Spectroscopic study and structure of (E)-2-[(2-chlorobenzylimino)methyl]methoxyphenol.
(E)-2-[(2-chlorobenzylimino)methyl]methoxyphenol has been synthesized from the reaction of 2-hydroxy-3-methoxy-1-benzaldehyde(o-vanillin) with 2-chlorobenzylamine. The title compound has been characterized by using elemental analysis, FT-IR, (1)H NMR, (13)C NMR and UV-vis spectroscopic techniques. The crystal structure of the title compound has also been examined cyrstallographically. It crystallizes in the orthorhombic space group Pbca with unit cell parameters: a = 7.208(1) A, b = 13.726(2) A, c = 27.858(4) A, V = 2756.0(1) A(3), D(c) = 1.18 g cm(-3) and Z = 8. The crystal structure was solved by direct methods and refined by full-matrix least squares to a find R = 0.046 for 2773 observed reflections.
Unver
Hüseyin
H
Department of Physics, Faculty of Science, Ankara University, TR-06100 Beşevler-Ankara, Turkey. unver@science.edu.tr
Yildiz
Mustafa
M
Ozay
Hava
H
Durlu
Tahsin Nuri
TN
D018360:Crystallography, X-Ray; D006139:Guaiacol / Q000031:analogs & derivatives* / Q000737:chemistry; D007536:Isomerism; D009682:Magnetic Resonance Spectroscopy; D010636:Phenols / Q000737:chemistry*; D012996:Solutions; D012997:Solvents / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D054159:Torsion, Mechanical
C546551:(E)-2-((2-chlorobenzylimino)methyl)methoxyphenol; D010636:Phenols; D012996:Solutions; D012997:Solvents; D006139:Guaiacol