title: Unexpected chemoselectivity in the Schiff condensation of amines with eta(2)(C,O)- eta(1)(O)-coordinated aldehyde.
abstract: The aldehyde function coordinated as eta(1); eta(2) is able to discriminate between aliphatic and aromatic amines in the Schiff condensation reaction.
authors.affiliation: IU CINQUIMA, Química Inorgánica, Universidad de Valladolid, E-47005, Valladolid, Spain.
authors.forename: Celedonio M
authors.initials: CM
authors.lastname: Alvarez
authors.forename: Raúl
authors.initials: R
authors.lastname: García-Rodríguez
authors.forename: Jose M
authors.initials: JM
authors.lastname: Martín-Alvarez
authors.forename: Daniel
authors.initials: D
authors.lastname: Miguel
mesh_terms: D000447:Aldehydes / Q000737:chemistry*; D000588:Amines / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008968:Molecular Conformation; D008982:Molybdenum / Q000737:chemistry; D012545:Schiff Bases / Q000737:chemistry
chemical_list: D000447:Aldehydes; D000588:Amines; D012545:Schiff Bases; D008982:Molybdenum