Supramolecular n/p-heterojunction photosystems with oriented multicolored antiparallel redox gradients (OMARG-SHJs).
Directional electron and hole transport is essential in photosynthesis. Applied to molecular optoelectronics such as organic solar cells, these lessons from nature call for oriented supramolecular n/p-heterojunctions (SHJs) that contain various chromophores and antiparallel redox gradients (OMARGs). In this tutorial review, we summarize recent progress made toward the construction of OMARG-SHJs. This conceptually innovative twist added to a timely topic should appeal to the synthetic organic, supramolecular, biological, physical, analytical and materials chemist as well as to the expert in energy and environmental sciences.
Bhosale
Rajesh
R
Department of Organic Chemistry, University of Geneva, Geneva, Switzerland.
Mísek
Jirí
J
Sakai
Naomi
N
Matile
Stefan
S
D001483:Base Sequence; D003116:Color; D004579:Electron Transport; D008956:Models, Chemical; D055668:Photochemical Processes