title: Multidimensional GC coupled to MS for the simultaneous determination of oxygenate compounds and BTEX in gasoline.
abstract: In the present work, carried out in relation to the European and American Directives on the quality of petrol and diesel fuels, the simultaneous determination of the oxygenate compounds and BTEX in gasoline was achieved through the use of a multidimensional GC (MDGC)/MS system, employing a Deans switch-based transfer system, with an innovative configuration; the latter enabled multiple heart-cut transfers with no hint of retention time shift, a phenomenon that can occur in MDGC, providing the possibility to achieve more then 20 different heart-cuts for the compounds of interest. In this study, 20 selected compounds were quantitatively transferred with 12 heart-cuts, from a first to a secondary column, in order to resolve primary column co-elutions. Analyte quantification and identification was achieved through a fast-scanning quadrupole mass analyzer, operated in full scan mode, in order to evaluate also the interfering compounds transferred together with the compounds of interest. The multidimensional method developed was subjected to validation. All attained data were in excellent correlation with results obtained through the UNI-EN 12177:2000, ASTM D 5580-02 and ASTM D 4815-04 MDGC methods, for the determination of benzene, BTEX and oxygenate compounds in gasoline, respectively.
authors.affiliation: Dipartimento Farmaco-chimico, Facoltà di Farmacia, Università di Messina, Messina, Italy.
authors.forename: Danilo
authors.initials: D
authors.lastname: Sciarrone
authors.forename: Peter Quinto
authors.initials: PQ
authors.lastname: Tranchida
authors.forename: Carla
authors.initials: C
authors.lastname: Ragonese
authors.forename: Luisa
authors.initials: L
authors.lastname: Schipilliti
authors.forename: Luigi
authors.initials: L
authors.lastname: Mondello
mesh_terms: D001554:Benzene / Q000032:analysis* / Q000737:chemistry; D001555:Benzene Derivatives / Q000032:analysis* / Q000737:chemistry; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods; D005742:Gasoline / Q000032:analysis*; D010126:Ozone / Q000032:analysis* / Q000737:chemistry; D014050:Toluene / Q000032:analysis* / Q000737:chemistry; D014992:Xylenes / Q000032:analysis* / Q000737:chemistry
chemical_list: D001555:Benzene Derivatives; D005742:Gasoline; D014992:Xylenes; D014050:Toluene; D010126:Ozone; D001554:Benzene; C004912:ethylbenzene