Unexpected chemoselectivity in the Schiff condensation of amines with eta(2)(C,O)- eta(1)(O)-coordinated aldehyde.
The aldehyde function coordinated as eta(1); eta(2) is able to discriminate between aliphatic and aromatic amines in the Schiff condensation reaction.
Alvarez
Celedonio M
CM
IU CINQUIMA, Química Inorgánica, Universidad de Valladolid, E-47005, Valladolid, Spain.
García-Rodríguez
Raúl
R
Martín-Alvarez
Jose M
JM
Miguel
Daniel
D
D000447:Aldehydes / Q000737:chemistry*; D000588:Amines / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008968:Molecular Conformation; D008982:Molybdenum / Q000737:chemistry; D012545:Schiff Bases / Q000737:chemistry
D000447:Aldehydes; D000588:Amines; D012545:Schiff Bases; D008982:Molybdenum