Spontaneous chiral resolution, nonlinear optical and luminescence of eight-coordinate lanthanide(III) complexes.
The first eight-coordinated trivalent lanthanide complexes with an achiral ligand 6,7-dicyanodipyridoquinoxaline (dicnq), [DyCl(3)(dicnq)(2)](n) (1 and 1') were found to exhibit spontaneous chiral resolution, SHG active (two times that of KDP) and blue luminescence.
Chen
Hui-Fen
HF
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China.
Guo
Guo-Cong
GC
Wang
Ming-Sheng
MS
Xu
Gang
G
Zou
Wen-Qiang
WQ
Guo
Sheng-Ping
SP
Wu
Mei-Feng
MF
Huang
Jin-Shun
JS
D007811:Lanthanum / Q000737:chemistry*; D008024:Ligands; D049449:Luminescence; D011810:Quinoxalines / Q000737:chemistry; D013237:Stereoisomerism
D008024:Ligands; D011810:Quinoxalines; D007811:Lanthanum