Encapsulated chloride coordinating with two in-in protons of bridgehead amines in an octaprotonated azacryptand.
An encapsulated chloride in a thiophene-based cryptand is bridged by two in-in protons of tertiary amines with an N...Cl(-) distance of 3.048(3) A, similar to that observed in Park and Simmons' katapinand chloride complex.
Department of Chemistry, Jackson State University, 1325 J. R. Lynch Street, P.O. Box 17910, Jackson, MS 39212, USA.
Musabbir A
MA
Saeed
Frank R
FR
Fronczek
Md Alamgir
MA
Hossain
D000588:Amines / Q000737:chemistry*; D053961:Azabicyclo Compounds / Q000737:chemistry*; D002712:Chlorides / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008968:Molecular Conformation; D011522:Protons
C525617:1,4,7,10,13,16,21,24-octaazabicyclo(8.8.8)hexacosane; D000588:Amines; D053961:Azabicyclo Compounds; D002712:Chlorides; D011522:Protons