Vanadium(II) heptacyanomolybdate(III)-based magnet exhibiting a high curie temperature of 110 K.
We prepared a vanadium heptacyanomolybdate-based magnet, V(II)(2)[Mo(III)(CN)(7)].(pyrimidine)(2).4.5H(2)O (VMo), with a Curie temperature (T(C)) of 110 K, which is the highest T(C) value in [Mo(III)(CN)(7)]-based magnets. Additionally, Mn(II)(2)[Mo(III)(CN)(7)].(pyrimidine)(2).2H(2)O (MnMo) of a monoclinic structure (P2(1)/n) with T(C) = 47 K was prepared to confirm the crystal structure of VMo.
Tomono
Keisuke
K
Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Toyko 113-0033, Japan.
Tsunobuchi
Yoshihide
Y
Nakabayashi
Koji
K
Ohkoshi
Shin-Ichi
S