2D ultrafast HMBC: a valuable tool for monitoring organic reactions.
Ultrafast 2D HMBC spectroscopy permits real-time monitoring of a reaction based on the structural changes produced in a carbonyl carbon atom. This new technique was used to study the reaction of ketones, nitriles, and Tf(2)O, affording relevant information about new intermediates and kinetic data.
Herrera
Antonio
A
Departamento de Química Orgánica and CAI de RMN Facultad de Químicas, Universidad Complutense de Madrid, 28040 Madrid, Spain. aherrera@quim.ucm.es
Fernández-Valle
Encarnación
E
Gutiérrez
Eva M
EM
Martínez-Alvarez
Roberto
R
Molero
Dolores
D
Pardo
Zulay D
ZD
Sáez
Elena
E