title: One-pot highly diastereoselective synthesis of cis-vinylaziridines via the sulfur ylide-mediated aziridination and palladium(0)-catalyzed isomerization.
abstract: Highly diastereoselective synthesis of cis-trisubstituted vinylaziridines containing a quaternary carbon center is realized by a one-pot protocol in which the combination of sulfur ylide-mediated aziridination of cyclic ketimines and Pd(0)-catalyzed isomerization is employed successfully.
authors.affiliation: School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215123, China.
authors.forename: Ben-Hu
authors.initials: BH
authors.lastname: Zhu
authors.forename: Jun-Cheng
authors.initials: JC
authors.lastname: Zheng
authors.forename: Chang-Bin
authors.initials: CB
authors.lastname: Yu
authors.forename: Xiu-Li
authors.initials: XL
authors.lastname: Sun
authors.forename: Yong-Gui
authors.initials: YG
authors.lastname: Zhou
authors.forename: Qi
authors.initials: Q
authors.lastname: Shen
authors.forename: Yong
authors.initials: Y
authors.lastname: Tang
mesh_terms: D001388:Aziridines / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism; D013457:Sulfur Compounds / Q000737:chemistry*; D014753:Vinyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D001388:Aziridines; D013457:Sulfur Compounds; D014753:Vinyl Compounds; D010165:Palladium