Leaching of biocides used in façade coatings under laboratory test conditions.
The European Biocidal Products Directive 98/8/EC requires a risk assessment concerning possible effects of active ingredients on the environment. Biocides can be leached from treated materials exposed to outdoor use. These emissions have to be estimated and evaluated during the authorization procedure. Different immersion and irrigation tests were performed to investigate leaching of biocides from façade coatings. Several marketed formulations of textured coatings and paints spiked with a mixture of commonly used active ingredients (OIT, DCOIT, IPBC, carbendazim, isoproturon, diuron, terbutryn, and Irgarol 1051) were investigated. The emission process can be described by time-dependent functions that depend on the test conditions. The results of all test procedures confirm that leachability is related to water solubility and n-octanol-water partition coefficient of the active ingredients and that leaching of biocides from façade coatings is mainly a diffusion controlled process. Other factors like the composition of the product, availability and transport of water, concentration of active ingredients in the coatings, as well as UV-exposure of the coatings influence biocide emissions.
Schoknecht
Ute
U
BAM Federal Institute for Materials Research and Testing, D-12200 Berlin, Germany. ute.schoknecht@bam.de
Gruycheva
Jana
J
Mathies
Helena
H
Bergmann
Hannelore
H
Burkhardt
Michael
M
D000818:Animals; D003252:Construction Materials; D004202:Disinfectants / Q000737:chemistry / Q000378:metabolism*; D004785:Environmental Pollutants / Q000737:chemistry / Q000378:metabolism*; D006540:Herbicides / Q000737:chemistry / Q000378:metabolism; D008422:Materials Testing; D010150:Paint; D014227:Triazines / Q000737:chemistry / Q000378:metabolism; D014867:Water / Q000737:chemistry
D004202:Disinfectants; D004785:Environmental Pollutants; D006540:Herbicides; D014227:Triazines; D014867:Water; C103341:irgarol 1051; C010347:terbutryne