Substrate-controlled diastereoselectivity switch in catalytic asymmetric direct Mannich reaction of glycine derivatives with imines: from anti- to syn-alpha,beta-diamino acids.
Hernández-Toribio
Jorge
J
Departamento de Química Orgánica, Universidad Autónoma de Madrid (UAM), Facultad de Ciencias, Cantoblanco, Cantoblanco, 28049 Madrid, Spain.
Gómez Arrayás
Ramón
R
Carretero
Juan Carlos
JC
D000596:Amino Acids / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry; D005998:Glycine / Q000031:analogs & derivatives* / Q000737:chemistry; D007097:Imines / Q000737:chemistry*; D013237:Stereoisomerism; D013379:Substrate Specificity
D000596:Amino Acids; D007097:Imines; D003300:Copper; D005998:Glycine