title: catena-Poly[[bis(acetonitrile-kappaN)manganese(II)]-bis(mu-trifluoromethanesulfonato-kappa2O:O')].
abstract: The title compound, [Mn(CF(3)SO(3))(2)(CH(3)CN)(2)](n), has an Mn(II) cation on an inversion centre in an octahedral environment. The trifluoromethanesulfonate anions act as bridging ligands and form a one-dimensional coordination polymer in the direction of the a axis. The F atoms of the trifluoromethanesulfonate anions form layers parallel to the ab plane, but despite short intermolecular distances, no stabilizing F...F interactions are detected. The Mn-N and C-C bonds of the acetonitrile ligand are analyzed according to the Hirshfeld rigid-bond test. Renninger effects in the reflection data are considered, explored and discussed.
authors.affiliation: Bijvoet Center for Biomolecular Research, Crystal and Structural Chemistry, Faculty of Science, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands. m.lutz@uu.nl
authors.forename: Martin
authors.initials: M
authors.lastname: Lutz
authors.forename: Antoine M M
authors.initials: AM
authors.lastname: Schreurs
authors.forename: Anthony L
authors.initials: AL
authors.lastname: Spek
authors.forename: Marcel A H
authors.initials: MA
authors.lastname: Moelands
authors.forename: Robertus J M
authors.initials: RJ
authors.lastname: Klein Gebbink
mesh_terms: D000838:Anions / Q000737:chemistry; D002412:Cations / Q000737:chemistry; D018360:Crystallography, X-Ray; D008024:Ligands; D008345:Manganese / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry
chemical_list: D000838:Anions; D002412:Cations; D008024:Ligands; D009942:Organometallic Compounds; D011108:Polymers; C547114:poly((bis(acetonitrile-kappaN)manganese(II))-bis(mu-trifluoromethanesulfonato-kappa2O,O')); D008345:Manganese