Selective recognition and binding of arsenate over phosphate.
A divanadium complex shows remarkable selectivity for arsenate in substitution reactions with oxoanions.
Egdal
Rune Kirk
RK
Department of Physics and Chemistry, University of Southern Denmark, Campusvej 55, 5230, Odense M, Denmark.
Raber
Georg
G
Bond
Andrew D
AD
Hussain
Munawar
M
Espino
Maria P B
MP
Francesconi
Kevin A
KA
McKenzie
Christine J
CJ
D001149:Arsenates / Q000737:chemistry*; D001665:Binding Sites; D018360:Crystallography, X-Ray; D007700:Kinetics; D010710:Phosphates / Q000737:chemistry*; D014639:Vanadium / Q000737:chemistry*; D017968:Vanadium Compounds / Q000737:chemistry*
D001149:Arsenates; D010710:Phosphates; D017968:Vanadium Compounds; D014639:Vanadium