BN benzonitrile: an electron-deficient 1,2-dihydro-1,2-azaborine featuring linkage isomerism.
BN Benzonitrile 2, a 1,2-dihydro-1,2-azaborine bearing an electron-withdrawing boron substituent was prepared and characterized, and its coordination chemistry investigated; reactivity studies revealed that BN benzonitrile 2 undergoes BCN-BNC linkage isomerism upon coordination to Cr(CO)(5).
Marwitz
Adam J V
AJ
Department of Chemistry, University of Oregon, Eugene, Oregon 97403, USA.
McClintock
Sean P
SP
Zakharov
Lev N
LN
Liu
Shih-Yuan
SY
D001372:Aza Compounds / Q000737:chemistry*; D004583:Electrons; D006571:Heterocyclic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D006841:Hydrocarbons, Aromatic / Q000138:chemical synthesis / Q000737:chemistry*; D015394:Molecular Structure; D009570:Nitriles / Q000737:chemistry*; D013237:Stereoisomerism
D001372:Aza Compounds; D006571:Heterocyclic Compounds; D006841:Hydrocarbons, Aromatic; D009570:Nitriles; C014356:benzonitrile