title: Pd-catalyzed oxidative coupling with organometallic reagents via C-H activation.
abstract: Direct selective palladium catalyzed C-H functionalization has become a highly attractive strategy in organic synthesis and represents a highly desirable goal. Compared with cross-coupling reactions of C-H bonds with aryl or alkyl halides/pseudohalides, the strategy of cross-coupling reactions of C-H bonds with organometallic reagents is of great significance and obvious advantages. This feature article provides a comprehensive summary of recent advances and an intensive analysis on Pd-catalyzed C-H activation and oxidative coupling with various organometallic reagents.
authors.affiliation: Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, Peking University, Beijing, China.
authors.forename: Chang-Liang
authors.initials: CL
authors.lastname: Sun
authors.forename: Bi-Jie
authors.initials: BJ
authors.lastname: Li
authors.forename: Zhang-Jie
authors.initials: ZJ
authors.lastname: Shi
mesh_terms: D002384:Catalysis; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D010165:Palladium / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; D010165:Palladium