title: Characterization and mechanistic analysis of the visible light response of cerium and nitrogen co-doped TiO2 nano-photocatalyst synthesized using a one-step technique.
abstract: Cerium and nitrogen co-doped anatase TiO(2) nanoparticles were synthesized using a one-step technique via a modified sol-gel process and characterized by XRD, BET, DRS, Raman and XPS. The photocatalytic mechanism of the degradation of methylene blue (MB) under fluorescent light and visible light irradiation was studied. Co-doping cerium and nitrogen in the crystal lattice of TiO(2) narrowed the band gap from 2.40 eV (Ce-doped TiO(2)) to 2.21 eV (Ce/N co-doped TiO(2)). Ce(4+)/Ce(3+) pairs, oxynitride species and Ti-O-N and Ti-O-Ce bonds were determined by XPS. The recombination of photogenerated electron-hole pairs was inhibited due to the synergistic effect of doping with Ce(4+)/Ce(3+) ions and N atoms. The optimal doping ratio was 0.70% Ce and 0.70% N using MB photocatalytic degradation under fluorescent light and visible light irradiation (lambda>420 nm). The enhanced photocatalytic degradation under visible light irradiation was attributed to the increasing number of photogenerated OH radicals. The recombination of photogenerated e(-)-h(+) was attributed to be the key factor for the decrease in the photocatalytic degradation efficiency of MB.
authors.affiliation: School of Environmental Science and Engineering, Tianjin University, Tianjin, 300072, China. lisat.yu@gmail.com
authors.forename: Tao
authors.initials: T
authors.lastname: Yu
authors.forename: Xin
authors.initials: X
authors.lastname: Tan
authors.forename: Lin
authors.initials: L
authors.lastname: Zhao
mesh_terms: D002384:Catalysis; D002563:Cerium / Q000737:chemistry; D004583:Electrons; D008027:Light; D049329:Nanostructures / Q000737:chemistry / Q000528:radiation effects; D009584:Nitrogen / Q000737:chemistry; D055668:Photochemical Processes; D014025:Titanium / Q000737:chemistry* / Q000528:radiation effects*
chemical_list: C009495:titanium dioxide; D002563:Cerium; D014025:Titanium; D009584:Nitrogen