Intramolecular alkynylcyclopropanation of olefins catalyzed by Bi(OTf)3: stereoselective synthesis of 1-alkynyl-3-azabicyclo[3.1.0]hexanes.
Komeyama
Kimihiro
K
Department of Chemistry and Chemical Engineering, Graduate School of Engineering, Hiroshima University, Kagamiyama, Higashi-Hiroshima 739-8527, Japan. kkome@hiroshima-u.ac.jp
Saigo
Natsuko
N
Miyagi
Motoyoshi
M
Takaki
Ken
K
D000475:Alkenes / Q000737:chemistry*; D001729:Bismuth / Q000737:chemistry*; D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000138:chemical synthesis / Q000737:chemistry*; D002384:Catalysis; D018360:Crystallography, X-Ray; D003521:Cyclopropanes / Q000737:chemistry*; D006586:Hexanes / Q000138:chemical synthesis / Q000737:chemistry*; D008697:Methane / Q000031:analogs & derivatives / Q000737:chemistry; D008968:Molecular Conformation; D013237:Stereoisomerism; D013438:Sulfhydryl Compounds / Q000737:chemistry*
C532932:3-azabicyclo(3.1.0)hexane; D000475:Alkenes; D019086:Bridged Bicyclo Compounds, Heterocyclic; D003521:Cyclopropanes; D006586:Hexanes; D013438:Sulfhydryl Compounds; C030011:carbene; C030797:cyclopropane; D008697:Methane; D001729:Bismuth