A two-dimensional metal-organic framework based on a ferromagnetic pentanuclear copper(II).
The hydrothermal reaction of CuSO(4), 1,2-benzenedicarboxylate (phth), and 1,2-bis(imidazol-1-yl)ethane (bime) yields the two-dimensional metal-organic framework {[Cu(5)(bime)(mu(3)-OH)(2)(phth)(4)](H(2)O)(2)}(n) (1), which is based on the pentanuclear copper(II) cluster [Cu(5)(mu(3)-OH)(2)(phth)(4)] and shows dominant ferromagnetic interactions within the pentanuclear cluster.
Zhu
Xia
X
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering and Material Science, Soochow University, Suzhou 215123, People's Republic of China.
Zhao
Jun-Wei
JW
Li
Bao-Long
BL
Song
You
Y
Zhang
Yu-Mei
YM
Zhang
Yong
Y