Rhodium-catalyzed dehydrogenative borylation of cyclic alkenes.
A rhodium-catalyzed dehydrogenative borylation of cyclic alkenes is described. This reaction provides direct access to cyclic 1-alkenylboronic acid pinacol esters, useful intermediates in organic synthesis. Suzuki-Miyaura cross-coupling applications are also presented.
Kondoh
Azusa
A
Massachusetts Institute of Technology, Department of Chemistry, Cambridge, Massachusetts 02139, USA.
Jamison
Timothy F
TF
D001895:Boron / Q000737:chemistry*; D002384:Catalysis; D003516:Cycloparaffins / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry; D012238:Rhodium / Q000737:chemistry*
D003516:Cycloparaffins; D010720:Phosphines; D012238:Rhodium; C044646:phosphine; D001895:Boron