title: Synthesis and photocatalytic properties of mixed polyoxometalate-porphyrin copolymers obtained from Anderson-type polyoxomolybdates.
abstract: Hybrid polyoxometalate-porphyrin copolymeric films are obtained by the electro-oxidation of zinc octaethylporphyrin (ZnOEP) and zinc 5,15-dipyridinium octaethylporphyrin (5,15-ZnOEP(py)(2)(2+)) in the presence of the polyoxometalate [MnMo(6)O(18){(OCH(2))(3)CNHCO(4-C(5)H(4)N)}(2)](3-) (Py-POM-Py). These films allow the photocatalytic reduction of Ag(I)(2)SO(4) under visible irradiation in air in the presence of propan-2-ol at the 2D interface between water and the copolymeric films. The formation of metallic Ag(0) nanowires and triangular nanosheets is observed.
authors.affiliation: Laboratoire de Chimie Physique, Groupe TEMiC, UMR 8000 au CNRS, Université Paris-Sud (XI), F-91405 Orsay Cedex, France.
authors.forename: Delphine
authors.initials: D
authors.lastname: Schaming
authors.forename: Clémence
authors.initials: C
authors.lastname: Allain
authors.forename: Rana
authors.initials: R
authors.lastname: Farha
authors.forename: Michel
authors.initials: M
authors.lastname: Goldmann
authors.forename: Sylvie
authors.initials: S
authors.lastname: Lobstein
authors.forename: Alain
authors.initials: A
authors.lastname: Giraudeau
authors.forename: Bernold
authors.initials: B
authors.lastname: Hasenknopf
authors.forename: Laurent
authors.initials: L
authors.lastname: Ruhlmann