Excited-state proton transfer of 3-hydroxybenzoic acid and 4-hydroxybenzoic acid.
The excited-state proton transfer of 3-hydroxybenzoic acid and 4-hydroxybenzoic acid was studied by time-resolved laser-induced fluorescence spectroscopy with ultra-short laser pulses. The excited-state reactions were identified in aqueous media as a function of the pH value. Apart from the well-known inversion of the ordinary dissociation properties of these compounds, new species were found which exist only in the excited-state resulting from a temporal and reversible annihilation of the aromatic bond system. These species and their reaction mechanisms were detected by their absorption and fluorescence spectra.
Vulpius
D
D
Forschungszentrum Dresden-Rossendorf e V, Institute of Radiochemistry, PO Box 510119, 01314 Dresden, Germany. d.vulpius@fzd.de
Geipel
G
G
Bernhard
G
G
D062385:Hydroxybenzoates / Q000737:chemistry*; D010226:Parabens / Q000737:chemistry*; D011522:Protons; D013050:Spectrometry, Fluorescence
D062385:Hydroxybenzoates; D010226:Parabens; D011522:Protons; C032948:3-hydroxybenzoic acid; C038193:4-hydroxybenzoic acid