'Super-reduced' iron under physiologically-relevant conditions.
EPR spectroscopy is employed to demonstrate chemical production of formally Fe(i) and Fe(0) states of phthalocyanines in water at room temperature, and physiologically-relevant pH.
Mot
Augustin
A
Babes-Bolyai University, 11 Arany Janos str, Cluj-Napoca, RO-400028, Romania. rsilaghi@chem.ubbcluj.ro
Zoltan
Kis
K
Svistunenko
Dimitri A
DA
Damian
Grigore
G
Silaghi-Dumitrescu
Radu
R
Makarov
Sergei V
SV
D004578:Electron Spin Resonance Spectroscopy; D006863:Hydrogen-Ion Concentration; D007211:Indoles / Q000737:chemistry; D007501:Iron / Q000737:chemistry*; D054833:Isoindoles; D013056:Spectrophotometry, Ultraviolet; D013696:Temperature; D014867:Water / Q000737:chemistry
D007211:Indoles; D054833:Isoindoles; D014867:Water; D007501:Iron; C013647:phthalocyanine