title: An enantiopure pseudo-C3-symmetric titanium triflate with propeller-like chirality as a catalyst for asymmetric sulfoxidation reactions.
abstract: A chiral pseudo-C(3)-symmetric titanium triflate that employs the point chirality of a single stereogenic centre to control the propeller chirality of its aryl rings has been used to catalyse an asymmetric sulfoxidation reaction.
authors.affiliation: Department of Chemistry, University of Bath, UK BA2 7AY.
authors.forename: Philip
authors.initials: P
authors.lastname: Axe
authors.forename: Steven D
authors.initials: SD
authors.lastname: Bull
authors.forename: Matthew G
authors.initials: MG
authors.lastname: Davidson
authors.forename: Matthew D
authors.initials: MD
authors.lastname: Jones
authors.forename: Diane E J E
authors.initials: DE
authors.lastname: Robinson
authors.forename: William L
authors.initials: WL
authors.lastname: Mitchell
authors.forename: John E
authors.initials: JE
authors.lastname: Warren
mesh_terms: D002384:Catalysis; D008698:Mesylates / Q000737:chemistry*; D008968:Molecular Conformation; D013237:Stereoisomerism; D013454:Sulfoxides / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*
chemical_list: D008698:Mesylates; D013454:Sulfoxides; D014025:Titanium; C012077:trifluoromethanesulfonic acid