Pd-catalyzed synthesis of allylic silanes from allylic ethers.
Allylic phenyl ethers serve as electrophiles toward Pd(0) en route to a variety of allylic silanes. The reactions can be run at room temperature in water as the only medium using micellar catalysis.
Moser
Ralph
R
Department of Chemistry & Biochemistry, University of California, Santa Barbara, California 93106, USA.
Nishikata
Takashi
T
Lipshutz
Bruce H
BH
D000498:Allyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D004987:Ethers / Q000737:chemistry*; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D010647:Phenyl Ethers / Q000138:chemical synthesis* / Q000737:chemistry; D012821:Silanes / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D000498:Allyl Compounds; D004987:Ethers; D010647:Phenyl Ethers; D012821:Silanes; C076695:phenyl allyl ether; D010165:Palladium