Synthesis and structure of D(3h)-symmetric triptycene trimaleimide.
A new D(3h) symmetric triptycene derivative has been synthesized with the aim of obtaining molecules that are able to assemble into porous structures, and can be used in the development of new ligands. The synthesis involves a Diels-Alder reaction as the key step, followed by an oxidation and the formation of a maleimide ring. Triptycene trimaleimide furnished single crystals which have been analyzed by means of X-ray diffraction.
Zonta
Cristiano
C
Dipartimento di Scienze Chimiche, Università di Padova, via Marzolo 1, 35131 Padova, Italy. cristiano.zonta@unipd.it
De Lucchi
Ottorino
O
Linden
Anthony
A
Lutz
Martin
M
D000873:Anthracenes / Q000138:chemical synthesis* / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008301:Maleimides / Q000138:chemical synthesis* / Q000737:chemistry*; D008958:Models, Molecular
D000873:Anthracenes; D008301:Maleimides; C520712:triptycene