Formation of inclusion complexes between 1,1'-dialkyl-3,3'-(1,4-phenylene)bisimidazolium dibromide salts and cucurbit[7]uril.
N,N'-Dialkyl-(1,4-phenylene)bisimidazolium salts form inclusion complexes with cucurbit[7]uril (CB[7]) with high association constants. The stoichiometry of the complexes depends on the alkyl chains and on the relative concentration of the imidazolium salt and CB[7]. The binding interactions of CB[7] with these bisimidazolium salts were studied experimentally by (1)H NMR, high resolution mass spectroscopy, and UV spectroscopy, and theoretically by semiempirical molecular modeling. Nonlinear regression analysis was used to calculate or estimate the binding parameters for the supramolecular inclusion complexes present in solution. The detailed study of the binding association of these imidazolium salts may allow us to understand the exact role of each recognition site in these salts and to assemble higher supramolecular complexes.
Noujeim
Nadim
N
Department of Chemistry, Université de Montréal, C.P. 6128 Succursale Centre-ville, Montréal, Québec, H3C 3J7, Canada.
Jouvelet
Benjamin
B
Schmitzer
Andreea R
AR