Zinc(II)-boron(III)-imidazolate framework (ZBIF) with unusual pentagonal channels prepared from deep eutectic solvent.
The first zinc(II)-boron(III)-imidazolate porous material Zn(2)(im)Cl(2)[B(im)(4)] (ZBIF-1, im = imidazolate) integrating the structural features of two distinctly different imidazolate frameworks (i.e., ZIFs with the Zn-im linkage and BIFs with B(im)(4)(-) complex) has been realized by utilizing the unique chemistry of deep eutectic solvents.
Chen
Shumei
S
Department of Chemistry and Biochemistry, California State University, Long Beach, 1250 Bellflower Boulevard, Long Beach, CA 90840, USA.
Zhang
Jian
J
Wu
Tao
T
Feng
Pingyun
P
Bu
Xianhui
X