Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides.
An unprecedented copper-catalysed allylic transposition enables the regioselective synthesis of branched allylic silanes from linear allylic halides through direct C-Si bond formation.
Vyas
Devendra J
DJ
Organisch-Chemisches Institut, Westfälische Wilhelms-Universität, Corrensstrasse 40, D-48149 Münster, Germany.
Oestreich
Martin
M