Indium chalcogenido clusters coordinated by 1,10-phenanthroline, [InQ(phen)Cl]4 (Q = Se, S), a simplified model of inorganic-organic hybrid material with cluster-to-ligand charge transfer.
Most metal-1,10-phenanthroline-complex-sensitized inorganic semiconductors are multicomponent materials. This fundamental study was devoted to the single-phase materials fused with moieties of the phen complex and inorganic chalcogenide. Compounds 1 and 2 are new types of cubic clusters with cluster-to-ligand charge transfer.
Lei
Zhi-Xin
ZX
Department of Chemistry and Key Laboratory of Organic Synthesis of Jiangsu Province, Soochow University, Suzhou 215123, People's Republic of China.
Zhu
Qin-Yu
QY
Zhang
Ming-Hui
MH
Jiang
Jian-Bing
JB
Zhang
Ya-Ping
YP
Dai
Jie
J
D007204:Indium / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D010618:Phenanthrolines / Q000737:chemistry*
D008024:Ligands; D010618:Phenanthrolines; D007204:Indium; C025205:1,10-phenanthroline