Asymmetric construction of rings A-D of daphnicyclidin-type alkaloids.
The aza-Cope-Mannich reaction and ring-closing metathesis are key steps in the assembly of intermediates containing rings A-D of Daphniphyllum alkaloids of the daphnicyclidin type such as daphnipaxinin and oldhamine A.
Dunn
Travis B
TB
Department of Chemistry, 1102 Natural Sciences II, University of California, Irvine, California 92697-2025, USA.
Ellis
J Michael
JM
Kofink
Christiane C
CC
Manning
James R
JR
Overman
Larry E
LE
D000470:Alkaloids / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism
D000470:Alkaloids; C493208:daphnipaxinin