Ultraviolet and visible light photodissociation of H3+ in an ion storage ring.
Ultraviolet and visible photodissociation of a vibrationally excited H(3)(+) ion beam, as produced by standard ion sources, was successfully implemented in an ion storage ring with the aim of investigating the decay of the excited molecular levels. A collinear beams configuration was used to measure the photodissociation of H(3)(+) into H(2)(+) + H fragments by transitions into the first excited singlet state with 266 and 532 nm laser beams. A clear signal could be observed up to 5 ms of storage, indicating that enough highly excited rovibrational states survive on the millisecond time scale of the experiment. The decay into H(2)(+) + H shows an effective time constant between about 1 and 1.5 ms. The initial photodissociating states are estimated to lie roughly 1 eV below the dissociation limit of 4.4 eV. The expected low population of these levels gives rise to an effective cross section of several 10(-20) cm(2) for ultraviolet and some 10(-21) cm(2) for visible light. For using multistep resonant dissociation schemes to monitor rotational populations of cold H(3)(+) in low-density environments, these measurements open promising perspectives.
Petrignani
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Max-Planck-Institut für Kernphysik, 69117 Heidelberg, Germany. A.Petrignani@mpi-hd.mpg.de
Bing
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Novotný
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Berg
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Buhr
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Grieser
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Jordon-Thaden
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Krantz
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Mendes
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Menk
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Novotny
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Orlov
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Repnow
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Stützel
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Urbain
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Wolf
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