Ni and Pd mediate asymmetric organoboron synthesis with ester functionality at the beta-position.
Catalytic systems based on Ni and Pd complexes modified with chiral P-P ligands can be used in a convenient strategy for enantioselectively adding a boron unit to the beta-position of alpha,beta-unsaturated esters.
Universidad Rovira i Virgili, C/Marcel.lí Domingo s/n. 43005 Tarragona, Spain.
Vanesa
V
Lillo
Michael J
MJ
Geier
Stephen A
SA
Westcott
Elena
E
Fernández