Anion-exchange-triggered 1,3-shift of an NH proton to iridium in protic n-heterocyclic carbenes: hydrogen-bonding and ion-pairing effects.
Song
Guoyong
G
The Scripps Research Institute, Scripps Florida, Jupiter, FL 33458, USA.
Su
Yan
Y
Periana
Roy A
RA
Crabtree
Robert H
RH
Han
Keli
K
Zhang
Hongjie
H
Li
Xingwei
X
D000838:Anions / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006571:Heterocyclic Compounds / Q000737:chemistry*; D006860:Hydrogen Bonding; D007495:Iridium / Q000737:chemistry*; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008968:Molecular Conformation; D011522:Protons; D013816:Thermodynamics; D014867:Water / Q000737:chemistry
D000838:Anions; D006571:Heterocyclic Compounds; D011522:Protons; D014867:Water; C030011:carbene; D007495:Iridium; D008697:Methane