title: Synthesis of carbamates from diethoxycarbonyl hydrazine derivatives by E1cB eliminative cleavage of the N-N'-bond rather than reduction.
abstract: Treatment of diethoxycarbonyl hydrazine derivatives with methyl bromoacetate/Cs(2)CO(3)/MeCN at 50 degrees C followed by heating to 80 degrees C resulted in N-N' bond cleavage to the corresponding carbamates.
authors.affiliation: Department of Chemistry and Biochemistry, University of Texas at Austin, 1 University Station A5300, Austin, Texas 78712-1167, USA. p.magnus@mail.utexas.edu
authors.forename: Philip
authors.initials: P
authors.lastname: Magnus
authors.forename: Negar
authors.initials: N
authors.lastname: Garizi
authors.forename: Kimberly A
authors.initials: KA
authors.lastname: Seibert
authors.forename: Alexandra
authors.initials: A
authors.lastname: Ornholt