Silver-catalysed protodecarboxylation of carboxylic acids.
A silver-based catalyst system has been discovered that effectively promotes the protodecarboxylation of various carboxylic acids at temperatures of 80-120 degrees C--more than 50 degrees C below those of the best known copper catalysts.
Goossen
Lukas J
LJ
FB Chemie-Organische Chemie, TU Kaiserslautern, Erwin-Schroedinger-Strasse, Geb. 54, 67663, Kaiserslautern, Germany. goossen@chemie.uni-kl.de
Linder
Christophe
C
Rodríguez
Nuria
N
Lange
Paul P
PP
Fromm
Andreas
A
D002264:Carboxylic Acids / Q000737:chemistry* / Q000528:radiation effects; D002384:Catalysis / Q000528:radiation effects*; D003653:Decarboxylation / Q000187:drug effects / Q000528:radiation effects*; D055668:Photochemical Processes; D012834:Silver / Q000737:chemistry*; D013696:Temperature
D002264:Carboxylic Acids; D012834:Silver