Directed synthesis of mesoporous TiO2 microspheres: catalysts and their photocatalysis for bisphenol A degradation.
This paper describes the fabrication of two different 3D mesoporous TiO2 microspheres via one-step solvothermal process without templates using different titanium sources. The resulting materials were characterized by XRD, FESEM, TEM, and nitrogen adsorption techniques. Their photodegradation of bisphenol A [2,2-bis(4-hydroxyphenyl)propane, BPA] in aqueous suspension was investigated under UV irradiation. The experimental results revealed that the photocatalytic effect of the two 3D mesoporous TiO2 microspheres was superior to the commercial P25 TiO2, and as-prepared samples as catalysts demonstrated that the smaller pore size it is, the higher the effective degradation for BPA is. Particular attention was paid to the identification of intermediates and analysis of photocatalytic degradation mechanism of BPA by HPLC-MS and HPLC-MS-MS. Five main intermediates were formed during photocatalytic degradation, and their evolution was discussed. On the basis of the evidence of oxidative intermediate formation, a detailed degradation pathway of BPA degradation by two mesoporous TiO2 microspheres photocatalysts are proposed.
Guo
Changsheng
C
College of Environmental Science and Engineering and Tianjin Key Laboratory of Environmental Remediation and Pollution Control, Nankai University, Tianjin, PR China 300071.
Ge
Ming
M
Liu
Lu
L
Gao
Guandao
G
Feng
Yinchang
Y
Wang
Yuqiu
Y
D001559:Benzhydryl Compounds; D002384:Catalysis; D008855:Microscopy, Electron, Scanning; D008863:Microspheres; D010636:Phenols / Q000737:chemistry*; D010777:Photochemistry; D014025:Titanium / Q000737:chemistry*; D014961:X-Ray Diffraction; D000098826:Bisphenol A Compounds
D001559:Benzhydryl Compounds; D010636:Phenols; D014025:Titanium; C009495:titanium dioxide; C006780:bisphenol A; D000098826:Bisphenol A Compounds