Host-guest influence on metallo-supramolecular assemblies with a cyclotriveratrylene-type ligand.
The structure-directing effect of guest binding in metallo-supramolecular assemblies of host-type ligands is observed with a 2-D coordination polymer formed between Cd(OAc)(2) and tris(4-pyridylmethylamino)cyclotriguaiacylene in the presence of the globular guest o-carborane, and a trinuclear Cd(II) complex formed in solution in the absence of the bulky guest.
Carruthers
Christopher
C
School of Chemistry, University of Leeds, Leeds, UK LS2 9JT.
Fisher
Julie
J
Harding
Lindsay P
LP
Hardie
Michaele J
MJ