title: Silicon nanosheets and their self-assembled regular stacking structure.
abstract: Silicon nanomaterials are encouraging candidates for application to photonic, electronic, or biosensing devices, due to their size-quantization effects. Two-dimensional silicon nanosheets could help to realize a widespread quantum field, because of their nanoscale thickness and microscale area. However, there has been no example of a successful synthesis of two-dimensional silicon nanomaterials with large lateral size and oxygen-free surfaces. Here we report that oxygen-free silicon nanosheets covered with organic groups can be obtained by exfoliation of layered polysilane as a result of reaction with n-decylamine and dissolution in an organic solvent. The amine residues are covalently bound to the Si(111) planes. It is estimated that there is ca. 0.7 mol of residue per mole of Si atoms in the reaction product. The amine-modified layered polysilane can dissolve in chloroform and exfoliate into nanosheets that are 1-2 microm wide in the lateral direction and with thicknesses on the order of nanometers. The nanosheets have very flat and smooth surfaces due to dense coverage of n-decylamine, and they are easily self-assembled in a concentrated state to form a regularly stacked structure. The nanosheets could be useful as building blocks to create various composite materials.
authors.affiliation: Toyota Central R&D Laboratories, Inc., Nagakute, Aichi 480-1192, Japan. h-okamoto@mosk.tytlabs.co.jp
authors.forename: Hirotaka
authors.initials: H
authors.lastname: Okamoto
authors.forename: Yoko
authors.initials: Y
authors.lastname: Kumai
authors.forename: Yusuke
authors.initials: Y
authors.lastname: Sugiyama
authors.forename: Takuya
authors.initials: T
authors.lastname: Mitsuoka
authors.forename: Koji
authors.initials: K
authors.lastname: Nakanishi
authors.forename: Toshiaki
authors.initials: T
authors.lastname: Ohta
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Nozaki
authors.forename: Satoshi
authors.initials: S
authors.lastname: Yamaguchi
authors.forename: Soichi
authors.initials: S
authors.lastname: Shirai
authors.forename: Hideyuki
authors.initials: H
authors.lastname: Nakano