Characterization of organic matter from composting of different residues by physicochemical and spectroscopic methods.
Chemical and spectroscopic methods were used to characterize organic matter transformations during the composting process. Four different residue mixtures were studied: P1--garden trimmings (GT) only, P2 - GT plus fresh cattle manure, P3--GT plus orange pomace and P4--GT plus filter cake. The thermophilic phase was not reached in P1 compost, but the P2, P3 and P4 composts showed all three typical process phases. The thermophilic phase and CEC/C ratio stabilized after 90 days, while C/N ratio and the ash content stabilized after 60 days. The increasing E(4)/E(6) ratio indicated oxidation reactions occurring during the process in the material from P2, P3 and P4. The (13)C NMR and FTIR results suggested extraction of both pectin and lignin in the HA-like fraction. The CEC/C ratio, temperature and E(4)/E(6) ratio showed that within 90 days P2, P3 and P4 composts were humified. However, material from P1 did not show characteristics of humified compost. From these data, it is apparent that C/N ratio and ash content are not reliable methods for monitoring the composting process.
Fialho
Lucimar Lopes
LL
Embrapa Instrumentação Agropecuária, Rua XV de Novembro, 1452 PO Box 741, 13560-970 São Carlos, SP, Brazil.
Lopes da Silva
Wilson Tadeu
WT
Milori
Débora M B P
DM
Simões
Marcelo Luiz
ML
Martin-Neto
Ladislau
L
D000818:Animals; D002244:Carbon / Q000737:chemistry; D002412:Cations; D002417:Cattle; D002627:Chemistry, Physical / Q000379:methods; D006812:Humic Substances; D006863:Hydrogen-Ion Concentration; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D009584:Nitrogen / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry; D012987:Soil; D013053:Spectrophotometry / Q000379:methods*; D013056:Spectrophotometry, Ultraviolet / Q000379:methods; D017550:Spectroscopy, Fourier Transform Infrared / Q000379:methods; D013696:Temperature
D002412:Cations; D006812:Humic Substances; D012987:Soil; D002244:Carbon; D009584:Nitrogen; D010100:Oxygen