Catalytic SNAr reaction of non-activated fluoroarenes with amines via Ru eta6-arene complexes.
Ru-catalyzed S(N)Ar reaction of non-activated fluoroarenes with secondary amines proceeded through eta(6)-arene complexes to give aminated products in up to 79% yield.
Otsuka
Maiko
M
Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Shinjuku, Tokyo, 169-8555, Japan.
Endo
Kohei
K
Shibata
Takanori
T
D000588:Amines / Q000737:chemistry*; D002384:Catalysis; D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry*; D005464:Fluorobenzenes / Q000737:chemistry*; D009025:Morpholines / Q000737:chemistry; D012428:Ruthenium / Q000737:chemistry*
D000588:Amines; D056831:Coordination Complexes; D005464:Fluorobenzenes; D009025:Morpholines; D012428:Ruthenium; C037574:morpholine