title: Spontaneous chiral resolution, nonlinear optical and luminescence of eight-coordinate lanthanide(III) complexes.
abstract: The first eight-coordinated trivalent lanthanide complexes with an achiral ligand 6,7-dicyanodipyridoquinoxaline (dicnq), [DyCl(3)(dicnq)(2)](n) (1 and 1') were found to exhibit spontaneous chiral resolution, SHG active (two times that of KDP) and blue luminescence.
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China.
authors.forename: Hui-Fen
authors.initials: HF
authors.lastname: Chen
authors.forename: Guo-Cong
authors.initials: GC
authors.lastname: Guo
authors.forename: Ming-Sheng
authors.initials: MS
authors.lastname: Wang
authors.forename: Gang
authors.initials: G
authors.lastname: Xu
authors.forename: Wen-Qiang
authors.initials: WQ
authors.lastname: Zou
authors.forename: Sheng-Ping
authors.initials: SP
authors.lastname: Guo
authors.forename: Mei-Feng
authors.initials: MF
authors.lastname: Wu
authors.forename: Jin-Shun
authors.initials: JS
authors.lastname: Huang
mesh_terms: D007811:Lanthanum / Q000737:chemistry*; D008024:Ligands; D049449:Luminescence; D011810:Quinoxalines / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D008024:Ligands; D011810:Quinoxalines; D007811:Lanthanum