Concise synthesis of pauciflorol F using a Larock annulation.
A Pd-catalyzed Larock annulation provides expedient access to a subset of resveratrol-derived natural products. The reported approach resulted in the structural revision of an intermediate en route to the natural product pauciflorol F, the total synthesis of which proceeded in two steps from the requisite pentannulation product.
Jeffrey
Jenna L
JL
Department of Chemistry, University of California, Berkeley, California 94720, USA.
Sarpong
Richmond
R
D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry*; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D015394:Molecular Structure; D013237:Stereoisomerism; D013267:Stilbenes / Q000138:chemical synthesis* / Q000737:chemistry
D000475:Alkenes; D013267:Stilbenes; C487911:pauciflorol F