Facile synthesis of sulfonyl amidines via carbon-nitrogen bond formation mediated by FeCl3.
A facile synthesis of sulfonyl amidines via carbon-nitrogen bond formation mediated by FeCl(3) was developed and an interesting major product of cyclic tertiary amine was observed, which showed the good selectivity of FeCl(3)-mediated activation of cyclic alpha-C-H bonds of cyclic tertiary amines.
Wang
Sujing
S
Hefei National Laboratory for Physical Science at the Microscale, Joint-lab of Green Synthetic Chemistry and Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. China.
Wang
Zhiyong
Z
Zheng
Xiaoqi
X
D000578:Amidines / Q000138:chemical synthesis*; D002244:Carbon / Q000737:chemistry*; D002712:Chlorides; D005290:Ferric Compounds / Q000737:chemistry*; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry*; D013457:Sulfur Compounds / Q000138:chemical synthesis*
D000578:Amidines; D002712:Chlorides; D005290:Ferric Compounds; D013457:Sulfur Compounds; D002244:Carbon; D009584:Nitrogen; C024555:ferric chloride