title: Electrochemical reactivity of aromatic molecules at nanometer-sized surface domains: from Pt(hkl) single crystal electrodes to preferentially oriented platinum nanoparticles.
abstract: This manuscript compares the electrochemically controlled adsorption of hydroquinone-derived adlayers and their reductive desorption from nanometer-sized Pt(111) domains present on the surface (i) of model stepped single-crystal electrodes and (ii) of preferentially oriented Pt nanoparticles. The results obtained using a stepped surface series, i.e., Pt(S)[(n - 1)(111)x(110)], suggest that in the presence of 2 mM H(2)Q((aq)) the electrochemically detected desorption-adsorption process takes place selectively from ordered Pt(111) domains present as terraces, while being precluded at other available surface sites, i.e., Pt(110) steps, where adsorption takes place irreversibly. This domain-selective electroanalytical detection scheme is employed later to selectively monitor desorption-adsorption of hydroquinone-derived adlayers from ordered, nanometer-scaled Pt(111) domains on the surface of preferentially oriented Pt nanoparticles, confirming the existence of well-ordered (111) domains on the surface of the Pt nanoparticles. A good correlation is noted between the electrochemical behavior at well-ordered Pt(hkl) surfaces and at preferentially oriented Pt nanoparticles. Key learnings and potential applications are discussed. The results demonstrate the technical feasibility of performing domain-selective decapping of nanoparticles by handle of an externally controlled parameter, i.e., the applied potential.
authors.affiliation: Department of Chemistry, Pontifical Catholic University of Puerto Rico, Ponce, Puerto Rico.
authors.forename: Margarita
authors.initials: M
authors.lastname: Rodríguez-López
authors.forename: Jose
authors.initials: J
authors.lastname: Solla-Gullón
authors.forename: Enrique
authors.initials: E
authors.lastname: Herrero
authors.forename: Paulino
authors.initials: P
authors.lastname: Tuñón
authors.forename: Juan M
authors.initials: JM
authors.lastname: Feliu
authors.forename: Antonio
authors.initials: A
authors.lastname: Aldaz
authors.forename: Arnaldo
authors.initials: A
authors.lastname: Carrasquillo