title: THE APPLICATION OF QUANTUM MECHANICS TO CERTAIN CASES OF HOMOGENEOUS CATALYSIS. I.
abstract: 1. The activation energy for the hydrolytic breaking of a peptid linkage has been calculated from quantum mechanical considerations. 2. The relative catalytic effects of H(+) and OH(-) and the mechanism of these effects have been calculated and discussed. 3. These effects are both qualitatively and semiquantitatively in agreement with experiment.
authors.affiliation: Division of Physical Chemistry, University of Missouri, Columbia.
authors.forename: A E
authors.initials: AE
authors.lastname: Stearn