title: Linear and V-shaped nonlinear optical chromophores with multiple 4H-pyran-4-ylidene moieties.
abstract: A simple synthesis of dipolar one- and two-dimensional chromophores bearing two or three 4H-pyran-4-ylidene moieties is reported. Whereas the pyranylidene fragments acting as donors are proaromatic, the spacer one is not. In the linear derivatives, chain elongation gives rise to a sharp increase in the second order nonlinear optical responses, but some V-shaped derivatives display first hyperpolarizabilities (beta) lower than those of their linear analogues. This uncommon feature lends experimental support to previous theoretical studies on the relative contribution and sign of the beta-tensor components.
authors.affiliation: Departamento de Química Orgánica, ICMA, Universidad de Zaragoza-CSIC, 50009 Zaragoza, Spain.
authors.forename: Raquel
authors.initials: R
authors.lastname: Andreu
authors.forename: Elena
authors.initials: E
authors.lastname: Galán
authors.forename: Javier
authors.initials: J
authors.lastname: Garín
authors.forename: Vanessa
authors.initials: V
authors.lastname: Herrero
authors.forename: Edurne
authors.initials: E
authors.lastname: Lacarra
authors.forename: Jesús
authors.initials: J
authors.lastname: Orduna
authors.forename: Raquel
authors.initials: R
authors.lastname: Alicante
authors.forename: Belén
authors.initials: B
authors.lastname: Villacampa