Synthesis of homogeneous antifreeze glycopeptides via a ligation-desulfurisation strategy.
Homogeneous glycopeptide analogues of fish antifreeze glycoproteins of discrete oligomeric length have been synthesised using a native chemical ligation-desulfurisation strategy.
Garner
James
J
School of Chemistry, The University of New South Wales, Sydney, NSW 2052, Australia.
Jolliffe
Katrina A
KA
Harding
Margaret M
MM
Payne
Richard J
RJ
D000818:Animals; D021301:Antifreeze Proteins / Q000138:chemical synthesis* / Q000737:chemistry; D005399:Fishes; D006020:Glycopeptides / Q000138:chemical synthesis / Q000737:chemistry*; D013329:Structure-Activity Relationship; D013455:Sulfur / Q000737:chemistry
D021301:Antifreeze Proteins; D006020:Glycopeptides; D013455:Sulfur