Alumina nanofibers grafted with functional groups: a new design in efficient sorbents for removal of toxic contaminants from water.
A new design in efficient sorbents for the removal of trace pollutants from water was proposed: grafting the external surface of gamma-alumina (gamma-Al(2)O(3)) nanofibers with functional groups that have a strong affinity to the contaminants. This new grafting strategy greatly improves the accessibility of these sorption sites to adsorbates and thus efficiency of the fibrous sorbents. The product sorbents could capture the pollutants selectively even when the concentration of the contaminants is extremely low. Two types of gamma-Al(2)O(3) nanofibers with different size were prepared via facile hydrothermal methods. Thiol groups were then grafted on the gamma-Al(2)O(3) fibers by refluxing the toluene solution of 3-mercaptopropyltrimethoxysilane (MPTMS). The thiol group modified fibers not only can efficiently remove heavy metal ions (Pb(2+) and Cd(2+)) from water at a high flux, but also display high sorption capacity under sorption equilibrium conditions. Similar result was obtained from the nanofibers grafted with octyl groups which are employed to selectively adsorb highly diluted hydrophobic 4-nonylphenol molecules from water. This study demonstrates that grafting nanofibers is a new and effective strategy for developing efficient sorbents.
Yang
Dongjiang
D
School of Physical and Chemical Sciences, Queensland University of Technology, Brisbane, Qld 4001, Australia.
Paul
Blain
B
Xu
Wujun
W
Yuan
Yong
Y
Liu
Erming
E
Ke
Xuebin
X
Wellard
Robert M
RM
Guo
Cheng
C
Xu
Yao
Y
Sun
Yuhan
Y
Zhu
Huaiyong
H
D000327:Adsorption; D000537:Aluminum Oxide / Q000737:chemistry*; D002152:Calorimetry, Differential Scanning; D057927:Hydrophobic and Hydrophilic Interactions; D009682:Magnetic Resonance Spectroscopy; D019216:Metals, Heavy / Q000302:isolation & purification; D057139:Nanofibers / Q000737:chemistry* / Q000648:ultrastructure; D009584:Nitrogen / Q000302:isolation & purification; D010636:Phenols / Q000302:isolation & purification; D017550:Spectroscopy, Fourier Transform Infrared; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D013818:Thermogravimetry; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*; D018508:Water Purification / Q000295:instrumentation*; D014961:X-Ray Diffraction
D019216:Metals, Heavy; D010636:Phenols; D013438:Sulfhydryl Compounds; D014874:Water Pollutants, Chemical; C041594:4-nonylphenol; D000537:Aluminum Oxide; D009584:Nitrogen