Stereoisomerically pure trisubstituted vinylaluminum reagents and their utility in copper-catalyzed enantioselective synthesis of 1,4-dienes containing Z or E alkenes.
Akiyama
Katsuhiro
K
Department of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02467, USA.
Gao
Fang
F
Hoveyda
Amir H
AH
D000475:Alkenes / Q000138:chemical synthesis*; D000478:Alkylation; D017607:Aluminum Compounds / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D007202:Indicators and Reagents; D009682:Magnetic Resonance Spectroscopy; D013237:Stereoisomerism; D014753:Vinyl Compounds / Q000032:analysis*
D000475:Alkenes; D017607:Aluminum Compounds; D007202:Indicators and Reagents; D014753:Vinyl Compounds; D003300:Copper