title: Ladder-type oligo-p-phenylene-containing copolymers with high open-circuit voltages and ambient photovoltaic activity.
abstract: Four ladder-type oligo-p-phenylene containing donor-acceptor copolymers were designed, synthesized, and characterized. The ladder-type oligo-p-phenylene was used as an electron donor unit in these copolymers to provide a deeper highest occupied molecular orbital (HOMO) level for obtaining polymer solar cells with a higher open-circuit voltage, while 4,7-dithien-2-yl-2,1,3-benzothiadiazole or 5,8-dithien-2-yl-2,3-diphenylquinoxaline was chosen as an electron acceptor unit to tune the electronic band gaps of the polymers for a better light harvesting ability. These copolymers exhibit field-effect mobilities as high as 0.011 cm(2)/(V s). Compared to fluorene containing copolymers with the same acceptor unit, these ladder-type oligo-p-phenylene containing copolymers have enhanced and bathochromically shifted absorption bands and much better solubility in organic solvents. Photovoltaic applications of these polymers as light-harvesting and hole-conducting materials are investigated in conjunction with [6,6]-phenyl-C61-butyric acid methyl ester (PC(61)BM) or [6,6]-phenyl-C71-butyric acid methyl ester (PC(71)BM). Without extensive optimization work, a power conversion efficiency (PCE) of 3.7% and a high open-circuit voltage of 1.06 V are obtained under simulated solar light AM 1.5 G (100 mW/cm(2)) from a solar cell with an active layer containing 20 wt % ladder-type tetra-p-phenylene containing copolymer (P3FTBT6) and 80 wt % PC(61)BM. Moreover, a high PCE of 4.5% was also achieved from a solar cell with an active layer containing 20 wt % P3FTBT6 and 80 wt % PC(71)BM.
authors.affiliation: Department of Materials Science and Engineering, The Johns Hopkins University, 102 Maryland Hall, 3400 North Charles Street, Baltimore, Maryland 21218, USA.
authors.forename: Qingdong
authors.initials: Q
authors.lastname: Zheng
authors.forename: Byung Jun
authors.initials: BJ
authors.lastname: Jung
authors.forename: Jia
authors.initials: J
authors.lastname: Sun
authors.forename: Howard E
authors.initials: HE
authors.lastname: Katz