Electrochemical assessment of the interaction of dihydrogen phosphate with a novel ferrocenyl receptor.
A novel ferrocene-based amide has been synthesized by condensation reaction and characterized by (1)H NMR and UV-vis spectroscopies. The electrochemical properties and anion recognition properties of the ferrocene-based amide were investigated by the CV and UV-vis techniques. An interesting phenomenon was revealed by CV: a second oxidative peak, and the first oxidative peak decreased. Therefore, an effective dihydrogen phosphate recognition sensor is expected from this compound in the future.
Li
Chao
C
State Key Laboratory of Chemical Engineering, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China.
Wang
Li
L
Deng
Libo
L
Yu
Haojie
H
Huo
Jia
J
Ma
Liang
L
Wang
Jianjun
J
D000838:Anions / Q000737:chemistry; D055664:Electrochemical Techniques / Q000379:methods*; D005296:Ferrous Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D000075163:Metallocenes; D008968:Molecular Conformation; D010710:Phosphates / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet
D000838:Anions; C546614:BAE-2Fc; D005296:Ferrous Compounds; D000075163:Metallocenes; D010710:Phosphates; D006859:Hydrogen; C004998:ferrocene