title: Comparison of toluene removal in air at atmospheric conditions by different corona discharges.
abstract: Different types of corona discharges, produced by DC of either polarity (+/-DC) and positive pulsed (+pulsed) high voltages, were applied to the removal of toluene via oxidation in air at room temperature and atmospheric pressure. Mechanistic insight was obtained through comparison of the three different corona regimes with regard to process efficiency, products, response to the presence of humidity and, for DC coronas, current/voltage characteristics coupled with ion analysis. Process efficiency increases in the order +DC < -DC < +pulsed, with pulsed processing being remarkably efficient compared to recently reported data for related systems. With -DC, high toluene conversion and product selectivity were achieved, CO(2) and CO accounting for about 90% of all reacted carbon. Ion analysis, performed by APCI-MS (Atmospheric Pressure Chemical Ionization-Mass Spectrometry), provides a powerful rationale for interpreting current/voltage characteristics of DC coronas. All experimental findings are consistent with the proposal that in the case of +DC corona toluene oxidation is initiated by reactions with ions (O(2)(+*), H(3)O(+) and their hydrates, NO(+)) both in dry as well as in humid air. In contrast, with -DC no evidence is found for any significant reaction of toluene with negative ions. It is also concluded that in humid air OH radicals are involved in the initial stage of toluene oxidation induced both by -DC and +pulsed corona.
authors.affiliation: Department of Chemical Sciences, Universita di Padova, 35131 Padova, Italy.
authors.forename: Milko
authors.initials: M
authors.lastname: Schiorlin
authors.forename: Ester
authors.initials: E
authors.lastname: Marotta
authors.forename: Massimo
authors.initials: M
authors.lastname: Rea
authors.forename: Cristina
authors.initials: C
authors.lastname: Paradisi
mesh_terms: D000388:Air; D001274:Atmospheric Pressure; D002245:Carbon Dioxide / Q000737:chemistry; D002248:Carbon Monoxide / Q000737:chemistry; D004563:Electrochemistry / Q000379:methods*; D006813:Humidity; D010084:Oxidation-Reduction; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature; D014050:Toluene / Q000737:chemistry; D055549:Volatile Organic Compounds / Q000737:chemistry
chemical_list: D055549:Volatile Organic Compounds; D002245:Carbon Dioxide; D014050:Toluene; D002248:Carbon Monoxide