Utilization of rice husk ash as silica source for the synthesis of mesoporous silicas and their application to CO2 adsorption through TREN/TEPA grafting.
Mesoporous MCM-41, MCM-48 and SBA-15 were synthesized using Rice husk ash (RHA) as the silica source and their defective Si-OH sites were functionalized by 3-chloropropyltrimethoxysilane (CPTMS) which was subsequently grafted with amine compounds, Tris(2-aminoethyl)amine (TREN) and Tetraethylenepentamine (TEPA). X-ray powder diffraction (XRD) and BET results of the parent mesoporous silica suggested their closeness of structural properties to those obtained from conventional silica sources. CO(2) adsorption of branched amine TREN and straight chain amine TEPA at 25, 50 and 75 degrees C was obtained by Thermogravimetric Analyser (TGA) at atmospheric pressure. TREN grafted mesoporous silica showed 7% of CO(2) adsorption while TEPA grafted mesoporous silicas showed less CO(2) adsorption, which is due to the presence of isolated amine groups in TREN. TREN grafted mesoporous silicas were also observed to be selective towards CO(2), thermally stable and recyclable. The order of CO(2) adsorption with respect to amount of amine grafting was observed to be MCM-48/TREN>MCM-41/TREN>SBA-15/TREN.
Bhagiyalakshmi
Margandan
M
Chemical Engineering Department, Hanseo University, Seosan 360-706, South Korea.
Yun
Lee Ji
LJ
Anuradha
Ramani
R
Jang
Hyun Tae
HT
D000327:Adsorption; D000588:Amines / Q000737:chemistry; D002245:Carbon Dioxide / Q000737:chemistry*; D005029:Ethylenediamines / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008956:Models, Chemical; D009584:Nitrogen / Q000737:chemistry; D012275:Oryza / Q000378:metabolism*; D016062:Porosity; D012821:Silanes / Q000737:chemistry*; D012822:Silicon Dioxide / Q000737:chemistry*; D013696:Temperature; D013818:Thermogravimetry / Q000379:methods; D014961:X-Ray Diffraction
C548971:3-chloropropyltrimethoxysilane; D000588:Amines; D005029:Ethylenediamines; D012821:Silanes; D002245:Carbon Dioxide; C099539:tris(2-aminoethyl)amine; D012822:Silicon Dioxide; D009584:Nitrogen; C071717:trimethoxysilane; C034269:tetraethylenepentamine