Rapid gas chromatographic analysis of less abundant compounds in distilled spirits by direct injection with ethanol-water venting and mass spectrometric data deconvolution.
The principal trace secondary compounds common to fermentation-derived distilled spirits can be rapidly quantified by directly injecting 5muL of spirit without sample preparation to a narrow-bore 0.15mm internal diameter capillary column. The ethanol-water is removed in an initial solvent venting step using a programmed temperature vapourization injector, followed by splitless transfer of the target analytes to the column. The larger injection facilitates trace analysis and ethanol-water removal extends column lifetime. Problems of coelution between analytes or with sample matrix were surmounted by using mass spectral deconvolution software for quantification. All operations in the analysis from injection with solvent venting to data reduction are fully automated for unattended sequential sample analysis. The synergy of the various contributory steps combines to offer an effective novel solution for this analysis. Applications include quantification of low ppm amounts of acids and esters and sub-ppm profiling of trace compounds from both the raw material malt and the ageing in wood barrels.
Macnamara
Kevin
K
Irish Distillers-Pernod Ricard, Midleton Distillery, Midleton, Co. Cork, Ireland. kevin.macnamara@idl.ie
Lee
Michelle
M
Robbat
Albert
A
D000434:Alcoholic Beverages / Q000032:analysis*; D002849:Chromatography, Gas / Q000295:instrumentation / Q000379:methods*; D057168:Distillation; D000431:Ethanol / Q000737:chemistry; D014867:Water / Q000737:chemistry
D014867:Water; D000431:Ethanol