Potential/charge induced nanoporous metal actuators.
The mechanical response to the electrochemical charging of nanoporous metals with their pore space wetted by electrolyte have been studied in-situ using dilatometry and wide angle x-ray diffractometry techniques. The actuation strain reported in this manuscript is purely elastic and completely reversible. The capacitive double layer charging became more effective near to the potential to zero charge (pzc) and contribute significantly to the variations of surface stress and crystal strain. In a suitable experimental setup, the actuator effect from porous metals can be amplified, where deliberate movements of the actuator parts are desirable with minimum external force, suggesting that metallic foam-like materials with high surface to volume ratio could be used to mimic natural muscles.
Viswanath
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Institut für Nanotechnologie Karlsruhe, Germany. Raghavan.Viswanath@int.fzk.de
D020811:Biomedical Technology / Q000295:instrumentation*; D004560:Electricity; D004563:Electrochemistry; D004573:Electrolytes / Q000737:chemistry; D008670:Metals / Q000737:chemistry*; D008904:Miniaturization; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure; D016062:Porosity; D013314:Stress, Mechanical; D013499:Surface Properties; D014961:X-Ray Diffraction
D004573:Electrolytes; D008670:Metals