Effects of titania nanoparticles on phosphorus fractions and its release in resuspended sediments under UV irradiation.
Little is known about the effects of nano-TiO(2) on the transformation and transport of phosphorus (P) in resuspended sediments. Chemical sequential extraction was used to investigate P fractions and its release in resuspended sediments under the influence of nano-TiO(2) and UV irradiation. The results showed that the contents of sediment P in all fractions decreased with increasing nano-TiO(2) concentration in UV irradiation, while increased in the dark controls. Furthermore, P release from all fractions was greater in UV irradiation than in the controls. Elevated concentrations (10-50 mg L(-1)) of nano-TiO(2) in UV irradiation significantly facilitated the release of P from organic and Fe oxide fractions, possibly resulting from the partial photo-degradation of organic matter and photochemical transformation of Fe oxides. Apparently, nano-TiO(2) in UV irradiation did not immobilize the loosely sorbed P and reductant soluble P release from the resuspended sediments, possible because (1) some of P released from those fractions were refurnished by the P released from OM; (2) photocatalysis of nano-TiO(2) reduced binding capacity of the resuspended sediments. Our results suggest that the photocatalysis of nano-TiO(2) may offer the potential to regulate the transformation and transport of sediment P in the aquatic environment.
Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China.
Zhuanxi
Z
Luo
Zhenhong
Z
Wang
Qingzhao
Q
Li
Qikun
Q
Pan
Changzhou
C
Yan
D002384:Catalysis; D053768:Metal Nanoparticles; D010758:Phosphorus / Q000737:chemistry*; D010777:Photochemistry; D014025:Titanium / Q000737:chemistry*; D014466:Ultraviolet Rays
D010758:Phosphorus; D014025:Titanium