The manganese(III) complex with chelating Schiff base ligand: X-ray structure, spectroscopic and computational studies.
A new Mn(III) complex, [MnCl(H(2)O)(L)].H(2)O.C(2)H(5)OH, where L=2,2'-[1,2-phenylenebis[nitrilomethylylidene]]bis(6-methoxyphenolate), has been synthesized and characterized by single-crystal X-ray diffraction. There is a good agreement between calculated and experimental structural data. The complex is crystallized in orthorhombic with space group Pbca. The Mn1 atom is coordinated with one Schiff base ligand, one water molecule and one chloride anion, forming a six-coordination number. The electronic and fluorescence spectra of the complex were also studied.
Eltayeb
Naser E
NE
School of Chemical Sciences, Universiti Sains Malaysia, Penang, Malaysia. Nasertaha90@hotmail.com
Teoh
Siang G
SG
Kusrini
Eny
E
Adnan
Rohana
R
Fun
H K
HK
D003198:Computer Simulation; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008024:Ligands; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D012545:Schiff Bases / Q000138:chemical synthesis / Q000737:chemistry*; D013050:Spectrometry, Fluorescence; D014961:X-Ray Diffraction
D008024:Ligands; D012545:Schiff Bases; D008345:Manganese