Identification of an acetyl disulfide derivative in the synthesis of thiosialosides.
The first report of the formation of an acetyl disulfide sialoside during the synthesis of thioglycosides is described. This compound is a by-product in the synthesis of the 2-thioacetyl sialoside commonly used in thioglycoside preparation. Our investigations into the identification of this novel disulfide are described.
Morais
Goreti Ribeiro
GR
Institute of Cancer Therapeutics, School of Life Sciences, University of Bradford, Bradford BD7 1DP, UK.
Oliveira
Ines Felix
IF
Humphrey
Andrew J
AJ
Falconer
Robert A
RA
D002851:Chromatography, High Pressure Liquid; D004220:Disulfides / Q000032:analysis* / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D013865:Thioglycosides / Q000138:chemical synthesis* / Q000737:chemistry*
D004220:Disulfides; D013865:Thioglycosides