Ring-rearrangement metathesis of cyclopropenes: synthesis of heterocycles.
Cyclopropenes substituted by an unsaturated side chain have been successfully involved in ring-rearrangement metatheses leading to heterocyclic compounds, thereby expanding the synthetic potential of metathesis reactions with this class of highly strained cycloalkenes.
Miege
Frédéric
F
Laboratoire de Chimie Organique, ESPCI ParisTech, CNRS, 10 rue Vauquelin, 75231 Paris Cedex 05, France.
Meyer
Christophe
C
Cossy
Janine
J
D003500:Cyclization; D003521:Cyclopropanes / Q000138:chemical synthesis* / Q000737:chemistry; D006571:Heterocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D013237:Stereoisomerism
D003521:Cyclopropanes; D006571:Heterocyclic Compounds; C021985:cyclopropene