Steam reforming of crude glycerol with in situ CO(2) sorption.
Steam reforming of the crude glycerol by-product of a biodiesel production plant has been evaluated experimentally at atmospheric pressure, with and without in situ CO(2) sorption, in a continuous flow fixed-bed reactor between 400 degrees C and 700 degrees C. The process outputs were compared to those using pure glycerol. Thermodynamic equilibrium calculations were used to assess the effect on the steam reforming process of the main crude impurities (methanol and four fatty acid methyl esters). The crude glycerol and steam conversions and the H(2) purity reached 100%, 11% and 68%, respectively at 600 degrees C. No CH(4) was found at and above 600 degrees C. Steam reforming of crude glycerol with in situ CO(2) removal is shown to be an effective means of achieving hydrogen purity above 88% in pre-CO(2) breakthrough conditions.
Dou
Binlin
B
School of Process, Environmental and Materials Engineering, University of Leeds, Leeds LS2 9JT, UK.
Rickett
Gavin L
GL
Dupont
Valerie
V
Williams
Paul T
PT
Chen
Haisheng
H
Ding
Yulong
Y
Ghadiri
Mojtaba
M
D000327:Adsorption; D002245:Carbon Dioxide / Q000737:chemistry*; D002248:Carbon Monoxide / Q000032:analysis; D002849:Chromatography, Gas; D005990:Glycerol / Q000737:chemistry*; D006859:Hydrogen / Q000032:analysis; D008697:Methane / Q000032:analysis; D008956:Models, Chemical; D013227:Steam; D013816:Thermodynamics
D013227:Steam; D002245:Carbon Dioxide; D002248:Carbon Monoxide; D006859:Hydrogen; D008697:Methane; D005990:Glycerol