title: Molecular dynamics simulations of atomically flat and nanoporous electrodes with a molten salt electrolyte.
abstract: The electric double layer (EDL) structure and capacitance have been studied for atomically flat and nanoporous conductive electrodes with a molten LiCl electrolyte using an electroactive interface molecular dynamics simulation methodology. For the atomically flat electrodes the electrolyte was observed to form a multilayer structure near the electrode described by exponentially decaying sinusoidal oscillations in ion and charge densities perpendicular to the electrode/electrolyte interface. The differential EDL capacitance vs. electrode potential was found to exhibit "U-shaped" behavior while the EDL capacitance exhibited complex dependence on electrode potential including regions of negative capacitance near zero electrode potential. Increased capacitance and an enhanced degree of electrode-electrolyte interface structure were observed with decreasing temperature. For nanoporous electrodes with both slit and cylindrical pore geometries, the electrolyte was observed to form highly structured alternating charged layers within the electrode nanopores. A maximum in the normalized (per unit electrode area) EDL capacitance was found for pore widths that accommodate several charged layers inside the pores. The observed dependence of capacitance on pore size appears to be a compromise between increasing structure/charge imbalance and decreasing ion density with decreasing pore width/diameter.
authors.affiliation: Department of Materials Science and Engineering, University of Utah, Salt Lake City, UT 84112, USA.
authors.forename: Jenel
authors.initials: J
authors.lastname: Vatamanu
authors.forename: Oleg
authors.initials: O
authors.lastname: Borodin
authors.forename: Grant D
authors.initials: GD
authors.lastname: Smith