title: Ionic liquid-based routes to conversion or reuse of recycled ammonium perchlorate.
abstract: New, potentially green, and efficient synthetic routes for the remediation and/or re-use of perchlorate-based energetic materials have been developed. Four simple organic imidazolium- and phosphonium-based perchlorate salts/ionic liquids have been synthesized by simple, inexpensive, and nonhazardous methods, using ammonium perchlorate as the perchlorate source. By appropriate choice of the cation, perchlorate can be incorporated into an ionic liquid which serves as its own electrolyte for the electrochemical reduction of the perchlorate anion, allowing for the regeneration of the chloride-based parent ionic liquid. The electrochemical degradation of the hazardous perchlorate ion and its conversion to harmless chloride during electrolysis was studied using IR and (35)Cl NMR spectroscopies.
authors.affiliation: Department of Chemistry and Center for Green Manufacturing, The University of Alabama, Box 870336, Tuscaloosa, AL 35467-0338, USA.
authors.forename: David B
authors.initials: DB
authors.lastname: Cordes
authors.forename: Marcin
authors.initials: M
authors.lastname: Smiglak
authors.forename: C Corey
authors.initials: CC
authors.lastname: Hines
authors.forename: Nicholas J
authors.initials: NJ
authors.lastname: Bridges
authors.forename: Meghna
authors.initials: M
authors.lastname: Dilip
authors.forename: Geetha
authors.initials: G
authors.lastname: Srinivasan
authors.forename: Andreas
authors.initials: A
authors.lastname: Metlen
authors.forename: Robin D
authors.initials: RD
authors.lastname: Rogers