title: Hybrid inorganic/organic alumina adsorbents-functionalized-purpurogallin for removal and preconcentration of Cr(III), Fe(III), Cu(II), Cd(II) and Pb(II) from underground water.
abstract: Metal pollution is well recognized as one of the major environmental problems that must be imperatively addressed and solved. In this study, three types of alumina adsorbents (I-III) were physically immobilized with purporogallin as a chelating ion exchangers. These were found to exhibit strong capability and selectivity characters for a series of heavy metal ions. Surface modification of hybrid alumina was characterized and identified from the determination of surface coverage and infrared analysis. Hybrid alumina adsorbents were identified for their strong resistivity to acid leaching in pH>2-7 as well as their high thermal stability up to 350 degrees C. The ability of newly synthesized hybrid inorganic/organic alumina adsorbents (I-III) to bind and extract various metal ions was examined and evaluated in various buffer solutions (pH 1.0-7.0) via determination of the metal adsorption capacity values. These were identified as high as 420-560, 500-580 and 500-590 micromol g(-1) for alumina adsorbents (I), (II) and (III), respectively in the case of high concentration levels of Cr(III), Fe(III) and Cu(II). The influence of alumina matrices were highly characterized when low concentration levels (microg ml(-1) and ng ml(-1)) of metal ions were used. Hybrid alumina adsorbents were successfully applied for selective extraction, removal and preconcentration of various heavy metals from underground water samples with percentage recovery values of 92-100+/-1-3%.
authors.affiliation: Faculty of Sciences, Chemistry Department, Alexandria University, P.O. Box 426, Ibrahimia 21321, Alexandria, Egypt. memahmoud10@yahoo.com
authors.forename: Mohamed E
authors.initials: ME
authors.lastname: Mahmoud
authors.forename: Osama F
authors.initials: OF
authors.lastname: Hafez
authors.forename: Maher M
authors.initials: MM
authors.lastname: Osman
authors.forename: Amr A
authors.initials: AA
authors.lastname: Yakout
authors.forename: Ahmed
authors.initials: A
authors.lastname: Alrefaay
mesh_terms: D000327:Adsorption; D000537:Aluminum Oxide / Q000737:chemistry*; D000975:Antioxidants / Q000737:chemistry; D001567:Benzocycloheptenes / Q000737:chemistry*; D002104:Cadmium / Q000302:isolation & purification; D002857:Chromium / Q000302:isolation & purification; D003300:Copper / Q000302:isolation & purification; D007501:Iron / Q000302:isolation & purification; D007854:Lead / Q000302:isolation & purification; D019216:Metals, Heavy / Q000302:isolation & purification*; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods
chemical_list: D000975:Antioxidants; D001567:Benzocycloheptenes; D019216:Metals, Heavy; D014874:Water Pollutants, Chemical; D002104:Cadmium; D002857:Chromium; D007854:Lead; D003300:Copper; D007501:Iron; C026133:purpurogallin; D000537:Aluminum Oxide