Reverse vesicles formed by hydrogen bonded arylamide-derived triammonium cyclophanes and hexaammonium capsule.
Hydrogen bonded rigid imine-based macrocycles and capsules have been reduced to cyclic triamines and two-layered hexaamines, the triammonium and hexaammonium derivatives of which are revealed to form reverse vesicles in organic liquids of low polarity, which are characterized by SEM, AFM, (HR)TEM, DLS and XRD.
State Key Lab of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China.
Xiao-Na
XN
Xu
Lu
L
Wang
Zhan-Ting
ZT
Li
D000577:Amides / Q000737:chemistry*; D006860:Hydrogen Bonding; D008855:Microscopy, Electron, Scanning; D000644:Quaternary Ammonium Compounds / Q000737:chemistry*
D000577:Amides; D000644:Quaternary Ammonium Compounds