Oxidation of cyclic acetals by ozone in ionic liquid media.
The application of ozone-stable pyrrolidinium based ionic liquids as safe reaction media resulted in selective hydroxy ester formation upon ozonation of cyclic acetals without using low temperatures or acetylating reagents.
Van Doorslaer
Charlie
C
Centre for Surface Chemistry and Catalysis, Department of Microbial and Molecular Systems, K.U.Leuven, Kasteelpark Arenberg 23, 3001 Leuven, Belgium.
Peeters
Annelies
A
Mertens
Pascal
P
Vinckier
Chris
C
Binnemans
Koen
K
De Vos
Dirk
D
D000080:Acetals / Q000737:chemistry*; D052578:Ionic Liquids / Q000737:chemistry*; D016877:Oxidants / Q000737:chemistry; D010084:Oxidation-Reduction; D010126:Ozone / Q000737:chemistry*; D013696:Temperature
D000080:Acetals; D052578:Ionic Liquids; D016877:Oxidants; D010126:Ozone