title: Micellar-mediated extractive spectrophotometric determination of hydrogen sulfide/sulfide through Prussian Blue reaction: application to environmental samples.
abstract: A sensitive surfactant-mediated extractive spectrophotometric method has been developed, based on the reaction of ferric iron with sulfide to form ferrous iron and its subsequent reaction with ferricyanide to form Prussian Blue, to quantify trace levels of hydrogen sulfide/sulfide in environmental samples. The method obeys Beer's law in the concentration range 2-10 microg of sulfide in 25 mL of aqueous phase with molar absorptivity (epsilon) of 3.92 x 10(4) L mol(-1) cm(-1). The colored species has been extracted into isoamyl acetate in the presence of a cationic surfactant i.e. cetylpyridinium chloride, to enhance the sensitivity of the method with epsilon value 5.2 x 10(4) L mol(-1) cm(-1). The relative standard deviation has been found to be 0.69% for 10 determinations at 4 microg of sulfide and the limit of detection was 0.009 microg mL(-1). The interference from common anions and cations has been studied. The proposed method has been applied to the determination of residual hydrogen sulfide in the laboratory fume hood as well as ambient atmospheric hydrogen sulfide in the vicinity of open sewer lines after fixing the analyte in ionic form using suitable trapping medium.
authors.affiliation: Department of Studies in Chemistry, Bangalore University, Central College Campus, Dr Ambedkar Veedi, Bangalore-560 001, India. mprangachem@gmail.com
authors.forename: Malingappa
authors.initials: M
authors.lastname: Pandurangappa
authors.forename: Devaramani
authors.initials: D
authors.lastname: Samrat
mesh_terms: D000393:Air Pollutants / Q000032:analysis*; D004784:Environmental Monitoring; D005290:Ferric Compounds / Q000737:chemistry; D005292:Ferricyanides / Q000737:chemistry; D005295:Ferrocyanides / Q000737:chemistry*; D006862:Hydrogen Sulfide / Q000032:analysis*; D007202:Indicators and Reagents; D008823:Micelles; D012015:Reference Standards; D012722:Sewage / Q000032:analysis; D012997:Solvents; D013056:Spectrophotometry, Ultraviolet; D013501:Surface-Active Agents / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D000393:Air Pollutants; D005290:Ferric Compounds; D005292:Ferricyanides; D005295:Ferrocyanides; D007202:Indicators and Reagents; D008823:Micelles; D012722:Sewage; D012997:Solvents; D013501:Surface-Active Agents; D014874:Water Pollutants, Chemical; C007931:hexacyanoferrate III; C000170:ferric ferrocyanide; D006862:Hydrogen Sulfide