Intensely luminescent gold(I)-silver(I) cluster with hypercoordinated carbon.
Intense solution and solid state phosphorescence was observed on a novel photostable gold(I)-silver(I) cluster with hypercoordinated carbon, [Au(6)Ag(2)(C)(dppy)(6)](BF(4))(4), which has a core structure of a hexagold(I) octahedron with two silver(I) atoms capping on a pair of its faces; the incorporation of silver atoms enhances the rigidity and integrity of the cluster.
Jia
Jian-Hua
JH
State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen, 361005, PR China.
Wang
Quan-Ming
QM
D002244:Carbon / Q000737:chemistry*; D006046:Gold / Q000737:chemistry*; D049408:Luminescent Agents / Q000737:chemistry*; D008163:Luminescent Measurements; D012834:Silver / Q000737:chemistry*
D049408:Luminescent Agents; D012834:Silver; D002244:Carbon; D006046:Gold