title: One-pot synthesis of indoles and aniline derivatives from nitroarenes under hydrogenation condition with supported gold nanoparticles.
abstract: One-pot sequences of hydrogenation/hydroamination to form indoles from (2-nitroaryl)alkynes and hydrogenation/reductive amination to form aniline derivatives from nitroarenes and aldehydes were catalyzed by Au nanoparticles supported on Fe(2)O(3). Nitro group selective hydrogenations and successive reactions were efficiently catalyzed under the conditions.
authors.affiliation: Department of Chemistry, Graduate School of Science, Kyushu University, Fukuoka 812-8581, Japan.
authors.forename: Yoshihiro
authors.initials: Y
authors.lastname: Yamane
authors.forename: Xiaohao
authors.initials: X
authors.lastname: Liu
authors.forename: Akiyuki
authors.initials: A
authors.lastname: Hamasaki
authors.forename: Tamao
authors.initials: T
authors.lastname: Ishida
authors.forename: Masatake
authors.initials: M
authors.lastname: Haruta
authors.forename: Takushi
authors.initials: T
authors.lastname: Yokoyama
authors.forename: Makoto
authors.initials: M
authors.lastname: Tokunaga
mesh_terms: D000814:Aniline Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D006046:Gold / Q000737:chemistry*; D006865:Hydrogenation; D007211:Indoles / Q000138:chemical synthesis* / Q000737:chemistry; D053768:Metal Nanoparticles / Q000737:chemistry*; D015394:Molecular Structure; D009578:Nitrobenzenes / Q000737:chemistry*; D010316:Particle Size; D013237:Stereoisomerism; D013499:Surface Properties
chemical_list: D000814:Aniline Compounds; D007211:Indoles; D009578:Nitrobenzenes; D006046:Gold; C023650:aniline