A tetranuclear iridium(iii) complex with a flavin analogue as a bridging ligand in different coordination modes and exchangeable anion encapsulation in a supramolecular cage.
A novel tetranuclear Ir(iii) complex involving unprecedented coordination modes of alloxazine formed a closed pi-space by intermolecular hydrogen bonding and the counter anions encapsulated in the space could be exchanged via self-assembly.
Kojima
Takahiko
T
Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba, Ibaraki 305-8571, Japan. kojima@chem.tsukuba.ac.jp
Inui
Yuji
Y
Miyazaki
Soushi
S
Shiro
Motoo
M
Fukuzumi
Shunichi
S