title: Insights into the mechanistic photodissociation of methyl formate.
abstract: In this work, we studied the photodissociation dynamics of methyl formate (CH(3)OC(O)H) using state-of-the-art multireference configuration interaction with single and double excitation and the complete active space self-consistent field methods. It was found that the direct alpha-C-O bond cleavage in the first excited singlet state (S(1)) is the dominant dissociation channel, consistent with the recent experiment [S. H. Lee, J. Chem. Phys. 129, 194304 (2008)]. This cleavage mechanism is different from that for aldehydes/ketones where it occurs in the lowest triplet state (T(1)) as a result of the S(1)-->T(1) intersystem crossing. On the basis of comparison to the alpha-bond fission in the asymmetrically substituted aliphatic carbonyl compounds studied previously, we suggest the photolytic reaction of CH(3)OC(O)H as a special type of Norrish type I reaction.
authors.affiliation: Chemistry College, Beijing Normal University, Beijing 100875, People's Republic of China.
authors.forename: Ganglong
authors.initials: G
authors.lastname: Cui
authors.forename: Feng
authors.initials: F
authors.lastname: Zhang
authors.forename: Weihai
authors.initials: W
authors.lastname: Fang