A rutile-type porous zinc(II)-phosphonocarboxylate framework: local proton transfer and size-selected catalysis.
The layered-solvothermal synthesis of zinc acetate dihydrate with 5-phosphonobenzene-1,3-dicarboxylic acid yields a three-dimensional rutile-type porous metal-organic framework, which is an anionic open-framework containing local proton transfer with hydrated protons and showing excellent size-selective properties.
Liao
Teng-Biao
TB
Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai (200433), China.
Ling
Yun
Y
Chen
Zhen-Xia
ZX
Zhou
Ya-Ming
YM
Weng
Lin-Hong
LH