Green molecular transformation by a B(12)-TiO(2) hybrid catalyst as an alternative to tributyltin hydride.
The B(12)-TiO(2) hybrid catalyst was effectively used for the radical reactions, such as 1,2-migrations of phenyl groups and acyl groups under irradiation by UV light, and the selectivity of the reaction was controlled by the solvent system.
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Motooka, Fukuoka 819-0395, Japan.
Hisashi
H
Shimakoshi
Makoto
M
Abiru
Shin-ichiro
S
Izumi
Yoshio
Y
Hisaeda
D002384:Catalysis; D014025:Titanium / Q000737:chemistry*; D014220:Trialkyltin Compounds / Q000737:chemistry*; D014466:Ultraviolet Rays; D014805:Vitamin B 12 / Q000737:chemistry*
D014220:Trialkyltin Compounds; C009495:titanium dioxide; C011559:tributyltin; D014025:Titanium; D014805:Vitamin B 12