title: Diastereoselective control through hydrogen bonding in the aziridination of the chiral allylic alcohols by acetoxyaminoquinazolinone.
abstract: A high diastereoselectivity (up to >99:1) is found for the aziridinations of chiral allylic alcohols with acetoxyaminoquinazolinone (Q-NHOAc). The selectivity is explained in terms of hydrogen bonding between the hydroxy functionality of the allylic alcohol and the remote carbonyl group of the quinazolinone.
authors.affiliation: Faculty of Sciences, Department of Chemistry, Ataturk University, 25240 Erzurum, Turkey.
authors.forename: Murat
authors.initials: M
authors.lastname: Cakici
authors.forename: Semistan
authors.initials: S
authors.lastname: Karabuga
authors.forename: Hamdullah
authors.initials: H
authors.lastname: Kilic
authors.forename: Sabri
authors.initials: S
authors.lastname: Ulukanli
authors.forename: Ertan
authors.initials: E
authors.lastname: Sahin
authors.forename: Fatma
authors.initials: F
authors.lastname: Sevin