Scope and limitations of imidazolium-based ionic liquids as room temperature glycosylation promoters.
The scope and limitations of imidazolium-based ionic liquids as room temperature glycosylation promoters have been studied. Herein, we report the effects of modifying the structure of the imidazolium cation and how important the choice of counter ion becomes on model glycosylation reactions of thioglycosides at room temperature in the presence of N-iodosuccinimide (NIS).
Galan
M Carmen
MC
School of Chemistry, University of Bristol, Bristol BS8 1TS, UK. M.C.Galan@bristol.ac.uk
Jouvin
Kevin
K
Alvarez-Dorta
Dimitri
D
D006031:Glycosylation; D007093:Imidazoles / Q000737:chemistry*; D052578:Ionic Liquids / Q000737:chemistry*; D013696:Temperature; D013865:Thioglycosides / Q000737:chemistry
D007093:Imidazoles; D052578:Ionic Liquids; D013865:Thioglycosides; C029899:imidazole