title: The manganese(III) complex with chelating Schiff base ligand: X-ray structure, spectroscopic and computational studies.
abstract: A new Mn(III) complex, [MnCl(H(2)O)(L)].H(2)O.C(2)H(5)OH, where L=2,2'-[1,2-phenylenebis[nitrilomethylylidene]]bis(6-methoxyphenolate), has been synthesized and characterized by single-crystal X-ray diffraction. There is a good agreement between calculated and experimental structural data. The complex is crystallized in orthorhombic with space group Pbca. The Mn1 atom is coordinated with one Schiff base ligand, one water molecule and one chloride anion, forming a six-coordination number. The electronic and fluorescence spectra of the complex were also studied.
authors.affiliation: School of Chemical Sciences, Universiti Sains Malaysia, Penang, Malaysia. Nasertaha90@hotmail.com
authors.forename: Naser E
authors.initials: NE
authors.lastname: Eltayeb
authors.forename: Siang G
authors.initials: SG
authors.lastname: Teoh
authors.forename: Eny
authors.initials: E
authors.lastname: Kusrini
authors.forename: Rohana
authors.initials: R
authors.lastname: Adnan
authors.forename: H K
authors.initials: HK
authors.lastname: Fun
mesh_terms: D003198:Computer Simulation; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008024:Ligands; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D012545:Schiff Bases / Q000138:chemical synthesis / Q000737:chemistry*; D013050:Spectrometry, Fluorescence; D014961:X-Ray Diffraction
chemical_list: D008024:Ligands; D012545:Schiff Bases; D008345:Manganese