title: Tripodal 4-pyridyl-derived host ligands and their metallo-supramolecular chemistry: stella octangula and bowl-shaped assemblies.
abstract: The synthesis of five new cyclotriveratrylene derivatives with 4-pyridyl side arms is reported, along with the crystal structures of three of these. Three ligands with extended 4-pyridylphenyl side arms and a ligand derived from cyclotriphenolene have been shown to form [Pd(6)L(8)](12+) stella octangula assemblies using diffusion-ordered spectroscopy NMR and electrospray MS techniques. This confirms the generality of the stella octagula assembly, providing that the ligand arms show a degree of rigidity. The more flexible ether-linked ligand tris(4-pyridylmethyl)cyclotriguaiacylene forms a smaller [Pd(3)L(4)](6+) bowl-shaped assembly in the solid state and in solution. The previously reported ligand tris(4-pyridylmethylamino)cyclotriguaiacylene forms a similar assembly in solution.
authors.affiliation: School of Chemistry, University of Leeds, Woodhouse Lane, Leeds, LS2 9JT, United Kingdom.
authors.forename: Tanya K
authors.initials: TK
authors.lastname: Ronson
authors.forename: Christopher
authors.initials: C
authors.lastname: Carruthers
authors.forename: Julie
authors.initials: J
authors.lastname: Fisher
authors.forename: Thierry
authors.initials: T
authors.lastname: Brotin
authors.forename: Lindsay P
authors.initials: LP
authors.lastname: Harding
authors.forename: Pierre J
authors.initials: PJ
authors.lastname: Rizkallah
authors.forename: Michaele J
authors.initials: MJ
authors.lastname: Hardie