Agents / Q000032:analysis / Q000737:chemistry / Q000633:toxicity; D000894:Anti-Inflammatory Agents, Non-Steroidal / Q000032:analysis / Q000737:chemistry / Q000633:toxicity; D002110:Caffeine / Q000032:analysis / Q000737:chemistry / Q000633:toxicity; D002220:Carbamazepine / Q000032:analysis / Q000737:chemistry / Q000633:toxicity; D002947:Cities; D003358:Cosmetics / Q000032:analysis / Q000737:chemistry / Q000633:toxicity; D052244:Endocrine Disruptors / Q000032:analysis / Q000737:chemistry / Q000633:toxicity; D052918:Environmental Restoration and Remediation / Q000379:methods*; D006540:Herbicides / Q000032:analysis / Q000737:chemistry / Q000633:toxicity; D006728:Hormones / Q000032:analysis / Q000737:chemistry / Q000633:toxicity; D006861:Hydrogen Peroxide / Q000737:chemistry; D007501:Iron / Q000737:chemistry; D010782:Photolysis; D014865:Waste Disposal, Fluid / Q000379:methods*; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000737:chemistry / Q000633:toxicity
D000890:Anti-Infective Agents; D000894:Anti-Inflammatory Agents, Non-Steroidal; D003358:Cosmetics; D052244:Endocrine Disruptors; C045076:Fenton's reagent; D006540:Herbicides; D006728:Hormones; D014874:Water Pollutants, Chemical; D002220:Carbamazepine; D002110:Caffeine; D006861:Hydrogen Peroxide; D007501:Iron