title: First efficient synthesis of fluorinated glycidic esters from ketones.
abstract: Treatment of various ketones with ethyl dibromofluoroacetate in the presence of diethylzinc and dimethylaminoethanol or triphenylphosphine provides rapid access to corresponding fluorinated glycidic esters. Simplified workup allowed first characterization of these compounds.
authors.affiliation: INSA de Rouen et Université de Rouen, CNRS UMR 6014 COBRA & FR 3038, IRCOF, Mont-Saint-Aignan Cedex, France.
authors.forename: Gérald
authors.initials: G
authors.lastname: Lemonnier
authors.forename: Ludivine
authors.initials: L
authors.lastname: Zoute
authors.forename: Jean-Charles
authors.initials: JC
authors.lastname: Quirion
authors.forename: Philippe
authors.initials: P
authors.lastname: Jubault
mesh_terms: D002384:Catalysis; D002625:Chemistry, Organic / Q000379:methods; D004852:Epoxy Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D004952:Esters; D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis* / Q000737:chemistry; D007659:Ketones / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D004852:Epoxy Compounds; D004952:Esters; D006845:Hydrocarbons, Fluorinated; D007659:Ketones