title: Long-term sustainability of metal immobilization by soil amendments: cyclonic ashes versus lime addition.
abstract: A soil column leaching experiment was used to gain insight into the long-term metal immobilization capacity of cyclonic ashes (CAH) compared to lime (LIME). Twenty six years of rainfall were simulated. Initially, all amended soils were brought to an equal soil pH. This was done to obtain optimal conditions for the detection of metal immobilization mechanisms different from just a pH effect. During the simulation period, soil pH in all treatments decreased in parallel. However, the evolution of metal mobility and phytoavailability showed a clearly distinct pattern. The strong reduction in metal immobilizing efficiency observed in the lime treatment at the end of the simulation period was much less pronounced, or even absent, in the CAH treatments. Moreover, metal accumulation in plants grown on the CAH amended soil was significantly lower compared to the untreated and the lime treated soil. CAH + SS treatment delivered the strongest reductions in metal mobility and bioavailability.
authors.affiliation: Hasselt University, Centre for Environmental Sciences, Agoralaan, building D, B-3590 Diepenbeek, Belgium.
authors.forename: A
authors.initials: A
authors.lastname: Ruttens
authors.forename: K
authors.initials: K
authors.lastname: Adriaensen
authors.forename: E
authors.initials: E
authors.lastname: Meers
authors.forename: A
authors.initials: A
authors.lastname: De Vocht
authors.forename: W
authors.initials: W
authors.lastname: Geebelen
authors.forename: R
authors.initials: R
authors.lastname: Carleer
authors.forename: M
authors.initials: M
authors.lastname: Mench
authors.forename: J
authors.initials: J
authors.lastname: Vangronsveld
mesh_terms: D000327:Adsorption; D017610:Calcium Compounds / Q000737:chemistry; D002622:Chemistry, Agricultural / Q000295:instrumentation* / Q000379:methods; D004784:Environmental Monitoring; D008670:Metals / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry; D012989:Soil Pollutants / Q000737:chemistry*
chemical_list: D017610:Calcium Compounds; D008670:Metals; D010087:Oxides; D012989:Soil Pollutants; C016538:lime