Molecular tectonics: design of 2-D networks by simultaneous use of charge-assisted hydrogen and coordination bonds.
Using a combination of charge-assisted H- and coordination-bonds, a tetra component system composed of a dicationic and a dianionic organic tecton, Ag(+) cation and XF(6)(-) (X= P, As, Sb) anion behaves as planned and leads to the formation of 2-D isostructural networks for which the energetic contributions of the two recognition events dominate the construction process.
Carpanese
Cristina
C
Laboratoire de Chimie de Coordination Organique, UMR CNRS 7140, Université de Strasbourg, Institut Le Bel, 4, rue Blaise Pascal, F-67000 Strasbourg, France.
Ferlay
Sylvie
S
Kyritsakas
Nathalie
N
Henry
Marc
M
Hosseini
Mir Wais
MW