title: The efficient synthesis of dibenzo[d,d']benzo[1,2-b:4,3-b']dithiophene and cyclopenta[1,2-b:4,3-b']bis(benzo[d]thiophen)-6-one.
abstract: With 3,3'-bi[benzo[b]thiophenyl] as starting material, dibenzo[d,d']benzo[1,2-b:4,3-b']dithiophene, a [5]heterohelicene, was synthesized efficiently in 60% yield via formylation and McMurry reaction. Cyclopenta[1,2-b:4,3-b']bis(benzo[d]thiophen)-6-one, another interesting helical ketone, was also prepared in 79% yield via deprotonation and ketonization of 3,3'-bi[benzo[b]thiophenyl]. In addition, the single-crystal structure of dibenzo[d,d']benzo[1,2-b:4,3-b']dithiophene and UV-vis spectra of both title compounds are described.
authors.affiliation: Key Lab for Special Functional Materials of Ministry of Education, Henan University, Kaifeng 475004, China.
authors.forename: Zhihua
authors.initials: Z
authors.lastname: Wang
authors.forename: Sheng
authors.initials: S
authors.lastname: Zhu
authors.forename: Jianwu
authors.initials: J
authors.lastname: Shi
authors.forename: Hua
authors.initials: H
authors.lastname: Wang