Quinone tailored selective oxidation of methane over palladium catalyst with molecular oxygen as an oxidant.
With the in situ generated H(2)O(2) tailored by the addition of p-tetrachlorobenzoquinone, the product can be effectively steered towards either HCOOH or the methanol derivative CF(3)COOCH(3) during the direct oxidation of methane with molecular oxygen over palladium catalyst.
Fan
Yafang
Y
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
An
Zengjian
Z
Pan
Xiulian
X
Liu
Xiumei
X
Bao
Xinhe
X