Phosphorus recovery by struvite crystallization in WWTPs: influence of the sludge treatment line operation.
Phosphorus recovery by struvite (MgNH(4)PO(4).6H(2)O) crystallization is one of the most widely recommended technologies for treating sludge digester liquors especially in wastewater treatments plants (WWTP) with enhanced biological phosphorus removal (EBPR). In this paper, phosphorus recovery by struvite crystallization is assessed using the rejected liquors resulting from four different operational strategies of the sludge treatment line. Phosphorus precipitation and recovery efficiencies of between 80-90% and 70-85%, respectively, were achieved in the four experiments. The precipitates formed were mainly struvite, followed by amorphous calcium phosphate and, in some experiments, by calcite. The highest global phosphorus recovery taking into account both the sludge line and the crystallizer was achieved when mixed thickening and high elutriation were carried out (8.4 gP/kg treated sludge). However, low struvite content was obtained in the crystallizer with this operation scheme due to the high calcium content in the elutriation stream. Therefore, if the final purpose is to obtain struvite, the reduction of the elutriation flowrate is widely recommended in the case of high water hardness.
Martí
N
N
Dpto. Ingeniería Química, Universidad de Valencia, Doctor Moliner 50, 46100 Burjassot, Valencia, Spain.
Pastor
L
L
Bouzas
A
A
Ferrer
J
J
Seco
A
A
D000465:Algorithms; D002119:Calcium Carbonate / Q000737:chemistry; D002130:Calcium Phosphates / Q000737:chemistry; D011232:Chemical Precipitation; D003460:Crystallization; D017616:Magnesium Compounds / Q000737:chemistry*; D010710:Phosphates / Q000737:chemistry*; D010758:Phosphorus / Q000737:chemistry*; D015203:Reproducibility of Results; D012722:Sewage / Q000737:chemistry*; D000069877:Struvite; D014865:Waste Disposal, Fluid / Q000379:methods*; D018508:Water Purification / Q000379:methods; D014961:X-Ray Diffraction
D002130:Calcium Phosphates; D017616:Magnesium Compounds; D010710:Phosphates; D012722:Sewage; C519480:amorphous calcium phosphate; D010758:Phosphorus; D000069877:Struvite; D002119:Calcium Carbonate