The corrected structure of rosmaridiphenol, a bioactive diterpene from Rosmarinus officinalis.
From the aerial parts of a Chilean sample of Rosmarinus officinalis L., a diterpene was isolated whose spectroscopic data and physical constants were coincident with that of rosmaridiphenol. However, careful examination of the spectroscopic data and chemical reactions led to a different structure, where the carbonyl function has to be placed at C-1 instead of C-20. The correct structure of rosmaridiphenol should therefore be changed to 11,12-dihydroxy-8,11,13-icetexatrien-1-one.
Pertino
Mariano Walter
MW
Laboratorio de Química de Productos Naturales, Instituto de Química de Recursos Naturales, Universidad de Talca, Talca, Chile.
Schmeda-Hirschmann
Guillermo
G
D004224:Diterpenes / Q000737:chemistry*; D015394:Molecular Structure; D035261:Plant Components, Aerial / Q000737:chemistry; D027542:Rosmarinus / Q000737:chemistry*
D004224:Diterpenes; C550800:rosmaridiphenol