title: Synthesis of densely functionalised C-glycosides by a tandem oxy Michael addition-Wittig olefination pathway.
abstract: Wittig olefination of 5,6-dideoxy-5,6-anhydro-6-nitro-D-glucofuranose (5) triggered a concomitant cyclisation via oxy Michael addition of the C2-hydroxyl group resulting in the formation of C-vinyl glycosides with Z-olefinic geometry.
authors.affiliation: Organic Chemistry Division, Central Leather Research Institute, Chennai, India.
authors.forename: R
authors.initials: R
authors.lastname: Senthil Kumar
authors.forename: K
authors.initials: K
authors.lastname: Karthikeyan
authors.forename: B V N
authors.initials: BV
authors.lastname: Phani Kumar
authors.forename: D
authors.initials: D
authors.lastname: Muralidharan
authors.forename: P T
authors.initials: PT
authors.lastname: Perumal
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D006027:Glycosides; D008956:Models, Chemical; D009005:Monosaccharides / Q000138:chemical synthesis* / Q000737:chemistry*; D013237:Stereoisomerism; D014753:Vinyl Compounds / Q000138:chemical synthesis / Q000737:chemistry
chemical_list: D000475:Alkenes; C438934:C-glycoside; D006027:Glycosides; D009005:Monosaccharides; D014753:Vinyl Compounds