Nickel-catalyzed efficient and practical Suzuki-Miyaura coupling of alkenyl and aryl carbamates with aryl boroxines.
Suzuki-Miyaura coupling of unactivated alkenyl carbamates is described to construct polysubstituted olefins. The developed process is also suitable for heteroaromatic and even electron-rich aromatic carbamates.
Xu
Li
L
Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Green Chemistry Center, Peking University, Department of Chemistry, Chengdu, Sichuan, China.
Li
Bi-Jie
BJ
Wu
Zhen-Hua
ZH
Lu
Xing-Yu
XY
Guan
Bing-Tao
BT
Wang
Bi-Qin
BQ
Zhao
Ke-Qing
KQ
Shi
Zhang-Jie
ZJ
D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry; D001896:Boron Compounds / Q000737:chemistry*; D002219:Carbamates / Q000138:chemical synthesis / Q000737:chemistry*; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*
D000475:Alkenes; D001896:Boron Compounds; D002219:Carbamates; D009532:Nickel