Synthesis of some new mono- and bis-polycyclic aromatic spiro and bis-nonspiro-beta-lactams.
Some new mono-and bis-polycyclic aromatic spiro-beta-lactams and bis-non spiro-polycyclic aromatic beta-lactams have been synthesized from imines derived from anthracene-9-carbaldehyde, 2-naphtaldehyde and a ketene derived from 9H-xanthene-9-carboxylic acid and phenoxyacetic acid by a [2+2] cycloaddition reaction. The cycloadducts were characterized by spectral data, including 1H-NMR, 13C-NMR, IR and elemental analyses. The configurations of some of these mono-spiro-beta-lactams were established by X-ray crystal analysis.
Jarrahpour
Aliasghar
A
Department of Chemistry, College of Sciences, Shiraz University, Shiraz 71454, Iran. jarrah@susc.ac.ir
Ebrahimi
Edris
E
D018360:Crystallography, X-Ray; D008958:Models, Molecular; D013141:Spiro Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D047090:beta-Lactams / Q000138:chemical synthesis* / Q000737:chemistry
D013141:Spiro Compounds; D047090:beta-Lactams