Uranium-hydrogen interactions: synthesis and crystal structures of tris(N,N-dimethylaminodiboranato)uranium(III).
The reaction of UCl(4) with Na(H(3)BNMe(2)BH(3)) in diethyl ether affords the uranium(III) product U(H(3)BNMe(2)BH(3))(3), which has been crystallized in two different structural isomers depending on the crystallization solvent. Both forms are polymeric, but the nature of the bridging interaction is different in the two forms.
Daly
Scott R
SR
School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, IL 61801, USA.
Girolami
Gregory S
GS