Hydride-induced cleavage of C-O bond in pyran ring of 2-pyranylidene carbene complexes: mechanism and synthetic application.
Hydride-induced cleavage of the C-O bond in the pyran ring followed by ring closure of unsaturated acylmetalates and reductive elimination was achieved.
Wang
Qifeng
Q
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
Liu
Lantao
L
Lin
Chen
C
Sun
Hui
H
Zhang
Wen-Xiong
WX
Xi
Zhenfeng
Z