Schiff bases from D-glucosamine and aliphatic ketones.
Despite the comprehensive literature and enormous versatility of chiral imines derived from aminosugars and aldehydes, the corresponding counterparts generated from ketones remain an underestimated research subject. Filling in the gap, this manuscript sheds light on the synthetic and structural aspects of such substances and updates the few antecedents reported so far.
Pérez
Esther M S
EM
Departamento de Química Orgánica e Inorgánica, QUOREX Research Group, Universidad de Extremadura, E-06071 Badajoz, Spain. espero@unex.es
Avalos
Martín
M
Babiano
Reyes
R
Cintas
Pedro
P
Light
Mark E
ME
Jiménez
José L
JL
Palacios
Juan C
JC
Sancho
Ana
A
D002236:Carbohydrate Conformation; D005944:Glucosamine / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D012394:Rosaniline Dyes / Q000737:chemistry; D013237:Stereoisomerism
D007659:Ketones; D012394:Rosaniline Dyes; C476677:Schiff's reagent; D005944:Glucosamine