title: A comparison of total maximum daily load (TMDL) calculations in urban streams using near real-time and periodic sampling data.
abstract: A network of in situ sensors and nutrient analyzers was deployed to measure nitrate, specific conductance (surrogate for chloride), and turbidity (surrogate for total suspended solids (TSS)) for 28 days in two urban streams near Minneapolis, MN. The primary objectives of the study were: (1) to determine the accuracy associated with quantifying pollutant loading using periodic discrete (i.e., grab) samples in comparison to in situ near real-time monitoring and (2) to identify pollutant sources. Within a highly impervious drainage area (>35%) the majority of pollutant load (>90% for nitrate, chloride, and TSS) was observed to be discharged in a small percentage of time (<20%). Consequently, periodic sampling is prone to underestimate pollutant loads. Additionally, when compared to loads based on near real-time sampling, average errors of 19-200% were associated with sampling 1-2 times a month. There are also limitations of periodic sampling with respect to pollutant source determination. Resulting implications with regard to total maximum daily load (TMDL) assessments are discussed.
authors.affiliation: Department of Civil Engineering, University of Minnesota, 500 Pillsbury Dr. SE, Minneapolis, MN 55455, USA.
authors.forename: Michael B
authors.initials: MB
authors.lastname: Henjum
authors.forename: Raymond M
authors.initials: RM
authors.lastname: Hozalski
authors.forename: Christine R
authors.initials: CR
authors.lastname: Wennen
authors.forename: Paige J
authors.initials: PJ
authors.lastname: Novak
authors.forename: William A
authors.initials: WA
authors.lastname: Arnold
mesh_terms: D000465:Algorithms; D002712:Chlorides / Q000032:analysis; D002947:Cities; D004784:Environmental Monitoring / Q000379:methods*; D019015:Geologic Sediments / Q000032:analysis / Q000737:chemistry; D008910:Minnesota; D009566:Nitrates / Q000032:analysis; D018570:Risk Assessment; D045483:Rivers / Q000737:chemistry*; D013997:Time Factors; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D002712:Chlorides; D009566:Nitrates; D014874:Water Pollutants, Chemical