title: Why does large relative humidity with respect to ice persist in cirrus ice clouds?
abstract: According to observations, a large relative humidity with respect to ice, RH(i) >> 100%, often persists outside and inside upper tropospheric cirrus ice clouds. The persistence of the large in-cloud RH(i) means that H(2)O is slowly deposited onto cloud ice crystals. This unusual physical situation is similar to one in which a released body would slowly fall owing to gravitation. Here we present a physical mechanism which can be responsible for the persistence of large in-cloud RH(i). We find that clear-sky RH(i) up to 176% can be built up prior to the formation of ice cirrus by the homogeneous freezing of aqueous droplets containing H(2)SO(4) and HNO(3). As the droplets are cooled, a phase separation, which occurs during freezing, leads to the formation of a residual solution coating around the ice crystals formed. The coating can serve as a shield, slowing the rate of ice growth by approximately 10(3) in comparison with uncoated ice, and this can be a reason for the persistence of the large in-cloud RH(i).
authors.affiliation: Department of Physics, P.O. Box 48, University of Helsinki, FIN-00014 Helsinki, Finland.
authors.forename: A
authors.initials: A
authors.lastname: Bogdan
authors.forename: M J
authors.initials: MJ
authors.lastname: Molina