title: Heterogenous catalysis mediated by plasmon heating.
abstract: We introduce a new method for performing and miniaturizing many types of heterogeneous catalysis involving nanoparticles. The method makes use of the plasmon resonance present in nanoscale metal catalysts to provide the necessary heat of reaction when illuminated with a low-power laser. We demonstrate our approach by reforming a flowing, liquid mixture of ethanol and water over gold nanoparticle catalysts in a microfluidic channel. Plasmon heating of the nanoparticles provides not only the heat of reaction but the means to generate both water and ethanol vapor locally over the catalysts, which in turn allows the chip and the fluid lines to remain at room temperature. The measured products of the reaction, CO(2), CO, and H(2), are consistent with catalytic steam reforming of ethanol. The approach, which we refer to as plasmon-assisted catalysis, is general and can be used with a variety of endothermic catalytic processes involving nanoparticles.
authors.affiliation: Division of Engineering and Applied Science, California Institute of Technology, Pasadena, California 91125, USA.
authors.forename: James R
authors.initials: JR
authors.lastname: Adleman
authors.forename: David A
authors.initials: DA
authors.lastname: Boyd
authors.forename: David G
authors.initials: DG
authors.lastname: Goodwin
authors.forename: Demetri
authors.initials: D
authors.lastname: Psaltis
mesh_terms: D002384:Catalysis; D004867:Equipment Design; D019544:Equipment Failure Analysis; D000431:Ethanol / Q000737:chemistry*; D006361:Heating / Q000295:instrumentation*; D044085:Microfluidics / Q000295:instrumentation*; D036103:Nanotechnology / Q000295:instrumentation*; D020349:Surface Plasmon Resonance / Q000295:instrumentation*
chemical_list: D000431:Ethanol