Microwave-assisted versatile hydrogenation of carbonyl compounds using supported metal nanoparticles.
The efficient microwave-assisted transfer hydrogenation of carbonyl compounds was performed using supported Pt and Pd nanoparticles on Al-SBA-15 materials. Excellent conversions, with exceedingly higher TOF values (4,000-20,000 h(-1)) compared to any previous literature report, were achieved in very short times of reaction (5-30 min), together with complete selectivities to the hydrogenated product.
Gracia
Maria Jose
MJ
Departamento de Química Orgánica, Universidad de Córdoba, Edificio Marie Curie, Ctra Nnal IV, Km 396, E-14014, Córdoba, Spain.
Campelo
Juan Manuel
JM
Losada
Elia
E
Luque
Rafael
R
Marinas
Jose Maria
JM
Romero
Antonio Angel
AA
D000438:Alcohols / Q000138:chemical synthesis / Q000737:chemistry; D006865:Hydrogenation; D007659:Ketones / Q000737:chemistry*; D053768:Metal Nanoparticles / Q000737:chemistry*; D008872:Microwaves; D010165:Palladium / Q000737:chemistry*; D010316:Particle Size; D010984:Platinum / Q000737:chemistry*; D013499:Surface Properties
D000438:Alcohols; D007659:Ketones; D010984:Platinum; D010165:Palladium