title: Extension of the charge separated-state lifetime by supramolecular association of a tetrathiafulvalene electron donor to a zinc/gold bisporphyrin.
abstract: Supramolecular triads were prepared by self-assembly of 4'-pyridyl-2-tetrathiafulvalene axially bound on ZnP-spacer-AuP(+) dyads; the lifetime of the charge separated state ((+)TTF-ZnP-Spacer-AuP ) formed upon light excitation of the triad is greatly increased with respect to that found in the parent dyad.
authors.affiliation: CEISAM, Chimie Et Interdisciplinarité, Synthèse, Analyse, Modélisation, CNRS, UMR CNRS 6230, UFR des Sciences et des Techniques 2, rue de la Houssinière - BP 92208, 44322 NANTES Cedex 3, France.
authors.forename: Julien
authors.initials: J
authors.lastname: Boixel
authors.forename: Jérôme
authors.initials: J
authors.lastname: Fortage
authors.forename: Errol
authors.initials: E
authors.lastname: Blart
authors.forename: Yann
authors.initials: Y
authors.lastname: Pellegrin
authors.forename: Leif
authors.initials: L
authors.lastname: Hammarström
authors.forename: Hans-Christian
authors.initials: HC
authors.lastname: Becker
authors.forename: Fabrice
authors.initials: F
authors.lastname: Odobel