title: Aryl sulfoxides from allyl sulfoxides via [2,3]-sigmatropic rearrangement and domino Pd-catalyzed generation/arylation of sulfenate anions.
abstract: Allylic sulfoxides, via [2,3]-sigmatropic rearrangement and oxidative addition of the resulting allylic sulfenate esters to Pd(0), are found to be excellent precursors of sulfenate anions. This hitherto unknown reactivity is applied in a new Pd(0)-catalyzed domino sequence involving sulfenate anion generation followed by arylation to afford aryl sulfoxides.
authors.affiliation: Université Pierre et Marie Curie-Paris 6, Laboratoire de Chimie organique (UMR CNRS 7611), Institut de Chimie Moléculaire (FR 2769), Case 183, 4 Place Jussieu, F-75252, Paris Cedex 05, France.
authors.forename: Elise
authors.initials: E
authors.lastname: Bernoud
authors.forename: Gaëtan
authors.initials: G
authors.lastname: Le Duc
authors.forename: Xavier
authors.initials: X
authors.lastname: Bantreil
authors.forename: Guillaume
authors.initials: G
authors.lastname: Prestat
authors.forename: David
authors.initials: D
authors.lastname: Madec
authors.forename: Giovanni
authors.initials: G
authors.lastname: Poli