title: Evidence for the formation of a mononuclear ferric-hydroperoxo complex via the reaction of dioxygen with an (N4S(thiolate))iron(II) complex.
abstract: Addition of O(2)(g) at low-temperature to a mononuclear, nonheme iron(ii) complex comprising a tetraazamacrocyclic N(4) donor and an arylthiolate S donor leads to the generation of a deep red complex assigned as a low-spin Fe(III)?OOH complex, formed via metal- and ligand-assisted oxidation.
authors.affiliation: Department of Chemistry, Johns Hopkins University, Baltimore, MD 21218, USA.
authors.forename: Yunbo
authors.initials: Y
authors.lastname: Jiang
authors.forename: Joshua
authors.initials: J
authors.lastname: Telser
authors.forename: David P
authors.initials: DP
authors.lastname: Goldberg
mesh_terms: D005290:Ferric Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D006861:Hydrogen Peroxide / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry; D013438:Sulfhydryl Compounds / Q000737:chemistry
chemical_list: D005290:Ferric Compounds; D013438:Sulfhydryl Compounds; D006861:Hydrogen Peroxide; C023884:thiolactic acid; D010100:Oxygen