Excited-state dynamics of the 2-hydroxypyridine-ammonia complex.
The excited-state lifetimes of different vibrational levels of the 2-hydroxypyridine-ammonia complex have been recorded with the picosecond pump probe technique. These lifetimes decrease with increasing energy. The decrease of the lifetime is discussed based on the possible enol keto isomerization computed using RI-CC2 methods.
Esboui
M
M
Laboratoire de Spectroscopie Atomique, Moléculaire et Applications, Département de Physique, Faculté des Sciences de Tunis, 1060 Tunis, Tunisia.
Jouvet
C
C
Dedonder
C
C
Ebata
T
T
D000641:Ammonia / Q000737:chemistry*; D003198:Computer Simulation; D011728:Pyridones / Q000737:chemistry*; D011789:Quantum Theory; D014732:Vibration
D011728:Pyridones; C017679:2-hydroxypyridine; D000641:Ammonia