Mirror symmetry breaking of silicon polymers--from weak bosons to artificial helix.
From elemental particles to human beings, matter and living worlds in our universe are dissymmetric with respect to mirror symmetry. Since the early 19th century, the origin of biomolecular handedness has been puzzling scientists. Nature's elegant bottom-up preference, however, sheds light on new concepts of generating, amplifying, and switching artificial polymers, supramolecules, liquid crystals, and organic crystals that can exhibit ambidextrous circular dichroism in the UV/Visible region with efficiency in production under milder ambient conditions. In the 1920s, Kipping, who first synthesized polysilanes with phenyl groups, had much interest in the handedness of inorganic and organic substances from 1898 to 1909 in his early research life. Polysilanes--which are soluble Si-Si bonded chain-like near-UV chromophores that carry a rich variety of organic groups--may become a bridge between animate and inanimate polymer systems. The present account focuses on several mirror symmetry breaking phenomena exemplified in polysilanes carrying chiral and/or achiral side groups, which are in isotropic dilute solution, as polymer particles dispersed in solution, and in a double layer film immobilized at the solid surface, and subtle differences in the helix, by dictating ultimately ultraweak chiral forces at subatomic, atomic, and molecular levels.
Fujiki
Michiya
M
Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara 630-0036, Japan. fujikim@ms.naist.jp
D000818:Animals; D019149:Bioreactors; D002942:Circular Dichroism / Q000379:methods; D003460:Crystallization; D006801:Humans; D008027:Light; D008956:Models, Chemical; D036103:Nanotechnology / Q000379:methods; D010316:Particle Size; D010777:Photochemistry; D011108:Polymers / Q000737:chemistry*; D012825:Silicon / Q000737:chemistry*
D011108:Polymers; D012825:Silicon