title: Borylene-based functionalization of Pt-alkynyl complexes by photochemical borylene transfer from [(OC)(5)Cr=BN(SiMe(3))(2)].
abstract: Photochemical borylene transfer from [(OC)(5)Cr=BN(SiMe(3))(2)] to the platinum sigma-alkynyl complex [Cl(PMe(3))(2)Pt-C[triple bond]CPh] gave facile access to the first transition metal-borirene complex. The title compound has been fully characterized in solution and by X-ray crystallography.
authors.affiliation: Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany. h.braunschweig@mail.uni-wuerzburg.de
authors.forename: Holger
authors.initials: H
authors.lastname: Braunschweig
authors.forename: Qing
authors.initials: Q
authors.lastname: Ye
authors.forename: Krzystof
authors.initials: K
authors.lastname: Radacki