Borylene-based functionalization of Pt-alkynyl complexes by photochemical borylene transfer from [(OC)(5)Cr=BN(SiMe(3))(2)].
Photochemical borylene transfer from [(OC)(5)Cr=BN(SiMe(3))(2)] to the platinum sigma-alkynyl complex [Cl(PMe(3))(2)Pt-C[triple bond]CPh] gave facile access to the first transition metal-borirene complex. The title compound has been fully characterized in solution and by X-ray crystallography.
Braunschweig
Holger
H
Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany. h.braunschweig@mail.uni-wuerzburg.de
Ye
Qing
Q
Radacki
Krzystof
K