title: Chiral bifunctional phase transfer catalysts for asymmetric fluorination of beta-keto esters.
abstract: Chiral bifunctional phase transfer catalysts introducing bis(diarylhydroxymethyl) substituents at 3,3'-positions of the chiral binaphthyl core were successfully applied to asymmetric fluorination of cyclic beta-keto esters with high enantioselectivities.
authors.affiliation: Laboratory of Synthetic Organic Chemistry, Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, 606-8502, Japan.
authors.forename: Xisheng
authors.initials: X
authors.lastname: Wang
authors.forename: Quan
authors.initials: Q
authors.lastname: Lan
authors.forename: Seiji
authors.initials: S
authors.lastname: Shirakawa
authors.forename: Keiji
authors.initials: K
authors.lastname: Maruoka
mesh_terms: D002384:Catalysis; D018360:Crystallography, X-Ray; D004952:Esters; D054879:Halogenation; D008968:Molecular Conformation; D009281:Naphthalenes / Q000737:chemistry*; D044367:Phase Transition; D013237:Stereoisomerism
chemical_list: D004952:Esters; D009281:Naphthalenes; C031721:naphthalene