Reactive conducting thiepin polymers.
We report the design and synthesis of annulated thiepins designed to undergo bent-to-planar transformation driven by aromatization under electrochemical control. Thiepins are conjugated seven-membered ring systems with a thioether in the macrocycle. We synthesized thermally stable thiepins that are electropolymerizable to give rise to thiepin-containing electroactive polymers. Extended thiepin systems undergo sulfur extrusion with oxidation, and this feature has utility in peroxide sensing.
Song
Changsik
C
Department of Chemistry and Institute for Soldier Nanotechnologies, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.
Swager
Timothy M
TM