title: Indium chalcogenido clusters coordinated by 1,10-phenanthroline, [InQ(phen)Cl]4 (Q = Se, S), a simplified model of inorganic-organic hybrid material with cluster-to-ligand charge transfer.
abstract: Most metal-1,10-phenanthroline-complex-sensitized inorganic semiconductors are multicomponent materials. This fundamental study was devoted to the single-phase materials fused with moieties of the phen complex and inorganic chalcogenide. Compounds 1 and 2 are new types of cubic clusters with cluster-to-ligand charge transfer.
authors.affiliation: Department of Chemistry and Key Laboratory of Organic Synthesis of Jiangsu Province, Soochow University, Suzhou 215123, People's Republic of China.
authors.forename: Zhi-Xin
authors.initials: ZX
authors.lastname: Lei
authors.forename: Qin-Yu
authors.initials: QY
authors.lastname: Zhu
authors.forename: Ming-Hui
authors.initials: MH
authors.lastname: Zhang
authors.forename: Jian-Bing
authors.initials: JB
authors.lastname: Jiang
authors.forename: Ya-Ping
authors.initials: YP
authors.lastname: Zhang
authors.forename: Jie
authors.initials: J
authors.lastname: Dai
mesh_terms: D007204:Indium / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D010618:Phenanthrolines / Q000737:chemistry*
chemical_list: D008024:Ligands; D010618:Phenanthrolines; D007204:Indium; C025205:1,10-phenanthroline