A new 2D hybrid indate-germanate based on the linkages of Ge4O10F2 clusters and {In2O6} dimers.
A novel layered indate-germanate InGe(2)O(5)F(dap) x 2 H(2)O (1, dap = 1,2-diaminopropane) has been hydrothermally synthesized and structurally characterized. Its structure consists of Ge(4)O(10)F(2) clusters and In(2)O(6) dimers, which are interconnected to form 4- and 6-ring layers. 1 displays luminescent emission at 422 nm.
Zhou
Jian
J
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
Yu
Zhi-Wu
ZW
Fang
Wei-hui
WH
Deng
Feng
F
Yang
Guo-Yu
GY