title: BN benzonitrile: an electron-deficient 1,2-dihydro-1,2-azaborine featuring linkage isomerism.
abstract: BN Benzonitrile 2, a 1,2-dihydro-1,2-azaborine bearing an electron-withdrawing boron substituent was prepared and characterized, and its coordination chemistry investigated; reactivity studies revealed that BN benzonitrile 2 undergoes BCN-BNC linkage isomerism upon coordination to Cr(CO)(5).
authors.affiliation: Department of Chemistry, University of Oregon, Eugene, Oregon 97403, USA.
authors.forename: Adam J V
authors.initials: AJ
authors.lastname: Marwitz
authors.forename: Sean P
authors.initials: SP
authors.lastname: McClintock
authors.forename: Lev N
authors.initials: LN
authors.lastname: Zakharov
authors.forename: Shih-Yuan
authors.initials: SY
authors.lastname: Liu
mesh_terms: D001372:Aza Compounds / Q000737:chemistry*; D004583:Electrons; D006571:Heterocyclic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D006841:Hydrocarbons, Aromatic / Q000138:chemical synthesis / Q000737:chemistry*; D015394:Molecular Structure; D009570:Nitriles / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D001372:Aza Compounds; D006571:Heterocyclic Compounds; D006841:Hydrocarbons, Aromatic; D009570:Nitriles; C014356:benzonitrile