CoS supersedes Pt as efficient electrocatalyst for triiodide reduction in dye-sensitized solar cells.
We report an efficient nonplatinized flexible counter electrode for dye-sensitized solar cells. In combination with a solvent-free ionic liquid electrolyte, we have demonstrated a approximately 6.5% cell with an amphiphilic ruthenium polypyridyl photosensitizer showing excellent stability measured under prolonged light soaking at 60 degrees C. Compared to the Pt deposited PEN film, the CoS deposited PEN film shows higher electrocatalytic activity for the reduction of triiodide. This is expected to have an important practical consequence on the production of flexible low-cost and lightweight thin film DSC devices based on the plastic matrix.
Wang
Mingkui
M
Laboratory for Photonics and Interfaces, Swiss Federal Institute of Technology, CH 1015, Lausanne, Switzerland.
Anghel
Alina M
AM
Marsan
Benoît
B
Cevey Ha
Ngoc-Le
NL
Pootrakulchote
Nuttapol
N
Zakeeruddin
Shaik M
SM
Grätzel
Michael
M
D002384:Catalysis; D003035:Cobalt / Q000737:chemistry*; D004396:Coloring Agents / Q000737:chemistry; D055664:Electrochemical Techniques; D004736:Energy-Generating Resources; D007454:Iodides / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry; D012993:Solar Energy
D004396:Coloring Agents; D007454:Iodides; D003035:Cobalt; D010984:Platinum; C027875:cobaltous sulfide