Self-assembly of star-shaped heteropoly-15-palladate(II).
A novel heteropolyoxopalladate structural type has been discovered: the polyoxo-15-palladate(II) [Pd(0.4)Na(0.6) subsetPd(15)P(10)O(50)H(6.6)](12-) (Pd(15)) has been prepared in a one-pot self-assembly reaction and characterized by single-crystal XRD, elemental analysis, IR, TGA, (31)P NMR and electrochemistry; preliminary catalytic studies showed that Pd(15) is active as a catalyst in alcohol oxidation by dioxygen.
Jacobs University, School of Engineering and Science, P.O. Box 750 561, 28725, Bremen, Germany.
Natalya V
NV
Izarova
Rosa Ngo
RN
Biboum
Bineta
B
Keita
Maria
M
Mifsud
Isabel W C E
IW
Arends
Geoffrey B
GB
Jameson
Ulrich
U
Kortz
D001149:Arsenates / Q000737:chemistry; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D010710:Phosphates / Q000737:chemistry
D001149:Arsenates; D009942:Organometallic Compounds; D010710:Phosphates; D010165:Palladium; C025657:arsenic acid