Dipyrrin based luminescent cyclometallated palladium and platinum complexes.
A series of complexes based on the combination of cyclometallated palladium or platinum moieties with functionalized dipyrrin ligands bearing mesityl- or benzonitrile groups have been prepared and characterized both in the solid state and in solution; these compounds exhibit a characteristic dipyrrin-centered luminescence with an emission intensity modulated by the degree of rotational freedom of the aromatic group attached to the dipyrrin chelate.
Bronner
Catherine
C
Laboratoire de Chimie de Coordination Organique, UMR CNRS 7140, Université de Strasbourg, F-67000, Strasbourg, France.
Baudron
Stéphane A
SA
Hosseini
Mir Wais
MW
Strassert
Cristian A
CA
Guenet
Aurélie
A
De Cola
Luisa
L