Anionic surfactant with hydrophobic and hydrophilic chains for nanoparticle dispersion and shape memory polymer nanocomposites.
An anionic surfactant comprising a hydrophilic poly(ethylene glycol) (PEG) chain, hydrophobic alkyl chain, and polymerizable vinyl group was synthesized as a capping agent of nanoparticles. TiO(2) nanoparticles modified by this surfactant were completely dispersible in various organic solvents with a wide range of polarities, such as nitriles, alcohols, ketones, and acetates. Furthermore, these particles were found to be dispersible in various polymers with different properties, such as thermosetting epoxy resins and radical polymerized poly(methylmethacrylate) (PMMA). A polymer composite of surface-modified TiO(2) nanoparticles in epoxy resins prepared by using the developed surfactant also possessed temperature-induced shape memory properties.
Iijima
Motoyuki
M
Institute of Symbiotic Science and Technology, Tokyo University of Agriculture and Technology, 2-24-16 Nakacho, Koganei, Tokyo 184-8588, Japan. motoyuki@cc.tuat.ac.jp
Kobayakawa
Murino
M
Yamazaki
Miwa
M
Ohta
Yasuhiro
Y
Kamiya
Hidehiro
H
D000838:Anions / Q000737:chemistry; D057927:Hydrophobic and Hydrophilic Interactions; D053758:Nanoparticles / Q000737:chemistry*; D010316:Particle Size; D011092:Polyethylene Glycols / Q000737:chemistry*; D019904:Polymethyl Methacrylate / Q000737:chemistry*; D013499:Surface Properties; D013501:Surface-Active Agents / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*; D014867:Water / Q000737:chemistry; D017155:Wettability
D000838:Anions; D013501:Surface-Active Agents; D014867:Water; C009495:titanium dioxide; D011092:Polyethylene Glycols; D019904:Polymethyl Methacrylate; D014025:Titanium