title: Improved automated analysis of radon (222Rn) and thoron (220Rn) in natural waters.
abstract: Natural radon ((222)Rn) and thoron ((220)Rn) can be used as tracers of various chemical and physical processes in the environment. We present here results from an extended series of laboratory experiments intended to improve the automated analysis of (222)Rn and (220)Rn in water using a modified RAD AQUA (Durridge Inc.) system. Previous experience with similar equipment showed that it takes about 30-40 min for the system to equilibrate to radon-in-water concentration increases and even longer for the response to return to baseline after a sharp spike. While the original water/gas exchanger setup was built only for radon-in-water measurement, our goal here is to provide an automated system capable of high resolution and good sensitivity for both radon- and thoron-in-water detections. We found that faster water flow rates substantially improved the response for both isotopes while thoron is detected most efficiently at airflow rates of 3 L/min. Our results show that the optimum conditions for fastest response and sensitivity for both isotopes are at water flow rates up to 17 L/min and an airflow rate of 3 L/min through the detector. Applications for such measurements include prospecting for naturally occurring radioactive material (NORM) in pipelines and locating points of groundwater/surface water interaction.
authors.affiliation: Department of Oceanography, Florida State University, Tallahassee, Florida 32306, USA. dimova@ocean.fsu.edu
authors.forename: Natasha
authors.initials: N
authors.lastname: Dimova
authors.forename: William C
authors.initials: WC
authors.lastname: Burnett
authors.forename: Derek
authors.initials: D
authors.lastname: Lane-Smith
mesh_terms: D001331:Automation; D005618:Fresh Water / Q000737:chemistry*; D011834:Radiation Monitoring / Q000295:instrumentation* / Q000379:methods*; D011886:Radon / Q000032:analysis*; D014875:Water Pollutants, Radioactive / Q000737:chemistry*
chemical_list: D014875:Water Pollutants, Radioactive; D011886:Radon