Molecular tectonics: crystal engineering of mixed valence Fe(II)/Fe(III) solid solutions.
Based on isostructurality between crystals formed upon combining the dicationic tecton 2 with either M(3)Fe(III)(CN)(6) or M(4)Fe(II)(CN)(6) (M = Cs), a rare example of an H-bonded mixed valence Fe(ii)-Fe(iii) solid solution ((Cs(2)2(3)-[Fe(II)(CN)(6)](2))(0.83)(2(3)-[Fe(III)(CN)(6)](2))(0.17))) and curious necklace-like composite crystals were generated.
Dechambenoit
Pierre
P
Laboratoire de Chimie de Coordination Organique, UMR CNRS 7140, Université de Strasbourg, Institut Le Bel, 4, rue Blaise Pascal, F-67000 Strasbourg, France.
Ferlay
Sylvie
S
Kyritsakas
Nathalie
N
Hosseini
Mir Wais
MW