title: A porous coordination network catalyzes an olefin isomerization reaction in the pore.
abstract: All-trans retinal efficiently diffused into the pore of a porous coordination network consisting of ZnI(2) and an electron-deficient triazine-cored ligand. Enclathrated retinal was isomerized into the 13-cis form and easily replaced with all-trans retinal in solution, thus revealing the catalysis of retinal isomerization by the porous network.
authors.affiliation: Department of Applied Chemistry, School of Engineering, The University of Tokyo, CREST-JST, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
authors.forename: Kazuaki
authors.initials: K
authors.lastname: Ohara
authors.forename: Masaki
authors.initials: M
authors.lastname: Kawano
authors.forename: Yasuhide
authors.initials: Y
authors.lastname: Inokuma
authors.forename: Makoto
authors.initials: M
authors.lastname: Fujita