Synthesis of N-substituted iminosugars from 2'-carbonyl-C-glycofuranosides.
Under basic conditions 2'-carbonyl 5-N-substituted-C-glycofuranosides undergo a tandem beta-elimination and intramolecular hetero-Michael addition to form N-substituted iminosugar derivatives in good to excellent yields.
Luo
Hairong
H
Natural Products Research Center, Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu 610041, China.
Zou
Wei
W
Shao
Huawu
H
D006027:Glycosides / Q000737:chemistry*; D050111:Imino Sugars / Q000138:chemical synthesis*; D055601:Organic Chemistry Phenomena
D006027:Glycosides; D050111:Imino Sugars