Fluoride-enhanced lanthanide luminescence and white-light emitting in multifunctional Al3Ln2 (Ln = Nd, Eu, Yb) heteropentanuclear complexes.
Multifunctional heteropentanuclear Al(3)Ln(2) (Ln = Nd, Eu, Yb) clusters with a novel structure exhibit significantly fluoride-enhanced lanthanide emission intensity and lifetime in both solid state and solution as well as unusual white-light emitting for an Al(3)Eu(2) complex.
Xu
Hai-Bing
HB
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
Chen
Xiao-Ming
XM
Zhang
Qi-Sheng
QS
Zhang
Li-Yi
LY
Chen
Zhong-Ning
ZN
D017607:Aluminum Compounds / Q000737:chemistry*; D018360:Crystallography, X-Ray; D005063:Europium / Q000737:chemistry*; D005459:Fluorides / Q000737:chemistry*; D008027:Light; D049449:Luminescence; D008958:Models, Molecular; D009354:Neodymium / Q000737:chemistry*; D013050:Spectrometry, Fluorescence; D015018:Ytterbium / Q000737:chemistry*
D017607:Aluminum Compounds; D009354:Neodymium; D005063:Europium; D015018:Ytterbium; D005459:Fluorides