title: Adsorption of chromium (VI) from aqueous solution by sugar beet bagasse-based activated charcoal.
abstract: Chromium (VI) is known to be potentially carcinogenic and mutagenic in humans. A low-cost industrial solid bioadsorbent, bagasse-based activated charcoal (BAC), has been investigated for removal of chromium from aqueous solution. All the experiments were carried out in batch process with laboratory-prepared samples to study the effects of adsorbent dose, contact time, pH and initial concentration of Cr(VI). The removal of chromium ion was found to be highly dependent on the pH of the solution, adsorbent dose and contact time. Also the equilibrium adsorption was analyzed by the Freundlich and Langmuir isotherm models. It was found that the Freundlich isotherm model best described the sorption of chromium by sugar beet bagasse-based activated charcoal (r2 > 0.9927). Experimental data of kinetic studies were fitted to pseudo-first-order, pseudo-second-order and modified pseudo-first-order models. The results showed pseudo-second order kinetics was best fitted to the collected data (r2 > 0.9893). Optimum conditions for adsorption were determined at pH 2 and a contact time of 180 minutes (92.7% removal). These retention capacities suggest that BAC can provide a simple, effective, and cheap method for removing Cr(VI) ions from effluents and water resources.
authors.affiliation: Department of Environmental Health Engineering, Faculty of Health and Center for Health Research, Hamadan University of Medical Sciences, Hamadan P.O. Box No. 4171, Iran. samadi@umsha.ac.ir
authors.forename: M T
authors.initials: MT
authors.lastname: Samadi
authors.forename: A R
authors.initials: AR
authors.lastname: Rahman
authors.forename: M
authors.initials: M
authors.lastname: Zarrabi
authors.forename: E
authors.initials: E
authors.lastname: Shahabi
authors.forename: F
authors.initials: F
authors.lastname: Sameei
mesh_terms: D000327:Adsorption; D027461:Beta vulgaris / Q000737:chemistry*; D002482:Cellulose / Q000737:chemistry*; D002606:Charcoal / Q000737:chemistry*; D002857:Chromium / Q000737:chemistry / Q000302:isolation & purification*; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D008956:Models, Chemical; D013696:Temperature; D018508:Water Purification / Q000379:methods*
chemical_list: D002857:Chromium; D002606:Charcoal; C074702:chromium hexavalent ion; D002482:Cellulose; C027433:bagasse