Difatty acyl urea from corn oil: synthesis and characterization.
In this study, difatty acyl urea has been successfully synthesized from corn oil using sodium ethoxide as a catalyst. Ethyl fatty ester and glycerol were produced as by-products. In this reaction, corn oil was refluxed with urea in ethanol. The highest conversion percentage (78%) was obtained when the process was carried out for 8 hours using urea to corn oil ratio of 5.6: 1.0 at 78 degrees C. Both difatty acyl urea and ethyl fatty ester have been characterized using elemental analysis, Fourier transform infrared (FTIR) spectroscopy and (1)H nuclear magnetic resonance (NMR) technique.
Al-Mulla
Emad A Jaffar
EA
Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, Serdang, Selangor, Malaysia.
Yunus
Wan Md Zin Wan
WM
Ibrahim
Nor Azowa Bt
NA
Rahman
Mohd Zaki A
MZ
D002384:Catalysis; D003314:Corn Oil / Q000737:chemistry*; D004952:Esters / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D017550:Spectroscopy, Fourier Transform Infrared; D014508:Urea / Q000138:chemical synthesis* / Q000737:chemistry*
D004952:Esters; D003314:Corn Oil; D014508:Urea