Rotating-disk sorptive extraction of nonylphenol from water samples.
In this study the sorption of nonylphenol was implemented on a rotating Teflon disk coated with a PDMS film on one of its surfaces. In this way, the disk, which has a high surface area, contacts only the liquid sample, which can be stirred at higher velocity than with the stir bar used in stir-bar sorptive extraction (SBSE), without damaging the phase while at the same time facilitating analyte mass transfer to the PDMS surface. We refer to the procedure as rotating-disk sorptive extraction (RDSE). Extraction variables such as disk rotational velocity, extraction time, and surface area of PDMS film were studied to establish the best conditions for extraction. With increasing rotational velocity, the amount of extracted analyte significantly increases because the stagnant layer concomitantly decreases. On the other hand, the extracted amount concomitantly increases with extraction time, reaching equilibrium at approximately 20 min, which can be reduced to 10 min when the surface area of PDMS increases from 1.74 to 6.97 cm(2). Precision of the method was determined by using the same disk (n=6) and different disks (n=3), showing relative standard deviations for the analyte of 3.7% and 10%, respectively. The detection limit of the method was 0.09 microg/L NP, defined at a signal to noise ratio of 3. The method was applied to a real sample, achieving quantitative recovery. The PDMS phase on the disk could be used for at least 50 experiments. In any case, replacement of the PDMS film on the disk is very easy and inexpensive, as compared to the commercial alternative SBSE.
Richter
Pablo
P
Department of Inorganic and Analytical Chemistry, Faculty of Chemical and Pharmaceutical Sciences, University of Chile, PO Box 233, Santiago, Chile. prichter@ciq.uchile.cl
Leiva
Claudio
C
Choque
Carlos
C
Giordano
Ady
A
Sepúlveda
Betsabet
B
D010636:Phenols / Q000032:analysis*; D052616:Solid Phase Extraction / Q000295:instrumentation / Q000379:methods*; D014874:Water Pollutants, Chemical / Q000032:analysis*
D010636:Phenols; D014874:Water Pollutants, Chemical; C025256:nonylphenol