title: Synthesis of nanocrystalline anatase TiO2 by one-pot two-phase separated hydrolysis-solvothermal processes and its high activity for photocatalytic degradation of rhodamine B.
abstract: Si-doped and un-doped nanocrystalline TiO(2) samples have been synthesized by simple one-pot water-organic two-phase separated hydrolysis-solvothermal (HST) processes, and characterized by XRD, BET, TEM, FT-IR, DRS and surface photovoltage techniques. The effects of the solvothermal temperature and Si doping on the anatase thermal stability, and on the photocatalytic activity for degrading rhodamine B were investigated in detail. The results show that, as the solvothermal temperature rises, the crystallinity and thermal stability of the resulting nano-sized anatase TiO(2) gradually increase. Noticeably, the as-prepared TiO(2) obtained at appropriate solvothermal temperature (160 degrees C) exhibits high photocatalytic activity. Moreover, although Si doping does not improve the photocatalytic activity of the as-prepared anatase TiO(2), it greatly enhances the anatase thermal stability and inhibits crystallite growth during the process of post-thermal treatment. Interestingly, the Si-doped TiO(2) post-treated at high temperature displays much higher photocatalytic activity than commercial P25 TiO(2). It is clearly demonstrated that the joint effects of high anatase crystallinity and large surface area lead to high photocatalytic activity. This work provides a simple and effective strategy for the synthesis of high-performance TiO(2)-based functional nanomaterials.
authors.affiliation: Key Laboratory of Functional Inorganic Materials Chemistry (Heilongjiang University), Ministry of Education, School of Chemistry and Materials Science, Harbin 150080, PR China.
authors.forename: Mingzheng
authors.initials: M
authors.lastname: Xie
authors.forename: Liqiang
authors.initials: L
authors.lastname: Jing
authors.forename: Jia
authors.initials: J
authors.lastname: Zhou
authors.forename: Jingsheng
authors.initials: J
authors.lastname: Lin
authors.forename: Honggang
authors.initials: H
authors.lastname: Fu
mesh_terms: D006868:Hydrolysis; D053758:Nanoparticles / Q000737:chemistry*; D055668:Photochemical Processes; D012235:Rhodamines / Q000737:chemistry*; D012997:Solvents; D013696:Temperature; D014025:Titanium / Q000737:chemistry*
chemical_list: D012235:Rhodamines; D012997:Solvents; C009495:titanium dioxide; D014025:Titanium; C029773:rhodamine B