Encapsulated chloride coordinating with two in-in protons of bridgehead amines in an octaprotonated azacryptand.
An encapsulated chloride in a thiophene-based cryptand is bridged by two in-in protons of tertiary amines with an N...Cl(-) distance of 3.048(3) A, similar to that observed in Park and Simmons' katapinand chloride complex.
Saeed
Musabbir A
MA
Department of Chemistry, Jackson State University, 1325 J. R. Lynch Street, P.O. Box 17910, Jackson, MS 39212, USA.
Fronczek
Frank R
FR
Hossain
Md Alamgir
MA
D000588:Amines / Q000737:chemistry*; D053961:Azabicyclo Compounds / Q000737:chemistry*; D002712:Chlorides / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008968:Molecular Conformation; D011522:Protons
C525617:1,4,7,10,13,16,21,24-octaazabicyclo(8.8.8)hexacosane; D000588:Amines; D053961:Azabicyclo Compounds; D002712:Chlorides; D011522:Protons