Non-centrosymmetric behavior of a clay film ion-exchanged with chiral metal complexes.
SHG measurements on a highly transparent clay film ion-exchanged with chiral metal complexes revealed that the mono-molecular layer of the chiral complexes in an interlayer space acquired a non-centrosymmetric character.
Suzuki
Yasutaka
Y
Graduate School of Medicine, Yamaguchi University, Yamaguchi, 753-8512, Japan.
Matsunaga
Ryoya
R
Sato
Hisako
H
Kogure
Toshihiro
T
Yamagishi
Akihiko
A
Kawamata
Jun
J
D000538:Aluminum Silicates / Q000737:chemistry*; D002942:Circular Dichroism; D000077215:Clay; D056831:Coordination Complexes / Q000737:chemistry*; D007477:Ions / Q000737:chemistry*; D018625:Microscopy, Atomic Force; D017975:Ruthenium Compounds / Q000138:chemical synthesis / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet; D013237:Stereoisomerism; D014961:X-Ray Diffraction
D000538:Aluminum Silicates; D056831:Coordination Complexes; D007477:Ions; D017975:Ruthenium Compounds; D000077215:Clay