Removal of polycyclic aromatic hydrocarbons from organic solvents by ashes wastes.
Polycyclic aromatic hydrocarbons (PAHs) can be formed during the refinery processes of crude petroleum. Their removal is of great importance. The same happens with other organic solvents used for the extraction of PAHs (hexane, acetonitrile...), which can be polluted with PAHs. Kinetic and equilibrium batch sorption tests were used to investigate the effect of wood ashes wastes as compared to activated carbon on the sorption of three representative PAHs from n-hexane and acetonitrile. Mussel shell ashes were discarded for batch sorption experiments because they were the only ashes containing PAHs. The equilibrium time was reached at 16 h. Physical sorption caused by the aromatic nature of the compounds was the main mechanism that governed the PAHs removal process. Our investigation revealed that wood ashes obtained at lower temperature (300 degrees C) did not show any PAHs sorption, while ashes obtained at higher temperature (>500 degrees C) have adsorbent sites readily available for the PAH molecules. An increase in the molecular weight of PAHs has a strong effect on sorption wood ashes wastes. As low the wood ashes particle size as high the sorption of PAHs, as a result of differences in adsorbent sites. The performance of wood ash wastes vs. activated carbon to remove 10 PAHs from organic solvents is competitive in price, and a good way for waste disposal.
Pérez-Gregorio
M R
MR
Nutrition and Bromatology Group, Analytical and Food Chemistry Department, Faculty of Food Science and Technology, University of Vigo, Ourense Campus, E32004 Ourense, Spain.
García-Falcón
M S
MS
Martínez-Carballo
E
E
Simal-Gándara
J
J
D000097:Acetonitriles / Q000737:chemistry; D000327:Adsorption; D000818:Animals; D049872:Bivalvia / Q000737:chemistry; D006586:Hexanes / Q000737:chemistry; D007220:Industrial Waste / Q000032:analysis*; D007700:Kinetics; D008970:Molecular Weight; D010316:Particle Size; D011084:Polycyclic Aromatic Hydrocarbons / Q000737:chemistry / Q000302:isolation & purification*; D012997:Solvents / Q000737:chemistry*; D013696:Temperature; D013816:Thermodynamics; D014934:Wood
D000097:Acetonitriles; D006586:Hexanes; D007220:Industrial Waste; D011084:Polycyclic Aromatic Hydrocarbons; D012997:Solvents