Zeolite formation from coal fly ash and its adsorption potential.
The possibility in converting coal fly ash (CFA) to zeolite was evaluated. CFA samples from the local power plant in Prachinburi province, Thailand, were collected during a 3-month time span to account for the inconsistency of the CFA quality, and it was evident that the deviation of the quality of the raw material did not have significant effects on the synthesis. The zeolite product was found to be type X. The most suitable weight ratio of sodium hydroxide (NaOH) to CFA was approximately 2.25, because this gave reasonably high zeolite yield with good cation exchange capacity (CEC). The silica (Si)-to-aluminum (Al) molar ratio of 4.06 yielded the highest crystallinity level for zeolite X at 79% with a CEC of 240 meq/100 g and a surface area of 325 m2/g. Optimal crystallization temperature and time were 90 degrees C and 4 hr, respectively, which gave the highest CEC of approximately 305 meq/100 g. Yields obtained from all experiments were in the range of 50-72%.
Ruen-ngam
Duangkamol
D
Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok, Thailand.
Rungsuk
Doungmanee
D
Apiratikul
Ronbanchob
R
Pavasant
Prasert
P
D000327:Adsorption; D000393:Air Pollutants / Q000737:chemistry; D000397:Air Pollution / Q000517:prevention & control; D002244:Carbon / Q000737:chemistry*; D003031:Coal / Q000032:analysis*; D060729:Coal Ash; D003460:Crystallization; D052638:Particulate Matter / Q000737:chemistry*; D012037:Refuse Disposal; D012972:Sodium Hydroxide; D013696:Temperature; D013997:Time Factors; D017641:Zeolites / Q000737:chemistry*
D000393:Air Pollutants; D003031:Coal; D060729:Coal Ash; D052638:Particulate Matter; D017641:Zeolites; D012972:Sodium Hydroxide; D002244:Carbon