title: High-resolution inventory of NO emissions from agricultural soils over the Ile-de-France region.
abstract: Arable soils are a significant source of nitric oxide (NO), a precursor of tropospheric ozone, and thereby contribute to ozone pollution. However, their actual impact on ozone formation is strongly related to their spatial and temporal emission patterns, which warrant high-resolution estimates. Here, we combined an agro-ecosystem model and geo-referenced databases to map these sources over the 12,000 km2 administrative region surrounding Paris, France, with a kilometric level resolution. The six most frequent arable crop species were simulated, with emission rates ranging from 1.4 kg N-NO ha(-1) yr(-1) to 11.1 kg N-NO ha(-1) yr(-1). The overall emission factor for fertilizer-derived NO emissions was 1.7%, while background emissions contributed half of the total NO efflux. Emissions were strongly seasonal, being highest in spring due to fertilizer inputs. They were mostly sensitive to soil type, crops' growing season and fertilizer N rates.
authors.affiliation: INRA, AgroParisTech, UMR 1091 Environnement et Grandes Cultures, F-78850 Grignon, France.
authors.forename: M-N
authors.initials: MN
authors.lastname: Rolland
authors.forename: B
authors.initials: B
authors.lastname: Gabrielle
authors.forename: P
authors.initials: P
authors.lastname: Laville
authors.forename: P
authors.initials: P
authors.lastname: Cellier
authors.forename: M
authors.initials: M
authors.lastname: Beekmann
authors.forename: J-M
authors.initials: JM
authors.lastname: Gilliot
authors.forename: J
authors.initials: J
authors.lastname: Michelin
authors.forename: D
authors.initials: D
authors.lastname: Hadjar
authors.forename: G
authors.initials: G
authors.lastname: Curci
mesh_terms: D018556:Crops, Agricultural / Q000254:growth & development; D004784:Environmental Monitoring; D005602:France; D008954:Models, Biological; D009569:Nitric Oxide / Q000737:chemistry*; D012621:Seasons; D012987:Soil / Q000032:analysis; D012989:Soil Pollutants / Q000737:chemistry*
chemical_list: D012987:Soil; D012989:Soil Pollutants; D009569:Nitric Oxide