Thermokinetic study of the rehydration process of a calcined MgAl-layered double hydroxide.
The rehydration process of a calcined MgAl-layered double hydroxide (LDH) with a Mg/Al molar ratio of 3 was systematically analyzed at different temperatures and relative humidity. Qualitative and quantitative experiments were done. In the first set of samples, the temperature or the relative humidity was varied, fixing the second variable. Both adsorption and absorption phenomena were present; absorption process was associated to the LDH regeneration. Of course, in all cases the LDH regeneration was confirmed by other techniques such as TGA, solid state NMR, and SAXS. In the second set of experiments, a kinetic analysis was performed, the results allowed to obtain different activation enthalpies for the LDH regeneration as a function of the relative humidity. The activation enthalpies varied from 137.6 to 83.3 kJ/mol as a function of the relative humidity (50 and 80%, respectively). All these experiments showed that LDH regeneration is highly dependent on the temperature and relative humidity.
Pfeiffer
Heriberto
H
Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito exterior s/n, Cd. Universitaria, CP 04510, México DF, Mexico.
Lima
Enrique
E
Lara
Víctor
V
Valente
Jaime S
JS