title: H2S(g) removal using a modified, low-ph liquid redox sulfur recovery (LRSR) process with electrochemical regeneration of the Fe catalyst couple.
abstract: A modified pH 1.0 liquid redox sulfur recovery (LRSR) process, based on reactive absorption of H(2)S((g)) in an acidic (pH 1.0) iron solution ([Fe(III)] = 9-8 g L(-1), [Fe(II)] = 1-2 g L(-1)) and electrochemical regeneration of the Fe(III)/Fe(II) catalyst couple, is introduced. Fe(II) was oxidized in a flow-through electrolytic cell by Cl(2(aq)) formed on a Ti/RuO(2) anode. pH 1.0 was applied to retard the potential precipitation of predominantly jarosite group Fe(III) species. At pH 1.0, the presence of chloride ions at [Cl(-)] = 30 g L(-1) allows for both efficient (indirect) electrochemical oxidation of Fe(II) and efficient H(2)S((g)) reactive absorption. The latter observation was hypothesized to be associated with higher concentrations of Fe(III)-Cl complexes that are more highly reactive toward H(2)S((aq)) than are free Fe(III) ions and Fe-SO(4) complexes that otherwise dominate pH 1.0 Fe(III) solutions in the absence of a significant Cl(-) concentration. At the described operational conditions the rate of Fe(II) oxidation in the experimental system was 0.793 kg Fe h(-1) per m(2) anode surface area, at a current efficiency of 58%. Electricity cost within the electrochemical step was approximated at $0.9 per kg H(2)S((g)) removed.
authors.affiliation: Faculty of Civil and Environmental Engineering, Technion, Haifa, 32000, Israel.
authors.forename: Youri
authors.initials: Y
authors.lastname: Gendel
authors.forename: No'omi
authors.initials: N
authors.lastname: Levi
authors.forename: Ori
authors.initials: O
authors.lastname: Lahav
mesh_terms: D000042:Absorption; D002384:Catalysis; D011232:Chemical Precipitation; D002712:Chlorides / Q000737:chemistry; D004560:Electricity; D055664:Electrochemical Techniques / Q000379:methods*; D004572:Electrolysis; D006862:Hydrogen Sulfide / Q000302:isolation & purification*; D006863:Hydrogen-Ion Concentration; D007501:Iron / Q000737:chemistry*; D007700:Kinetics; D010084:Oxidation-Reduction; D012995:Solubility; D012996:Solutions; D013455:Sulfur / Q000737:chemistry*; D013997:Time Factors
chemical_list: D002712:Chlorides; D012996:Solutions; D013455:Sulfur; D007501:Iron; D006862:Hydrogen Sulfide