Structure investigations of dichloroaluminum benzoates: an unprecedented example of a monomeric aluminum complex with a chelating carboxylate ligand.
Dichloroaluminum benzoate and its adducts with Lewis bases show a large structural variety from molecular complexes to ionic species as indicated by X-ray diffraction, spectroscopic studies, and quantum-chemical calculations.
Florjańczyk
Zbigniew
Z
Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland. evala@ch.pw.edu.pl
Bury
Wojciech
W
Zygadło-Monikowska
Ewa
E
Justyniak
Iwona
I
Balawender
Robert
R
Lewiński
Janusz
J
D000535:Aluminum / Q000737:chemistry*; D001565:Benzoates / Q000737:chemistry*; D002264:Carboxylic Acids / Q000737:chemistry*; D002614:Chelating Agents / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D011789:Quantum Theory
D001565:Benzoates; D002264:Carboxylic Acids; D002614:Chelating Agents; D008024:Ligands; D009942:Organometallic Compounds; D000535:Aluminum