SOLUBILITY OF MUSTARD GAS [BIS (beta-CHLOROETHYL) SULFIDE] IN WATER, MOLAR SODIUM CHLORIDE, AND IN SOLUTIONS OF DETERGENTS.
1. The solubility of mustard (H) in water and in molar sodium chloride was found to be 5.8 x 10(-3) molar and 3.2 x 10(-3) molar respectively or 0.92 mg. per ml. and 0.5 mg. per ml. Solubility curves have been drawn and the usefulness of this method in examining the homogeneity of H preparations as well as in establishing their solubility, is discussed. 2. Certain detergents increase the solubility of H in water. The solubility was found to increase with the concentration of detergent. 3. Many detergents were found to affect the interfacial tension between H and water so that with slight agitation liquid H breaks up into minute droplets. This in turn greatly accelerates the rate of solution.
Herriott
R M
RM
Laboratories of The Rockefeller Institute for Medical Research, Princeton, New Jersey.
D003902:Detergents; D008963:Molar; D009151:Mustard Gas; D012965:Sodium Chloride; D012995:Solubility; D012996:Solutions; D013440:Sulfides; D014867:Water
D003902:Detergents; D012996:Solutions; D013440:Sulfides; D014867:Water; D012965:Sodium Chloride; D009151:Mustard Gas