catena-Poly[[bis(acetonitrile-kappaN)manganese(II)]-bis(mu-trifluoromethanesulfonato-kappa2O:O')].
The title compound, [Mn(CF(3)SO(3))(2)(CH(3)CN)(2)](n), has an Mn(II) cation on an inversion centre in an octahedral environment. The trifluoromethanesulfonate anions act as bridging ligands and form a one-dimensional coordination polymer in the direction of the a axis. The F atoms of the trifluoromethanesulfonate anions form layers parallel to the ab plane, but despite short intermolecular distances, no stabilizing F...F interactions are detected. The Mn-N and C-C bonds of the acetonitrile ligand are analyzed according to the Hirshfeld rigid-bond test. Renninger effects in the reflection data are considered, explored and discussed.
Lutz
Martin
M
Bijvoet Center for Biomolecular Research, Crystal and Structural Chemistry, Faculty of Science, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands. m.lutz@uu.nl
Schreurs
Antoine M M
AM
Spek
Anthony L
AL
Moelands
Marcel A H
MA
Klein Gebbink
Robertus J M
RJ
D000838:Anions / Q000737:chemistry; D002412:Cations / Q000737:chemistry; D018360:Crystallography, X-Ray; D008024:Ligands; D008345:Manganese / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry
D000838:Anions; D002412:Cations; D008024:Ligands; D009942:Organometallic Compounds; D011108:Polymers; C547114:poly((bis(acetonitrile-kappaN)manganese(II))-bis(mu-trifluoromethanesulfonato-kappa2O,O')); D008345:Manganese