title: Nonradiative inter- and intramolecular energy transfer from the aromatic donor anisole to a synthesized photoswitchable acceptor system.
abstract: We report steady state and time resolved fluorescence measurements on acetonitrile (ACN) solutions of the model compounds, energy donor anisole (A) and a photoswitchable acceptor N,N'-1,2-phenylene di-p-tosylamide (B) and the multichromophore (M) where A and B are connected by a spacer containing both rigid triple (acetylenic) and flexible methylene bonds. Both steady state and time correlated single photon counting measurements demonstrate that though intermolecular energy transfer, of Forster type, between the donor and acceptor moieties occurs with rate 10(8)s(-1) but when these two reacting components are linked by a spacer (multichromophore, M) the observed transfer rate ( approximately 10(11)s(-1)) enhances. This seemingly indicates that the imposition of the spacer by inserting a triple bond may facilitate in the propagation of electronic excitation energy through bond. The time resolved fluorescence measurements along with the theoretical predictions using Configuration interaction singles (CIS) method by using 6-31G (d,p) basis set, implemented in the Gaussian package indicate the formations of the two excited conformers of B. The experimental findings made from the steady state and time resolved fluorescence measurements demonstrate that, though two different isomeric species of the acceptor B are formed in the excited singlet states, the prevailing singlet-singlet nonradiative energy transfer route was found from the donor A to the relatively longer-lived isomeric species of B.
authors.affiliation: Department of Spectroscopy, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700032, India.
authors.forename: Munmun
authors.initials: M
authors.lastname: Bardhan
authors.forename: Sudeshna
authors.initials: S
authors.lastname: Bhattacharya
authors.forename: Tapas
authors.initials: T
authors.lastname: Misra
authors.forename: Rupa
authors.initials: R
authors.lastname: Mukhopadhyay
authors.forename: Asish
authors.initials: A
authors.lastname: De
authors.forename: Joydeep
authors.initials: J
authors.lastname: Chowdhury
authors.forename: Tapan
authors.initials: T
authors.lastname: Ganguly
mesh_terms: D000840:Anisoles / Q000737:chemistry*; D004735:Energy Transfer; D015394:Molecular Structure; D010777:Photochemistry; D013050:Spectrometry, Fluorescence; D014105:Tosyl Compounds / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: D000840:Anisoles; D014105:Tosyl Compounds; C060998:anisole