First diastereoselective construction of butane-type and butyrolactone-type secocyclolignane structures.
The first diastereoselective construction of butane-type and butyrolactone-type secocyclolignanes was achieved by the application of a high-valency heterobimetallic Ir-Sn complex to benzyl alcohols prepared from an Evans's anti-aldol product. The elimination of an acetoxymethyl group to give a cinnamyl structure by using a high-valency heterobimetallic Ir-Sn complex was also observed in this study.
Morita
Masao
M
Faculty of Agriculture, Ehime University, Matsuyama, Ehime, Japan.
Yamauchi
Satoshi
S
D001554:Benzene / Q000737:chemistry; D002073:Butanes / Q000737:chemistry*; D007783:Lactones / Q000737:chemistry*; D017705:Lignans / Q000138:chemical synthesis* / Q000737:chemistry*; D013237:Stereoisomerism; D013379:Substrate Specificity
D002073:Butanes; D007783:Lactones; D017705:Lignans; C046888:butane; D001554:Benzene