Oxidative carbon-carbon bond formation via allyldimethylsilyl enol ethers.
A method for the oxidative alkylation of ketones through intramolecular allyl-group transfer within preformed allyldimethylsilyl enol ethers is reported. A number of examples are detailed, including a study into the effects of resident sterocenters within cyclic enol ethers.
Konkol
Leah C
LC
Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA.
Jones
Brian T
BT
Thomson
Regan J
RJ
D000478:Alkylation; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D004987:Ethers / Q000737:chemistry*; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D017646:Organosilicon Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction
D004987:Ethers; D007659:Ketones; D017646:Organosilicon Compounds