title: Ni(II)-catalyzed enantioselective conjugate addition of acetylenes to alpha,beta-enones.
abstract: Alkynylaluminum reagents undergo enantioselective conjugate addition to cyclic alpha,beta-enones in the presence of chiral bisphosphine complexes of Ni(II).
authors.affiliation: Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA.
authors.forename: Oleg V
authors.initials: OV
authors.lastname: Larionov
authors.forename: E J
authors.initials: EJ
authors.lastname: Corey
mesh_terms: D000480:Alkynes / Q000138:chemical synthesis* / Q000737:chemistry*; D002384:Catalysis; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000480:Alkynes; D007659:Ketones; D009942:Organometallic Compounds; D009532:Nickel