title: Iron-catalyzed redox radical cyclizations of 1,6-dienes and enynes.
abstract: Treatment of 1,6-dienes and enynes with FeCl(3) or Fe(Pc) in the presence of NaBH(4) and air or O(2) causes radical cyclization to give five-membered carbo or heterocyclic compounds, into which a halogen atom or hydroxyl group was introduced.
authors: School of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan.
authors: Tsuyoshi
authors: T
authors: Taniguchi
authors: Naoya
authors: N
authors: Goto
authors: Asami
authors: A
authors: Nishibata
authors: Hiroyuki
authors: H
authors: Ishibashi
mesh_terms: D002384:Catalysis; D002712:Chlorides; D003500:Cyclization; D005290:Ferric Compounds / Q000737:chemistry; D006571:Heterocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D007501:Iron / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D011090:Polyenes / Q000737:chemistry*
chemical_list: D002712:Chlorides; D005290:Ferric Compounds; D006571:Heterocyclic Compounds; D011090:Polyenes; D007501:Iron; C024555:ferric chloride