Synthesis of spiro compounds through tandem oxidative coupling and a framework rearrangement reaction.
A highly efficient oxidative coupling of 2-naphthols and a rearrangement tandem reaction to afford unique spiro compounds in the presence of FeCl(3).6H(2)O in up to 88% yield have been developed.
Sue
Daisuke
D
Institute for Chemical Research, Kyoto University, Uji, Kyoto, 611-0011, Japan.
Kawabata
Takeo
T
Sasamori
Takahiro
T
Tokitoh
Nobuhiro
N
Tsubaki
Kazunori
K
D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D009284:Naphthols / Q000737:chemistry; D010084:Oxidation-Reduction; D013141:Spiro Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D009284:Naphthols; D013141:Spiro Compounds; C028405:2-naphthol