Tandem Diels-Alder/cross-coupling reactions of generated in situ organoindium reagents in a one-pot process.
Tandem Diels-Alder/cross-coupling reactions with organoindium reagents generated in situ from 1-bromo-2,3-butadiene and indium were developed in a one-pot process. [4 + 2] Cycloaddition reactions using organoindium reagents and subsequent Pd-catalyzed cross-coupling reactions provided the rapid synthesis of six-membered carbocycles starting from 1-bromo-2,3-butadiene.
Mo
Juntae
J
Department of Chemistry, Kangwon National University, Chuncheon 200-701, Republic of Korea.
Kim
Sung Hong
SH
Lee
Phil Ho
PH