Confined growth of cyanide-based magnets in two dimensions.
Herein we report the first hybrid magnetic material resulting from the intercalation of a cyanide-based molecular magnet into a solid-state layered host. More specifically, the use of a diamagnetic cationic Zn(II)-Al(lII) layered double hydroxide host allows for the formation of an anionic two-dimensional ferromagnetic Ni(II)-Cr(III) Prussian Blue analogue, from the templated assembly of its ionic molecular components in the confined interlamellar space offered by the inorganic host.
Coronado
Eugenio
E
Universidad de Valencia (ICMol), Polígono de la Coma s/n, 46980 Paterna, Spain. eugenio.coronado@uv.es
Martí-Gastaldo
Carlos
C
Navarro-Moratalla
Efrén
E
Ribera
Antonio
A