title: Removal of Cr (VI) with wheat-residue derived black carbon: reaction mechanism and adsorption performance.
abstract: The removal of Cr (VI) from aqueous solutions using black carbon (BC) isolated from the burning residues of wheat straw was investigated as a function of pH, contact time, reaction temperature, supporting electrolyte concentration and analytical initial Cr (VI) concentration in batch studies. The effect of surface properties on the adsorption behavior of Cr (VI) was investigated with scanning electron microscope (SEM) equipped with the energy dispersive X-ray spectroscope (EDS) and Fourier transform-infrared (FTIR) spectroscopy. The removal mechanism of Cr (VI) onto the BC was investigated and the result showed that the adsorption reaction consumed a large amount of protons along the reduction of Cr (VI) to Cr (III). The oxidation of the BC took place concurrently to the chromium reduction and led to the formation of hydroxyl and carboxyl functions. An initial solution pH of 1.0 was most favorable for Cr (VI) removal. The adsorption process followed the pseudo-second order equation and Freundlich isotherm very well. The Cr (VI) adsorption was temperature-dependent and almost independent on the sodium chloride concentrations. The maximum adsorption capacity for Cr (VI) was found at 21.34 mg/g in an acidic medium, which is comparable to other low-cost adsorbents.
authors.affiliation: Department of Chemical Engineering, Huaihai Institute of Technology, Lianyungang, Jiangsu, 222005, China. snowpine1969@yahoo.com.cn
authors.forename: Xue Song
authors.initials: XS
authors.lastname: Wang
authors.forename: Li Fang
authors.initials: LF
authors.lastname: Chen
authors.forename: Fei Yan
authors.initials: FY
authors.lastname: Li
authors.forename: Kuan Liang
authors.initials: KL
authors.lastname: Chen
authors.forename: Wen Ya
authors.initials: WY
authors.lastname: Wan
authors.forename: Yu Jun
authors.initials: YJ
authors.lastname: Tang
mesh_terms: D000327:Adsorption; D002244:Carbon / Q000737:chemistry*; D002857:Chromium / Q000737:chemistry*; D004573:Electrolytes; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D008855:Microscopy, Electron, Scanning / Q000379:methods; D012965:Sodium Chloride / Q000737:chemistry; D013052:Spectrometry, X-Ray Emission / Q000379:methods; D017550:Spectroscopy, Fourier Transform Infrared / Q000379:methods; D013696:Temperature; D013997:Time Factors; D014908:Triticum / Q000378:metabolism*; D014874:Water Pollutants, Chemical / Q000302:isolation & purification; D018508:Water Purification / Q000379:methods*
chemical_list: D004573:Electrolytes; D014874:Water Pollutants, Chemical; D002857:Chromium; D012965:Sodium Chloride; D002244:Carbon