A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium(IV) dicarboxylates.
The exchange of the monocarboxylate ligand of the zirconium methacrylate oxocluster Zr(6)O(4)(OH)(4)(OMc)(12) (OMc = CH(2)=CH(CH(3))COO) with dicarboxylic acids (trans,trans muconic acid and terephthalic acid) leads to porous zirconium dicarboxylates exhibiting the UiO-66 architecture; the mild reaction conditions allow the control of their particle size.
Guillerm
Vincent
V
Institut Lavoisier, UMR CNRS 8180, Université de Versailles Saint-Quentin, 78035 Versailles cedex, France.
Gross
Silvia
S
Serre
Christian
C
Devic
Thomas
T
Bauer
Matthias
M
Férey
Gérard
G
D006843:Hydrocarbons, Chlorinated / Q000737:chemistry*; D010316:Particle Size; D016062:Porosity; D013499:Surface Properties; D013696:Temperature; D015040:Zirconium / Q000737:chemistry*
D006843:Hydrocarbons, Chlorinated; D015040:Zirconium