Reduction of solid-supported olefins and alkynes.
The reduction of carbon-carbon multiple bonds in alkynes and olefins supported on a polystyrene resin has been investigated. Homogeneous catalysis by titanocene reagents is effective for the stereoselective preparation of cis-olefins from diarylacetylenes, while the use of copper(I) hydride reagents is effective for the reduction of alpha,beta-unsaturated ketones.
Dickson
David P
DP
University of Illinois at Chicago Department of Chemistry (MC 111) 845 West Taylor Street, Room 4500 SES, Chicago, Illinois 60607, USA.
Toh
Christine
C
Lunda
Menaka
M
Yermolina
Maria V
MV
Wardrop
Duncan J
DJ
Landrie
Chad L
CL
D000114:Acetylene / Q000031:analogs & derivatives / Q000737:chemistry; D000475:Alkenes / Q000737:chemistry*; D000480:Alkynes / Q000737:chemistry*; D001555:Benzene Derivatives / Q000737:chemistry; D002244:Carbon / Q000737:chemistry; D002384:Catalysis; D003300:Copper / Q000737:chemistry; D007659:Ketones / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry; D011137:Polystyrenes / Q000737:chemistry; D012117:Resins, Synthetic / Q000737:chemistry; D013237:Stereoisomerism; D013696:Temperature
D000475:Alkenes; D000480:Alkynes; D001555:Benzene Derivatives; D007659:Ketones; D009942:Organometallic Compounds; D011137:Polystyrenes; D012117:Resins, Synthetic; C406884:titanocene; D002244:Carbon; D003300:Copper; D000114:Acetylene