title: Supramolecular ordering in oligothiophene-fullerene monolayers.
abstract: Scanning tunneling microscopy (STM) of monolayers comprising oligothiophene and fullerene molecular semiconductors reveals details of their molecular-scale phase separation and ordering with potential implications for the design of organic electronic devices, in particular future bulk heterojunction solar cells. Prochiral terthienobenzenetricarboxylic acid (TTBTA) self-assembles at the solution/graphite interface into either a porous chicken wire network linked by dimeric hydrogen bonding associations of COOH groups (R(2)(2) (8)) or a close-packed network linked in a novel hexameric hydrogen bonding motif (R(6)(6) (24)). Analysis of high-resolution STM images shows that the chicken wire phase is racemically mixed, whereas the close-packed phase is enantiomerically pure. The cavities of the chicken wire structure can efficiently host C60 molecules, which form ordered domains with either one, two, or three fullerenes per cavity. The observed monodisperse filling and long-range co-alignment of fullerenes is described in terms of a combination of an electrostatic effect and the commensurability between the graphite and molecular network, which leads to differentiation of otherwise identical adsorption sites in the pores.
authors.affiliation: INRS-EMT, Université du Québec, 1650 Boulevard Lionel-Boulet, Varennes, Quebec, Canada J3X 1S2.
authors.forename: Jennifer M
authors.initials: JM
authors.lastname: MacLeod
authors.forename: Oleksandr
authors.initials: O
authors.lastname: Ivasenko
authors.forename: Chaoying
authors.initials: C
authors.lastname: Fu
authors.forename: Tyler
authors.initials: T
authors.lastname: Taerum
authors.forename: Federico
authors.initials: F
authors.lastname: Rosei
authors.forename: Dmitrii F
authors.initials: DF
authors.lastname: Perepichka