title: Survey of Ar-tagged predissociation and vibrationally mediated photodetachment spectroscopies of the vinylidene anion, C2H2-.
abstract: We report predissociation spectra of Ar-tagged C(2)H(2)(-) and C(2)D(2)(-) anions, and explore vibrationally mediated photodetachment from various vibrational levels of the bare C(2)H(2)(-) ion using velocity-map imaging. Intense photodetachment resonances are observed in the C-H stretching region that are strongly correlated with vibrational hot bands in the anion photoelectron spectra, indicating that one-color, resonant two-photon photodetachment (R2PD) is complicated by excitation of vibrationally excited states with autodetaching upper levels embedded in the continuum. Isolation of the R2PD spectrum was achieved using a two-color, IR-IR scheme in which vibrational excitation and photodetachment were carried out in two separate laser interaction regions.
authors.affiliation: Sterling Chemistry Laboratory, Yale University, P.O. Box 208107, New Haven, Connecticut 06520, USA.
authors.forename: Helen K
authors.initials: HK
authors.lastname: Gerardi
authors.forename: Kristin J
authors.initials: KJ
authors.lastname: Breen
authors.forename: Timothy L
authors.initials: TL
authors.lastname: Guasco
authors.forename: Gary H
authors.initials: GH
authors.lastname: Weddle
authors.forename: George H
authors.initials: GH
authors.lastname: Gardenier
authors.forename: Jennifer E
authors.initials: JE
authors.lastname: Laaser
authors.forename: Mark A
authors.initials: MA
authors.lastname: Johnson