title: Vectorial growth/regulations in a {P8W48}-type polyoxotungstate compartment: trapped unusual molybdenum oxide acts as a handle.
abstract: Reaction of the cyclic {P(8)W(48)} polyoxotungstate host with sodium molybdate in solution in the presence of a reducing agent leads to the formation and stabilization of unprecedented neutral {Mo(V)(4)O(10)(H(2)O)(3)} aggregates with handle function, thereby proving the potential of the present host for performing future interesting studies related to mixed-valence type chemistry under confined conditions.
authors.affiliation: Fakultät für Chemie, Universität Bielefeld, Postfach 100131, D-33501 Bielefeld, Germany.
authors.forename: Filipa L
authors.initials: FL
authors.lastname: Sousa
authors.forename: Hartmut
authors.initials: H
authors.lastname: Bögge
authors.forename: Alice
authors.initials: A
authors.lastname: Merca
authors.forename: Pierre
authors.initials: P
authors.lastname: Gouzerh
authors.forename: René
authors.initials: R
authors.lastname: Thouvenot
authors.forename: Achim
authors.initials: A
authors.lastname: Müller