title: Degradation of 1,2,3-trichloropropane (TCP): hydrolysis, elimination, and reduction by iron and zinc.
abstract: 1,2,3-Trichloropropane (TCP) is an emerging contaminant because of increased recognition of its occurrence in groundwater, potential carcinogenicity, and resistance to natural attenuation. The physical and chemical properties of TCP make it difficult to remediate, with all conventional options being relatively slow or inefficient. Treatments that result in alkaline conditions (e.g., permeable reactive barriers containing zerovalent iron) favor base-catalyzed hydrolysis of TCP, but high temperature (e.g., conditions of in situ thermal remediation) is necessary for this reaction to be significant. Common reductants (sulfide, ferrous iron adsorbed to iron oxides, and most forms of construction-grade or nano-Fe(0)) produce insignificant rates of reductive dechlorination of TCP. Quantifiable rates of TCP reduction were obtained with several types of activated nano-Fe(0), but the surface area normalized rate contants (k(SA)) for these reactions were lower than is generally considered useful for in situ remediation applications (10(-4) L m(-2) h(-1)). Much faster rates of degradation of TCP were obtained with granular Zn(0), (k(SA) = 10(-3) - 10(-2) L m(-2) h(-1)) and potentially problematic dechlorination intermediates (1,2- or 1,3-dichloropropane, 3-chloro-1-propene) were not detected. The advantages of Zn(0) over Fe(0) are somewhat peculiar to TCP and may suggest a practical application for Zn(0) even though it has not found favor for remediation of contamination with other chlorinated solvents.
authors.affiliation: Division of Environmental and Biomolecular Systems, Oregon Health & Science University, Portland, Oregon 97006, USA.
authors.forename: Vaishnavi
authors.initials: V
authors.lastname: Sarathy
authors.forename: Alexandra J
authors.initials: AJ
authors.lastname: Salter
authors.forename: James T
authors.initials: JT
authors.lastname: Nurmi
authors.forename: Graham
authors.initials: G
authors.lastname: O'Brien Johnson
authors.forename: Richard L
authors.initials: RL
authors.lastname: Johnson
authors.forename: Paul G
authors.initials: PG
authors.lastname: Tratnyek
mesh_terms: D006868:Hydrolysis; D007501:Iron / Q000737:chemistry*; D011407:Propane / Q000031:analogs & derivatives* / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000737:chemistry; D015032:Zinc / Q000737:chemistry*
chemical_list: D014874:Water Pollutants, Chemical; C009536:1,2,3-trichloropropane; D007501:Iron; D015032:Zinc; D011407:Propane