title: Scope and limitations of imidazolium-based ionic liquids as room temperature glycosylation promoters.
abstract: The scope and limitations of imidazolium-based ionic liquids as room temperature glycosylation promoters have been studied. Herein, we report the effects of modifying the structure of the imidazolium cation and how important the choice of counter ion becomes on model glycosylation reactions of thioglycosides at room temperature in the presence of N-iodosuccinimide (NIS).
authors.affiliation: School of Chemistry, University of Bristol, Bristol BS8 1TS, UK. M.C.Galan@bristol.ac.uk
authors.forename: M Carmen
authors.initials: MC
authors.lastname: Galan
authors.forename: Kevin
authors.initials: K
authors.lastname: Jouvin
authors.forename: Dimitri
authors.initials: D
authors.lastname: Alvarez-Dorta
mesh_terms: D006031:Glycosylation; D007093:Imidazoles / Q000737:chemistry*; D052578:Ionic Liquids / Q000737:chemistry*; D013696:Temperature; D013865:Thioglycosides / Q000737:chemistry
chemical_list: D007093:Imidazoles; D052578:Ionic Liquids; D013865:Thioglycosides; C029899:imidazole