Homogeneous photocatalytic production of hydrogen from water by a bioinspired [Fe(2)S(2)] catalyst with high turnover numbers.
A three-component homogeneous catalyst system, composed of a cyclometalated iridium(iii) photosensitizer, a bioinspired diiron complex, and TEA in aqueous acetone, proved to be catalytically active for photoinduced H(2) production, with up to 660 turnovers over 8 h of irradiation.
Zhang
Pan
P
State Key Laboratory of Fine Chemicals, DUT-KTH Joint Education and Research Center on Molecular Devices, Dalian University of Technology (DUT), Dalian, 116012, China.
Wang
Mei
M
Na
Yong
Y
Li
Xueqiang
X
Jiang
Yi
Y
Sun
Licheng
L