Europium complexes of a novel ethylenedioxythiophene-derivatized bis(pyrazolyl)pyridine ligand exhibiting efficient lanthanide sensitization.
A new class of highly luminescent nine-coordinated europium(III) tris(beta-diketonate) bis[(ethylenedioxythiophene)pyrazolyl]pyridine (L) complexes has been synthesized and the photophysical properties studied: 1 = Eu(hfac)(3)(L); 2 = Eu(tta)(3)(L); 3 = Eu(btfac)(3)(L). The solid-state structure of complex 1 has been determined by single-crystal X-ray crystallography and shows the geometry of the local coordination environment around the Eu(III) ion to be a slightly distorted tricapped trigonal prism. Luminescence lifetimes were found to be 581, 473, and 576 micros for complexes 1-3, respectively. Absolute quantum yields for complexes 1-3 were measured as 16.4 +/- 1.4%, 27.5 +/- 1.2%, and 22.2% +/- 0.3%, respectively.
Stanley
Julie M
JM
Department of Chemistry and Biochemistry and Center for Electrochemistry, The University of Texas at Austin, 1 University Station, A5300, Austin, Texas 78712-0165, USA.
Zhu
Xunjin
X
Yang
Xiaoping
X
Holliday
Bradley J
BJ
D000042:Absorption; D005063:Europium / Q000737:chemistry*; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D008024:Ligands; D049408:Luminescent Agents / Q000138:chemical synthesis / Q000737:chemistry; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*; D013876:Thiophenes / Q000737:chemistry*
D028581:Lanthanoid Series Elements; D008024:Ligands; D049408:Luminescent Agents; D009942:Organometallic Compounds; D011725:Pyridines; D013876:Thiophenes; D005063:Europium