Microscale hexagonal rods of a charge-assisted second-sphere coordination compound [Co(DABP)3][Fe(CN)6].
A second-sphere complex [Co(DABP)(3)][Fe(CN)(6)] (1) (DABP = 5,5'-diamino-2,2'-bipyridine) is constructed from [Co(DABP)(3)](3+) and [Fe(CN)(6)](3-) through charge-assisted N-H((NH(2)))N((CN)) hydrogen bonds; hexagonal microrods of 1 are obtained via a facile self-assembly method in the presence of surfactant.
Zhuge
Fuyu
F
State Key Laboratory for Oxo Synthesis & Selective Oxidation, Lanzhou Institute of Chemical Physics, CAS, Lanzhou 730000, China.
Wu
Biao
B
Yang
Jin
J
Janiak
Christoph
C
Tang
Ning
N
Yang
Xiao-Juan
XJ