Stereodivergent syntheses at the glucose backbone.
Both diastereomers of 2-C-branched carbohydrates with various functional groups are selectively available from the same malonate precursor in good yields in only a few steps.
Yin
Jian
J
Department of Chemistry, University of Potsdam, Karl-Liebknecht Str. 24-25, D-14476 Potsdam/Golm, Germany.
Linker
Torsten
T
D002236:Carbohydrate Conformation; D005947:Glucose / Q000031:analogs & derivatives / Q000138:chemical synthesis* / Q000737:chemistry*; D013237:Stereoisomerism
D005947:Glucose