title: How the shape of an H-bonded network controls proton-coupled water activation in HONO formation.
abstract: Many chemical reactions in atmospheric aerosols and bulk aqueous environments are influenced by the surrounding solvation shell, but the precise molecular interactions underlying such effects have rarely been elucidated. We exploited recent advances in isomer-specific cluster vibrational spectroscopy to explore the fundamental relation between the hydrogen (H)-bonding arrangement of a set of ion-solvating water molecules and the chemical activity of this ensemble. We find that the extent to which the nitrosonium ion (NO+)and water form nitrous acid (HONO) and a hydrated proton cluster in the critical trihydrate depends sensitively on the geometrical arrangement of the water molecules in the network. Theoretical analysis of these data details the role of the water network in promoting charge delocalization.
authors.affiliation: Department of Chemistry, Yale University, Post Office Box 208107, New Haven, CT 06520, USA.
authors.forename: Rachael A
authors.initials: RA
authors.lastname: Relph
authors.forename: Timothy L
authors.initials: TL
authors.lastname: Guasco
authors.forename: Ben M
authors.initials: BM
authors.lastname: Elliott
authors.forename: Michael Z
authors.initials: MZ
authors.lastname: Kamrath
authors.forename: Anne B
authors.initials: AB
authors.lastname: McCoy
authors.forename: Ryan P
authors.initials: RP
authors.lastname: Steele
authors.forename: Daniel P
authors.initials: DP
authors.lastname: Schofield
authors.forename: Kenneth D
authors.initials: KD
authors.lastname: Jordan
authors.forename: Albert A
authors.initials: AA
authors.lastname: Viggiano
authors.forename: Eldon E
authors.initials: EE
authors.lastname: Ferguson
authors.forename: Mark A
authors.initials: MA
authors.lastname: Johnson