An expeditious route to 1alpha,25-dihydroxyvitamin D(3) and its analogues by an aqueous tandem palladium-catalyzed a-ring closure and suzuki coupling to the C/D unit.
Gogoi
Pranjal
P
Departamento de Química Orgánica, Universidad de Santiago de Compostela y Unidad Asociada al CSIC, Avda de las Ciencias s/n, 15782 Santiago de Compostela, Spain.
Sigüeiro
Rita
R
Eduardo
Silvina
S
Mouriño
Antonio
A
D002384:Catalysis; D003500:Cyclization; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism; D014807:Vitamin D / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry
C118756:dihydroxy-vitamin D3; D014807:Vitamin D; D010165:Palladium