title: Novel dienone-phenol type rearrangement of 4,4-disubstituted cyclohexadienone system using thiosilane.
abstract: Thiosilane and a catalytic amount of a Brønsted acid mediate the novel domino-type rearrangement reaction of the 4,4-disubstituted cyclohexadienones to produce the 3,4-disubstituted benzenethioethers; the key step is 1,2-addition of thiosilane to dienone.
authors.affiliation: Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamada-oka, Suita, Osaka, 565-0871, Japan.
authors.forename: Yasufumi
authors.initials: Y
authors.lastname: Wada
authors.forename: Kouji
authors.initials: K
authors.lastname: Otani
authors.forename: Noriko
authors.initials: N
authors.lastname: Endo
authors.forename: Yasuyuki
authors.initials: Y
authors.lastname: Kita
authors.forename: Hiromichi
authors.initials: H
authors.lastname: Fujioka
mesh_terms: D000143:Acids / Q000737:chemistry; D002384:Catalysis; D053138:Cyclohexenes / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry; D015394:Molecular Structure; D012821:Silanes / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000138:chemical synthesis / Q000737:chemistry
chemical_list: D000143:Acids; D053138:Cyclohexenes; D007659:Ketones; D012821:Silanes; D013438:Sulfhydryl Compounds; C507608:cyclohexadienone