Tracking the formation of cobalt substituted ALPO-5 using simultaneous in situ X-ray diffraction and X-ray absorption spectroscopy techniques.
We followed the formation of metal ion substituted aluminophosphate, a redox molecular sieve, using a newly developed in situ simultaneous X-ray diffraction and X-ray absorption spectroscopic technique. The study showed that a cobalt-phosphorous network forms prior to the crystallisation.
Simmance
Kerry
K
Department of Chemistry, University College London, 20 Gordon Street, London, UK WC1H 0AJ.
Sankar
Gopinathan
G
Bell
Robert G
RG
Prestipino
Carmelo
C
van Beek
Wouter
W