[Effects of several low-molecular-weight organic acids on the release kinetic of endosulfan from red soil].
The kinetic release behaviors of a-endosulfan from red soil with three kinds of low-molecular-weight organic acids (LMWOA: oxalate, tartrate and citrate) solution and water leaching were investigated by kinetic device designed by ourselves and batch method. The results show that: the release percentage of endosulfan from red soil by tartrate and citrate solution (10 mmol/L) can increase by 7%-18% more than that by distilled water and oxalate solution, especially for tartrate solution. There is no significant difference between distilled water and oxalate solution for the release percentage of endosulfan (p > 0.05). There are two stages of quick and slow for the release of endosulfan from red soil, and the leaching speed is quicker especially for the initial 200 mL leaching solution. When using distilled water or oxalate solution as leaching solution, the best equations that described the kinetic release behavior of endosulfan from red soil were parabola diffuse equation and double constant equation, and weren't the apparent first dynamics equation that represented the simple surface diffusion mechanism. The kinetic release behavior of endosulfan in tartrate or citrate leaching system can be described by Elovich equation (R2 > 0.99, p < 0.0001), it implied that the simple surface diffusion mechanism is not the primary factor that effected the release of endosulfan, which three-dimensional molecule structure is complex, from red soil in aqueous phase leaching systems, and it maybe related to the outward diffuse mechanism from soil particle, activation and deactivation function of soil particles surface, the dissolution of soil mineral surface and structure change of inherent organic matter that coating onto the soil mineral surface induced by LMW organic acid. It suggested that the tartrate and citrate induced the complication of the release mechanisms of the pesticides from red soil.
Zhao
Zhen-hua
ZH
Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes, Ministry of Education, Hohai University, Nanjing 210098, China. zzh4000@126.com
Wu
Yu
Y
Jiang
Xin
X
Xia
Li-ling
LL
Ni
Li-xiao
LX
D000143:Acids / Q000737:chemistry*; D004726:Endosulfan / Q000737:chemistry* / Q000378:metabolism; D007306:Insecticides / Q000737:chemistry / Q000378:metabolism; D007700:Kinetics; D008970:Molecular Weight; D009930:Organic Chemicals / Q000737:chemistry*; D012987:Soil / Q000032:analysis*; D012989:Soil Pollutants / Q000737:chemistry* / Q000378:metabolism
D000143:Acids; D007306:Insecticides; D009930:Organic Chemicals; D012987:Soil; D012989:Soil Pollutants; D004726:Endosulfan