title: A modified acid digestion procedure for extraction of tungsten from soil.
abstract: Interest in tungsten occurrence and geochemistry is increasing due to increased use of tungsten compounds and its unknown biochemical effects. Tungsten has a complex geochemistry, existing in most environmental matrices as the soluble and mobile tungstate anion, as well as poly- and heteropolytungstates. Because the geochemistry of tungsten is substantially different than most trace metals, including the formation of insoluble species under acidic conditions, it is not extracted from soil matrices using standard acid digestion procedures. Therefore, the current work describes a modification to a commonly used acid digestion procedure to facilitate quantification of tungsten in soil matrices. Traditional soil digestion procedures, using nitric and hydrochloric acids with hydrogen peroxide yield <1 up to 50% recovery on soil matrix spike samples, whereas the modified method reported here, which includes the addition of phosphoric acid, yields spike recoveries in the 76-98% range. Comparison of the standard and modified digestion procedures on National Institute of Standards and Technology Standard Reference Materials yielded significantly improved tungsten recoveries for the phosphoric acid modified method. The modified method also produces comparable results for other acid extractable metals as the standard methods, and therefore can be used simultaneously for tungsten and other metals of interest.
authors.affiliation: U.S. Army Engineer Research and Development Center, Environmental Laboratory, 3909 Halls Ferry Rd., Vicksburg, MS 39180, United States. Anthony.J.Bednar@usace.army.mil
authors.forename: A J
authors.initials: AJ
authors.lastname: Bednar
authors.forename: W T
authors.initials: WT
authors.lastname: Jones
authors.forename: M A
authors.initials: MA
authors.lastname: Chappell
authors.forename: D R
authors.initials: DR
authors.lastname: Johnson
authors.forename: D B
authors.initials: DB
authors.lastname: Ringelberg
mesh_terms: D005591:Chemical Fractionation / Q000379:methods*; D006861:Hydrogen Peroxide / Q000737:chemistry; D013058:Mass Spectrometry; D017942:Nitric Acid / Q000737:chemistry; D010756:Phosphoric Acids / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry; D012987:Soil; D012995:Solubility; D013054:Spectrophotometry, Atomic; D013997:Time Factors; D014414:Tungsten / Q000032:analysis / Q000737:chemistry* / Q000302:isolation & purification*
chemical_list: D010756:Phosphoric Acids; D011108:Polymers; D012987:Soil; D017942:Nitric Acid; D006861:Hydrogen Peroxide; C030242:phosphoric acid; D014414:Tungsten