Biaryl construction through Kumada coupling with diaryl sulfates as one-by-one electrophiles under mild conditions.
Diaryl sulfates were successfully applied as one-by-one organo electrophiles in Kumada coupling to construct biaryls with the emission of harmless inorganic salts.
Guan
Bing-Tao
BT
Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.
Lu
Xing-Yu
XY
Zheng
Yang
Y
Yu
Da-Gang
DG
Wu
Tong
T
Li
Kun-Lin
KL
Li
Bi-Jie
BJ
Shi
Zhang-Jie
ZJ
D001713:Biphenyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D009942:Organometallic Compounds / Q000737:chemistry; D013464:Sulfuric Acids / Q000737:chemistry*
D001713:Biphenyl Compounds; D009942:Organometallic Compounds; D013464:Sulfuric Acids