Single and double substrate insertion into the Ti=N(alpha) bonds of terminal titanium hydrazides.
Nitriles, CO(2) and isocyanates undergo net single or double insertion reactions into the Ti=N(alpha) multiple bonds of terminal titanium hydrazides. These are the first such examples of this type of reactivity for any transition metal hydrazide complex.
Tiong
Pei-Jen
PJ
Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford, UK.
Schofield
A Daniel
AD
Selby
Jonathan D
JD
Nova
Ainara
A
Clot
Eric
E
Mountford
Philip
P