title: Steric decompression of picket-strapped porphyrins for the synthesis of side-differentiated chelates.
abstract: A general method to synthesize various alphabeta alphabeta bis-strapped porphyrins, with a different functionalization on each side of the macrocycle, is described. The resulting new chelates may find applications as analogues of heme protein active sites, bifunctional chelates, or specific bis-chelating molecules with potential medical utility.
authors: Université de Rennes1-Sciences Chimiques de Rennes, UMR CNRS 6226 (I.C.M.V.), 35042 Rennes, France.
authors: S
authors: S
authors: Balieu
authors: I
authors: I
authors: Hijazi
authors: N
authors: N
authors: Motreff
authors: F
authors: F
authors: Lachaud
authors: P
authors: P
authors: Even-Hernandez
authors: B
authors: B
authors: Boitrel
mesh_terms: D001665:Binding Sites; D002614:Chelating Agents / Q000138:chemical synthesis* / Q000737:chemistry; D006420:Hemeproteins / Q000187:drug effects; D008665:Metalloporphyrins / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D002614:Chelating Agents; D006420:Hemeproteins; D008665:Metalloporphyrins