Intramolecular chalcogen-tin interactions in [(o-MeEC6H4)CH2]2SnPh(2-n)Cl(n) (E = S, O, CH2; n = 0, 1, 2) and intermolecular chlorine-tin interactions in the meta- and para-methoxy isomers.
Organotin(IV) compounds of the type [(o-MeEC(6)H(4))CH(2)](2)SnPh(2-n)Cl(n) were synthesized, E = O, n = 0 (1), n = 1 (2), and n = 2 (3); E = S, n = 0 (4), n = 1 (5), and n = 2 (6); and E = CH(2), n = 0 (7), n = 1 (8), and n = 2 (9). The dichloro compounds 3 and 6 have been investigated by single-crystal X-ray diffraction and exhibit bicapped tetrahedral geometry at the tin atom as a consequence of significant intramolecular Sn...O (3) and Sn...S (6) secondary bonding, in monomolecular units. Compound 3, when crystallized from a hexane/THF solvent mixture, shows two different conformers, 3' and 3'', in the crystal structure; 3' has two equivalent Sn...O interactions, while 3'' has two nonequivalent Sn...O interactions. Upon the recrystallization of 3 from hexane, only a single structural form is observed, 3'. The Sn...E distances in 3', 3'', and 6 are 71.3, 73.5 and 72.9, and 76.3% of the SigmavdW radii, respectively. The meta- and para-substituted isomers of 3 (10, 11) exhibit a distortion at the tin atom due to self-association via intermolecular Sn...Cl interactions, resulting in polymeric structures. (119)Sn NMR spectroscopy suggests that the intramolecular Sn...E interactions persist in solution for the dichloride compounds 3 and 6.
Vargas-Pineda
Diana Gabriela
DG
Department of Chemistry, University of Texas at El Paso, El Paso, Texas 79968-0513, USA.
Guardado
Tanya
T
Cervantes-Lee
Francisco
F
Metta-Magana
Alejandro J
AJ
Pannell
Keith H
KH
D018011:Chalcogens / Q000737:chemistry*; D002713:Chlorine / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D009947:Organotin Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D014001:Tin / Q000737:chemistry*
D018011:Chalcogens; D009947:Organotin Compounds; D002713:Chlorine; D014001:Tin