An undecanuclear Fe(III) single-molecule magnet.
The undecanuclear complex in [Fe(III)(11)(mu(4)-O)(3)(mu(3)-O)(4)(L)(3)(mu-O(2)CCMe(3))(12)]Cl.5MeCN has been synthesized and characterized by single-crystal X-ray crystallography. Mossbauer spectroscopy and bulk susceptibility studies reveal that the complex has an S = (13)/(2) spin ground state and exhibits single-molecule-magnet behavior.
Ako
Ayuk M
AM
Institut für Anorganische Chemie der Universität Karlsruhe, Engesserstrasse 15, Geb. 30.45, D-76131 Karlsruhe, Germany.
Mereacre
Valeriu
V
Lan
Yanhua
Y
Wernsdorfer
Wolfgang
W
Clérac
Rodolphe
R
Anson
Christopher E
CE
Powell
Annie K
AK