title: A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium(IV) dicarboxylates.
abstract: The exchange of the monocarboxylate ligand of the zirconium methacrylate oxocluster Zr(6)O(4)(OH)(4)(OMc)(12) (OMc = CH(2)=CH(CH(3))COO) with dicarboxylic acids (trans,trans muconic acid and terephthalic acid) leads to porous zirconium dicarboxylates exhibiting the UiO-66 architecture; the mild reaction conditions allow the control of their particle size.
authors.affiliation: Institut Lavoisier, UMR CNRS 8180, Université de Versailles Saint-Quentin, 78035 Versailles cedex, France.
authors.forename: Vincent
authors.initials: V
authors.lastname: Guillerm
authors.forename: Silvia
authors.initials: S
authors.lastname: Gross
authors.forename: Christian
authors.initials: C
authors.lastname: Serre
authors.forename: Thomas
authors.initials: T
authors.lastname: Devic
authors.forename: Matthias
authors.initials: M
authors.lastname: Bauer
authors.forename: Gérard
authors.initials: G
authors.lastname: Férey
mesh_terms: D006843:Hydrocarbons, Chlorinated / Q000737:chemistry*; D010316:Particle Size; D016062:Porosity; D013499:Surface Properties; D013696:Temperature; D015040:Zirconium / Q000737:chemistry*
chemical_list: D006843:Hydrocarbons, Chlorinated; D015040:Zirconium