title: Transport coefficients in nonequilibrium gas-mixture flows with electronic excitation.
abstract: In the present paper, a one-temperature model of transport properties in chemically nonequilibrium neutral gas-mixture flows with electronic excitation is developed. The closed set of governing equations for the macroscopic parameters taking into account electronic degrees of freedom of both molecules and atoms is derived using the generalized Chapman-Enskog method. The transport algorithms for the calculation of the thermal-conductivity, diffusion, and viscosity coefficients are proposed. The developed theoretical model is applied for the calculation of the transport coefficients in the electronically excited N/N(2) mixture. The specific heats and transport coefficients are calculated in the temperature range 50-50,000 K. Two sets of data for the collision integrals are applied for the calculations. An important contribution of the excited electronic states to the heat transfer is shown. The Prandtl number of atomic species is found to be substantially nonconstant.
authors.affiliation: Department of Mathematics and Mechanics, Saint Petersburg State University, Saint Petersburg, Russia. elena_kustova@mail.ru
authors.forename: E V
authors.initials: EV
authors.lastname: Kustova
authors.forename: L A
authors.initials: LA
authors.lastname: Puzyreva
mesh_terms: D045424:Complex Mixtures / Q000737:chemistry* / Q000528:radiation effects*; D003198:Computer Simulation; D004574:Electromagnetic Fields; D005740:Gases / Q000737:chemistry* / Q000528:radiation effects*; D006358:Hot Temperature; D007700:Kinetics; D008962:Models, Theoretical; D017711:Nonlinear Dynamics; D012212:Rheology / Q000379:methods*
chemical_list: D045424:Complex Mixtures; D005740:Gases