title: Low-density extraction solvent-based solvent terminated dispersive liquid-liquid microextraction combined with gas chromatography-tandem mass spectrometry for the determination of carbamate pesticides in water samples.
abstract: A simple and fast method of low-density extraction solvent-based solvent terminated dispersive liquid-liquid microextraction (ST-DLLME) was developed for the highly sensitive determination of carbamate pesticides in the water samples by gas chromatography-tandem mass spectrometry (GC-MSMS). After dispersing, the obtained emulsion cleared into two phases quickly when an aliquot of acetonitrile was introduced as a chemical demulsifier into the aqueous bulk. Therefore, the developed procedure does not need centrifugation to achieve phase separation. It was convenient for the usage of low-density extraction solvents in DLLME. Under the optimized conditions, the limits of detection for all target carbamate pesticides were in range of 0.001-0.50 ng mL(-1) and the precisions were in the range of 2.3-6.8% (RSDs, 2 ng mL(-1), n=5). The proposed method has been successfully applied to the analysis of real water samples and good spiked recoveries over the range of 94.5-104% were obtained.
authors.affiliation: Department of Chemistry, College of Science, Huazhong Agricultural University, Wuhan 430070, China. hchenhao@mail.hzau.edu.cn
authors.forename: Hao
authors.initials: H
authors.lastname: Chen
authors.forename: Ruiwen
authors.initials: R
authors.lastname: Chen
authors.forename: Shengqing
authors.initials: S
authors.lastname: Li
mesh_terms: D002219:Carbamates / Q000032:analysis*; D005591:Chemical Fractionation / Q000379:methods*; D005618:Fresh Water / Q000032:analysis*; D008401:Gas Chromatography-Mass Spectrometry / Q000191:economics / Q000379:methods*; D057230:Limit of Detection; D010575:Pesticides / Q000032:analysis*; D012680:Sensitivity and Specificity; D012997:Solvents
chemical_list: D002219:Carbamates; D010575:Pesticides; D012997:Solvents