CH/pi interaction between benzene and hydrocarbons having six carbon atoms in their binary liquid mixtures.
Molecular interactions between benzene and hydrocarbons having six carbon atoms, such as hexane, cyclohexane and 1-hexene in their binary liquid mixtures were studied through the measurements of density, viscosity, self-diffusion coefficient, (13)C NMR spin-lattice relaxation time and (1)H NMR chemical shift. CH/pi attraction between hexane and benzene in their binary mixture was observed in a relatively benzene rich region, whereas a special attractive interaction was not observed between cyclohexane and benzene. On the other hand, 1-hexene and benzene in their binary mixtures were characteristic in their self-diffusion coefficient behaviors: 1-hexene more strongly attract benzene not only by the CH/pi attraction but also probably by the p/p interaction between the double bond in 1-hexene and the p-electron in benzene ring.
Kasahara
Yasutoshi
Y
School of Science, Kitasato University, Sagamihara 228-8555, Japan.
Suzuki
Yuji
Y
Kabasawa
Aino
A
Minami
Hideyuki
H
Matsuzawa
Hideyo
H
Iwahashi
Makio
M
D001554:Benzene / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D006838:Hydrocarbons / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D014783:Viscosity
D006838:Hydrocarbons; D002244:Carbon; D006859:Hydrogen; D001554:Benzene