Influence of bicarbonate and carbonate ions on sonochemical degradation of Rhodamine B in aqueous phase.
The influence of bicarbonate and carbonate ions on sonolytic degradation of cationic dye, Rhodamine B (RhB), in water was investigated. As a consequence of ultrasonic cavitation that generates .OH radicals, carbonate radicals were secondary products of water sonochemistry when it contains dissolved bicarbonate or carbonate ions. The results clearly demonstrated the significant intensification of sonolytic destruction of RhB in the presence of bicarbonate and carbonate, especially at lower dye concentrations. Degradation intensification occurs because carbonate radicals sonochemically formed undergo radical-radical recombination at a lesser extent than hydroxyl radicals. The generated carbonate radicals are likely able to migrate far from the cavitation bubbles towards the solution bulk and are suitable for degradation of an organic dye such as RhB. Therefore, at low dye concentrations, carbonate radical presents a more selective reactivity towards RhB molecules than hydroxyl radical. In the presence of bicarbonate, degradation rate reached a maximum at 3 g L(-1) bicarbonate, but subsequent addition retards the destruction process. In RhB solutions containing carbonate, the oxidation rate gradually increased with increasing carbonate concentration up to 10 g L(-1) and slightly decreased afterward. Carbonate radicals sonochemically generated are suitable for total removal of COD of sonicated RhB solutions.
Merouani
Slimane
S
Laboratory of Environmental Engineering, Department of Process Engineering, Faculty of Engineering, University of Annaba, P.O. Box 12, 23000 Annaba, Algeria.
Hamdaoui
Oualid
O
Saoudi
Fethi
F
Chiha
Mahdi
M
Pétrier
Christian
C
D001639:Bicarbonates / Q000737:chemistry*; D002254:Carbonates / Q000737:chemistry*; D004396:Coloring Agents / Q000737:chemistry; D005947:Glucose / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D017665:Hydroxyl Radical; D007477:Ions / Q000737:chemistry; D007700:Kinetics; D008956:Models, Chemical; D012235:Rhodamines / Q000737:chemistry*; D013431:Sulfates / Q000737:chemistry; D014465:Ultrasonics; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000302:isolation & purification*; D014876:Water Pollution; D018508:Water Purification / Q000379:methods*
D001639:Bicarbonates; D002254:Carbonates; D004396:Coloring Agents; D007477:Ions; D012235:Rhodamines; D013431:Sulfates; D014874:Water Pollutants, Chemical; C012036:sodium sulfate; D017665:Hydroxyl Radical; D005947:Glucose; C029773:rhodamine B