New SnO2/MgAl-layered double hydroxide composites as photocatalysts for cationic dyes bleaching.
A new type of nanocomposite containing SnO(2) has been obtained by wet impregnation of dehydrated Mg/Al-hydrotalcite-type compounds with ethanolic solutions of SnCl(4).2H(2)O. Tin chloride hydrolysis was achieved using NaOH or NH(4)OH aqueous solutions, at pH around 9, followed by the conversion into corresponding hydroxides through calcinations. The powder X-ray diffraction (PXRD) and UV-Vis diffuse reflectance (UV-DR) methods confirmed the structure of as-synthesized solids. The chemical composition and morphology of the synthesized materials were investigated by energy dispersive X-ray analysis (EDX), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The as-synthesized materials were used for photocatalytic studies showing a good activity for methylene blue decolourization, which varies with SnO(2) content and used as a hydrolysing agent. The proposed mechanism is based on the shifting of flat band potential of SnO(2) due to the interaction with Mg/Al-LDH, this being energetically favourable to the formation of hydroxyl radicals responsible for methylene blue degradation.
Dvininov
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E
Department of Physical and Theoretical Chemistry and Materials Chemistry, Al I Cuza University, Bd Carol I, No 11, 700506 Iasi, Romania. m1i2m3i4@yahoo.com
Ignat
M
M
Barvinschi
P
P
Smithers
M A
MA
Popovici
E
E
D000535:Aluminum; D002384:Catalysis; D002412:Cations; D004396:Coloring Agents / Q000737:chemistry*; D004785:Environmental Pollutants / Q000737:chemistry*; D006868:Hydrolysis; D006878:Hydroxides; D017665:Hydroxyl Radical; D008274:Magnesium; D008751:Methylene Blue / Q000737:chemistry*; D053761:Nanocomposites; D055668:Photochemical Processes; D017971:Tin Compounds / Q000737:chemistry*
D002412:Cations; D004396:Coloring Agents; D004785:Environmental Pollutants; D006878:Hydroxides; D017971:Tin Compounds; D017665:Hydroxyl Radical; D000535:Aluminum; D008274:Magnesium; C045358:stannic oxide; D008751:Methylene Blue