title: Evaluation of quantum dots applied as switchable layer in a light-controlled electrochemical sensor.
abstract: Gold electrodes with switchable conductance are created by coating the gold surface with different colloidal quantum dots. For the quantum dot immobilization, a dithiol compound was used. By polarizing the electrode and applying a light pointer, local photocurrents were generated. The performance of this setup was characterized for a variety of different nanoparticle materials regarding drift and signal-to-noise ratio. We varied the following parameters: quantum dot materials and immobilization protocol. The results indicate that the performance of the sensor strongly depends on how the quantum dots are bound to the gold electrode. The best results were obtained by inclusion of an additional polyelectrolyte film, which had been fabricated using layer-by-layer assembly.
authors.affiliation: Department of Physics, Philipps University Marburg, 35037, Marburg, Germany.
authors.forename: Zhao
authors.initials: Z
authors.lastname: Yue
authors.forename: Waqas
authors.initials: W
authors.lastname: Khalid
authors.forename: Marco
authors.initials: M
authors.lastname: Zanella
authors.forename: Azhar Zahoor
authors.initials: AZ
authors.lastname: Abbasi
authors.forename: Andrea
authors.initials: A
authors.lastname: Pfreundt
authors.forename: Pilar
authors.initials: P
authors.lastname: Rivera Gil
authors.forename: Kirsten
authors.initials: K
authors.lastname: Schubert
authors.forename: Fred
authors.initials: F
authors.lastname: Lisdat
authors.forename: Wolfgang J
authors.initials: WJ
authors.lastname: Parak
mesh_terms: D015374:Biosensing Techniques / Q000295:instrumentation* / Q000379:methods; D004563:Electrochemistry / Q000295:instrumentation* / Q000379:methods; D004566:Electrodes; D004867:Equipment Design; D006046:Gold / Q000737:chemistry; D045663:Quantum Dots
chemical_list: D006046:Gold